CN115223874A - Semiconductor structure and method of making the same - Google Patents
Semiconductor structure and method of making the same Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 238000002955 isolation Methods 0.000 claims abstract description 30
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- 238000005530 etching Methods 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 41
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 16
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical group N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 8
- 238000005137 deposition process Methods 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000011049 filling Methods 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 11
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 238000000151 deposition Methods 0.000 description 7
- 230000008021 deposition Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 150000004767 nitrides Chemical class 0.000 description 5
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 5
- 229920005591 polysilicon Polymers 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 239000011810 insulating material Substances 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 3
- 238000000206 photolithography Methods 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 238000004528 spin coating Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 229910002601 GaN Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
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- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/018—Spacers formed inside holes at the prospective gate locations, e.g. holes left by removing dummy gates
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/10—Shapes, relative sizes or dispositions of the regions of the semiconductor bodies; Shapes of the semiconductor bodies
- H10D62/113—Isolations within a component, i.e. internal isolations
- H10D62/115—Dielectric isolations, e.g. air gaps
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/01—Manufacture or treatment
- H10D64/021—Manufacture or treatment using multiple gate spacer layers, e.g. bilayered sidewall spacers
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Abstract
该发明公开了一种半导体结构及其制备方法,所述制备方法包括提供衬底,在衬底内形成隔离结构以及有源区;形成隔离结构的步骤包括:在衬底内形成凹槽;形成第一绝缘层,第一绝缘层位于凹槽的底部和侧壁;形成第二绝缘层,第二绝缘层位于第一绝缘层表面,其中,去除部分第二绝缘层,使得第二绝缘层的顶表面低于第一绝缘层的顶表面;形成第三绝缘层,第三绝缘层部分覆盖第二绝缘层,第一绝缘层、第二绝缘层和第三绝缘层填充凹槽;形成介质层,介质层覆盖第一绝缘层、第二绝缘层和第三绝缘层表面以及有源区且填充满去除部分第二绝缘层形成的凹陷。所述制备方法能够避免在隔离结构和有源区之间形成凹陷处形成残留物而影响半导体结构的性能。
The invention discloses a semiconductor structure and a preparation method thereof. The preparation method includes providing a substrate, and forming an isolation structure and an active region in the substrate; the steps of forming the isolation structure include: forming a groove in the substrate; forming A first insulating layer, the first insulating layer is located on the bottom and sidewalls of the groove; a second insulating layer is formed, and the second insulating layer is located on the surface of the first insulating layer, wherein part of the second insulating layer is removed, so that the second insulating layer is The top surface is lower than the top surface of the first insulating layer; a third insulating layer is formed, the third insulating layer partially covers the second insulating layer, and the first insulating layer, the second insulating layer and the third insulating layer fill the groove; forming a dielectric layer , the dielectric layer covers the surfaces of the first insulating layer, the second insulating layer and the third insulating layer, as well as the active region, and fills the recess formed by removing part of the second insulating layer. The preparation method can avoid the formation of residues at the recess formed between the isolation structure and the active region, thereby affecting the performance of the semiconductor structure.
Description
技术领域technical field
本发明涉及半导体技术领域,具体涉及一种半导体结构及其制备方法。The invention relates to the technical field of semiconductors, in particular to a semiconductor structure and a preparation method thereof.
背景技术Background technique
相关技术的半导体结构在制备过程中,有源区之间形成有隔离区,所述隔离区由于绝缘层材料不同,刻蚀效率存在差异,在后续执行刻蚀工艺时,有源区表面的绝缘层被刻蚀而容易在有源区和邻近的绝缘层之间形成凹槽,在后续沉积形成栅极结构时,在凹槽内容易形成难以去除的残留物而影响器件性能。During the preparation process of the semiconductor structure of the related art, an isolation region is formed between the active regions. Due to the different materials of the insulating layer, the etching efficiency of the isolation region is different. During the subsequent etching process, the insulation on the surface of the active region is The layer is etched to easily form a groove between the active region and the adjacent insulating layer. When the gate structure is formed by subsequent deposition, residues that are difficult to remove are easily formed in the groove and affect device performance.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种半导体结构的制备方法,所述制备方法能够避免在隔离结构和有源区之间形成凹陷,进而防止在凹陷处形成残留物而影响半导体结构的性能。An object of the present invention is to provide a method for preparing a semiconductor structure, which can avoid forming a recess between the isolation structure and the active region, thereby preventing residues from being formed in the recess and affecting the performance of the semiconductor structure.
根据本发明实施例半导体结构的制备方法,包括:提供衬底,在所述衬底内形成隔离结构以及有源区;形成所述隔离结构的步骤包括:在衬底内形成凹槽;形成第一绝缘层,所述第一绝缘层位于所述凹槽的底部和侧壁;形成第二绝缘层,所述第二绝缘层位于所述第一绝缘层表面,其中,去除部分所述第二绝缘层,使得所述第二绝缘层的顶表面低于所述第一绝缘层的顶表面;形成第三绝缘层,所述第三绝缘层部分覆盖所述第二绝缘层,所述第一绝缘层、所述第二绝缘层和所述第三绝缘层填充所述凹槽;形成介质层,所述介质层覆盖所述第一绝缘层、第二绝缘层和第三绝缘层表面以及所述有源区且填充满去除部分所述第二绝缘层形成的凹陷。A method for fabricating a semiconductor structure according to an embodiment of the present invention includes: providing a substrate, and forming an isolation structure and an active region in the substrate; the step of forming the isolation structure includes: forming a groove in the substrate; forming a first an insulating layer, the first insulating layer is located on the bottom and sidewalls of the groove; a second insulating layer is formed, the second insulating layer is located on the surface of the first insulating layer, wherein a part of the second insulating layer is removed insulating layer, so that the top surface of the second insulating layer is lower than the top surface of the first insulating layer; forming a third insulating layer, the third insulating layer partially covers the second insulating layer, the first insulating layer The insulating layer, the second insulating layer and the third insulating layer fill the groove; a dielectric layer is formed, and the dielectric layer covers the surfaces of the first insulating layer, the second insulating layer and the third insulating layer and all the The active region is filled with the recess formed by removing part of the second insulating layer.
根据本发明的一些实施例,去除所述部分第二绝缘层的步骤包括:在所述衬底表面形成暴露所述第二绝缘层的掩膜层,刻蚀去除部分所述第一绝缘层和所述第二绝缘层。According to some embodiments of the present invention, the step of removing the part of the second insulating layer includes: forming a mask layer on the surface of the substrate exposing the second insulating layer, etching and removing part of the first insulating layer and the second insulating layer.
根据本发明的一些实施例,在去除部分所述第一绝缘层和所述第二绝缘层的步骤中,同时对所述第一绝缘层和所述第二绝缘层进行刻蚀,所述第一绝缘层和所述第二绝缘层的刻蚀速率不同。According to some embodiments of the present invention, in the step of removing part of the first insulating layer and the second insulating layer, the first insulating layer and the second insulating layer are simultaneously etched, and the first insulating layer and the second insulating layer are etched simultaneously. The etching rates of an insulating layer and the second insulating layer are different.
根据本发明的一些实施例,在去除部分所述第一绝缘层和所述第二绝缘层的步骤中,所述第二绝缘层的刻蚀速率大于第一绝缘层的刻蚀速率。According to some embodiments of the present invention, in the step of removing part of the first insulating layer and the second insulating layer, the etching rate of the second insulating layer is greater than the etching rate of the first insulating layer.
根据本发明的一些实施例,所述第二绝缘层刻蚀深度为18-20nm。According to some embodiments of the present invention, the etching depth of the second insulating layer is 18-20 nm.
根据本发明的一些实施例,所述掩膜层的厚度为350nm-500nm,套刻精度为0-8nm。According to some embodiments of the present invention, the thickness of the mask layer is 350nm-500nm, and the overlay accuracy is 0-8nm.
根据本发明的一些实施例,采用热氧化工艺形成所述第一绝缘层,所述第一绝缘层为氧化硅。According to some embodiments of the present invention, the first insulating layer is formed by a thermal oxidation process, and the first insulating layer is silicon oxide.
根据本发明的一些实施例,采用沉积工艺形成所述第二绝缘层,所述第二绝缘层为氮化硅。According to some embodiments of the present invention, the second insulating layer is formed by a deposition process, and the second insulating layer is silicon nitride.
根据本发明的一些实施例,在形成所述介质层后,对所述介质层进行减薄,并暴露所述有源区表面。According to some embodiments of the present invention, after the dielectric layer is formed, the dielectric layer is thinned to expose the surface of the active region.
根据本发明的一些实施例,所述第二绝缘层的顶表面与所述第一绝缘层的顶表面距离差为5nm-10nm。According to some embodiments of the present invention, the distance difference between the top surface of the second insulating layer and the top surface of the first insulating layer is 5 nm-10 nm.
根据本发明的一些实施例,所述第二绝缘层厚度为20nm-100nm。According to some embodiments of the present invention, the thickness of the second insulating layer is 20 nm-100 nm.
根据本发明的一些实施例,所述第二绝缘层厚度为20nm-50nm。According to some embodiments of the present invention, the thickness of the second insulating layer is 20 nm-50 nm.
本发明还提出了一种半导体结构。The present invention also provides a semiconductor structure.
根据本发明实施例的半导体结构可以包括:衬底,所述衬底内形成隔离结构、凹槽以及有源区;所述隔离结构包括第一绝缘层、第二绝缘层和第三绝缘层以及介质层,所述绝缘层位于所述凹槽的底部和侧壁,所述第二绝缘层位于所述第一绝缘层表面,其中所述第二绝缘层的顶表面低于所述第一绝缘层的顶表面,所述第三绝缘层位于所述第二绝缘层表面,所述第一绝缘层、所述第二绝缘层和所述第三绝缘层填充所述凹槽,所述介质层覆盖所述第一绝缘层、第二绝缘层和第三绝缘层表面以及所述有源区。A semiconductor structure according to an embodiment of the present invention may include: a substrate in which an isolation structure, a groove, and an active region are formed; the isolation structure includes a first insulating layer, a second insulating layer, and a third insulating layer, and a dielectric layer, the insulating layer is located on the bottom and sidewalls of the groove, the second insulating layer is located on the surface of the first insulating layer, wherein the top surface of the second insulating layer is lower than the first insulating layer the top surface of the layer, the third insulating layer is located on the surface of the second insulating layer, the first insulating layer, the second insulating layer and the third insulating layer fill the groove, the dielectric layer covering the surfaces of the first insulating layer, the second insulating layer and the third insulating layer and the active region.
根据本发明的一些实施例,所述第二绝缘层的上表面到有源区的上表面的高度差为18-20nm。According to some embodiments of the present invention, the height difference from the upper surface of the second insulating layer to the upper surface of the active region is 18-20 nm.
根据本发明的一些实施例,所述半导体结构还包括栅极结构,所述栅极结构形成在所述有源区上。According to some embodiments of the present invention, the semiconductor structure further includes a gate structure formed on the active region.
根据本发明的一些实施例,所述第三绝缘层不覆盖所述第二绝缘层的顶表面。According to some embodiments of the present invention, the third insulating layer does not cover the top surface of the second insulating layer.
根据本发明实施例的半导体结构及其制备方法,通过去除部分第二绝缘层,使得第二绝缘层的顶表面低于第一绝缘层的顶表面,并形成介质层填充第二绝缘层被去除部分后的凹陷,在后续进行刻蚀时,即使对介质层进行过刻蚀,由于第二绝缘层顶表面高度低于第一绝缘层的顶表面,从而能够避免过刻蚀导致在第二绝缘层和有源区之间形成凹陷而影响半导体结构的性能,而且现有技术中,由于第一绝缘层被过刻蚀,导致第二绝缘层和有源区之间存在凹陷,由于刻蚀特性,凹陷会导致第二绝缘层和有源区之间的第一绝缘层被进一步过刻蚀,因此通过防止在第二绝缘层和有源区之间形成凹陷,也能够进一步地减小后续工艺中隔离结构尤其是第一绝缘层的刻蚀。According to the semiconductor structure and the manufacturing method thereof according to the embodiments of the present invention, by removing part of the second insulating layer, the top surface of the second insulating layer is lower than the top surface of the first insulating layer, and a dielectric layer is formed to fill the second insulating layer and the second insulating layer is removed. After part of the recess, in the subsequent etching, even if the dielectric layer is over-etched, because the height of the top surface of the second insulating layer is lower than that of the first insulating layer, it can avoid over-etching and cause damage to the second insulating layer. A recess is formed between the layer and the active region, which affects the performance of the semiconductor structure, and in the prior art, since the first insulating layer is over-etched, there is a recess between the second insulating layer and the active region. , the recess will cause the first insulating layer between the second insulating layer and the active region to be further over-etched, so by preventing the formation of the recess between the second insulating layer and the active region, the subsequent process can also be further reduced The middle isolation structure, especially the etching of the first insulating layer.
附图说明Description of drawings
图1-图10为根据本发明实施例的半导体结构的制备方法的各步骤的剖视图。1-10 are cross-sectional views of steps of a method for fabricating a semiconductor structure according to an embodiment of the present invention.
附图标记:Reference number:
100:半导体结构;100: semiconductor structure;
1:衬底,11:有源区,12:掩膜层;1: substrate, 11: active region, 12: mask layer;
2:隔离结构,21:第一绝缘层,22:第二绝缘层,23:第三绝缘层,24:介质层,25:凹陷;2: isolation structure, 21: first insulating layer, 22: second insulating layer, 23: third insulating layer, 24: dielectric layer, 25: recess;
3:栅极结构,31:多晶硅层,32:金属栅极,33:金属材料层,34:金属氮化物层;3: gate structure, 31: polysilicon layer, 32: metal gate, 33: metal material layer, 34: metal nitride layer;
4:栅极掩膜层,41:氮化硅层,42:旋涂掩膜层,43:氮氧化物层;4: gate mask layer, 41: silicon nitride layer, 42: spin coating mask layer, 43: oxynitride layer;
5:光刻胶图案;5: photoresist pattern;
61:栅极结构侧部的侧墙氮化硅层,62:侧墙氧化硅层。61: the sidewall silicon nitride layer on the side of the gate structure, 62: the sidewall silicon oxide layer.
具体实施方式Detailed ways
以下结合附图和具体实施方式对本发明提出的一种半导体结构100及其制备方法作进一步详细说明。A
下面参考附图描述根据本发明实施例的半导体结构100及其制备方法。The
如图1-图10所示,根据本发明实施例的半导体结构100的制备方法可以包括:提供衬底1,在所述衬底1内形成隔离结构2以及有源区11;形成所述隔离结构2的步骤包括:在衬底1内形成凹槽;形成第一绝缘层21,所述第一绝缘层21位于所述凹槽的底部和侧壁;形成第二绝缘层22,所述第二绝缘层22位于所述第一绝缘层21表面,其中,去除部分所述第二绝缘层22,使得所述第二绝缘层22的顶表面低于所述第一绝缘层21的顶表面;形成第三绝缘层23,所述第三绝缘层23部分覆盖所述第二绝缘层22,所述第一绝缘层21、所述第二绝缘层22和所述第三绝缘层23填充所述凹槽;形成介质层4,所述介质层4覆盖所述第一绝缘层21、第二绝缘层22和第三绝缘层23表面以及所述有源区11且填充满去除部分所述第二绝缘层22形成的凹陷25。As shown in FIG. 1 to FIG. 10 , a method for fabricating a
具体地,在提供衬底1的步骤中,所述衬底1可以是但不限于硅衬底,本具体实施方式以所述衬底1为硅衬底为例进行说明。在其他示例中,所述衬底1可以为氮化镓、砷化镓、碳化镓、碳化硅或SOI等半导体衬底。所述衬底1用于支撑在其上方的所述器件结构。所述衬底1的顶表面是指所述衬底1朝向所述器件结构的表面。Specifically, in the step of providing the
结合图1-图7所示,在所述衬底1内形成隔离结构2以及有源区11,具体地,有源区11可通过刻蚀衬底1形成,通过对衬底1进行刻蚀可形成多个有源区11,多个有源区11呈阵列分布,所述有源区11上可用于形成器件结构,所述隔离结构2包围有源区11。1-7, the
结合图1-图7所示,形成隔离结构2的步骤可以包括以下步骤:1-7, the step of forming the
在衬底1内形成凹槽,具体地,可通过光刻工艺对衬底1进行光刻以形成凹槽,通过凹槽可将衬底1分割为多个有源区11,隔离结构2可形成在凹槽内,以形成在有源区11之间起到隔离作用。Forming grooves in the
如图1所示,形成第一绝缘层21,第一绝缘层21位于凹槽的底部和侧壁,具体地可采用化学气相沉积法、物理气相沉积法以及原子层沉积法中的至少一种沉积形成第一绝缘层21,第一绝缘层21覆盖凹槽的内壁面,具体来说,在形成凹槽后,可在凹槽的内壁面(即凹槽的底部和侧壁)以及有源区11的表面沉积绝缘材料,然后去除位于有源区11表面的绝缘材料,仅保留位于凹槽内的绝缘材料以形成第一绝缘层21。可选地,可采用化学机械研磨工艺去除位于有源表面的绝缘材料,第一绝缘层21的顶表面可与有源区11的顶表面平齐。As shown in FIG. 1 , a first
于第一绝缘层21表面形成第二绝缘层22,第二绝缘层22的材料与第一绝缘层21不同,即第一绝缘层21和第二绝缘层22具有一定的选择刻蚀比,在相同的刻蚀条件下,第一绝缘层21和第二绝缘层22的刻蚀速率不同。A second
形成第三绝缘层23,第三绝缘层23位于第二绝缘层22表面,第一绝缘层21、第二绝缘层22和第三绝缘层23可以填充凹槽,其中第三绝缘层23覆盖第二绝缘层22的底部和侧壁。第三绝缘层23、第一绝缘层21和第二绝缘层22共同填充凹槽,可以理解的是,隔离结构2也可以形成为包括更多绝缘层的叠层结构,(例如ONO叠层结构,即氧化层与氮化层交替的结构如氧化层-氮化层-氧化层),本发明可不做特殊限定,本发明实施例中以第一绝缘层21、第二绝缘层22以及第三绝缘层23填充凹槽为例进行描述。可选地,第三绝缘层23的材料可与第一绝缘层21相同,例如第一绝缘层21和第三绝缘层23均可以为氧化硅层。The third insulating
如图2-图4所示,去除部分第二绝缘层22,使得第二绝缘层22的顶表面低于第一绝缘层21的顶表面,从而可防止第一绝缘层21被过度刻蚀而在有源区11和第二绝缘层22之间形成凹陷。在此步骤中可采用湿法刻蚀或干法刻蚀对第二绝缘层22进行刻蚀以去除部分第二绝缘层22,进一步地,被去除的第二绝缘层22的高度不低于后续刻蚀工艺中第一绝缘层21被过度刻蚀的高度。As shown in FIG. 2-FIG. 4, part of the second insulating
如图5所示,形成介质层4,所述介质层4覆盖所述第一绝缘层21、第二绝缘层22和第三绝缘层23表面以及所述有源区11且填充满去除部分所述第二绝缘层22形成的凹陷25。换言之,所述介质层4覆盖第一绝缘层21、第二绝缘层22、第三绝缘层23以及有源区11的顶表面,并填充去除部分第二绝缘层22后在第三绝缘层23和第一绝缘层21之间形成的凹陷25,从而形成隔离结构2,这样,在后续进行刻蚀时,即使对介质层4进行过刻蚀,由于第二绝缘层22顶表面高度低于第一绝缘层21的顶表面,从而能够避免过刻蚀导致在第二绝缘层22和有源区11之间形成凹陷25而影响半导体结构100的性能,而且现有技术中,由于第一绝缘层21被过度刻蚀,导致第二绝缘层22和有源区11之间存在凹陷,由于刻蚀特性,凹陷会导致第二绝缘层22和有源区11之间的第一绝缘层21被进一步过刻蚀,因此通过防止在第二绝缘层22和有源区11之间形成凹陷,也能够进一步地减小后续工艺中隔离结构2尤其是第一绝缘层21的刻蚀。As shown in FIG. 5 , a dielectric layer 4 is formed, the dielectric layer 4 covers the surfaces of the first insulating
在本发明的一些实施例中,如图2所示,去除部分所述第二绝缘层22的步骤可以包括:在衬底1表面形成暴露第二绝缘层22的掩膜层12,刻蚀去除部分第二绝缘层22,其中掩膜层12可以覆盖有源区11的表面和部分隔离结构2的表面,可仅暴露第二绝缘层22的表面,以便于对第二绝缘层22进行刻蚀。可选地,在此步骤中,可同时可刻蚀去除部分第一绝缘层21,具体地,掩膜层12可暴露第二绝缘层22和邻近第二绝缘层22的部分第一绝缘层21,在对第二绝缘层22进行刻蚀时可同时刻蚀去除部分与第二绝缘层22邻近的部分第一绝缘层21,从而使得第二绝缘层22能够被刻蚀干净,避免在第一绝缘层21上部侧壁具有部分第二绝缘层22残留。而且第二绝缘层22的厚度较小,通过同时刻蚀部分第一绝缘层21和第二绝缘层22也有利于掩膜层12的形成和光刻套准。其中在去除部分所述第二绝缘层22后可去除掩膜层12。In some embodiments of the present invention, as shown in FIG. 2 , the step of removing part of the second insulating
在本发明的一些实施例中,第一绝缘层21、第三绝缘层23和介质层4可以为相同材料,例如第一绝缘层21、第三绝缘层23和介质层4均可以为氧化硅层,在去除部分第二绝缘层22的步骤中,掩膜层12可覆盖有源区11,同时刻蚀去除部分第一绝缘层21、第二绝缘层22和第三绝缘层23,其中第二绝缘层22刻蚀深度大于第一绝缘层21和第三绝缘层23的刻蚀深度,使得第二绝缘层22的顶表面低于第一绝缘层21的顶表面和第三绝缘层23的顶表面,然后形成介质层4,介质层4可填充被去除的部分第二绝缘层22形成的凹陷25,同时介质层4覆盖第一绝缘层21和第三绝缘层23,由于介质层4与第一绝缘层21与第三绝缘层23的材料相同,因此在刻蚀第二绝缘层22的步骤中,掩膜层12可仅覆盖有源区11即可,后续形成介质层4可填充第一绝缘层21和第三绝缘被刻蚀的部分。In some embodiments of the present invention, the first insulating
在本发明的一些示例中,所述掩膜层12可以为光刻胶层,即可在衬底1表面直接形成暴露第二绝缘层22的光刻胶层,执行光刻工艺以去除部分第二绝缘层22,工艺简单且刻蚀精准。In some examples of the present invention, the
在本发明的一些实施例中,所述掩膜层12的厚度可以为350nm-500nm,例如所述掩膜层12的厚度350nm、400nm、450nm或500nm,套刻精度可以为0-8nm,进一步地,套刻精度可以为0-4nm。In some embodiments of the present invention, the thickness of the
在本发明的一些实施例中,在去除部分第一绝缘层21和第二绝缘层22的工艺中,可同时对第一绝缘层21和第二绝缘层22进行刻蚀,第一绝缘层21和第二绝缘层22刻蚀速率不同,即第一绝缘层21和第二绝缘层22在同等刻蚀条件下,刻蚀速率不同,例如第一绝缘层21和第二绝缘层22可具有高选择刻蚀比。可选地,第二绝缘层22的刻蚀速率大于第一绝缘层21的刻蚀速率,由此,在刻蚀过程中,从而能够保证刻蚀后第二绝缘层22的顶表面的低于第一绝缘层21的顶表面,第二绝缘层22的顶表面低于有源区11的顶表面,从而能够避免在有源区11上部的侧部形成凹陷而影响后续其它工艺的执行。In some embodiments of the present invention, in the process of removing part of the first insulating
在本发明的一些实施例中,第一绝缘层21可以为氧化硅,第二绝缘层22可以为氮化硅或氮氧化硅,可选地,第一绝缘层21可采用热氧化工艺形成,例如可对有源区11的侧壁和底部进行热氧化工艺以形成第一绝缘层21,当然可以理解的是,可以直接采用沉积工艺在有源区11的侧壁和底部形成第一绝缘层21。在一些具体示例中,第二绝缘层22可以为氮化硅,所述第二绝缘层22可采用沉积工艺形成,例如第二绝缘层22可采用化学气相沉积法、物理气相沉积法以及原子层沉积法中的一种工艺沉积形成。In some embodiments of the present invention, the first insulating
在本发明的一些实施例中,所述第二绝缘层22刻蚀深度为18-20nm,也就是说,第二绝缘层22被去除的部分的高度为18-20nm,从而可防止第二绝缘层22被刻蚀过多而影响绝缘效果,也可减小由于过刻蚀而导致刻蚀难度增加,进一步地也可避免刻蚀深度过小,导致后续第一绝缘层21被过度刻蚀深度大于第二绝缘层22刻蚀深度而在第二绝缘层22和有源区11之间形成凹陷,需要说明的是,这里的深度以及高度指的是沿衬底1厚度方向的深度以及高度,即附图3的上下方向的高度和深度。进一步地,所述第二绝缘层22的深度可以为18nm、18.5nm、19nm、19.5或20nm。In some embodiments of the present invention, the etching depth of the second insulating
在本发明的一些实施例中,如图5-图6所示,在形成所述介质层4后,可对所述介质层4进行减薄,并暴露所述有源区11表面,以有利于栅极结构3的形成,具体地,为了使得沉积形成的介质层4能够填充第二绝缘层22被部分去除后形成的凹陷,介质层4需要沉积足够的厚度以填充所述凹陷25,这样导致沉积的介质层4位于衬底1上的厚度较大,需要对其进行减薄以保证形成的半导体结构100的性能。In some embodiments of the present invention, as shown in FIGS. 5-6 , after the dielectric layer 4 is formed, the dielectric layer 4 may be thinned, and the surface of the
在本发明的一些具体示例中,所述介质层4的沉积厚度可以为90nm-110nm,例如介质层4的沉积厚度可以为100nm,在对介质层4进行减薄时可进行多次减薄,以便于对介质层4减薄厚度的控制。在一些示例中,如图5所示,可采用化学机械研磨工艺对介质层4进行减薄,以将介质层4减薄至位于有源区11顶表面的厚度为10nm-20nm,然后如图6所示,可采用化学气相刻蚀将介质层4减薄至位于有源区11顶表面的厚度为0-2nm,在此步骤可采用氢氟酸为刻蚀剂并通过刻蚀控制将介质层4减薄至保留在有源区11的顶表面的厚度为0-2nm停止。In some specific examples of the present invention, the deposition thickness of the dielectric layer 4 may be 90 nm-110 nm, for example, the deposition thickness of the dielectric layer 4 may be 100 nm, and the thinning of the dielectric layer 4 may be performed multiple times. In order to facilitate the control of the thinning thickness of the dielectric layer 4 . In some examples, as shown in FIG. 5 , a chemical mechanical polishing process may be used to thin the dielectric layer 4 to thin the dielectric layer 4 to a thickness of 10 nm-20 nm on the top surface of the
在对第二绝缘层22进行刻蚀时,同时会对部分第一绝缘层21进行刻蚀,使得第一绝缘层21的顶表面下降,所述第二绝缘层22的顶表面与所述第一绝缘层21的顶表面存在距离差,在本发明的一些实施例中,所述第二绝缘层22的顶表面与所述第一绝缘层21的顶表面距离差为5nm-10nm,第二绝缘层22的顶表面与第一绝缘层21的顶表面距离差可以为5nm、7nm、9nm以及10nm,由此使得即使后续刻蚀工艺造成第一绝缘层21被过度刻蚀,也可防止由于第二绝缘层22与第一绝缘层21平齐或高度差较小而导致在第二绝缘层22和有源区11之间形成凹陷。When the second insulating
在本发明的一些实施例中,所述第二绝缘层22厚度可以为20nm-100nm。可选地,所述第二绝缘层22厚度可以为20nm-50nm,进一步地,所述第二绝缘层22厚度可以为20nm、30nm、40nm或50nm,从而能够提高半导体结构100中有源区11之间的绝缘效果。In some embodiments of the present invention, the thickness of the second insulating
在本发明的一些实施例中,结合图7-图10所示所述半导体结构100的形成方法还可以包括:于有源区11上形成栅极结构3,具体地,如图7所示,在介质层4的表面依次形成多晶硅层31和金属栅极32,可选地,所述金属栅极32可以为金属材料、金属氮化物材料中的至少一种,例如所述金属栅极32可以为金属钨层等金属材料层,或者所述金属栅极32可以为金属氮化物层例如氮化钛层,在如图7所示的示例中,金属栅极32可以包括金属材料层33和金属氮化物层34,例如形成在多晶硅层31表面的氮化钛层34和形成在氮化钛层34表面的金属钨层33。In some embodiments of the present invention, the method for forming the
如图7-图8所示,在金属栅极32的表面形成栅极掩膜层4以用于形成掩膜来刻蚀金属栅极32和多晶硅层31和介质层4,如图8所示,在栅极掩膜层4表面形成光刻胶图案5,以用于定义形成栅极结构3的区域,然后执行光刻工艺对多晶硅层31和金属栅极32以及衬底1表面的介质层4进行刻蚀,以形成栅极结构3。可选地,所述栅极掩膜层4可以形成为组合掩膜层12,在如图8所示的示例中,所述栅极掩膜层4可以包括氮化硅层41、旋涂掩膜层42和氮氧化硅层43,其中所述氮化硅层41位于所述金属栅极32表面,所述旋涂掩膜层42位于氮化硅层43表面,所述氮氧化硅层43位于所述旋涂掩膜层42表面。As shown in FIG. 7-FIG. 8, a gate mask layer 4 is formed on the surface of the
如图10所示,然后在栅极结构3的表面以及位于栅极结构3下方的部分介质层4的侧壁形成绝缘层,具体地,可在在栅极结构3的表面以及位于栅极结构3下方的部分介质层4的侧壁沉积氮化硅层61,然后在氮化硅层61的侧壁形成侧墙氧化硅层62。其中在形成栅极结构3的步骤中,可保留位于栅极结构3表面的部分栅极掩膜层4,例如可保留部分位于栅极结构3表面的氮化硅层41以用于后续形成绝缘层,然后在栅极结构3的侧壁、位于栅极结构3下方的部分介质层4的侧壁以及保留的氮化硅层的侧壁沉积形成侧墙氮化硅层61,之后在侧墙氮化硅层的表面形成侧墙氧化硅层62。As shown in FIG. 10 , an insulating layer is then formed on the surface of the
由于前序工艺中第二绝缘层22的顶表面低于第一绝缘层21的顶表面,且通过后续形成介质层4,由此在形成栅极结构3的步骤中可防止在第二绝缘层22和有源区11之间形成凹陷而影响后续工艺和半导体结构100的性能。Since the top surface of the second insulating
本发明还提出了一种半导体结构100。The present invention also provides a
根据本发明实施例的半导体可以包括衬底1,所述衬底1内形成隔离结构2、凹槽以及有源区11;所述隔离结构2包括第一绝缘层21、第二绝缘层22和第三绝缘层23以及介质层4,所述绝缘层位于所述凹槽的底部和侧壁,所述第二绝缘层22位于所述第一绝缘层21表面,其中,去除部分所述第二绝缘层22,使得所述第二绝缘层22的顶表面低于所述第一绝缘层21的顶表面,所述第三绝缘层23位于所述第二绝缘层22表面,所述第一绝缘层21、所述第二绝缘层22和所述第三绝缘层23填充所述凹槽,所述介质层4覆盖所述第一绝缘层21、第二绝缘层22和第三绝缘层23表面以及所述有源区11且填充满去除部分所述第二绝缘层22形成的凹陷25。A semiconductor according to an embodiment of the present invention may include a
由此,后续在上述半导体结构100上形成其它结构如栅极结构3等器件时,例如在后续对半导体结构100进行刻蚀时,即使对介质层4进行过刻蚀,由于第二绝缘层22顶表面高度降低,从而能够避免过刻蚀导致在第二绝缘层22和有源区11之间形成凹陷而影响半导体结构100的性能,而且相比现有技术中,由于第一绝缘层21被过度刻蚀,导致第二绝缘层22和有源区11之间存在凹陷,由于刻蚀特性,凹陷会导致第二绝缘层22和有源区11之间的第一绝缘层21被进一步过刻蚀,因此本发明实施例的半导体结构100通过防止在第二绝缘层22和有源区11之间形成凹陷,也能够进一步地减小后续工艺中隔离结构2尤其是第一绝缘层21的刻蚀。Therefore, when other structures such as the
根据本发明的一些实施例,所述第三绝缘层23不覆盖所述第二绝缘层22的顶表面。According to some embodiments of the present invention, the third insulating
在本发明的一些实施例中,所述第二绝缘层22的上表面到有源区11的上表面的高度差为18-20nm。In some embodiments of the present invention, the height difference between the upper surface of the second insulating
在本发明的一些实施例中,所述半导体结构100还可以包括栅极结构3,所述栅极结构3形成在所述有源区11上。In some embodiments of the present invention, the
以上仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above are only the preferred embodiments of the present invention. It should be pointed out that for those skilled in the art, without departing from the principles of the present invention, several improvements and modifications can also be made, and these improvements and modifications should also be regarded as the present invention. the scope of protection of the invention.
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