CN114732746A - Low-irritation hair dyeing cream and preparation method thereof - Google Patents

Low-irritation hair dyeing cream and preparation method thereof Download PDF

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Publication number
CN114732746A
CN114732746A CN202210252636.XA CN202210252636A CN114732746A CN 114732746 A CN114732746 A CN 114732746A CN 202210252636 A CN202210252636 A CN 202210252636A CN 114732746 A CN114732746 A CN 114732746A
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hair dye
hair
antioxidant
composition
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李陈连
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Guangdong Gexiu Technology Co ltd
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Guangdong Gexiu Technology Co ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/347—Phenols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/676—Ascorbic acid, i.e. vitamin C
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes
    • A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/522—Antioxidants; Radical scavengers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/592—Mixtures of compounds complementing their respective functions

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Abstract

The invention belongs to the technical field of cosmetics, and particularly discloses a low-irritation hair dyeing paste and a preparation method thereof, wherein the low-irritation hair dyeing paste comprises a hair dyeing composition and an antioxidant composition; the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 0.8 to 1.2; the hair dye composition comprises the following raw materials: chelating agent, aromatic, first antioxidant, hair dye, humectant, first emulsifier, hair conditioner, pH regulator, thickener, and deionized water. The hair dye cream has good stability and oxidation resistance, good hair dyeing effect and even dyeing, and is low in irritation and amine substances.

Description

Low-irritation hair dyeing cream and preparation method thereof
Technical Field
The invention relates to the technical field of cosmetics, in particular to a low-irritation hair dyeing cream and a preparation method thereof.
Background
With the rapid development of hair dyeing and beauty industry and the continuous pursuit of beauty, hair dyeing is accepted by more and more people, and hair dyeing products are generally classified into three types, namely temporary hair dyeing products, semi-permanent hair dyeing products and permanent hair dyeing products. At present, the permanent chemical hair dye occupies about 95 percent of the market share, and the rest two hair dyes have only 5 percent of the market share.
The prior semi-permanent hair dye cream generally consists of a hair dye composition and an antioxidant composition, wherein the stability of the hair dye composition is insufficient, and the service life of the hair dye composition is influenced.
Disclosure of Invention
The low-irritation hair dyeing paste has good stability and oxidation resistance, has good hair dyeing effect and is uniform in dyeing.
The invention adopts the following technical scheme for solving the technical problems:
a low irritation hair dye cream comprises hair dye composition, antioxidant composition;
the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 0.8 to 1.2;
the hair dye composition comprises the following components in parts by weight: 0.1-0.3 part of chelating agent, 0.3-0.6 part of aromatic, 0.6-1 part of first antioxidant, 2-3.2 parts of hair dye, 2-6 parts of humectant, 2-6 parts of first emulsifier, 4-6 parts of hair conditioner, 4.5-8 parts of pH regulator, 6-12 parts of thickening agent and 50-70 parts of deionized water.
As a preferable scheme, the hair dye composition comprises the following components in parts by weight: 0.1-0.25 part of chelating agent, 0.4-0.6 part of aromatic, 0.8-1 part of first antioxidant, 2.5-3.2 parts of hair dye, 2-5 parts of humectant, 3-6 parts of first emulsifier, 5-6 parts of hair conditioner, 5-8 parts of pH regulator, 8-12 parts of thickening agent and 55-70 parts of deionized water.
As a preferable scheme, the hair dye composition comprises the following components in parts by weight: 0.2 part of chelating agent, 0.5 part of aromatic, 0.85 part of first antioxidant, 3.1 parts of hair dye, 3.5 parts of humectant, 5 parts of first emulsifier, 5.5 parts of hair conditioner, 7 parts of pH regulator, 10 parts of thickening agent and 64.35 parts of deionized water.
As a preferable scheme, the first antioxidant is prepared from sodium sulfite and sodium erythorbate according to a weight ratio of 1:0.5 to 2.
As a most preferred scheme, the first oxidant is sodium sulfite and sodium erythorbate in a weight ratio of 1: 0.7. The first antioxidant consisting of sodium sulfite and sodium erythorbate is adopted to ensure that the hair dye begins to be oxidized when entering corresponding positions of hair, thereby improving the hair dyeing effect.
Preferably, the hair dye is prepared from p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, toluene-2, 5-diamine sulfate according to a weight ratio of 12-18: 4-6: 4-6: 1-4: 1-4: 0.5 to 2.
As a most preferable mode, the hair dye is prepared by mixing p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, toluene-2, 5-diamine sulfate in a weight ratio of 15: 5: 5: 3: 2: 1.
Preferably, the hair conditioner in the hair dyeing composition is prepared from petrolatum, mink oil, lanolin, polyquaternium-63 in a weight ratio of 20-40: 8-15: 8-15: 2 to 6.
As a most preferable scheme, the hair conditioner in the hair dyeing composition is composed of petrolatum, mink oil, lanolin and polyquaternium-63 according to a weight ratio of 30:10:10: 5.
As a preferable embodiment, the chelating agent in the hair dyeing composition is tetrasodium ethylenediaminetetraacetate, and it should be noted that a person skilled in the art can select a specific type of chelating agent according to actual needs as long as a corresponding chelating effect is achieved, for example, the chelating agent includes, but is not limited to, tetrasodium ethylenediaminetetraacetate.
As a preferable scheme, the aromatic in the hair dyeing composition is an essence, and it should be noted that, a person skilled in the art can select an appropriate essence according to actual needs as long as a corresponding aromatic effect is achieved.
Preferably, the humectant in the hair dyeing composition consists of propylene glycol and aloe extract according to the weight ratio of 6: 0.5-2. It should be noted that, those skilled in the art can select a suitable moisturizing agent according to actual needs, as long as the corresponding moisturizing effect is achieved.
Preferably, the first emulsifier in the hair dyeing composition consists of ceteareth-25, a composite emulsifier and glyceryl stearate in a weight ratio of 2-5: 0.5-2. Preferably, the composite emulsifier is prepared from stearyl trimethyl ammonium chloride, ethanol and cetrimide in a weight ratio of 50-80: 10-30: 5 to 20. The ternary emulsifier can effectively improve the emulsification stability of the hair dye composition under the specific weight proportion, so that the hair dye composition can not generate the phenomena of layering and emulsion breaking, and the stability of the hair dye is improved.
As a preferable scheme, the pH regulator is at least two of ammonium hydroxide, ammonium bicarbonate and triethanolamine, and it should be noted that a person skilled in the art can select a suitable pH regulator according to actual needs as long as a corresponding pH regulation effect is achieved.
As a preferable scheme, the thickening agent in the hair dyeing composition is cetearyl alcohol, and the thickening agent can achieve good thickening effect, improve the using effect of the hair dyeing cream and improve the stability of the whole formula, but the corresponding effect cannot be achieved by adopting the traditional thickening agents such as xanthan gum and carbomer.
As a preferable scheme, the antioxidant composition comprises the following components in parts by weight: 0.05-0.15 part of stabilizer, 0.05-0.12 part of antibacterial agent, 3-4 parts of hair conditioner, 0.1-0.4 part of aromatic, 0.2-0.5 part of pH regulator, 3.5-5 parts of second emulsifier, 4-8 parts of humectant, 4-7 parts of second antioxidant and 65-80 parts of deionized water.
As a preferable scheme, the antioxidant composition comprises the following components in parts by weight: 0.1 part of stabilizing agent, 0.1 part of antibacterial agent, 3.5 parts of hair conditioner, 0.2 part of aromatic, 0.35 part of pH regulator, 4.3 parts of second emulsifier, 6 parts of humectant, 6.5 parts of second antioxidant and 78.95 parts of deionized water.
As a preferable scheme, the stabilizing agent is sodium stannate, and sodium stannate is taken as the stabilizing agent, so that the stabilizing auxiliary effect can be achieved under the formula system of the invention.
As a preferable scheme, the antibacterial agent is salicylic acid, and it should be noted that a person skilled in the art can select a suitable antibacterial agent according to actual needs as long as a corresponding antibacterial effect is achieved.
As a preferable scheme, the hair conditioner is composed of mineral oil and mink oil according to a weight ratio of 6: 0.5-2, and it should be noted that a person skilled in the art can select a proper hair conditioner according to actual needs as long as a corresponding conditioning effect is achieved.
As a preferable embodiment, the pH regulator is disodium hydrogen phosphate, and it should be noted that, a person skilled in the art can select a suitable pH regulator according to actual needs as long as a corresponding pH regulating effect is achieved.
Preferably, the second emulsifier is composed of cetearyl alcohol, ceteareth-25 and glyceryl stearate according to a weight ratio of 1-4: 0.5-2: 0.2-0.6. The ternary emulsifier consisting of cetearyl alcohol, ceteareth-25 and glyceryl stearate can effectively improve the stability of the whole formula.
As a preferable scheme, the aromatic in the antioxidant composition is an essence, and it should be noted that a person skilled in the art can select an appropriate essence according to actual needs as long as a corresponding aromatic effect is achieved.
As a preferable scheme, the second antioxidant is prepared from hydroxyethyldiphosphonic acid, hydrogen peroxide and deionized water according to a weight ratio of 0.5-2: 8-15: 8 to 15. The second antioxidant consisting of the hydroxyethylidene diphosphate, the hydrogen peroxide and the deionized water is adopted, so that the hair dye begins to be oxidized when entering the corresponding position of the hair, and the hair dyeing effect is improved.
The invention is characterized in that the first antioxidant is added into the hair dyeing composition, the second antioxidant is added into the antioxidant composition, and the first antioxidant and the second antioxidant are combined under a system to ensure that the hair dyeing agent starts to be gradually oxidized after reaching the corresponding position of the hair, so that the dyeing uniformity and the dyeing effect are improved.
The invention also provides a preparation method of the low-irritation hair dyeing paste, which is used for preparing the hair dyeing paste and comprises the following steps:
s1, preparation of the hair dye composition: adding the hair dye and the humectant into part of deionized water, uniformly mixing to obtain a premix, adding a chelating agent, a first antioxidant, a first emulsifier, a hair conditioner and a thickening agent into the other part of deionized water, uniformly stirring at 65-80 ℃, cooling to 40-48 ℃, adding the premix, an aromatic and a pH regulator, and uniformly stirring to obtain a hair dye composition;
s2, preparation of an antioxidant composition: adding a stabilizer, an antibacterial agent, a hair conditioner, a second emulsifier and a humectant into deionized water, uniformly stirring at 65-80 ℃, cooling to 40-48 ℃, adding an aromatic, a pH regulator and a second antioxidant, and uniformly stirring to obtain an antioxidant composition;
s3, when in use, the hair dye composition and the antioxidant composition are uniformly mixed to obtain the hair dye cream.
The invention has the beneficial effects that: the low-irritation hair dye cream has good stability and oxidation resistance, has good hair dyeing effect and uniform dyeing, is low in irritation and low in amine substances, and can gradually oxidize the hair dye after reaching the corresponding position of hair by using the first antioxidant and the oxidation-resistant composition, so that the dyeing uniformity and the dyeing effect are improved.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the present invention, the parts are all parts by weight unless otherwise specified.
Example 1
A low irritation hair dye cream comprises hair dye composition, antioxidant composition; the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 1.
the hair dye composition comprises the following components in parts by weight: 0.2 part of chelating agent, 0.5 part of aromatic, 0.85 part of first antioxidant, 3.1 parts of hair dye, 3.5 parts of humectant, 5 parts of first emulsifier, 5.5 parts of hair conditioner, 7 parts of pH regulator, 10 parts of thickening agent and 64.35 parts of deionized water.
The first oxidant is prepared from sodium sulfite and sodium erythorbate according to a weight ratio of 1: 0.7.
The hair dye is prepared from p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, and toluene-2, 5-diamine sulfate according to the weight ratio of 15: 5: 5: 3: 2: 1.
The conditioner for hair in the hair dyeing composition is composed of petrolatum, mink oil, lanolin and polyquaternium-63 according to the weight ratio of 30:10:10: 5.
The chelating agent in the hair dyeing composition is ethylenediaminetetraacetic acid tetrasodium salt.
The flavoring agent in the hair dyeing composition is essence.
The humectant in the hair dyeing composition is prepared from propylene glycol and aloe extract according to a weight ratio of 6: 1.
The first emulsifier in the hair dyeing composition is prepared from ceteareth-25, a composite emulsifier and glyceryl stearate according to a weight ratio of 3:1: 1. The composite emulsifier is prepared from stearyl trimethyl ammonium chloride, ethanol and cetrimide according to a weight ratio of 70: 20: 10.
The pH regulator is composed of ammonium hydroxide, ammonium bicarbonate and triethanolamine according to the weight ratio of 1:1: 2.
The thickening agent in the hair dyeing composition is cetearyl alcohol.
The antioxidant composition comprises the following components in parts by weight: 0.1 part of stabilizer, 0.1 part of antibacterial agent, 3.5 parts of hair conditioner, 0.2 part of aromatic, 0.35 part of pH regulator, 4.3 parts of second emulsifier, 6 parts of humectant, 6.5 parts of antioxidant and 78.95 parts of deionized water.
The stabilizer is sodium stannate.
The antibacterial agent is salicylic acid.
The hair conditioner is prepared from mineral oil and mink oil according to a weight ratio of 6: 1.
The pH regulator is disodium hydrogen phosphate.
The second emulsifier is composed of cetearyl alcohol, ceteareth-25 and glyceryl stearate in a weight ratio of 2.8:1: 0.5.
The aromatic in the antioxidant composition is essence.
The second antioxidant is prepared from hydroxyethyldiphosphonic acid, hydrogen peroxide and deionized water according to the weight ratio of 1: 12: 13 of the composition.
The humectant is prepared from glycerol and propylene glycol according to a weight ratio of 5: 1.
The preparation method of the hair dye cream comprises the following steps:
s1, preparation of the hair dye composition: adding the hair dye and the humectant into part of deionized water, uniformly mixing to obtain a premix, adding the chelating agent, the first antioxidant, the first emulsifier, the hair conditioner and the thickener into the other part of deionized water, uniformly stirring at 70 ℃, cooling to 42 ℃, adding the premix, the aromatic and the pH regulator, and uniformly stirring to obtain the hair dye composition;
s2, preparation of an antioxidant composition: adding stabilizer, antibacterial agent, hair conditioner, second emulsifier and humectant into deionized water, stirring at 70 deg.C, cooling to 42 deg.C, adding aromatic, pH regulator and second antioxidant, and stirring to obtain antioxidant composition;
s3, when in use, the hair dye composition and the antioxidant composition are uniformly mixed to obtain the low-irritation hair dye cream.
Example 2
A low irritation hair dye cream comprises hair dye composition, antioxidant composition; the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 1.
the hair dye composition comprises the following components in parts by weight: 0.1 part of chelating agent, 0.6 part of aromatic, 0.6 part of first antioxidant, 3.2 parts of hair dye, 2 parts of humectant, 4.2 parts of first emulsifier, 6 parts of hair conditioner, 4.5 parts of pH regulator, 9 parts of thickening agent and 69.8 parts of deionized water.
The first oxidant is prepared from sodium sulfite and sodium erythorbate according to a weight ratio of 1: 0.9.
The hair dye is prepared from p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, and toluene-2, 5-diamine sulfate according to the weight ratio of 15: 5: 5: 3: 2: 1.
The conditioner for hair in the hair dyeing composition is composed of petrolatum, mink oil, lanolin and polyquaternium-63 according to the weight ratio of 30:10:10: 5.
The chelating agent in the hair dyeing composition is ethylenediaminetetraacetic acid tetrasodium salt.
The aromatic in the hair dyeing composition is essence.
The humectant in the hair dyeing composition is prepared from propylene glycol and aloe extract according to a weight ratio of 6: 1.
The first emulsifier in the hair dyeing composition is prepared from ceteareth-25, a composite emulsifier and glyceryl stearate according to a weight ratio of 4: 1: 0.5. The composite emulsifier is prepared from stearyl trimethyl ammonium chloride, ethanol and cetrimide according to a weight ratio of 60: 30: 10.
The pH regulator is composed of ammonium hydroxide, ammonium bicarbonate and triethanolamine according to the weight ratio of 1:1: 2.
The thickening agent in the hair dyeing composition is cetearyl alcohol.
The antioxidant composition comprises the following components in parts by weight: 0.05 part of stabilizing agent, 0.12 part of antibacterial agent, 3 parts of hair conditioner, 0.4 part of aromatic, 0.3 part of pH regulator, 4 parts of second emulsifier, 8 parts of humectant, 5 parts of second antioxidant and 79.13 parts of deionized water.
The stabilizer is sodium stannate.
The antibacterial agent is salicylic acid.
The hair conditioner is prepared from mineral oil and mink oil according to a weight ratio of 6: 1.
The pH regulator is disodium hydrogen phosphate.
The second emulsifier is composed of cetearyl alcohol, ceteareth-25 and glyceryl stearate in a weight ratio of 3:1: 0.4.
The aromatic in the antioxidant composition is essence.
The second antioxidant is prepared from hydroxyethyldiphosphonic acid, hydrogen peroxide and deionized water according to a weight ratio of 0.5: 15: 8, the components are mixed.
The humectant is prepared from glycerol and propylene glycol according to a weight ratio of 5: 1.
The preparation method of the hair dye cream comprises the following steps:
s1, preparation of the hair dye composition: adding the hair dye and the humectant into part of deionized water, uniformly mixing to obtain a premix, adding the chelating agent, the first antioxidant, the first emulsifier, the hair conditioner and the thickener into the other part of deionized water, uniformly stirring at 70 ℃, cooling to 42 ℃, adding the premix, the aromatic and the pH regulator, and uniformly stirring to obtain the hair dye composition;
s2, preparation of an antioxidant composition: adding stabilizer, antibacterial agent, hair conditioner, second emulsifier and humectant into deionized water, stirring at 70 deg.C, cooling to 42 deg.C, adding aromatic, pH regulator and second antioxidant, and stirring to obtain antioxidant composition;
s3, when in use, the hair dye composition and the antioxidant composition are uniformly mixed to obtain the low-irritation hair dye cream.
Example 3
A low irritation hair dye cream comprises hair dye composition, antioxidant composition; the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 1.
the hair dye composition comprises the following components in parts by weight: 0.3 part of chelating agent, 0.3 part of aromatic, 0.8 part of first antioxidant, 2.5 parts of hair dye, 6 parts of humectant, 3.8 parts of first emulsifier, 5 parts of conditioner for hair, 6 parts of pH regulator, 8 parts of thickener and 67.3 parts of deionized water.
The first oxidant is prepared from sodium sulfite and sodium erythorbate according to a weight ratio of 1: 1.
The hair dye is prepared from p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, and toluene-2, 5-diamine sulfate according to the weight ratio of 15: 5: 5: 3: 2: 1.
The conditioner for hair in the hair dyeing composition is composed of petrolatum, mink oil, lanolin and polyquaternium-63 according to the weight ratio of 30:10:10: 5.
The chelating agent in the hair dyeing composition is ethylenediaminetetraacetic acid tetrasodium salt.
The flavoring agent in the hair dyeing composition is essence.
The humectant in the hair dyeing composition is prepared from propylene glycol and aloe extract according to a weight ratio of 6: 1.
The first emulsifier in the hair dyeing composition is prepared from ceteareth-25, a composite emulsifier and glyceryl stearate according to a weight ratio of 5: 0.5: 1. The composite emulsifier is prepared from stearyl trimethyl ammonium chloride, ethanol and cetrimide according to a weight ratio of 80: 10: 10.
The pH regulator is composed of ammonium hydroxide, ammonium bicarbonate and triethanolamine according to the weight ratio of 1:1: 2.
The thickening agent in the hair dyeing composition is cetostearyl alcohol.
The antioxidant composition comprises the following components in parts by weight: 0.15 part of stabilizing agent, 0.05 part of antibacterial agent, 4 parts of hair conditioner, 0.1 part of aromatic, 0.5 part of pH regulator, 3.5 parts of second emulsifier, 8 parts of humectant, 5 parts of second antioxidant and 78.7 parts of deionized water.
The stabilizer is sodium stannate.
The antibacterial agent is salicylic acid.
The hair conditioner is prepared from mineral oil and mink oil according to a weight ratio of 6: 1.
The pH regulator is disodium hydrogen phosphate.
The second emulsifier is prepared from cetearyl alcohol, ceteareth-25 and glyceryl stearate in a weight ratio of 2: 2: 0.6.
The aromatic in the antioxidant composition is essence.
The second antioxidant is prepared from hydroxyethyldiphosphonic acid, hydrogen peroxide and deionized water according to the weight ratio of 1: 10: 15.
The humectant is prepared from glycerol and propylene glycol according to a weight ratio of 5: 1.
The preparation method of the hair dye cream comprises the following steps:
s1, preparation of the hair dye composition: adding the hair dye and the humectant into part of deionized water, uniformly mixing to obtain a premix, adding a chelating agent, a first antioxidant, a first emulsifier, a hair conditioner and a thickening agent into the other part of deionized water, uniformly stirring at 70 ℃, cooling to 42 ℃, adding the premix, an aromatic and a pH regulator, and uniformly stirring to obtain a hair dye composition;
s2, preparation of an antioxidant composition: adding stabilizer, antibacterial agent, hair conditioner, second emulsifier and humectant into deionized water, stirring at 70 deg.C, cooling to 42 deg.C, adding aromatic, pH regulator and second antioxidant, and stirring to obtain antioxidant composition;
s3, when in use, the hair dye composition and the antioxidant composition are uniformly mixed to obtain the low-irritation hair dye cream.
Comparative example 1
Comparative example 1 differs from example 1 in that the first emulsifier described in comparative example 1 is different from example 1, and is otherwise the same.
In this comparative example, the first emulsifier was composed of tween 60, glycerol glucoside, glycerol stearate in a weight ratio of 3:1: 1.
Comparative example 2
Comparative example 2 is different from example 1 in that the first emulsifier described in comparative example 2 is different from example 1 and is the same as others.
In the present comparative example, the first emulsifier was prepared from span 80, C12-20 alkyl glucoside, glyceryl stearate in a weight ratio of 3:1: 1.
To further demonstrate the effect of the present invention, the following test methods were provided:
the hair dye compositions described in examples 1 to 3 and comparative examples 1 to 3 (before use, i.e., before mixing with the antioxidant composition) were stored at 48 ℃ and-10 ℃ respectively, and observed once a day, and the time at which the delamination emulsion breaking phenomenon occurred was recorded.
TABLE 1 test results
Figure DEST_PATH_IMAGE001
As can be seen from table 1, the hair coloring compositions of the present invention have good stability.
Comparing example 1 with comparative examples 1-2, it can be seen that the stability of the first emulsifier of the present invention is significantly reduced when the first emulsifier is replaced with another emulsifier.
In light of the foregoing description of preferred embodiments according to the invention, it is clear that many changes and modifications can be made by the person skilled in the art without departing from the scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.

Claims (10)

1. A low-irritation hair dye cream is characterized by comprising a hair dye composition and an antioxidant composition;
the weight ratio of the hair dyeing composition to the antioxidant composition is 1: 0.8 to 1.2;
the hair dye composition comprises the following components in parts by weight: 0.1-0.3 part of chelating agent, 0.3-0.6 part of aromatic, 0.6-1 part of first antioxidant, 2-3.2 parts of hair dye, 2-6 parts of humectant, 2-6 parts of first emulsifier, 4-6 parts of hair conditioner, 4.5-8 parts of pH regulator, 6-12 parts of thickening agent and 50-70 parts of deionized water.
2. The low irritation hair dye paste according to claim 1, wherein the hair dye composition comprises, in parts by weight: 0.1-0.25 part of chelating agent, 0.4-0.6 part of aromatic, 0.8-1 part of first antioxidant, 2.5-3.2 parts of hair dye, 2-5 parts of humectant, 3-6 parts of first emulsifier, 5-6 parts of hair conditioner, 5-8 parts of pH regulator, 8-12 parts of thickening agent and 55-70 parts of deionized water.
3. The low irritation hair dye paste according to claim 1, wherein the hair dye composition comprises, in parts by weight: 0.2 part of chelating agent, 0.5 part of aromatic, 0.85 part of first antioxidant, 3.1 parts of hair dye, 3.5 parts of humectant, 5 parts of first emulsifier, 5.5 parts of hair conditioner, 7 parts of pH regulator, 10 parts of thickening agent and 64.35 parts of deionized water.
4. The low irritancy hair dye cream according to claim 1, wherein the first antioxidant is prepared from sodium sulfite, sodium erythorbate in a weight ratio of 1:0.5 to 2.
5. The low-irritation hair dye cream according to claim 1, wherein the hair dye is prepared from p-phenylenediamine, resorcinol, m-aminophenol, phenylmethylpyrazolone, 2, 4-diaminophenoxyethanol hydrochloride, toluene-2, 5-diamine sulfate in a weight ratio of 12-18: 4-6: 4-6: 1-4: 1-4: 0.5 to 2.
6. The low-irritation hair dye cream according to claim 1, wherein the hair conditioner is prepared from petrolatum, mink oil, lanolin, polyquaternium-63 in a weight ratio of 20-40: 8-15: 8-15: 2 to 6.
7. The low irritation hair dye cream according to claim 1, wherein said antioxidant composition comprises, in parts by weight: 0.05-0.15 part of stabilizer, 0.05-0.12 part of antibacterial agent, 3-4 parts of hair conditioner, 0.1-0.4 part of aromatic, 0.2-0.5 part of pH regulator, 3.5-5 parts of second emulsifier, 4-8 parts of humectant, 4-7 parts of second antioxidant and 65-80 parts of deionized water.
8. The low irritation hair dye cream according to claim 1, wherein said antioxidant composition comprises, in parts by weight: 0.1 part of stabilizing agent, 0.1 part of antibacterial agent, 3.5 parts of hair conditioner, 0.2 part of aromatic, 0.35 part of pH regulator, 4.3 parts of second emulsifier, 6 parts of humectant, 6.5 parts of second antioxidant and 78.95 parts of deionized water.
9. The low-irritation hair dye cream according to claim 7, wherein the second antioxidant is selected from hydroxyethyldiphosphonic acid, hydrogen peroxide and deionized water according to a weight ratio of 0.5-2: 8-15: 8 to 15.
10. A method for preparing a low-irritation hair dye cream, which is used for preparing the low-irritation hair dye cream according to any one of claims 1 to 9, comprising the steps of:
s1, preparation of the hair dye composition: adding the hair dye and the humectant into part of deionized water, uniformly mixing to obtain a premix, adding a chelating agent, a first antioxidant, a first emulsifier, a hair conditioner and a thickening agent into the other part of deionized water, uniformly stirring at 65-80 ℃, cooling to 40-48 ℃, adding the premix, an aromatic and a pH regulator, and uniformly stirring to obtain a hair dye composition;
s2, preparation of an antioxidant composition: adding a stabilizer, an antibacterial agent, a hair conditioner, a second emulsifier and a humectant into deionized water, uniformly stirring at 65-80 ℃, cooling to 40-48 ℃, adding an aromatic, a pH regulator and a second antioxidant, and uniformly stirring to obtain an antioxidant composition;
s3, when in use, the hair dye composition and the antioxidant composition are uniformly mixed to obtain the low-irritation hair dye cream.
CN202210252636.XA 2022-03-15 2022-03-15 Low-irritation hair dyeing cream and preparation method thereof Pending CN114732746A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117618310A (en) * 2023-12-08 2024-03-01 佛山市喜妆化妆品有限公司 Hair dye for reducing hair damage and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010037314A (en) * 2008-08-08 2010-02-18 Kao Corp Hairdye composition
CN112870145A (en) * 2021-02-05 2021-06-01 安徽美好仁家网络科技有限公司 Hair dye with mild components and preparation method thereof
CN113350240A (en) * 2021-06-25 2021-09-07 张勇 Planting extract hair dyeing cream and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010037314A (en) * 2008-08-08 2010-02-18 Kao Corp Hairdye composition
CN112870145A (en) * 2021-02-05 2021-06-01 安徽美好仁家网络科技有限公司 Hair dye with mild components and preparation method thereof
CN113350240A (en) * 2021-06-25 2021-09-07 张勇 Planting extract hair dyeing cream and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117618310A (en) * 2023-12-08 2024-03-01 佛山市喜妆化妆品有限公司 Hair dye for reducing hair damage and preparation method thereof

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