CN106982837A - A kind of Pesticidal combination containing fluorine cyanogen insect amide and its application - Google Patents
A kind of Pesticidal combination containing fluorine cyanogen insect amide and its application Download PDFInfo
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- CN106982837A CN106982837A CN201710327804.6A CN201710327804A CN106982837A CN 106982837 A CN106982837 A CN 106982837A CN 201710327804 A CN201710327804 A CN 201710327804A CN 106982837 A CN106982837 A CN 106982837A
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- insect amide
- fluorine cyanogen
- cyanogen insect
- mti
- pesticidal combination
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a kind of Pesticidal combination containing fluorine cyanogen insect amide, its active ingredient is fluorine cyanogen insect amide and MTI-446, and both mass ratioes are 50:1~1:50, the gross mass percentage composition of active ingredient is 10%~85% in composition.The present composition can be configured to suspending agent, suspension emulsion, microemulsion, aqueous emulsion, wettable powder, water dispersible granules, microcapsule suspending agent or dispersible oil-suspending agent.Instant component is reasonable, it is adaptable to prevent and treat the insects such as paddy rice, the striped rice borer on vegetables, planthopper and thrips.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, especially a kind of Pesticidal combination containing fluorine cyanogen insect amide and its preventing and treating
The application of insect, belongs to technical field of compounded pesticide on crops.
Background technology
The common insect pests such as thrips, plant hopper have that host range is wide, breeding is fast, generation overlap and easily produce resistance etc. to agricultural chemicals
Feature, greater loss is caused to agricultural production, at present conventional pesticide control such as AVM, ethyl pleocidin and anabasine
Imidacloprid, Diacloden, Acetamiprid etc. produced it is more resistance.Therefore in the market be badly in need of a kind of preventing and treating thrips of high-efficiency low-toxicity and
The medicament of the insects such as plant hopper.
Fluorine cyanogen insect amide, english common name：Tetraniliprole, test code number is BCS-CL73507,2014 by
The bisamide insecticides of Bayer Cropscience exploitation, it has very under low dosage to Lepidoptera, coleoptera and Diptera pest
Good prevention effect, especially has outstanding effect to the insect of the hardly possible preventing and treating such as striped rice borer, plant hopper, aphid, thrips.
MTI-446, english common name：Dinotefuran, is a kind of third generation anabasine insecticide, with it is interior suction with
Tag stomach poison function, plant absorption substantially, mainly acts on insect CNS cynapse to top distributional effects.
Up to now, there is not yet fluorine cyanogen insect amide and MTI-446 carry out relevant report of the compounding for pest control, especially
It is striped rice borer.
The content of the invention
It is an object of the invention to：A kind of Pesticidal combination for being adapted to agriculturally use is provided, and helps to reduce use
Dose, delay insect produce resistance and reduction use cost, reduce environmental pollution.
Inventor is tested by a large amount of indoor bioassay, it is found that fluorine cyanogen insect amide and MTI-446 are compounded with certain proportion
Afterwards, planthopper, thrips are had significant synergies.
The technical scheme is that：A kind of Pesticidal combination containing fluorine cyanogen insect amide, it is characterised in that：Containing effective
Composition fluorine cyanogen insect amide and MTI-446, both mass ratioes are 50:1~1:50, preferred mass ratio is 10:1~1:10.
In the Pesticidal combination of the present invention, the gross mass percentage composition of active ingredient is 10%~85%, remaining be auxiliary agent,
Filler and other it is beneficial to the known substance that active ingredient is stable in storage and use and drug effect is played.
The composition pesticide of the present invention can be prepared into any one agent for being adapted to agriculturally use using known method
Type, preferable formulation have suspending agent, suspension emulsion, microemulsion, aqueous emulsion, wettable powder, water dispersible granules, microcapsule suspending agent or
Dispersible oil-suspending agent.
Described composition pesticide is also containing the usual auxiliaries needed for preparation pesticidal preparations, and usual auxiliaries are dispersant, breast
Mixing more than one or both of agent, wetting agent, stabilizer, thickener, defoamer, antifreezing agent, filler etc., is agricultural chemicals
The various auxiliary agents commonly used in preparation, are not specially limited, can be varied from according to different situations.
Described composition pesticide, for preventing and treating the insect on crops, composition pesticide described in the invention can be with
Finished product preparation form is provided, i.e., exist as a mixture, the composition of composition can also unit dose form provide, using preceding direct
Mixed in proportion in bucket or tank, be then diluted to required concentration.
The good effect that the present invention is produced is：(1) compared with single dose, composition synergistic effect is substantially, indoor to prevent with field
Effect is significantly increased；(2) field dosage and use cost are not only reduced after composition compounding, and it is residual to reduce agricultural chemicals
Stay and environmental pollution；(3) composition by different mechanism of action combination of active principles, action site increase, be conducive to overcoming and
Insect is delayed to produce resistance.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.
The pesticide active ingredient of different types of structure is compounded, is cost during current solution agricultural chemicals single dose use
And effective measures the problems such as resistance.After the pesticide active ingredient mixing of different types of structure, three kinds of works are typically exhibited
With type, i.e. summation action, synergistic effect and antagonism.But it is specially which kind of effect, it is impossible to predict, can only be by largely trying
Testing can just draw a conclusion.Compound synergic is preferably formulated, and can improve actual prevention effect, reduces Pesticide use dosage, delays evil
Worm is drug-fast to be produced, and is one of important means of resistance management.
The present composition has obvious synergistic effect to planthopper and thrips etc., not exclusively two kinds pharmacy effects
It is simple to be added, it is clear that in this result that can be tested from following Toxicity Determination.
Assays Example 1：Fluorine cyanogen insect amide and MTI-446 compound the indoor joint toxicity measuring test to planthopper
Subjects：Brown paddy plant hopper Nilaparvata lugens (Stdl), indoors artificial raises many generations.
Test method：Test method reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1154.11-2008》, adopt
Method is soaked with rice stem.The rice strain of the late tillering state of stalwartness is extracted with root, cleans, is cut into the band root rice stem of 15cm length, 4 plants one group, in
Shady place is dried in the air to surface without washmarking.Rice stem is soaked 30 seconds in the medicament diluted respectively, after taking-up is dried, with the degreasing soaked
Cotton embraces root and is put into culture dish, draws 3 age mid-term nymphs and is put into culture dish, 25 every glass, if leaching clear water is blank pair
According to each concentration is repeated 4 times.It is 16h to handle rearmounted 27 DEG C of temperature, photoperiod:8h(L:D raised in culture dish).Examined after 5 days
Look into death toll.Statistical analysis is carried out with DPS9.50 statistical analysis softwares, the LC of each medicament is calculated50, then according to the abundant method calculating of Sun Yun altogether
Malicious coefficient (CTC).
When CTC≤80, then composition shows as antagonism, as 80 ＜ CTC ＜ 120, then composition shows as being added and made
With when CTC≤120, then composition shows as synergistic effect.
Survey toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
A percentage composition+B medicament toxicity index in theoretical toxicity index (TTI)=A medicament toxicity index × mixture × mixed
B percentage composition in agent
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100.Poison
Power measurement result is shown in Table 1.
The indoor joint toxicity measuring test result of table 1, fluorine cyanogen insect amide and MTI-446 compounding to brown paddy plant hopper
Result of the test can be seen that the proportioning of fluorine cyanogen insect amide and MTI-446 50 from table 1:1~1:It is right when between 50
The co-toxicity coefficient of brown paddy plant hopper is more than 120, with synergistic effect.Particularly match 10:1~1:When between 10, synergy is made
With most substantially, its co-toxicity coefficient is more than 220.
Assays Example 2：Fluorine cyanogen insect amide and MTI-446 compound the indoor joint toxicity measuring test to thrips
Subjects：Palm thrips (Thrips palmi Karny), the generation of artificial feeding seven.
Test method：Experiment reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1154.7-2006》Using leaching leaf
Method is measured.Preprepared cabbage leaf (3 ㎝ × 4 ㎝) is soaked 10 seconds in decoction, take out nature dry to
Surface is chosen into palm thrips 3 age nymph with writing brush without washmarking, test worm is moved to (25 ± 1) DEG C, 14/10 (L/D), relative humidity
Normally cultivated in 70% greenhouse.3 repetitions are often handled, often repeatedly 30 test worms.
Statistical analysis is carried out with DPS9.50 statistical analysis softwares, the LC of each medicament is calculated50, then according to the abundant method calculating of Sun Yun altogether
Malicious coefficient (CTC).Toxicity test is the results detailed in Table 2.
The indoor joint toxicity measuring test result of table 2, fluorine cyanogen insect amide and MTI-446 compounding to palm thrips
Result of the test can be seen that the proportioning of fluorine cyanogen insect amide and MTI-446 50 from table 2:1~1:It is right when between 50
The co-toxicity coefficient of palm thrips is more than 120, with synergistic effect.Particularly match 10:1~1:When between 10, synergy
Effect is most notable, and its co-toxicity coefficient is more than 220.
Pesticidal combination of the present invention can be prepared into the various formulations for being adapted to agriculturally use with known method, preferably
Formulation has suspending agent, suspension emulsion, microemulsion, water dispersible granules, wettable powder, aqueous emulsion, microcapsule suspending agent or dispersible oil
Suspending agent.As described below is only the present invention preferably embodiment, only to explain the present invention, therefore can not be interpreted as pair
The limitation of the scope of the claims of the present invention.
Example of formulations 1：51% fluorine cyanogen insect amide MTI-446 suspending agent
Fluorine cyanogen insect amide 50%, MTI-446 1%, phenethyl phenol polyoxyethylene groups ether phosphate 1%, Negel
3%th, xanthans 3%, ethylene glycol 3%, aluminium-magnesium silicate 1%, deionized water supplies 100%.Mentioned component is added according to a conventional method
Work can be prepared by 51% fluorine cyanogen insect amide MTI-446 suspending agent.
Example of formulations 2：82% pair of the third ring worm ester sulfoxaflor wettable powder
Fluorine cyanogen insect amide 80%, MTI-446 2%, alkylphenol-polyethenoxy base ether phosphate 3%, alkyl naphthalene sulfonic acid calcium 6%,
Kaolin supplies 100%.Mentioned component is processed according to a conventional method and can be prepared by 82% fluorine cyanogen insect amide MTI-446 wettable
Pulvis.
Example of formulations 3：15.5% fluorine cyanogen insect amide dinotefuran micron-emulsion
Fluorine cyanogen insect amide 15%, MTI-446 0.5%, 1-METHYLPYRROLIDONE 10%, Nongru-700 #4%, polyethenoxy ether
10%th, triphenyl phosphite 3%, organosilicon 3%, thiophene ketone 4%, deionized water supplies 100%.By mentioned component according to a conventional method
Processing can be prepared by 15.5% fluorine cyanogen insect amide dinotefuran micron-emulsion.
Example of formulations 4：21% fluorine cyanogen insect amide MTI-446 aqueous emulsion
Fluorine cyanogen insect amide 20%, MTI-446 1%, cyclohexanone 5%, agriculture breast 600#3%, Tween-60 #2%, agriculture breast 2201#
4%th, polycarboxylate 6%, benzoic acid 3%, propane diols 3%, deionized water supplies 100%.Mentioned component is added according to a conventional method
Work can be prepared by 21% fluorine cyanogen insect amide MTI-446 aqueous emulsion.
Example of formulations 5：11% fluorine cyanogen insect amide MTI-446 microcapsule suspending agent
Fluorine cyanogen insect amide 10%, MTI-446 1%, macromolecule cyst material polymer MDI3%, solvent linseed oil 5% and S-
200 solvent naphthas 9%, emulsifying agent triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer 3.5%, dispersant alkylnaphthalene sulphur
Sour sodium 5%.Above-mentioned active ingredient, macromolecule cyst material, solvent are mixed, make to be dissolved into homogeneous oil phase, emulsifying agent, dispersant
It is soluble in water to be prepared into homogeneous aqueous phase, in a shear condition, oil phase is added in aqueous phase solution, emulsion is prepared into, stirring is lower to be added
Enter 10% ethylenediamine solution 4%, be warming up to 65 DEG C of insulation reaction 4.0h, two kinds of materials react in oil-water interfaces, formed
High score ascus wall, you can 11% fluorine cyanogen insect amide MTI-446 microcapsule suspending agent is made.
Example of formulations 6：72% fluorine cyanogen insect amide MTI-446 water dispersible granules
Fluorine cyanogen insect amide 60%, MTI-446 12%, sodium lignin sulfonate 6%, calcium dodecylbenzenesulfonate 10%, alkyl sulfide
Sour calcium 5%, polyethylene glycol 3%, kaolin supplies 100%.Mentioned component is processed according to a conventional method and can be prepared by 72% fluorine cyanogen
Insect amide MTI-446 water dispersible granules.
Example of formulations 7：20% fluorine cyanogen insect amide MTI-446 suspending agent
Fluorine cyanogen insect amide 10%, MTI-446 10%, alkyl naphthalene formaldehyde condensation product sodium sulfonate 4%, alkyl sulfonic acid calcium 5%, first
Base cellulose 4%, ethylene glycol 5%, silicone oil 1.5%, deionized water supplies 100%.Mentioned component is processed i.e. according to a conventional method
20% fluorine cyanogen insect amide MTI-446 suspending agent can be made.
Example of formulations 8：12% fluorine cyanogen insect amide dinotefuran micron-emulsion
Fluorine cyanogen insect amide 2%, MTI-446 10%, cyclohexanone 10%, Nongru-700 #3%, alkylphenol-formaldehyde resin polyoxy second
Alkene ether 10%, epoxychloropropane 2%, organosilicon 3%, thiophene ketone 5%, deionized water supplies 100%.Mentioned component is routinely square
Method processing can be prepared by 12% fluorine cyanogen insect amide dinotefuran micron-emulsion.
Example of formulations 9：22% fluorine cyanogen insect amide MTI-446 nitrile aqueous emulsion
Fluorine cyanogen insect amide 2%, MTI-446 20%, solvent naphtha 15%, triphenoethyl benzene phenol polyethenoxy ether phosphate 4%,
Tween-60 #3%, agriculture breast 600#4%, xanthans 5%, benzoic acid 3%, glycerine 2%, deionized water supplies 100%.Will be upper
State composition and process according to a conventional method and can be prepared by 22% fluorine cyanogen insect amide MTI-446 aqueous emulsion.
Example of formulations 10：21% fluorine cyanogen insect amide MTI-446 microcapsule suspending agent
Fluorine cyanogen insect amide 1%, MTI-446 20%, macromolecule cyst material polymer MDI 2%, the and of solvent linseed oil 5%
S-200 solvent naphthas 7%, emulsifying agent agriculture breast 600#4%, dispersant alkyl naphthalene sulfonic acid calcium 3%.By above-mentioned active ingredient, macromolecule
Cyst material, solvent mixing, make to be dissolved into homogeneous oil phase, emulsifying agent, dispersant are soluble in water to be prepared into homogeneous aqueous phase, in shearing
Under the conditions of, oil phase is added in aqueous phase solution, emulsion is prepared into, stirring is lower to add 10% ethylenediamine solution 4%, is warming up to 65
DEG C insulation reaction 4.0h, two kinds of materials react in oil-water interfaces, form high score ascus wall, you can 21% fluorine cyanogen worm acyl is made
Amine MTI-446 microcapsule suspending agent.
Example of formulations 11：The 31% dispersible oil-suspending agent of fluorine cyanogen insect amide MTI-446
Weigh fluorine cyanogen insect amide 1%, MTI-446 30%, phenethyl phenol polyoxyethylene groups ether phosphate 3%, anhydrous sorbitol
Fatty acid ester APEO 3%, agriculture breast 600#3%, alkylnaphthalene sulfonate sodium 5%, bentonite 3%, sodium carboxymethylcellulose
2%th, dibutyl hydroxy toluene 3%, soybean oil supplies 100%.Above-mentioned raw materials are blended, are sanded with sand mill to particle diameter and are less than 5 μ
M is that the 31% dispersible oil-suspending agent of fluorine cyanogen insect amide MTI-446 is made.
Example of formulations 12：41% fluorine cyanogen insect amide MTI-446 nitrile suspension emulsion
Fluorine cyanogen insect amide 1%, MTI-446 40%, ethoxylated castor oil 5%, AEO sulfosuccinic acid
Monoesters dicalcium 12%, MODIFIED LIGNOSULPHONATE 5%, carboxymethyl cellulose 5%, bentonite 3%, propane diols 5%, deionized water
Supply 100%.First MTI-446 is dissolved in Solvesso200, ethoxylated castor oil is added and obtains MTI-446 missible oil, then will
Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspending agent.The oil phase of MTI-446 is added to fluorine-containing cyanogen insect amide
Suspending agent in, obtain 41% fluorine cyanogen insect amide MTI-446 suspension emulsion.
Example of formulations 13：51% fluorine cyanogen insect amide MTI-446 water dispersible granules
Fluorine cyanogen insect amide 1%, MTI-446 50%, naphthalenesulfonate formaldehyde condensation compound 6%, alkylsurfuric acid calcium 10%, white carbon
Supply 100%.Mentioned component is processed according to a conventional method and can be prepared by 51% fluorine cyanogen insect amide MTI-446 water dispersible granules.
Field information embodiment 1：Fluorine cyanogen insect amide MTI-446 compounds the field control effectiveness test to rice-stem borer
Experiment selection is rushed village in Yunfu City Yuncheng District Shicheng town Thunder God and carried out, and experiment plot striped rice borer over the years occurs
Seriously.Plot area 30m2, 4 repetitions are often handled, totally 64 cells.In rice plant of tillering stage (striped rice borer 1-2 instar larvaes peak
Phase) spray pesticide 1 time, investigate 1 preventive effect when 28d blank districts damage symptoms are obvious after medicine.Sampled using parallel great-jump-forward,
50 clumps of paddy rice are investigated per cell, withered heart strain number, insecticidal effect is counted, withered heart rate and preventive effect is calculated.Computational methods are as follows：
Withered heart rate (%)=(withered heart strain number/total strain number) × 100
Prevention effect (the %)=blank control of (blank district withered heart rate-chemicals treatment district withered heart rate) × 100/
Insecticidal effect (the %)=blank control of (blank district withered heart rate-chemicals treatment district withered heart rate) × 100/
Table 3, fluorine cyanogen insect amide MTI-446 built agent preventing and treating rice-stem borer field control effectiveness test result
Result of the test can be seen that fluorine cyanogen insect amide MTI-446 built agent in preventing and treating rice-stem borer field from table 3
During the test of pesticide effectiveness, 28d preventive effect is above the fluorine cyanogen insect amide suspending agent of comparison medicament 10% and 22% furan worm after each built agent medicine
The preventive effect of amine suspending agent, illustrates that fluorine cyanogen insect amide MTI-446 compound drug is good to the prevention effect of rice-stem borer.Experiment
During, also observe each medicament on paddy rice and natural enemy without influence.
Field information embodiment 2：Fluorine cyanogen insect amide MTI-446 compounds the field control effectiveness test to capsicum palm thrips
Experiment selection is carried out in the only village in Hainan Province Sanya Nan Bin farms.Plot area 20m2, often handle and be repeated 4 times,
Per cell 10 plants of Hot Pepper Seedlings of mark, 4 leaves of every plant of mark investigate 1d, 3d and 7d after insect population, medicine and investigate residual respectively before dispenser
Borer population living is stayed, blank district spray clear water calculates prevention effect.
Insect population × 100 before Revision insect recluced rate %=(borer population living after insect population-medicine before medicine)/medicine
Prevention effect (%)=(treatment region Revision insect recluced rate-clear area Revision insect recluced rate)/(100- clear areas insect population declines
Rate) × 100
Table 4, fluorine cyanogen insect amide MTI-446 built agent preventing and treating capsicum palm thrips field control effectiveness test result
Result of the test can be seen that fluorine cyanogen insect amide MTI-446 built agent in preventing and treating capsicum palm thrips field from table 4
Between the test of pesticide effectiveness when, 1d, 3d and 7d preventive effect are apparently higher than 50% MTI-446 water dispersible granules of control and 10% fluorine cyanogen worm after medicine
The preventive effect of amide suspending agents, shows to be superior to the quick-acting and lasting effect of palm thrips after fluorine cyanogen insect amide MTI-446 compounding
Two kinds of single doses are obvious to palm thrips prevention effect.
Field information embodiment 3：Fluorine cyanogen insect amide MTI-446 compounding preventing and treating Brown Planthopper field control effectiveness test
Experiment selection is carried out in Hubei Province Hanchuan City Liu Jia every town morning twilight village.Ridging before experiment, draws cell, and plot area is
25m2, even spraying is carried out using knapsack sprayer, the paddy rice growth of selection is basically identical, is in the envelope departure date, brown
That a situation arises is basically identical for plant hopper, is clapped using basin and insect population is investigated before method medicine, and in 3d, 7d, 15d, 30d investigation worm living after medicine
Number.Prevention effect computational methods are with Field information embodiment 2.
Table 5, fluorine cyanogen insect amide MTI-446 built agent preventing and treating Brown Planthopper field control effectiveness test result
Result of the test can be seen that fluorine cyanogen insect amide MTI-446 built agent in preventing and treating Brown Planthopper field from table 5
During the test of pesticide effectiveness, 3d, 7d, 15d and 30d preventive effect are apparently higher than the MTI-446 suspending agent of comparison medicament 22% and 10% fluorine cyanogen after medicine
The preventive effect of insect amide suspending agent, illustrates obvious to the prevention effect of brown paddy plant hopper after fluorine cyanogen insect amide MTI-446 compounding.
From the result of the test of above-mentioned field control effectiveness test embodiment can be seen that Pesticidal combination of the present invention to striped rice borer,
Palm thrips and brown paddy plant hopper prevention effect are protruded, and composition quick-acting has significant improvement than single dose, and lasting effect is also carried
It is high.Meanwhile, process of the test Chinese medicine is to for studying thing and natural enemies security, being worthy of popularization.
Claims (5)
1. a kind of Pesticidal combination containing fluorine cyanogen insect amide, it is characterised in that：The active ingredient of the Pesticidal combination is fluorine
Cyanogen insect amide and MTI-446, both mass ratioes are 50:1~1:50.
2. Pesticidal combination according to claim 1, it is characterised in that：The matter of active ingredient fluorine cyanogen insect amide and MTI-446
Amount is than being 10:1~1:10.
3. Pesticidal combination according to claim 1 or 2, it is characterised in that：The gross mass hundred of active ingredient in composition
It is 10%~85% to divide content.
4. Pesticidal combination according to claim 3, it is characterised in that：It is made during practical application and is adapted to what is agriculturally used
Any one formulation, its formulation is suspending agent, suspension emulsion, aqueous emulsion, wettable powder, water dispersible granules, microcapsule suspending agent, micro-
Emulsion or dispersible oil-suspending agent.
5. Pesticidal combination described in claim 1 be used to preventing and treating paddy rice, on vegetables striped rice borer, planthopper and thrips purposes.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107258793A (en) * | 2017-05-28 | 2017-10-20 | 陕西康禾立丰生物科技药业有限公司 | A kind of Pesticidal combination containing four Tolfenpyrads and anabasine |
| CN114901074A (en) * | 2019-12-31 | 2022-08-12 | 阿达玛马克西姆有限公司 | Insecticide mixtures |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103068235B (en) * | 2010-06-18 | 2016-04-20 | 拜耳知识产权有限责任公司 | There is the active ingredient combination of desinsection and acaricidal properties |
-
2017
- 2017-05-11 CN CN201710327804.6A patent/CN106982837A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103068235B (en) * | 2010-06-18 | 2016-04-20 | 拜耳知识产权有限责任公司 | There is the active ingredient combination of desinsection and acaricidal properties |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107258793A (en) * | 2017-05-28 | 2017-10-20 | 陕西康禾立丰生物科技药业有限公司 | A kind of Pesticidal combination containing four Tolfenpyrads and anabasine |
| CN114901074A (en) * | 2019-12-31 | 2022-08-12 | 阿达玛马克西姆有限公司 | Insecticide mixtures |
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