CN117618310A - Hair dye for reducing hair damage and preparation method thereof - Google Patents
Hair dye for reducing hair damage and preparation method thereof Download PDFInfo
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- CN117618310A CN117618310A CN202311677119.8A CN202311677119A CN117618310A CN 117618310 A CN117618310 A CN 117618310A CN 202311677119 A CN202311677119 A CN 202311677119A CN 117618310 A CN117618310 A CN 117618310A
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- 239000000118 hair dye Substances 0.000 title claims abstract description 80
- 230000001603 reducing effect Effects 0.000 title claims abstract description 44
- 230000003700 hair damage Effects 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title abstract description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 34
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 28
- 229940107131 ginseng root Drugs 0.000 claims abstract description 27
- 229920002197 Sodium polyaspartate Polymers 0.000 claims abstract description 26
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 26
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000975 dye Substances 0.000 claims abstract description 21
- 230000029663 wound healing Effects 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 239000002216 antistatic agent Substances 0.000 claims abstract description 14
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- CLAHOZSYMRNIPY-UHFFFAOYSA-N 2-hydroxyethylurea Chemical compound NC(=O)NCCO CLAHOZSYMRNIPY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 240000003377 Shepherdia canadensis Species 0.000 claims abstract description 11
- 235000018324 Shepherdia canadensis Nutrition 0.000 claims abstract description 11
- 239000004359 castor oil Substances 0.000 claims abstract description 11
- 235000019438 castor oil Nutrition 0.000 claims abstract description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 11
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 11
- 229940031575 hydroxyethyl urea Drugs 0.000 claims abstract description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 11
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 11
- 239000002738 chelating agent Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 238000002156 mixing Methods 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 36
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 28
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 17
- 239000011976 maleic acid Substances 0.000 claims description 17
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 16
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 15
- 239000001630 malic acid Substances 0.000 claims description 15
- 235000011090 malic acid Nutrition 0.000 claims description 15
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 14
- 235000006708 antioxidants Nutrition 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 9
- 229960002798 cetrimide Drugs 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 235000010378 sodium ascorbate Nutrition 0.000 claims description 7
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 claims description 7
- 229960005055 sodium ascorbate Drugs 0.000 claims description 7
- 235000010265 sodium sulphite Nutrition 0.000 claims description 7
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 claims description 7
- 229940082500 cetostearyl alcohol Drugs 0.000 claims description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 6
- KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 claims description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 229940113490 2,4-diaminophenoxyethanol hydrochloride Drugs 0.000 claims description 3
- PBVFDMZFBPZIMC-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(OCCO)C(N)=C1 PBVFDMZFBPZIMC-UHFFFAOYSA-N 0.000 claims description 3
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 claims description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- IBCDZZHMNXXYAP-UHFFFAOYSA-N 2-(4,5-diaminopyrazol-1-yl)ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.NC=1C=NN(CCO)C=1N IBCDZZHMNXXYAP-UHFFFAOYSA-N 0.000 claims description 2
- YWNSGSNRKLNTHJ-UHFFFAOYSA-N 2-(4-aminoanilino)ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.NC1=CC=C(NCCO)C=C1 YWNSGSNRKLNTHJ-UHFFFAOYSA-N 0.000 claims description 2
- BMTSZVZQNMNPCT-UHFFFAOYSA-N 2-aminopyridin-3-ol Chemical compound NC1=NC=CC=C1O BMTSZVZQNMNPCT-UHFFFAOYSA-N 0.000 claims description 2
- 229940018563 3-aminophenol Drugs 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 210000004209 hair Anatomy 0.000 abstract description 85
- 230000000694 effects Effects 0.000 abstract description 27
- 230000006378 damage Effects 0.000 abstract description 15
- 238000004040 coloring Methods 0.000 abstract description 13
- 208000027418 Wounds and injury Diseases 0.000 abstract description 11
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 208000014674 injury Diseases 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000000686 essence Substances 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 description 16
- 238000004043 dyeing Methods 0.000 description 16
- 206010052428 Wound Diseases 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 238000010828 elution Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 230000037308 hair color Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000003809 water extraction Methods 0.000 description 4
- 241001289529 Fallopia multiflora Species 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 244000296912 Ageratum conyzoides Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009044 synergistic interaction Effects 0.000 description 2
- 206010013954 Dysphoria Diseases 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
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- 238000007405 data analysis Methods 0.000 description 1
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- 231100000640 hair analysis Toxicity 0.000 description 1
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- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- STZCRXQWRGQSJD-GEEYTBSJSA-M methyl orange Chemical compound [Na+].C1=CC(N(C)C)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-GEEYTBSJSA-M 0.000 description 1
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- 108010064470 polyaspartate Proteins 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
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- 230000003664 tensile strength of the hair Effects 0.000 description 1
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Abstract
The invention relates to the technical field of cosmetics, in particular to a hair dye for reducing hair damage and a preparation method thereof. A hair dye for reducing hair damage, comprising the following components: ammonia water, a thickening agent, an emulsifying agent, a solubilizer, an antioxidant, a chelating agent, a dye, an antistatic agent, essence, sodium polyaspartate, an acidity regulator, hydroxyethyl urea, ginseng root extract, a wound healing villus extract, castor oil maleate, soapberry extract, polydimethylsiloxane and the balance of water. A hair dye for reducing hair injury is prepared by mixing the above materials. The application provides the hair dye with good coloring effect, which can reduce hair damage and ammonia water residue.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to a hair dye for reducing hair damage and a preparation method thereof.
Background
The hair dye has a long history, and as early as the ancient Egypt period, vegetable dyes are used for dyeing hair. With the continuous development of society, people have increasingly high requirements on the diversity and durability of hair colors, and hair dyes mainly containing various chemical substances are sequentially developed. The oxidative hair dye mainly comprises dye composed of intermediate and coupling agent, and is used in combination with color-developing agent prepared from hydrogen peroxide, etc., to permanently color hair.
The oxidative hair dye is used by opening the hair scales of the hair with an alkaline substance such as ammonia water in the first step, thereby promoting the intermediate and coupler to enter the cortex layer of the hair through the opened hair scales. In real life, after ammonia water is selected as an alkaline agent to open hair scales of hair, ammonia water tends to remain in the hair, so that the hair has a long-lasting ammonia smell, and the experience after dyeing is seriously affected. In the prior art, essence is mainly added into the hair dye to cover the smell of ammonia by using the smell of the essence, but the smell of the ammonia can be covered by the essence with stronger smell, so that the smell of hair after dyeing is too strong, and people with very sensitive smell are more difficult to adapt.
Therefore, there is a need for further improving the formulation of hair dye, thereby reducing the residue of ammonia on hair, and further reducing the ammonia smell of hair after dyeing.
Disclosure of Invention
In order to reduce the residue of ammonia water on hair and further reduce the ammonia smell of the hair after dyeing, the application provides a hair dye for reducing hair damage and a preparation method thereof.
In a first aspect, the present application provides a hair dye for reducing hair damage, which adopts the following technical scheme:
a hair dye for reducing hair damage, which comprises the following components in percentage by mass: 5 to 7 percent of ammonia water, 5 to 10 percent of thickening agent, 3 to 6 percent of emulsifying agent, 2 to 4 percent of solubilizer, 0.3 to 0.6 percent of antioxidant, 0.1 to 0.3 percent of chelating agent, 0.33 to 0.76 percent of dye, 1.1 to 3.2 percent of antistatic agent, 0.1 to 0.5 percent of essence, 3 to 5 percent of sodium polyaspartate, 3 to 4.5 percent of acidity regulator, 3 to 5 percent of hydroxyethyl urea, 0.5 to 1 percent of ginseng root extract, 0.5 to 1 percent of extract of wound healing villus flower, 0.4 to 0.8 percent of castor oil maleate, 0.2 to 0.5 percent of soapberry extract, 0.5 to 1 percent of polydimethylsiloxane and the balance of water.
According to the technical scheme, the apple acid regulator is added into the hair dye, so that the pH value of the hair dye can be obviously reduced, and the damage of ammonia water to hair scales of hair is reduced, so that the damage of the hair scales in the hair dyeing process is reduced, and the damage of hair dyeing to the hair is reduced; according to the hair dye, the sodium polyaspartate, the ginseng root extract and the wound villus flower extract are further added, under the good synergistic interaction, the dye can be promoted to enter between the hair scale and the cortex layer better under the condition of small opening degree of the hair scale, so that more macromolecular colored dye is generated through reaction, the hair coloring effect is improved, meanwhile, the compounding of the sodium polyaspartate, the ginseng root extract and the wound villus flower extract also has the unexpected effect of reducing the residual quantity of ammonia water on the hair, the elution of residual ammonia water adhered on the hair scale, between the hair scale and the cortex layer can be promoted, the ammonia odor remained on the hair after dyeing is further reduced, the sustainable damage of the residual ammonia water to the hair is reduced, and the use experience of the hair dye is further improved; furthermore, the sodium polyaspartate, hydroxyethyl urea that add in this application can moisturize, moisten and strengthen the hair structure, ginseng root extract, treat and hinder villus flower extract and soapberry extract contain abundant nutrient substance and moisturizing composition, can provide comprehensive nutrition and supply and moisturizing effect for the hair, maleic acid castor oil ester possesses good film forming effect, can further smooth the hair scale of dysphoria, and polydimethylsiloxane possesses good lubrication hair effect, can reduce the hair friction to reduce the damage of hair scale, this application has obtained the hair dye that possesses good coloring effect through the cooperation effect of foretell many aspects effect that can reduce the hair damage again can reduce ammonia water residue.
Preferably, the mass ratio of the sodium polyaspartate to the ginseng root extract to the wound-healing downy flower extract is 4:0.7:0.9.
in the technical scheme, the mass ratio of the sodium polyaspartate, the ginseng root extract and the wound-healing villus extract is 4:0.7:0.9, under the mass ratio, the sodium polyaspartate, the ginseng root extract and the wound villus flower extract have better synergistic cooperation effect, so that the residual ammonia odor on the hair after dyeing can be further reduced, the sustainable damage of residual ammonia water to the hair is reduced, and the coloring effect of the hair dye is further improved.
Preferably, the acidity regulator is prepared from malic acid, maleic acid and glycolic acid in an amount of (1 to 1.5): (1-1.5): (1-1.5) by mass ratio.
In the technical scheme, the acid regulator is prepared from malic acid, maleic acid and glycollic acid (1-1.5): (1-1.5): the hair dye is prepared by mixing the components (1-1.5) according to the mass ratio, so that the damage of ammonia water to hair scales is reduced better, sodium polyaspartate, ginseng root extract and hair-wound floss flower extract are matched better, the residual quantity of ammonia water on hair is further reduced, the elution of residual ammonia water adhered on the hair scales and between the hair scales and cortex layers is further promoted, the residual ammonia odor on dyed hair is further reduced, and the use experience of the hair dye is further improved.
Preferably, the dye comprises one or more of toluene-2, 5-diamine sulfate, resorcinol, 2, 4-diamino phenoxy ethanol hydrochloride, 4-amino-2-hydroxy toluene, p-phenylenediamine, m-aminophenol, N-bis (2-hydroxyethyl) p-phenylenediamine sulfate, p-aminophenol, 1-hydroxyethyl-4, 5-diamino pyrazole sulfate, 2-amino-3-hydroxypyridine, toluene-2, 5-diamine sulfate.
According to the technical scheme, the dye is selected to reduce the stimulation to the scalp as much as possible on the basis of better dyeing effect, and the use experience of the hair dye is further improved.
Preferably, the antioxidant comprises sodium sulfite and sodium ascorbate, wherein the sodium sulfite accounts for 0.2-0.4% of the hair dye, and the sodium ascorbate accounts for 0.1-0.2% of the hair dye.
Among the above-mentioned technical scheme, this application is through adopting sodium sulfite and sodium ascorbate as the antioxidant, can further improve the stability of hair dye, further improves the coloring effect of hair dye.
Preferably, the emulsifier comprises cetostearyl alcohol polyether-25 and cetrimide, wherein the cetrimide polyether-25 accounts for 2% -4% of the hair dye, and the cetrimide accounts for 1% -2% of the hair dye.
In the technical scheme, the cetostearyl alcohol polyether-25 and cetrimide are adopted as the emulsifying agents, so that all components in the hair dye are dispersed more uniformly, and the coloring uniformity of the hair dye is further improved.
Preferably, the antistatic agent comprises polyquaternium-10 and polyquaternium-7, wherein the polyquaternium-10 accounts for 0.1-0.2% of the hair dye, and the polyquaternium-7 accounts for 1-3% of the hair dye.
In the technical scheme, the antistatic agent is polyquaternium-10 and polyquaternium-7, so that good antistatic effect of hair after dyeing is ensured, and further damage of friction to hair scales is reduced.
Preferably, the mass concentration of the ammonia water is 25%.
In a second aspect, the present application provides a method for preparing a hair dye for reducing hair damage, which adopts the following technical scheme:
a method for preparing hair dye for reducing hair damage, comprising the following steps:
step 1: mixing water, a thickening agent, an emulsifying agent and a solubilizing agent, heating to 75-85 ℃, homogenizing for 5-10 min, and stirring until the mixture is completely dissolved;
step 2: cooling the product obtained in the step 1 to 60-65 ℃, sequentially adding raw materials of antioxidants, dyes, chelating agents, antistatic agents, sodium polyaspartate, malic acid, maleic acid and glycolic acid composition, hydroxyethyl urea, ginseng root extract, wound-healing villus extract, castor oil maleate, soapberry fruit extract and polydimethylsiloxane, homogenizing until the raw materials are completely dissolved, and stirring uniformly;
step 3: and (3) cooling the product obtained in the step (2) to 40-45 ℃, adding the rest other raw materials, and uniformly stirring to obtain the hair dye for reducing hair damage.
In the technical scheme, the hair dye prepared by the preparation method has good dispersibility and stability, and can exert better coloring effect and reduce hair damage when in use.
In summary, the present application includes at least one of the following beneficial technical effects:
1. according to the hair dye, the sodium polyaspartate, the ginseng root extract and the wound villus flower extract are added into the hair dye, and under the good synergistic interaction, the sodium polyaspartate, the ginseng root extract and the wound villus flower extract can promote the dye to enter between the hair scale and the leather layer better under the condition of small opening degree of the hair scale, so that more macromolecule colored dye is generated through reaction, the hair coloring effect is improved, meanwhile, the compounding of the sodium polyaspartate, the ginseng root extract and the wound villus flower extract also has the unexpected effect of reducing the residual quantity of ammonia on the hair, the elution of residual ammonia on the hair scale and between the hair scale and the leather layer can be promoted, the residual ammonia odor on the hair after dyeing is further reduced, the sustainable damage of the residual ammonia on the hair is reduced, and the use experience of the hair dye is further improved.
2. The acid regulator is defined by malic acid, maleic acid and glycollic acid (1-1.5): (1-1.5): the hair dye is prepared by mixing the components (1-1.5) according to the mass ratio, so that the damage of ammonia water to hair scales is reduced better, sodium polyaspartate, ginseng root extract and hair-wound floss flower extract are matched better, the residual quantity of ammonia water on hair is further reduced, the elution of residual ammonia water adhered on the hair scales and between the hair scales and cortex layers is further promoted, the residual ammonia odor on dyed hair is further reduced, and the use experience of the hair dye is further improved.
Detailed Description
For a better description of the objects, technical solutions and advantages of the present invention, the present invention will be further described with reference to the following specific examples.
Example 1
A hair dye for reducing hair damage, comprising the following components: 57.74kg of water, 7kg of ammonia water, 10kg of thickener, 5kg of emulsifier, 2kg of solubilizer, 0.6kg of antioxidant, 0.1kg of chelating agent, 0.76kg of dye, 3.1kg of antistatic agent, 0.1kg of essence, 3kg of sodium polyaspartate, 4.5kg of acidity regulator, 3kg of hydroxyethyl urea, 1kg of ginseng root extract, 0.5kg of wound healing villus extract, 0.4kg of castor oil maleate, 0.2kg of soapberry extract and 1kg of polydimethylsiloxane.
Wherein the thickener is cetostearyl alcohol.
Wherein the emulsifier comprises 4kg of cetostearyl alcohol polyether-25 and 1kg of cetrimide.
Wherein the solubilizing agent is ethanol.
Wherein the antioxidant comprises 0.4kg sodium sulfite and 0.2kg sodium ascorbate.
Wherein the chelating agent is disodium edetate.
Wherein the dye comprises 0.5kg of toluene-2, 5-diamine sulfate, 0.06kg of resorcinol, 0.1kg of 2, 4-diaminophenoxy ethanol hydrochloride and 0.1kg of 4-amino-2-hydroxytoluene.
Wherein the antistatic agent comprises 0.1kg of polyquaternium-10 and 3kg of polyquaternium-7.
Wherein, sodium polyaspartate is purchased from Shanghai Yuan Yes Biotechnology Co., ltd., product number S25535.
Wherein the acidity regulator is a mixture of 1.5kg malic acid, 1.5kg maleic acid and 1.5kg glycolic acid.
Among them, hydroxyethyl urea is purchased from sigma aldrich (Shanghai) trade company, cat No. 554693.
Wherein, the ginseng root extract is purchased from the western security australian biotechnology limited company and is extracted by adopting a water extraction method, and the extraction ratio is 1:10.
wherein, the extract of the wound-healing villus flowers is purchased from Shanghai Yuyu new material science and technology Co., ltd, and is extracted by adopting a water extraction method according to an extraction ratio of 1:10.
wherein, the maleic acid castor oil ester is purchased from the company of the chemical industry, the product number is: HC5454.
Wherein, soapberry fruit extract is purchased from Shaanxi green and Lai biotechnology limited company, and is extracted by adopting a water extraction method, and the extraction ratio is 1:10.
among them, polydimethylsiloxane was purchased from sigma aldrich (Shanghai) trade company, product number PHR1518.
Wherein, the preparation method of the hair dye for reducing hair damage comprises the following steps:
step 1: mixing water, thickener, emulsifier and solubilizer, heating to 85deg.C, homogenizing at 3000r/min for 5min, and stirring at 300r/min to dissolve completely.
Step 2: cooling the product obtained in the step 1 to 65 ℃, sequentially adding raw materials of antioxidant, dye, chelating agent, antistatic agent, sodium polyaspartate, malic acid, maleic acid and glycolic acid composition, hydroxyethyl urea, ginseng root extract, wound-healing villus extract, castor oil maleate, soapberry fruit extract and polydimethylsiloxane, homogenizing at 3000r/min until the raw materials are completely dissolved, and stirring uniformly at 300 r/min.
Step 3: cooling the product obtained in the step 2 to 45 ℃, adding the rest other raw materials, and uniformly stirring at 300r/min to obtain the hair dye for reducing hair damage.
Example 2
Unlike example 1, the hair dye for reducing hair damage comprises the following components: 62.64kg of water, 5kg of ammonia water, 5kg of thickener, 4kg of emulsifier, 4kg of solubilizer, 0.3kg of antioxidant, 0.3kg of chelating agent, 0.76kg of dye, 1.2kg of antistatic agent, 0.5kg of essence, 5kg of sodium polyaspartate, 3kg of acidity regulator, 5kg of hydroxyethyl urea, 0.5kg of ginseng root extract, 1kg of extract of villus, 0.8kg of castor oil maleate, 0.5kg of soapberry extract and 0.5kg of polydimethylsiloxane.
Wherein the emulsifier comprises 2kg of cetostearyl alcohol polyether-25 and 2kg of cetrimide.
Wherein the antioxidant comprises 0.2kg sodium sulfite and 0.1kg sodium ascorbate.
Wherein the antistatic agent comprises 0.2kg of polyquaternium-10 and 1kg of polyquaternium-7.
Wherein the acidity regulator is a mixture of 1kg malic acid, 1kg maleic acid and 1kg glycolic acid.
Wherein, the preparation method of the hair dye for reducing hair damage comprises the following steps:
step 1: mixing water, thickener, emulsifier and solubilizer, heating to 75deg.C, homogenizing at 2000r/min for 10min, and stirring at 200r/min to dissolve completely.
Step 2: cooling the product obtained in the step 1 to 60 ℃, sequentially adding raw materials of antioxidant, dye, chelating agent, antistatic agent, sodium polyaspartate, malic acid, maleic acid and glycolic acid composition, hydroxyethyl urea, ginseng root extract, wound-healing villus extract, castor oil maleate, soapberry fruit extract and polydimethylsiloxane, homogenizing at 2000r/min until the raw materials are completely dissolved, and stirring uniformly at 200 r/min.
Step 3: cooling the product obtained in the step 2 to 40 ℃, adding the rest other raw materials, and uniformly stirring at 200r/min to obtain the hair dye for reducing hair damage.
Example 3
Unlike example 1, the hair dye for reducing hair damage was adjusted to 4kg of sodium polyaspartate, 0.7kg of ginseng root extract, 0.9kg of wound-healing villus extract, and 56.64kg of water.
Example 4
Unlike example 3, the acid conditioner was 4.5kg of malic acid, which is a hair dye for reducing hair damage.
Example 5
Unlike example 3, the hair dye for reducing hair damage was 4.5kg of maleic acid as the acid regulator.
Example 6
Unlike example 3, the hair dye for reducing hair damage was 4.5kg of glycolic acid as the acid regulator.
Comparative example 1
Unlike example 3, the hair dye was replaced with sodium polyaspartate in the same amount.
Comparative example 2
A hair dye is different from example 3 in that the extract of ginseng root is replaced with the extract of Polygonum multiflorum in equal amount.
Wherein, the polygonum multiflorum extract is from commercial market, and is extracted by adopting a water extraction method, and the extraction ratio is 1:10.
comparative example 3
A hair dye is different from example 3 in that the extract of the hair-wound-healing villus is replaced with the extract of Polygonum multiflorum in equal amount.
Comparative example 4
Unlike example 3, the hair dye does not contain a malic acid, maleic acid, and glycolic acid composition.
Detection test
Preparation of test samples: 10 natural white hair strands selected from the same source were dyed with a hydrogen peroxide solution having a mass concentration of 6% by using the hair dyes of the above examples and comparative examples of the present application, respectively, and the hair strands had a length of about 10cm and a weight of about 5g.
The specific hair dyeing process is as follows: 3mL of the hair dye of each of the above examples and comparative examples and 3mL of a hydrogen peroxide solution having a mass concentration of 6% were taken at room temperature of 25℃and humidity of 75% at a ratio of 1:1, uniformly coating the mixture on the corresponding hair bundles, waiting for 20min, continuously cleaning the hair bundles for 3 times by adopting 60mL of clean water, and kneading 20 times by using 20mL of clean water each time. After the cleaning is finished, the towel is used for sucking up the moisture until the hair bundles are not dripped, and then the hair bundles are naturally dried.
Test 1
Detecting ammonia water residue of hair bundle
50mL of clear water and 3 drops of methyl orange indicator at a mass fraction of 0.1% were each added to the Erlenmeyer flask. The hair tresses were suspended in a conical flask and sealed, after 12h of standing, the tresses were removed and titrated with 0.2moL of hydrochloric acid solution until the colorless solution in the conical flask suddenly changed to orange-red, the titration was stopped, and the amount of hydrochloric acid solution used was recorded in table 1.
Test 2
Coloring effect detection
Detecting the L, a and b values of each hair bundle by using a color difference instrument, and calculating the hair color difference value and the color difference value by taking the L1, a1 and b1 values of the hair bundles before dyeing as the referenceThe test results are recorded in Table 1, with a larger ΔE representing a better coloring effect.
Test 3
Hair tensile strength detection
The tensile strength value (N) of the hair bundle sample which was not dyed was measured by a push-pull tester and was recorded as an initial tensile strength value, and then 10 hair test hairs were randomly extracted from each of the dyed hair bundles, and the tensile strength change rate (%) = [ (initial tensile strength value-tensile strength value)/initial tensile strength value ]. Times.100% was calculated, and the smaller the tensile strength change rate (%) was, the smaller the damage of hair to hair was proved, and the test results were recorded in table 1.
Table 1:
it can be seen that the hair dyes of examples 1 to 6 have good hair damage reducing effects, ammonia water residue reducing effects and coloring effects by combining examples 1 to 6 and comparative examples 1 to 4.
Specifically, in combination with the analysis of example 3 and comparative examples 1 to 3, the difference between comparative examples 1 to 3 and example 3 is that example 3 was added with sodium polyaspartate, ginseng root extract and wound-healing villus flower extract, and the effect of reducing hair damage, the effect of reducing ammonia water residue and the coloring effect of example 3 were all better to some extent. From this analysis holds that this application is through adding polyaspartic acid sodium, ginseng root extract and treating injury villus flower extract simultaneously in the hair dye, the three is under good cooperation effect, can still promote the better entering of dyestuff between the hair scale and the cortex layer under the less circumstances of hair scale degree of opening, improve the coloring effect of hair, still have unexpected effect of reducing the residual quantity of aqueous ammonia on the hair, can promote the elution of the residual aqueous ammonia of adhesion on the hair scale, between hair scale and the cortex layer, further reduce the remaining ammonia peculiar smell on the hair after the hair dyeing and reduce the lasting harm of residual aqueous ammonia to hair, further improve the use experience of hair dye.
The difference between examples 4-6 and example 3, which were analyzed in particular in combination with example 3 and examples 4-6, is that the acid modifiers of examples 4-6 were malic acid, maleic acid and glycolic acid, respectively, and the hair damage reducing effect, ammonia water residue reducing effect and coloring effect of example 3 were all better to some extent. The applicant considers from this analysis that, through the simultaneous addition of malic acid, maleic acid and glycolic acid, the effect of better reducing the damage of ammonia water to hair scales is achieved, and sodium polyaspartate, ginseng root extract and wound-healing villus flower extract can also be better matched, so that the residual quantity of ammonia water on hair is further reduced, the elution of residual ammonia water adhered on hair scales and between hair scales and leather layers is further promoted, the residual ammonia odor on hair after dyeing is further reduced, and then the data analysis of a color difference value delta E is specifically combined, the coloring effect of the hair dye can be further improved to a certain extent by compounding malic acid, maleic acid and glycolic acid.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (9)
1. A hair dye for reducing hair damage, which is characterized by comprising the following components in percentage by mass: 5% -7% of ammonia water, 5% -10% of a thickening agent, 3% -6% of an emulsifying agent, 2% -4% of a solubilizing agent, 0.3% -0.6% of an antioxidant, 0.1% -0.3% of a chelating agent, 0.33% -0.76% of a dye, 1.1% -3.2% of an antistatic agent, 0.1% -0.5% of essence, 3% -5% of sodium polyaspartate, 3% -4.5% of an acid regulator, 3% -5% of hydroxyethyl urea, 0.5% -1% of ginseng root extract, 0.5% -1% of a wound healing villus extract, 0.4% -0.8% of castor oil maleate, 0.2% -0.5% of a soapberry extract, 0.5% -1% of polydimethylsiloxane and the balance of water.
2. The hair dye for reducing hair damage according to claim 1, wherein the mass ratio of the sodium polyaspartate, the ginseng root extract and the wound-healing villus extract is 4:0.7:0.9.
3. the hair dye for reducing hair damage according to claim 1, wherein the acidity regulator is a dye prepared from malic acid, maleic acid and glycolic acid in an amount of (1 to 1.5): (1-1.5): (1-1.5) by mass ratio.
4. The hair dye for reducing hair damage according to claim 1, wherein the dye comprises one or more of toluene-2, 5-diamine sulfate, resorcinol, 2, 4-diaminophenoxy ethanol hydrochloride, 4-amino-2-hydroxy toluene, p-phenylenediamine, m-aminophenol, N-bis (2-hydroxyethyl) p-phenylenediamine sulfate, p-aminophenol, 1-hydroxyethyl-4, 5-diaminopyrazole sulfate, 2-amino-3-hydroxypyridine, toluene-2, 5-diamine sulfate.
5. The hair dye for reducing hair damage according to claim 1, wherein the antioxidant comprises sodium sulfite and sodium ascorbate, wherein sodium sulfite is 0.2% -0.4% of the hair dye, and sodium ascorbate is 0.1% -0.2% of the hair dye.
6. The hair dye for reducing hair damage according to claim 1, wherein the emulsifier comprises cetostearyl alcohol polyether-25 and cetrimide, the cetrimide polyether-25 accounts for 2% -4% of the hair dye, and the cetrimide chloride accounts for 1% -2% of the hair dye.
7. The hair dye for reducing hair damage according to claim 1, wherein the antistatic agent comprises polyquaternium-10 and polyquaternium-7, wherein the polyquaternium-10 accounts for 0.1% -0.2% of the hair dye, and wherein the polyquaternium-7 accounts for 1% -3% of the hair dye.
8. The hair dye for reducing hair damage according to claim 1, wherein the mass concentration of the aqueous ammonia is 25%.
9. A method of preparing a hair dye for reducing hair damage according to any one of claims 1 to 8, comprising the steps of:
step 1: mixing water, a thickening agent, an emulsifying agent and a solubilizing agent, heating to 75-85 ℃, homogenizing for 5-10 min, and stirring until the mixture is completely dissolved;
step 2: cooling the product obtained in the step 1 to 60-65 ℃, sequentially adding raw materials of antioxidants, dyes, chelating agents, antistatic agents, sodium polyaspartate, malic acid, maleic acid and glycolic acid composition, hydroxyethyl urea, ginseng root extract, wound-healing villus flower extract, castor oil maleate, soapberry fruit extract and polydimethylsiloxane, homogenizing until the raw materials are completely dissolved, and stirring uniformly;
step 3: and (3) cooling the product obtained in the step (2) to 40-45 ℃, adding the rest other raw materials, and uniformly stirring to obtain the hair dye for reducing hair damage.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1087450A (en) * | 1996-09-13 | 1998-04-07 | Mitsubishi Chem Corp | Hair dye composition |
| CN1518973A (en) * | 2002-12-06 | 2004-08-11 | ���ŷ� | Compsn. of oxydation dyeing of keratin fiber |
| JP2007308427A (en) * | 2006-05-19 | 2007-11-29 | Milbon Co Ltd | Oxidative hair dye composition |
| CN102245714A (en) * | 2008-12-15 | 2011-11-16 | 巴斯夫欧洲公司 | Polymeric hair dyes |
| CN111265416A (en) * | 2020-04-01 | 2020-06-12 | 佛山市南海区喜创科技有限公司 | Permanent wave composition for reducing hair damage |
| CN114732746A (en) * | 2022-03-15 | 2022-07-12 | 广东歌秀科技有限公司 | Low-irritation hair dyeing cream and preparation method thereof |
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2023
- 2023-12-08 CN CN202311677119.8A patent/CN117618310A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1087450A (en) * | 1996-09-13 | 1998-04-07 | Mitsubishi Chem Corp | Hair dye composition |
| CN1518973A (en) * | 2002-12-06 | 2004-08-11 | ���ŷ� | Compsn. of oxydation dyeing of keratin fiber |
| JP2007308427A (en) * | 2006-05-19 | 2007-11-29 | Milbon Co Ltd | Oxidative hair dye composition |
| CN102245714A (en) * | 2008-12-15 | 2011-11-16 | 巴斯夫欧洲公司 | Polymeric hair dyes |
| CN111265416A (en) * | 2020-04-01 | 2020-06-12 | 佛山市南海区喜创科技有限公司 | Permanent wave composition for reducing hair damage |
| CN114732746A (en) * | 2022-03-15 | 2022-07-12 | 广东歌秀科技有限公司 | Low-irritation hair dyeing cream and preparation method thereof |
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