CN1175139C - 金叠层织物及其制造方法 - Google Patents
金叠层织物及其制造方法 Download PDFInfo
- Publication number
- CN1175139C CN1175139C CNB018140882A CN01814088A CN1175139C CN 1175139 C CN1175139 C CN 1175139C CN B018140882 A CNB018140882 A CN B018140882A CN 01814088 A CN01814088 A CN 01814088A CN 1175139 C CN1175139 C CN 1175139C
- Authority
- CN
- China
- Prior art keywords
- fabric
- layer
- concentration
- fabric substrate
- citrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 120
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 64
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052737 gold Inorganic materials 0.000 claims abstract description 44
- 239000010931 gold Substances 0.000 claims abstract description 44
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052802 copper Inorganic materials 0.000 claims abstract description 38
- 239000010949 copper Substances 0.000 claims abstract description 38
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 28
- 230000008569 process Effects 0.000 claims abstract description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 50
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 238000007747 plating Methods 0.000 claims description 26
- 229910052759 nickel Inorganic materials 0.000 claims description 25
- 239000000835 fiber Substances 0.000 claims description 22
- 239000000126 substance Substances 0.000 claims description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 13
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 238000009713 electroplating Methods 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 150000003504 terephthalic acids Chemical class 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 5
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 5
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 claims description 5
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 5
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims description 5
- 239000001119 stannous chloride Substances 0.000 claims description 5
- 235000011150 stannous chloride Nutrition 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 150000002343 gold Chemical class 0.000 claims description 3
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 3
- 229920002972 Acrylic fiber Polymers 0.000 claims description 2
- 238000005530 etching Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims 4
- 229960001484 edetic acid Drugs 0.000 claims 2
- 150000001879 copper Chemical class 0.000 claims 1
- 238000001465 metallisation Methods 0.000 claims 1
- 238000007772 electroless plating Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 206010020751 Hypersensitivity Diseases 0.000 description 4
- 208000030961 allergic reaction Diseases 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 101150003085 Pdcl gene Proteins 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- KPQDSKZQRXHKHY-UHFFFAOYSA-N gold potassium Chemical compound [K].[Au] KPQDSKZQRXHKHY-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- -1 platinum ion Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/125—Deflectable by temperature change [e.g., thermostat element]
- Y10T428/12507—More than two components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/125—Deflectable by temperature change [e.g., thermostat element]
- Y10T428/12514—One component Cu-based
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12875—Platinum group metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12882—Cu-base component alternative to Ag-, Au-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/105—Comprising a composite fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/109—Metal or metal-coated fiber-containing scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/109—Metal or metal-coated fiber-containing scrim
- Y10T442/126—Including a preformed film, foil, or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/134—Including a carbon or carbonized fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/138—Including a metal layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/145—Including a preformed film, foil, or sheet
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/184—Nonwoven scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/184—Nonwoven scrim
- Y10T442/186—Comprising a composite fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/184—Nonwoven scrim
- Y10T442/188—Metal or metal-coated fiber-containing scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/184—Nonwoven scrim
- Y10T442/198—Coated or impregnated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3008—Woven fabric has an elastic quality
- Y10T442/3016—Including a preformed layer other than the elastic woven fabric [e.g., fabric or film or foil or sheet layer, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3382—Including a free metal or alloy constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3382—Including a free metal or alloy constituent
- Y10T442/3407—Chemically deposited metal layer [e.g., chemical precipitation or electrochemical deposition or plating, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3382—Including a free metal or alloy constituent
- Y10T442/3415—Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the woven fabric]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3382—Including a free metal or alloy constituent
- Y10T442/3415—Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the woven fabric]
- Y10T442/3423—Plural metallic films or foils or sheets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/475—Including a free metal or alloy constituent
- Y10T442/481—Chemically deposited metal layer [e.g., chemical precipitation or electrochemical deposition or plating, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
- Y10T442/656—Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the nonwoven fabric]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/654—Including a free metal or alloy constituent
- Y10T442/657—Vapor, chemical, or spray deposited metal layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Chemically Coating (AREA)
Abstract
本发明公开了一种导电织物，该导电织物通过以下步骤制造：制备呈纺织片、无纺片或网孔片形式的基础纤维织物基底；根据化学镀工艺，在纤维织物基底上形成第一层，第一层由铜形成；以及在第一层上连续地形成作为外露层的第二层，第二层由金或铂形成。
Description
技术领域
本发明涉及一种金叠层织物(gold layer-laminated fabric)及其制造方法，更具体地涉及一种通过在纤维织物基底上连续地镀一铜层、以及一金或铂层而制造的纤维织物，从而允许该织物具有良好的热导性、电导性、防蛀性和抗菌力。此外，本发明还涉及一种通过在纤维织物基底上镀一铜层、以及一金或铂层来制造织物的方法。
背景技术
导电织物起初是由国家航空和航天局(NASA)为了防止不允许差错的航天设备的误操作而开发的。现在，这种导电织物用于所有的工业领域，以为人体提供良好的保护，并防止因工业设备的误操作导致的损失。
传统导电织物的一个例子是一种具有电磁屏蔽层的织物，该层通过在一织物基底上喷涂或涂敷导电的碳、铜、锰和粘结剂的混合物而形成。然而，这种织物的缺点在于，即使电磁屏蔽层提供了抵御电磁波的屏蔽作用，但是作为织物的本质特性的其加工性、透气性和柔性因电磁屏蔽层是利用在织物基底上直接喷涂或涂敷该混合物的方法而制造而下降。
也已经开发出了多种织物产品，其中，其暴露在外界下的最外层由镍、铜、碳或银制造。在采用镍的情形下，在该最外层长期接触皮肤时，可能发生过敏反应。此时，还存在腐蚀或褪色的问题。此外，此产品具有较低的热导性和电导性。在利用铜或银的织物产品中，存在腐蚀或褪色的问题。在使用碳的情形下，存在的问题是具有非常低的热导性和电导性。
通常，由具有金属涂层的织物制造的衣服仅开发来以提供诸如电磁屏蔽功能的特殊功能，而不考虑穿着者的健康或这些衣服的美学效果。此外，无线通讯中的新发展导致了对具有与无线通讯相关的功能的功能性衣服的需要。然而，没有与这样的功能性衣服相关的实际产品。
因此，本发明的一个目的是提供一种织物，其具有良好的透气性、防蛀性、抗菌力、热导性和电导性。
本发明的另一个目的是提供一种织物，其不褪色，且同时对人体无害并具有金属光泽。
本发明的另一个目的是提供一种织物，其能避免因其最外层的剥离而暴露的其内层引起的对穿着者身体有害的过敏反应。
本发明的再一个目的是提供一种制造能实现上述目的的织物的方法。
发明内容
根据一个方面，本发明提供一种导电织物，其包括：呈纺织片(woven)、无纺片(non-woven)、或网孔片(mesh sheet)形式的纤维织物基底；通过化学镀工艺(electroless plating process)形成在该纤维织物基底上的第一层铜层；连续形成在第一层上的作为外露层的第二层金或铂层。该导电织物还可以包括由镍形成的且间插在该纤维织物基底与该第一层之间的第三层，该第三层用化学镀工艺形成。
镍和铜层可以利用化学镀工艺形成，而金或铂层可以利用电镀工艺或化学镀工艺形成。优选地，镍层厚度为0.1至0.2微米，铜层厚度为0.3至0.7微米，且金或铂层的厚度为0.05至0.2微米。
纤维织物基底可以由选自聚酯纤维、丙烯酸纤维和聚酰胺纤维构成的组中的一种纤维制造。纤维织物基底由呈单丝(mono-filament)或多丝(multi-filament)形式的纤维制成。
根据另一方面，本发明提供一种制造导电织物的方法，该方法包括步骤：制备利用对苯二酸和异丙醇的缩合聚合物制成的聚酯基纤维制造的纤维织物基底；在该纤维织物上涂上80至90g/l的氢氧化钠，并在80℃的温度下对纤维织物基底执行腐蚀工艺，以部分去除对苯二酸；在纤维织物基底上涂上盐酸来中和氢氧化钠，然后在纤维织物基底上涂上由氯化钯(PdCl2)、氯化锡(SnCl2)和盐酸(HCl)构成的复合盐，以该复合盐代替对苯二酸被去除了的位置；在约40至约60℃的温度下将硫酸涂到纤维织物基底上，以在纤维织物基底上金属化以离子态存在的钯；清洗该纤维织物基底，并在纤维织物基底上涂上氯化亚铜、福尔马林、罗谢尔盐、柠檬酸盐、乙二胺四醋酸(EDTA)和氢氧化钠，以在纤维织物基底上形成铜层；以及在纤维织物基底上涂敷氰化金钾(potassium gold cyanids)、EDTA、柠檬酸盐、以及氨水，以在铜层上形成金层。
优选地，铜层利用在约40至50℃的温度和12.0至13.0的pH值下进行的化学镀工艺形成为具有0.3至0.7微米的厚度，该工艺中，使用氯化亚铜浓度为约10至30g/l，福尔马林浓度为约10至30g/l，罗谢尔盐的浓度为约5至10g/1，柠檬酸盐的浓度为约5至10g/l，EDTA的浓度为约20至30g/l，氢氧化钠的浓度为约5至10g/l。优选地，金层利用化学镀工艺形成得具有0.05至0.2微米的厚度，该工艺利用浓度约为0.5至2g/l的氰化金钾、浓度约为15至25g/l的EDTA、浓度约为15至25g/l的柠檬酸盐、以及浓度约为10至30ml/l的氨水来进行。
可选地，金层的形成利用在20至50℃的温度和3.8至4.3的pH值下执行的电镀工艺来进行，该工艺利用了浓度约为60至80g/l的氰化金钾、浓度约为0.7至0.9g/l的钴、以及所需浓度的导电盐。
为了提供铜层对纤维织物基底的提高的粘结力，具有与活化的靶离子相似的电导性的镍可以镀在纤维织物基底上。镍层可以通过采用硫酸镍、次磷酸钠(sodium hypophospite)和柠檬酸盐的化学镀工艺来形成为具有0.1至0.2微米的厚度。优选地，镍层的形成利用在约30至40℃的温度下进行的化学镀工艺来执行，该工艺采用浓度约为10至20g/l的硫酸镍、浓度约为7.5至15g/l的次磷酸钠、以及浓度约为15至30g/l的柠檬酸盐。
附图说明
图1是示出根据本发明的织物的一部分的分解透视图；
图2是沿图1的线2-2截取的横截面图；
图3是示出根据本发明另一实施例的织物的横截面图；
图4是根据本发明的利用单丝制造的织物的SEM照片；以及
图5是根据本发明的利用多丝制造的织物的SEM照片。
具体实施方式
以下，将结合本发明的优选实施例来说明根据本发明的导电织物及制作该导电织物的方法。
图1是示出根据本发明的织物的一部分的放大透视图。
如图1所示，由附图标记10标注的织物利用处理过的纤维而制造为具有纺织片、无纺片或网孔片的形式。该纤维可以具有由单根丝构成的单丝10a的形式，或具有由捻在一起的多根丝构成的多丝10b的形式。优选地，用于本发明的纤维由选自聚酯、丙烯酸和聚酰胺树脂的树脂材料制造。
图2是沿图1的线2-2截取的横截面图、
参见图2，示出了纤维织物基底12，其上镀有铜，以形成铜层14。根据本发明的一个实施例，在纤维织物基底12上镀铜是以化学镀工艺进行。优选地，铜层14具有0.3至0.7微米的厚度。
如上所述，纤维织物基底12由呈单丝或多丝形式的纤维制造。在纤维织物基底12由呈多丝形式的纤维制造的情形下，由于镀层是对捻在一起的多丝纤维进行，所以提供了增大的镀层面积。因而此时，获得了粘附力和柔性的提高。
然后金或铂镀在铜层14上，从而形成金或铂层16。镀此金或铂层16可利用化学镀方法或电镀方法来进行。优选地，金或铂层16具有0.05至0.2微米的厚度。在此厚度范围内，最终的产品可以具有0.01至5.0Ω的所需表面电阻和0.1至5.0cal/cm·sec·℃的所需表面热导率。为了具有高纯度，金或铂16由通过如下步骤而析出的金或铂来制造，以具有99.9％或更高的纯度，该步骤为：将金或铂盐溶解到水中，从而使盐离子化，然后在离子化的盐上施加化学或电能。
根据本发明的所示实施例，提供了多种优点。
首先，即使作为织物最外部的镀层的金或铂层部分剥离，也可以避免过敏反应。这是因为穿着者的皮肤因金或铂层的部分剥离而与铜层接触。
此外，由于良好的导电和导热性通过基底纤维上的铜镀层来获得，所以用于形成金或铂层的金或铂的量可以减少。由于铜层具有能够允许利用电镀法来形成金或铂层的足够的厚度，所以制造成本也可以显著降低。
由于直接与穿着者的身体接触的最外层由金或铂层构成，所以可以通过金或铂层的良好导热性而迅速地向外释放从穿着者的身体发射的热。还可保持织物上的均匀温度分布。
由于金或铂层具有良好的导电性，所以还可以释放织物和穿着者身体之间产生的静电。这导致了避免由静电引起的电击的作用。
此外，借助直接接触身体的金或铂层的金或铂离子，有促进穿着者身体的血液循环的效果。金或铂层有中和毒负作用的功能，使得其提供了防蛀效果和抑制细菌繁殖的抗菌力。
由于织物的最外层由金或铂制造，所以具有了金或铂的特有金属光泽，而无任何腐蚀或褪色。
在该织物用于衣物的情况下，由于金或铂具有良好的延展性而获得了柔性的显著提高。
参见图3，示出了根据本发明另一实施例的织物。
此织物不同于上述实施例的地方在于在纤维织物基底12与铜层14之间间插有镍层18。镍层18以化学镀的方式镀在纤维织物基底12上。优选地，镍层18具有0.1至0.3微米的厚度。
在纤维织物基底12与铜层14之间间插镍层18的原因在于提高铜层14对纤维织物基底12的粘结力。即，镍可以牢固地粘结到纤维织物基底12上，因为在化学镀工艺过程中，镍与纤维织物基底12表面上粘附的金属靶(Pd)之间有较小的过渡差异(transition difference)。
虽然在本实施例中镍涂敷在了纤维织物基底上，但是可避免由镍引起的过敏反应。这是因为即使金或铂层部分剥离了，镍层仍被镀在其上的铜层维持在遮蔽状态，使得仅铜层可以接触穿着者的身体。
同时，图4和5是根据本发明的、分别采用单丝和多丝制造的织物的SEM照片。
下面将说明具有根据本发明的上述结构的织物的制造方法。
根据此实施例，纤维织物基底首先利用聚酯基纤维而被制备成具有纺织片、无纺片或网孔片的形式，该聚酯基纤维由对苯二酸和异丙醇的缩合聚合物制造。该纤维可以具有由单根丝构成的单丝的形式，或者可以具有由捻在一起的多根丝构成的多丝的形式。虽然可以采用任何纤维，但是在本发明中聚酯基纤维是优选的。
氢氧化钠以80至90g/l的浓度涂到纤维织物基底上，以获得后续镀层工艺中粘结力的提高。然后在80℃的温度下执行腐蚀工序，以部分去除对苯二酸。腐蚀工序之后，清洗纤维织物基底。
在清洗工序之后，在纤维织物基底上涂上10％的盐酸，以中和残存的氢氧化钠。然后清洗所得到的纤维织物基底。其后，在纤维织物基底上涂上由2g/l的氯化钯(PdCl2)、2g/l的氯化锡(SnCl2)和10％的盐酸(HCl)构成的复合盐，来进行催化以该复合盐代替对苯二酸被去除了的位置。借助于催化作用，形成钯离子核，为作为非导体的纤维织物基底提供电导性。在催化之后，清洗所得到的纤维织物基底。
随后，在约40至60℃的温度下将10％的硫酸涂到纤维织物基底上，以将钯由离子态活化为金属态。或者，在室温下在纤维织物基底上涂上100g/l的氢氧化钠和10％的硫酸。然后清洗所得到的纤维织物基底。
其后，化学镀工艺利用约10至30g/l的氯化亚铜、约10至30g/l的福尔马林、约5至10g/l的罗谢尔盐、约5至10g/l的柠檬酸盐、约20至30g/l的EDTA、以及约5至10g/l的氢氧化钠，在约40至50℃的温度和12.0至13.0的pH值下进行，从而在纤维织物基底上形成铜层。优选地，铜层具有0.3至0.7微米的厚度。然后清洗所得到的结构。
为了在铜层上形成金层，接着利用约0.5至2g/l的氰化金钾、约15至25g/l的EDTA、约15至25g/l的柠檬酸盐、以及约10至30ml/l的氨水，在约80至90℃的温度下，进行化学镀工艺1至3分钟。
或者，金层的形成可以在20至50℃的温度和3.8至4.3的pH值下，采用约6至7g/l的氰化金钾、约60至80g/l的柠檬酸盐、约0.7至0.9g/l的钴、以及所需量的其它导电盐进行的电镀工艺中获得。在采用电镀工艺的情形中，可以减少所用的金量，从而实现成本的降低。这可以通过充分增厚用作金层的下部支撑层的铜层来实现，从而获得电阻的降低。
优选地，金层具有0.05至0.2微米的厚度。
虽然铜层在所示实施例中直接镀在纤维织物基底上，但是可在纤维织物基底和铜层之间间插一镍层。在此情形中，因镍与纤维织物基底表面上的活化钯离子牢固地结合，所以镍层提供了改善铜层的粘结效果的优点。
镍层的形成通过在30至40℃的温度和8至9的pH值下进行的采用约10至20g/l的硫酸镍、约7.5至15g/l的次磷酸钠、以及约15至30g/l的柠檬酸盐的化学镀工艺来实现，从而在纤维织物基底上沉积镍。优选地，镍层具有0.1至0.3微米的厚度。
根据本发明的方法，通过适当地调整铜层的厚度，金层可以具有小的厚度。借助通过厚度调整的铜层而获得的良好导电性，可以将电镀工艺用于金层的形成。因此，可以减少所用的金量，从而获得成本的降低。
虽然为了说明的目的已经公开了本发明的优选实施例，但是本领域技术人员将理解，在不脱离本发明的由所附权利要求所定义的范围和精髓的情况下，可作各种更改、附加和替换。
Claims (15)
1.一种导电织物，包括：
纤维织物基底；
通过化学镀工艺形成在该纤维织物基底上的第一层铜层；
连续形成在该第一层上且暴露在外的第二层金或铂层。
2.如权利要求1所述的导电织物，还包括间插在该纤维织物基底与该第一层之间且由化学镀工艺形成的第三层镍层。
3.如权利要求2所述的导电织物，其中，该第一层的厚度为0.3至0.7微米，该第二层的厚度为0.05至0.2微米，且该第三层的厚度为0.1至0.3微米。
4.如权利要求1所述的导电织物，其中，该第二层通过由化学镀工艺和电镀工艺中选出的一种形成。
5.如权利要求1所述的导电织物，其中，该纤维织物基底由选自聚酯纤维、丙烯酸纤维和聚酰胺纤维构成的组中的一种纤维制造。
6.如权利要求1所述的导电织物，其中，该纤维织物基底由呈单丝形式的纤维制成。
7.如权利要求1所述的导电织物，其中，该纤维织物基底由呈多丝形式的纤维制成。
8.如权利要求1所述的导电织物，其中，该纤维织物基底具有选自纺织形式、无纺形式和网孔形式构成的组中的一种形式。
9.一种制造导电织物的方法，该方法包括步骤：
制备利用作为对苯二酸和异丙醇的缩合聚合物的聚酯基纤维制造的纤维织物基底；
在80℃的温度下，执行在该纤维织物基底上涂上80至90g/l的氢氧化钠的腐蚀工艺，以从该纤维织物基底上部分地去除对苯二酸；
在该纤维织物基底上涂上盐酸来中和氢氧化钠；
以复合盐代替对苯二酸被去除了的位置，其中，该复合盐包括氯化钯、氯化锡和盐酸；
在约40至60℃的温度下将硫酸涂到纤维织物基底上，以金属化复合盐中包含的钯离子；
清洗该纤维织物基底，并将该纤维织物基底浸到第一溶液中，以在该纤维织物基底上形成铜层，该第一溶液包括氯化亚铜、福尔马林、罗谢尔盐、柠檬酸盐、乙二胺四乙酸和氢氧化钠；以及
将纤维织物基底浸到第二溶液中，以在铜层上形成金层，该第二溶液包括氰化金钾、乙二胺四乙酸、柠檬酸盐、以及氨水。
10.如权利要求9所述的方法，其中，该金层通过化学镀工艺形成，该工艺利用浓度约为0.5至2g/l的氰化金钾、浓度约为15至25g/l的EDTA、浓度约为15至25g/l的柠檬酸盐、以及浓度约为30ml/l的氨水来进行。
11.如权利要求9所述的方法，其中，该铜层通过化学镀工艺形成，该工艺在约40至50℃的温度和12.0至13.0的pH值下，利用浓度为约10至30g/l的氯化亚铜、浓度为约10至30g/l的福尔马林、浓度为约5至10g/l的罗谢尔盐、浓度为约5至10g/l的柠檬酸盐、浓度为约20至30g/l的EDTA、以及浓度为约5至10g/l的氢氧化钠来进行。
12.如权利要求9或11所述的方法，其中，该金层利用电镀工艺形成，该工艺利用氰化金钾、柠檬酸盐、钴、以及导电盐来进行。
13.如权利要求12所述的方法，其中，该电镀工艺在20至50℃的温度和3.8至4.3的pH值下，利用浓度约为6至7g/l的氰化金钾、浓度约为60至80g/l的柠檬酸盐、浓度约为0.7至0.9g/l的钴、以及所需浓度的导电盐来进行。
14.如权利要求9所述的方法，还包括步骤：
就在形成铜层之前，通过进行采用硫酸镍、次磷酸钠和柠檬酸盐的化学镀工艺来在纤维织物基底上形成镍层。
15.如权利要求14所述的方法，其中，该化学镀在约30至40℃的温度下，采用浓度约为10至20g/l的硫酸镍、浓度约为7.5至15g/l的次磷酸钠、以及浓度约为15至30g/l的柠檬酸盐来进行。
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR2000/37748 | 2000-07-03 | ||
| KR2000/18971U | 2000-07-03 | ||
| KR1020000037748A KR100344958B1 (ko) | 2000-07-03 | 2000-07-03 | 도전성 직물지의 제조방법 |
| KR2020000018971U KR200211121Y1 (ko) | 2000-07-03 | 2000-07-03 | 금층이 형성된 직물지 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1446280A CN1446280A (zh) | 2003-10-01 |
| CN1175139C true CN1175139C (zh) | 2004-11-10 |
Family
ID=26637804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018140882A Expired - Fee Related CN1175139C (zh) | 2000-07-03 | 2001-03-03 | 金叠层织物及其制造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6831024B2 (zh) |
| JP (1) | JP2004502055A (zh) |
| CN (1) | CN1175139C (zh) |
| AU (1) | AU2001241218A1 (zh) |
| DE (1) | DE10196402T1 (zh) |
| WO (1) | WO2002002861A1 (zh) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3103597U (ja) * | 2003-08-18 | 2004-08-19 | 和立聯合科技股▲ふん▼有限公司 | 電磁波シールド用金属被覆繊維布帛 |
| WO2007089053A1 (en) * | 2006-02-03 | 2007-08-09 | Keuk-Jun Kim | Treatment method of inorganic antibacterial agent for textile |
| WO2007117191A1 (en) * | 2006-04-07 | 2007-10-18 | Bactiguard Ab | Novel antimicrobial substrates and uses thereof |
| CN101748599B (zh) * | 2009-12-25 | 2012-07-04 | 浙江三元电子科技有限公司 | 一种导电纱及其制备方法 |
| CN101808432B (zh) * | 2010-03-26 | 2012-02-08 | 吉林华阳电力装备制造有限公司 | 湿浸拉缩法生产碳素发热线的工艺 |
| US20140057127A1 (en) * | 2012-08-22 | 2014-02-27 | Infineon Technologies Ag | Method for processing at least one carbon fiber, method for fabricating a carbon copper composite, and carbon copper composite |
| KR20170074644A (ko) * | 2015-12-22 | 2017-06-30 | 에스케이하이닉스 주식회사 | 반도체 패키지 |
| DE102018000272A1 (de) * | 2018-01-16 | 2019-07-18 | Elfolion Gmbh | Folienartiges Funktionsmaterial und Verfahren zu dessen Herstellung |
| CZ308348B6 (cs) * | 2018-11-06 | 2020-06-10 | Bochemie A.S. | Způsob kontinuálního pokovení textilního materiálu, zařízení k provádění tohoto způsobu, pokovený textilní materiál a jeho použití |
| CN111093353A (zh) * | 2019-12-10 | 2020-05-01 | 中国航空工业集团公司成都飞机设计研究所 | 轻质柔性高效线束电磁屏蔽套 |
| CN112626850A (zh) * | 2020-12-01 | 2021-04-09 | 嘉兴学院 | 一种抗菌纤维及其制备方法 |
| CN113235295B (zh) * | 2021-04-30 | 2022-07-15 | 青岛天银纺织科技有限公司 | 混合金属化防核辐射材料及其制备方法和服装 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0246710B2 (ja) * | 1985-07-18 | 1990-10-17 | Nippon Kagaku Kogyo Kk | Mudenkaimetsukiseninoseizoho |
| JPH05186967A (ja) * | 1992-01-07 | 1993-07-27 | Mitsubishi Paper Mills Ltd | 導電性を有する繊維、編織布並びに不織布、及びそれらの製造方法 |
| KR100222338B1 (ko) * | 1995-12-04 | 1999-10-01 | 박남일 | 전도성섬유의 제조방법 |
| CN1094030C (zh) * | 1996-08-05 | 2002-11-06 | 精仁株式会社 | 导电性材料及其制造方法 |
-
2001
- 2001-03-03 AU AU2001241218A patent/AU2001241218A1/en not_active Abandoned
- 2001-03-03 DE DE2001196402 patent/DE10196402T1/de not_active Ceased
- 2001-03-03 JP JP2002507101A patent/JP2004502055A/ja active Pending
- 2001-03-03 US US10/332,073 patent/US6831024B2/en not_active Expired - Fee Related
- 2001-03-03 WO PCT/KR2001/000328 patent/WO2002002861A1/en active Application Filing
- 2001-03-03 CN CNB018140882A patent/CN1175139C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6831024B2 (en) | 2004-12-14 |
| AU2001241218A1 (en) | 2002-01-14 |
| DE10196402T1 (de) | 2003-06-05 |
| WO2002002861A1 (en) | 2002-01-10 |
| CN1446280A (zh) | 2003-10-01 |
| JP2004502055A (ja) | 2004-01-22 |
| US20030102225A1 (en) | 2003-06-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1175139C (zh) | 金叠层织物及其制造方法 | |
| CN110983764B (zh) | 一种具有复合金属镀层结构的导电芳香族聚酰胺纤维 | |
| CN101215693A (zh) | 高性能导电纤维的制备方法 | |
| KR101004282B1 (ko) | 전자파 장해 방지용 도전성 섬유의 제조 방법 | |
| CN1314533C (zh) | 一种复合泡沫金属及其制备方法 | |
| CN1558017A (zh) | 一种镍铜复合金属织物及其制备方法 | |
| KR20010070270A (ko) | 금속피복섬유재료 | |
| CN107513858A (zh) | 一种Co‑Ni‑P‑Nd合金电磁屏蔽织物的制备方法 | |
| JP5160057B2 (ja) | 銀めっき付き繊維材料 | |
| KR100377265B1 (ko) | 도전성 직물지 및 그의 제조방법 | |
| CN115216755A (zh) | 一种无纺布表面两步法铜盐活化化学镀铜的方法 | |
| JPH09107195A (ja) | 高電磁波シールド性複合シートの製造方法 | |
| JP4634063B2 (ja) | 黒色導電性メッシュ織物およびその製造方法 | |
| JP4575583B2 (ja) | 金属被覆繊維材料 | |
| KR100344958B1 (ko) | 도전성 직물지의 제조방법 | |
| KR20000059156A (ko) | 금속과 셀룰로오스로 조성된 스킨-코어 단섬유 | |
| CN115322014B (zh) | 含有金属涂层的陶瓷基底及其制备方法 | |
| KR200217600Y1 (ko) | 최외부층에 금층이 형성된 도전성 직물지 | |
| KR20010026385A (ko) | 전자파 차단용 도전성 섬유 및 그 제조방법 | |
| CN109371668A (zh) | 一种电磁屏蔽防辐射导电布 | |
| CN114752906B (zh) | 一种导电布及其制备方法和应用 | |
| JP2005048243A (ja) | 導電性めっき繊維構造物およびその製造方法 | |
| KR20030068601A (ko) | 폴리에스테르 도금사의 제조방법 | |
| JP2010126824A (ja) | 金属めっき繊維構造物及びそれを焼成してなる金属構造物 | |
| JP3070467U (ja) | 金属被覆繊維材料 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20041110 Termination date: 20100303 |