CN117229098A - Special fertilizer for corn and preparation method thereof - Google Patents

Special fertilizer for corn and preparation method thereof Download PDF

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Publication number
CN117229098A
CN117229098A CN202311216682.5A CN202311216682A CN117229098A CN 117229098 A CN117229098 A CN 117229098A CN 202311216682 A CN202311216682 A CN 202311216682A CN 117229098 A CN117229098 A CN 117229098A
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China
Prior art keywords
parts
corn
fertilizer
urea
inhibitor
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CN202311216682.5A
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Inventor
武良
高璐阳
肖晨星
郭武松
姜国庆
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Shandong Xinyangfeng Fertilizer Co ltd
Xinyangfeng Agricultural Science And Technology Co ltd
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Shandong Xinyangfeng Fertilizer Co ltd
Xinyangfeng Agricultural Science And Technology Co ltd
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Priority to CN202311216682.5A priority Critical patent/CN117229098A/en
Publication of CN117229098A publication Critical patent/CN117229098A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

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  • Fertilizers (AREA)

Abstract

The invention provides a fertilizer special for corn and a preparation method thereof. The special fertilizer for corn is prepared from stable fertilizer containing an inhibitor and precisely compounded polymer coated controlled release urea, wherein the stable fertilizer containing the inhibitor comprises the following raw materials in parts by weight: 60-70 parts of common urea, 20-30 parts of monoammonium phosphate, 30-40 parts of monopotassium phosphate, 10-20 parts of potassium chloride, 30-48 parts of medium trace elements, 25-35 parts of humic acid, 1.5-7.5 parts of nitrification inhibitor and 20-40 parts of filler. The special fertilizer for corn has the advantages of long-acting yield increase and high fertilizer utilization rate, can provide necessary nutrient elements for corn growth when being applied to soil, comprehensively and uniformly supply corn nutrients, remarkably improve corn yield, improve corn quality and realize agricultural sustainable production.

Description

Special fertilizer for corn and preparation method thereof
Technical Field
The invention relates to the technical field of fertilizers, in particular to a special fertilizer for corn and a preparation method thereof.
Background
Corn is a high-yield grain crop in China, is an important feed source in animal husbandry, breeding industry and the like, is also one of indispensable raw materials in food, medical and health, light industry, chemical industry and the like, and has wide planting area in China. The improvement of the economic yield of the corn is influenced by the reduction of soil fertility and diseases and insect pests, the unscientific fertilization seriously leads to the increase of corn harmful substances, the quality of the corn is reduced, the fertilizer is used in a large amount, the soil is easy to harden, the water and fertilizer retention performance is deteriorated, and the normal growth of the corn is seriously influenced.
The special fertilizer for corn of different types has different properties, and the nutrient content, solubility, pH value, stability, mobility in soil, fertilizer efficiency speed, lasting effect length and the like of the special fertilizer can all influence the utilization rate of the corn fertilizer. Therefore, the special fertilizer for corn provided by the invention has the advantages of long-acting yield increase and high fertilizer utilization rate, can comprehensively and uniformly supply corn nutrients when being applied to soil, and has important significance for realizing agricultural sustainable production.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention aims to provide the special fertilizer for the corn and the preparation method thereof, so as to solve the problems in the prior art.
In order to achieve the above object, the present invention is realized by the following technical scheme: the special fertilizer for corn is prepared from stable fertilizer containing an inhibitor and precisely compounded polymer coated controlled release urea, wherein the polymer coated controlled release urea is polyurethane coated controlled release urea with a controlled release period of 60 days, the mass fraction of nitrogen is 44%, and the stable fertilizer containing the inhibitor comprises the following raw materials in parts by weight: 60-70 parts of common urea, 20-30 parts of monoammonium phosphate, 30-40 parts of monopotassium phosphate, 10-20 parts of potassium chloride, 30-48 parts of medium trace elements, 25-35 parts of humic acid, 1.5-7.5 parts of nitrification inhibitor and 20-40 parts of filler.
Further, the medium trace elements comprise 5-10 parts of calcium, 20-30 parts of boron and 6-8 parts of molybdenum.
Further, the medium trace elements are calcium gluconate, sodium octaborate tetrahydrate and ammonium molybdate.
Further, the humic acid is 25-35 parts of fulvic acid.
Further, the nitrification inhibitor is 1.5-7.5 parts of 3, 4-dimethylpyrazole phosphate; the filler is 20-40 parts of attapulgite.
The preparation method of the fertilizer special for corn comprises the following steps of raw material crushing, mixing and melting, slurry spraying and granulating, cooling and screening, blending and the like, and the specific steps are as follows: step one, crushing urea, and then placing the crushed urea into a urea melting tank to prepare urea melt; adding the nitrification inhibitor into urea melt, and fully and uniformly mixing to obtain mixed melt containing the inhibitor; step three, monoammonium phosphate, monopotassium phosphate, potassium chloride, medium trace elements, humic acid and filler are placed in a mixing tank to obtain mixed melt; step four, adding the mixed melt obtained in the step one into a mixing tank in the step three to be uniformly mixed so as to obtain a eutectic; step five, preparing a stable fertilizer containing an inhibitor; and step six, preparing special corn fertilizers with different precise compounding proportions.
Further, the internal temperature of the melting tank in the first step is raised to 130-140 ℃; .
In the third step, the raw materials in the third step are crushed and heated to 50-60 ℃ in a mixing tank; in the fifth step, a slurry spraying granulation and cooling screening process is adopted.
And step six, the stable fertilizer containing the inhibitor and the polymer coated controlled release urea prepared in step five are put into a stirrer according to different weight portions to be stirred for 6-10min, and are uniformly mixed.
The invention has the beneficial effects that:
1. the special fertilizer for corn has scientific nutrient proportion, and the addition of humic acid and medium trace elements can lead the nutrients of the fertilizer to be more balanced, meet the requirements for the nutrients in the growth process of corn, ensure that the fertilizer is applied once without additional fertilizer, and meet the technical requirement of once fertilization of corn.
2. According to the special fertilizer for corn, the nitrification inhibitor is added, so that volatilization of fertilizer nutrients in a gaseous ammonia form can be effectively reduced, nitrogen loss is reduced, fertilizer application cost is further reduced, and environmental pollution is reduced.
3. The special fertilizer for corn can obviously increase the economic yield of corn, improve the quality of corn, obviously improve the utilization rate of fertilizer, and has safe and environment-friendly raw materials and no toxic effect on corn.
Drawings
FIG. 1 is a schematic structural view of the appearance of a fertilizer special for corn and a preparation method thereof.
Detailed Description
The invention is further described in connection with the following detailed description, in order to make the technical means, the creation characteristics, the achievement of the purpose and the effect of the invention easy to understand.
Referring to fig. 1, the present invention provides a technical solution: the invention discloses a special fertilizer for corn and a preparation method thereof, wherein test materials used in the embodiment of the invention are all conventional test materials in the field, and can be purchased through commercial channels.
Example 1
(1) Crushing 65 parts by weight of urea, putting the crushed urea into a urea melting tank, and heating to 135 ℃ to obtain urea melt;
(2) Adding 5.5 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 25 parts by weight of monoammonium phosphate, 35 parts by weight of monopotassium phosphate, 15 parts by weight of potassium chloride, 7.5 parts by weight of calcium gluconate, 25 parts by weight of sodium octaborate tetrahydrate, 7 parts by weight of ammonium molybdate, 30 parts by weight of fulvic acid and 30 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating the crushed materials to 55 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) Granulating by spraying, cooling and sieving to obtain a stable fertilizer containing the inhibitor;
(6) And (3) placing the stable fertilizer containing the inhibitor prepared in the step (5) and the polymer coated controlled release urea into a stirrer for stirring for 8min according to the weight ratio of 6:4, and uniformly mixing to obtain the corn special fertilizer with different precise compound proportions.
Example 2
(1) Crushing 60 parts by weight of urea, and then placing the crushed urea into a urea melting tank, and heating to 130 ℃ to obtain urea melt;
(2) Adding 5.0 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 20 parts by weight of monoammonium phosphate, 30 parts by weight of monopotassium phosphate, 10 parts by weight of potassium chloride, 5 parts by weight of calcium gluconate, 20 parts by weight of sodium octaborate tetrahydrate, 6 parts by weight of ammonium molybdate, 35 parts by weight of fulvic acid and 40 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating to 50 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) Granulating by spraying, cooling and sieving to obtain a stable fertilizer containing the inhibitor;
(6) And (3) placing the stable fertilizer containing the inhibitor prepared in the step (5) and the polymer coated controlled release urea into a stirrer for stirring for 8min according to the weight ratio of 6:4, and uniformly mixing to obtain the corn special fertilizer with different precise compound proportions.
Example 3
(1) 70 parts by weight of urea is crushed and then put into a urea melting tank, and the temperature is raised to 140 ℃ to obtain urea melt;
(2) Adding 6.0 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 30 parts by weight of monoammonium phosphate, 40 parts by weight of monopotassium phosphate, 20 parts by weight of potassium chloride, 10 parts by weight of calcium gluconate, 30 parts by weight of sodium octaborate tetrahydrate, 8 parts by weight of ammonium molybdate, 25 parts by weight of fulvic acid and 20 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating to 60 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) Granulating by spraying, cooling and sieving to obtain a stable fertilizer containing the inhibitor;
(6) And (3) placing the stable fertilizer containing the inhibitor prepared in the step (5) and the polymer coated controlled release urea into a stirrer for stirring for 8min according to the weight ratio of 6:4, and uniformly mixing to obtain the corn special fertilizer with different precise compound proportions.
Comparative example 1
(1) Crushing 65 parts by weight of urea, putting the crushed urea into a urea melting tank, and heating to 135 ℃ to obtain urea melt;
(2) Adding 5.5 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 25 parts by weight of monoammonium phosphate, 35 parts by weight of monopotassium phosphate, 15 parts by weight of potassium chloride, 7.5 parts by weight of calcium gluconate, 25 parts by weight of sodium octaborate tetrahydrate, 7 parts by weight of ammonium molybdate, 30 parts by weight of fulvic acid and 30 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating the crushed materials to 55 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) Granulating by spraying, cooling and sieving to obtain a stable fertilizer containing the inhibitor;
(6) And (3) placing the stable fertilizer containing the inhibitor prepared in the step (5) and the polymer coated controlled release urea into a stirrer for stirring for 6min according to the weight ratio of 4:6, and uniformly mixing to obtain the corn special fertilizer with different precise compound proportions.
Comparative example 2
(1) Crushing 65 parts by weight of urea, putting the crushed urea into a urea melting tank, and heating to 135 ℃ to obtain urea melt;
(2) Adding 5.5 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 25 parts by weight of monoammonium phosphate, 35 parts by weight of monopotassium phosphate, 15 parts by weight of potassium chloride, 7.5 parts by weight of calcium gluconate, 25 parts by weight of sodium octaborate tetrahydrate, 7 parts by weight of ammonium molybdate, 30 parts by weight of fulvic acid and 30 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating the crushed materials to 55 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) Granulating by spraying, cooling and sieving to obtain a stable fertilizer containing the inhibitor;
(6) And (3) placing the stable fertilizer containing the inhibitor prepared in the step (5) and the polymer coated controlled release urea into a stirrer for stirring for 10min according to the weight ratio of 8:2, and uniformly mixing to obtain the corn special fertilizer with different precise compound proportions.
Comparative example 3
(1) Crushing 65 parts by weight of urea, putting the crushed urea into a urea melting tank, and heating to 135 ℃ to obtain urea melt;
(2) Adding 5.5 parts by weight of nitrification inhibitor (3, 4-dimethylpyrazole phosphate) into urea melt, and fully and uniformly mixing to form mixed melt containing the inhibitor;
(3) Crushing 25 parts by weight of monoammonium phosphate, 35 parts by weight of monopotassium phosphate, 15 parts by weight of potassium chloride, 7.5 parts by weight of calcium gluconate, 25 parts by weight of sodium octaborate tetrahydrate, 7 parts by weight of ammonium molybdate, 30 parts by weight of fulvic acid and 30 parts by weight of attapulgite, and then placing the crushed materials in a mixing tank, and heating the crushed materials to 55 ℃ to obtain mixed melt;
(4) Adding the mixed melt obtained in the step (1) into a mixing tank in the step (3) to be uniformly mixed so as to obtain a eutectic;
(5) And granulating by spraying, cooling and sieving to obtain the stable fertilizer containing the inhibitor.
The corn special fertilizer prepared in examples 1-3 and comparative examples 1-3 was subjected to field trials.
In this example, the test site: the soil type of the test field is Jian Yo wet leaching soil (brown soil) which grows on a fourth loess-like matrix in the corn field in the Shandong province, the texture is sticky and heavy, the topography is flat, the previous crop is garlic, the basic physicochemical property of the soil before sowing is pH 6.95, the organic matter is 18.4g/kg, the alkaline hydrolysis nitrogen is 104mg/kg, the quick-acting phosphorus is 20.2mg/kg, the quick-acting potassium is 128.2mg/kg, the total nitrogen is 1.22g/kg, the total phosphorus is 1.04g/kg and the total potassium is 18.2g/kg.
Test materials: the variety of the corn is Zhengdan 958.
Test treatment: the test is carried out by 6 treatments, each treatment is repeated for 3 times, 18 test cells are total, the length of each cell is 10m, the width of each cell is 5.4m, the test cells are arranged in a completely random block mode, the periphery of each test cell is provided with protection rows, the corn plant spacing is 25cm, and the row spacing is 60cm. The special fertilizers for corn prepared in examples 1-3 and comparative examples 1-3 are applied at one time in each test area, the fertilizing amount is 50 kg/mu, and the field management after corn planting is daily management. The test results are shown in Table 1.
TABLE 1 Effect of different corn fertilizers on corn yield and fertilizer utilization
As can be seen from the analysis of Table 1, the economic yields of the corn of examples 1-3 and comparative examples 1-2 are respectively increased by 11.41%, 4.15%, 10.64%, 8.16% and 3.04%, and the fertilizer utilization rates are respectively increased by 6.10%, 2.23%, 0.10%, 4.06% and 2.02%, which shows that the use of the stabilized fertilizer containing the inhibitor in various proportions in combination with the polymer coated controlled release urea can effectively increase the economic yield and fertilizer utilization rate of the corn as compared with the use of the stabilized fertilizer containing the inhibitor alone. The special fertilizer for corn has good gain effect, can obviously increase the economic yield of corn, improve the quality of corn and obviously improve the utilization rate of the fertilizer.
While the fundamental and principal features of the invention and advantages of the invention have been shown and described, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present disclosure describes embodiments, not every embodiment is provided with a separate embodiment, and that this description is provided for clarity only, and that the disclosure is not limited to the embodiments described in detail below, and that the embodiments described in the examples may be combined as appropriate to form other embodiments that will be apparent to those skilled in the art.

Claims (9)

1. A special fertilizer for corn is characterized in that: the special fertilizer for corn is prepared from stable fertilizer containing an inhibitor and precisely compounded polymer coated controlled release urea, wherein the polymer coated controlled release urea is polyurethane coated controlled release urea with a controlled release period of 60 days, the mass fraction of nitrogen is 44%, and the stable fertilizer containing the inhibitor comprises the following raw materials in parts by weight: 60-70 parts of common urea, 20-30 parts of monoammonium phosphate, 30-40 parts of monopotassium phosphate, 10-20 parts of potassium chloride, 30-48 parts of medium trace elements, 25-35 parts of humic acid, 1.5-7.5 parts of nitrification inhibitor and 20-40 parts of filler.
2. The special fertilizer for corn of claim 1, wherein the medium trace elements are 5-10 parts of calcium, 20-30 parts of boron and 6-8 parts of molybdenum.
3. A fertilizer for corn as defined in claim 2, wherein: the medium trace elements are calcium gluconate, sodium octaborate tetrahydrate and ammonium molybdate.
4. The fertilizer for corn of claim 1, wherein: the humic acid is 25-35 parts of fulvic acid.
5. The fertilizer for corn of claim 1, wherein: the nitrification inhibitor is 1.5-7.5 parts of 3, 4-dimethylpyrazole phosphate; the filler is 20-40 parts of attapulgite.
6. A method for preparing the fertilizer special for corn as claimed in claim 1, wherein: the preparation method comprises the steps of raw material crushing, mixing and melting, slurry spraying and granulating, cooling and screening, blending and the like, and comprises the following specific steps: step one, crushing urea, and then placing the crushed urea into a urea melting tank to prepare urea melt; adding the nitrification inhibitor into urea melt, and fully and uniformly mixing to obtain mixed melt containing the inhibitor; step three, monoammonium phosphate, monopotassium phosphate, potassium chloride, medium trace elements, humic acid and filler are placed in a mixing tank to obtain mixed melt; step four, adding the mixed melt obtained in the step one into a mixing tank in the step three to be uniformly mixed so as to obtain a eutectic; step five, preparing a stable fertilizer containing an inhibitor; and step six, preparing special corn fertilizers with different precise compounding proportions.
7. The method of manufacturing according to claim 6, wherein: the internal temperature of the melting tank in the first step is raised to 130-140 ℃; .
8. The method of manufacturing according to claim 6, wherein: in the third step, the raw materials in the step are crushed and heated to 50-60 ℃ in a mixing tank; in the fifth step, a slurry spraying granulation and cooling screening process is adopted.
9. The method of manufacturing according to claim 8, wherein: and step six, the stable fertilizer containing the inhibitor and the polymer coated controlled release urea prepared in the step five are put into a stirrer according to different weight parts to be stirred for 6-10min, and are uniformly mixed.
CN202311216682.5A 2023-09-20 2023-09-20 Special fertilizer for corn and preparation method thereof Pending CN117229098A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101045655A (en) * 2007-04-06 2007-10-03 中国农业大学 Special fertilizer for northeast corn and preparation method thereof
CN102503639A (en) * 2011-10-29 2012-06-20 史丹利化肥股份有限公司 Melt granulation humic acid functional fertilizer special for corns and preparing method thereof
CN102807443A (en) * 2012-08-29 2012-12-05 史丹利化肥股份有限公司 High-efficiency all-nutritional corn special fertilizer prepared by granulation of tower-type melt and production method thereof
CN104829396A (en) * 2015-04-30 2015-08-12 河南神州大化肥业有限公司 Humic acid controlled release blended fertilizer dedicated for corn
CN106242826A (en) * 2016-08-26 2016-12-21 山东三方化工集团有限公司 A kind of drought resisting, all nutrition type Semen Maydis long-acting special fertilizer and preparation method thereof
CN106673828A (en) * 2016-12-26 2017-05-17 中化化肥有限公司临沂农业研发中心 High-tower dual-effect inhibitor type corn stability special fertilizer and production method thereof
CN108558561A (en) * 2018-04-16 2018-09-21 史丹利化肥遂平有限公司 A kind of corn fertilizer and its manufacturing method of improvement soil
CN110698305A (en) * 2019-11-20 2020-01-17 河南心连心化学工业集团股份有限公司 Fulvic acid compound fertilizer suitable for corn planting in northeast region and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101045655A (en) * 2007-04-06 2007-10-03 中国农业大学 Special fertilizer for northeast corn and preparation method thereof
CN102503639A (en) * 2011-10-29 2012-06-20 史丹利化肥股份有限公司 Melt granulation humic acid functional fertilizer special for corns and preparing method thereof
CN102807443A (en) * 2012-08-29 2012-12-05 史丹利化肥股份有限公司 High-efficiency all-nutritional corn special fertilizer prepared by granulation of tower-type melt and production method thereof
CN104829396A (en) * 2015-04-30 2015-08-12 河南神州大化肥业有限公司 Humic acid controlled release blended fertilizer dedicated for corn
CN106242826A (en) * 2016-08-26 2016-12-21 山东三方化工集团有限公司 A kind of drought resisting, all nutrition type Semen Maydis long-acting special fertilizer and preparation method thereof
CN106673828A (en) * 2016-12-26 2017-05-17 中化化肥有限公司临沂农业研发中心 High-tower dual-effect inhibitor type corn stability special fertilizer and production method thereof
CN108558561A (en) * 2018-04-16 2018-09-21 史丹利化肥遂平有限公司 A kind of corn fertilizer and its manufacturing method of improvement soil
CN110698305A (en) * 2019-11-20 2020-01-17 河南心连心化学工业集团股份有限公司 Fulvic acid compound fertilizer suitable for corn planting in northeast region and preparation method thereof

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