CN115176806A - Insecticidal composition, pesticide preparation, application and use method - Google Patents
Insecticidal composition, pesticide preparation, application and use method Download PDFInfo
- Publication number
- CN115176806A CN115176806A CN202110355723.3A CN202110355723A CN115176806A CN 115176806 A CN115176806 A CN 115176806A CN 202110355723 A CN202110355723 A CN 202110355723A CN 115176806 A CN115176806 A CN 115176806A
- Authority
- CN
- China
- Prior art keywords
- agents
- composition
- pyridalyl
- insecticidal composition
- pesticidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 239000000575 pesticide Substances 0.000 title claims abstract description 24
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000005926 Pyridalyl Substances 0.000 claims abstract description 26
- AEHJMNVBLRLZKK-UHFFFAOYSA-N pyridalyl Chemical group N1=CC(C(F)(F)F)=CC=C1OCCCOC1=C(Cl)C=C(OCC=C(Cl)Cl)C=C1Cl AEHJMNVBLRLZKK-UHFFFAOYSA-N 0.000 claims abstract description 25
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 19
- 241001414989 Thysanoptera Species 0.000 claims abstract description 9
- 239000004480 active ingredient Substances 0.000 claims abstract description 9
- 241000258937 Hemiptera Species 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 230000000361 pesticidal effect Effects 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 239000003381 stabilizer Substances 0.000 claims description 4
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 230000000857 drug effect Effects 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- 239000004563 wettable powder Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims 1
- 231100000419 toxicity Toxicity 0.000 abstract description 11
- 230000001988 toxicity Effects 0.000 abstract description 11
- 230000009471 action Effects 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 10
- 230000009286 beneficial effect Effects 0.000 abstract description 7
- 231100000053 low toxicity Toxicity 0.000 abstract description 5
- 206010059866 Drug resistance Diseases 0.000 abstract description 4
- 230000007246 mechanism Effects 0.000 abstract description 4
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 abstract 1
- 229960005199 tetramethrin Drugs 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 15
- 241000238631 Hexapoda Species 0.000 description 10
- 239000002689 soil Substances 0.000 description 10
- 239000003814 drug Substances 0.000 description 9
- 241001233061 earthworms Species 0.000 description 7
- 230000001018 virulence Effects 0.000 description 7
- 239000005822 Propiconazole Substances 0.000 description 6
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- 241000254127 Bemisia tabaci Species 0.000 description 3
- 239000008272 agar Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 231100000820 toxicity test Toxicity 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000243686 Eisenia fetida Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008485 antagonism Effects 0.000 description 2
- 238000010009 beating Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- -1 dicyclanil ester Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000000447 pesticide residue Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 244000299906 Cucumis sativus var. sativus Species 0.000 description 1
- 241000927584 Frankliniella occidentalis Species 0.000 description 1
- HLFSDGLLUJUHTE-SNVBAGLBSA-N Levamisole Chemical compound C1([C@H]2CN3CCSC3=N2)=CC=CC=C1 HLFSDGLLUJUHTE-SNVBAGLBSA-N 0.000 description 1
- LVDRREOUMKACNJ-BKMJKUGQSA-N N-[(2R,3S)-2-(4-chlorophenyl)-1-(1,4-dimethyl-2-oxoquinolin-7-yl)-6-oxopiperidin-3-yl]-2-methylpropane-1-sulfonamide Chemical compound CC(C)CS(=O)(=O)N[C@H]1CCC(=O)N([C@@H]1c1ccc(Cl)cc1)c1ccc2c(C)cc(=O)n(C)c2c1 LVDRREOUMKACNJ-BKMJKUGQSA-N 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 241000736285 Sphagnum Species 0.000 description 1
- 231100000215 acute (single dose) toxicity testing Toxicity 0.000 description 1
- 238000011047 acute toxicity test Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 229960001614 levamisole Drugs 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- BACHBFVBHLGWSL-UHFFFAOYSA-N methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Abstract
The invention discloses an insecticidal composition, a pesticide preparation, application and a using method, which mainly comprise active ingredients of dicyclopropionate and pyridalyl, wherein the weight ratio of the dicyclopropionate to the pyridalyl is 50-1: 1 to 1. The insecticidal composition of the invention is composed of active ingredients with different action mechanisms, and the action sites are increased, thus being beneficial to overcoming the generation of drug resistance of pests and being beneficial to the treatment of resistant pests; the compounded of the dicyclopropyl tetramethrin and the pyridalyl have a synergistic effect, have good toxicity to whiteflies and thrips, and have low toxicity to other beneficial organisms.
Description
Technical Field
The invention belongs to the technical field of pesticide application, and particularly relates to an insecticidal composition containing propiconazole and pyridalyl, which is used for preventing and treating pests with piercing-sucking mouthparts and rasping-sucking mouthparts.
Background
Conventionally, piercing-sucking mouthpart pests are difficult to control in agriculture, and simultaneously, due to the single action site of the pesticide and the unscientific use of the pesticide, the piercing-sucking mouthpart pests have higher resistance to the currently used chemical pesticides. Frequent mass application of the pesticide results in high production cost and aggravates environmental pollution. Therefore, new varieties which are high in efficiency, low in toxicity and environment-friendly are urgently needed in agricultural production.
Triflupyranyl (Pyridalyl), also known as Pyridalyl, is used mainly for controlling lepidopteran pest larvae. Is a high-efficiency and low-toxicity pesticide. At present, no report is found for compounding the dicyclopropionate and the pyridalyl.
Disclosure of Invention
The invention provides an insecticidal composition, a pesticide preparation and application, which can solve the defects in the prior art.
The technical scheme of the invention is as follows:
an insecticidal composition mainly comprises active ingredients of dipropionate and pyridalyl, wherein the weight ratio of the dipropionate to the pyridalyl is 50-1: 1 to 1. The insecticidal composition provided by the invention is composed of active ingredients with different action mechanisms, and the action sites are increased, so that the generation of drug resistance of pests is overcome, and the treatment of resistant pests is facilitated; the compounded of the propiconazole and the pyridalyl has a synergistic effect, has good toxicity to whiteflies and thrips, and has low toxicity to other beneficial organisms.
In some embodiments, the weight ratio of propiconazole to pyridalyl is 10 to 1: 1-1, has strong toxicity to whitefly and thrips and stronger synergistic effect.
In some embodiments, the composition is in the form of one of water dispersible granules, wettable powder, suspending agent, microemulsion, water emulsion and dispersible oil suspending agent.
In some embodiments, the weight percentage of the propiconazole and the pyridalyl in the total mass of the composition is 0.9-85%, and the balance is auxiliary agents, fillers, stabilizers (beneficial to the stability of the effective components in storage and use) or auxiliary agents for promoting the exertion of drug effects.
In some embodiments, the composition further comprises common auxiliary agents required for preparing pesticide preparations, wherein the common auxiliary agents are one or a mixture of several of dispersing agents, emulsifying agents, wetting agents, stabilizing agents, thickening agents, defoaming agents, antifreezing agents and filling agents.
The invention also provides a pesticide preparation prepared from the insecticidal composition.
The invention also provides the application of the insecticidal composition or the pesticide preparation in preventing and treating pests with piercing-sucking mouthparts or rasping-sucking mouthparts.
The pests with the piercing-sucking mouthparts or the rasping-sucking mouthparts are whiteflies and thrips.
The invention also provides a using method of the insecticidal composition, and provides the insecticidal composition, wherein the insecticidal composition is used as a preparation formed by a mixture, and a pesticide product is prepared from two effective components and the common auxiliary agents. Or the dicyclopropyl tetramat and the pyridalyl are respectively packaged and mixed according to a preset proportion when in use.
Compared with the prior art, the invention has the following beneficial effects:
(1) The insecticidal composition has obvious synergistic effect, and the control effect of the composition is obviously improved compared with that of a single agent; (2) After the pesticide effect is improved, the field pesticide dosage and the use cost are reduced, and the pesticide residue and the environmental pollution are reduced; (3) The composition consists of active ingredients with different action mechanisms, and the action sites are increased, so that the composition is favorable for overcoming the generation of drug resistance of pests and is favorable for treating resistant pests.
Of course, it is not necessary for any product in which the invention is practiced to achieve all of the above-described advantages at the same time.
Detailed Description
The invention provides a synergistic composition mainly comprising dicyclopropyl tetramisole and pyridalyl, which has obvious synergistic effect on preventing and treating pests with piercing-sucking mouthparts or rasping-sucking mouthparts.
Compared with a single agent, the composition has obvious synergy on the piercing-sucking pests, and improves the application effect; the field dosage is greatly reduced, the use cost is reduced, and the environmental pollution and the pesticide residue are reduced; the two active ingredients in the composition have completely different action mechanisms, so that the generation of drug resistance of pests is overcome, and the treatment of resistant pests is facilitated.
Compounding the pesticide active ingredients with different structure types is an effective measure for solving the problems of cost, resistance and the like in the use process of a single pesticide. Pesticide active ingredients of different structural types generally exhibit three types of action, namely additive action, synergistic action and antagonistic action, when mixed. However, the specific action cannot be predicted, and can only be concluded through a large number of experiments. The formula with good compound synergism can improve the actual control effect, reduce the dosage of pesticides, is beneficial to delaying the generation of resistance, and is one of important means for resistance treatment.
The compositions according to the invention have a marked synergistic effect on thrips, whitefly, etc., and not only a simple addition of the effects of the two agents, as is evident from the results of the examples below.
In the present invention, it should be noted that:
mortality (%) = dead insects/total number of treated insects 100
Corrected mortality (%) = (treatment group mortality-control group mortality)/(1-control group mortality) × 100, statistical analysis was performed using DPS9.50 statistical analysis software, LC50 of each drug was calculated by correcting mortality for each treatment with different concentration gradients, and co-toxicity coefficient (CTC) was calculated by the sun cloud lung method.
When the CTC is less than or equal to 80, the composition shows antagonism, when the CTC is more than 80 and less than 120, the composition shows additive action, and when the CTC is more than or equal to 120, the composition shows synergism.
Actually measured virulence index (ATI) = (standard medicament LC 50/test medicament LC 50) × 100
Theoretical virulence index (TTI) = a agent virulence index x percent a in the mixture + B agent virulence index x percent B in the mixture.
Co-toxicity coefficient (CTC) = [ measured toxicity index (ATI)/theoretical toxicity index of the mixture (TTI) ] × 100.
In the description of the present invention, the pesticidal composition, which is used for controlling pests on crops, may be provided in the form of a finished preparation, i.e., in the form of a mixture, or the components of the composition may be provided in the form of a single dose, mixed in proportion in a tank or a can directly before use, and then diluted to a desired concentration.
In this context, a range expressed by "one value to another value" is a general expression avoiding all values in the range from being enumerated in the specification. Thus, recitation of a range of values herein is intended to encompass any value within the range and any smaller range defined by any value within the range, as if the range and smaller range were explicitly recited in the specification.
The invention will be further illustrated with reference to the following specific examples. It should be understood that these examples are only for illustrating the present invention and are not intended to limit the scope of the present invention. In practice, the invention will be understood to cover all modifications and variations of the invention as may be practiced by those skilled in the art.
Example 1 indoor combined toxicity determination test of diclofop-methyl and pyridalyl compounded on thrips
Test subjects: franjliniella occidentalis (Pergande) is cultured for seven generations in a constant-temperature seedling room.
Preparing a liquid medicine: the liquid medicines were prepared according to the formulations in table 1, respectively.
The test method comprises the following steps: the test is carried out by adopting a leaf dipping method according to the agricultural industry standard NY/T1154.14-2008 of the people's republic of China. Soaking prepared leaf (3 cm × 4 cm) of caulis et folium Brassicae Capitatae in the medicinal liquid for 10s, taking out, naturally drying until there is no water mark on the surface, picking 3-year-old nymph of Frankliniella occidentalis with writing brush, transferring the test insect to a greenhouse with a relative humidity of 70% (25 + -1) deg.C, 14/10 (L/D), and culturing normally. Each treatment was repeated 4 times, with 30 replicates. The virulence determination results are shown in table 1.
TABLE 1 test results for toxicity determination of thrips
As can be seen from the table 1, when the weight ratio of the compounded diproprionate and pyridalyl is 50-1:1, the cotoxicity coefficients are 128.40, 137.37, 144.18, 212.94, 205.13, 262.53 and 365 respectively, according to the cotoxicity coefficient standard, the cotoxicity coefficients are less than 80, the antagonism is realized, the addition effect is realized when the cotoxicity coefficients are 80-120, and the synergism is realized when the cotoxicity coefficients are more than 120. Therefore, the 7 dicyclanil ester and pyridalyl compound agents have synergistic effect on the toxicity of the thrips.
Example 2 Combined virulence assay for Bemisia tabaci
The raw drugs were formulated into the required test agents according to table 2, the test method being agar moisturizing leaf soaking.
Firstly, single agents (propiconazole and pyridalyl) and various mixed agents (60. The insect testing greenhouse bemisia tabaci is collected from the field, cucumber seedlings are fed for 1 generation in the greenhouse, and uniform nymphs of 3 years old are selected for later use. A puncher is used for beating fresh and flat host leaves into leaf disks, and large and thick leaf veins are avoided as much as possible during beating. Soaking the leaf disk in the liquid medicine to be tested for 10s, taking out, drying, spreading the leaf disk with its front face downward in a flat-bottom glass tube filled with agar, and tightly adhering the leaf disk to the agar and the tube wall without leaving any gap. Each treatment was repeated 4 times, and the treatment without the agent was used as a control.
The glass tube with the laid leaf disc is obliquely and inversely placed on a host plant of the greenhouse trialeurodes vaporariorum, the plant is tapped or blown by a mouth, so that the trialeurodes vaporariorum enters the tube, 20 heads of each tube are arranged, the opening of each tube is plugged to a position which is about 15mm away from the tube bottom when the trialeurodes vaporariorum flies (climbs) into the leaf disc at the tube bottom, and the trialeurodes vaporariorum is forcibly positioned on the leaf disc at the tube bottom. After the test insects are inoculated for about 10min, the number of the live insects in each tube is checked and recorded one by one. The treated test insects are placed upside down at the temperature of (25 soil 1) DEG C, the relative humidity of 60% -80% and the photoperiod of L: d =14h: feeding and observing under 10h condition, and adjusting test environment condition under special condition. After 48h of treatment, the number of dead insects in each tube is checked one by one and recorded, and the dead insects are considered to die when the test insects are still or can not act normally.
TABLE 2 indoor combined virulence determination results of liquid medicine to bemisia tabaci
Indoor toxicity test results show that the weight ratio of the compounded dicoformate and pyridalyl is 50:1-1:1, has better toxicity to the whitefly and shows a synergistic effect.
Example 3 soil method toxicity test
The artificial soil reference (OECD, 1984,2004) was slightly modified. Consisting of 10% ground sphagnum (< 0.5 mm), 20% kaolinite clay (> 50% kaolinite) and 68% fine sand and 2% calcium carbonate. In toxicity experiments, soil moisture content was 35% of dry weight.
Each test agent (propiconazole and pyridalyl and each compound 60. The fine sand mixed with the medicament is placed for half a day at room temperature to ensure that the acetone is completely evaporated. And fully and uniformly mixing the fine sand and the prepared wet artificial soil. Distilled water is added to make the water content of the artificial soil reach 35 percent. A total of 0.675kg (0.5 kg of artificial soil) of pesticide-containing soil was placed in black plastic pots (18 cm in surface diameter, 14cm in bottom diameter, 7cm in height) each containing 10 earthworms, and a perforated lid was placed to prevent the earthworms from falling out. The control was acetone only. The earthworms are put into an incubator with a constant light source of 20 +/-1 ℃, the humidity of 80-85 percent and 400-800lux, and the death condition of the earthworms is investigated after 7 days and 14 days of treatment. The mortality rate of the control group did not exceed 10%.
An equal scale of 5-6 concentrations tested and controls were used for each pesticide to give LC50. Each concentration was in triplicate, each replicate contained 10 earthworms. Earthworms were placed under the same conditions as untreated soil for 24 hours prior to dose response testing.
The grading standard of toxicity of pesticides on earthworms adopts the standard (artificial soil method) in the test criterion of chemical pesticide environmental safety evaluation: LC50 is less than or equal to 1.0mg/kg, which is high-toxicity grade; 1.0mg/kg is more than LC50 and less than or equal to 10.0mg/kg, which is the poisoning grade; LC50 is more than 10.0mg/kg, and is low-toxicity grade.
TABLE 3 indoor acute toxicity test results for Eisenia foetida
The results in table 3 show that the weight ratio of the compounded dicoformate and pyridalyl is 60:1-1:1 hour, has low toxicity to Eisenia foetida.
The foregoing disclosure discloses only the preferred embodiments of the invention. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.
In light of the above teachings, those skilled in the art will readily appreciate that the materials and their equivalents, the processes and their equivalents, as listed or exemplified herein, are capable of performing the invention in any of its several forms, and that the upper and lower limits of the parameters of the materials and processes, and the ranges of values between these limits are not specifically enumerated herein.
Claims (9)
1. An insecticidal composition characterized by: the insecticidal composition mainly comprises active ingredients of the dicyclopropionate and the pyridalyl, wherein the weight ratio of the dicyclopropionate to the pyridalyl is 50-1: 1 to 1.
2. The insecticidal composition of claim 1, wherein: the weight ratio of the dicyclopropanate to the pyridalyl is 10-1: 1 to 1.
3. The pesticidal composition of claim 1 or 2, wherein: the composition is one of water dispersible granules, wettable powder, suspending agents, micro-emulsions, aqueous emulsions and dispersible oil suspending agents.
4. The pesticidal composition of claim 1 or 2, wherein: the weight of the dicyclopropanate and the pyridalyl accounts for 0.9 to 85 percent of the total mass of the composition, and the balance is auxiliary agents, fillers, stabilizing agents or auxiliary agents for promoting the drug effect to be exerted.
5. The pesticidal composition of claim 1 or 2, wherein: the composition also contains common auxiliary agents required by pesticide preparation, wherein the common auxiliary agents are one or a mixture of more of dispersing agents, emulsifying agents, wetting agents, stabilizing agents, thickening agents, defoaming agents, antifreezing agents and filling agents.
6. A pesticidal formulation prepared using the pesticidal composition according to any one of claims 1 to 5.
7. Use of the pesticidal composition according to any one of claims 1 to 5 or the pesticidal formulation according to claim 6 for controlling piercing-sucking mouthpart or rasping-sucking mouthpart pests.
8. Use according to claim 7, characterized in that: the pests with piercing-sucking mouthparts or rasping-sucking mouthparts are whiteflies and thrips.
9. A method of using an insecticidal composition, comprising: providing the insecticidal composition according to any one of claims 1 to 5, wherein the insecticidal composition is used as a formulation formed by a mixture, or the dicyclopropyl insecticide and the pyridalyl are separately packaged and mixed according to a predetermined ratio when used.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110355723.3A CN115176806B (en) | 2021-04-01 | 2021-04-01 | Insecticidal composition, pesticide preparation, application and use method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202110355723.3A CN115176806B (en) | 2021-04-01 | 2021-04-01 | Insecticidal composition, pesticide preparation, application and use method |
Publications (2)
Publication Number | Publication Date |
---|---|
CN115176806A true CN115176806A (en) | 2022-10-14 |
CN115176806B CN115176806B (en) | 2024-04-26 |
Family
ID=83511697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202110355723.3A Active CN115176806B (en) | 2021-04-01 | 2021-04-01 | Insecticidal composition, pesticide preparation, application and use method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN115176806B (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015044791A (en) * | 2013-07-29 | 2015-03-12 | クミアイ化学工業株式会社 | Agricultural and horticultural pest control agent and method for controlling pest |
CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
JP2016199527A (en) * | 2015-04-14 | 2016-12-01 | アグロカネショウ株式会社 | Pest controlling agent composition |
CN107920507A (en) * | 2015-10-14 | 2018-04-17 | 组合化学工业株式会社 | Granular agrichemical composition |
CN109221228A (en) * | 2018-08-23 | 2019-01-18 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing double third ring worm esters and cycloxaprid |
-
2021
- 2021-04-01 CN CN202110355723.3A patent/CN115176806B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015044791A (en) * | 2013-07-29 | 2015-03-12 | クミアイ化学工業株式会社 | Agricultural and horticultural pest control agent and method for controlling pest |
CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
JP2016199527A (en) * | 2015-04-14 | 2016-12-01 | アグロカネショウ株式会社 | Pest controlling agent composition |
CN107920507A (en) * | 2015-10-14 | 2018-04-17 | 组合化学工业株式会社 | Granular agrichemical composition |
CN109221228A (en) * | 2018-08-23 | 2019-01-18 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing double third ring worm esters and cycloxaprid |
Also Published As
Publication number | Publication date |
---|---|
CN115176806B (en) | 2024-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103734171A (en) | Pesticide composition containing imidacloprid | |
CN114847293B (en) | Pesticide composition and application thereof | |
CN114732023B (en) | Insecticidal composition containing Oxazosulfyl and chlorantraniliprole and application thereof | |
CN115176806B (en) | Insecticidal composition, pesticide preparation, application and use method | |
CN114375958B (en) | Nematicidal composition containing cyclopurifiuram and application thereof | |
CN113080195B (en) | Termite trapping bait and using method thereof | |
CN105532680B (en) | A kind of highly efficiency compositional composition pesticide of pyrimidine containing trifluoro-benzene and cycloxaprid | |
CN110122502B (en) | Seed coating composition and preparation method and application thereof | |
CN106982837A (en) | A kind of Pesticidal combination containing fluorine cyanogen insect amide and its application | |
CN111466414A (en) | Medicament for killing black cutworm | |
CN113207897A (en) | Insecticide composition containing metalaxyl-M and application thereof | |
CN109169688A (en) | A kind of Pesticidal combination and application thereof containing thiocyclam and emamectin-benzoate | |
CN116172006B (en) | Pesticide composition for preventing and controlling balsam pear melon fruit fly | |
CN104397008A (en) | Insecticidal composition | |
CN105104402B (en) | Insecticide acaricide composition and its application | |
CN114342959B (en) | Composition for simultaneously preventing and controlling cucumber aphids and cucumber bacterial angular leaf spot | |
CN108124892A (en) | It is a kind of to kill aphid composition containing rotenone and guadipyr | |
CN115281205B (en) | Insecticidal composition for preventing and controlling peach fruit borer | |
CN105248446A (en) | Complex synergism insecticide and application thereof | |
CN108477174A (en) | Four chlorine type agricultural insecticide composition of ring bromine, its preparation and application | |
CN116998498A (en) | Pesticide composition containing cyantraniliprole and application thereof | |
CN117204429A (en) | Insecticidal composition containing spinetoram and acetamiprid and application thereof | |
CN116548450A (en) | Preparation method and application of nano suspending agent | |
CN111213643A (en) | Tubatoxin insecticidal composition containing diatomite, insecticide and preparation method thereof | |
CN116548452A (en) | Application of chlorantraniliprole-containing composition in control of plutella xylostella |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |