CN115971719A - Solder paste for improving welding cavity of large-area bonding pad of electronic device - Google Patents

Solder paste for improving welding cavity of large-area bonding pad of electronic device Download PDF

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Publication number
CN115971719A
CN115971719A CN202310171228.6A CN202310171228A CN115971719A CN 115971719 A CN115971719 A CN 115971719A CN 202310171228 A CN202310171228 A CN 202310171228A CN 115971719 A CN115971719 A CN 115971719A
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percent
alloy powder
acid
solder paste
electronic devices
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李维俊
段佐芳
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Shenzhen Vital New Material Compangy Ltd
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Shenzhen Vital New Material Compangy Ltd
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Abstract

A solder paste for improving welding holes of large-area bonding pads of electronic devices comprises alloy powder and soldering flux, wherein the alloy powder is formed by mixing one or more than two tin-based alloy powders and has eutectic composition, and the soldering flux is composed of the following components in percentage by weight: 22 to 44 percent of modified rosin, 11 to 16 percent of thixotropic agent, 4 to 10 percent of organic acid active agent, 5 to 8 percent of surfactant and 0.5 to 1.5 percent of organic modified polysiloxane, and the balance of phenyl (tetrahydro-2H-pyran-4-yl) methanol, wherein the phenyl methanol has a low boiling point design, the boiling point temperature is 112 to 113 degrees, and the low boiling point is designed, so that the phenyl methanol can be boiled quickly in the temperature rising process, not only the bubble formation in the welding process is broken, but also a quick escape channel is formed, and the release efficiency and the effect of gas can be greatly improved.

Description

Solder paste for improving welding cavity of large-area bonding pad of electronic device
Technical Field
The invention relates to the field of processing materials of electronic devices, in particular to a soldering paste for improving a welding cavity of a large-area bonding pad of an electronic device.
Background
In the current electronic assembly connection, a Surface Mount Technology (SMT) is generally adopted, and solder paste welding is more and more widely applied to the welding process of various electronic devices and can well play the welding role. With the higher precision of electronic devices, higher requirements are put forward on the reliability of welding spots, including mechanical properties such as welding strength, welding spot brittleness, impact toughness, shock resistance, drop resistance and the like, and also including heat conduction performance and electric conduction performance of the welding spots. Among these critical properties, solder voiding is a major concern. Once the area of the cavity is too large, the mechanical performance of the solder joint is reduced, and meanwhile, the transmission of electrical signals and the heat transmission of the device during working are influenced, so that the service life of the solder joint is finally greatly reduced, and the reliability problem of soldering is caused.
In the actual welding process, water contained in the solder paste is heated and evaporated into water vapor, the water vapor generated by the reaction of the organic acid activator and the metal oxide and other solvents are volatilized into gas, the gas substances must smoothly escape from the molten solder to form a full welding point, otherwise, the gas substances are wrapped by the subsequently solidified solder alloy to form a cavity inside or on the surface of the welding point. When the area of the welding spot is smaller, on one hand, the volume of the required solder paste is smaller, and the amount of the formed volatile gas is less; on the other hand, the gas has small resistance and short distance to escape to the welding spot, and the gas can escape more easily. Therefore, the welding void ratio of the small welding spots is usually smaller, and most of the solder paste in the current industry can meet the welding void requirement of the small welding spots. On the contrary, the welding holes of the large-area welding pad are not controlled, the required amount of tin paste is large, more water vapor is needed, the water vapor is easier to wrap by a large amount of molten solder, the number of the holes formed after welding is large, and the single area is huge. Such as a heat sink pad of QFN, a heat sink pad of MOS, a DBC of igbt, etc. The voids of QFN and MOS heat dissipation pads are basically above 25%, and even below 40% are difficult to control. There is no effective solution for this within the industry.
In contrast, chinese patent CN200580045159 and japanese patent 2003-264367 both solve the problem of bubble voids by selecting a special rosin resin, while in japanese patent 10-178261, the void voids are reduced by selecting a specific active agent, and chinese patent CN 102528315A uses a specific acid anhydride additive to eliminate moisture during the soldering process, but this method only consumes moisture to a certain extent and reduces voids caused by moisture residue, and cannot substantially contribute to the volatilization of the solvent in the solder paste.
The Chinese invention patent CN202011178823.5 discloses a laser soldering tin paste and a preparation method thereof, and the adopted technical scheme is as follows: a laser welding solder paste comprises, by weight, 86-88% of alloy powder and 12-14% of paste flux; the alloy powder is an alloy powder with eutectic components formed by mixing one or more than two tin-based alloy powders; the paste flux consists of the following raw materials in percentage by weight: 35-50% of rosin, 5-10% of thixotropic agent, 3-6% of organic acid active agent, 1-3% of organic halogen active agent, 35-45% of organic solvent and 5-10% of special solvent. The invention has the advantages that: the flux boiling caused by rapid temperature rise can be inhibited, and the effect of inhibiting the solder balls and the flux from splashing caused by rapid heating of the solder paste is realized.
Disclosure of Invention
The invention aims to provide soldering paste for improving the welding cavity of a large-area bonding pad of an electronic device, which can greatly reduce the welding cavity of the large-area bonding pad and improve the welding quality of a large welding spot.
In order to achieve the purpose, the invention provides the following technical scheme:
a solder paste for improving welding holes of large-area bonding pads of electronic devices comprises alloy powder and soldering flux, wherein the alloy powder is formed by mixing one or more than two tin-based alloy powders and has eutectic composition, and the soldering flux is composed of the following components in percentage by weight: 22 to 44 percent of modified rosin, 11 to 16 percent of thixotropic agent, 4 to 10 percent of organic acid active agent, 5 to 8 percent of surfactant, 0.5 to 1.5 percent of organic modified polysiloxane and the balance of solvent phenyl (tetrahydro-2H-pyran-4-yl) methanol.
Further, the modified rosin is preferably at least one of water-white hydrogenated rosin and acrylic rosin.
Further, the thixotropic agent is preferably at least one of a stemmed castor oil, stearic acid, oleic acid amide and a high molecular paraffin.
Further, the organic acid activator is preferably at least one of succinic acid, adipic acid, azelaic acid, glutaric acid, citric acid, and malic acid.
Further, the surfactant is preferably at least one of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether, and dodecylphenol polyoxyethylene ether.
Further, the alloy powder was Sn42Bi58 having a melting point of 138 ℃ or Sn96.5Ag3.0Cu0.5 having a melting point of 217 ℃.
Has the advantages that:
the modified rosin used in the invention has good wettability and high activity, and can quickly remove micro oxides on the surface of a large bonding pad and oxides on the surface of tin powder, so that molten solder can be quickly spread on the surface of the bonding pad;
the used organic modified polysiloxane serving as the bubble inhibitor can greatly improve the exhaust efficiency of the molten solder at high temperature, and provides a channel for quickly escaping water vapor generated in the welding process, so that large-area cavities caused by bubble residues are reduced, and the effect is particularly obvious in the welding process of large-area bonding pads.
The solvent adopts phenyl (tetrahydro-2H-pyran-4-yl) methanol, not only has the effect of the solvent, but also has the design of low boiling point, the boiling point temperature is 112-113 degrees, compared with the traditional solvent of tetraethylene glycol dibutyl ether, the boiling point is about 370 degrees, the boiling point is low, so that the solvent can be quickly boiled in the temperature rising process, not only bubbles are broken in the welding process, but also a quick escape channel is formed, and the release efficiency and the effect of gas can be greatly improved.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
Example 1:
a solder paste for improving welding cavities of large-area bonding pads of electronic devices comprises the following raw materials in parts by weight: the soldering flux consists of soldering flux and alloy powder, wherein the alloy powder is 89.5 percent, and the soldering flux is 10.5 percent. Wherein the alloy powder is Sn96.5Ag3.0Cu0.5 with the melting point of 138 ℃ prepared according to the joint industrial standard J-STD-005; the soldering flux consists of the following components: 17% of water white hydrogenated rosin and 19% of acrylic acid rosin; the thixotropic agent is 11% of the stemmed castor oil; the organic acid active agents comprise 3.5 percent of succinic acid and 2.6 percent of malic acid; the surfactant is 5.6 percent of nonylphenol polyoxyethylene ether; 1.5 percent of organic modified polysiloxane; the balance being phenyl (tetrahydro-2H-pyran-4-yl) methanol.
The test performance results are shown in table 1 for example 1.
Example 2
A solder paste for improving welding cavities of large-area bonding pads of electronic devices comprises the following raw materials in parts by weight: the soldering flux consists of soldering flux and alloy powder, wherein the alloy powder is 89.5 percent, and the soldering flux is 10.5 percent. Wherein the alloy powder is Sn96.5Ag3.0Cu0.5 with the melting point of 138 ℃ prepared according to the joint industrial standard J-STD-005; the soldering flux consists of the following components: water white hydrogenated rosin 35%; the thixotropic agent is 16% of high molecular paraffin; the organic acid active agent is 6.5 percent of azelaic acid and 2.6 percent of citric acid; the surfactant is 8% of octyl phenol polyoxyethylene ether; 1% of organic modified polysiloxane; the balance being phenyl (tetrahydro-2H-pyran-4-yl) methanol.
The test performance results are shown in table 1, example 2.
Example 3:
a solder paste for improving welding cavities of large-area bonding pads of electronic devices comprises the following raw materials in parts by weight: the soldering flux consists of 90.5% of soldering flux and 9.5% of alloy powder. Wherein the alloy powder is Sn96.5Ag3.0Cu0.5 with the melting point of 138 ℃ prepared according to the joint industrial standard J-STD-005; the soldering flux consists of the following components: 14% of water-white hydrogenated rosin and 16% of acrylic rosin; the thixotropic agent is 14 percent of the stemmed castor oil; the organic acid active agents comprise 4.5 percent of succinic acid and 3.6 percent of malic acid; the surfactant is 8% of nonylphenol polyoxyethylene ether; the bubble inhibitor is 1.0 percent of organic modified polysiloxane; the balance being tetraethylene glycol dibutyl ether.
The test performance results are shown in table 1, example 3.
Comparative example 1:
the comparative example consists of the following raw materials in weight ratio: the soldering flux consists of soldering flux and alloy powder, wherein the alloy powder is 89.5 percent, and the soldering flux is 10.5 percent. Wherein the alloy powder is Sn96.5Ag3.0Cu0.5 with the melting point of 138 ℃ prepared according to the joint industrial standard J-STD-005; the soldering flux consists of the following components: 17% of water white hydrogenated rosin and 19% of acrylic rosin; the thixotropic agent is 11% of the stemmed castor oil; the organic acid active agents comprise 3.5 percent of succinic acid and 2.6 percent of malic acid; 5.6 percent of nonylphenol polyoxyethylene ether as a surfactant; the balance of organic solvent diethylene glycol octyl ether.
The results of the test properties are shown in table 1 for comparative example 1.
Comparative example 2:
the comparative example consists of the following raw materials in weight ratio: the soldering flux consists of 90.5% of soldering flux and 9.5% of alloy powder. Wherein the alloy powder is Sn96.5Ag3.0Cu0.5 with the melting point of 138 ℃ prepared according to the joint industrial standard J-STD-005; the soldering flux consists of the following components: 14% of water-white hydrogenated rosin and 16% of acrylic rosin; the thixotropic agent is 14 percent of the stemmed castor oil; the organic acid activator is 4.5 percent of succinic acid and 3.6 percent of malic acid; the surfactant is 8% of nonylphenol polyoxyethylene ether; the balance being tetraethylene glycol dibutyl ether.
The test performance results are shown in table 1 for comparative example 2.
Table 1 test performance results
DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION Hole test data
Example 1 11.3%
Example 2 13.6%
Example 3 19.6%
Comparative example 1 33.4%
Comparative example 2 31.7%
As can be seen from table 1, it is,
the use of the bubble inhibitor resulted in a very significant reduction in the number of dissolved voids, and it was found that the inhibitor organomodified polysiloxane indeed improved the venting efficiency of molten solder during high temperature soldering, and ultimately significantly reduced solder voids.
After the new solvent is replaced, the welding cavity is reduced more obviously, so that the generation of the cavity is broken by adding the phenylcarbinol with the low boiling point, the airflow release rate and the release effect are improved, and the welding cavity is reduced greatly finally.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.

Claims (7)

1. The utility model provides an improve empty soldering paste of electron device large tracts of land pad welding, includes alloy powder and scaling powder, and the alloy powder is mixed by one or more than two kinds of tin base alloy powder and is formed, has the alloy powder that the eutectic is constituteed, its characterized in that: the soldering flux consists of the following components in percentage by weight: 22 to 44 percent of modified rosin, 11 to 16 percent of thixotropic agent, 4 to 10 percent of organic acid active agent, 5 to 8 percent of surfactant, 0.5 to 1.5 percent of organic modified polysiloxane and the balance of solvent phenyl (tetrahydro-2H-pyran-4-yl) methanol.
2. The solder paste for improving solder voiding of large area pads of electronic devices as claimed in claim 1, wherein: the soldering paste comprises 88% -92% of alloy powder and 8% -12% of soldering flux.
3. The solder paste for improving void formation in soldering of large area pads of electronic devices as claimed in claim 1, wherein: the modified rosin is at least one of water-white hydrogenated rosin and acrylic acid rosin.
4. The solder paste for improving solder voiding of large area pads of electronic devices as claimed in claim 1, wherein: the thixotropic agent is at least one of the stemmed castor oil, stearic acid, oleamide and high molecular paraffin.
5. The solder paste for improving solder voiding of large area pads of electronic devices as claimed in claim 1, wherein: the organic acid activator is at least one of succinic acid, adipic acid, azelaic acid, glutaric acid, citric acid and malic acid.
6. The solder paste for improving solder voiding of large area pads of electronic devices as claimed in claim 1, wherein: the surfactant is at least one of nonylphenol polyoxyethylene ether, octylphenol polyoxyethylene ether and dodecylphenol polyoxyethylene ether.
7. The solder paste for improving solder voiding of large area pads of electronic devices as claimed in claim 2, wherein: the alloy powder is Sn42Bi58 with a melting point of 138 ℃ or Sn96.5Ag3.0Cu0.5 with a melting point of 217 ℃.
CN202310171228.6A 2023-02-27 2023-02-27 Solder paste for improving welding cavity of large-area bonding pad of electronic device Pending CN115971719A (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102528315A (en) * 2012-01-11 2012-07-04 深圳市唯特偶新材料股份有限公司 Lead-free and cleaning-free solder paste capable of realizing few-cavity welding layers and preparation method of lead-free cleaning-free solder paste
KR101284603B1 (en) * 2012-11-19 2013-07-10 주식회사 에코이앤씨 Method of repairing and reinforcing cross section of concrete structures
CN104668818A (en) * 2015-01-16 2015-06-03 北京鹏瑞中联科技有限公司 Low-voidage soldering paste for packaging semiconductor chip and preparation method of low-voidage soldering paste
CN105073967A (en) * 2013-03-26 2015-11-18 宝洁公司 Cleaning compositions for cleaning a hard surface
CN106624457A (en) * 2016-11-30 2017-05-10 重庆微世特电子材料有限公司 Low-corrosiveness water-based soldering flux composite
CN107498208A (en) * 2017-08-24 2017-12-22 广东中实金属有限公司 A kind of lead-free soldering wire for being applied to drag welding technology
CN109514125A (en) * 2018-12-18 2019-03-26 深圳市唯特偶新材料股份有限公司 A kind of solder(ing) paste
JP2021007963A (en) * 2019-06-28 2021-01-28 株式会社タムラ製作所 Solder composition and electronic circuit mounting substrate
CN112276412A (en) * 2020-10-29 2021-01-29 苏州恩斯泰金属科技有限公司 Laser welding solder paste and preparation method thereof
CN115070260A (en) * 2022-07-02 2022-09-20 宏桥金属制品(昆山)有限公司 High-performance tin soldering rod and preparation method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102528315A (en) * 2012-01-11 2012-07-04 深圳市唯特偶新材料股份有限公司 Lead-free and cleaning-free solder paste capable of realizing few-cavity welding layers and preparation method of lead-free cleaning-free solder paste
KR101284603B1 (en) * 2012-11-19 2013-07-10 주식회사 에코이앤씨 Method of repairing and reinforcing cross section of concrete structures
CN105073967A (en) * 2013-03-26 2015-11-18 宝洁公司 Cleaning compositions for cleaning a hard surface
CN104668818A (en) * 2015-01-16 2015-06-03 北京鹏瑞中联科技有限公司 Low-voidage soldering paste for packaging semiconductor chip and preparation method of low-voidage soldering paste
CN106624457A (en) * 2016-11-30 2017-05-10 重庆微世特电子材料有限公司 Low-corrosiveness water-based soldering flux composite
CN107498208A (en) * 2017-08-24 2017-12-22 广东中实金属有限公司 A kind of lead-free soldering wire for being applied to drag welding technology
CN109514125A (en) * 2018-12-18 2019-03-26 深圳市唯特偶新材料股份有限公司 A kind of solder(ing) paste
JP2021007963A (en) * 2019-06-28 2021-01-28 株式会社タムラ製作所 Solder composition and electronic circuit mounting substrate
CN112276412A (en) * 2020-10-29 2021-01-29 苏州恩斯泰金属科技有限公司 Laser welding solder paste and preparation method thereof
CN115070260A (en) * 2022-07-02 2022-09-20 宏桥金属制品(昆山)有限公司 High-performance tin soldering rod and preparation method thereof

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