CN116606167A - Amazon texture pattern-penetrated brick and preparation method thereof - Google Patents
Amazon texture pattern-penetrated brick and preparation method thereof Download PDFInfo
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- 239000011449 brick Substances 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title abstract description 5
- 238000007639 printing Methods 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims description 95
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 60
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 33
- 229910052802 copper Inorganic materials 0.000 claims description 33
- 239000010949 copper Substances 0.000 claims description 33
- 229910052759 nickel Inorganic materials 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000000919 ceramic Substances 0.000 claims description 27
- 238000001035 drying Methods 0.000 claims description 24
- 239000004575 stone Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 21
- 229910017052 cobalt Inorganic materials 0.000 claims description 20
- 239000010941 cobalt Substances 0.000 claims description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000007650 screen-printing Methods 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 238000004040 coloring Methods 0.000 claims description 11
- 238000003825 pressing Methods 0.000 claims description 11
- 238000010304 firing Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005498 polishing Methods 0.000 claims description 7
- 150000001868 cobalt Chemical class 0.000 claims description 6
- 150000001879 copper Chemical class 0.000 claims description 6
- 150000002815 nickel Chemical class 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 238000007688 edging Methods 0.000 claims description 5
- 230000000149 penetrating effect Effects 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 21
- 238000001764 infiltration Methods 0.000 abstract description 11
- 230000008595 infiltration Effects 0.000 abstract description 11
- 238000010586 diagram Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000003837 high-temperature calcination Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910001429 cobalt ion Inorganic materials 0.000 description 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical compound [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/606—Drying
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The application discloses an amazon texture mosaic tile and a preparation method thereof, and relates to the technical field of tiles. The amazon texture pattern infiltration brick consists of a blank body and amazon texture patterns infiltrated into the blank body, wherein the amazon texture patterns are prepared by printing a preset pattern screen, and the preset pattern screen is divided into a first pattern screen, a second pattern screen and a third pattern screen according to the pattern size sequence to jointly form the amazon texture patterns. According to the application, the Amazon texture pattern is divided into a first pattern net, a second pattern net and a third pattern net according to the sequence of the sizes of the patterns to serve as a preset pattern screen plate, so that the Amazon texture pattern-penetrated brick is prepared. Therefore, the texture layering sense and the texture effect of the Amazon texture patterns on the Amazon texture mosaic tile are effectively guaranteed, and the color effect of the mosaic tile is enriched.
Description
Technical Field
The application relates to the technical field of ceramic tiles, in particular to an amazon texture mosaic tile and a preparation method thereof.
Background
With the continuous development of ceramic technology, the consumption level and the aesthetic level of people are continuously improved, and the requirements of people on the decoration effect of ceramic tiles are also continuously improved.
The glazed tile is one kind of building material product produced through the steps of impregnating glaze material into green body, high temperature calcination, polishing and grinding. The polished tile is popular because the polished tile has the advantages of wear resistance and durability, and has the advantage of rich color of the polished tile. Although the current tile infiltration production technology is very mature, the tile infiltration pattern on the current market is relatively single.
Disclosure of Invention
The application mainly aims to provide an amazon texture mosaic tile, and aims to solve the technical problem that the mosaic tile has single pattern.
In order to achieve the above object, in a first aspect, the present application provides an amazon texture infiltration tile, where the amazon texture infiltration tile is composed of a blank and an amazon texture pattern infiltrated into the blank, and the amazon texture pattern is made by printing a preset pattern screen, where the preset pattern screen is divided into a first pattern screen, a second pattern screen and a third pattern screen according to a pattern size sequence, and the amazon texture pattern is formed together.
In the first aspect, the element mass ratio of the first pigment of the first patterned mesh is nickel: 12-16, copper: 2-8, cobalt: 1-3.
According to the first aspect, or any implementation manner of the first aspect, the element mass ratio of the second pigment of the second patterned network is copper: 12-16, nickel: 3-7, cobalt: 0.5-2.
According to the first aspect, or any implementation manner of the first aspect, the element mass ratio of the third pigment of the third patterned mesh is copper: 12-17, nickel: 0-2.
In a second aspect, the present application provides a method for preparing an amazon texture mosaic tile, applied to an amazon texture mosaic tile as described above, the method comprising:
preparing ceramic powder, and respectively preparing the pattern-penetrating glaze corresponding to a first pattern screen, a second pattern screen and a third pattern screen in the preset pattern screen according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen;
pressing ceramic powder into a green body and drying;
sequentially carrying out screen printing on the surface of the green body by adopting the pattern-penetrating glaze to obtain Amazon texture patterns;
and (3) kiln firing is carried out on the printed green body, firing is carried out, polishing and edging are carried out, and the amazon texture mosaic tile is obtained.
According to a second aspect, the steps of preparing the pattern-penetrating glaze corresponding to the first pattern mesh, the second pattern mesh and the third pattern mesh in the preset pattern mesh according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern mesh respectively include:
respectively weighing corresponding soluble nickel salt, soluble copper salt and soluble cobalt salt according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen to obtain corresponding first pigment, second pigment and third pigment;
and respectively adding a solvent and a thickening agent into the first pigment, the second pigment and the third pigment, and uniformly stirring to obtain the pattern-penetrating glaze corresponding to the first pattern net, the second pattern net and the third pattern net in the preset pattern screen.
According to a second aspect, or any implementation manner of the second aspect, the element mass ratio of the first pigment is nickel: 12-16, copper: 2-8, cobalt: 1-3; the mass ratio of the elements of the second pigment is copper: 12-16, nickel: 3-7, cobalt: 0.5-2; the element mass ratio of the third pigment is copper: 12-17, nickel: 0-2.
According to a second aspect, or any implementation manner of the second aspect, before the steps of preparing the pattern-penetrating glaze corresponding to the first pattern mesh, the second pattern mesh and the third pattern mesh in the preset pattern mesh according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern mesh respectively, the method includes:
selecting natural stone with Amazon texture patterns, and scanning the natural stone to obtain Amazon texture scanning patterns;
and carrying out color separation on the Amazon texture scanning image, and respectively manufacturing a first pattern net, a second pattern net and a third pattern net according to the sequence of the patterns to serve as a preset pattern screen.
According to a second aspect, or any implementation manner of the second aspect, the step of drying after pressing the ceramic powder into a green body includes:
and heating and drying the green body to reduce the water content of the green body to 1.04-1.09%, wherein the heating temperature of the drying is 200-250 ℃.
According to a second aspect, or any implementation manner of the second aspect, after the step of pressing the ceramic powder into a green body and drying, the method includes:
and cooling the dried green body to reduce the temperature of the green body to 59-63 ℃.
The amazon texture pattern-penetrating brick provided by the application consists of a blank body and amazon texture patterns penetrating into the blank body, wherein the amazon texture patterns are prepared by printing a preset pattern screen, and the preset pattern screen is divided into a first pattern screen, a second pattern screen and a third pattern screen according to the pattern size sequence to jointly form the amazon texture patterns. According to the application, the Amazon texture pattern is divided into a first pattern net, a second pattern net and a third pattern net according to the sequence of the sizes of the patterns to serve as a preset pattern screen plate, so that the Amazon texture pattern-penetrated brick is prepared. Therefore, the texture layering sense and the texture effect of the Amazon texture patterns on the Amazon texture mosaic tile are effectively guaranteed, and the color effect of the mosaic tile is enriched.
Drawings
FIG. 1 is a schematic representation of Amazon texture in accordance with the present application;
FIG. 2 is a schematic flow chart of an embodiment of a method for preparing an amazon texture mosaic according to the present application;
FIG. 3 is an effect diagram of out-of-order printing involved in an embodiment of the present application;
fig. 4 is an effect diagram of sequential printing involved in an embodiment of the present application.
The achievement of the objects, functional features and advantages of the present application will be further described with reference to the accompanying drawings, in conjunction with the embodiments. The drawings and the written description are not intended to limit the scope of the inventive concepts in any way, but rather to illustrate the inventive concepts to those skilled in the art by reference to the specific embodiments.
Detailed Description
It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the application.
The following description of the embodiments of the present application will be made clearly and fully with reference to the accompanying drawings, in which it is evident that the embodiments described are some, but not all embodiments of the application. All other embodiments, which can be made by those skilled in the art based on the embodiments of the application without making any inventive effort, are intended to be within the scope of the application.
It should be understood that the experimental methods used in the following examples of the present application are conventional methods unless otherwise specified. Materials, reagents and the like used in the following examples of the present application are commercially available unless otherwise specified.
With the continuous development of ceramic technology, the consumption level and the aesthetic level of people are continuously improved, and the requirements of people on the decoration effect of ceramic tiles are also continuously improved.
The glazed tile is one kind of building material product produced through the steps of impregnating glaze material into green body, high temperature calcination, polishing and grinding. The polished tile is popular because the polished tile has the advantages of wear resistance and durability, and has the advantage of rich color of the polished tile. Although the current tile infiltration production technology is very mature, the tile infiltration pattern on the current market is relatively single. The color-matching tile with the hierarchical texture and color matching effect for the natural stone with amazon texture is still blank in the market.
Referring to fig. 1, fig. 1 is a schematic diagram of amazon texture according to the present application. Fig. 1 is a picture of amazon green stone. The Amazon texture is derived from Brazil precious stone, amazon green, and has crisscross surface color green, white and brown, and tropical rainforest-like color and texture.
In order to make up market blank, the embodiment of the application provides an amazon texture infiltration tile, which consists of a blank body and amazon texture patterns infiltrated into the blank body, wherein the amazon texture patterns are prepared by printing preset pattern screens, and the preset pattern screens are divided into a first pattern screen, a second pattern screen and a third pattern screen according to the pattern size sequence to jointly form the amazon texture patterns. According to the application, the Amazon texture pattern is divided into a first pattern net, a second pattern net and a third pattern net according to the sequence of the sizes of the patterns to serve as a preset pattern screen plate, so that the Amazon texture pattern-penetrated brick is prepared. Therefore, the texture layering sense and the texture effect of the Amazon texture patterns on the Amazon texture mosaic tile are effectively guaranteed, and the color effect of the mosaic tile is enriched.
In addition, the element mass ratio (i.e. the ratio of the mass of each element) of the first pigment of the first patterned mesh is nickel: 12-16, copper: 2-8, copper: 1-3. The mass ratio of the elements of the second pigment of the second pattern net is copper: 12-16, nickel: 3-7, cobalt: 0.5-2. The element mass ratio of the third pigment of the third pattern net is copper: 12-17, nickel: 0-2. The nickel, copper and cobalt are present in the form of inorganic salts, and the element mass ratio of the coloring material is the weight ratio of the copper, nickel and cobalt elements. According to the embodiment of the application, the Amazon texture pattern is divided into three pattern meshes according to the sequence of the sizes of the patterns for printing, and each pattern mesh adopts different element mass ratios of pigments to realize different color effects. The amazon texture mosaic tile prepared by the embodiment of the application not only can be more attached to the texture of the natural stone with the real amazon texture on the texture layering sense and the texture effect of the amazon texture pattern, but also can be more natural and real in color collocation.
Referring to fig. 2, fig. 2 is a schematic flow chart of an embodiment of a method for preparing an amazon texture mosaic tile according to the present application. It should be noted that although a logical order is depicted in the flowchart, in some cases the steps depicted or described may be performed in a different order than presented herein.
The embodiment of the application provides a preparation method of an amazon texture mosaic tile, which is applied to the amazon texture mosaic tile, and comprises the following steps:
step S100, preparing ceramic powder, and respectively preparing a pattern penetrating glaze corresponding to a first pattern screen, a second pattern screen and a third pattern screen in a preset pattern screen according to the element mass ratio of a first pigment, the element mass ratio of a second pigment and the element mass ratio of a third pigment of the preset pattern screen;
step S200, pressing ceramic powder into a green body and drying;
step S300, sequentially carrying out screen printing on the surface of the green body by adopting the pattern-penetrating glaze to obtain Amazon texture patterns;
and step S400, kiln firing is carried out on the printed green body, firing is carried out, polishing and edging are carried out, and the amazon texture mosaic tile is obtained.
The ceramic powder in the embodiment is powder for preparing a green body of the conventional mosaic ceramic tile, which is prepared according to the proportion of the conventional mosaic ceramic tile. The granular ceramic powder is prepared from raw materials such as kaolin, feldspar, quartz, wollastonite and the like through proportioning, ball milling pulping, spray drying granulation, and the chemical composition range of the granular ceramic powder is as follows (parts by weight): siO (SiO) 2 ：64-74%， Al 2 O 3 ：16-24%，MgO+CaO：0.5-5%，K 2 O+Na 2 O:4-8%, and the balance being impurities.
As the pattern-penetrating glaze is equivalent to printing ink in the common screen printing process, in order to ensure the layering and effect of the printed Amazon textures, the first pattern net, the second pattern net and the third pattern net are sequentially printed according to the sequence of the sizes of the patterns. Therefore, the corresponding element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment are designed according to different color collocations of the first pattern net, the second pattern net and the third pattern net in the preset pattern screen. According to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen, the pattern penetrating glaze corresponding to the first pattern screen, the second pattern screen and the third pattern screen in the preset pattern screen is prepared respectively and is used for printing patterns on the first pattern screen, the second pattern screen and the third pattern screen in the preset pattern screen.
After the ceramic powder is prepared, the ceramic powder may be pressed into a green body and then dried. As an example, after pressing the ceramic powder to obtain a green body, the green body is subjected to temperature-raising drying to reduce the water content of the green body to 1.04-1.09%, wherein the heating temperature of the drying is 200-250 ℃. Illustratively, the weight of the infiltrant is typically 25 kg/square meter, and the moisture content of the green body is reduced to 65-68 grams after the green body is temperature-dried, taking as an example 500mm x 500mm specification infiltrant.
And sequentially carrying out screen printing on the surface of the green body by adopting the pattern penetrating glaze to sequentially carry out screen printing on a first pattern net, a second pattern net and a third pattern net in a preset pattern screen plate to obtain the green body with Amazon texture patterns. And then kiln firing is carried out on the green body with the Amazon texture pattern after printing, and the Amazon texture pattern-penetrated tiles are obtained after polishing and edging. Referring to fig. 3 and 4, fig. 3 is a schematic diagram of out-of-order printing according to an embodiment of the present application, and fig. 4 is a schematic diagram of in-order printing according to an embodiment of the present application. Fig. 3 shows the textures printed in a disordered order, and fig. 3 shows the textures printed in a pattern order from small to large. It is apparent that the texture printed in the out-of-order of fig. 3 is less sharp and the layers between textures are not apparent. The textures printed in the order of the patterns from small to large in fig. 4 are more clear and more distinct than the textures in fig. 3 because the mutual masking between the patterns is avoided.
In step S100, the steps of preparing the pattern-penetrating glaze corresponding to the first pattern mesh, the second pattern mesh and the third pattern mesh in the preset pattern mesh according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment in the preset pattern mesh respectively include:
step S110, respectively weighing corresponding soluble nickel salt, soluble copper salt and soluble cobalt salt according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen to obtain corresponding first pigment, second pigment and third pigment;
and step S120, respectively adding a solvent and a thickening agent into the first pigment, the second pigment and the third pigment, and uniformly stirring to prepare the pattern-penetrating glaze corresponding to the first pattern net, the second pattern net and the third pattern net in the preset pattern screen.
In this embodiment, the solvent is water or a mixed solution of water and ethanol. The thickening agent is a reagent for adjusting the pattern-penetrating glaze, such as ethylene diamine tetraacetic acid, sodium citrate, an ammonium complexing agent, sodium tripolyphosphate, sodium carboxymethyl cellulose and other thickening agents.
And then respectively weighing the corresponding soluble nickel salt, soluble copper salt and soluble cobalt salt according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen to obtain the corresponding first pigment, the second pigment and the third pigment. Wherein the soluble nickel salt, soluble copper salt and soluble cobalt salt can be inorganic salts such as chloride salt, nitrate salt and the like. And then adding solvents into the first pigment, the second pigment and the third pigment respectively to dissolve the pigments, and then stirring the mixture with a thickening agent uniformly to prepare the pattern-penetrating glaze corresponding to the first pattern net, the second pattern net and the third pattern net in the preset pattern screen. Wherein, the element mass ratio of the first pigment is nickel: 12-16, copper: 2-8, cobalt: 1-3; the mass ratio of the elements of the second pigment is copper: 12-16, nickel: 3-7, cobalt: 0.5-2; the element mass ratio of the third pigment is copper: 12-17, nickel: 0-2. The nickel, copper and copper are present in the form of a soluble nickel salt, a soluble copper salt and a soluble cobalt salt, and the pigment has an elemental mass ratio of copper, nickel and cobalt.
According to the embodiment, three patterns with different sizes are used for three different pigments, so that the color collocation of the Amazon texture patterns on the prepared Amazon texture mosaic tile is ensured to be more natural, and the color collocation of the Amazon texture patterns is more matched with the color displayed by the Amazon texture of the natural stone.
Before the step of preparing the pattern-penetrating glaze corresponding to the first pattern mesh, the second pattern mesh and the third pattern mesh in the preset pattern mesh according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment in the preset pattern mesh in the step S100, the method comprises the following steps:
step A10, selecting a natural stone with Amazon texture patterns, and scanning the natural stone to obtain Amazon texture scanning patterns;
and step A20, carrying out color separation on the Amazon texture scanning image, and respectively manufacturing a first pattern net, a second pattern net and a third pattern net according to the sequence of the pattern sizes to serve as a preset pattern screen.
In order to make the Amazon texture pattern of the Amazon texture infiltration tiles more natural in the embodiments of the present application. A piece of natural stone with Amazon texture patterns can be selected, and the stone which can show the color texture effect on the oozed tile is selected by evaluating the color and texture level of the surface of the natural stone. And then carrying out fine scanning on the natural stone so that the obtained Amazon texture scanning image can keep the fine layering sense of Amazon textures on the natural stone. And then the color separation is carried out, and a first pattern net, a second pattern net and a third pattern net are respectively manufactured according to the sequence of the sizes of the patterns to be used as a preset pattern screen. The first pattern net, the second pattern net and the third pattern net can be manufactured according to the sequence from big to small of the patterns on the Amazon texture scanning pattern as a preset pattern screen. Or the first pattern net, the second pattern net and the third pattern net can be manufactured according to the sequence from small to large of the patterns on the Amazon texture scanning pattern as a preset pattern screen.
The preset pattern screen plate obtained by the embodiment can more clearly, accurately and finely reserve layering sense of Amazon textures on the natural stone. Therefore, the texture layering sense of the Amazon texture pattern on the prepared Amazon texture infiltration tile can be further ensured through the preset pattern screen.
Wherein, the step S300 is a step of drying after pressing the ceramic powder into a green body, and comprises the following steps:
and heating and drying the green body to reduce the water content of the green body to 1.04-1.09%, wherein the heating temperature of the drying is 200-250 ℃.
In this example, it will be appreciated that subsequent screen printing will be affected by the moisture content of the green body. The water content of the green body mainly refers to the water content when the green body enters the screen printing process through the drying process, and the influence of the water content on the screen printing process is large. When the water content of the green body is too low, the pattern-penetrated glaze is quickly absorbed by the green body when passing through mesh openings of a silk screen, and the pattern-penetrated glaze is easy to gather and dry, so that the mesh openings are blocked, and the printing is difficult. When the water content is too high, the absorption speed of the green body to the pattern-penetrating glaze is low, if the distance between the green body and the silk screen is small at this time, after the scraping plate scrapes, the silk screen can not leave the surface of the green body before the pattern-penetrating glaze is adhered to the mesh, namely the pattern-penetrating glaze is easy to adhere to the silk screen, and the mesh is blocked. Thus, in this example, the green body was dried by heating to reduce the water content of the green body to 1.04 to 1.09%. Wherein the heating temperature of the drying is 200-250 ℃, and the drying of the green body can be realized faster while avoiding the need to spend more time cooling the dried green body.
Wherein, after the step of pressing the ceramic powder into a green body and then drying in step S300, it includes:
and cooling the dried green body to reduce the temperature of the green body to 59-63 ℃.
In this embodiment, it should be understood that if the temperature of the green body is too high (e.g. higher than 70 ℃), the moisture in the pattern-penetrating glaze will quickly evaporate after encountering the high Wen Piti in the printing process, so that the viscosity of the pattern-penetrating glaze becomes large, and the thick pattern-penetrating glaze easily blocks the mesh of the silk screen, which makes printing difficult. And coloring ions (such as copper ions, nickel ions, cobalt ions and the like) entering the green body can migrate along with the evaporation of moisture in the oozing glaze, and a large amount of coloring ions are concentrated on the surface of the green body from the inside of the green body, so that oozing is not deep and the pattern is blurred. However, if the temperature of the green body is too low (below 30 ℃), capillary holes in the green body shrink, the resistance of the infiltrated glaze to the green body correspondingly increases, coloring ions are difficult to enter the green body, so that the infiltrated glaze is spread transversely on the surface of the green body, the product pattern is blurred, and the color is light. Therefore, in this embodiment, the temperature of the dried green body is reduced to 59-63 ℃. Thereby effectively improving the printing quality of the amazon texture mosaic tile.
In the embodiment, the pattern-penetrating glaze corresponding to the first pattern mesh, the second pattern mesh and the third pattern mesh in the preset pattern mesh is prepared by preparing ceramic powder according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern mesh; pressing ceramic powder into a green body and drying; sequentially carrying out screen printing on the surface of the green body by adopting the pattern-penetrating glaze to obtain Amazon texture patterns; and (3) kiln firing is carried out on the printed green body, firing is carried out, polishing and edging are carried out, and the amazon texture mosaic tile is obtained. According to the embodiment of the application, the Amazon texture pattern is divided into three pattern meshes according to the sequence of the sizes of the patterns for printing, so that the texture layering sense and the texture effect of the Amazon texture pattern on the prepared Amazon texture infiltration tile are ensured. And each pattern net adopts different element mass ratios of the pigment to realize different color effects. The amazon texture mosaic tile prepared by the embodiment of the application not only can be more attached to the texture of the natural stone with the real amazon texture on the texture layering sense and the texture effect of the amazon texture pattern, but also can be more natural and real in color collocation.
Example 1
In example 1, a first pattern net, a second pattern net and a third pattern net were produced as a preset pattern screen in the order of small patterns on the amazon texture scan pattern of the natural stone material. The element mass ratio of the first pigment is nickel: 15, copper: 5, cobalt: 3, a step of; the mass ratio of the elements of the second pigment is copper: 15, nickel: 4, cobalt: 0.5; the element mass ratio of the third pigment is copper: 15, nickel: 2. temperature of green body at the time of entering screen printing process: the green body had a moisture content of 66 grams (500 mm x 500mm for the amazon texture tile size specification) at 62 ℃. The heating temperature in the drying step was 220 ℃.
The amazon texture mosaic tile prepared by the method has good imitation effect on amazon texture of natural stone, and is natural in color matching and more matched with the natural stone.
Example 2
In example 2, a first pattern net, a second pattern net and a third pattern net were produced as a preset pattern screen in the order of small patterns on the amazon texture scan pattern of the natural stone material. The element mass ratio of the first pigment is nickel: 12, copper: 8, cobalt: 1, a step of; the mass ratio of the elements of the second pigment is copper: 16, nickel: 3, cobalt: 2; the element mass ratio of the third pigment is copper: 17, nickel: 1. temperature of green body at the time of entering screen printing process: 60 ℃, 61 grams of water content of the green body (the dimension specification of the amazon texture tile is 500mm x 500 mm). The heating temperature in the drying step was 220 ℃.
The amazon texture mosaic tile prepared by the method has good imitation effect on amazon texture of natural stone and good color matching, but is slightly less natural than that of example 1.
Example 3
In example 3, a first pattern net, a second pattern net and a third pattern net were produced as a preset pattern screen in the order of small patterns on the amazon texture scan pattern of the natural stone material. The element mass ratio of the first pigment is nickel: 16, copper: 2, cobalt: 3, a step of; the mass ratio of the elements of the second pigment is copper: 12, nickel: 7, cobalt: 1, a step of; the element mass ratio of the third pigment is copper: 12, nickel: 0. temperature of green body at the time of entering screen printing process: 61 ℃, water content of the green body 63 grams (the dimension specification of the amazon texture tile is 500mm x 500 mm). The heating temperature in the drying step was 220 ℃.
The amazon texture mosaic tile prepared by the method has good imitation effect on amazon texture of natural stone, and good color matching, but is slightly inferior to the embodiments 1 and 2.
It should be noted that, in this document, relational terms such as first and second, and the like are used solely to distinguish one entity/operation/object from another entity/operation/object without necessarily requiring or implying any actual such relationship or order between such entities/operations/objects; the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or system that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or system. Without further limitation, an element defined by the phrase "comprising one … …" does not exclude the presence of other like elements in a process, method, article, or system that comprises the element.
The foregoing embodiment numbers of the present application are merely for the purpose of description, and do not represent the advantages or disadvantages of the embodiments.
The foregoing description is only of the preferred embodiments of the present application, and is not intended to limit the scope of the application, but rather is intended to cover any equivalents of the structures or equivalent processes disclosed herein or in the alternative, which may be employed directly or indirectly in other related arts.
Claims (10)
1. The amazon texture pattern-penetrating brick is characterized by comprising a blank body and amazon texture patterns penetrating into the blank body, wherein the amazon texture patterns are prepared by printing a preset pattern screen, and the preset pattern screen is divided into a first pattern screen, a second pattern screen and a third pattern screen according to the pattern size sequence to jointly form the amazon texture patterns.
2. The amazon texture mosaic tile of claim 1, wherein the first colorant of the first patterned network comprises the following elements in mass ratio: 12-16, copper: 2-8, cobalt: 1-3.
3. The amazon texture mosaic tile according to claim 2, wherein the second pigment of the second road network has an elemental mass ratio of copper: 12-16, nickel: 3-7, cobalt: 0.5-2.
4. The amazon texture mosaic tile according to claim 3, wherein the element mass ratio of the third coloring material of the third patterned network is copper: 12-17, nickel: 0-2.
5. A method for preparing an amazon texture mosaic tile, applied to an amazon texture mosaic tile according to any one of claims 1 to 4, comprising:
preparing ceramic powder, and respectively preparing the pattern-penetrating glaze corresponding to a first pattern screen, a second pattern screen and a third pattern screen in the preset pattern screen according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen;
pressing ceramic powder into a green body and drying;
sequentially carrying out screen printing on the surface of the green body by adopting the pattern-penetrating glaze to obtain Amazon texture patterns;
and (3) kiln firing is carried out on the printed green body, firing is carried out, polishing and edging are carried out, and the amazon texture mosaic tile is obtained.
6. The method according to claim 5, wherein the step of preparing the pattern-bleeding glaze corresponding to the first pattern mesh, the second pattern mesh, and the third pattern mesh in the preset pattern mesh according to the element mass ratio of the first coloring material, the element mass ratio of the second coloring material, and the element mass ratio of the third coloring material of the preset pattern mesh, respectively, comprises:
respectively weighing corresponding soluble nickel salt, soluble copper salt and soluble cobalt salt according to the element mass ratio of the first pigment, the element mass ratio of the second pigment and the element mass ratio of the third pigment of the preset pattern screen to obtain corresponding first pigment, second pigment and third pigment;
and respectively adding a solvent and a thickening agent into the first pigment, the second pigment and the third pigment, and uniformly stirring to obtain the pattern-penetrating glaze corresponding to the first pattern net, the second pattern net and the third pattern net in the preset pattern screen.
7. The method of claim 6, wherein the first colorant comprises nickel in an elemental mass ratio of: 12-16, copper: 2-8, cobalt: 1-3; the mass ratio of the elements of the second pigment is copper: 12-16, nickel: 3-7, cobalt: 0.5-2; the element mass ratio of the third pigment is copper: 12-17, nickel: 0-2.
8. The method according to claim 7, wherein before the steps of preparing the pattern-bleeding glaze corresponding to the first pattern mesh, the second pattern mesh, and the third pattern mesh in the preset pattern mesh, respectively, according to the element mass ratio of the first coloring material, the element mass ratio of the second coloring material, and the element mass ratio of the third coloring material of the preset pattern mesh, the method comprises:
selecting natural stone with Amazon texture patterns, and scanning the natural stone to obtain Amazon texture scanning patterns;
and carrying out color separation on the Amazon texture scanning image, and respectively manufacturing a first pattern net, a second pattern net and a third pattern net according to the sequence of the patterns to serve as a preset pattern screen.
9. The method of manufacturing according to claim 5, wherein the step of drying after pressing the ceramic powder into a green body comprises:
and heating and drying the green body to reduce the water content of the green body to 1.04-1.09%, wherein the heating temperature of the drying is 200-250 ℃.
10. The method of manufacturing according to claim 9, comprising, after the step of drying after pressing the ceramic powder into a green body:
and cooling the dried green body to reduce the temperature of the green body to 59-63 ℃.
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