CN1163455C - 带有通流管的泡罩塔反应器和再生其中的催化剂的方法 - Google Patents

带有通流管的泡罩塔反应器和再生其中的催化剂的方法 Download PDF

Info

Publication number
CN1163455C
CN1163455C CNB988008939A CN98800893A CN1163455C CN 1163455 C CN1163455 C CN 1163455C CN B988008939 A CNB988008939 A CN B988008939A CN 98800893 A CN98800893 A CN 98800893A CN 1163455 C CN1163455 C CN 1163455C
Authority
CN
China
Prior art keywords
gas
regeneration
draft tube
bubble
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB988008939A
Other languages
English (en)
Chinese (zh)
Other versions
CN1230941A (zh
Inventor
C
C·马勒托
V·比科罗
D·卡萨纳威
P·加尔提尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Agip Petroli SpA
Eni SpA
Original Assignee
IFP Energies Nouvelles IFPEN
Agip Petroli SpA
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN, Agip Petroli SpA, Eni SpA filed Critical IFP Energies Nouvelles IFPEN
Publication of CN1230941A publication Critical patent/CN1230941A/zh
Application granted granted Critical
Publication of CN1163455C publication Critical patent/CN1163455C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34Apparatus, reactors
    • C10G2/342Apparatus, reactors with moving solid catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0485Set-up of reactors or accessories; Multi-step processes
    • C07C1/049Coupling of the reaction and regeneration of the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00115Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00132Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/0084Stationary elements inside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00033Continuous processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CNB988008939A 1997-06-26 1998-06-20 带有通流管的泡罩塔反应器和再生其中的催化剂的方法 Expired - Fee Related CN1163455C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT97MI001509A IT1292422B1 (it) 1997-06-26 1997-06-26 Reattore a bolle con draft tube e procedimento per la rigenerazione del catalizzatore in esso contenuto
ITMI97A001509 1997-06-26

Publications (2)

Publication Number Publication Date
CN1230941A CN1230941A (zh) 1999-10-06
CN1163455C true CN1163455C (zh) 2004-08-25

Family

ID=11377442

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB988008939A Expired - Fee Related CN1163455C (zh) 1997-06-26 1998-06-20 带有通流管的泡罩塔反应器和再生其中的催化剂的方法

Country Status (14)

Country Link
US (1) US6162754A (US06559137-20030506-C00021.png)
EP (1) EP0923413B1 (US06559137-20030506-C00021.png)
JP (1) JP4083819B2 (US06559137-20030506-C00021.png)
CN (1) CN1163455C (US06559137-20030506-C00021.png)
CA (1) CA2264572C (US06559137-20030506-C00021.png)
DE (1) DE69816576T2 (US06559137-20030506-C00021.png)
ES (1) ES2205529T3 (US06559137-20030506-C00021.png)
ID (1) ID21080A (US06559137-20030506-C00021.png)
IT (1) IT1292422B1 (US06559137-20030506-C00021.png)
MY (1) MY120749A (US06559137-20030506-C00021.png)
NO (1) NO318137B1 (US06559137-20030506-C00021.png)
RU (1) RU2198868C2 (US06559137-20030506-C00021.png)
SA (1) SA98190950B1 (US06559137-20030506-C00021.png)
WO (1) WO1999000191A2 (US06559137-20030506-C00021.png)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2751227B1 (fr) * 1996-07-19 1998-11-27 Rhone Merieux Formule de vaccin polynucleotidique contre les pathologies canines, notamment les pathologies respiratoires et digestives
US6323248B1 (en) * 2000-06-02 2001-11-27 Exxonmobil Research And Engineering Company Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production
US20020143075A1 (en) * 2001-03-27 2002-10-03 Agee Kenneth L. Low-profile moving bed reactor
US20040000474A1 (en) * 2002-02-22 2004-01-01 Catalytic Distillation Technologies Liquid-continuous column distillation
US6838487B1 (en) * 2003-12-04 2005-01-04 Rentech, Inc. Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst
AU2005321240B2 (en) * 2004-12-31 2009-06-04 Shell Internationale Research Maatschappij B.V. Reactor for solid/liquid/gas reactions
JP5674271B2 (ja) 2005-03-17 2015-02-25 サソール テクノロジー(プロプライエタリー)リミテッド 流動床反応器を動作させる方法
JP2007197636A (ja) * 2006-01-30 2007-08-09 Nippon Steel Engineering Co Ltd 気泡塔型炭化水素合成反応器
US7666366B2 (en) 2006-07-10 2010-02-23 Exxonmobil Chemical Patents Inc. Internal loop reactor and Oxo process using same
CN104209125A (zh) * 2006-08-25 2014-12-17 新日铁工程技术株式会社 从合成气体制造烃的催化剂、催化剂的制造方法、催化剂的再生方法以及从合成气体制造烃的方法
RU2456080C2 (ru) * 2007-05-11 2012-07-20 Сасол Текнолоджи (Проприетери) Лимитед Способ регенерации кобальтового катализатора синтеза фишера-тропша
RU2442815C2 (ru) * 2007-08-10 2012-02-20 САСОЛ ТЕКНОЛОДЖИ (ПиТиУай) ЛТД Способ синтеза углеводородов
US8614158B2 (en) * 2008-02-29 2013-12-24 Schlumberger Technology Corporation Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process
US8293805B2 (en) * 2008-05-29 2012-10-23 Schlumberger Technology Corporation Tracking feedstock production with micro scale gas-to-liquid units
AU2009299339B2 (en) * 2008-09-30 2013-05-09 Cosmo Oil Co., Ltd. Bubble column reactor and method of controlling bubble column reactor
CA2755952C (en) * 2008-12-15 2016-10-11 Sasol Technology (Proprietary) Limited Process for regenerating spent particulate wax-containing cobalt-based fischer-tropsch synthesis catalyst
JP2012512735A (ja) * 2008-12-18 2012-06-07 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 酸化し、炭酸アンモニウム、水酸化アンモニウムおよび水の混合物を用いて処理することによるフィッシャー・トロプシュ触媒の再生
US8497310B2 (en) 2008-12-22 2013-07-30 Shell Oil Company Integrated process and reactor arrangement for hydrocarbon synthesis
US20100303684A1 (en) * 2009-05-04 2010-12-02 Kelvin John Hendrie Reactor comprising cooling modules
JP2014136767A (ja) 2013-01-17 2014-07-28 Japan Oil Gas & Metals National Corp 炭化水素合成反応装置
WO2015025225A2 (en) * 2013-08-21 2015-02-26 Saudi Basic Industries Corporation A process for the production of hydrocarbons
JP6518480B2 (ja) * 2015-03-30 2019-05-22 株式会社クボタ 気泡塔型スラリー床反応装置
RU204762U1 (ru) * 2019-07-19 2021-06-09 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Устройство для проведения реакций в суспензионном слое наноразмерного катализатора
RU195804U1 (ru) * 2019-07-19 2020-02-05 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А. В. Топчиева Российской академии наук (ИНХС РАН) Устройство для проведения каталитических процессов в трехфазном суспензионном слое

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS501700B1 (US06559137-20030506-C00021.png) * 1969-06-21 1975-01-21
EP0325337B1 (en) * 1988-01-20 1993-08-25 Paques B.V. Process for reducing the hysteresis effect in a gaslift loop reactor with suspended solid particles
US5292705A (en) * 1992-09-24 1994-03-08 Exxon Research & Engineering Co. Activation of hydrocarbon synthesis catalyst
US5252613A (en) * 1992-12-18 1993-10-12 Exxon Research & Engineering Company Enhanced catalyst mixing in slurry bubble columns (OP-3723)
US5288673A (en) * 1992-12-18 1994-02-22 Exxon Research And Engineering Company Temperature control in draft tubes for catalyst rejuvenation
US5268344A (en) * 1992-12-18 1993-12-07 Exxon Research & Engineering Company Draft tube for catalyst rejuvenation and distribution
FR2751564B1 (fr) * 1996-07-26 2001-10-12 Inst Francais Du Petrole Procede et dispositif pour le fonctionnement d'une colonne a bulles triphasique avec application en synthese fischer-tropsch
IT1283774B1 (it) * 1996-08-07 1998-04-30 Agip Petroli Processo di fischer-tropsch con reattore a colonna a bolle multistadio

Also Published As

Publication number Publication date
ES2205529T3 (es) 2004-05-01
DE69816576D1 (de) 2003-08-28
ITMI971509A0 (US06559137-20030506-C00021.png) 1997-06-26
EP0923413B1 (en) 2003-07-23
ID21080A (id) 1999-04-15
WO1999000191A2 (en) 1999-01-07
SA98190950B1 (ar) 2006-05-01
NO318137B1 (no) 2005-02-07
CA2264572C (en) 2007-05-29
IT1292422B1 (it) 1999-02-08
US6162754A (en) 2000-12-19
JP4083819B2 (ja) 2008-04-30
CA2264572A1 (en) 1999-01-07
DE69816576T2 (de) 2004-05-13
ITMI971509A1 (it) 1998-12-26
WO1999000191A3 (en) 1999-03-25
RU2198868C2 (ru) 2003-02-20
EP0923413A2 (en) 1999-06-23
CN1230941A (zh) 1999-10-06
NO990881L (no) 1999-04-26
MY120749A (en) 2005-11-30
JP2000516966A (ja) 2000-12-19
NO990881D0 (no) 1999-02-24

Similar Documents

Publication Publication Date Title
CN1163455C (zh) 带有通流管的泡罩塔反应器和再生其中的催化剂的方法
CN1020678C (zh) 用于合成气转化为烃的含钴-铼的催化剂
RU2189857C2 (ru) Способ и устройство для функционирования пузырьковой реакционной колонны с трехфазной реакционной средой с применением для синтеза фишера - тропша
CN1069323C (zh) 气相聚合方法
CN1198758C (zh) 用适合的催化剂通过可逆转化生产一氧化碳的方法
CN1127376C (zh) 催化剂活化和再生方法
CN1308224C (zh) 合成气的制备方法
CN1059680C (zh) α-烯烃气相聚合方法及设备
CN1226251C (zh) 乙苯脱氢生产苯乙烯的方法
CN101080481A (zh) 在生产领域中最优化氢生产的加氢转化序列和蒸汽重整方法
CN1246267C (zh) 费-托法
CN1929908A (zh) 反应器的气体分布器
JP2004534873A (ja) フィッシャートロプシュ法
CN102596386A (zh) 一种沸腾床反应器及其加氢方法
CN1275968A (zh) 优化烃类合成的方法
CN1911502A (zh) 一种纳米级低碳烷烃脱氢催化剂
AU2001292045A1 (en) Fischer-tropsch process
CN1121259C (zh) 从气体原料生产液体和/或气体产品的方法
CN1025182C (zh) 丙烯的制备方法
CN1084719C (zh) 由含有异丁烯和1-丁烯的碳4馏分制造高纯度异丁烯的方法
CA2525007A1 (en) Process for producing liquid and, optionally, gaseous products from gaseous reactants
CN1188373C (zh) 改进的费-托方法
CN1082386C (zh) 甲醛的多相放热合成的方法和反应器
JP4388753B2 (ja) 不均一系触媒を用いた酢酸の製造方法
US8183301B2 (en) Preparation methods for liquid hydrocarbons by Fischer-Tropsch synthesis through slurry reaction

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20040825

Termination date: 20170620

CF01 Termination of patent right due to non-payment of annual fee