JP2016199527A - Pest controlling agent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a pest controlling agent composition exhibiting controlling effect on various noxious organism at low dose by enhancing bactericidal/insecticidal activity of at least one kind of compound selected from 2-amino nicotinic acid ester derivative and a salt thereof.SOLUTION: At least one kind of compound selected from 2-amino nicotinic acid ester derivative represented by the formula [I], where Rrepresents a hydrogen atom or a Cto Calkyl group, Rrepresents a hydrogen atom, a halogen atom, a Cto Calkyl group or a Cto Calkoxy group, A represents a nitrogen atom or a methine group (CH), Y represents an oxygen atom, a methylene group (CH) or a methyleneoxy group (OCH) or a salt thereof and at least one kind of compound selected from compounds having an insecticidal activity are mixed.SELECTED DRAWING: None

Description

  The present invention relates to a pesticidal composition containing at least one compound selected from 2-aminonicotinic acid ester derivatives and salts thereof and at least one compound selected from compounds having insect-control activity.

（式中、Ｒ¹は水素原子またはＣ₁〜Ｃ₄のアルキル基を表し、Ｒ²は水素原子、ハロゲン原子、Ｃ₁〜Ｃ₄のアルキル基またはＣ₁〜Ｃ₄のアルコキシ基を表し、Ａは窒素原子またはメチン基（ＣＨ）を表し、Ｙは酸素原子、メチレン基（ＣＨ₂）またはメチレンオキシ基（ＯＣＨ₂）を表す。）で示される２−アミノニコチン酸エステル誘導体が植物病害防除剤の有効成分として有用であることが公知である（特許文献１参照）。 Formula [I]

Wherein R ¹ represents a hydrogen atom or a C ₁ -C ₄ alkyl group, R ² represents a hydrogen atom, a halogen atom, a C ₁ -C ₄ alkyl group or a C ₁ -C ₄ alkoxy group, A represents a nitrogen atom or a methine group (CH), and Y represents an oxygen atom, a methylene group (CH ₂ ) or a methyleneoxy group (OCH ₂ ).) A 2-aminonicotinic acid ester derivative represented by a plant disease control It is known to be useful as an active ingredient of an agent (see Patent Document 1).

In recent years, environmental pollution caused by agricultural chemicals has become a problem, and there is a demand for a drug that exhibits a high effect at a lower dose in order to reduce the environmental burden. If a synergistic effect is obtained and the activity is improved by using a mixed agent, it is possible to reduce the number of application times and to simultaneously control a plurality of diseases by one application, which can lead to labor saving.
On the other hand, in the field of bactericides, benzimidazole fungicides, dicarboximide fungicides, anilinopyrimidine fungicides, strobilurin fungicides, and SDHI (succinic acid dehydrogenase inhibitors). Although bactericides have been developed and marketed, resistant bacteria have emerged shortly after market launch, and the reduction in effectiveness has become a problem. Also, in the insecticide field, organophosphorus insecticides, pyrethroid insecticides, benzoylurea insecticides, diamide insecticides, organotin acaricides, etc. have been developed and marketed so far. Shortly after launch, resistant pests and ticks have emerged, and the decline in effectiveness has become a problem. Accordingly, there is a strong demand from the market for fungicides and insecticides having a new mechanism of action, and pest control compositions that reduce the development risk of resistant bacteria and resistant pests.

  Patent Document 1 discloses that a 2-aminonicotinic acid ester derivative represented by the formula [I] and other insecticides may be used in combination as active ingredients of agricultural and horticultural fungicides. However, in Patent Document 1, although the control effect of an emulsion containing only the 2-aminonicotinic acid ester derivative represented by the formula [I] as an active ingredient has been confirmed, the 2-aminonicotinic acid ester derivative and other insecticides The control effect of the agricultural and horticultural fungicide using these as an active ingredient has not been confirmed. Patent Document 1 does not examine the synergistic control effect of the combination of the 2-aminonicotinic acid ester derivative represented by the formula [I] and other insecticides.

WO2014 / 006945 pamphlet

  The present invention controls various pests at a low dose by enhancing the bactericidal and insecticidal activity of at least one compound selected from 2-aminonicotinic acid ester derivatives represented by the formula [I] and salts thereof. It is an object of the present invention to provide a pest control composition that exhibits an effect.

  As a result of intensive studies to solve the above problems, the present inventors have found that at least one compound selected from 2-aminonicotinic acid ester derivatives represented by the formula [I] and salts thereof, and compounds having insecticidal activity By mixing with at least one compound selected from the group consisting of 2-aminonicotinic acid ester derivative alone or a compound having an insect repellent activity, a low dose that cannot provide a sufficient effect and high against pests Found to show activity. That is, the present invention relates to the following [1] to [9].

（式中、Ｒ¹は水素原子またはＣ₁〜Ｃ₄のアルキル基を表し、Ｒ²は水素原子、ハロゲン原子、Ｃ₁〜Ｃ₄のアルキル基またはＣ₁〜Ｃ₄のアルコキシ基を表し、Ａは窒素原子またはメチン基（ＣＨ）を表し、Ｙは酸素原子、メチレン基（ＣＨ₂）またはメチレンオキシ基（ＯＣＨ₂）を表す。）で示される２−アミノニコチン酸エステル誘導体およびその塩から選ばれる少なくとも１種の化合物と、
（Ｂ）アジンホスメチル、アセフェート、クロルピリホス、ダイアジノン、ジクロルボス、ジメトン-Ｓメチル、ジメトエート、ジメチルビンホス、ジスルフォトン、エチオン、フェニトロチオン、フェンチオン、イソキサチオン、マラチオン、メタミドホス、メチダチオン、モノクロトホス、ナレド、オキシデプロホス、パラチオン、フェンソエート、ホサロン、ピリミホスメチル、ピリダフェンチオン、プロフェノホス、プロチオホス、プロパホス、ピラクロホス、サリチオン、スルプロホス、チオメトン、テトラクロルビンホス、トリクロルホン、バミドチン、アラニカルブ、ベンダイオカルブ、ベンフラカルブ、カルバリル、カルボフラン、カルボスルファン、エチオフェンカルブ、フェノブカルブ、フラチオカルブ、イソプロカルブ、メソミル、メトルカルブ、ピリミカルブ、プロポクスル、チオジカルブ、アルドリン、クロルデン、ＤＤＴ、エンドサルファン、リンデン、アクリナトリン、アレスリン、ビフェントリン、シクロプロトリン、シフルトリン、シハロトリン、シフェノトリン、シペルメトリン、デルタメトリン、エトフェンプロックス、フェンプロパトリン、フェンバレレート、フルシトリネート、フルフェンプロックス、フルバリネート、フラメトリン、ハロフェンプロックス、イミプロトリン、ペルメトリン、フェノトリン、プラレトリン、ピレトリン、レスメトリン、シラフルオフェン、テフルトリン、トラロメトリン、トランスフルスリン、アセタミプリド、クロチアニジン、ジノテフラン、イミダクロプリド、ニテンピラム、チアクロプリド、チアメトキサム、クロラントラニリプロール、シアントラニリプロール、シクラニリプロール、テトラニリプロール、フルベンジアミド、ビストリフロン、クロロフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、ノビフルムロン、テフルベンズロン、トリフルムロン、ブプロフェジン、シロマジン、クロマフェノジド、ハロフェノジド、メトキシフェノジド、テブフェノジド、ジオフェノラン、フェノキシカルブ、ヒドロプレン、メソプレン、ピリプロキシフェン、アバメクチン、エマメクチンベンゾエート、イベルメクチン、レピメクチン、ミルベメクチン、ネマデクチン、ニッコーマイシン、スピネトラム、スピノサドー、ＢＴ剤、アナバシン、アザジラクチン、デグエリン、脂肪酸グリセリド、ヒドロキシプロピルデンプン、大豆レシチン、ニコチン、ノルニコチン、オレイン酸ナトリウム、マシン油、プロピレングリコールモノ脂肪酸エステル、なたね油、ロテノン、アセトプロール、アフィドピロペン、ベンスルタップ、ブロフラニリド、カルタップ、チオシクラム、クロルフェナピル、ジアフェンチウロン、ジクロロメゾチアズ、エチプロール、フィプロニル、フロメトキン、フロニカミド、フルヘキサフォン、フルピラジフロン、ヒドラメチルノン、インドキサカルブ、メタフルミゾン、メタアルデヒド、硫酸ニコチン、ピメトロジン、プラフルプロール、ピリダリル、ピリフルキナゾン、ピリプロール、スピロテトラマト、スルフルラミド、スルホキサフロル、トリフルメゾピリム、トルフェンピラド、トリアザメート、アセキノシル、アミトラズ、アゾシクロチン、ベンゾメート、ビフェナゼート、ビナパクリル、フェニソブロモレート、キノメチオネート、クロフェンテジン、シエノピラフェン、シフルメトフェン、水酸化トリシクロヘキシルスズ、ジコホル、ジエノクロル、ジフロビダジン、エトキサゾール、フェナザフロル、フェナザキン、酸化フェンブタスズ、フェノチオカルブ、フェンピロキシメート、フルアクリピリム、ヘキシチアゾクス、ピリミジフェン、ポリナクチン複合体、プロパルギル、ピフルブミド、ピリダベン、スピロジクロフェン、スピロメシフェン、テブフェンピラド、テトラジホン、リン化アルミニウム、ベンクロトラズ、カズサホス、エトプロホス、フルエンスルフォン、フルオピラム、ホスチアゼート、イミシアホス、塩酸レバミゾール、メスルフェンホス（ｍｅｓｕｌｆｅｎｆｏｓ）、カーバム、メチルイソシアネート、酒石酸モランテル、オキサミル、チフルザミド、チオキサザフェン、クロロファシノン、クマテトラリル、ダイファシン、モノフルオル酢酸塩、ワルファリンからなる群から選択される少なくとも１種の化合物と、
を含有する有害生物防除剤組成物。 [1]
(A) Formula [I]

Wherein R ¹ represents a hydrogen atom or a C ₁ -C ₄ alkyl group, R ² represents a hydrogen atom, a halogen atom, a C ₁ -C ₄ alkyl group or a C ₁ -C ₄ alkoxy group, A represents a nitrogen atom or a methine group (CH), and Y represents an oxygen atom, a methylene group (CH ₂ ) or a methyleneoxy group (OCH ₂ ).) From 2-aminonicotinic acid ester derivatives and salts thereof At least one compound selected;
(B) Azinphosmethyl, acephate, chlorpyrifos, diazinon, dichlorvos, dimeton-S methyl, dimethoate, dimethylvinphos, disulfone, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos, metidathion, monocrotophos, nared, oxydeprophos, parathion , Fensoate, hosalon, pyrimifosmethyl, pyridafenthion, profenofos, prothiofos, propaphos, pyracrofos, salicione, sulprofos, thiometone, tetrachlorvinphos, trichlorphone, bamidtin, alaniculb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, etiofencarb Fenobucarb, furatiocarb, isoprocarb , Mesomil, Metorcarb, Pirimicarb, Propoxur, Thiodicarb, Aldrin, Chlorden, DDT, Endosulfan, Linden, Acrinatrin, Areslin, Bifenthrin, Cycloproton, Cyfluthrin, Cyhalothrin, Ciphenothrin, Cypermethrin, Deltamethrinfen, Etofenprox Propatrin, fenvalerate, flucitrinate, flufenprox, fulvalinate, framethrin, halofenprox, imiprothrin, permethrin, phenothrin, praretrin, pyrethrin, resmethrin, silafluophene, tefluthrin, tralomethrin, transfluthrin, acetamiprid, clothianfurandi , Imidacloprid, nitenpyram, thiacloprid, chi Metoxam, Chlorantraniliprole, Cyantraniliprole, Cyclaniliprol, Tetraniliprol, Flubenzilamide, Bistriflon, Chlorofluazuron, Diflubenzuron, Fluccycloxuron, Flufenoxuron, Hexaflumuuron, Lufenuron, Novallon, Nobiflumuron, Teflubenzuron, Triflumuron, Buprofezin, Ciromazine, Chromafenozide, Halofenozide, Methoxyphenozide, Tebufenozide, Diofenolane, Phenoxycarb, Hydroprene, Mesoprene, Pyriproxyfen, Memectin, Benimactin, Emamectin Benzoctin, Emamectin , Spinosadow, BT agent, Anabasine, Azadirach , Deguelin, fatty acid glycerides, hydroxypropyl starch, soy lecithin, nicotine, nornicotine, sodium oleate, machine oil, propylene glycol monofatty acid ester, rapeseed oil, rotenone, acetoprole, aphidopyrrolene, bensultap, brofuranilide, cartap, thiocyclam, chlorfenapyr, dia Fenthiuron, dichloromezothiaz, etiprole, fipronil, furometokin, flonicamid, fluhexaphone, flupiradifurone, hydramethylnon, indoxacarb, metaflumizone, metaldehyde, nicotine sulfate, pymetrozine, pulafluprolol, pyridalyl, pyrifluquinazone, pyriprolol , Spirotetramat, Sulfluramide, Sulfoxafurol, Triflumezopyrim, Tolu Fenpyrad, triazamate, acequinosyl, amitraz, azocyclotin, benzomate, biphenazate, binapacryl, phenisobromolate, quinomethionate, clofentedine, sienopyrafen, ciflumethophene, hydroxyhydrated tricyclohexyltin, dicophor, dienochlor, difluvidazine, ethofoxazole, zafoxazole Fenbutazin, phenothiocarb, fenpyroximate, fluacrylpyrim, hexythiazox, pyrimidifene, polynactin complex, propargyl, piflumbide, pyridaben, spirodiclofen, spiromesifen, tebufenpyrad, tetradiphone, aluminum phosphide, benclotraz, kazusafos, ethoprophos, fluprosulfone At least one selected from the group consisting of thiazate, imisiaphos, levamisole hydrochloride, mesulfenfos, carbam, methyl isocyanate, morantel tartrate, oxamyl, tifluzamide, thioxaphene, chlorofacinone, coumatetralyl, difacin, monofluoroacetate, warfarin A compound,
A pest control composition comprising:

[2] In the component (A), R ¹ is H or CH ₃ , R ² is H, F, CH ₃ or OCH ₃ , A is CH or N, and Y is O, OCH ₂ or The pest control composition as described in [1] above, which is CH ₂ and is at least one compound selected from the 2-aminonicotinic acid ester derivative represented by the formula [I] and a salt thereof.

[3] The component (A) is
(1) R ¹ is H, R ² is H, A is CH, and Y is O.
(2) R ¹ is CH ₃ , R ² is H, A is CH, and Y is O.
(3) R ¹ is CH ₃ , R ² is F, A is CH, and Y is O.
(4) R ¹ is CH ₃ , R ² is CH ₃ , A is CH, and Y is O.
(5) R ¹ is CH ₃ , R ² is OCH ₃ , A is CH, and Y is O.
(6) R ¹ is CH ₃ , R ² is H, A is N, and Y is O.
(7) R ¹ is CH ₃ , R ² is H, A is CH, Y is OCH ₂ , or (8) R ¹ is CH ₃ and R ² is H, A is CH and Y is CH ₂ .
The pest control composition as described in [2] above, which is a 2-aminonicotinic acid ester derivative represented by the formula [I].

[4] The component (B) is acephate, chlorpyrifos, diazinon, fenitrothion, malathion, methidathion, profenofos, prothiophos, alanicarb, benfuracarb, carbaryl, mesomil, thiodicarb, cyfluthrin, cypermethrin, etofenprox, fenpropatoline, full Citrinate, permethrin, silafluophene, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, thiamethoxam, chlorantraniliprole, cyantraniliprolol, cyclaniliprol, tetraniliprol, fulbenzamide, chlorofluazuron, full Phenoxuron, lufenuron, teflubenzuron, buprofezin, cyromazine, chromafenodi , Tebufenozide, abamectin, emamectin benzoate, repimectin, milbemectin, spinetoram, spinosadow, BT agent, azadirachtin, cartap, thiocyclam, chlorfenapyr, diafenthiuron, ethiprol, fipronil, flonicamid, flupiradiflilzone, flupidadifluarzone Spirotetramat, Sulfoxafurol, Triflumezopyrim, Acequinosyl, Amitraz, Bifenazate, Sienopyraphene, Ciflumethofene, Dienochlor, Diflovidazine, Etoxazole, Fenbutazin oxide, Hexithiazox, Propargyl, Pifulbumide, Spiromecifen, Dipyromethifene, Spiromecifen Hosti Zeto, Imishiahosu is selected from the group consisting of oxamyl and Chiokisazafen, the [1] to pesticidal composition according to any one of [3].

[5] The pest control composition according to any one of [1] to [4], wherein the mass ratio of the component (A) to the component (B) is 500: 1 to 1: 500.

[6] The pesticidal composition according to any one of [1] to [5], further including a bulking agent and / or a surfactant.

[7] Use of the pesticidal composition according to any one of [1] to [6] for controlling pests.

[8] A method for controlling pests, which comprises treating the pests and / or their habitats with the pest control composition according to any one of [1] to [6]. .

[9] A pest control composition as described in any one of [1] to [6] above is applied to a place where a useful crop is to be grown or a place where the useful crop is grown or a growing crop. A method for controlling pests, characterized by:

  According to the present invention, the bactericidal / insecticidal activity of at least one compound selected from the 2-aminonicotinic acid ester derivatives represented by the formula [I] and salts thereof is enhanced, and the control effect is low and effective against various pests. It is possible to provide a pest control composition that exhibits the following.

  The 2-aminonicotinic acid ester derivative represented by the above formula [I] used in the present invention is a known compound, and its preparation method is also known as disclosed in, for example, Patent Document 1.

In the 2-aminonicotinic acid ester derivative represented by the formula [I], examples of the C ₁ -C ₄ alkyl group represented by R ¹ and R ² include a methyl group, an ethyl group, an n-propyl group, and isopropyl. Group, n-butyl group, isobutyl group, sec-butyl group, tert-butyl group and the like. Examples of the halogen atom represented by R ² include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Examples of the C ₁ -C ₄ alkoxy group represented by R ² include methoxy group, ethoxy group, n-propoxy group, isopropoxy group, n-butoxy group, isobutoxy group, sec-butoxy group, tert-butoxy group. Groups.

Preferred specific examples of 2-aminonicotinic acid ester derivatives are shown in Table 1. The compound numbers in Table 1 are referenced in the following description.

  On the other hand, the compounds having insect repellent activity to be used in the present invention include The Pesticide Manual Fifteenth Edition (published by British Crop Production Council) and SHIBUYA INDEX 17th Edition 2014 (SHIBUYAUPEw website). .Alanwood.net / pesticides "and the like. These compounds can be synthesized by known production methods or can be obtained from existing manufacturers.

  A compound having an insecticidal activity exhibiting a synergistic control effect against pests by using in combination with at least one compound selected from 2-aminonicotinic acid ester derivatives represented by the formula [I] and salts thereof: Although an example is given, this invention is not limited to these.

  Examples of the organic phosphorous agent include azinephos-methyl, acephate, chlorpyrifos, diazinon, dichlorvos, dimethon-S-methyl, and dimethon-S-methyl. ), Dimethylvinphos, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidothioth hion), monocrotophos, nared, oxydeprofos, parathion, phensoate, fosalone, pirimiphos-methyl phosphide, i profenofos, prothiofos, propopafos, pyraclofos, salithion, sulprofos, thiomethon, tetrachlorvinphos (tetrochlorv) richlorphon), mention may be made of Bamidochin (vamidothion) and the like.

  Examples of carbamate agents include alanical carb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfane, ethiophencarb, ethofencarb. , Furathiocarb, isoprocarb, methomyl, metolcarb, pirimicarb, propoxur, thiodicarb, etc.

  Examples of the organic chlorine agent include aldrin, chlordane, DDT (p, p'-DDT), endosulfan, lindane, and the like.

  Examples of pyrethroid agents include acrinathrin, allethrin, bifenthrin, cycloprotorin, cyfluthrin, cyhalothrin, cyhalothrin, cyhalothrin, cyhalothrin, cyhalothrin , Deltamethrin, etofenprox, fenpropathrin, fenvalerate, flucitrinate, flufenprox, flufenprox linate, furamethrin, halofenprox, imiprothrin, permethrin, phenothrin, plethrin, phrethrin, pyrethrin, pyrethrin. (Tefluthrin), tralomethrin, transfluthrin and the like.

  Examples of neonicotinoid agents include acetamiprid, clothianidin, dinotefran, imidacloprid, nitenpyram, and thiacloprid.

  Examples of the diamide agent include chlorantraniprole, cyantraniprole, cyclaniliprole, tetraniliprole, and flubenzamide. .

  Examples of insect growth control agents such as benzoyl urea agents include bistrifluron, chlorofluazuron, diflubenzuron, flucycloxuron, flufenoxuron, and flufenoxuron. May include hexafluuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron, buprofezine, and buprofezine.

  Examples of the diacylhydrazone agent include chromafenozide, halofenozide, methoxyphenozide, tebufenozide, and the like.

  Examples of the juvenile hormone agent include diophenolan, phenoxycarb, hydroprene, methoprene, and pyriproxyfen.

  Examples of insecticidal substances produced by microorganisms include, for example, abamectin, emamectin benzoate, ivermectin, repimectin, milbemectin, nemadectin, and nemadectin. Examples include Nikkomycin, spinetram, spinosad, and BT agent (Bacillus thuringiensis and insecticidal protein product).

  Examples of the insecticidal substances derived from natural products include anabasine, azadirachtin, deguelin, fatty acid glyceride, hydroxypropyl starch, soybean, and soybean. ), Nornicotine, sodium acid oleate, machine oil, petroleum glycol monofatty acid ester, rape oil, rotenone, rotenone, etc. It is possible.

  Other insecticides include, for example, acetoprole, afidopyropen, bensultap, brofuranilide, cartap, thiocyclam, chlorphen, chlorphen diafentiuron, dichloromezothiaz, etiprole, fipronil, flometoquin, flonicamid, fluhexaflon, fluhexaflon, fluhexaflon Renone (hydramethylnon), Indoxacarb, metaflumizone, metaldehyde, nicotin sulfate, pymetrozine, pirafluryl, pirafluryl ), Pyriprole, spirotetramat, sulfluramide, sulfoxafluor, triflumezopyrim, tolfenpyrad, tolfenpyrad Mention (triazamate) etc. can be mentioned.

  Examples of acaricides include acequinocyl, amitraz, azocyclotin, benzomate, bifenazate, binopacryl bromide, benzocyclate , Clofentezine, cyenopyrafen, cyflumethofen, tricyclohexyltin hydroxide, dicofol, dienochlor, diflovida, dilovida Tetrazole (ethoxazole), Fenazafuroru (fenazaflor), fenazaquin (fenazaquin), fenbutatin oxide (fenbutatin oxide), fenothiocarb (fenothiocarb), fenpyroximate (fenpyroximate), fluacrypyrim (fluacrypyrim), hexythiazox (hexythiazox), pyrimidifen (pirimidifen), polynactin complex (Polynactins), propargite, piflubumide, pyridaben, spirodiclofen, spiromesifen, tebufenpyrad (Tebufenpyrad), tetradiphone and the like.

  Examples of nematicides include aluminum phosphide, benclothiaz, cadusafos, etoprofos, fluensulfate, fluopyramite, fluopyrathium imicyafos), levamisol hydrochloride, mesulfenfos, metham-ammonium, methyl isothiocynate, morranteltartrate tartrate , Thifluzamide (thifluzamide), can be exemplified Chiokisazafen (tioxazafen) or the like.

  Examples of the poison bait include chlorofacinone, coumatetralyl, diphacin, difluoroacetate, warfarin, and the like.

  At least one compound selected from a 2-aminonicotinic acid ester derivative represented by the formula [I] and a salt thereof, which is an active ingredient of the pesticidal composition of the present invention, and at least a compound selected from compounds having an insecticidal activity. The mass ratio with one compound is 0.1: 99 to 99: 0.1 (ratio of the total mass when two or more are mixed), preferably 0.1: 80 to 80: 0.1, More preferably, it is 0.1: 50 to 50: 0.1 (ratio of the total mass when two or more are mixed).

  The pest control composition provided by the present invention can be used for the prevention, extermination and treatment of harmful pests in agriculture, indoors, forests, people, livestock, hygiene and the like. Specific use scenes, target pests, and usage methods are shown below, but the contents of the present invention are not limited to these.

  The pest control composition of the present invention includes agricultural crops such as food crops (rice, barley, wheat, rye, oats and other wheat, potatoes, sweet potatoes, taro, potatoes such as potatoes, soybeans, red beans, Beans such as broad beans, green beans, green beans, peanuts, corn, persimmons, buckwheat, etc., vegetables (cabbage, Chinese cabbage, radish, persimmon, broccoli, cauliflower, komatsuna), cruciferous crops, pumpkin, cucumber, watermelon, mama Cucumber, melon, zucchini, cucumber, cucumber, cucumber, aubergine, eggplant, tomato, pepper, red pepper, mushrooms, mushrooms, mushrooms, spinach, red pepper, etc. Carrot, Mitsuba, Parsley, Celery, Udon and other cereals, lettuce, burdock and other asteraceae, garlic, onion, green onions, leeks Green onions, asparagus, shiso, lotus root, etc.), mushrooms (shiitake, mushrooms, etc.), fruit trees / fruits (citrus, apple, pear, peach, plum, cherry peach, Yi, apricot, persimmon, persimmon, persimmon, no flower fruit) , Akebono, Blueberry, Raspberry, Pineapple, Mango, Kiwifruit, Banana, Strawberry, Olive, Walnut, Chestnut, Almond, etc.) Fragrance and other ornamental crops (lavender, rosemary, thyme, sage, pepper, ginger, etc.), special Crops (tobacco, tea, sugar beets, sugar cane, igusa, sesame, konjac, hops, cotton, hemp, olives, rubber, coffee, rapeseed, sunflower, mulberry, etc.), crops for pasture and feed (timothy, clover, alfalfa, etc.) Legume grass, corn, sorghum, orchard grass, etc.), turf (Korean turf, bentgrass, etc.), forest (Todomatsu, Ezomatsu, pine, hiba, cedar, camellia, etc.) and ornamental plants (kiku, rose, carnation, lily, eustoma, perennial haze, stachys, orchid, herbs, sakura, etc. Pests such as arthropods, molluscs, nematodes, etc., and fungi such as fungal gates, deformed fungi, bacterial gates, actinomycetes, etc. Can also be used to Specific pests are shown below.

  Examples of the Lepidoptera of the Arthropoda family include, for example, Helicoverpa armigera, Heliothis spp., Agrotis segetum, and Amanira agura. Trichoplusia ni), Mushroom brassicae, Spodoptera physalis moth (Spodoptera algae), Spodoptera algae (Spodoptera moth) Agrophyceae (Adoxophyces honmai), Midlekakumonamaki (Archips fuscocupreanus), Chachamaki (Homona magnima) et al. (Lyonetia punifoliella malinella), peach leaf moth (Lyonetia clarkella), and the like, Phyllocnistis citrella, and the like, Etc. Atohigekoga Department of Negikoga (Acrolepiopsis sapporensis), etc. Kosukashiba of sesiidae (Synanthedon quercus), etc. Kakinohetamushiga of Nisemaikoga Department (Stathmopoda masinissa), such as pink bollworm of Kibaga Department (Pectinophora gossypiella), peach fruit moth of Shinkuiga Department (Carposina niponensis), etc., Ilaga (Monema flavcens), Hiloheria Oiraga (Parasa lepida), Himekuroiraga (Scopelodes contracus), etc. s), Cnaphalocrosis medinalisa, Hamella undalis, Pseudomonas terridium, Pseudosidae, D. , Swallowtail butterflies (Papilio xtus), etc., Pieris rapae crucivora, etc. Spruce family shrimps (Agrius convolvuli), etc. Examples include adults, larvae and eggs such as Spirosoma imparilis), Hyphantria cunea, etc., Grapeberry moss (Endopizia viteena), Kodlinga (Laspeyresia pomonella) and the like.

  As for Coleoptera, for example, Anomala cupuria, Populus japonica, Oxycetonia jucunda, and Acramula genus ), Etc., Melanotus fornumi, etc. hoderus et al., Alacophora femorialis, root worm species (Diabrotica spp.), killer beetle (Pyllotreta striata), sid beetle (Cassida nebulosa) Epilachna varivestis), Colorado potato beetle (Leptinotarsa decemlineata), etc. Worms (Curculio sikkimensis), rice weevil (Lissohoptrus oryzophylus), adult weevil (Anthonymus gradis grandis), swan weevil (Pseudophrus venus, etc.) .

  Examples of the Hemoptera Heteroptera include, for example, the Eurydema rugosum, Eysarcoris lewisi, Egesarvus, Eminsarvus Chabae stink bug (Platia stali), Hedgehog beetle (Harymorpha mista), etc. clavatus), Hosoharikameme (Cletus puntiger), etc. Azogicalus spp. (Apolygus spinolina), Akasujikasmikame (Stenothus rubrovittalus), Trichonotylus coelestialium, etc .; Eggs and the like.

  Examples of Homoptera are Homoptera, such as Platypleura kaempferi, Arboridia apicalis, and E. cincticeps), Nephotettix virescens, etc., Lamindelfadi stellatellus, Niloparavata lugens, Sagelochamocha Tissima) and other species, Psylla pyrisuga, Diphaphorina citri, and the like Citrus whitefly (Dialeurodes citri), Onitsu whitefly (Trialeurodes vapariorum), etc., Grape aphids of the phyllocera family (Viteus vitifolisii), etc. civora), cotton aphid (Aphis gossypii), potato aphid (Aulacorthum solani), radish aphid (Brevicoryne brassicae), Komi can aphid (Toxoptera aurantii), mandarin orange black aphid (Toxoptera citricidus), elder aphid (Aulacorthum magnoliae), pear Aphids (Schizophis piricola), Nasimidori aphids (Nippolachnus piri), Nisedaikon aphids (Liphaphis erysimi), Momokotera punishi (Hyrapterus pruni) richophorus chrysanthemi), chrysanthemum Princess aphid (Macrosiphoniella sanborni), broad bean aphid (Megoura crassicauda), thorns aphid (Sitobion ibarae), tulip aphid (Macrosiphum euphorbiae), instead Cobb aphid (Myzus varians), green peach aphid (Myzus persicae ), Red butterfly aphid (Rhopalosiphum rufiabdominalis), wheat beetle aphid (Rhopalosiphum padi), wheat aphid (Sitobion akebiae), apple rotifer ( Riosoma lanigerum, etc., Icerya purchasi, etc. Horned weevil (Ceroplastes ceriferus), ruby rotifer (Ceroplastes rubens), etc., Aonidiella aurantii, Compositocaspis perniciosa, udaulacaspis pentagoa), Unaspis yanonensis (Unaspis yanonensis) adult like include larvae and eggs.

  The Thysanoptera includes, for example, the thrips, the thrips, the thrips, the thrips, and the thrips. , Citrus thrips dips leatus) adults such as, include the larvae and eggs.

  Examples of the bees (Hymenoptera) include, for example, the wasps of the wasps (Athalia roseae ruficornis), the horn bees (Arge pagana) and the like; Examples include adults, larvae and eggs such as Megachile nipponica nipponica, and other species of the antaceae, such as Formica japonica.

  Examples of the fly order (Diptera) include, for example, Asphondylia yushimai, etc., and Rhabocchlaena japonica, etc. Drosophila suzukii, and the like, the leafy legume, Lilymyza trifolii, and zoe Flies family seedcorn maggot (Delia platura), onion maggot (Delia antiqua) adult like include larvae and eggs.

  Examples of the locust (Orthooptera) include, for example, Rusporia lineosa, etc., crickets, Truljalia hibinonis, etc., vegetatives such as Glylotalpa orientalis, etc. Examples include adults, larvae and eggs.

  Examples of the termites (Isoptera) include adults, larvae and eggs such as the termite family Odontotermes formosanus.

  Examples of the order of the order Dermaptera include adults, larvae and eggs such as the beetle (Labidura riparia).

  Examples of Collembola of the Arthropoda elegans include Coleoptera (Sminthulus viridis), adults such as Onchiurus matsumotoi, and larvae such as Onchiurus matsumotoi.

  Examples of the Isopoda of the arthropod crustacean include adults, larvae, and eggs such as Armadillium vulgare of the family Dendrobidae.

  Examples of the mites of the arthropod spider class (Acari) include, for example, Polyphagotarsonemus latus and Pythanemus pallidus, and Penthaleus mahidae. Spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite spider mite (Pananychus urmiw), a spider spider mite spider mite (Pananychus ulmi), a spider mite spider mite (Tetranichus urtica), iennesis), Ogonychus ununguis, Eottranychuis kankitus, Clover spider mite (Bryobia praeosa), and Acarops pelek Grape ticks (Colomerus vitis), moss mite (Aculus fockeuui), chanosabi mite (Calacarus carinatus), and the like, Tyrophagus putrescentiae, Robin maggot ini) and the like, larvae and eggs.

  Examples of the archaeenioglossa of the molluscian gastropods include, for example, Pomacea caliculata, etc., Plumata, for example, Achatina falica, Achatina falica, The slugs (Meghiatum bilineatum), Niwako-ura-nakuji (Milax gagates), The-spotted-spotted aphidaceae (Lehmannina valeniana), and the spiders of the family A.

  Examples of the Tylenchidae of the linear animal genus genus class include, for example, the Anguinaceae Imogusaresenchu (Ditylenchus destructor), the Tyrenchorinchus Crytonienaceae, Pratylenchus penetran, Pratylenchus coffeae, etc., Helicotylenchus dihystera, etc. yne incognita), etc., such as the sum of the Kurikonema Department of nematodes (Criconema jaejuense), strawberries main nematode (Nothotylenchus acris), etc. of Anguina family, affection blast Lee Death Department of strawberry nematode (Aphelecchoides fragarriae), and the like.

  Examples of the Coleoptera, Drymeridae, include the long-tailed nematode (Xifinema sp.) And the trichodrus family Trichodorus sp.

Examples of fungi and bacteria such as fungal gates, deformed fungi, bacterial gates, actinomycetes, etc. include rice blast (Piculararia oryzae), sesame leaf blight (Cochliobolus miyabeanus), and blight (Rhizoctonia solani). , Pantoea ananatis, idiot seedling disease (Gibberella fujikuroi), seedling blight (Pythium graminicolum), brown streak (Acidovorax avene subcodine avenae), leaf sheath brown disease Xanthomonas oryzae pv. Oryzae), withering bacterial diseases (Burkholderia plantarii), etc .; wheat powdery mildew ( rysiphe graminis), red rot (Gibberella zeae), red rust (Puccinia striformis, P. graminis, P. recondita, P. hordei), snow rot (Typhala sp. U. nuda), Tilletia caries, Pyodercosporella herphotrechoids (Rhynchosporium leaf), Cloudy disease (Rhynchosporum secolid), Septoria tritium disease ) Helminthosporum zonatum Ikata, black node disease (Pseudomonas syringae pv. Japonica), etc .; citrus black spot disease (Diapotheum citri), common scab (Elsinoti foil rot) Brown rot (Phytophthora citrophthora, P. nicotianaae), black scab (Phyllostictina citricarpa), etc .; apple monilia disease (Monilonia palli disease), brown spot disease (Diplocarpal illness) leukotricha) Spotted leaf disease (Alternaria mali), black spot disease (Venturia inaequalis), black spot disease (Mycospherella aporum), anthracnose (Colletotrichum acutarum), red leaf disease (Bloemella cingula) Disease (Zygophyla jamaicensis), soot spot disease (Gloodes pomigena), etc .; none black spot disease (Venturia nashicola, V. pirina), powdery mildew (Phyllactinia mary), black spot disease (Alternaria kikuchiana), erythematosis (Gimnosporium haraenum), erythema disease (monilia fructigena) Monilinia fracticola, anthrax (Glomerella cingula), larvae of larvae (Monilinia fukuticola), black scab (Cladosporium carposis) Disease (Xanthomonas camp) estris pv. pruni) et al; Grapes black rot (Elsinoe ampelina), late rot (Colletotrichum acutatum), Glomerella cinulata, powdery mildew (Uncinula necator), rust pso , Downy mildew (Plasmopara viticola), black scab (Cladosporium viticolum), root bacilli (Agrobacterium vitis), etc .; oyster anthracnose (Gloeosporium kaki), powdery mildew (Phila leaf disease) Cercospora kaki, My Oshaerella nawae), Kiwi fruit horn spot disease (Phomopsis sp.), Anthracnose (Colletotrichum gloeosporioides), White leaf blight (Rosellinia necatrix leaf spot) eriobotryae), etc .; Colletotrichum lagenarium, powdery mildew (Sphaerotheca furiginea, Oidiopsis taurium), vine blight (Didymella brilliae), operonospora cubensis), late blight (Phytophthora sp. ), Seedling blight (Phythium sp., Rhizoctonia solani), etc .; cucumber spot bacterial disease (Pseudomonas syringae pv. Melon brown spot bacterial disease (Xanthomonas campestris pv. Cucurbitae), hair root disease (Agrobacterium rhizogens), scab (Septopmyces sp.), Etc .; Bacterial disease of vegetables (Ralstonia solanacerum) ) Etc .; Tomato ring-rot (Alternaria solani), leaf mold (Cladosporium fulvum), plague (Phytophthora infestans), scab (Pseudocercospora fulgena), powdery mildew (Ericum cerium). michiganense), stem rot (Pseudomonas corrugata), soft rot (Pectobacterium carotovorum subsp. carotovorum), etc .; brown scab (Phomopsis vexans), mildew disease verosiella natrassii), black blight (Corynespora melangenae), brown rot (Paracercospora egenula), brown rot (Phytophthora acaporici) and vermicillium palliosis Black spot disease (Alternaria japonica), white spot disease (Cercosporella brassicae) soft rot disease (Pectobacterium carotovorum subsp. Carotovorum), yellowing disease (Verticillium dahliau eda pu seu) pudding, marginalis), black rot (Xanthomonas campestris pv campestris) and the like;. lettuce downy mildew (Bremia lactucae) bottom rot (Rhizoctonia solani), Rot (Pseudomonas cichorii, Pseudomonas viridiflava), spot Bacterial (Xanthomonas campestris pv. vitians), downy mildew (Peronospora destructor), black spot (Alternaria porri), rust (Puccinia allii),
Southern blight (Sclerotium rolfsii), etc.; (. Colletotrichum truncatum, Colletotrichum trifolii, Glomerella glycines, Gloeosporium sp) Soybean purpura (Cercospora kikuchii), anthracnose, downy mildew (Peronospora manshurica), stem blight (Phytophthora sojae) , Black mildew (Elsinoe glycines), black spot disease (Diaporthe phaseolum var. Sojae), bacterial spot disease (Pseudomonas savasanoi pv. Glycinea et al. Colletotrichum lindemthianum, blight (Pseudomonas savastanoi pv. Phaseoliola), leaf blight (Xanthomonas campesti ps. Phasori disease) personata), brown spot disease (Cercospora arachidicola), etc .; pea bean powdery mildew (Erysiphe pisi), etc .; potato summer fungus (Alternaria solanonis), plague (Phytophthora insoils disease) (Pectobacterium c . Rotovorum subsp carotovorum) and the like; strawberry powdery mildew (Sphaerotheca humuli), anthracnose (Colletotrichum gloeosporioides, Colletotrichum actatum, Glomerella cingulata), late blight (Phytophthora nicotianae), Wamadarabyo (Dendrophoma obscurans), buds bacterial grain rot (Pseudomonas marginalis pv. marginalis) et al; brown brown streak of tea (Pseudocercospora theae), anthracnose (Desculatheae-sinensis), ring spot disease (Pestarotropis theae, Pestarotropis longiseta), the network has disease (Exobasidium reticulatum), has disease (Exobasidium vexans), win disease (Elsinoe leucospila), red grilled disease (Pseudomonas syringae pv. theae, scab (Xanthomonas campestris pv. theicola), etc .; tobacco red rot (Alternaria longipes), powdery mildew (Erysiphaticobacter's disease) Nicotianae, Blight disease (Ralstonia solaacearum), Cavity disease (Pectobacterium carotovorum subsp. carotovorum) and the like; Cercospora beticola, root rot (Rhiston rot) erys), seedling blight (Aphanomyces cochliodes), etc .; rose black spot (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosain), etc .; Agrobacterium tumefaciens, etc .; Gray mold disease of various crops such as eggplant, cucumber and lettuce; Botrytis cinerotiarum; Sclerotidium sclerotiorum; incarnate, Fusarium nivale, Sclerotinia boreali ), Powdery mildew (Erysiphe graminis), Faringling disease (Lycoperdon perlatum, Lepista subnudo, Marasumius oreades), pseudoleaf rot (Ceratobasidium spp.), Blight disease , Leaf rot (Rhizoctonia solani), Pysium disease (Phythium periplocum, Pythium vanterpoolii), rust disease (Puccinia spp.), Dollar spot disease (Sclerotinia humamorp) Disease (Colletotrichum sp. ), Fusarium oxysporum f. Sp. Batatas, carnation powdery mildew (Oidium dianthi), gerbera powdery mildew (Sphaerotheca fuliginea), anthracnose (Collesprit. sclerotiorum), mushroom wilt disease (Fusarium oxysporum), powdery mildew (Erysiphe cichoracearum), mycorrhizal disease (Sclerotinia sclerioirum), vermicillium dahliae phytopathy (Colletotrichum gloeosporioi es), powdery mildew (Oidium subgenus Reticuloidium), mycorrhizal disease (Sclerotinia sclerotiorum), cosmos anthracnose (Colletotrichum acutatum, Gloesporium sp.), powdery mildew (Sca Kasmiso powdery mildew (Oidium sp.), Fusarium monoliforme, mycorrhizal disease (Sclerotinia sclerotiorum), sweet pea powdery mildew (Oidium sp.), Wilt disease (Fusarium sp.) (Verticillium dahlia), anthrax (Glomere) la cingulata, Colletotrichum gloeosporioides), Stachys anthracnose (Glomerella cingulata), powdery mildew (Oidium sp.), Fusarium oxysporum Schlechtendrh. Anthracnose (Colletotrichum gleoosporioides, Colletotrichum higginsianum), Blight (Fusarium avenaceum), Half body wilt (Verticillium dahliae), Anthracnose of Eustoma tum), stalk rot (Fusarium avenaceum), powdery mildew (Oidium sp. ), Sclerotia sclerotiarum, sunflower powdery mildew (Sphaerotheca fusca, Erysiphe cichoraceuarum), sclerotia sclerotia peltih Examples include fungi and bacteria that cause scab (Sphaerotheca fulignea, Oidium sp.), Mycorrhizal disease (Sclerotinia sclerotiorum), marigold half body wilt (Verticillium dahliae), etc.

  The pest control composition of the present invention works indoors in buildings including ordinary houses, harms wood and its processed wooden furniture, stored food, clothing, books, etc., and damages our lives. It can also be used to control pests that give off. Specific pests are shown below.

  Examples of the termites of the Arthropoda elegans include, for example, Reticulitermes superatus and Cyptotermes larvae (Cryptoptermes larvae) and Cyptotermes larvae (Cryptothermes larvae). Can be mentioned.

  As for Coleoptera, for example, weevil (Sitophilus zeamais), weevil (Stophyrus zeumis) such as weevil (Stophylus zeumis), burs weevil (Bracus weevil). Trilobium castaneum, Tricholium confusum, etc., Solanumaceae, Oryzaephilus surinamensis, and the like. Tobacco beetle (Lasioderma serricorne), drugstore beetle (Stegobium paniceum), etc., Hime beetle (Attagenus unicolor japonicus), varied carpet beetle (Anthrenus verbasci), Hara Giro carpet beetle (Dermestes maculatus) and the like, fake cell circle leopard Hong Musi of Hyouhonmushi Department of Dermestidae (Gibium aequinnoctiale) and other species of the genus Nagasinkidae (Dinoderus minutus), Rhizopertha dominica, and the like, the scallop worm (Lycnecus worm) Adult larvae such as larvae and eggs.

  As the Lepidoptera, for example, Cadra cautella, Ephestia kuehniella, Plodia interpuntella, and the like, (Tinea translucens), adult larvae such as Koiga (Tineola bisselliella), larvae and eggs.

  Examples of the scallops include adults, larvae, and eggs such as Lepinothus reticulatus and the like, Liposcelis botrychofilus.

  Examples of the cockroach include adult insects such as cockroaches of the cockroach family (Blattella germanica), cockroaches of the cockroach family (Periplaneta fuliginosa), periplaneta japonica, and larvae.

  Examples of the order include adults such as Yamatosimi (Ctenolepisma villosa) and Lepisma saccharina (Lepidma saccharina), larvae and eggs.

  Examples of the fly order include adults, larvae, and eggs such as Drosophila melanogaster, Pseophilae cheese flies, and the like.

  Examples of the mites of Arthropoda spiders include, for example, Tyrophagus putrescentiae, Lardoglyphus konoi, and the like, and Carpoglyphus lactis, an adult of the mite larvae and Carpolyphus lactis.

  The pest control composition of the present invention can also be used to control pests that damage or weaken trees in natural forests, artificial forests, and urban green spaces. Specific pests are shown below.

  Examples of the Lepidoptera of Arthropoda are, for example, Calliteaara argentata, Chadokuga (Euprocitis dispurocondasper), Origia recombis (Orygia genga pusuma), , Species of the family of the family of the family (Melacosoma nestria testacea), matsukareha (Dendrolimus superbalis), etc. Tum), etc., Phycholoma lecheana circumcrusana, Ciriga cyti kurokoi, H. stigma (Cyptera) Stigmella castanopsiella, etc., Paratha lepida of the family Iraga, Scopelodes contracus, adults such as Microleon longipalpis, and the like.

  As for Coleoptera, for example, Anomala rufocuprea, Heptophylla picea, etc. Japanese cedar beetle (Basilepta pallidula), etc. Bark beetles (Indocryphalus aceris), etc., Naga Shinkuimushi family lesser grain borer (Rhizopertha dominica) adult like include larvae and eggs.

  Examples of the order of the stink bug include Cinara todocola of Aphididae, Ezomatsukaabura of Aphididae (Adelges japiconicus), Apidiotus cypropidae of Aphididae, And adults such as (Ceroplasts ceriferus), larvae and eggs.

  Examples of the bees include adults such as the bee family Papynematus itoi and the like, the honey bee family Neodipion serf and the like, and the young adults such as the bee family Drycosmus kuriohilus and the like.

  Examples of the fly order include, for example, Tipula aino in the family Ganbo, etc .; Examples include larvae and eggs.

  Examples of the mites of the arthropod arachnid include adults, larvae, and eggs such as Oligonicus hornoensis and Oligonicus ununguis.

  Examples of the linear animal genital genus Tylenoptera include, for example, Bursaphelenchus xylophilus belonging to the family Parasitaferenx.

  Examples of fungi and bacteria such as fungal gates, modified fungi, bacterial gates, actinomycetes, and the like include, for example, Acacia shark skin blight (Botryosphaeria sp.), Anthrax (Glomerella singulata), hydrangea ring pattern Disease (Phoma exigua), spot disease (Phyllosticta hydrangea), brown spot disease (Corynespora cassiicola), leaf rot (Rhizoctonia solaini), powdery mildew (Oidium sp. hydrangeae), ginkgo soy spot disease (Gonatobotryum apiculatum), red rot disease (Erythricium salmonicoror) ), Red rot of rice (Gymnosporangium yamadae), white rot (Rosellinia necatrix), black rot of maple (Rhytisma acerinum), crested leaf blight (Cristularella moricola), body rot. , Cercospora sp., Anthracnose (Colletotrichum gloeosporioides), Red rot (Erythricium salmonicol), Powdery mildew (Uncinula sp., Sawadaea sp. Phomatospora albomaculans), powdery mildew (Uncinula sp., Microspha) ra alphitoides, Erysiphe gracilis), Karamatsu arai mellia, rot heart disease (Phaeolus schweinitzii), citrus brown leaf disease (Septoria chiensis), or the body blight. Anthracnose (Glomerella singulata), suspicious mildew (Pesaloora okinawaensis), spot disease (Phaeosphaerella gardeniae), brown spot of zelkova (Pseudocercospora zelmello) Phyllactinia magnoliae, Spotted disease (Phyllosticta concentrica), Phelalacta phytoidosis, Nectaria galidigena, Neckia phellitus adenosis (Agrobacterium tumefaciens) Diseases (Taphrina wiesneri), larvae of nuclear disease (Monilinia kasanoi), bamboo shoots (Armilaria mellea), blight (Valsa ambiens), scab (Sphaceroma punicaeul) ), Brown Diseases (Pseudocercospora lythracearum), ring-leaf blight (Cristulariella moricola), scabies (Pseudocercospora crataephalus), leaf blight (Bascheaealus disease) Colletotrichum gleosporioides, leaf spot disease (Pseudocercospora handelii), white spotted blight (Rosellinia necatrix), shoot blight (Sclerotium sp.). ), Red blight (Cercospora sequoiae), microphage nuclear disease (Macrophopha phaseolina), red leaf blight (Ascochyta sp.), Azalea powdery mildew (Microsphaera izuensis), brown spot disease (S) , White leaf blight (Rosellinia necatrix), seedling blight (Rhizoctonia solani), leaf spot (Pseudocercospora handelii), spot disease (Phylostatica maxima), flower rot fungus nuclei ), Root rot of Tsubaki (Phytophthora cinnamomi), anthrax (G omerella singulata), falcon symptom (Armillariella mellea), powdery mildew of rose (Sphaerotheca pannosa, Oidium sp.), downy mildew (Peronospora sparsa), morco disease, cercos ), Black scab (Marssonina rosea, Diplocarpon rosae), rot (Cryptosporella umbrina), white rot (Rosellinia necatrix), cypress morbidity (Armillariella peltiera) alotiopsis sp.), Erwinia herbicola pv. milletiae, poinsettia root rot (Rythium sp.), bedridden plague (Phytophthora cactorum), powdery mildew (Ery. ), Anthracnose (Gloeosporium sp.), Brown spot (Pseudocercospora variicolor), mycorrhizal disease (Sclerotinia sclerotiorum), blight (Botrytis paeoniae), white rot (Resellid) euonymi-japonici), brown spot (Pseudocer) cospora destructiva), knot disease (Cronartium quercuum), seedling blight (Rhizoctonia solani, Fusarium sp.). , Phythium sp ,,), leaf blight (Pseudocercospora pini-densiflorae), backspot of edible mushrooms (Coccoidea querricola), powdery mildew of citrus (Misphaea or ol pud) Disease (Marssonina brunea), Eucalyptus keratosis (Cercospora epicoccides), Snowy-headed fungus (Pseudocercospora spiraeciala), Powdery mildew (Sphaerotheca spirae), Sphaerotheca spirae , Fungi and bacteria that cause branch 枯菌 rot (Sclerotinia sclerotiorum), and the like.

  The pest control composition of the present invention is used internally or externally to vertebrates, particularly warm-blooded vertebrates such as cattle, sheep, goats, horses, pigs, poultry, dogs, cats and fish. It can also be used to prevent, treat, or control parasitic arthropods, nematodes, flukes, tapeworms, protozoa, and fungi. It can also be used to prevent and treat the occurrence and spread of diseases of organs such as the skin, digestive system, and respiratory system caused by the infestation of pests on the surface of humans, livestock, and pets. . In addition to the above, the target animal species include rodents such as mice, rats, hamsters and squirrels, carnivores such as ferrets, avian pets such as ducks and pigeons, and experimental animals. Specific pests are shown below.

  Examples of the fly order of the Arthropoda class include, for example, Tabanus rufidens, Tabanus chrysurus, etc. E., Gasterophilus intestinalis, etc., B. flies, Hypoderma bovis, etc., Oestrus ovis, etc., M. spiracularis), etc. Flies flies (Sepsis punctum), etc. Culex pipiens triaienorhynchus summorosus, Ades albopictus, etc. coides schulzei), chicken midges (Culicoides arakawae) adult like include larvae and eggs.

  Examples of fleas include adults, larvae and eggs of the family flea family (Plexex irritans), dog fleas and the like (Ctenocephalides canis).

  Examples of the lice include: Haematopinidae suis, Haematopinidae eurystenus, etc., L. Examples include adults such as chicken lice (Menpon gallinae), larvae and eggs.

  Examples of the mites of Arthropoda spiders include, for example, the honeybee mite (Varroa jacobsoni), the spider mite (Haemaphysalis longicornis), tick (Ixodes ovatatus), bovine tick (Ixodes ovatus), (Amblyomma testidinarium), etc. ), Etc. triacylate mites (Knemidocoptes mutans), ear mites (Otodectes cynotis of Kyuusendani family), bovine 9,000 mites (Psoroptes communis) adult like include larvae and eggs.

  Examples of the round worms of the linear animal gate line include cattle worms, swine nematodes, swine lung worms, ciliate nematodes, bovine intestinal nodules, and the like.

  Examples of roundworms include roundworms of pigs, roundworms of chickens, and the like.

  Examples of the genus Chlamydomonas include: Schistosoma japonicum, liver tetsu, deer buccal fluke, Westermann lung fluke, Japanese chicken egg fluke.

  Examples of tapeworms include foliate tapeworms, extended tapeworms, Benedencous tapeworms, square tapeworms, stabulata tapeworms, and ringworms.

  Examples of the root flagellate of the Protozoan gate flagellate class include Histomonas, etc., Protoflagellates, such as Leishmania, Trypanosoma, etc., Multiflagellates, such as Giardia, and Trichomonas, such as Trichomonas.

  Examples of the amoeba of the meat quality rope include, for example, Entamoeba.

  Examples of the sporeworm class Pyroplasma subclass include Theilaria, Babesia, etc., and examples of the late sporeworm subclass include Eimeria, Plasmodium, Toxoplasma, etc.

  Examples of the fungi and bacteria include Trichophyton rubrum and Trichophyton mentagrophytes which are ringworm fungi; Gram-negative bacteria, Gram-positive bacteria such as Staphylococcus aureus, and the like.

  The pest control composition of the present invention maintains a public health state against pests that cause direct harm or discomfort to the human body, or against pests that carry or transmit pathogens and diseases caused by them. Can also be used. Specific pests are shown below.

  Examples of the Lepidoptera of Arthropoda elegans include, for example, Spragageidus similis, etc., Kunugia undans, etc., Parasa consocia, etc. martini) and the like.

  Examples of the order of Coleoptera include Xanthochaa waterhousei, etc., Epicauta gorhani, etc.

  Examples of bees include, for example, Vespa simillima xanthoptera, Brachyponera chinensis, etc., and Batozonellus anulus anulus.

  Examples of the fly order include, for example, Armigeras subalbatus, etc., Cypridoidus nipponensis, and Chironomus yosimuum, etc. , Hirosia humilis, etc., Musca domestica, etc., Fannia cercolaris, etc., P. falconae, Phromidae. Adult larvae such as larvae and eggs.

  Examples of fleas include adults such as human fleas (Pulex irritans), larvae and eggs.

  Examples of the cockroach include the German cockroach (Blatella germanica), the cockroach family (Peripraneta americana), the black cockroach (Periplaneta fuliginosa), and the like.

  Examples of the locust (Orthooptera) include adults, larvae, and eggs such as Drostrammena japonica and Dystrammena apicalis.

  Examples of the lice include adults, larvae, and eggs such as the head lice (Pediculus humnus humus) of the family Lamiaceae and the pheasant pheasant (Phyrius pubis).

  Examples of the order of the stink bug include adults, larvae and eggs of the grass turtle (Isyndus obscurus) such as the bed bug (Cimex electrarius).

  Examples of the Coleoptera of the arthropoda side insect class include adults, larvae, and eggs such as the genus Hypostrura communis of the family Murasakibambimuidae.

  As the mites of the arthropod spider class, for example, Ixodes persulcatus, etc., Mite mite (Ornithonyssus bacoti), etc. (Pyemotes ventriciosus), etc. And eggs.

  Examples of the true spiders include the genus Spiders of the family Spiders of the genus Spiridae (Chiracanthium japonicum, etc.), the spiders of the family Spiders of the genus Spiders, Examples include adult larvae, larvae and eggs such as Uroctea compactis, Plexippus paykulli and Plexippus adanoni.

  Examples of the scorpion include adults, larvae and eggs such as the spotted scorpion (Isometrus europaeus).

  Examples of the centipede of the arthropod rhododendron include adults, larvae and eggs such as the centipede family Scorpendra subspinipes mutilans, Aompodade (Scorpendra subspinipes japonica), and the like.

  Examples of the moths include adults, larvae, and eggs such as the geese of the family Geleidae.

  Examples of the order of the order of the arthropod diploid class include adults, larvae and eggs such as the Oxidus gracilis.

  Examples of the isopods of the arthropod crustacean include adults, larvae and eggs such as Porcellio scabers of the family Paramecidae.

  Examples of the annelids of the annelid genus Lepidoptera include yamavir (Haemadipsa zeylanica japonica) and the like.

  The pest control composition of the present invention controls pests such as arthropods, gastropods, nematodes and fungi that damage crops, natural forests, artificial forests, urban greenery trees and ornamental plants. Especially for the prevention, treatment or control of pests such as arthropods, gastropods, nematodes, flukes, tapeworms, protozoa, fungi that harm or parasitize warm-blooded animals worth it. In such situations, the pesticidal composition of the present invention can be applied to other active compounds such as fungicides, synergists, plants in their commercially useful formulations and use forms prepared by these formulations. It can also be present as an admixture with modifiers, baits, pharmaceuticals or herbicides.

  The pest control composition of the present invention can be used as it is or in general as a pesticide, for example, a wettable powder, a wettable granule, a dry flowable, an aqueous solvent, an emulsion, a liquid, an oil, an aqueous suspension or aqueous. It can be used in dosage forms such as flowable agents such as emulsions, capsules, powders, granules, fine granules, baits, tablets, sprays, aerosols, aerosols and the like. For the preparation of these dosage forms, methods known in the technical field of agricultural and horticultural drugs can be used. In these preparations, the active ingredient compound is contained in a total amount of usually 0.1 to 99.9% by mass, preferably 0.2 to 80% by mass. In order to obtain these dosage forms, various agricultural chemical adjuvants conventionally used in the technical field of agricultural and horticultural medicine can be used as appropriate. Such agrochemical adjuvants can be used for the purpose of, for example, improving the effects, stabilizing, and improving dispersibility of agricultural and horticultural chemicals. Examples of the agricultural chemical adjuvant include a carrier (diluent), a spreading agent, an emulsifier, a wetting agent, a dispersing agent, a disintegrating agent, and the like.

  Liquid carriers include water, aromatic hydrocarbons such as toluene and xylene, alcohols such as methanol, butanol and glycol, ketones such as acetone, amides such as dimethylformamide, sulfoxides such as dimethyl sulfoxide, methyl Mention may be made of naphthalene, cyclohexane, animal and vegetable oils, fatty acids and the like. As the solid carrier, clay, kaolin, talc, diatomaceous earth, silica, calcium carbonate, montmorillonite, bentonite, feldspar, quartz, alumina, sawdust, nitrocellulose, starch, gum arabic and the like can be used.

  As the emulsifier and the dispersant, a normal surfactant can be used. For example, anionic surfactants such as higher alcohol sodium sulfate, stearyltrimethylammonium chloride, polyoxyethylene alkylphenyl ether, lauryl betaine, etc. Cationic surfactants, nonionic surfactants, amphoteric surfactants, and the like can be used.

  Moreover, spreading agents, wetting agents such as dialkylsulfosuccinate, fixing agents such as carboxymethylcellulose and polyvinyl alcohol, disintegrating agents such as sodium lignin sulfonate and sodium lauryl sulfate can be used.

  In order to control pests such as arthropods, gastropods, nematodes, and pathogenic fungi, pest control compositions are usually used in places where damage is caused by these pests. In addition to spraying on the stems and leaves of the plant where possible, all soil layers are mixed, cropping, side striping, floor soil mixing, cell seedling treatment, planting hole treatment, plant root treatment, top dress It can also be used after being treated in soil, etc., and absorbed from the roots, such as rice box treatment and water surface application. It can also be used by soaking seeds in chemicals, seed dressing, seed treatment such as calper treatment, application to nutrient solution in nutrient solution (hydroponic) cultivation, smoke, or trunk injection.

When used, it varies depending on the type and amount of pests and the target crop / tree type and cultivation form / growth state, but generally 0.1 to 1000 g, preferably 1 to 1000 g in total amount of active ingredients per 1000 m ² . Apply 100 g. To treat this, dilute with water in wettable powder, granule wettable powder, aqueous solvent, emulsion, liquid, flowable preparation such as aqueous suspension and emulsion, capsules, etc. Generally, it may be sprayed on crops or the like at an application rate of 10 to 1000 liters per 1000 m ² , although it varies depending on the type of plant and the cultivation form and growth state. Moreover, what is necessary is just to process to a crop etc. in the state of the formulation in a powder agent, a spray agent, or an aerosol agent.

When the target pest primarily harms plants in the soil or when the drug is absorbed from the roots to control the target pest, for example, the preparation is diluted or diluted with water. Without applying to plant stock or seedling nursery, etc., spraying granules to plant seedling or seedling nursery, etc., before sowing or transplanting, powder, wettable powder, granule Method of spraying wettable powder, granule, etc. and mixing with the whole soil, spraying powder, wettable powder, wettable granule powder, granule, etc. before sowing or planting planting holes, crops etc. Methods and the like. For wettable powders, granular wettable powders, aqueous solvents, emulsions, liquids, flowables such as aqueous suspensions and emulsions, capsules, etc., dilute with water and generally apply 5 to 500 liters per 1000 m ² Then, it may be sprayed on the soil surface or irrigated into the soil so as to be uniform over the entire area to be treated. In the case of powder, granule, bait or the like, the preparation may be sprayed on the soil surface so as to be even over the entire area to be treated. Spraying or irrigation may be around the seeds, crops or trees that you want to protect from harm. Further, the active ingredient can be mechanically dispersed by tilling during or after spraying. When processing to soil, it depends on the type and amount of pests and the target crop / tree type, cultivation form / growth state or soil type, but generally the total amount of active ingredients per 1000 m ² is 0.1. Apply ~ 1000g, preferably 1-500g.

  As a method for applying paddy rice to seedling boxes, the dosage form may vary depending on the time of application such as application at seeding, greening period, application at transplanting, etc., for example, powder, granules, fine granules In wettable powders, granular wettable powders, aqueous solvents, emulsions, liquids, flowable agents such as aqueous suspensions and aqueous emulsions, capsules and the like, they may be diluted with water. It can also be applied by mixing with cultivated soil, and can be mixed with cultivated soil and powder or granules, for example, mixed with floor soil, mixed with cover soil, mixed into the entire cultivated soil, and the like. Alternatively, the culture medium and various preparations may be applied alternately in layers.

  As a method of application to paddy fields, solid preparations such as jumbo agents, packs, granules, granule wettable powders, and liquid preparations such as flowables and emulsions are usually sprayed on flooded paddy fields. In addition, at the time of rice planting, an appropriate preparation can be sprayed and injected into the soil as it is or mixed with fertilizer. In addition, by using chemicals such as wettable powder, emulsion, flowable, etc. as the source of water flowing into the paddy field such as a water mouth or an irrigation device, it can be applied labor-saving along with the supply of water.

  Seed treatment methods include, for example, a method in which a liquid or solid preparation is diluted or undiluted and the seed is immersed in a liquid state to attach and permeate the drug, a solid preparation or a liquid preparation is mixed with the seed, Examples thereof include a method of dressing and adhering to the surface of the seed, a method of coating the seed by mixing with an adhesive carrier such as resin and polymer, and a method of spraying around the seed simultaneously with planting. The “seed” for performing the seed treatment means a plant body at an early stage of cultivation used for plant propagation. For example, in addition to seeds, nutrition for bulbs, tubers, seed buds, buds, baskets, bulbs or cuttings cultivation Mention may be made of plants for breeding. In addition, the “soil” or “cultivation carrier” of a plant when applied refers to a support for cultivating crops, particularly a support for growing roots, and the material is not particularly limited. Any material can be used as long as it can grow, so-called soil, seedling mat, water, etc. Specific materials include, for example, sand, pumice, vermiculite, diatomaceous earth, agar, gel material, polymer material, rock Examples include wool, glass wool, wood chips, and bark. When used, 0.001 to 50 g, preferably 0.01 to 10 g, of the total amount of active ingredients per kilogram of seed is applied.

  As the treatment of the cultivated plant to be transplanted and the treatment of the seedling raising period, in addition to the direct treatment to the seed, the irrigation treatment of the liquefied drug or the granule spraying treatment to the seedling nursery is preferred. In addition, it is also preferable to treat a granule in a planting hole at the time of planting or to mix it with a cultivation carrier in the vicinity of the transplantation site.

The pest control composition of the present invention is also valuable for protecting wood (standing trees, fallen trees, processed wood, storage wood or structural wood) from harms such as termites or cucumbers. In such a situation, it is possible to control oil, emulsion, wettable powder, sol, spraying, pouring, irrigation, application, dusting, granulation, etc. on wood or surrounding soil. it can. Also, oils, emulsions, wettable powders, powders, etc. used in this scene are mixed with other active compounds such as insecticides, acaricides, nematicides, fungicides, repellents or synergists. In these preparations, the total amount of the active ingredient compounds is 0.0001 to 95% by mass, preferably 0.005 to 10% by mass for oils, powders and granules, emulsions and hydration. In the case of an agent and a sol, it can be contained in an amount of 0.01 to 50 mass%. In the case of controlling termites or licorice, 0.01 to 100 g of active ingredient compound per 1 m ² is sprayed on the soil or wood surface.

  The pest control composition of the present invention can be used for storing products such as cereals, fruits, nuts, spices and tobacco as they are, in a powdered state or mixed in the product. It can be used to protect against damage by mosses and ticks. In addition, when storing animal products (skin, hair, wool, feathers, etc.) and plant products (cotton, paper, etc.) in a natural or converted state, attacks from Lepidoptera, Coleoptera, Spots and Cockroaches It can be protected, and can be protected from attacks by Lepidoptera, Coleoptera, flies and ticks when storing food such as meat and fish. In such situations, spraying oils, emulsions, wettable powders, powders, etc., installing resin transpiration agents, treating smoke and fumes, installing granules, tablets and poison baits, spraying aerosols, etc. Can be controlled with. These formulations can also be present as a mixture with other active compounds such as insecticides, acaricides, nematicides, fungicides, repellents or synergists, in these formulations. May contain 0.0001 to 95% by mass of the active ingredient compounds in a total amount.

  The pest control composition of the present invention is a composition of arthropods, humans and domestic animals / pets that directly parasitize human skin, livestock and pets, and cause direct harm such as eating or sucking skin. Arthropods, nematodes, flukes, tapeworms, protozoa, fungi, and other diseases that infest the body and cause or spread disease in organs such as the skin, digestive system, and respiratory system It is valuable for the control, prevention, or treatment of arthropods, which are mediators of arthropods, and arthropods that cause discomfort to humans. In such a situation, the pesticidal composition of the present invention is mixed in a small meal or feed, or contains an appropriate orally ingestible pharmaceutical composition, such as a pharmaceutically acceptable carrier or coating substance. Oral administration as tablets, pills, capsules, pastes, gels, beverages, medicinal feeds, medicinal drinking water, medicinal supplements, sustained-release large pills, and other sustained-release devices that are retained in the gastrointestinal tract Alternatively, it can be transdermally administered as a spray, powder, grease, cream, ointment, emulsion, lotion, spot-on, pour-on, shampoo and the like. In order to achieve the effect by such a method, the active ingredient compound is generally contained in a total amount of 0.0001 to 0.1% by mass, preferably 0.001 to 0.01% by mass. In addition, as a method for transdermal administration or local administration, a device (for example, a collar, a medallion, an ear tag, or the like) attached to an animal so as to control the arthropod locally or systemically can be used.

  Hereinafter, specific oral administration methods and transdermal administration methods when the pest control composition of the present invention is used as an anthelmintic agent, preventive agent, or therapeutic agent for animals such as domestic animals and pets or humans are shown. However, it is not necessarily limited to these.

  When administered orally as a medicinal drinking water, the active ingredient is dissolved or suspended or dispersed in a suitable non-toxic solvent or water with a suspending or wetting agent such as bentonite or other excipients. Solution, suspension or dispersion may be used. In general, beverages also contain an antifoam agent. The beverage formulation contains 0.01 to 1.0 mass%, preferably 0.01 to 0.1 mass%, of the active ingredient compounds in total.

  When it is desirable to administer orally in a dry individual unit dosage form, capsules, pills or tablets containing a predetermined amount of the active ingredient are usually used. These uses consist of mixing the active ingredient homogeneously with suitably finely divided diluents, fillers, disintegrants and / or binders such as starch, lactose, talc, magnesium stearate, vegetable gum and the like. Manufactured by. Such unit use formulations can vary widely in the content of active ingredients depending on the type of host animal to be treated, the degree of infection and the type of parasite and the body weight of the host.

  When administered by animal feed, the pest control composition of the present invention can be homogeneously dispersed in the feed, used as a top dressing, or used in the form of pellets. In order to achieve a desirable antiparasitic effect, the active ingredient compounds are contained in the final feed in a total amount of 0.0001 to 0.05% by mass, preferably 0.0005 to 0.01% by mass.

  An active ingredient dissolved or dispersed in a liquid carrier vehicle can be parenterally administered to animals by intragastric, intramuscular, intratracheal or subcutaneous injection. For parenteral administration, the active ingredient compounds are preferably mixed with a suitable vegetable oil, such as peanut oil or cottonseed oil. Such a prescription generally contains 0.05 to 50 mass%, preferably 0.1 to 5.0 mass% of the active ingredient compounds in total.

  Alternatively, a formulation in which the active ingredient is mixed with a suitable carrier such as dimethyl sulfoxide or a hydrocarbon solvent can be applied directly to the outer surface of the animal by spraying or direct injection.

  In addition, the pest control composition of the present invention is used as an anthelmintic agent for arthropods that directly cause harm or arthropods that are disease vectors, and the surrounding environment in which these pests can be latent. In contrast, spraying, injecting, irrigating and applying oils, emulsions, wettable powders, spraying powders, etc., fumigants, mosquito coils, self-burning smoke, chemical reaction fumes, etc. Dropping agent, treatment of smoke agent such as fogging, ULV agent, etc., installation of granules, tablets and poison bait, or floating powder, granules, etc. It can also be used by a method such as addition of. Furthermore, it can be controlled in the same way as the above-mentioned methods for farming, forest pests, etc., and for flies, etc., it is mixed in the feed of livestock. For example, a method of volatilizing the mosquitoes into the air with an electric mosquito trap is also effective. The preparations in these use forms can also exist as a mixture with other active compounds such as insecticides, acaricides, nematicides, fungicides, repellents or synergists. In this preparation, the active ingredient compounds are contained in a total amount of 0.0001 to 95% by mass.

[Formulation example]
Examples will be described below, but the present invention is not limited thereto.

Formulation Example 1
Compound No. 1 (10 parts) and fenitrothion (5 parts), xylene (55 parts), N-methyl-2-pyrrolidone (20 parts) and Solpol 3005X (mixture of nonionic and anionic surfactants, Toho Chemical Kogyo Co., Ltd. (trade name) (10 parts) was uniformly mixed and dissolved to obtain an emulsion.

Formulation Example 2
Compound No. 2 (10 parts) and etofenprox (2 parts), nip seal NS-K (white carbon, Tosoh Silica Co., Ltd., trade name) (20 parts), kaolin clay (Kaolinite, Takehara Chemical Co., Ltd., trade name) ) (58 parts), Sun extract P-252 (sodium lignin sulfonate, Nippon Paper Chemical Co., Ltd., trade name) (5 parts) and Lunox P-65L (alkyl allyl sulfonate, Toho Chemical Co., Ltd., trade name) ) (5 parts) was uniformly mixed and ground in an air mill to obtain a wettable powder.

Formulation Example 3
Compound No. 7 (20 parts) and Alanicarb (10 parts), nip seal NS-K (white carbon, Tosoh Silica Co., Ltd., trade name) (60 parts), LUNOX 1000C (naphthalene sulfonate condensate, Toho Chemical Industry Co., Ltd.) Product name) (5 parts) and Solpol 5276 (nonionic surfactant, Toho Chemical Co., Ltd., trade name) (5 parts) were uniformly mixed and ground in an air mill to obtain a wettable powder.

Formulation Example 4
Compound No. 5 was mixed with propylene glycol (5 parts), Solpol 7933 (anionic surfactant, Toho Chemical Co., Ltd., trade name) (5 parts) and water (55 parts) mixed in advance. 1 (10 parts) and buprofezin (5 parts) were dispersed to form a slurry mixture, and this slurry mixture was then wet pulverized with Dinomill (Shinmaru Enterprises Co., Ltd.), and then xanthan gum (0.2 parts) in advance. Was mixed well and dispersed in water (19.8 parts) to obtain a flowable agent.

Formulation Example 5
Compound No. 2 (10 parts) and tetradiphone (4 parts), Newkalgen FS-26 (mixture of dioctyl sulfosuccinate and polyoxyethylene tristyryl phenyl ether, Takemoto Yushi Co., Ltd., trade name) (5 parts), propylene glycol (8 Part) and water (56 parts) were mixed in advance, and this slurry-like mixture was wet-pulverized with Dynomill (Shinmaru Enterprises). Next, xanthan gum (0.2 parts) was thoroughly mixed and dispersed in water (16.8 parts) to prepare a gel-like material, which was sufficiently mixed with the pulverized slurry to obtain a flowable agent.

[Example of pest control test]
Examples of pest control will be described below, but the present invention is not limited thereto.
A 2-aminonicotinic acid ester derivative (compound A in the table below) which is an active ingredient of the pesticidal composition of the present invention and a compound having other insecticidal activity (compound B in the table below) are each acetone. After dissolving with dimethyl sulfoxide, it was diluted with water or dissolved with water to prepare a chemical solution in which Compound A and Compound B were mixed so as to have the concentrations shown in the table.
In addition, the compound A in a table | surface represents the compound of Table 1. Further, “-” in the table indicates that the corresponding drug was not tested.

Test Example 1: The insecticidal effect test for scallops was carried out for 3 weeks after sowing seeds in a jiffy pot. The chemical solution prepared to a predetermined concentration by the method described above was sufficiently sprayed on the leaves of the pot plant using an air brush. After air-drying the chemical solution, inoculate 10 eel larvae and keep them in a constant temperature room at 25 ° C. After 5 days of larvae, investigate the larvae's viability and bitter melon. Asked. The test was conducted using 1 seedling in each group.
Using the obtained insecticidal rate, the presence or absence of a synergistic effect was tested based on the following Colby equation (Calculating Synthetic and Antistatic Responses of Herbicide Combination, Weed 15, pp20-22, 1967).
E = A + B−A × B / 100
Here, E represents the expected value of the insecticidal rate, A represents the insecticidal rate of the compound A single treatment, and B represents the insecticidal rate of the compound B single treatment.
When the insecticidal rate (experimental value) obtained in the actual experiment is higher than the expected value (E) of the insecticidal rate calculated by the Colby formula, the pesticide composition of the present invention is synergistic with respect to pest control. It will have an effect. The results are shown in Table 2.

Table 2

  From the results of Table 2, in the effect test in which the pest control composition of the present invention was tested, the insecticidal rate obtained therefrom exceeded the expected value calculated by the above Colby's formula, and both have synergistic effects. showed that.

Test Example 2: Insecticidal effect test of cabbage against Japanese pearlworm The chemical solution prepared to a predetermined concentration by the above-described method was sufficiently sprayed onto the leaf stem portion of a pot-planted cabbage seedling grown for 4 weeks after sowing using an air brush. After the spray solution was air-dried, the leaves were cut out and placed in a resin cup having a diameter of 9 cm and a height of 5 cm together with five 3rd-year-old Spodoptera litura, and kept in a thermostatic chamber at 25 ° C. The mortality of the larvae and bitterness were investigated 4 days after the release, and the insecticidal rate (%) was determined by dying the bitter worms. The test was conducted with 2 seedlings in each ward, and the test was conducted with 20 animals per ward (1 ward, 5 heads, 4 trains).
Insecticidal rate (%) = Number of dead larvae / number of test larvae × 100
Using the obtained insecticidal rate, the presence or absence of a synergistic effect was tested based on the Colby equation described in Test Example 1. The results are shown in Table 3.

Table 3

  From the results of Table 3, in the effect test in which the pest control composition of the present invention was tested, the insecticidal rate obtained therefrom exceeded the expected value calculated by the above-mentioned Colby formula, both of which are synergistic effects showed that.

Test Example 3: Insecticidal effect test on peach peach aphids Leaf pieces infested with 50 to 80 aphid adult larvae were inoculated into the leaves of potted potato seedlings grown for about 1 month. The chemical solution prepared to a predetermined concentration by the above-described method was sprayed onto the leaf stem portion of the axillary seedling infested with aphids on the next day of inoculation using an air brush. Seven days after the treatment, the number of parasitic aphids was examined, and the control rate was calculated according to the following formula. The test was conducted using 1 seedling in each group.
Control rate (%) = (1−A / B × D / C) × 100
A: Number of adult aphids before spraying in untreated area per seedling B: Number of adult aphids before spraying in treated area per seedling C: Number of adult aphids 7 days after spraying in untreated area per seedling D: Number of seedlings per seedling The number of adult aphids 7 days after spraying in the treated area Using the obtained control rate, the presence or absence of a synergistic effect was tested based on the Colby equation described in Test Example 1. The results are shown in Table 4.

Table 4

  From the results of Table 4, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above Colby equation, and both were synergistic effects. showed that.

Test Example 4: Insecticidal effect test of cucumber on cotton aphids 50 to 80 infested adult aphids were inoculated into the leaves of potted cucumber seedlings grown for about 1.5 months. The chemical solution prepared to a predetermined concentration by the above-described method was sprayed using an air brush to the leaf stalk portion of the cucumber seedling infested with aphids the day after inoculation. Seven days after the treatment, the number of parasitic aphids was examined, and the control rate was calculated according to the following formula. The test was conducted using 1 seedling in each group.
Control rate (%) = (1−A / B × D / C) × 100
A: Number of adult aphids before spraying in untreated area per seedling B: Number of adult aphids before spraying in treated area per seedling C: Number of adult aphids 7 days after spraying in untreated area per seedling D: Number of seedlings per seedling The number of adult aphids 7 days after spraying in the treated area Using the obtained control rate, the presence or absence of a synergistic effect was tested based on the Colby equation described in Test Example 1. The results are shown in Table 5.

Table 5

  From the results of Table 5, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above-mentioned Colby formula, and both were synergistic effects. showed that.

Test Example 5: Insecticidal Effect Test on Eggplant Tobacco Whitefly Potted eggplant seedlings grown for about two months after sowing were placed in a greenhouse where tobacco whitefly was generated and allowed to lay eggs in tobacco whiteflies. After investigating the number of eggs laid on the leaves, the chemical solution prepared at a predetermined concentration by the method described above was sprayed onto the leaf stems of the seedlings using an air brush. On the 14th day after the treatment, the number of live whitefly larvae was examined, and the control rate was calculated according to the following formula. The test was conducted using 3 seedlings in each section.
Control rate (%) = (1−A / B × D / C) × 100
A: The number of tobacco whitefly eggs before spraying in the untreated area per seedling B: The number of tobacco whitefly larvae before spraying in the treated area per seedling C: The number of tobacco whitefly eggs 14 days after spraying in the untreated area per seedling D: per seedling 14 days after spraying in the treated area, the number of tobacco whitefly larvae was tested for the presence or absence of a synergistic effect based on the Colby equation described in Test Example 1 using the obtained control rate. The results are shown in Table 6.

Table 6

  From the results of Table 6, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above-mentioned Colby formula, and all were synergistic effects. showed that.

Test Example 6: Insecticidal effect test against southern blue thrips A 430 ml polyethylene cup containing water was capped with a hole (diameter about 5 mm) in the center. A slit having a width of about 1 cm was cut into a circular filter paper having a diameter of 6.5 cm, and a strip-like portion hanging downward was inserted so as to be immersed in water in the cup through a hole in the lid, and absorbent cotton was placed on the filter paper. In this way, two leaf discs (2 cm x 5 cm) made from the initial leaves of kidney bean are placed on the cotton wool that has been constantly replenished with water in the cup, and the southern southern thrips adult per one leaf disc. Were inoculated and allowed to lay eggs. 2 ml of the chemical solution prepared to a predetermined concentration by the above-described method was sprayed per cup using an air brush. After spraying, it was kept in a constant temperature room at 25 ° C. Eight days after the treatment, the number of hatched larvae was investigated under a binocular. The control rate (%) was calculated according to the following formula. The test was conducted using 1 cup of each section.
Control rate (%) = (1−number of hatched larvae in treated group / number of hatched larvae in untreated group) × 100
Based on the Colby equation described in Test Example 1, the presence or absence of a synergistic effect was tested using the obtained control rate. The results are shown in Table 7.

Table 7

  From the results of Table 7, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above Colby's formula, both of which are synergistic effects showed that.

Test Example 7: Insecticidal effect test against citrus blue thrips A 430 ml polyethylene cup containing water was covered with a lid with a hole (diameter: about 5 mm) in the center. A slit having a width of about 1 cm was cut into a circular filter paper having a diameter of 6.5 cm, and a strip-like portion hanging downward was inserted so as to be immersed in water in the cup through a hole in the lid, and absorbent cotton was placed on the filter paper. In this way, two leaf discs (2 cm x 5 cm) made from the initial leaves of kidney bean are placed on the cotton wool that has been constantly replenished with water in the cup, and adult citrus thrips per one leaf disc. Were inoculated and allowed to lay eggs. 2 ml of the chemical solution prepared to a predetermined concentration by the above-described method was sprayed per cup using an air brush. After spraying, it was kept in a constant temperature room at 25 ° C. Eight days after the treatment, the number of hatched larvae was investigated under a binocular. The control rate (%) was calculated according to the following formula. The test was conducted using 1 cup of each section.
Control rate (%) = (1−number of hatched larvae in treated group / number of hatched larvae in untreated group) × 100
Based on the Colby equation described in Test Example 1, the presence or absence of a synergistic effect was tested using the obtained control rate. The results are shown in Table 8.

Table 8

  From the results of Table 8, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above Colby's formula, and both were synergistic effects. showed that.

Test Example 8: Insecticidal effect test of peas against the sand flies Foliar stems of pot-planted pea seedlings seeded for 3 weeks after seeding were sprayed with a chemical solution prepared to a predetermined concentration by the method described above. The sprayed solution was air-dried and then kept in the greenhouse where the sand fly was generated and allowed to lay eggs. Seven days after the treatment, the number of perforations of the sand fly was investigated according to the perforation size (small, medium, large), and the control rate was calculated according to the following formula. The test was conducted using 3 seedlings in each section.
Control rate (%) = (1−A / B × D / C) × 100
A: Total number of perforations by Larvae larvae in untreated area per seedling (small perforations + medium perforations + large perforations)
B: Total number of drilled holes by small sand fly larvae in the treated area per seedling (number of small holes + number of medium holes + number of large holes)
C: Number of perforations having a medium or larger size due to Larvae larvae in the untreated section per seedling (number of medium perforations + number of large perforations)
D: Number of perforations having a medium or larger size due to larvae of larvae in the treated area per seedling (number of medium perforations + number of perforations)
Based on the Colby equation described in Test Example 1, the presence or absence of a synergistic effect was tested using the obtained control rate. The results are shown in Table 9.

Table 9

  From the results of Table 9, in the effect test in which the pest control composition of the present invention was tested, the control rate obtained therefrom exceeded the expected value calculated by the above-mentioned Colby formula, both synergistic effects showed that.

Test Example 9: Effect of testing for insecticidal effect against nymph mite A 430 ml polyethylene cup containing water was capped with a hole (diameter: about 5 mm) in the center. A slit having a width of about 1 cm was cut into a circular filter paper having a diameter of 6.5 cm, and a strip-like portion hanging downward was inserted so as to be immersed in water in the cup through a hole in the lid, and absorbent cotton was placed on the filter paper. In this way, two leaf discs (2 cm × 5 cm) made from the initial leaves of kidney bean are placed on the absorbent cotton in a state in which the water in the cup is constantly replenished, and adult female nymph mite 10 per one leaf disc. The head was inoculated. This cup was placed in an acrylic cylinder having a height of 50 cm and a diameter of 10 cm, and 2 ml of the chemical solution prepared to a predetermined concentration by the above-described method was sprayed with an air brush. After spraying, it was kept in a constant temperature room at 25 ° C. Four days after the treatment, the life and death of adult worms and bitter melons were investigated under a binocular, and the morbidity (%) was determined by dying the bitter worms. The test was conducted using 1 cup of each section.
Based on the Colby formula described in Test Example 1, the presence or absence of synergistic effect was tested using the obtained miticide rate. The results are shown in Table 10.

Table 10

  From the results of Table 10, in the effect test in which the pesticidal composition of the present invention was tested, the miticide rate obtained therefrom exceeded the expected value calculated by the above Colby equation, and both were synergistic. Showed the effect.

Test Example 10: Ovicidal effect on nymph spider mite A 430 ml polyethylene cup filled with water was capped with a hole (diameter about 5 mm) in the center. A slit having a width of about 1 cm was cut into a circular filter paper having a diameter of 6.5 cm, and a strip-like portion hanging downward was inserted so as to be immersed in water in the cup through a hole in the lid, and absorbent cotton was placed on the filter paper. In this way, two leaf discs (2 cm x 5 cm) made from the initial leaves of bean sprouts are placed on the cotton wool that has been constantly replenished with water in the cup, and adult female nymph mite per one leaf disc. Five animals were inoculated. After investigating the number of eggs laid on the leaf disk, 2 ml of a chemical solution prepared to a predetermined concentration by the method described above was sprayed per cup using an air brush. After spraying, it was kept in a constant temperature room at 25 ° C. Eight days after the treatment, the number of unhatched eggs and the viability and agony of the hatched larvae were investigated under a binocular. According to the following formula, the egg killing + larvae killing rate (%) was calculated. The test was conducted using 1 cup of each section.
Egg killing + larvae kill rate (%) = (number of unincubated eggs + number of bitter larvae + number of dead larvae) / number of test eggs × 100
Using the obtained egg killing rate + larvae killing rate, the presence or absence of synergistic effect was tested based on the Colby equation described in Test Example 1. The results are shown in Table 11.

Table 11

  From the results of Table 11, in the effect test in which the pest control composition of the present invention was tested, the egg killing + larvae rate (%) obtained therefrom exceeded the expected value calculated by the above Colby equation. All showed synergistic effects.

Test Example 11: Test soil for sweet potato root-knot nematode density adjusted to 200 heads / 20g of soil 200ml of test soil (river sand and black soil mixed at 4: 1) was placed in a styrene cup (diameter 9cm, height 6.5cm). After irrigating 50 ml of the chemical solution prepared to the predetermined concentration by the method described above, 13 tomato seeds were sown and grown in a greenhouse. On the 14th day after sowing, the degree of root nodules was evaluated in 5 stages (no root nodules: 0, small nodules: 1, medium nodules: 2, root nodules high: 3, root nodules 甚: 4) According to the following formula, the Nekob index and the control value were calculated. The test was conducted using 1 cup of each section.
Root Cobb Index = Σ (about root cobb x number of relevant strains) / (4 x number of surveyed strains)
Control value (%) = [1− (root cobb index of treated area / root cobb index of untreated area)] × 100
Based on the Colby equation described in Test Example 1, the presence or absence of a synergistic effect was tested using the obtained control value. The results are shown in Table 12.

Table 12

  From the results of Table 12, in the effect test in which the pest control composition of the present invention was tested, the control value obtained therefrom exceeded the expected value calculated by the above-mentioned Colby formula, and all were synergistic effects. showed that.

  The pest control composition of the present invention can be preferably used as an agricultural and horticultural agent.

Claims (9)

(A) Formula [I]

Wherein R ¹ represents a hydrogen atom or a C ₁ -C ₄ alkyl group, R ² represents a hydrogen atom, a halogen atom, a C ₁ -C ₄ alkyl group or a C ₁ -C ₄ alkoxy group, A represents a nitrogen atom or a methine group (CH), and Y represents an oxygen atom, a methylene group (CH ₂ ) or a methyleneoxy group (OCH ₂ ).) From 2-aminonicotinic acid ester derivatives and salts thereof At least one compound selected;
(B) Azinphosmethyl, acephate, chlorpyrifos, diazinon, dichlorvos, dimeton-S methyl, dimethoate, dimethylvinphos, disulfone, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos, metidathion, monocrotophos, nared, oxydeprophos, parathion , Fensoate, hosalon, pyrimifosmethyl, pyridafenthion, profenofos, prothiofos, propaphos, pyracrofos, salicione, sulprofos, thiometone, tetrachlorvinphos, trichlorphone, bamidtin, alaniculb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, etiofencarb Fenobucarb, furatiocarb, isoprocarb , Mesomil, Metorcarb, Pirimicarb, Propoxur, Thiodicarb, Aldrin, Chlorden, DDT, Endosulfan, Linden, Acrinatrin, Areslin, Bifenthrin, Cycloproton, Cyfluthrin, Cyhalothrin, Ciphenothrin, Cypermethrin, Deltamethrinfen, Etofenprox Propatrin, fenvalerate, flucitrinate, flufenprox, fulvalinate, framethrin, halofenprox, imiprothrin, permethrin, phenothrin, praretrin, pyrethrin, resmethrin, silafluophene, tefluthrin, tralomethrin, transfluthrin, acetamiprid, clothianfurandi , Imidacloprid, nitenpyram, thiacloprid, chi Metoxam, Chlorantraniliprole, Cyantraniliprole, Cyclaniliprol, Tetraniliprol, Flubenzilamide, Bistriflon, Chlorofluazuron, Diflubenzuron, Fluccycloxuron, Flufenoxuron, Hexaflumuuron, Lufenuron, Novallon, Nobiflumuron, Teflubenzuron, Triflumuron, Buprofezin, Ciromazine, Chromafenozide, Halofenozide, Methoxyphenozide, Tebufenozide, Diofenolane, Phenoxycarb, Hydroprene, Mesoprene, Pyriproxyfen, Memectin, Benimactin, Emamectin Benzoctin, Emamectin , Spinosadow, BT agent, Anabasine, Azadirach , Deguelin, fatty acid glycerides, hydroxypropyl starch, soy lecithin, nicotine, nornicotine, sodium oleate, machine oil, propylene glycol monofatty acid ester, rapeseed oil, rotenone, acetoprole, aphidopyrrolene, bensultap, brofuranilide, cartap, thiocyclam, chlorfenapyr, dia Fenthiuron, dichloromezothiaz, etiprole, fipronil, furometokin, flonicamid, fluhexaphone, flupiradifurone, hydramethylnon, indoxacarb, metaflumizone, metaldehyde, nicotine sulfate, pymetrozine, pulafluprolol, pyridalyl, pyrifluquinazone, pyriprolol , Spirotetramat, Sulfluramide, Sulfoxafurol, Triflumezopyrim, Tolu Fenpyrad, triazamate, acequinosyl, amitraz, azocyclotin, benzomate, biphenazate, binapacryl, phenisobromolate, quinomethionate, clofentedine, sienopyrafen, ciflumethophene, hydroxyhydrated tricyclohexyltin, dicophor, dienochlor, difluvidazine, ethofoxazole, zafoxazole Fenbutazin, phenothiocarb, fenpyroximate, fluacrylpyrim, hexythiazox, pyrimidifene, polynactin complex, propargyl, piflumbide, pyridaben, spirodiclofen, spiromesifen, tebufenpyrad, tetradiphone, aluminum phosphide, benclotraz, kazusafos, ethoprophos, fluprosulfone At least one selected from the group consisting of thiazate, imisiaphos, levamisole hydrochloride, mesulfenfos, carbam, methyl isocyanate, morantel tartrate, oxamyl, tifluzamide, thioxaphene, chlorofacinone, coumatetralyl, difacin, monofluoroacetate, warfarin A compound,
A pest control composition comprising: In the component (A), R ¹ is H or CH ₃ , R ² is H, F, CH ₃ or OCH ₃ , A is CH or N, and Y is O, OCH ₂ or CH ₂ The pest control composition according to claim 1, which is at least one compound selected from the 2-aminonicotinic acid ester derivative represented by the formula [I] and a salt thereof. The component (A) is
(1) R ¹ is H, R ² is H, A is CH, and Y is O.
(2) R ¹ is CH ₃ , R ² is H, A is CH, and Y is O.
(3) R ¹ is CH ₃ , R ² is F, A is CH, and Y is O.
(4) R ¹ is CH ₃ , R ² is CH ₃ , A is CH, and Y is O.
(5) R ¹ is CH ₃ , R ² is OCH ₃ , A is CH, and Y is O.
(6) R ¹ is CH ₃ , R ² is H, A is N, and Y is O.
(7) R ¹ is CH ₃ , R ² is H, A is CH, Y is OCH ₂ , or (8) R ¹ is CH ₃ and R ² is H, A is CH and Y is CH ₂ .
The pest control composition according to claim 2, which is a 2-aminonicotinic acid ester derivative represented by the formula [I].   The component (B) is acephate, chlorpyrifos, diazinon, fenitrothion, malathion, methidathion, profenofos, prothiophos, alanicarb, benfuracarb, carbaryl, mesomil, thiodicarb, cyfluthrin, cypermethrin, etofenprox, fenpropatoline, flucitrinate, Permethrin, silafluophene, acetamiprid, clothianidin, dinotefuran, imidacloprid, thiacloprid, thiamethoxam, chlorantraniliprole, cyantraniliprole, cyclaniliprol, tetraniliprol, fulvendiamide, chlorofluazuron, diflubenzuron, flufenoxuron Lufenuron, teflubenzuron, buprofezin, cyromazine, chromafenozide, te Phenozide, abamectin, emamectin benzoate, repimectin, milbemectin, spinetoram, spinosadoo, BT agent, azadirachtin, cartap, thiocyclam, chlorfenapyr, diafenthiuron, ethiprole, fipronil, flonicamid, flupiradifuron, indoxacarb pyriflunazone Tetramat, Sulfoxafurol, Triflumezopyrim, Acequinosyl, Amitraz, Bifenazate, Sienopyrafen, Ciflumethofene, Dienochlor, Diflovidazine, Etoxazole, Fenbutazin oxide, Hexithiazox, Propargyl, Piflubumide, Spiromethifen, Phosphisulfene , Imishiahosu is selected from the group consisting of oxamyl and Chiokisazafen, pesticidal composition according to any one of claims 1 to 3.   The pest control composition according to any one of claims 1 to 4, wherein a mass ratio of the component (A) to the component (B) is 500: 1 to 1: 500.   The pest control composition according to any one of claims 1 to 5, further comprising a bulking agent and / or a surfactant.   Use of the pest control composition according to any one of claims 1 to 6 for controlling pests.   A method for controlling pests, comprising treating the pests and / or their habitat with the pest control composition according to any one of claims 1 to 6. 7. The pest control composition according to any one of claims 1 to 6 is treated on a place where a useful crop is to be grown or a place where the useful crop is grown or a growing crop. , How to control pests.