CN116065147A - 用于制造制动盘的方法和制动盘 - Google Patents
用于制造制动盘的方法和制动盘 Download PDFInfo
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- CN116065147A CN116065147A CN202211327401.9A CN202211327401A CN116065147A CN 116065147 A CN116065147 A CN 116065147A CN 202211327401 A CN202211327401 A CN 202211327401A CN 116065147 A CN116065147 A CN 116065147A
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- Prior art keywords
- carbide
- titanium
- metal matrix
- iron
- friction surface
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 38
- 239000011159 matrix material Substances 0.000 claims abstract description 34
- 229910052751 metal Inorganic materials 0.000 claims abstract description 34
- 239000002184 metal Substances 0.000 claims abstract description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 27
- 239000000956 alloy Substances 0.000 claims abstract description 27
- 239000010410 layer Substances 0.000 claims abstract description 27
- 239000002344 surface layer Substances 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 26
- 238000005507 spraying Methods 0.000 claims abstract description 16
- 229910001069 Ti alloy Inorganic materials 0.000 claims abstract description 15
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 12
- 239000010936 titanium Substances 0.000 claims abstract description 12
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 12
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 8
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910001567 cementite Inorganic materials 0.000 claims abstract description 6
- UFGZSIPAQKLCGR-UHFFFAOYSA-N chromium carbide Chemical compound [Cr]#C[Cr]C#[Cr] UFGZSIPAQKLCGR-UHFFFAOYSA-N 0.000 claims abstract description 6
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910003470 tongbaite Inorganic materials 0.000 claims abstract description 6
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims abstract description 6
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 22
- 239000002131 composite material Substances 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910001208 Crucible steel Inorganic materials 0.000 claims description 4
- 229910001060 Gray iron Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000002861 polymer material Substances 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 239000007921 spray Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000007788 roughening Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007773 kinetic metallization Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
在制造制动盘(1)的方法中,通过颗粒混合物的冷气喷涂将摩擦面层(10a,10b)喷涂到基体(2)上或者喷涂到在基体(2)上涂覆的中间层(12a,12b)上,所述颗粒混合物由25至75重量%的金属基质材料和75至25重量%的碳化物材料构成。所述金属基质材料由铁基合金、镍基合金、钛或钛合金组成。所述碳化物材料由碳化钨、碳化钛、碳化铁、碳化硅、碳化铬或碳化铌组成。
Description
本发明涉及根据权利要求1的前序部分的用于制造制动盘的方法和根据权利要求6的前序部分的用于盘式制动器的制动盘。
用于车辆盘式制动器的制动盘通常具有一个例如由灰铸铁、铸钢或铸铝构成的基体,所述基体具有用作为摩擦面的侧面。此外,还已知由聚合物材料或复合材料生产的基体。
盘式制动器是摩擦制动器。制动效果或车辆的减速通常是通过以机械、液压或气动方式将装有制动衬片的制动块从对面压到旋转的制动盘摩擦面来实现的。在这种情况下,制动盘在两侧分别具有一个圆环形摩擦面。此外,制动盘还用于全盘式制动器,其中制动盘的整个侧面用作摩擦面。
由于高摩擦力和由此产生的热量发展,已知的制动盘通常会出现高磨损。另一个问题是已知制动盘的腐蚀敏感性。
此外,各种类型的涂层工艺是已知的,用这些涂层工艺可以用某些材料对例如由金属或塑料构成的工件或其它基材进行涂层。一种此类工艺是冷气喷涂工艺(也称为动力涂层、冷气喷涂、冷喷涂、动力金属化或动力熔融)。在冷气喷涂中,涂层材料以粉末形式存在,并以非常高的速度,特别是超音速涂覆到基材上。为此使用一种工艺气体,在高压下将其导入喷枪,并加热至最高约1200℃的温度。气体在收敛-发散型喷嘴(拉瓦尔喷嘴)中的后续膨胀导致工艺气体加速至超音速并在此过程中强烈冷却。注入喷嘴的喷涂粉末也被加速到超音速,并由于高动能而牢固地结合在基材上。与其它工艺相比,其中喷涂材料既不会熔融也不会在基材上被熔化。
因此,本发明的任务在于提供一种制造制动盘的方法,使用该方法可以以成本低廉且可靠的方式制造在耐磨性以及耐温度和耐腐蚀性方面具有特别良好性能的制动盘。此外,应制得具有此类特性的制动盘。
根据本发明,通过具有权利要求1的特征的方法和具有权利要求6的特征的制动盘来完成该任务。在进一步的权利要求中描述了本发明的有利实施形式。
在根据本发明的方法中,通过颗粒混合物的冷气喷涂将摩擦面层喷涂到基体上或喷涂到在基体上涂覆的中间层上,其中所述颗粒混合物由25至75重量%金属基质材料和75至25重量%碳化物材料构成。所述金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金。
碳化物材料由以下材料之一构成:
-碳化钨,
-碳化钛,
-碳化铁,
-碳化硅,
-碳化铬,
-碳化铌。
借助根据本发明的方法,在基体上或在涂覆于基体的中间层上形成具有极高耐磨性的摩擦面层。冷气喷涂工艺和喷涂的复合材料的结合致使相对于已知制动盘直至99%的磨损降低。
由于基体上或在中间层上摩擦面层的高粘附强度,摩擦面层的分层风险大大降低。摩擦面层具有很高的耐腐蚀性。通过冷气喷涂工艺进入基体的热量输入非常低,从而使基体的变形最小化或不发生。如果使用铁基合金、钛或钛合金作为金属基质材料,则应避免使用例如镍或铜等对环境有害的材料。由于摩擦面层改善的性能,在功能非常强劲的盘式制动器的情况下也能由轻材料(例如轻金属)制成基体,从而可以大幅减轻制动盘的重量。此外,借助根据本发明的方法,由于高效的冷气喷涂工艺与根据本发明的颗粒混合物的结合可以以成本非常低廉的方式制造制动盘。
根据本发明的摩擦面层可以直接喷涂到制动盘的基体上或喷涂到在基体上事先涂覆的中间层上。根据一种有利的实施例形式,同样通过颗粒状金属基质材料的冷气喷涂将中间层喷涂到基体上,其中所述颗粒状金属基体材质由以下材料之一构成:
-铁基合金,
-镍基合金,
-钛,
-钛合金。
中间层可以由与摩擦面层的金属基质材料相同的金属基质材质或另一种金属基质材质构成。例如可能的是,中间层的金属基质材料由铁基合金构成,而摩擦面层的金属基质材料,即复合材料,由镍基合金、钛或钛合金构成。中间层材料的有利选择一方面取决于基体的材料,另一方面则取决于摩擦面层的材料,从而实现层之间以及层与基体的特别良好的粘附性。
根据一个有利的实施形式,用于摩擦面层和/或中间层的金属基质材料的铁基合金含有5至40重量%铬。这可以实现特别有利的腐蚀性能。
根据一个有利的实施方案,用于摩擦面层和/或中间层的金属基质材料的钛合金含有5.5至6.75重量%铝和3.5至4.5重量%钒。这使得所形成的摩擦面层和中间层特别稳定和耐热。
根据一个有利的实施形式,在喷涂用于形成摩擦面层的颗粒混合物或用于形成中间层的颗粒状金属基质材料的区域内,于所述喷涂之前,基体被机械、化学或借助激光粗糙化。这实现了摩擦面层或中间层在基体上的特别良好的粘合性。
所述任务还通过用于盘式制动器的一种制动盘完成,其中所述制动盘具有基体和在所述基体的至少一侧上具有摩擦面层,所述摩擦面层具有摩擦面。制动盘的所述摩擦面层由一种复合材料构成,该复合材料是通过在基体上或者在涂覆于基体上的中间层上进行颗粒混合物的冷气喷涂产生的,其中所述颗粒混合物由25到75重量%的金属基质材料和75至25重量%的碳化物材料构成。所述金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金。
所述碳化物材料由以下材料之一构成:
-碳化钨
-碳化钛
-碳化铁
-碳化硅
-碳化铬
-碳化铌。
通过本发明的制动盘,就制动盘的制造方法而言,实现了如上所述的相同的技术效果和优点。
优选地,所述基体全部或部分由铸钢、灰铸铁、铸铝、聚合物或复合材料构成。
下面将参考附图更详细地解释本发明。其显示:
图1:根据本发明第一实施形式的制动盘的截面图;
图2:图1细节II的放大图;和
图3:与图2相对应的本发明第二实施形式的截面图。
图1显示了用于车辆盘式制动器的制动盘1,如轿车、卡车、摩托车、自行车或轨道车辆。
制动盘1包括一个基体2,在图示的实施例中,该基体2具有一个杯状的中心部分3和以及从中心部件3径向向外延伸的环形盘体4。
基体2在所示实施例1中是一个整体,但也可以是多部分的。优选地,基体由铸钢、灰铸铁、铸铝、聚合物或复合材料构成。
中心部件3以已知方式用于将制动盘1固定到旋转部件上,例如固定到车辆轮毂上。
所述径向延伸出中心部件3的环形盘体4设置在与制动盘1的中心轴5垂直的主平面内。此外,在所示实施例中,盘体4以已知的方式由两个平行的环形盘元件6a、6b组成,所述环形盘元件借助多个片层状、优选通过在制动盘1的圆周上规则分布的连接腹板7相互连接,并且彼此保持一定距离,以便环形盘元件6a、6b之间形成一个空间。经此,冷却空气进入环形制动盘元件6a、6b之间,从而提高制动盘1的冷却效果。
借助本发明的方法,也可以很容易地对整个盘进行(Vollscheiben)涂层。
在盘体4的两侧,即外侧面9a、9b上,通过冷气喷涂工艺分别涂覆摩擦面层10a、10b。这两个摩擦面层10a、10b优选相同地形成,并可以特别是由相同的材料构成,且具有相同的厚度。摩擦面层10a、10b的横向外表面形成摩擦面11a、11b。在所示实施例中,如此形成摩擦面层10a、10b,其使得可以相对于车辆静止的制动钳相互开合移动并具有适当的制动衬片的未示出的制动块,可以从对立侧相向地向摩擦面层10a、10b的摩擦面11a、11b压紧,从而通过制动产生在制动块与盘体4之间所需的摩擦力。
摩擦面层10a、10b由金属基质材料与碳化物材料组成的复合材料构成。根据本发明,所述金属基质材料由优选具有5至40重量%铬的铁基合金(含或不含附加合金成分)、镍基合金、钛或者钛合金(例如具有5.5至6.75%的铝和3.5%的钒的Ti6Al4V)构成。
所述碳化物材料由碳化钨、碳化钛、碳化铁、碳化硅、碳化铬或碳化铌构成。
摩擦面层10a、10b的复合材料通过喷涂粉末混合物或颗粒混合物产生,其由25至75重量%金属基质材料和75至25重量%碳化物材料组成。
通过在涂层前以适当的方式制备盘体4的侧面9a、9b,可以使摩擦面层10a、10b在盘体4上产生特别良好的粘附性。特别是,可以使用使侧面9a、9b粗糙化的方法。这可以通过喷砂工艺、机械粗化、化学处理、激光结构化等实现。
图3显示了本发明的第二实施形式,其中仅显示了与图2中第一实施形式相关的制动盘部分。在第二实施形式中,基体2与第一实施例的基体2相同,因此在这方面参考第一实施形式。
与第一实施形式相反,在第二实施形式中,摩擦面层10a、10b不是直接喷涂到基体2的盘体4上,而是喷涂到中间层12a、12b上,在喷涂摩擦面层10a、10b之前同样借助冷气喷涂工艺将所述中间层喷涂到盘体4的侧面9a、9b上。
这两个中间层12a、12b可以相同地形成。此外,所述中间层12a、12b由金属基质材料构成,所述金属基质材料由铁基合金(优选具有5至40%的铬)、镍基合金、钛或钛合金(例如,具有5.5至6.76%铝和3.5至5.5%钒的Ti6Al4V)构成。
所述中间层12a、12b的金属基质材料可以由与摩擦面层10a、10b相同的或另一种金属基质材料构成。
同样在第二实施形式中有利的是,在喷涂中间层12a、12b之前,以适当的方式预处理盘体4的侧面9a、9b,特别是进行粗糙化。这可以通过与第一实施形式相关的描述以相同的方法来实现。
Claims (11)
1.制造制动盘(1)的方法,所述制动盘具有基体(2)和在所述基体(2)的至少一侧上的摩擦面层(10a,10b),所述摩擦面层具有摩擦面(11a,11b),其特征在于,通过颗粒混合物的冷气喷涂将摩擦面层(10a,10b)喷涂到基体(2)上或喷涂到在基体(2)上涂覆的中间层(12a,12b)上,其中所述颗粒混合物由25至75重量%金属基质材料和75至25重量%碳化物材料构成,其中所述金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金,
且其中碳化物材料由以下材料之一构成:
-碳化钨
-碳化钛
-碳化铁
-碳化硅
-碳化铬
-碳化铌。
2.根据权利要求1所述的方法,其特征在于,所述中间层(12a,12b)通过将颗粒状金属基质材料的冷气喷涂喷涂到基体(2)上,其中所述颗粒状金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金。
3.根据权利要求1或2所述的工艺,其特征在于,所述铁基合金含有5–40重量%铬。
4.根据上述任一权利要求所述的方法,其特征在于,所述钛合金含有5.5至6.75重量%铝和3.5-4.5重量%钒。
5.根据前述权利要求之一的方法,其特征在于,在喷涂用于形成摩擦面层(10a,10b)的颗粒混合物或用于形成中间层(12a,12b)的颗粒状金属基质材料的区域内,于所述喷涂之前,基体(2)被机械、化学或借助激光粗糙化。
6.用于盘式制动器的制动盘,其中所述制动盘(1)具有基体(2)和在所述基体(2)的至少一侧上的摩擦面层(10a,10b),所述摩擦面层具有摩擦面(11a,11b),其特征在于,所述摩擦面层(10a,10b)由复合材料构成,所述复合材料是通过在基体(2)上或者在涂覆于基体(2)上的中间层(12a,12b)上进行颗粒混合物的冷气喷涂产生的,其中所述颗粒混合物由25至75重量%的金属基质材料和75至25重量%的碳化物材料构成,
其中所述金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金,
其中所述碳化物材料由以下材料之一构成:
-碳化钨,
-碳化钛,
-碳化铁,
-碳化硅,
-碳化铬,
-碳化铌。
7.根据权利要求6所述的制动盘,其特征在于,所述中间层(12a,12b)至少主要由通过冷气喷涂在基体(2)上喷涂的颗粒状金属基质材料构成,所述金属基质材料由以下材料之一构成:
-铁基合金
-镍基合金
-钛
-钛合金。
8.根据权利要求6或7所述的制动盘,其特征在于,所述铁基合金含有5–40重量%铬。
9.根据权利要求6至8中任一项所述的制动盘,其特征在于,所述钛合金含有5.5至6.75重量%铝和3.5至4.5重量%钒。
10.根据权利要求6至9中任一项所述的制动盘,其特征在于,在喷涂形成摩擦面层(10a,10b)的颗粒混合物或形成中间层(12a,12b)的颗粒状金属基质材料的区域内,于所述喷涂之前,基体(2)被机械、化学或借助激光粗糙化。
11.根据权利要求6至10中任一项所述的制动盘,其特征在于,基体(2)全部或部分由铸钢、灰铸铁、铸铝、聚合物或复合材料构成。
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WO2010089047A1 (de) * | 2009-02-09 | 2010-08-12 | Daimler Ag | Bremsscheibe für ein fahrzeug sowie verfahren zu ihrer herstellung |
DE102013009955A1 (de) * | 2013-06-13 | 2014-12-18 | Daimler Ag | Bauteil mit verschleißbeständiger Reibschicht |
DE102016200951A1 (de) * | 2016-01-25 | 2017-07-27 | Volkswagen Aktiengesellschaft | Verfahren zum Erzeugen einer verschleiß- und/oder korrosionsfesten Beschichtung auf einer Reibfläche eines Bremskörpers sowie nach dem Verfahren herstellbarer Bremskörper |
US20200072307A1 (en) * | 2018-09-04 | 2020-03-05 | Ford Global Technologies, Llc | Brake disk and method for producing a brake disk |
DE102019208411A1 (de) * | 2019-06-08 | 2020-12-10 | Robert Bosch Gmbh | Reibbremskörper für eine Reibbremse eines Kraftfahrzeugs, Reibbremse und Verfahren zur Herstellung eines Reibbremskörpers |
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JP4627346B2 (ja) | 2000-03-31 | 2011-02-09 | 本田技研工業株式会社 | ブレーキディスク |
US6915964B2 (en) | 2001-04-24 | 2005-07-12 | Innovative Technology, Inc. | System and process for solid-state deposition and consolidation of high velocity powder particles using thermal plastic deformation |
GB2541610B (en) | 2014-06-06 | 2021-04-07 | Nat Res Council Canada | Bi-layer iron coating of lightweight metallic substrate |
DE102017212706A1 (de) * | 2017-07-25 | 2019-01-31 | Robert Bosch Gmbh | Bremsscheibe und Verfahren zur Herstellung einer Bremsscheibe |
ES2938462T3 (es) * | 2018-09-04 | 2023-04-11 | Ford Global Tech Llc | Disco de freno y procedimiento para producir el mismo |
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- 2022-10-27 CN CN202211327401.9A patent/CN116065147A/zh active Pending
- 2022-10-27 JP JP2022171914A patent/JP2023067824A/ja active Pending
- 2022-10-27 US US17/975,052 patent/US20230135647A1/en active Pending
- 2022-10-27 KR KR1020220140288A patent/KR20230062416A/ko unknown
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2010089047A1 (de) * | 2009-02-09 | 2010-08-12 | Daimler Ag | Bremsscheibe für ein fahrzeug sowie verfahren zu ihrer herstellung |
DE102013009955A1 (de) * | 2013-06-13 | 2014-12-18 | Daimler Ag | Bauteil mit verschleißbeständiger Reibschicht |
DE102016200951A1 (de) * | 2016-01-25 | 2017-07-27 | Volkswagen Aktiengesellschaft | Verfahren zum Erzeugen einer verschleiß- und/oder korrosionsfesten Beschichtung auf einer Reibfläche eines Bremskörpers sowie nach dem Verfahren herstellbarer Bremskörper |
US20200072307A1 (en) * | 2018-09-04 | 2020-03-05 | Ford Global Technologies, Llc | Brake disk and method for producing a brake disk |
DE102019208411A1 (de) * | 2019-06-08 | 2020-12-10 | Robert Bosch Gmbh | Reibbremskörper für eine Reibbremse eines Kraftfahrzeugs, Reibbremse und Verfahren zur Herstellung eines Reibbremskörpers |
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DE102021128374B4 (de) | 2023-10-26 |
US20230135647A1 (en) | 2023-05-04 |
JP2023067824A (ja) | 2023-05-16 |
EP4174212A1 (de) | 2023-05-03 |
KR20230062416A (ko) | 2023-05-09 |
DE102021128374A1 (de) | 2023-05-04 |
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