CN116685234A - 用于卷曲头发或卷曲睫毛的新型组合物 - Google Patents
用于卷曲头发或卷曲睫毛的新型组合物 Download PDFInfo
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- CN116685234A CN116685234A CN202180087336.4A CN202180087336A CN116685234A CN 116685234 A CN116685234 A CN 116685234A CN 202180087336 A CN202180087336 A CN 202180087336A CN 116685234 A CN116685234 A CN 116685234A
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Abstract
本发明涉及用于卷曲头发或卷曲睫毛的新型组合物，其包含氨基酸、蛋白质、醇、植物油和至少一种有机酸；以及使用所述组合物卷曲头发的方法或卷曲睫毛的方法。
Description
技术领域
本发明涉及用于卷曲头发或卷曲睫毛的新型组合物，其包含氨基酸、蛋白质、醇、植物油和至少一种有机酸；以及使用所述组合物卷曲头发的方法或卷曲睫毛的方法。
背景技术
在头发护理领域，卷曲头发对应于一种可以暂时或长期地卷曲头发的发型设计技术。
希望卷曲他们的头发的消费者不仅寻求获得具有良好保持力的卷曲头发，而且寻求获得持久的结果，特别是通过耐受随后的洗发剂洗发。
为了以持久的方式改变头发的形状，通常使用机械和/或热处理。
机械处理包括通过在等待头发干燥的同时，将湿头发缠绕在圆柱形工具(如圆形刷子或卷曲器)上，给湿头发定型并且在干燥时保持该形状。
热处理依次包括将每绺头发在加热到160℃至230℃的圆柱形熨斗上缠绕并保持10至15秒。
这些处理允许发型的外观在形状方面和在头发的总体积方面进行视觉改变。它们使得可以获得卷曲的视觉外观，显著增加光泽，耐潮湿和耐热，以全天保持发型。
然而，这些方法的效果非常有限，因为卷曲的保持在数小时到数天之间变化，并且使用高温加热的工具会对头发造成不可逆的损伤。
因此，为了延长它们的效果，在机械和热处理之前，通常用特定的组合物对头发进行“化学”处理。
为了获得头发的卷曲，通常使用的技术包括，首先，使用含有硫还原剂的一般碱性组合物打开角蛋白(角质蛋白)的二硫键-S-S-(还原步骤)，然后，在用水漂洗如此处理的头发后，通过向预先拉紧的头发涂敷氧化组合物来二次重建所述二硫键(氧化步骤，也称为固定步骤)，从而最终赋予头发期望的形状。所用的组合物通常是基于巯基化或氨化还原剂的碱性或弱酸性组合物。尽管最终获得的卷曲效果通常是持久的，但是这些组合物需要严格遵守供应商推荐的应用条件，特别是在产品量和等待时间方面。此外，由于这些组合物的高度腐蚀作用，它们禁用于脆弱的头发和敏感的头皮。经常观察到头发断裂或甚至烧焦以及头皮发炎的问题。最后，这些组合物是难闻的。
因此，在本发明之日，仍然需要开发一种组合物，该组合物使得可以在容易的涂敷条件下以有效且持久的方式卷曲头发，而不劣化头发的质量。
国际专利申请WO-A-2019/012219描述了一种组合物，该组合物允许根据易于实施的涂敷方法进行有效且持久的头发拉直同时保持头发的质量，所述组合物包含氨基酸、蛋白质、醇和植物油。拉直效果是由于纤维的适度且可逆的变性的过程而获得的，该过程允许纤维在数月的时间段内保持直且光滑的外观，并耐受随后的洗发剂洗发，同时保持纤维的完整性。这种变性过程不足以用于卷曲头发。
然而，现在已经令人惊奇地发现，与专利申请WO-A-2019/012219中描述的组合物相似的组合物(其中加入了一定比例的一种或多种有机酸)使得可以根据易于实施的涂敷方法，以有效且持久的方式卷曲头发，同时保持头发的质量。此外，该组合物还可以用于根据易于实施的涂敷方法，以有效且持久的方式卷曲睫毛，同时保持睫毛的质量。
发明内容
因此，本发明涉及一种用于卷曲头发或卷曲睫毛的组合物，其包含：
-氨基酸；
-蛋白质；
-醇；
-植物油；和
-至少1％(w/w)的至少一种有机酸或其有机或无机盐。
根据本发明的组合物使得可以根据一种容易且舒适实施的涂敷方法以有效且持久的方式卷曲头发，同时保持头发的质量，特别是由于不存在热工具和巯基化和/或氨化还原剂。此外，该组合物还可以用于根据易于实施的涂敷方法，以有效且持久的方式卷曲睫毛，同时保持睫毛的质量。
在本发明的上下文中：
-“卷曲头发”应理解为可以卷曲直发以使其具有螺旋形或S形或使其具有明显波状表面的任何处理；
-“卷曲睫毛”应理解为使睫毛变弯(rounded)，以使睫毛具有比其自然形状(也就是说在处理之前)更弯曲的形状的任何处理；
-“氨基酸”应理解为本领域技术人员已知的任何氨基酸，特别是以下通式(I)或(II)的氨基酸：
其中
·R代表氢原子，任选被至少一个选自羟基、氨基的基团取代的C1-C5-烷基；-C(O)-OH；-S(O)2-OH；-C(O)-O-，M+；-S(O)2-O-，M+；
·M+代表阳离子反离子，例如碱金属、碱土金属或铵；
·n为0或1；
及其甜菜碱形式；其光学异构体；其溶剂化物，如水合物；及其酸性或碱性有机或无机盐；
所述氨基酸可以任选地接枝到异种分子上，该异种分子可能地是有机硅、碳水化合物、脂肪酸或衍生物、阴离子、阳离子、非离子或两性表面活性剂；
-“植物油”应理解为通过含油植物(也就是说其种子、坚果或果实含有脂质、甘油三酯或油酸、硬脂酸或亚油酸的植物)的任何压榨制备、离心、酯化或皂化方法提取的任何脂肪物质，其可任选地接枝到异种分子上，例如有机硅或具有阴离子、阳离子、非离子或两性性质的表面活性剂；
-“蛋白质”应理解为任何蛋白质、异种蛋白质或蛋白质衍生物，如接枝在分子上或异种分子上的蛋白质，所述异种分子可以是有机硅，碳水化合物，有机化合物，脂肪酸或其衍生物，发色团，具有阴离子、阳离子、非离子或两性性质的表面活性剂，所述蛋白质具有可变的尺寸和形状，由一个或多个负载有氨基酸并通过肽键键合的链形成。优选地，蛋白质是三级或四级结构；
-“Cx-Cy-烷基”应理解为直链或支链的饱和烃链，并且包含x至y个碳原子；
-“醇”应理解为被羟基、氨基醇、羟醛或酮醇取代的含有1至10个碳原子的任何直链或支链碳链。优选地，“醇”是指式CnH2n+1OH的任何直链或支链化合物，其中n为包含在1和10之间的整数；
-“有机酸”应理解为，由酸、多元酸(特别是二酸)、含氢酸和/或由于羧基(-
COOH)、羟基(-OH)或烯醇基的存在的含氧酸官能团组成，并且能够在水性介质中释放一种或多种阳离子的任何化学或有机化合物及其有机或无机盐；和
-“多元醇”应理解为被至少两个羟基取代的任何C1-C10-烷基。优选地，“多元醇”应理解为选自甘油、丙二醇、丙烷-1,3-二醇或山梨醇的任何化合物。
此外，在本发明的上下文中，除非另有说明，以％表示的比例对应于相对于相关对象的总重量的重量百分比。
因此，根据本发明的组合物包含氨基酸、蛋白质、醇、植物油和至少1％(w/w)的至少一种氨基酸。优选地，本发明涉及一种如前所述的组合物，其具有单独或组合考虑的以下特征：
-氨基酸选自赖氨酸、牛磺酸或蛋白氨基酸或其酸性或碱性有机或无机盐。
优选地，氨基酸选自蛋白氨基酸或其酸性或碱性有机或无机盐。更优选地，所述氨基酸选自天冬氨酸、谷氨酸、天冬酰胺、肉毒碱、半胱氨酸、谷氨酰胺、组氨酸、亮氨酸、异亮氨酸、甲硫氨酸、N-苯丙氨酸、脯氨酸、羟脯氨酸、苏氨酸、色氨酸、酪氨酸、缬氨酸、甘氨酸、丙氨酸、丝氨酸、β-丙氨酸和精氨酸或其酸性或碱性有机或无机盐。最优选地，氨基酸选自谷氨酸、半胱氨酸和精氨酸；
-所述组合物含有0.1％至20％的如上定义的氨基酸，优选0.1％至5％的如上定义的氨基酸，更优选0.1％至3％的如上定义的氨基酸；
-所述蛋白质选自任选地水解的肌酸、任选地水解的小麦蛋白、任选地水解的丝蛋白、任选地水解的螺旋藻蛋白、任选地水解的植物角蛋白、任选地水解的大豆蛋白、任选地水解的胶原蛋白、任选地水解的弹性蛋白、任选地水解的豌豆蛋白、任选地水解的大米蛋白、任选地水解的贝壳硬蛋白和任选地水解的乳清蛋白。最优选地，所述蛋白质选自肌酸、任选地水解的螺旋藻蛋白、任选地水解的小麦蛋白、任选地水解的丝蛋白和任选地水解的大豆蛋白；-所述组合物含有0.1％至20％的如上定义的蛋白质，更优选0.1％至10％的如上定义的蛋白质，最优选0.1％至5％的如上定义的蛋白质；
-所述醇选自乙醇、丁醇、异丙醇和苯甲醇。更优选地，所述醇选自乙醇或苯甲醇；
-所述组合物含有0.5％至20％的如上定义的醇，更优选0.5％至10％的如上定义的醇，最优选0.5％至4％的如上定义的醇；
-所述植物油含有至少1％的亚麻酸或羧酸。更优选地，所述植物油选自甜杏仁油、大豆油、阿甘油、杜松油、巴巴苏油、西兰花油、鳄梨油、亚麻籽油、杏仁油、黄瓜油、黑种草子油、巴西坚果油、葡萄籽油、乳木果油、芝麻油和番茄油。最优选地，所述植物油选自大豆油或乳木果油；
-所述组合物含有0.1％至10％的如上定义的植物油，更优选0.1％至6％的如上定义的植物油，最优选0.1％至4％的如上定义的植物油；
-所述有机酸是一种二酸。优选地，有机酸是具有抗氧化特性的二酸。更优选地，所述有机酸选自甲酸、乙酸、磺酸、羧酸、水杨酸、乙酰水杨酸、抗坏血酸、抗坏血酸钠、过硫酸铵、过硫酸钠和过硫酸钾。更优选地，所述有机酸选自抗坏血酸、水杨酸和过硫酸铵。最优选地，所述有机酸被选择为抗坏血酸；
-该组合物包含至少两种有机酸。优选地，该组合物包含至少两种选自二酸的有机酸。
更优选地，该组合物包含至少两种选自具有抗氧化特性的二酸的有机酸。更优选地，该组合物包含至少两种选自以下的有机酸：甲酸、乙酸、磺酸、羧酸、水杨酸、乙酰水杨酸、抗坏血酸、抗坏血酸钠、过硫酸铵、过硫酸钠和过硫酸钾。更优选地，该组合物包含抗坏血酸和至少一种选自以下的有机酸：甲酸、乙酸、磺酸、羧酸、水杨酸、乙酰水杨酸、过硫酸铵、过硫酸钠和过硫酸钾。最优选地，该组合物包含抗坏血酸和至少一种选自水杨酸、乙酰水杨酸和过硫酸铵的有机酸。
-所述组合物含有1％至20％的如上定义的有机酸；更优选1.5％至15％的如上定义的有机酸；更优选3％至10％的如上定义的有机酸；和/或
-所述组合物进一步含有多元醇。
根据本发明的组合物可以是膏、凝胶、水包油或油包水乳液、头发洗剂或洗发剂的形式。优选地，根据本发明的组合物是膏或头发洗剂的形式。
根据本发明的组合物可以是单一组合物的形式或包括两种、三种或四种单独的组合物的套装的形式，所述单独的组合物各含有一种或多种根据本发明的组合物的成分。优选地，本发明还涉及一种可用于制备如上所定义的用于卷曲头发的组合物的套装，所述套装包括：
-一方面，含有如上定义的蛋白质和任选的如上定义的氨基酸、醇、植物油和/或有机酸的组合物；和
-另一方面，含有至少一种如上定义的有机酸和任选的如上定义的氨基酸、醇和/或植物油的组合物。
根据本发明的组合物，无论其是否为套装的形式，可以根据本领域技术人员已知的任何方法应用。
当用于卷曲头发时，根据本发明的组合物优选根据包括以下步骤的方法应用：
-将根据本发明的组合物直接涂敷至干燥或湿的头发；
-常规缠绕在传统卷曲器上；
-作用一段时间，所述一段时间可以5分钟到30分钟变化；
-在逐渐放卷(unwinding)的同时干燥整个头发；和
-用水漂洗头发。
根据本发明的方法还可以通过以下来补充：
-漂洗头发后涂敷洗发剂；和/或
-涂敷洗发后香膏或免洗处理剂。
根据本发明的方法可以容易地实施，并且使得可以在不使用卷曲熨斗或巯基化和/或氨化还原剂的情况下，以有效且持久的方式卷曲头发，从而保持头发的质量。
当用于卷曲睫毛时，根据本发明的组合物优选根据包括以下步骤的方法应用：
-用合适的产品清洗睫毛；
-在眼睑上施用睫毛“卷曲器”或“垫”型工具；
-施加合适的粘合剂，以将睫毛保持在工具上；
-将根据本发明的组合物涂敷至睫毛；
-作用一段时间，所述一段时间可以从5分钟到30分钟变化；
-用湿棉或洗剂漂洗睫毛；和
-取下工具。
根据本发明的方法可以容易地实施，并且使得可以在不使用过氧化氢或巯基化和/或氨化还原剂的情况下，以有效且持久的方式卷曲睫毛，从而保持睫毛的质量。
通过以下实施例以非限制性方式说明本发明。
实施例1-根据本发明的组合物
制备一种即用型膏，所述膏包含氨基酸、蛋白质、醇、植物油和两种有机酸，所述膏的组成报告在下表1中。
| 成分 | 量(％/w) |
| 精氨酸(氨基酸) | 1.00 |
| 半胱氨酸HCl(氨基酸) | 0.60 |
| 水解螺旋藻(蛋白质) | 2.00 |
| 苄醇(醇) | 0.30 |
| 乙醇(醇) | 1.50 |
| 大豆油(植物油) | 2.60 |
| 抗坏血酸(有机酸) | 3.00 |
| 水杨酸(有机酸) | 1.05 |
| 甘油 | 6.11 |
| 麦芽糖 | 3.5 |
| 乳木果油 | 2.60 |
| 鲸蜡硬脂醇 | 2.60 |
| 癸基葡糖苷 | 2.09 |
| 阿拉伯树胶 | 1.05 |
| 橄榄油酰谷氨酸钠 | 0.75 |
| 椰油酰谷氨酸二钠 | 0.75 |
| 黄原胶 | 0.40 |
| 香料 | 0.30 |
| 生育酚醋酸酯 | 0.30 |
| 生育酚 | 0.15 |
| 太阳花油 | 0.15 |
| 氯化钠 | 0.13 |
| 水 | 67.07 |
表1-根据本发明的卷发膏
实施例2-头发卷曲测试
2.1-卷曲方法
上面实施例1中所述的卷发膏用于卷曲脆弱的头发，这些头发因重复的巯基化烫发尝试而变弱(图1)。
根据本发明的组合物的应用根据以下方案进行。
步骤1：将洗发水直接涂敷至湿头发
将根据本发明的组合物涂敷至整个湿头发并用梳子分配。
步骤2：缠绕在卷曲器上
然后将这样处理的头发以常规的方式缠绕在传统的卷曲器上，然后将产品在玻璃纸中并在climazon带帽吹发器下放置20分钟。
步骤3：干燥和放卷
然后用吹风机在热空气中吹干头发。然后取下卷曲器。
步骤4：漂洗
然后使头发冷却并用水漂洗，然后如果需要，用洗发剂进行两次连续的洗发剂洗发。
步骤5：自然干燥
用吹风机在热空气中吹干头发，或者用刷定型。
2.2-所得结果
获得了柔软且易打理的头发，具有更浓密的外观、显著的体积增加和显著的卷曲，没有任何敏化的痕迹(图2)。观察到的这种卷曲的寿命是三个月(图3)。
实施例3-根据本发明的组合物
制备一种即用型膏，所述膏包含氨基酸、蛋白质、醇、植物油和有机酸，所述膏的组成报告在下表2中。
| 成分 | 量(％/w) |
| 精氨酸(氨基酸) | 1.00 |
| 半胱氨酸HCl(氨基酸) | 0.60 |
| 水解螺旋藻(蛋白质) | 2.00 |
| 苄醇(醇) | 0.30 |
| 乙醇(醇) | 1.50 |
| 大豆油(植物油) | 0.10 |
| 抗坏血酸(有机酸) | 3.00 |
| 甘油 | 6.10 |
| 麦芽糖 | 3.50 |
| 乳木果油 | 2.60 |
| 鲸蜡硬脂醇 | 2.60 |
| 癸基葡糖苷 | 2.09 |
| 木瓜蛋白酶 | 0.9 |
| 橄榄油酰谷氨酸钠 | 0.75 |
| 椰油酰谷氨酸二钠 | 0.75 |
| 黄原胶 | 0.40 |
| 香料 | 0.30 |
| 生育酚醋酸酯 | 0.30 |
| 生育酚 | 0.15 |
| 太阳花油 | 0.15 |
| 氯化钠 | 0.13 |
| 水 | 70.78 |
表2-根据本发明的卷发膏
实施例4-头发卷曲测试
4.1-卷曲方法
上面实施例3中所述的卷发膏用于卷曲非常直且厚的头发，这种头发通常很难卷曲且不定型(图4)。
根据本发明的组合物的应用根据以下方案进行。
步骤1：涂覆中性洗发剂来清洗头发。
将根据本发明的组合物涂敷至整个湿头发并用梳子分配。
步骤2：缠绕在卷曲器上
然后将这样处理的头发以常规的方式缠绕在传统的卷曲器上，然后将产品在玻璃纸中并在climazon带帽吹发器下放置20分钟。
步骤3：干燥和放卷
然后用吹风机在热空气中吹干头发。然后取下卷曲器。
步骤4：漂洗
然后使头发冷却并用水漂洗，然后如果需要，进行洗发剂洗发。
步骤5：自然干燥
使头发自然风干。
4.2-所得结果
获得了漂亮的有弹性的卷曲、有光泽的、柔软的且强韧的头发，没有任何脱水的迹象(图5)。观察到的这种卷曲的寿命是三个月(图6)。
实施例5-对比头发卷曲测试
5.1-测试的组合物
制备即用型膏，其包含氨基酸、蛋白质、醇和植物油但含有少于1％的有机酸。其组成报告在下表3中。
该组合物对应于申请WO-A-2019/012219中描述的拉直组合物。
表3–根据WO-A-2019/012219的拉直组合物
5.2-卷曲方法
上面实施例中描述的膏用于检查是否可以卷曲直发(图7)。
根据本发明的拉直组合物的应用根据以下方案进行。
步骤1：将洗发水直接涂敷至湿头发
将根据本发明的组合物涂敷至整个湿头发并用梳子分配。
步骤2：缠绕在卷曲器上
然后将这样处理的头发以常规的方式缠绕在传统的卷曲器上(图8)，然后将产品在玻璃纸中并在climazon带帽空气干燥器下放置20分钟。
步骤3：干燥和放卷
然后用吹风机在热空气中吹干头发。然后取下卷曲器。
步骤4：漂洗
然后使头发冷却并用水漂洗，然后如果需要，用洗发剂进行两次连续的洗发剂洗发。
步骤5：自然干燥
使头发在室温下自然风干。
5.3-所得结果
获得了具有更浓密外观和更柔软纤维的头发。然而，没有观察到卷曲(图9)。
因此，在申请WO-A-20219/012219中描述的直发组合物不能使涂覆它的头发卷曲。
实施例6-睫毛卷曲测试
6.1-卷曲方法
上面实施例1中所述的卷发膏用于卷曲硬且直的睫毛(图10)。
根据本发明的组合物的应用根据以下方案进行。
步骤1：清洗睫毛
用合适的乳液清洗睫毛，然后将卷曲器或粘合垫放在上眼睑上。
步骤2：卷曲睫毛
使用刷子或混合擦笔(blending stump)将根据本发明的组合物涂敷到睫毛边缘，然后将产品在玻璃纸中放置5至30分钟。
步骤3：漂洗
用湿棉漂洗产品，然后剥去垫或卷曲器。
6.2-所得结果
获得弯曲的睫毛边缘，具有更浓密的外观，没有任何敏化的痕迹(图11)。观察到这种卷曲的寿命为四周。
Claims (15)
1.用于卷曲头发或卷曲睫毛的组合物，其包含：
-氨基酸；
-蛋白质；
-醇；
-植物油；和
-至少1％(w/w)的至少一种有机酸或其有机或无机盐。
2.根据权利要求1所述的组合物，其特征在于所述氨基酸选自赖氨酸、牛磺酸或蛋白氨基酸或其酸性或碱性有机或无机盐。
3.根据权利要求2所述的组合物，其特征在于所述氨基酸是选自以下的蛋白氨基酸或其酸性或碱性有机或无机盐：天冬氨酸、谷氨酸、天冬酰胺、肉毒碱、半胱氨酸、谷氨酰胺、组氨酸、亮氨酸、异亮氨酸、甲硫氨酸、N-苯丙氨酸、脯氨酸、羟脯氨酸、苏氨酸、色氨酸、酪氨酸、缬氨酸、甘氨酸、丙氨酸、丝氨酸、β-丙氨酸和精氨酸或其酸性或碱性有机或无机盐。
4.根据权利要求1至3中任一项所述的组合物，其特征在于所述蛋白质选自任选地水解的肌酸、任选地水解的小麦蛋白、任选地水解的丝蛋白、任选地水解的螺旋藻蛋白、任选地水解的植物角蛋白、任选地水解的大豆蛋白、任选地水解的胶原蛋白、任选地水解的弹性蛋白、任选地水解的豌豆蛋白、任选地水解的大米蛋白、任选地水解的贝壳硬蛋白和任选地水解的乳清蛋白。
5.根据权利要求4所述的组合物，其特征在于所述蛋白质选自肌酸、任选地水解的螺旋藻蛋白、任选地水解的小麦蛋白、任选地水解的丝蛋白和任选地水解的大豆蛋白。
6.根据权利要求1至5中任一项所述的组合物，其特征在于所述醇选自乙醇、丁醇、异丙醇和苯甲醇。
7.根据权利要求1至6任一项所述的组合物，其特征在于所述植物油选自甜杏仁油、大豆油、阿甘油、杜松油、巴巴苏油、西兰花油、鳄梨油、亚麻籽油、杏仁油、黄瓜油、黑种草子油、巴西坚果油、葡萄籽油、乳木果油、芝麻油和番茄油。
8.根据权利要求7所述的组合物，其特征在于所述植物油选为大豆油或乳木果油。
9.根据权利要求1至8中任一项所述的组合物，其特征在于所述有机酸为二酸。
10.根据权利要求9所述的组合物，其特征在于所述有机酸为具有抗氧化特性的二酸。
11.根据权利要求10所述的组合物，其特征在于所述有机酸选自甲酸、乙酸、磺酸、羧酸、水杨酸、乙酰水杨酸、抗坏血酸、抗坏血酸钠、过硫酸铵、过硫酸钠和过硫酸钾。
12.根据权利要求1至11中任一项所述的组合物，其特征在于其包含至少两种有机酸。
13.根据权利要求12所述的组合物，其特征在于其包含抗坏血酸和至少一种选自以下的有机酸：甲酸、乙酸、磺酸、羧酸、水杨酸、乙酰水杨酸、过硫酸铵、过硫酸钠和过硫酸钾。
14.一种用于卷曲头发的方法，其包含以下步骤：
-将根据权利要求1至13中任一项所述的组合物直接涂敷至干燥或湿的头发；
-常规缠绕在传统卷曲器上；
-作用一段时间，所述一段时间可以从5分钟到30分钟变化；
-在逐渐放卷的同时干燥整个头发；和
-用水漂洗头发。
15.一种用于卷曲睫毛的方法，其包含以下步骤：
-用合适的产品清洗睫毛；
-在眼睑上施用睫毛“卷曲器”或“垫”型工具；
-涂敷合适的粘合剂，以将睫毛保持在工具上；
-将根据本发明的组合物涂敷至睫毛；
-作用一段时间，所述一段时间可以从5分钟到30分钟变化；-用湿棉或洗剂漂洗睫毛；和
-取下工具。
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|---|---|---|---|
| FRFR20/14069 | 2020-12-23 | ||
| FR2014069A FR3117821B1 (fr) | 2020-12-23 | 2020-12-23 | Nouvelle composition pour boucler les cheveux |
| PCT/FR2021/052433 WO2022136803A1 (fr) | 2020-12-23 | 2021-12-22 | Nouvelle composition pour boucler les cheveux ou recourber les cils |
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| CN116685234A true CN116685234A (zh) | 2023-09-01 |
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| EP (1) | EP4267092A1 (zh) |
| JP (1) | JP2024501493A (zh) |
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| CN (1) | CN116685234A (zh) |
| CA (1) | CA3200423A1 (zh) |
| FR (1) | FR3117821B1 (zh) |
| WO (1) | WO2022136803A1 (zh) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2006040445A1 (fr) * | 2004-10-07 | 2006-04-20 | L'oreal | Procédé de traitement cosmétique des fibres kératiniques, et utilisation cosmétique d'un modulateur de transglutaminase. |
| CN101390600B (zh) * | 2008-11-05 | 2012-06-27 | 天津市双星香精香料有限公司 | 一种海鲜风味香精的制备方法 |
| FR3060991B1 (fr) * | 2016-12-22 | 2019-05-31 | L'oreal | Procede de detente de boucles et/ou de lissage des fibres keratiniques, mettant en œuvre des agents reducteurs et des solvants organiques polaires, et kit de lissage |
| US11497707B2 (en) * | 2017-07-11 | 2022-11-15 | Di Visco | Composition for straightening hair |
| RU2677275C1 (ru) * | 2018-01-17 | 2019-01-16 | Талагаева Елена Владимировна | Маски и бальзам для волос (варианты) |
| FR3096896A1 (fr) * | 2019-06-07 | 2020-12-11 | Di Visco | Nouvelle composition pour la coloration des cheveux |
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- 2021-12-22 WO PCT/FR2021/052433 patent/WO2022136803A1/fr active Application Filing
- 2021-12-22 EP EP21848014.3A patent/EP4267092A1/fr active Pending
- 2021-12-22 JP JP2023536516A patent/JP2024501493A/ja active Pending
- 2021-12-22 CN CN202180087336.4A patent/CN116685234A/zh active Pending
- 2021-12-22 CA CA3200423A patent/CA3200423A1/fr active Pending
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| KR20230130665A (ko) | 2023-09-12 |
| WO2022136803A1 (fr) | 2022-06-30 |
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| JP2024501493A (ja) | 2024-01-12 |
| US20240050346A1 (en) | 2024-02-15 |
| FR3117821A1 (fr) | 2022-06-24 |
| CA3200423A1 (fr) | 2022-06-30 |
| EP4267092A1 (fr) | 2023-11-01 |
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