CN115341393A - 一种新型纱线防滑脱助剂的制备及其在织物三防整理中应用 - Google Patents
一种新型纱线防滑脱助剂的制备及其在织物三防整理中应用 Download PDFInfo
- Publication number
- CN115341393A CN115341393A CN202210973021.6A CN202210973021A CN115341393A CN 115341393 A CN115341393 A CN 115341393A CN 202210973021 A CN202210973021 A CN 202210973021A CN 115341393 A CN115341393 A CN 115341393A
- Authority
- CN
- China
- Prior art keywords
- slip
- yarn anti
- agent
- yarn
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 46
- 239000012752 auxiliary agent Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims description 19
- 229920005989 resin Polymers 0.000 claims abstract description 35
- 239000011347 resin Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 19
- 239000010703 silicon Substances 0.000 claims abstract description 19
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 239000004902 Softening Agent Substances 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 238000010008 shearing Methods 0.000 claims description 44
- 238000003756 stirring Methods 0.000 claims description 43
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 30
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 23
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 11
- 229920002545 silicone oil Polymers 0.000 claims description 11
- -1 polydimethylsiloxane Polymers 0.000 claims description 10
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 8
- 150000002193 fatty amides Chemical class 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000001804 emulsifying effect Effects 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 229920013822 aminosilicone Polymers 0.000 claims description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003093 cationic surfactant Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 13
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 238000005303 weighing Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000012748 slip agent Substances 0.000 description 7
- 239000013530 defoamer Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 241000907903 Shorea Species 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供了一种新型的纱线防滑脱助剂,其特征在于,由如下重量百分比的组分制造而成:MQ硅树脂15%~25%,柔软剂3%~8%,溶剂5%~10%,表面活性剂3%~6%,酸0.1%~0.3%,消泡剂0.1%~0.3%,去离子水余量。该纱线防滑脱助剂能有效应用于化纤类面料纱线的三防整理。
Description
技术领域
本发明涉及纺织印染后整理加工技术领域,特别涉及一种织物三防配套用防滑移剂乳液的制备及其用途,该防滑移剂乳液适用于化纤类纺织面料的后整理加工。
背景技术
纱线滑脱,也叫纰裂,是指面料经缝合后,由于织物结构疏松或交织助力较弱,缝口受外力的作用后,平行于缝边的纱线(经纱或纬纱)发生移位而产生的纰裂现象。面料纰裂现象直接影响到服装的外观和穿着寿命。服装面料产生纱线滑脱的原因主要有以下几种:
①纤维本身特性的原因,光滑类的无捻长丝面料,由于其本身纤维较光滑,经纬纱间易产生滑动,缝制成衣后,缝口在受纬向拉力时,沿经向的缝隙处易裂开,造成面料纱线滑脱。较为典型的有真丝缎、真丝斜纹绸、电力纺、涤丝纺、尼丝纺、塔夫绸等。
②面料组织疏稀、线材细弱的原因组织紧度稀疏、线材细弱的面料,极易产生纱线滑脱。若衣服的纵向缝口受纬向拉伸时,便会使经纱沿纬向作横向运动。
③面料组织交织点少的原因在面料组织中,经纬纱的交织点越少,经纬纱浮长线就越多越长,面料紧度就越小,缝制成衣后缝口处的面料极易产生纱线滑脱,如各种缎组织的面料。
④面料经纬纱捻向的影响若经纬纱的捻向相反时,两纱线接触面处的纤维几乎成垂直,纤维间不能抱合而易产生滑动。
⑤面料加工处理的影响,某些助剂如柔软剂和织物三防类的助剂,由于这些助剂会改变纱线的动静摩擦系数,纱线间的抱合力变差,从而产生纱线滑脱现象。
目前,市面上比较常用的纱线防滑脱助剂主要为胶质二氧化硅类,由于它能提高纱线的摩擦系数,所以能一定程度改善纱线的滑脱现象。这类防滑脱助剂由于分子量比较小对于防滑移要求不是特别高的化纤类面料能起到一定的效果,而对于高支高密的塔夫绸类的化纤面料或者是春亚纺面料其改善防滑脱的作用并不是特别显著。
织物三防(防水,防油,防污)加工在面料后整理加工中占有比较高的比重,比较常见的三防助剂主要有丙烯酸类,聚氨酯类,石蜡类,硅油类,由于这些结构的助剂的摩擦系数比较低,或多或少都会影响纱线间的交织及抱合力,从而产生滑脱现象;
此外,胶质类二氧化硅的防滑脱助剂和织物三防类的助剂一起使用时,虽然滑脱现象能有一定的改善,但是,由于胶质二氧化硅类的助剂它们不具有防水效果或者是有一定的亲水性,和三防类的助剂一起配套使用有比较大的冲突,而且也会影响面料的手感(手感偏硬),应用受到很大的限制。
发明内容
本发明旨在克服上述缺陷,提出一种新类型的纱线防滑脱助剂的制备,改纱线防滑脱助剂能够显著改善化纤类面料纱线的防滑移效果。
本发明提供的一种新型的纱线防滑脱助剂,其特征在于,由如下重量百分比的组分制造而成:
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述MQ硅树脂的分子式为(R2SiO0.5)m(SiO2)n;
其中,m/n=0.2~4.0;
R相同或不相同,选自烷基或羟基。
MQ硅树脂可以为所示的结构或其类似结构:
式中R全部为甲基或大部分为甲基(少部分为乙基、羟基);
例如:甲基:羟基=1:0.3-0.4;
优选分子量在50000-100000之间的MQ硅树脂中的一种或几种。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述柔软剂选自聚二甲基硅油、氨基硅油、羟基硅油、脂肪酰胺类柔软剂、烷基硅油中的一种或几种的混合。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述表面活性剂选自非离子表面活性剂、阳离子表面活性剂中的一种或几种。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述非离子表面活性剂选自直链烷基聚氧乙烯醚、直链烷基聚氧丙烯聚氧乙烯醚、异构烷基聚氧乙烯醚、异构烷基聚氧丙烯聚氧乙烯醚;
上述阳离子表面活性剂选自脂肪胺聚氧乙烯醚、十八烷基三甲基氯化铵、双十八烷基二甲基氯化铵。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述溶剂选自白油、异戊二醇、丁醇、乙二醇、三丙二醇、二丙二醇、乙二醇丁醚、二丙二醇甲醚中的一种或几种。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述酸选自醋酸、苹果酸、柠檬酸、羟基乙酸中的一种或几种。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:
上述消泡剂选自聚醚类消泡剂、有机硅类消泡剂中的一种或几种。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:其具体制备方法包括如下步骤:
S1.将MQ硅树脂和溶剂混合后,加热搅拌至80℃-100℃,完全溶解至透明状;
S2.加入柔软剂搅拌均匀,降温至40-50℃;
S3.加入表面活性剂,常温搅拌混合0.5-1.5小时;
S4.采用高速剪切机乳化(剪切速率调至20000rpm-30000rpm),边剪切边加入去离子水,每次加水5%-10%直至添加完毕,时间间隔5-10分钟,温度设定为40-50℃;
S5.加入酸,消泡剂混合均匀。
进一步地,本发明提供的一种纱线防滑脱助剂,其特征在于:具有如下用途中的至少一种:
A.应用于织物三防整理;
B.与其他助剂复配后,应用于织物三防整理;
上述其他助剂选自丙烯酸类,聚氨酯类,石蜡类,硅油类三防助剂中的一种或几种;
其中,如权利要求1-8任一上述的一种纱线防滑脱助剂与其他助剂的质量比例为1:0.1-10。
与现有织物防滑脱助剂相比,本发明具有以下优点:
(1)具有很好的防滑脱性。MQ树脂由于分子量大,性质独特,防滑脱性更好
(2)防水效果强。MQ树脂的网状结构和低表面张力赋予织物较强的拒水性能,与织物三防类的防水剂并用时不影响面料的防水效果,同时可以改善面料的防滑脱性能。
(3)手感柔软。MQ树脂和柔软剂的协同作用,在改善面料防滑脱性的同时,也可赋予织物较为柔软的手感风格。
具体实施方式
实施例1:
一种新型纱线防滑脱助剂的制备方法
分别称量15%重量的MQ树脂(分子量约50000),5%重量的乙二醇,混合均匀,加热至80℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的1000粘度的聚二甲基硅油搅拌均匀,降温至40℃。向体系中加入2%重量的十二烷基聚氧乙烯醚,1%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至20000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后加入0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例2:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约50000),8%重量的三丙二醇,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的1000粘度的聚二甲基硅油搅拌均匀,降温至40℃。向体系中加入3%重量的异构十二烷基聚氧乙烯醚,1%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后加入0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例3:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约80000),10%重量的乙二醇,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的1000粘度的聚二甲基硅油搅拌均匀,降温至40℃。向体系中加入3%重量的异构十二烷基聚氧乙烯醚,1%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例4:
一种新型纱线防滑脱助剂的制备方法
分别称量25%重量的MQ树脂(分子量约100000),10%重量的乙二醇,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的1000粘度的聚二甲基硅油搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例5:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约100000),10%重量的乙二醇丁醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的1000粘度的氨基硅油搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例6:
一种新型纱线防滑脱助剂的制备方法
分别称量25%重量的MQ树脂(分子量约50000),6%重量的乙二醇丁醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入5%重量的1000粘度的氨基硅油搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例7:
一种新型纱线防滑脱助剂的制备方法
分别称量15%重量的MQ树脂(分子量约50000),5%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的脂肪酰胺类柔软剂搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至20000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为40℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例8:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约80000),8%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入5%重量的脂肪酰胺类柔软剂搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至20000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例9:
一种新型纱线防滑脱助剂的制备方法
分别称量25%重量的MQ树脂(分子量约100000),10%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入8%重量的脂肪酰胺类柔软剂搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至20000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例10:
一种新型纱线防滑脱助剂的制备方法
分别称量15%重量的MQ树脂(分子量约50000),10%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的脂肪酰胺类柔软剂,5%重量的烷基硅油搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例11:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约80000),8%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入2%重量的脂肪酰胺类柔软剂,4%重量的烷基硅油搅拌均匀,降温至40℃。向体系中加入3%重量的异构十二烷基聚氧乙烯醚,1%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例12:
一种新型纱线防滑脱助剂的制备方法
分别称量25%重量的MQ树脂(分子量约100000),10%重量的二丙二醇甲醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量的脂肪酰胺类柔软剂,3%重量的烷基硅油搅拌均匀,降温至40℃。向体系中加入3%重量的异构十二烷基聚氧乙烯醚,1%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后0.3%醋酸和0.1%硅系消泡剂,搅拌混合均匀。
实施例13:
一种新型纱线防滑脱助剂的制备方法
分别称量20%重量的MQ树脂(分子量约50000),10%重量的乙二醇丁醚,混合均匀,加热至90℃,搅拌1小时,至MQ树脂完全溶解呈透明液体。加入3%重量1000粘度的聚二甲基硅油,3%重量1000粘度的氨基硅油搅拌均匀,降温至40℃。向体系中加入4%重量的异构十二烷基聚氧乙烯醚,2%重量的十八烷基三甲基氯化铵,常温搅拌混合均匀1小时。对该组分采用高速剪切机乳化,剪切速率调至30000rpm,边剪切边加入去离子水,每次加水5%,时间间隔5分钟,温度设定为50℃摄氏度。最后加入0.3%苹果酸和0.1%聚醚类消泡剂,搅拌混合均匀。
实施例14:性能测试
1.接缝滑移测试:GB/T 13772.1,经纱和纬纱各测试三成取平均值
2.防水性测试:AATCC-22
3.手感测试:触感评价面料的柔软程度
测试表1:
由测试表格1可以看出本发明制备的防滑移剂比胶质硅酸类的防滑移剂的防滑脱性要好,而且加工完的面料具有较强的防水效果,手感也比较柔软,应用的范围也比较广泛,单独使用时可以做为防滑移剂用,也可做为无氟类的防水剂,可以兼顾防水、手感和防滑脱性。
测试表2:
由测试表格2可以看出本单独的丙烯酸类的无氟防水剂加工处理后的210T涤塔夫面料,其缝目滑脱性变差;胶质硅酸类的防滑移剂能再一定程度上改善其防滑移性,但是对面料的防水性能影响很大,不适应于织物三防类的加工处理;本发明的新型防滑移剂和丙烯酸系的无氟防水剂一起使用时,面料的防滑性能不单有比较好的改善,而且不影响面料的防水性能,同时面料的手感也在一定程度上有改善。
Claims (10)
2.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述MQ硅树脂的分子式为(R2SiO0.5)m(SiO2)n;
其中,m/n=0.2~4.0;
R相同或不相同,选自烷基或羟基。
3.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述柔软剂选自聚二甲基硅油、氨基硅油、羟基硅油、脂肪酰胺类柔软剂、烷基硅油中的一种或几种的混合。
4.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述表面活性剂选自非离子表面活性剂、阳离子表面活性剂中的一种或几种。
5.如权利要求4所述的一种纱线防滑脱助剂,其特征在于:
所述非离子表面活性剂选自直链烷基聚氧乙烯醚、直链烷基聚氧丙烯聚氧乙烯醚、异构烷基聚氧乙烯醚、异构烷基聚氧丙烯聚氧乙烯醚;
所述阳离子表面活性剂选自脂肪胺聚氧乙烯醚、十八烷基三甲基氯化铵、双十八烷基二甲基氯化铵。
6.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述溶剂选自白油、异戊二醇、丁醇、乙二醇、三丙二醇、二丙二醇、乙二醇丁醚、二丙二醇甲醚中的一种或几种。
7.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述酸选自醋酸、苹果酸、柠檬酸、羟基乙酸中的一种或几种。
8.如权利要求1所述的一种纱线防滑脱助剂,其特征在于:
所述消泡剂选自聚醚类消泡剂、有机硅类消泡剂中的一种或几种。
9.如权利要求1-8任一所述的一种纱线防滑脱助剂,其特征在于,其具体制备方法包括如下步骤:
S1.将MQ硅树脂和溶剂混合后,加热搅拌至80℃-100℃,完全溶解至透明状;
S2.加入柔软剂搅拌均匀,降温至40-50℃;
S3.加入表面活性剂,常温搅拌混合0.5-1.5小时;
S4.采用高速剪切机乳化,边剪切边加入去离子水,每次加水5%-10%,时间间隔5-10分钟,温度设定为40-50℃;
S5.加入酸,消泡剂混合均匀。
10.如权利要求1-8任一所述的一种纱线防滑脱助剂,其特征在于,具有如下用途中的至少一种:
A.应用于织物三防整理;
B.与其他助剂复配后,应用于织物三防整理;
所述其他助剂选自丙烯酸类,聚氨酯类,石蜡类,硅油类三防助剂中的一种或几种;
其中,如权利要求1-8任一所述的一种纱线防滑脱助剂与其他助剂的质量比例为1:0.1-10。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210973021.6A CN115341393B (zh) | 2022-08-15 | 2022-08-15 | 一种纱线防滑脱助剂的制备及其在织物三防整理中应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210973021.6A CN115341393B (zh) | 2022-08-15 | 2022-08-15 | 一种纱线防滑脱助剂的制备及其在织物三防整理中应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN115341393A true CN115341393A (zh) | 2022-11-15 |
CN115341393B CN115341393B (zh) | 2024-04-09 |
Family
ID=83951401
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210973021.6A Active CN115341393B (zh) | 2022-08-15 | 2022-08-15 | 一种纱线防滑脱助剂的制备及其在织物三防整理中应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN115341393B (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011052366A (ja) * | 2009-08-03 | 2011-03-17 | Matsumoto Yushi Seiyaku Co Ltd | 精練剤組成物および精練処理済み布帛の製造方法 |
CN107385928A (zh) * | 2017-08-04 | 2017-11-24 | 青岛惠陆有机硅有限公司 | 一种防水透气新材料 |
CN110628326A (zh) * | 2019-10-25 | 2019-12-31 | 广州玖盈化工材料有限公司 | 一种环保型有机硅三防涂料及其制备方法 |
CN112608676A (zh) * | 2020-12-01 | 2021-04-06 | 中科院广州化学有限公司 | 一种纳米银掺杂硅树脂基抗菌防污剂及其制备方法与应用 |
CN113668251A (zh) * | 2021-09-17 | 2021-11-19 | 苏州同构科技有限公司 | 一种军用纺织面料专用防水剂及制备方法 |
-
2022
- 2022-08-15 CN CN202210973021.6A patent/CN115341393B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011052366A (ja) * | 2009-08-03 | 2011-03-17 | Matsumoto Yushi Seiyaku Co Ltd | 精練剤組成物および精練処理済み布帛の製造方法 |
CN107385928A (zh) * | 2017-08-04 | 2017-11-24 | 青岛惠陆有机硅有限公司 | 一种防水透气新材料 |
CN110628326A (zh) * | 2019-10-25 | 2019-12-31 | 广州玖盈化工材料有限公司 | 一种环保型有机硅三防涂料及其制备方法 |
CN112608676A (zh) * | 2020-12-01 | 2021-04-06 | 中科院广州化学有限公司 | 一种纳米银掺杂硅树脂基抗菌防污剂及其制备方法与应用 |
CN113668251A (zh) * | 2021-09-17 | 2021-11-19 | 苏州同构科技有限公司 | 一种军用纺织面料专用防水剂及制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN115341393B (zh) | 2024-04-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0342834B1 (en) | Treatment of fibrous materials | |
US4207071A (en) | Durable modification of fibrous substrates using a polyoxyethylene-containing silane and articles therefrom | |
CN109487560B (zh) | 复合蜡微乳液组合物及其制备方法和应用 | |
CA2004622C (en) | Fiber treatment agent composition | |
WO2019110960A1 (en) | Improvements relating to crease recovery in textiles | |
US4848981A (en) | Method of improving the draining of water from textiles during a laundering operation | |
EP1753906B9 (en) | Textile treatments using fluoropolymer-branched silicone polyethers | |
US6649692B2 (en) | Organopolysiloxane composition, emulsion-forming concentrates and aqueous emulsions formed therefrom and use of the emulsions in the treatment of textiles | |
JP4925622B2 (ja) | シリコーン系柔軟仕上剤 | |
US4810253A (en) | Method of improving the draining of water from textiles during a laundering operation | |
EP1401920A1 (en) | Modified polyorganosiloxanes, aqueous emulsions thereof, their production and their use | |
CN111877020B (zh) | 一种改性硅油柔软剂及其制备方法 | |
EP3724284A1 (de) | Silicon-copolymere, deren herstellung und deren verwendung zur behandlung von faserigen substraten | |
CN116043547A (zh) | 一种丙烯酸酯类无氟防水剂及其应用 | |
CN116876120A (zh) | 一种干法氨纶经编专用的纺丝油剂 | |
JP2017197863A (ja) | 皮膜形成性シリコーンエマルション組成物 | |
CN115341393A (zh) | 一种新型纱线防滑脱助剂的制备及其在织物三防整理中应用 | |
DE10259291B4 (de) | Hochkonzentrierte, selbstemulgierende Zubereitungen, enthaltend Organopolysiloxane und Alkylammoniumverbindungen und deren Verwendung in wässrigen Systemen | |
CN107761397A (zh) | 一种抑黄变助剂及其制备方法 | |
US7632910B2 (en) | Polysiloxane and textile auxiliary containing a polysiloxane | |
US20020175310A1 (en) | Process for treating organic fibers | |
US6815493B2 (en) | Mixtures of polysiloxane emulsions | |
Czech et al. | Modified Silicone Softeners for Fluorocarbon Soil Release Treatments. | |
JPH0122390B2 (zh) | ||
CN111441175A (zh) | 一种氨基硅油乳液及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |