CN117025320A - Clothing camphor-removing pill composition and preparation method and using method thereof - Google Patents
Clothing camphor-removing pill composition and preparation method and using method thereof Download PDFInfo
- Publication number
- CN117025320A CN117025320A CN202310876296.2A CN202310876296A CN117025320A CN 117025320 A CN117025320 A CN 117025320A CN 202310876296 A CN202310876296 A CN 202310876296A CN 117025320 A CN117025320 A CN 117025320A
- Authority
- CN
- China
- Prior art keywords
- composition
- clothes
- clothing
- camphor
- parts
- Prior art date
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- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000006187 pill Substances 0.000 title claims description 18
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 claims abstract description 84
- 241000723346 Cinnamomum camphora Species 0.000 claims abstract description 81
- 229960000846 camphor Drugs 0.000 claims abstract description 81
- 229930008380 camphor Natural products 0.000 claims abstract description 81
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 20
- 239000000194 fatty acid Substances 0.000 claims abstract description 20
- 229930195729 fatty acid Natural products 0.000 claims abstract description 20
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 20
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 19
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 19
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 15
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 14
- 150000003077 polyols Chemical class 0.000 claims abstract description 9
- 229920005862 polyol Polymers 0.000 claims abstract description 8
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 20
- 239000000243 solution Substances 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 16
- 239000003755 preservative agent Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 230000002335 preservative effect Effects 0.000 claims description 12
- 239000002738 chelating agent Substances 0.000 claims description 11
- 239000002562 thickening agent Substances 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000005639 Lauric acid Substances 0.000 claims description 2
- 235000021314 Palmitic acid Nutrition 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 21
- 239000000796 flavoring agent Substances 0.000 abstract description 9
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract description 8
- 235000019634 flavors Nutrition 0.000 abstract description 7
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 abstract description 4
- 229940117389 dichlorobenzene Drugs 0.000 abstract description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 27
- 239000004744 fabric Substances 0.000 description 19
- 239000007788 liquid Substances 0.000 description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 9
- 238000010998 test method Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002781 deodorant agent Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 102000004190 Enzymes Human genes 0.000 description 6
- 108090000790 Enzymes Proteins 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 229960005323 phenoxyethanol Drugs 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- 238000009423 ventilation Methods 0.000 description 4
- 229940025250 camphora Drugs 0.000 description 3
- 239000010238 camphora Substances 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- KUKRLSJNTMLPPK-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]hept-2-ene Chemical compound C1CC2(C)C=CC1C2(C)C KUKRLSJNTMLPPK-UHFFFAOYSA-N 0.000 description 2
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 2
- 206010067125 Liver injury Diseases 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- 231100000234 hepatic damage Toxicity 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 230000008818 liver damage Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- AMNOXHYEOXDZMU-UHFFFAOYSA-J [Na+].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CN)N.[Na+].[Na+].[Na+] Chemical compound [Na+].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CN)N.[Na+].[Na+].[Na+] AMNOXHYEOXDZMU-UHFFFAOYSA-J 0.000 description 1
- MVCMTOJZXPCZNM-UHFFFAOYSA-I [Na+].[Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.NCCNCCN Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.NCCNCCN MVCMTOJZXPCZNM-UHFFFAOYSA-I 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 208000007475 hemolytic anemia Diseases 0.000 description 1
- 210000003734 kidney Anatomy 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- -1 sodium fatty alcohol Chemical class 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- OFYLYBVZQCOXRQ-UHFFFAOYSA-J tetrasodium;cyclohexane-1,1-diamine;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O.NC1(N)CCCCC1 OFYLYBVZQCOXRQ-UHFFFAOYSA-J 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0068—Deodorant compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a clothing camphor ball-taste removing composition, a preparation method and a use method thereof, wherein the clothing camphor ball-taste removing composition comprises the following components in parts by weight: 4-15 parts of polyol, 2-8 parts of fatty alcohol polyoxyethylene ether sulfate, 3-9 parts of fatty acid and 0.5-2 parts of sodium hydroxide or potassium hydroxide. The invention uses the products of the reaction of the polyalcohol, the fatty alcohol polyoxyethylene ether sulfate and the fatty acid with the alkali metal hydroxide to increase the solubility of the dichlorobenzene, and the products react with the naphthol in the camphor ball, thereby removing the dichlorobenzene and the naphthol in the flavor of the camphor ball on clothes. The composition for removing the camphor ball taste of the clothes can remove the camphor ball taste of the clothes made of different materials, and has good removal effect and simple removal method.
Description
Technical Field
The invention relates to the field of clothes washing, in particular to a composition for removing camphor and ball taste of clothes, a preparation method and a use method thereof.
Background
At present, many consumers put camphorballs into clothes for insect prevention, moth prevention and mildew prevention. The main component of the camphora pill is paradichlorobenzene, naphthalene or 2-camphene, wherein the content of paradichlorobenzene accounts for about 80%, and paradichlorobenzene has irritation to eyes and upper respiratory tract, has inhibitory effect on central nerve and mainly causes liver damage. 2-camphene has small toxicity, has excitation effect on central nervous system, has stimulation effect on mucous membrane, has stimulation and sensitization effect on skin, and naphthalene is a condensed ring aromatic compound extracted from crude oil or coal tar, and has stimulation effect, and high concentration is easy to cause hemolytic anemia and liver and kidney damage. The camphor balls of clothes stored in the wardrobe have obvious smell, and naphthalene or paradichlorobenzene on the clothes has a stimulating effect on skin and respiratory tract, so that liver damage is easy to occur. And clothes stained with camphor ball smell can only fade smell after washing for many times, and the camphor ball smell can not be completely removed. At present, products and a removal method for removing camphor balls on clothes temporarily have no pertinence in the market, the effects of concentrated laundry liquid, peculiar smell removing laundry liquid, full-effect laundry liquid and the like on the aspect of removing the camphor balls are not obvious, and the camphor balls on the clothes after washing remain obvious, so that the health and wearing mood of consumers are influenced. Therefore, the clothes with camphor ball smell can be completely removed only by hanging and ventilating for a long time, and the smell removal time is long.
Disclosure of Invention
In order to overcome the problems of the prior art as described above, it is an object of the present invention to provide a composition for removing camphor balls from clothes.
The second object of the present invention is to provide a method for preparing the composition for removing camphor ball taste of clothes.
The invention also aims to provide a using method of the composition for removing camphor ball taste of clothes.
The fourth object of the present invention is to provide a washing liquid.
The fifth object of the present invention is to provide the use of a composition for removing camphorbolus from clothes in the field of clothes washing.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
the invention provides a composition for removing camphor balls from clothes, which comprises the following raw materials in parts by weight: 4-15 parts of polyol, 2-8 parts of fatty alcohol polyoxyethylene ether sulfate, 3-9 parts of fatty acid and 0.5-2 parts of sodium hydroxide or potassium hydroxide. The invention adopts sodium hydroxide or potassium hydroxide to react, the texture is softer, the saponified salt is more stable, the sediment is not easy to form, the textures of other kinds of salts are harder, the saponified salt is unstable, the sediment is easy to generate, and thus the aqueous solution of the prepared composition for removing camphor ball taste of clothes has sediment delamination.
Preferably, the weight part of the polyhydric alcohol in the composition for removing camphor ball taste of clothes is 4-6 parts.
Preferably, in the composition for removing camphor ball taste of clothes, the weight part of the fatty alcohol polyoxyethylene ether sulfate is 2-4 parts.
Preferably, the fatty alcohol-polyoxyethylene ether sulfate is at least one selected from fatty alcohol-polyoxyethylene ether sodium sulfate and fatty alcohol-polyoxyethylene ether potassium sulfate. The fatty alcohol polyoxyethylene ether sulfate has the following functions in the invention: has buffer effect on high pH soap base, and reduces irritation of soap base.
Preferably, the weight part of fatty acid in the composition for removing camphor ball taste of clothes is 3-6 parts.
Preferably, the mass percent of polyol in the composition is not less than 4%.
Preferably, the mass percentage of the fatty alcohol-polyoxyethylene ether sulfate is not less than 2%.
Preferably, the mass percentage of the fatty acid is less than 9% and not less than 3%.
Preferably, the aqueous solution of the composition has a pH of 9.6 to 9.8.
Preferably, the composition further comprises at least one of chelating agents, thickeners, preservatives, water.
Preferably, the composition further comprises the following raw materials in parts by weight: 0.01 to 0.1 part of chelating agent, 0.1 to 0.5 part of preservative, 0.1 to 0.2 part of thickener and 75 to 90 parts of water.
Preferably, the chelating agent is at least one selected from disodium EDTA, ethylenediamine tetraacetic acid, ethylenediamine tetrapropionic acid sodium salt, cyclohexanediamine tetraacetic acid sodium salt, sodium citrate, diethylenetriamine pentaacetic acid sodium salt; further preferably, the chelating agent is at least one selected from disodium EDTA, ethylenediamine tetraacetic acid, sodium citrate. The chelating agent functions in the present invention to chelate metal ions in water.
Preferably, the thickener is at least one selected from hydroxypropyl methylcellulose, sodium carboxymethylcellulose, sodium alginate, xanthan gum and carrageenan; further preferably, the thickener is at least one selected from hydroxypropyl methylcellulose and sodium carboxymethylcellulose. The thickener functions in the present invention as follows: increasing the viscosity of the composition and preventing delamination of the composition.
Preferably, the preservative is at least one selected from phenoxyethanol and ethylhexyl glycerol; further preferably, the preservative is phenoxyethanol. The preservative has the functions of inhibiting the growth and proliferation of microorganisms such as bacteria, fungi and the like, and prolonging the shelf life and the storage stability.
Preferably, the polyol is at least one selected from glycerol, propylene glycol, ethylene glycol, pentaerythritol, 1, 4-butanediol, 1, 6-hexanediol and neopentyl glycol; further preferably, the polyol is at least one selected from glycerol, propylene glycol, ethylene glycol; still further preferably, the polyol is glycerol. The polyol functions in the present invention to disperse and dissolve the product of the reaction of the fatty acid and the alkali metal hydroxide.
Preferably, the fatty acid is at least one selected from the group consisting of C12-C18 fatty acids.
Preferably, the fatty acid is at least one selected from lauric acid, myristic acid, palmitic acid and stearic acid.
In a second aspect, the invention provides a method for preparing a composition for removing camphor ball taste from clothes, which is prepared by adopting a first method or a second method:
the method comprises the following steps: the method comprises the following steps:
s1: heating and mixing sodium hydroxide or potassium hydroxide, part of water, chelating agent and polyalcohol, and then slowly adding fatty acid to obtain solution A; dispersing a thickener in the residual water, and then mixing with fatty alcohol polyoxyethylene ether sulfate to obtain a solution B;
s2: cooling the solution A, then mixing with the solution B and a preservative, and adjusting the pH value to obtain the composition for removing camphor and pilling taste of clothes;
the second method is as follows: the method comprises the following steps:
s11: heating and mixing sodium hydroxide or potassium hydroxide, part of water, fatty alcohol polyoxyethylene ether sulfate, a chelating agent and polyalcohol, and then slowly adding fatty acid to obtain a solution A; dispersing a thickener in the residual water to obtain a solution B;
s22: and (3) cooling the solution A, then mixing the solution A with the solution B and a preservative, and adjusting the pH value to obtain the composition for removing camphor and pilling smell of clothes.
The invention adopts a mode of slowly adding the fatty acid, so that bubbles in the system during stirring can be avoided.
Preferably, the clothing camphorremoving pellet taste composition is the clothing camphorremoving pellet taste composition provided in the first aspect of the present invention.
Preferably, in the first and second methods, the heating temperature in the heating and mixing step is 80-90 ℃; further preferably, in the first and second methods, the heating temperature in the heating and mixing step is 84 to 88 ℃.
Preferably, in the first and second methods, the cooling step is to cool to a temperature of 40-45 ℃.
Preferably, in the first and second methods, the step of adjusting pH is: and adjusting the pH to 9.6-9.8 by adopting a citric acid diluted solution. The pH after saponification is generally above 9.8 and requires the addition of citric acid to adjust the pH.
Preferably, in the first and second methods, the mass ratio of part of water to the remaining water is (0.7 to 1.5): 1, a step of; further preferably, in the first and second methods, the mass ratio of part of water to the remaining water is (0.9 to 1.3): 1.
in a third aspect, the present invention provides a method of using a composition for removing camphorbolus from clothing, comprising the steps of:
soaking the clothes in the aqueous solution containing the composition for removing camphor balls for 3-20 min, and then washing and rinsing the clothes.
Preferably, in the aqueous solution of the clothing camphorremoving pill composition, the mass volume ratio of the clothing camphorremoving pill composition to water is 1: (40-60) g/mL.
Preferably, the soaking time is 5-10 min.
Preferably, the washing is hand washing or machine washing.
Preferably, the washing step is: rubbing the clothes with hands for 5-30 times; further preferably, the washing step is: rubbing the clothes with hands for 5-20 times; still further preferably, the washing step is: the clothes are rubbed and washed by hands for 8 to 12 times.
In a fourth aspect the present invention provides a cleaning solution comprising the garment camphorpill composition of the first aspect of the present invention.
Preferably, the wash liquor further comprises an enzyme and a surfactant.
Preferably, the laundry camphorball-removing composition is added in an amount of 1 to 50% to the washing liquid.
A fifth aspect of the present invention provides the use of a garment camphorremoving pill composition as provided in the first aspect of the present invention in the field of laundry.
The beneficial effects of the invention are as follows: the invention uses the products of the reaction of the polyalcohol, the fatty alcohol polyoxyethylene ether sulfate and the fatty acid with the alkali metal hydroxide to increase the solubility of the dichlorobenzene, and the products react with the naphthol in the camphor ball, thereby removing the dichlorobenzene and the naphthol in the flavor of the camphor ball on clothes. The composition for removing the camphor ball taste of the clothes can remove the camphor ball taste of the clothes made of different materials, and has good removal effect and simple removal method.
The preparation method of the composition for removing camphor smell of clothes is simple, is easy to operate, has no dependence on equipment, and can be popularized and applied in a large scale.
Drawings
FIG. 1 is a flow chart showing the preparation process of the composition for removing camphor ball taste from clothes in examples 1 to 4 of the present invention.
FIG. 2 is a flow chart of a method of using the camphorpill composition for clothing according to the present invention in example 10.
Detailed Description
Specific embodiments of the present invention will be described in further detail below with reference to the drawings and examples, but the practice and protection of the present invention are not limited thereto. It should be noted that the following processes, unless otherwise specified, are all realized or understood by those skilled in the art with reference to the prior art. The reagents or apparatus used were not manufacturer-specific and were considered conventional products commercially available.
Examples 1 to 4
The amounts of the components of the compositions for removing camphorball taste for clothes in examples 1 to 4 are shown in Table 1, respectively.
Referring to the preparation process flow chart shown in fig. 1, the preparation method of the composition for removing camphor ball taste of clothes in examples 1 to 4 comprises the following steps:
step one, preparing phase A: adding potassium hydroxide into cold water for dissolution, then respectively adding EDTA disodium, fatty alcohol polyoxyethylene ether sulfate and glycerol, and heating to 85 ℃ after uniform dissolution;
and (3) preparing phase B: heating the fatty acid to 85 ℃;
preparing a phase C, dispersing HPMC in cold water, and then dissolving in a water bath at 60 ℃;
slowly adding the phase B into the phase A (the slow addition can avoid the generation of bubbles in the system due to stirring as much as possible), and keeping the temperature of the system at 80+/-2 ℃ for 30min after the phase B is completely added;
step three, adding a C phase and a D phase (preservative phenoxyethanol) when the temperature is reduced to about 40 ℃, and adding 10% citric acid diluent to adjust the pH value to 9.6;
and fourth, cooling to room temperature, and discharging to obtain the clothing camphor ball taste removing composition in examples 1-4.
TABLE 1 Components and component proportions (unit: wt%) of compositions for removing Camphor smell from clothes
Examples 5 to 9
The amounts of the components of the compositions for removing camphorball taste for clothes in examples 5 to 9 are shown in Table 2, respectively.
Referring to fig. 1, the preparation method of the composition for removing camphor ball taste of clothes in examples 5 to 9 comprises the following steps:
step one, preparing phase A: adding potassium hydroxide into cold water for dissolution, then respectively adding EDTA disodium and glycerol, and heating to 85 ℃ after uniform dissolution;
and (3) preparing phase B: heating the fatty acid to 85 ℃;
preparing a phase C, dispersing HPMC in cold water, dissolving in a water bath at 60 ℃, and mixing with fatty alcohol polyoxyethylene ether sulfate;
slowly adding the phase B into the phase A (the slow addition can avoid the generation of bubbles in the system due to stirring as much as possible), and keeping the temperature of the system at 80+/-2 ℃ for 30min after the phase B is completely added;
step three, adding a C phase and a D phase (preservative phenoxyethanol) when the temperature is reduced to about 40 ℃, and adding 10% citric acid diluent to adjust the pH value to 9.6;
and fourth, cooling to room temperature, and discharging to obtain the clothing camphor ball-removing composition in examples 5-9.
Table 2 Components and component proportions (unit: wt%) of the compositions for removing camphora smell from clothes in examples 5 to 9
Example 10
Referring to the flowchart of the method of use in fig. 2, the present example provides a method of using a composition for removing camphor balls from clothing (non-down jackets), comprising the steps of:
step a: adding 500mL tap water into a washtub, adding 10g of the composition for removing camphor balls from clothes, and uniformly mixing to prepare a deodorant; the dosage of the deodorant needs to be properly adjusted according to the size of the clothes and the type of the clothes;
step b: d, completely immersing the clothes into the deodorant in the step a, and standing for 5min; the standing time can be adjusted according to the types of clothes;
step c: washing the whole clothes by rubbing 10 times, and then manually rinsing or washing by a conventional machine;
step d: hanging and airing or drying the cleaned clothes.
Example 11
The application method of the composition for removing camphor balls of the down jackets comprises the following steps:
step a: adding 2000mL tap water into a washtub, adding 40g of the composition for removing camphor balls from clothes, and uniformly mixing to prepare a deodorant;
step b: c, fully immersing the down jackets into the deodorant in the step a, and standing for 10min; the standing time can be adjusted according to the types of clothes;
step c: rubbing down the whole down jacket for 10 times, and then manually rinsing or washing by a conventional machine;
step d: hanging, airing or drying the washed down jackets.
Comparative examples 1 to 5
The amounts of the respective components of the compositions for removing camphorball taste of clothes in comparative examples 1 to 5 are shown in Table 1, respectively.
The preparation methods of the compositions for removing camphor ball taste of clothes in comparative examples 1 to 5 were prepared with reference to the preparation methods of examples 1 to 4.
Performance testing
(1) Test of Camphor removal effect
To test the odor removal effect of the inventive laundry camphorpill composition, the following test methods were used: taking 500mL of tap water in a beaker respectively, then adding 10g of the compositions for removing camphor balls in the clothes in examples 1-9 (the compositions for removing camphor balls in comparative examples 1-5 or the commercial laundry detergent 1-4 are respectively added in a comparative test group), and uniformly mixing to prepare a deodorant; the cloth piece with camphor ball taste (the odor grade is D grade) is fully immersed into the deodorant, kept stand for 5min, rubbed and washed for 10min as a whole, then rinsed manually, the washed cloth piece is hung and dried, and then the removal effect of camphor ball taste on clothes is evaluated by the evaluation method in the following table 3.
Table 3 evaluation method of clothes odor
The camphor ball taste removal effect of the clothing camphor ball taste removal compositions of examples 1 to 4 and comparative examples 1 to 5 was evaluated according to the above test methods and clothing smell evaluation methods in table 3, respectively, and specific test results are shown in table 4.
Table 4 results of deodorizing effect test of the compositions for removing camphorball taste of clothes in examples 1 to 4 and comparative examples 1 to 5
As shown by the test results in Table 4, when the content of glycerin in the composition for removing camphor ball taste of clothes is more than or equal to 4%, the content of sodium fatty alcohol polyoxyethylene ether sulfate is more than or equal to 2%, and the content of 9% and more than or equal to 3%, the camphor ball taste on clothes can be effectively removed. Wherein the laundry camphorball-taste removing composition of example 1 is lower in cost while maintaining a good taste removing effect.
The clothing camphora pill-removing compositions in examples 1 and 5 to 9 and the commercial laundry liquids 1 to 4 (the commercial laundry liquid comprises surfactant, enzyme and auxiliary agent) were evaluated according to the above test methods and the clothing odor evaluation methods in table 3, respectively, and specific test results are shown in table 5:
TABLE 5 Effect of removal of Camphor ball taste on polyester Material
The clothing camphora-removing pellet-flavor compositions in example 1 and examples 5 to 9 and the commercial laundry liquids 1 to 4 (the commercial laundry liquid comprises surfactant, enzyme and auxiliary agent) were evaluated according to the above-mentioned test methods and the clothing odor evaluation methods in table 3, respectively, and specific test results are shown in table 6:
TABLE 6 Effect of removal of Camphor ball taste on cotton Material
The clothing camphora-removing pellet-flavor compositions in example 1 and examples 5 to 9 and the commercial laundry liquids 1 to 4 (the commercial laundry liquid comprises surfactant, enzyme and auxiliary agent) were evaluated according to the above test methods and the clothing odor evaluation methods in table 3, respectively, and specific test results are shown in table 7:
TABLE 7 Effect of removal of Camphor ball taste on wool materials
The clothing camphorremoving pellet taste compositions in examples 1 and 5 to 9 and the commercial laundry liquids 1 to 4 (the commercial laundry liquid comprises surfactant, enzyme and auxiliary agent) were evaluated according to the above test methods and the clothing odor evaluation methods in table 3, respectively, and specific test results are shown in table 8:
TABLE 8 Effect of removal of Camphor ball taste on Silk Material
The clothing camphorremoving pellet taste compositions of example 1 and examples 5 to 9 and the commercial laundry liquids 1 to 4 (the commercial laundry liquid comprises surfactant, enzyme and auxiliary agent) were evaluated according to the above test methods and the clothing odor evaluation methods of table 3, respectively, and specific test results are shown in table 9:
TABLE 9 Effect of removal of Camphor ball taste on Down jackets
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As is clear from tables 5-9, the residual concentration of the camphor ball on the polyester and down jacket clothes is higher than that on the cotton and wool clothes, and the currently marketed laundry detergent has poor deodorizing effect on the camphor ball clothes.
In the prior art, the effect of removing camphor balls on clothes by natural ventilation is also commonly adopted, the inventor ventilates terylene materials, cotton materials, wool materials, silk materials and down jackets with D-class peculiar smell grades at room temperature, and records the peculiar smell degree on the clothes when the natural ventilation is carried out for 7D and 14D respectively, and the specific test results are shown in table 10.
Table 10 Natural Ventilation deodorizing Effect of clothing made of different materials
| Sequence number | Terylene | Cotton cotton | Wool | Silk | Down jacket |
| Type of odor | Camphor pill flavor | Camphor pill flavor | Camphor pill flavor | Camphor pill flavor | Camphor pill flavor |
| Degree of odor | Class D | Class D | Class D | Class D | Class D |
| Natural draft 7d | Class C | Class B | Class C | Class B | Class C |
| Natural draft 14d | Class A | Class A | Class A | Class A | Class B |
As can be seen from table 10, the camphor ball smell on the clothes can be removed by natural ventilation, but the removal time is long, and more than two weeks are required to completely remove the smell.
(2) Effect on fabric color (chroma)
The method is characterized by selecting a reactive dye cloth piece which is possibly hydrolyzed, a direct dye with lower color fastness and an acid dye cloth piece which is not alkali-resistant for testing, wherein the specific testing method is as follows:
the processing method of the test cloth sample comprises the following steps: putting 500g of water into a beaker, adding 10g of the composition for removing camphor balls of the clothes in the embodiment 1, uniformly stirring, putting into a cloth piece, soaking the cloth piece for 5min, respectively stirring for 5min clockwise and anticlockwise, rinsing, putting the cloth piece on a tray flatly after rinsing, and baking for 30min at 50 ℃ for culture.
The processing method of the standard cloth sample comprises the following steps: putting 500g of water into a beaker, putting the cloth pieces, soaking the cloth pieces for 5min, stirring for 5 clockwise and anticlockwise respectively, rinsing, putting the cloth pieces on a tray flatly after rinsing, and baking for 30min in culture at 50 ℃.
The delta E value of the cloth piece after the test cloth sample and the standard cloth sample are tested and treated by a light-splitting color meter, wherein the delta E value is less than 1.0 and represents that the color fastness has small influence, and no obvious difference exists in naked eyes; the ΔE value of 1.0 or more represents a large effect on color fastness, and a clear difference can be observed with naked eyes, and then the test results are recorded in the following Table 11.
Table 11 effect of the garment camphorball-taste removal composition of example 1 on fabric color
As can be seen from Table 11, the cloth piece treated with the inventive composition has a DeltaE value < 1.0, i.e., the color fastness of the cloth piece is less affected by the treatment with the composition, and the composition can be used for removing the camphor balls on clothes of different colors and materials.
(3) Safety technical index and sensory physicochemical index test
The contents, appearance, smell, stability and pH of the microorganism and toxic substances in the compositions for removing camphorshot taste of clothes in examples 1 to 9 were respectively tested, wherein the test results of the contents of the microorganism and the toxic substances satisfy the requirements in table 12, the test results of the appearance, the smell, the stability and the pH satisfy the requirements in table 13, and further, the compositions for removing camphorshot taste of clothes in the present invention satisfy the requirements of cosmetic safety specifications and the requirements of sensory physicochemical indexes.
TABLE 12 cosmetic safety specification index test results
TABLE 13 sensory physicochemical index test results
(4) Validity test
The specific test method comprises the following steps:
collecting clothing information
Selecting clothes: 156 pieces of clothing with camphor ball taste (grade D) selection
And (3) grouping design: all the clothes are randomly divided into 6 groups of 26 pieces, and the 4 groups of clothes have no obvious difference in material ratio and camphor ball taste concentration and are comparable.
The testing method comprises the following steps:
taking 500mL of tap water in a washtub, respectively adding 10g of the compositions for removing camphor balls from the clothes in the examples 1 and 5-9, uniformly stirring, and properly adjusting the preparation dosage of the diluent according to the size of the clothes; then putting the clothes, fully soaking the clothes, standing for 5min, rubbing the whole clothes for 10min, then manually rinsing or washing by a conventional machine, hanging the clothes for airing or drying, then evaluating the odor grade of camphor ball on the clothes according to the clothes odor evaluation method in Table 3, and then calculating the total effective rate, wherein the specific test result is shown in Table 14.
Table 14 results of the test for the effectiveness of the compositions for removing camphorball taste for clothes of example 1, examples 5 to 9
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As can be seen from Table 14, the effective rate of removing the camphor ball taste of the clothes in the composition for removing the camphor ball taste of the clothes reaches more than 90 percent, and the composition for removing the camphor ball taste of the clothes with various materials can be used for removing the camphor ball taste of the clothes.
While the embodiments of the present invention have been described in detail, the present invention is not limited to the above embodiments, and various changes may be made without departing from the spirit of the present invention within the knowledge of those skilled in the art. Furthermore, embodiments of the invention and features of the embodiments may be combined with each other without conflict.
Claims (10)
1. A composition for removing camphor balls from clothing, characterized in that: the material comprises the following raw materials in parts by weight: 4-15 parts of polyol, 2-8 parts of fatty alcohol polyoxyethylene ether sulfate, 3-9 parts of fatty acid and 0.5-2 parts of sodium hydroxide or potassium hydroxide.
2. The clothing camphorremoving pill composition of claim 1, wherein: the aqueous solution of the composition has a pH of 9.6 to 9.8.
3. The clothing camphorremoving pill composition of claim 1, wherein: the composition further comprises at least one of a chelating agent, a thickener, a preservative, and water.
4. A clothing camphorremoving pill composition according to claim 1 or 3, wherein: the composition also comprises the following raw materials in parts by weight: 0.01 to 0.1 part of chelating agent, 0.1 to 0.5 part of preservative, 0.1 to 0.2 part of thickener and 75 to 90 parts of water.
5. The clothing camphorremoving pill composition of claim 1, wherein: the mass percentage of the polyol in the composition is not less than 4%; and/or the mass percentage of the fatty alcohol polyoxyethylene ether sulfate is not less than 2%; and/or, the mass percentage of the fatty acid is less than 9% and not less than 3%.
6. The clothing camphorremoving pill composition of claim 1, wherein: the polyalcohol is at least one selected from glycerol, propylene glycol, ethylene glycol, pentaerythritol, 1, 4-butanediol, 1, 6-hexanediol and neopentyl glycol.
7. The clothing camphorremoving pill composition of claim 1, wherein: the fatty acid is at least one selected from lauric acid, myristic acid, palmitic acid and stearic acid.
8. A method for preparing a composition for removing camphor and smell of clothes, which is characterized in that: the preparation method adopts a first method or a second method:
the method comprises the following steps: the method comprises the following steps:
s1: heating and mixing sodium hydroxide or potassium hydroxide, part of water, chelating agent and polyalcohol, and then slowly adding fatty acid to obtain solution A; dispersing a thickener in the residual water, and then mixing with fatty alcohol polyoxyethylene ether sulfate to obtain a solution B;
s2: cooling the solution A, then mixing with the solution B and a preservative, and adjusting the pH value to obtain the composition for removing camphor and pilling taste of clothes;
the second method is as follows: the method comprises the following steps:
s11: heating and mixing sodium hydroxide or potassium hydroxide, part of water, fatty alcohol polyoxyethylene ether sulfate, a chelating agent and polyalcohol, and then slowly adding fatty acid to obtain a solution A; dispersing a thickener in the residual water to obtain a solution B;
s22: and (3) cooling the solution A, then mixing the solution A with the solution B and a preservative, and adjusting the pH value to obtain the composition for removing camphor and pilling smell of clothes.
9. A method of using a composition for removing camphor balls from clothing, comprising: the method comprises the following steps:
soaking the clothes in the aqueous solution containing the composition for removing camphor balls for 3-20 min, and then washing and rinsing the clothes.
10. Use of a laundry camphorremoving pill composition according to any of the claims 1-7 in the laundry field.
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| CN202310876296.2A CN117025320A (en) | 2023-07-17 | 2023-07-17 | Clothing camphor-removing pill composition and preparation method and using method thereof |
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| CN202310876296.2A CN117025320A (en) | 2023-07-17 | 2023-07-17 | Clothing camphor-removing pill composition and preparation method and using method thereof |
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