CN1173019C - 一种手动变速箱油添加剂组合物 - Google Patents
一种手动变速箱油添加剂组合物 Download PDFInfo
- Publication number
- CN1173019C CN1173019C CNB01130779XA CN01130779A CN1173019C CN 1173019 C CN1173019 C CN 1173019C CN B01130779X A CNB01130779X A CN B01130779XA CN 01130779 A CN01130779 A CN 01130779A CN 1173019 C CN1173019 C CN 1173019C
- Authority
- CN
- China
- Prior art keywords
- compositions
- component
- derivative
- additives
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000000654 additive Substances 0.000 title claims abstract description 46
- 230000000996 additive effect Effects 0.000 title claims abstract description 16
- 230000005540 biological transmission Effects 0.000 title abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 238000005260 corrosion Methods 0.000 claims abstract description 6
- 230000007797 corrosion Effects 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 4
- 239000011593 sulfur Substances 0.000 claims abstract description 4
- -1 phosphorous acid ester Chemical class 0.000 claims description 16
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- 238000007254 oxidation reaction Methods 0.000 claims description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 239000007866 anti-wear additive Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 claims description 4
- CYRPECJLOQEQDX-UHFFFAOYSA-N oxo(sulfanylidene)molybdenum Chemical compound O=[Mo]=S CYRPECJLOQEQDX-UHFFFAOYSA-N 0.000 claims description 4
- 239000002530 phenolic antioxidant Substances 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 150000003852 triazoles Chemical class 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- 239000003921 oil Substances 0.000 abstract description 20
- 239000002199 base oil Substances 0.000 abstract description 9
- 230000003078 antioxidant effect Effects 0.000 abstract description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 239000011574 phosphorus Substances 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000010687 lubricating oil Substances 0.000 description 6
- 238000003556 assay Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000012208 gear oil Substances 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000158728 Meliaceae Species 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/049—Phosphite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/14—Chemical after-treatment of the constituents of the lubricating composition by boron or a compound containing boron
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
本发明提供了一种手动变速箱油添加剂组合物，它包括(A)至少一种含硫的极压抗磨剂；(B)至少一种抗氧抗腐剂；(C)至少一种含磷的抗磨剂；(D)至少一种摩擦改进剂；(E)至少一种防锈剂；(F)至少一种抗氧剂。将上述添加剂组合物按2.4wt%加入到中粘度指数或高粘度指数或超高粘度指数的基础油，或前述基础油的混合物中，可制备达到APIMT-1规格的卡车手动变速箱油。
Description
(一)技术领域
本发明涉及一种手动变速箱油添加剂组合物，尤其是一种卡车手动变速箱用润滑油的添加剂组合物，属于润滑油添加剂技术领域。
(二)背景技术
手动变速箱油复合剂是用于调制各种粘度牌号并满足国际标准API MT-1的卡车手动变速箱油复合剂，其加剂量是衡量该复合剂水平、技术经济性最重要的指标之一。通过国外专利查询，US 5763372公开的手动变速箱油复合剂由烃基的丁二酰亚胺和含硫抗磨剂、含磷抗磨剂组成，与本发明组合物组成不同。国内专利齿轮润滑油添加剂组合物(97112341.1)及专利97112340.3涉及到手动变速箱油及其复合剂，但其复合剂的加剂量与本发明相比明显偏高，而且使用该复合剂调制的手动变速箱油达不到API MT-1规格要求。
(三)发明内容
本发明的目的是：提供一种手动变速箱油添加剂组合物，可适用于各种基础油，用其调制的90、140、85W/90、85W/140、80W/90、80W/140、75W/90等粘度牌号的卡车手动变速箱油均满足API MT-1规格要求。
本发明为了实现上述目的，对添加剂组合物中的各种添加剂组分进行精心选择。除了考虑各组分功能添加剂自身的性能和突出的优点外，同时把热安定性、防腐性及耐久性作为优先考虑的条件之一。因此，仅靠添加剂各组分的性能远远不能实现上述目的，还必须对组合物中的各添加剂组分之间的性能进行平衡考察，以达到复合剂整体性能的平衡与统一。
本发明调配的卡车手动变速箱油复合剂，产品的硫含量为26.0～30.0wt％，磷含量为1.50～2.00wt％，氮含量为0.20～0.60wt％。具有良好的热安定性、防腐性及高温耐久性，产品以2.4wt％加剂量调制的90、140、85W/90、85W/140、80W/90、80W/140、75W/90等各种粘度牌号的卡车手动变速箱油均满足API MT-1规格要求。该产品加剂量低，生产成本低，具有很好的经济效益与社会效益。该复合剂组合物调配方便，性能优良，有广阔的推广应用前景。
本发明的卡车手动变速箱润滑油添加剂组合物，它含有：(A)至少一种含硫的极压抗磨剂；(B)至少一种抗氧抗腐剂；(C)至少一种含磷的抗磨剂；(D)至少一种摩擦改进剂；(E)至少一种防锈剂；(F)至少一种抗氧剂。所说的(A)为硫化异丁烯，所说的添加剂组合物，含(A)组分40～90wt％；所说的(B)为二烷基二硫代磷酸锌盐及其衍生物，所说的添加剂组合物，含(B)组分1～20wt％；所说的(C)为亚磷酸酯及其衍生物，或磷酸酯及其衍生物，或它们任意组合的混合物，所说的添加剂组合物，含(C)组分10～40wt％；所说的(D)为苯三唑脂肪胺盐及其衍生物，或二烷基二硫代磷酸硫氧化钼及其衍生物，或脂肪酸酯及其硼化物，或它们任意组合的混合物，所说的添加剂组合物，含(D)组分0.5～10wt％；所说的(E)为丁二酰亚胺及其硼化物，或有机磺酸盐，或脂肪酸酰胺及其硼化物，或它们任意组合的混合物，所说的添加剂组合物，含(E)组分2～15wt％；所说的(F)为硼酸酯及其衍生物，或胺类抗氧剂，或酚类抗氧剂，或它们任意组合物的混合物，所说的添加剂组合物，含(F)组分0.5～10wt％。
更进一步，本发明的卡车手动变速箱润滑油添加剂组合物，它含有：(A)至少一种含硫的极压抗磨剂；(B)至少一种抗氧抗腐剂；(C)至少一种含磷的抗磨剂；(D)至少一种摩擦改进剂；(E)至少一种防锈剂；(F)至少一种抗氧剂。
其中所说的(A)组分较适宜的是硫化异丁烯，组分(A)在添加剂组合物中的适宜含量为40～80wt％；
(B)组分较适宜的是二烷基二硫代磷酸锌盐及其衍生物，组分(B)在添加剂组合物中的适宜含量为1～15wt％；
(C)组分较适宜的是酸性亚磷酸酯，或中性磷酸酯，或它们任意组合的混合物，组分(C)在添加剂组合物中的适宜含量为10～30wt％；
(D)组分较适宜的是苯三唑脂肪胺盐及其衍生物，或二烷基二硫代磷酸硫氧化钼及其衍生物，或脂肪酸及其硼化物，或它们任意组合的混合物，组分(D)在添加剂组合物中的适宜含量为1.0～8.0wt％；
(E)组分较适宜的是丁二酰亚胺及其硼化物，或有机磺酸盐，或脂肪酸酰胺及其硼化物，或它们任意组合的混合物，组分(E)在添加剂组合物中的适宜含量为2～10wt％；
(F)组分较适宜的是硼酸酯及其衍生物，或胺类抗氧剂，或酚类抗氧剂，或它们任意组合的混合物，组分(F)在添加剂组合物中的适宜含量为1.0～8.0wt％。
制法：上述卡车手动变速箱润滑油添加剂组合物的制备方法是：先将按比例所需要的极压抗磨剂(A)、抗磨剂(C)、摩擦改进剂(D)加入带搅拌器的搪瓷调合釜中，其次按比例加入所需的抗氧抗腐剂(B)、防锈剂(E)、抗氧剂(F)，在60～70℃下，搅拌4h，至混合物全部溶解，并均匀透明。
为了筛选添加剂组分和添加剂组合物，本发明在实验室采用了各种试验方法进行模拟评定。其中有润滑油极压性能测定法(GB/T3142)，润滑油抗磨性能测定法(SH/T0189)。
为了评价添加剂组合物加入基础油后，是否符合API MT-1的国际标准，进行了石油产品铜片腐蚀试验法(GB/T5096或ASTM D130)，润滑油承载能力测定法(CL-100)(SH/T0306或ASTM D5182)，齿轮油热氧化安定性测定法(L-60、L-60-1)，齿轮油高温稳定性测定法(ASTM D5579)，与密封材料的适应性(ASTM D5662)，润滑油抗泡性能测定法(ASTM D892)。
(四)具体实施方式
本发明的效果通过下面的实施例进一步说明。但应明白，下面的实施例不是限制本发明的范围，任何不超过本发明的构思和范围的改动，都在本发明的范围之内。
实施例1：
添加剂组合物(I)，它包括：70wt％硫化异丁烯(组分A)；5wt％二烷基二硫代磷酸锌碱式盐(组分B)；15wt％酸性亚磷酸酯(组分C)；3wt％二烷基二硫代磷酸硫氧化钼(组分D)；5wt％中碱值石油磺酸钙(组分E)；2wt％胺类抗氧剂(组分F)。添加剂组合物(II)除不含二烷基二硫代磷酸锌碱式盐(组分B)外，其余均用组合物(I)。组合物(I)和(II)均以2.4wt％加入85W/90基础油中，其评定结果列表2中。
表1 85W/90基础油性质
| 项 目 | 性 质 |
| 100℃运动粘度，mm2/s-12℃表观粘度，mpa·s倾点℃闪点(开)℃ | 18.73119800-17212 |
表2 组合物(I)、(II)评价结果
| 项 目 | 组合物(I) | 组合物(II) |
| 铜片腐蚀(121℃×3h)级 | 1a | 3b |
实验结果表明，二烷基二硫代磷酸锌盐及其衍生物可明显改善卡车手动变速箱油添加剂组合物的防腐性能。
实施例2：
添加剂组合物(III)除不含酸性亚磷酸酯(组分C)外，其余均同组合物(I)。组合物(I)和(III)均以2.4wt％加入75W/90基础油中，其评定结果列表4中。
表3 75W/90基础油性质
| 项 目 | 性 质 |
| 运动粘度(100℃)，mm2/s-40℃表观粘度，mpa·s倾点℃闪点(开)℃ | 14.87138900-47189 |
表4 组合物(I)、(III)评价结果
| 项 目 | 组合物(I) | 组合物(III) |
| 四球极压试验PB，N四球磨损试验d，mm(392N、60min) | 10780.39 | 8820.52 |
实验结果表明，酸性亚磷酸酯(组分C)可明显提高卡车手动变速箱油添加剂组合物的极压抗磨性能。
实施例3：
添加剂组合物(IV)，它包括：60wt％硫化异丁烯(组分A)；8wt％二烷基二硫代磷酸锌碱式盐(组分B)；15wt％中性磷酸酯(组分C)；5wt％苯三唑脂肪胺盐(组分D)；10wt％硼化丁二酰亚胺(组分E)；2wt％酚类抗氧剂(组分F)。添加剂组合物(IV)以2.4wt％加入85W/90基础油中，其评定结果列表5。
实验结果表明：添加剂组合物(IV)具有良好的热安定性、防腐性及高温耐久性，以2.4wt％(质量)加剂量调制的85W/90卡车手动变速箱油完全满足API MT-1规格要求。
表5 组合物(IV)评价结果
| 项 目 | 指标(API MT-1) | 实测值 |
| 热安定性及部件清净度(L-60-1) | 大齿轮积炭、漆膜评分 不小于7.5油泥评分 不小于9.4 | 8.139.67 |
| 与密封材料的适应性(ASTM D5662)与铜部件的适应性(ASTM D130)抗磨性(FZG) | 通过评级 不大于2a失败级 不小于11 | 通过1a大于11 |
| 抗氧化性能(L-60) | 粘度增长％ 不大于100戊烷不溶物％ 不大于3.0甲苯不溶物％ 不大于2.0 | 31.551.600.90 |
| 高温润滑稳定性(ASTM D5579) | 循环次数 不小于66000 | 155800 |
| 抗泡性能(ASTM D892) | 24℃ 不大于20/093.5℃ 不大于50/0后24℃ 不大于20/0 | 0/010/00/0 |
| 贮存稳定性(FTM3440) | 液体沉积物v％ 不大于0.50固体沉淀物m％ 不大于0.25 | 00.004 |
Claims (8)
1.一种手动变速箱油添加剂组合物，其特征在于它含有：
(A)至少一种含硫的极压抗磨剂。为硫化异丁烯，组合物含组分(A)40～90wt％，
(B)至少一种抗氧抗腐剂，为二烷基二硫代磷酸锌盐及衍生物，组合物含组分(B)1～20wt％，
(C)至少一种含磷的抗磨剂，为亚磷酸酯及其衍生物，或磷酸酯及其衍生物，或它们任意组合的混合物，组合物含组分(C)10～40wt％，
(D)至少一种摩擦改进剂，为苯三唑脂肪胺盐及其衍生物，或二烷基二硫代磷酸硫氧化钼及其衍生物，或脂肪酸酯及其硼化物，或它们任意组合的混合物，组合物含组分(D)0.5～10wt％，
(E)至少一种防锈剂，为丁二酰亚胺及其硼化物，或有机磺酸盐，或脂肪酸酰胺及其硼化物，或它们任意组合的混合物，组合物含组分(E)2～15wt％，
(F)至少一种抗氧剂，为硼酸酯及其衍生物，或胺类抗氧剂，或酚类抗氧剂，或它们任意组合的混合物，组合物含组分(F)0.5～10wt％。
2.根据权利要求1所述的添加剂组合物，其特征在于(A)组分含量为40～80wt％。
3.根据权利要求1所述的添加剂组合物，其特征在于(B)组分含量为1～15wt％。
4.根据权利要求1所述的添加剂组合物，其特征在于(C)组分为酸性亚磷酸酯，或中性磷酸酯，或它们任意组合的混合物，含量为10～30wt％。
5.根据权利要求1所述的添加剂组合物，其特征在于(D)组分含量为1.0～8.0wt％。
6.根据权利要求1所述的添加剂组合物，其特征在于(E)组分含量为2～10wt％。
7.根据权利要求1所述的添加剂组合物，其特征在于(F)组分含量为1.0～8.0wt％。
8.根据权利要求1所述的添加剂组合物的应用，其特征在于该添加剂组合物以2.4wt％加剂量调制的卡车手动变速箱油满足APIMT-1规格，用于车辆变速箱的润滑。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01130779XA CN1173019C (zh) | 2001-08-24 | 2001-08-24 | 一种手动变速箱油添加剂组合物 |
| US10/222,606 US6774092B2 (en) | 2001-08-24 | 2002-08-16 | Additive composition for gearbox oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB01130779XA CN1173019C (zh) | 2001-08-24 | 2001-08-24 | 一种手动变速箱油添加剂组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1403548A CN1403548A (zh) | 2003-03-19 |
| CN1173019C true CN1173019C (zh) | 2004-10-27 |
Family
ID=4670138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB01130779XA Expired - Lifetime CN1173019C (zh) | 2001-08-24 | 2001-08-24 | 一种手动变速箱油添加剂组合物 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US6774092B2 (zh) |
| CN (1) | CN1173019C (zh) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329492C (zh) * | 2004-04-29 | 2007-08-01 | 张为光 | 一种节能环保润滑油 |
| US7482312B2 (en) * | 2005-04-01 | 2009-01-27 | Shell Oil Company | Engine oils for racing applications and method of making same |
| CN101376861B (zh) * | 2008-08-29 | 2012-01-11 | 上海金兆节能科技有限公司 | 一种微量润滑系统铝合金润滑剂及其制备方法和用途 |
| CN101613602B (zh) * | 2009-06-22 | 2013-11-27 | 衡阳市金化科技有限公司 | 用于热轧无缝钢管的硼砂抗氧化剂及其制备方法 |
| CN104046420B (zh) * | 2014-04-25 | 2016-06-22 | 蚌埠市鸿安精密机械有限公司 | 一种高铁道岔防锈油 |
| CN104046421A (zh) * | 2014-04-25 | 2014-09-17 | 蚌埠市正园电子科技有限公司 | 一种含滑石粉的拉丝油 |
| CN104004570A (zh) * | 2014-04-25 | 2014-08-27 | 蚌埠市时代电子有限公司 | 一种无腐蚀性防老化拉丝油 |
| CN103992866B (zh) * | 2014-04-25 | 2016-05-25 | 蚌埠市正园电子科技有限公司 | 一种快速散热高效拉丝油 |
| CN103992858B (zh) * | 2014-04-25 | 2016-05-18 | 蚌埠市鸿安精密机械有限公司 | 一种环保触变性防锈油 |
| CN103992863A (zh) * | 2014-04-25 | 2014-08-20 | 蚌埠市正园电子科技有限公司 | 一种含脂溶性维生素的拉丝油 |
| CN103992860B (zh) * | 2014-04-25 | 2016-05-18 | 蚌埠市鸿安精密机械有限公司 | 一种多功能复合防锈油 |
| CN104611097A (zh) * | 2015-01-04 | 2015-05-13 | 吴江华威特种油有限公司 | 一种润滑油组合物 |
| CN105296115B (zh) * | 2015-11-24 | 2019-01-01 | 江西科比润滑油制品有限公司 | 一种地铁列车专用齿轮油及其制备方法 |
| WO2018000433A1 (zh) * | 2016-07-01 | 2018-01-04 | 深圳市恒兆智科技有限公司 | 防锈剂、金属工件及其防锈处理方法 |
| WO2018112135A1 (en) * | 2016-12-16 | 2018-06-21 | The Lubrizol Corporation | Lubrication of an automatic transmission with reduced wear on a needle bearing |
| EP3736318B1 (en) * | 2019-05-09 | 2022-03-09 | Infineum International Limited | Transmission fluid composition for improved wear protection |
| CN113930271B (zh) * | 2020-06-29 | 2022-08-02 | 中国石油天然气股份有限公司 | 一种液压导轨油及其添加剂组合物 |
| CN116478751A (zh) * | 2022-01-13 | 2023-07-25 | 中国石油天然气股份有限公司 | 一种手动变速箱油复合添加剂 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2040819A1 (en) * | 1990-05-17 | 1991-11-18 | Stephen Norman | Lubricant compositions |
| US5415794A (en) * | 1990-12-28 | 1995-05-16 | Institut Francais Du Petrole | New sulfured compounds, their preparation and their use as additives for lubricating oils |
| US5843874A (en) * | 1996-06-12 | 1998-12-01 | Ethyl Corporation | Clean performing gear oils |
| US5763372A (en) * | 1996-12-13 | 1998-06-09 | Ethyl Corporation | Clean gear boron-free gear additive and method for producing same |
| EP0972821A3 (en) * | 1998-07-15 | 2001-04-04 | Nippon Mitsubishi Oil Corporation | Grease composition suitable for a constant velocity joint |
| US5944982A (en) | 1998-10-05 | 1999-08-31 | Uop Llc | Method for high severity cracking |
| JP4774151B2 (ja) * | 1998-10-19 | 2011-09-14 | ザ ルブリゾル コーポレイション | 改善された熱安定性およびスリップ性能を有する潤滑組成物 |
| US6303547B1 (en) * | 2000-09-19 | 2001-10-16 | Ethyl Corporation | Friction modified lubricants |
| US6444622B1 (en) * | 2000-09-19 | 2002-09-03 | Ethyl Corporation | Friction modified lubricants |
-
2001
- 2001-08-24 CN CNB01130779XA patent/CN1173019C/zh not_active Expired - Lifetime
-
2002
- 2002-08-16 US US10/222,606 patent/US6774092B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US6774092B2 (en) | 2004-08-10 |
| CN1403548A (zh) | 2003-03-19 |
| US20030045436A1 (en) | 2003-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1173019C (zh) | 一种手动变速箱油添加剂组合物 | |
| CN101298576B (zh) | 齿轮润滑油添加剂组合物 | |
| CN101298578B (zh) | 小轿车手动变速箱齿轮润滑油组合物 | |
| CN1209449C (zh) | 一种齿轮润滑油添加剂组合物 | |
| US4609480A (en) | Lubricant composition for improving fatigue life | |
| US4648985A (en) | Extreme pressure additives for lubricants | |
| US7871965B2 (en) | Gear oil having low copper corrosion properties | |
| CA2163206C (en) | Lubricating oil composition | |
| US9296973B2 (en) | Lubricating oil composition for use in all transmission systems | |
| CN101298574B (zh) | 通用工业齿轮油添加剂组合物 | |
| CN1115396C (zh) | 抗磨液压润滑油添加剂组合物 | |
| CN102417846B (zh) | 合成工业润滑油添加剂组合物 | |
| CN107418656A (zh) | 一种低气味车辆齿轮油复合添加剂 | |
| CN102492525A (zh) | 液压油添加剂组合物及其制备方法 | |
| CN1203160C (zh) | 一种工业齿轮油添加剂组合物 | |
| CN102417849A (zh) | 清洁型通用齿轮润滑油组合物 | |
| CN102131906B (zh) | 与含银材料接触的润滑油组合物 | |
| CN1727459A (zh) | 通用齿轮油组合物 | |
| EP0239088A2 (en) | A lubricant and process for its production | |
| EP0855437A1 (en) | Lubricating oil composition | |
| CA2606952C (en) | Lubricating composition having improved storage stability | |
| CN104220571A (zh) | 具有改进的同步啮合性能的手动变速器润滑剂 | |
| US3093669A (en) | Reaction products of molybdenum pentachloride and dialkylphosphites | |
| JP7453449B1 (ja) | 潤滑油組成物 | |
| WO2008024111A1 (en) | Lubricating composition having improved storage stability |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20041027 |
|
| CX01 | Expiry of patent term |