CN116589319A - Fertilizer containing plant polyphenol and preparation method thereof - Google Patents

Fertilizer containing plant polyphenol and preparation method thereof Download PDF

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Publication number
CN116589319A
CN116589319A CN202310592271.XA CN202310592271A CN116589319A CN 116589319 A CN116589319 A CN 116589319A CN 202310592271 A CN202310592271 A CN 202310592271A CN 116589319 A CN116589319 A CN 116589319A
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China
Prior art keywords
plant polyphenol
polyphenol
plant
solution
water
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CN202310592271.XA
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Chinese (zh)
Inventor
王田波
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Longt Mining Group Ltd Uk
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Longt Mining Group Ltd Uk
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Priority to CN202310592271.XA priority Critical patent/CN116589319A/en
Publication of CN116589319A publication Critical patent/CN116589319A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/02Solvent extraction of solids
    • B01D11/0261Solvent extraction of solids comprising vibrating mechanisms, e.g. mechanical, acoustical
    • B01D11/0265Applying ultrasound
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/50Surfactants; Emulsifiers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Physics & Mathematics (AREA)
  • Acoustics & Sound (AREA)
  • Plant Pathology (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fertilizers (AREA)

Abstract

The invention is suitable for the technical field of fertilizer preparation, and provides a fertilizer containing plant polyphenol. The plant polyphenol liquid consists of plant polyphenol stock solution 20-30 wt%, alginic acid 10-15 wt%, glucose 5-10 wt%, sugar alcohol 10-15 wt%, surfactant 5 wt% and water 30-45 wt%, and the total weight of the components is 100 wt%. The fertilizer has wide raw material sources, the used raw materials are green and pollution-free, and substances harmful to crops and surrounding environments are not generated after complete decomposition; the plant root system development can be enhanced, the soil environment can be improved, and the soil air permeability and the water retention capacity can be improved, so that the activity of the plant root system can be increased; can also promote nutrient absorption and metabolism of crops and increase the yield and quality of crops.

Description

Fertilizer containing plant polyphenol and preparation method thereof
Technical Field
The invention is suitable for the technical field of fertilizer preparation, and provides a fertilizer containing plant polyphenol and a preparation method thereof.
Background
Plant polyphenol is a secondary metabolite of plants, widely exists in leaves, shells, pulp and seed coats of plants, and mainly comprises lignin, tannin, flavonoids and the like. Common plant polyphenols include tea polyphenols, grape polyphenols, apple polyphenols, etc., and polyphenols have astringency, can cause dyspepsia of plant eating pests, can influence reproduction of pests, and reduce survival rate. The synergistic effect of polyphenol substances and polyphenol oxidase can inhibit the stress of soil acidity and heavy metals on plants, so that the plants grow normally in adverse circumstances. The polyphenol structure of the plant polyphenol can be used for inactivating the activity of heavy metals in soil and carrying out organic chelation with trace element fertilizer.
The plant polyphenol can be chelated with other microelements such as Zn, cu, mn and the like, and can effectively solve the problem that the yield of crops is reduced due to the lack of microelements in the growing and developing process. The plant polyphenol has wide functions of antioxidation, antibiosis, disease resistance and the like, is a natural organic matter, is easy to biodegrade, does not have environmental risk, and is not widely applied in the field of crop planting at present.
Therefore, development of a plant polyphenol water-soluble fertilizer which can promote crop growth and increase crop yield is needed.
Disclosure of Invention
The invention aims to provide a fertilizer containing plant polyphenol and a preparation method thereof, which have wide sources of raw materials and can play roles in promoting the growth of crops and improving the yield of the crops.
In order to achieve the above object, the present invention provides a plant polyphenol-containing fertilizer comprising the following components:
20-30% of plant polyphenol stock solution, 10-15% of alginic acid, 5-10% of glucose, 10-15% of sugar alcohol, 5% of surfactant and 30-45% of water, wherein the sum of the mass percentages of the components is 100%.
Further, the plant polyphenol is one or more of tea polyphenol, apple polyphenol, seaweed polyphenol and grape polyphenol.
Further, the surfactant is rhamnolipid.
Further, the preparation method of the plant polyphenol stock solution comprises the following steps:
(1) cleaning at least one of tea tree branches and leaves, apples, grape skin and seaweed, drying and pulverizing;
(2) adding the plants treated in the step (1) into ethanol solution for ultrasonic leaching, centrifuging and filtering;
(3) adding the ultrasonic leaching extract obtained in the step (2) into macroporous resin for adsorption;
(4) washing the macroporous resin adsorbed in the step (3) with water, then desorbing the adsorbed macroporous resin with ethanol solution, and collecting desorption liquid;
(5) and (3) removing ethanol in the desorption liquid in the step (4) to obtain plant polyphenol stock solution.
A preparation method of a fertilizer containing plant polyphenol comprises the following steps:
(1) firstly adding water into a stirring tank, starting stirring and adding plant polyphenol stock solution until the plant polyphenol stock solution is completely dissolved, and obtaining plant polyphenol solution;
(2) adding glucose into the plant polyphenol solution while stirring until the glucose is completely dissolved, so as to obtain a mixed solution A;
(3) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(4) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
The plant polyphenol stock solution can enhance plant root system development, improve soil environment, and improve soil ventilation and water retention capacity, thereby increasing the activity of plant root systems, promoting nutrient absorption and metabolism of crops, and increasing the yield and quality of crops.
The alginic acid has the functions of enhancing the efficacy and fertilizer efficiency, relieving the phytotoxicity and fertilizer injury, improving the soil environment, improving the stress resistance of crops, improving the quality and the quality of crops and improving the utilization rate of the modifier.
The sugar alcohol has moisture keeping effect, and can prevent leaf from being burnt due to topical concentration of micronutrient, and improve stress resistance of plant.
Glucose, as an organic substance, can provide nutrients that provide conditions for the formation of microbial metabolites. The metabolites of the microorganisms can be stabilized in the soil to form new organic matters, which is beneficial to soil improvement and fertility improvement.
Rhamnolipids have good biodegradability and excellent surface activity, and dissolve various substances in a solution, so that they are more uniformly dispersed in the solution, thereby improving the speed and dissolution rate of dissolution reaction.
The invention aims to provide a fertilizer containing plant polyphenol, which has the following beneficial effects:
(1) the raw materials have wide sources, the used raw materials are green and pollution-free, and substances harmful to crops and the surrounding environment are not generated after the raw materials are completely decomposed.
(2) Enhancing plant root system development, improving soil environment, improving soil air permeability and water retention capacity, thereby increasing plant root system activity.
(3) Can promote nutrient absorption and metabolism of crops and increase the yield and quality of crops.
Detailed Description
The present invention will be described in further detail below with reference to examples of the present invention in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
Example 1:
the water-soluble fertilizer containing plant polyphenol comprises the following components in parts by weight: 20% of plant polyphenol stock solution, 10% of alginic acid, 5% of glucose, 15% of sugar alcohol, 5% of rhamnolipid and 45% of water, wherein the plant polyphenol is tea polyphenol or apple polyphenol.
The preparation method of the plant polyphenol stock solution comprises the following steps:
(1) cleaning tea tree branches, leaves and apples, drying and crushing;
(2) adding the plants treated in the step (1) into ethanol solution for ultrasonic leaching, centrifuging and filtering;
(3) adding the ultrasonic leaching extract obtained in the step (2) into macroporous resin for adsorption;
(4) washing the macroporous resin adsorbed in the step (3) with water, then desorbing the adsorbed macroporous resin with ethanol solution, and collecting desorption liquid;
(5) and (3) removing ethanol in the desorption liquid in the step (4) to obtain plant polyphenol stock solution.
Wherein, the plant polyphenol can also be selected from seaweed polyphenol and grape polyphenol, and the seaweed polyphenol and the grape polyphenol can be prepared by selecting seaweed and grape skin as raw materials according to the steps.
The preparation method of the fertilizer containing plant polyphenol comprises the following steps:
(1) respectively weighing plant polyphenol stock solution, alginic acid, glucose, sugar alcohol, rhamnolipid and water according to a preset proportion;
(2) firstly adding water into a stirring tank, starting stirring and adding plant polyphenol stock solution until the plant polyphenol stock solution is completely dissolved, and obtaining plant polyphenol solution;
(3) adding glucose into the plant polyphenol solution while stirring until the glucose is completely dissolved, so as to obtain a mixed solution A;
(4) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(5) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
Example 2:
the water-soluble fertilizer containing plant polyphenol comprises the following components in parts by weight: 30% of plant polyphenol stock solution, 15% of alginic acid, 10% of glucose, 10% of sugar alcohol, 5% of rhamnolipid and 30% of water, wherein the plant polyphenol is tea polyphenol or apple polyphenol.
The preparation method of the plant polyphenol stock solution of this example is the same as that of example 1.
The preparation method of the fertilizer containing plant polyphenol comprises the following steps:
(1) respectively weighing plant polyphenol stock solution, alginic acid, glucose, sugar alcohol, rhamnolipid and water according to a preset proportion;
(2) firstly adding water into a stirring tank, starting stirring and adding plant polyphenol stock solution until the plant polyphenol stock solution is completely dissolved, and obtaining plant polyphenol solution;
(3) adding glucose into the plant polyphenol solution while stirring until the glucose is completely dissolved, so as to obtain a mixed solution A;
(4) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(5) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
Example 3:
the water-soluble fertilizer containing plant polyphenol comprises the following components in parts by weight: 25% of plant polyphenol stock solution, 12% of alginic acid, 8% of glucose, 12% of sugar alcohol, 5% of rhamnolipid and 38% of water, wherein the plant polyphenol is tea polyphenol or apple polyphenol.
The preparation method of the plant polyphenol stock solution of this example is the same as that of example 1.
The preparation method of the fertilizer containing plant polyphenol comprises the following steps:
(1) respectively weighing plant polyphenol stock solution, alginic acid, glucose, sugar alcohol, rhamnolipid and water according to a preset proportion;
(2) firstly adding water into a stirring tank, starting stirring and adding plant polyphenol stock solution until the plant polyphenol stock solution is completely dissolved, and obtaining plant polyphenol solution;
(3) adding glucose into the plant polyphenol solution while stirring until the glucose is completely dissolved, so as to obtain a mixed solution A;
(4) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(5) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
Comparative example 1:
the contrast solution comprises the following components in parts by weight: 10% of alginic acid, 10% of glucose, 15% of sugar alcohol, 5% of rhamnolipid and 60% of water.
The comparative solution was prepared as follows:
(1) respectively weighing alginic acid, glucose, sugar alcohol, rhamnolipid and water according to a preset proportion;
(2) firstly, adding water into a stirring tank, starting stirring, and adding glucose until the glucose is completely dissolved to obtain a mixed solution A;
(3) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(4) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
The soil used in the above examples was brown soil, and the object was tomatoes. The implementation method comprises the following steps: five tomato fields are selected, wherein the area of each field is 50 square meters, 4 tomato fields are experimental areas, and the other tomato fields are control areas. The experiment starts from tomato planting, the fertilizers of the embodiments 1, 2 and 3 and the comparative example 1 are respectively used in an experiment area, the fertilizer is diluted by 800 times of water and sprayed on the leaf surfaces of tomatoes when the seedlings of the tomatoes are planted, then additional fertilization is carried out every 12 days, the same clear water is sprayed in a control area for comparison when the seedlings of the tomatoes are planted and the follow-up additional fertilization is carried out, and other treatment experiment areas and control areas are the same.
The implementation effects are shown in Table 1:
as can be seen from Table 1, the area where the fertilizer of the present invention is used has high tomato yield, high sweetness and small pest ratio, and the main reasons may be as follows, and as can be seen from the analysis of comparative example 1, the plant polyphenol stock solution is added in the examples to improve the adaptability of crops to the environmental stress, so that the survival rate of the crops is improved, the plant polyphenol can promote the growth and development of the crops, increase the leaf area and root system development degree of the crops, improve the photosynthesis efficiency of the crops, and the pest reproduction is affected and the pest survival rate is reduced due to the dyspepsia of the plant pests caused by the convergence of the polyphenol.
Of course, the present invention is capable of other various embodiments and its several details are capable of modification and variation in light of the present invention, as will be apparent to those skilled in the art, without departing from the spirit and scope of the invention as defined in the appended claims.

Claims (5)

1. The fertilizer containing plant polyphenol is characterized by comprising the following components in percentage by mass: 20-30% of plant polyphenol stock solution, 10-15% of alginic acid, 5-10% of glucose, 10-15% of sugar alcohol, 5% of surfactant and 30-45% of water, wherein the sum of the mass percentages of the components is 100%.
2. A plant polyphenol containing fertilizer according to claim 1 wherein the plant polyphenol is one or more of tea polyphenol, apple polyphenol, algae polyphenol, grape polyphenol.
3. A plant polyphenol containing fertilizer according to claim 1 wherein the surfactant is rhamnolipid.
4. The plant polyphenol-containing fertilizer of claim 1, wherein the preparation method of the plant polyphenol stock solution comprises the following steps:
(1) cleaning at least one of tea tree branches and leaves, apples, grape skin and seaweed, drying and pulverizing;
(2) adding the plants treated in the step (1) into ethanol solution for ultrasonic leaching, centrifuging and filtering;
(3) adding the extract obtained in the step (2) into macroporous resin for adsorption;
(4) washing the macroporous resin adsorbed in the step (3) with water, then desorbing the adsorbed macroporous resin with ethanol solution, and collecting desorption liquid;
(5) and (3) removing ethanol in the desorption liquid in the step (4) to obtain plant polyphenol stock solution.
5. A method for preparing a plant polyphenol containing fertilizer according to any of claims 1 to 4 comprising the steps of:
(1) firstly adding water into a stirring tank, starting stirring and adding plant polyphenol stock solution until the plant polyphenol stock solution is completely dissolved, and obtaining plant polyphenol solution;
(2) adding glucose into the plant polyphenol solution while stirring until the glucose is completely dissolved, so as to obtain a mixed solution A;
(3) sequentially adding alginic acid and sugar alcohol into the mixed solution A while stirring until the alginic acid and sugar alcohol are completely dissolved to obtain a mixed solution B;
(4) and adding rhamnolipid into the mixed solution B while stirring until the rhamnolipid is completely dissolved, so as to obtain the water-soluble fertilizer containing plant polyphenol.
CN202310592271.XA 2023-05-24 2023-05-24 Fertilizer containing plant polyphenol and preparation method thereof Pending CN116589319A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310592271.XA CN116589319A (en) 2023-05-24 2023-05-24 Fertilizer containing plant polyphenol and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310592271.XA CN116589319A (en) 2023-05-24 2023-05-24 Fertilizer containing plant polyphenol and preparation method thereof

Publications (1)

Publication Number Publication Date
CN116589319A true CN116589319A (en) 2023-08-15

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Country Status (1)

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