CN107920507A - Granular agrichemical composition - Google Patents

Granular agrichemical composition Download PDF

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Publication number
CN107920507A
CN107920507A CN201680050108.9A CN201680050108A CN107920507A CN 107920507 A CN107920507 A CN 107920507A CN 201680050108 A CN201680050108 A CN 201680050108A CN 107920507 A CN107920507 A CN 107920507A
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CN
China
Prior art keywords
granular agrichemical
activity component
pesticide activity
composition
agrichemical composition
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201680050108.9A
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Chinese (zh)
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CN107920507B (en
Inventor
山崎聪信
冈田优也
加藤贤太郎
田中龙
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Kumiai Chemical Industry Co Ltd
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Kumiai Chemical Industry Co Ltd
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Publication of CN107920507A publication Critical patent/CN107920507A/en
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Abstract

The subject of the invention is to provide a kind of granular agrichemical composition, it is characterized in that, contain pesticide activity component, particle with more than particle diameter 3mm accounts for more than 80% size distribution and the property on the water surface of swimming, and is disintegrated in 30 minutes on the water surface, although the granular agrichemical composition contains pesticide activity component with high concentration, but disintegrative is good, easy to manufacture, hygroscopicity is low, easily spreads.Granular agrichemical composition for solving the problem is containing pesticide activity component, surfactant, the ducted body and solid carrier that particle diameter is 1 600 μm, particle with more than particle diameter 3mm accounts for more than 80% size distribution and the granular agrichemical composition for the property swum on the water surface and be disintegrated in 30 minutes on the water surface, it is characterized in that, the particle diameter of the pesticide activity component is the 1/10 of more than 10 μm and the minor axis less than granular agrichemical composition.

Description

Granular agrichemical composition
Technical field
The present invention relates to the large-scale granular agrichemical composition of water floating, in more detail, it is related to such as by paddy field The water surface on partly directly spread a small amount of large-scale granular agriculture of water floating that just can equably spread pesticide activity component Drug composition.
Background technology
In the past, the composition pesticide used in paddy field etc. is generally granula, pulvis, emulsion, wettable powder and suspends Agent.In these composition pesticides, granula and pulvis are commonly angled relative to 10a paddy fields and are not diluted in water with the amount of 1~4kg and direct Spread, in recent years, advocate the Labor-saving that pesticide is spread, in order to tackle this strategy, seeking to improve in composition pesticide Pesticide activity component content and reduce the dispersion volume as composition pesticide, or can not enter paddy field and only by being thrown from dike side Enter the composition pesticide of the i.e. spreadable laborsaving distribution of reply.
For such requirement, the composition pesticide of various Labor-savings is have studied, discloses its technology, as especially effective Composition pesticide, in patent document 1, disclose a kind of large-scale granular agrichemical composition of water floating, it is characterised in that Containing pesticide activity component, the size distribution that the particle with more than particle diameter 3mm is more than 80% and the property on the water surface of swimming Matter, and be disintegrated in 30 minutes on the water surface.Above-mentioned composition pesticide has high self-diffusion, due to by relative to 10a paddy fields directly spread a small amount of composition pesticide of 250~500g or so, and pesticide activity component just can be on whole paddy field It is distributed, therefore can be spread from dike side to throw evenly, can be referred to as preferably to tackle the composition pesticide of laborsaving distribution.
In order to reduce the distribution weight as composition pesticide, the agriculture of the such laborsaving distribution of reply of above patent document 1 Drug composition is the dense type composition pesticide for improving the pesticide activity component content in composition pesticide.By spreading on a small quantity Composition pesticide, effortlessly realizes the processing with the pesticide activity component of traditional composition pesticide isodose, but such Composition pesticide due to spreading as a result, grain number is few on a small quantity, it is difficult to uniformly dispersing.When each place in paddy field, pesticide activity During the treating capacity uneven distribution of component, in the place of pesticide activity component deficiency, effect is insufficient, and in pesticide activity component Superfluous place, produces poisoning sometimes.In order to overcome this point, in the composition pesticide to patent document 1, by water While swimming on the water surface while being disintegrated, even non-uniform distribution, pesticide activity component also can be from expansion when field is handled Dissipate and assign the design homogenized in paddy field.That is, for the composition pesticide of patent document 1, before its performance is played Carry, it is desirable to its on the water surface in a short time, the function being specifically disintegrated within 30 minutes.
For the overwhelming majority for the pesticide activity component being currently known, though their size degree is different, but mostly For with hydrophobic organic compound.In the composition pesticide of above patent document 1, surfactant is combined with to assign The function being disintegrated on the water surface, but in general, the presence of organic compound particle, which has, hinders the agriculture as caused by surfactant The tendency of the disintegration of drug composition.In more detail, in order to build more unordered system, the organic compound particle being placed in water First have to be dissolved in the water, but cause to dissolve or dissolve what is slowly carried out due to organic compound hydrophobicity in itself In the case of, in order to stablize the thermodynamic state of its own, cause in particle surface catch surface activating agent (if there is no surface Activating agent, then aggegation between particle, is moved in a manner of reducing the area of exposure in water), in addition, simply by the presence of organic compound Thing particle, the hydrophobic group of surfactant can also adsorb the direction on its surface, showing and minimizing the interface of itself and water On.As a result, the surfactant occupied on organic compound particle surface cannot participate in the disintegration of composition pesticide, it is impossible to send out Wave the disintegration function as desired cooperation purpose.
In general, by still there is the surfactant of surplus after coordinating absorption on pesticide activity component, can be to avoid upper State problem, but the pesticide activity component content in composition pesticide is set to it is higher, must for being disintegrated the composition pesticide The use level of the surfactant needed is also higher.On the other hand, come for being combined with the composition pesticide of exhibiting high surface activating agent Say, when being mediated to raw material, become the very high grume of viscosity, it is difficult by the manufacture of extruding pelletization, and even if exert oneself Pressure is made, and due to becoming the composition pesticide of easy moisture absorption, hinders distribution etc., the use level existence of Surfactant Reason restricts.Therefore, the content of the pesticide activity component in composition pesticide can be naturally also restricted.
But for composition pesticide, pesticide activity component dispersiveness in water, suspension are considered, in addition, being Rapid performance effect, as its volume average particle size is, for example, less than 10 μm or small in general, by pesticide activity component Crushing of Ultrafine Used (for example, referring to patent document 2-3) in 5 μm of particulate.In this way, at composition pesticide to paddy field Deng Tian gardens After reason, the contact area of pesticide activity component and water present in Tian Pu expands, and pesticide activity component can be made to exist more quickly Dissolution in water.The composition pesticide of above-mentioned such corresponding laborsaving distribution is also not shown in this embodiment, by pesticide activity component Coordinate again after Crushing of Ultrafine be pesticidal preparations field general knowledge.
Prior art literature
Patent document
Patent document 1：Special open 2002-179507 publications
Patent document 2：Unexamined Patent 11-228305 publications
Patent document 3：Special open 2005-336170 publications
The content of the invention
The subject that the invention solves
The object of the present invention is to provide a kind of granular agrichemical composition, it is characterised in that containing pesticide activity component, has The particle of more than particle diameter 3mm accounts for more than 80% size distribution and the property on the water surface of swimming, and in water in 30 minutes It is disintegrated, is especially to provide a kind of as the dense type pesticide combination for improving the pesticide activity component content in composition pesticide on face The above-mentioned granular agrichemical composition of thing, its disintegrative is good, and easy to manufacture, hygroscopicity is low, easily spreads.
The means to solve the problem
The inventors of the present invention by further investigation it turns out that, the pesticide activity component contained in granular agrichemical composition Volume average particle size can solve for more than 10 μm and 1/10 granular agrichemical composition less than the granular agrichemical composition minor axis Certainly the above subject, so far completes the present invention.
That is, the present invention is herein below.
[1] granular agrichemical composition, it containing pesticide activity component, surfactant, particle diameter is 1-600 μm hollow that it, which is, Body and solid carrier, with more than particle diameter 3mm particle account for more than 80% size distribution and swim on the water surface and at 30 points Clock is with the granular agrichemical composition for the property being disintegrated on the inherent water surface, it is characterised in that the particle diameter of above-mentioned pesticide activity component is More than 10 μm and less than the 1/10 of granular agrichemical composition minor axis.
[2] granular agrichemical composition described in above-mentioned [1], wherein, the particle diameter of pesticide activity component is 10-300 μm.
[3] granular agrichemical composition described in above-mentioned [1] or [2], wherein, using the total amount of granular agrichemical composition as base Standard, the proportioning of pesticide activity component add up to more than 8 mass %.
[4] above-mentioned [1]-[3] any one of them granular agrichemical composition, wherein, with the total amount of granular agrichemical composition On the basis of, the proportioning of pesticide activity component adds up to more than 16 mass %.
[5] above-mentioned [1]-[4] any one of them granular agrichemical composition, wherein, pesticide activity component contains selected from four Azoles Sulfometuron Methyl, Fluoxastrobin, anilofos, Isoprothiolane, three azole amides, imazosulfuron, imidacloprid, indanofan, ethiprole, ethoxy Sulphur is grand, oxadiargyl, oxaziclomefones, cafenstrole, cartap hydrochloride, carfentrazoneethyl, quinoclamine, cumyluron, chloroformyl grass Amine, cyanogen insect amide, cypromisulfuron, cycloprothrin, dinotefuran, cyhalofop-butyl, isoamyl are net, sulfoxaflor, daimuron, thiophene Careless amine, special chaff ester ketone, fluorine ketone sulphur grass amine, tricyclazole, trifluoro-benzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazoxyfen, the phonetic sulphur of pyrrole Grand, pyrazolate, pyriftalid, pyributicarb, Pyr imisulfan (chemical names：N- [2- [(4,6- dimethoxypyridin -2- bases) - Hydroxymethyl] -6- (methoxy) phenyl] -1,1- difluoro Methanesulfomides, molecular formula C16H19F2N3O6S, CAS accession number： 221205-90-9), KIH 6127, pyroquilon, Fenoxasulfone (chemical names：3- [(the chloro- 4- ethoxyl phenenyls of 2,5- bis-) first Sulphonyl] -4,5- dihydros -5,5- dimethyl,-isoxazole, molecular formula C14H17Cl2NO4S, CAS accession number：639826-16-7)、 Fenquinotrione (chemical names：2- [the chloro- 4- of 8- (4- methoxyphenyls) -3- oxo quinoxaline -2- carbonyls] hexamethylene -1, 3- diketone, molecular formula C22H17ClN2O5, CAS accession number：1342891-70-6), fentrazamide, butachlor, flucetosulfuron, third Careless amine, promazine Sulfometuron Methyl, probenazole, bromobutide, bensultap, bensulfuron-methyl, benzobicylon, benzofenap, dogstail It is one kind or two or more in pellet, Huan Wu Evil humulones, piperazine pyrazosulfuron, SSF 126 and mefenacet.
[6] above-mentioned [1]-[4] any one of them granular agrichemical composition, wherein, pesticide activity component contains selected from azoles Pyrazosulfuron, ethiprole, oxaziclomefones, cafenstrole, clomeprop, dinotefuran, sulfoxaflor, special chaff ester ketone, fluorine ketone sulphur Careless amine, trifluoro-benzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazosulfuron, Pyrimisulfan, KIH 6127, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, bensulfuron-methyl, benzobicylon, pyrrole grass It is one kind or two or more in ketone, Huan Wu Evil humulones, SSF 126 and mefenacet.
[7] above-mentioned [1]-[4] any one of them granular agrichemical composition, wherein, pesticide activity component contains selected from second Worm nitrile, cafenstrole, clomeprop, dinotefuran, sulfoxaflor, special chaff ester ketone, pyraclonil, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, benzobicylon, benzofenap, Huan Wu Evil grass It is one kind or two or more in ketone, SSF 126 and mefenacet.
[8] above-mentioned [1]-[7] any one of them granular agrichemical composition, wherein, the ratio of minor axis and major diameter is 1-3.
[9] above-mentioned [1]-[8] any one of them granular agrichemical composition, it includes the outer of curved surface with particle surface Shape.
Invention effect
According to the present invention, for be characterized in that containing pesticide activity component, with more than particle diameter 3mm particle account for 80% with On size distribution and swim the property on the water surface and the granular agrichemical composition that was disintegrated in 30 minutes on the water surface comes Say, the diffusivity of disintegrative and pesticide activity component when being applied to the water surface significantly improves, therefore can be in extensive scope Equably show drug effect.It can particularly provide as the dense type agriculture for improving the pesticide activity component content in composition pesticide The above-mentioned granular agrichemical composition of drug composition, the granular agrichemical composition disintegrative is good, easy to manufacture, hygroscopicity is low, holds Easily spread.
Embodiment
In this specification, when referring to the particle diameter and size distribution of granular agrichemical composition, " minor axis " refers to granular pesticide The length of short part in the shape of composition, " major diameter " refer to the length of the part of length, are pressed from both sides specifically referring to vernier caliper The firmly any two ends of granular agrichemical composition and each most short, longest value for measuring.In addition, " particle diameter " refers to use regulation net The sieve of eye, the particle diameter tried to achieve by sieve method, " size distribution " refer to the accumulative of the specified particle size scope tried to achieve by sieve method Percentage by weight.On the other hand, particle diameter and size distribution using pesticide activity component as each inscape of representative are being referred to When, " particle diameter " refers to the volume mean diameter tried to achieve respectively by laser diffractometry, and " size distribution " refers to pass through laser diffraction The cumulative volume percentage for the specified particle size scope that method is tried to achieve (is measured by wet method；SK laser particle analyzers (Laser Micron Sizer) LMS-2000e (セ イ シ Application enterprise system)).
The granular agrichemical composition of the present invention is to contain pesticide activity component, surfactant, ducted body and solid carrier It is forming, carried out the granular agrichemical composition of extruding pelletization, it is characterised in that account for 80% with the particle of more than particle diameter 3mm Size distribution above and the property on the water surface of swimming, and disintegration time is within 30 minutes.Such granular pesticide combination Thing can obtain by the following method：Mixing forms the raw material of the granular agrichemical composition first, adds the water of ormal weight, carries out Mediate, it is dry from the sieve extruding pelletization of more than aperture 3mm, such as using 2 different sieves of width of mesh, take out and it is expected grain The shot-like particle of degree.
In the granular agrichemical composition of the present invention, pesticide activity component can suitably be lived using the pesticide at normal temperatures for solid Property component, but under room temperature be liquid pesticide activity component, can also by making its absorption carriage on oil absorption material With under room temperature be solid pesticide activity component in the same manner as operate.Therefore, all or part of for pesticide activity component, can To use the pesticide activity component under room temperature for liquid.In addition, in the granular agrichemical composition of the present invention, under using room temperature In the case of pesticide activity component for liquid, it is necessary to make its absorption carriage on oil absorption material to use.As above-mentioned suction Oily material, can illustrate amorphous silica, zeolite, Porous cellulose etc., but be not particularly limited, and can arbitrarily use it Purposes is known material.In addition, the use ratio of above-mentioned oil absorption material is also not particularly limited, in general, relative to being inhaled It is 1 mass parts of pesticide activity component of liquid under the room temperature of attached load, is 0.4-4 mass parts.In this case, in room temperature The pesticide activity component for liquid, which can be regarded as, down has the particle diameter suitable with the particle diameter of the oil absorption material used in the absorption carriage, In addition, in the present invention, can regard as so.In following this specification, do not distinguish sometimes under room temperature as the pesticide activity of solid It is the pesticide activity component of liquid under component and room temperature, all referred to as pesticide activity component, unless otherwise specified, under room temperature Record of the definition based on this section for the particle diameter of the pesticide activity component of liquid explains.It can be used in the present invention illustrated below Pesticide activity component, but be not limited to this.
[herbicidal active component]
Ioxynil (ioxynil), aclonifen (aclonifen), methacrylaldehyde (acrolein), azafenidin (azafenidin), acifluorfen (acifluorfen) (including salt with sodium etc.), azimsulfuron (azimsulfuron), sulphur grass clever (asulam), Acetochlor (acetochlor), atrazine (atrazine), anilofos (anilofos), amicarbazone (amicarbazone), amidosulfuron (amidosulfuron), Amrol (amitrole), chlorine Third pyrimidine acid (aminocyclopyrachlor), chlorine Fampridine sour (aminopyralid), amiprophos-methyl (amiprofos- Methyl), ametryn (ametryn), alachlor (alachlor), alloxydimsodium are (alloxydim), Yi Evil grand (isouron), different Evil chlorine humulone (isoxachlortole), isoxaflutoles (isoxaflutole), Yi Evil acyl grass amine (isoxaben), isoproturon (isoproturon), three azole amides (ipfencarbazone), imazaquin (imazaquin), AC 263222 (imazapic) (including salt with amine etc.), imazapyr (imazapyr) (including salt with isopropylamine etc.), miaow oxalic acid (imazamethabenz-methyl), imazamox (imazamox), imazethapyr (imazethapyr), the phonetic sulphur of azoles pyrrole Grand (imazosulfuron), indenes piperazine benfluralin (indaziflam), indanofan (indanofan), radix glycyrrhizae Tianjin (eglinazine- Ethyl), esprocarb (esprocarb), ethametsulfuron (ethametsulfuron-methyl), ethalfluralin (ethalfluralin), ethidimuron (ethidimuron), ethoxysulfuron (ethoxysulfuron), ethoxyfen-ethyl (ethoxyfen-ethyl), ethofumesate (ethofumesate), ethobenzanid (etobenzanid), Aquathol sodium Salt (endothal-disodium), Evil humulones (oxadiazon), oxadiargyl (oxadiargyl), oxaziclomefones (oxaziclomefone), Oxyfluorfen (oxyfluorfen), oryzalin (oryzalin), orthosulfamuron (orthosulfamuron), orbencarb (orbencarb), cafenstrole (cafenstrole), carfentrazoneethyl (carfentrazone-ethyl), karbutilate (karbutilate), carbetamide (carbetamide), quizalofop-ethyl (quizalofop-ethyl), Quizalotop-ethyl (quizalofop-P-ethyl), quizalofopPtefuryl (quizalofop-P- Tefuryl), quinoclamine (quinoclamine), dichloro quinolinic acid (quinclorac), quinmerac (quinmerac), benzyl Careless grand (cumyluron), chlorine acyl grass phosphine (clacyfos), glyphosate (glyphosate) (including with sodium, potassium, ammonium, amine, propylamine, The salt of isopropylamine, dimethylamine or trimethylsulfonium (trimesium) etc.), glufosinate-ammonium (glufosinate) is (including with amine or sodium etc. Salt), smart glufosinate-ammonium sodium salt (glufosinate-P-sodium), clethodim (clethodim), alkynes oxalic acid (clodinafop- Propargyl), clopyralid (clopyralid), clomazones (clomazone), chlomethoxyfen (chlomethoxyfen), clomeprop (clomeprop), cloransulammethyl (cloransulam-methyl), chloramben (chloramben), chloridazon (chloridazon), chlorimuronethyl (chlorimuron-ethyl), chlorine sulphur are grand (chlorsulfuron), chlorthaldimethyl (chlorthal-dimethyl), chlorthiamide (chlorthiamid), chlorine phthalein Imines (chlorphthalim), chlorflurenol (chlorflurenol-methyl), chlorpropham (chlorpropham), chlorine bromine Grand (chlorbromuron), chloroxifenidium (chloroxuron), chlortoluron (chlorotoluron), benzene flumetsulam (saflufenacil), cyanazine (cyanazine), cyanamide (cyanamide), diuron (diuron), acetyl alachlor (diethatyl-ethyl), Mediben (dicamba) (including with amine, diethylamine, isopropylamine, diglycolamine, sodium or lithium etc. Salt), cycloate (cycloate), cycloxydim (cycloxydim), diclosulam (diclosulam), cypromisulfuron (cyclosulfamuron), Cyclopyrimorate, dichlobenil (dichlobenil), smart diclofop-methyl (diclofop-P- Methyl), diclofop-methyl (diclofop-methyl), 2,4- drops propionic acid (dichlorprop), essence 2,4- drop propionic acid (dichlorprop-P), diquat dibromide (diquat), dithiopyr (dithiopyr), Tupersan (siduron), dinitramine (dinitramine), cinidon-ethyl (cinidon-ethyl), cinosulfuron (cinosulfuron), dinoterb (dinoterb), cyhalofop-butyl (cyhalofop-butyl), diphenamide (diphenamid), difenzoquat (difenzoquat), diflufenican (diflufenican), diflufenzopyr (diflufenzopyr), Simanex (simazine), dimethachlor (dimethachlor), isoamyl net (dimethametryn), dimethenamid (dimethenamid), smart dimethenamid (dimethenamid-P), symetryne (simetryn), dimepiperate (dimepiperate), oxazoles grand (dimefuron), cinmethylin (cinmethylin), swep (swep), sulphur humulone (sulcotrione), sulfentrazone (sulfentrazone), sethoxydim (sethoxydim), terbacil (terbacil), kill Careless grand (daimuron), Dalapon (dalapon), thrizopyr (thiazopyr), Tiafenacil, thiophene ketone sulphur are grand (thiencarbazone) (including sodium salt, methyl esters etc.), tiocarbazil (tiocarbazil), benthiocarb (thiobencarb), thiophene Two cafenstroles (thidiazimin), thifensulfuronmethyl (thifensulfuron-methyl), desmedipham (desmedipham), enemy Careless net (desmetryne), P DimethenamidP (thenylchlor), tebutam (tebutam), tebuthiuron (tebuthiuron), pyrrole Mutter humulone (tepraloxydim), special chaff ester ketone (tefuryltrione), ring sulphur ketone (tembotrione), Garagard (terbuthylazine), terbutryn (terbutryn), Te Dingtong (terbumeton), topramezone (topramezone), Tralkoxydim (tralkoxydim), triaziflam (triaziflam), triasulfuron (triasulfuron), fluorine ketone sulphur Careless amine (triafamone), tri-allate (tri-allate), trietazine (trietazine), trichlopyr (triclopyr), triclopyr butoxyethyl ester (triclopyr-butotyl), Trifludimoxazin, fluoroform Sulphur grand (tritosulfuron), triflusulfuronmethyl (triflusulfuron-methyl), trefanocide (trifluralin), trifluoro Pyridine sulphur grand (trifloxysulfuron-sodium), tribenuron-methyl (tribenuron-methyl), Tolpyralate, quinclorac (naptalam) (including salt with sodium etc.), naproanilide (naproanilide), napropamide (napropamide), napropamide-M (napropamide-M), neburea (neburon), norflurazon (norflurazon), vernolate (vernolate), paraquat (paraquat), fluorine chloropyridine ester (halauxifen-methyl), fluazifop-butyl (haloxyfop), haloxyfop-r-methyl (haloxyfop-P), fluorine pyrrole second standing grain clever (haloxyfop-etotyl), halosulfuronmethyl (halosulfuron-methyl), ammonia Chloropyridine acid (picloram), fluorine pyrrole acyl grass amine (picolinafen), fluorine benzofenap (bicyclopyrone), bispyribac-sodium (bispyribac-sodium), pinoxaden (pinoxaden), bifenox (bifenox), piperophos (piperophos), pyraclonil (pyraclonil), sulphonyl grass pyrazoles (pyrasulfotole), pyrazoxyfen (pyrazoxyfen), pyrazosulfuron (pyrazosulfuron-ethyl), pyrazolate (pyrazolynate), bialaphos (bilanafos), pyraflufen-ethyl (pyraflufen-ethyl), chlorobenzene are rattled away alcohol (pyridafol), pyrithiobac-sodium (pyrithiobac-sodium), pyridate (pyridate), pyriftalid (pyriftalid), pyributicarb (pyributicarb), pyribenzoxim (pyribenzoxim), Pyrimisulfan, KIH 6127 (pyriminobac- Methyl), sulfone pyrrole grass azoles (pyroxasulfone), pyroxsulam (pyroxsulam), phenisopham (phenisopham), non- Careless grand (fenuron), Fenoxasulfone, fenoxaprops (fenoxaprop-P-ethyl), Fenquinotrione, Diclofop-methyl thiazole (fenthiaprop-ethyl), fentrazamide (fentrazamide), phenmedipham (phenmedipham), Formamido group Sulfometuron Methyl (foramsulfuron), butachlor (butachlor), butafenacil (butafenacil), suppression grass Phosphorus (butamifos), butylate (butylate), butenachlor (butenachlor), butralin (butralin), butylbenzene grass Ketone (butroxydim), flazasulfuron (flazasulfuron), wheat straw fluorine (flamprop) (including methyl esters, ethyl ester, isopropyl Ester), fluorine (flamprop-M) (including methyl esters, ethyl ester, isopropyl ester), fluazifop (fluazifop-butyl), smart pyrrole Fluorine diclofop-methyl (fluazifop-P-butyl), fluazolate (fluazolate), fluometuron (fluometuron), second carboxylic fluorine Careless ether (fluoroglycofen-ethyl), flucarbazone (flucarbazone-sodium), fluchloraline (fluchloralin), flucetosulfuron (flucetosulfuron), fluthiacet (fluthiacet-methyl), fluorine pyridine are phonetic Sulphur grand (flupyrsulfuron-methyl-sodium), flufenacet (flufenacet), flufenpyrethyl (flufenpyr- Ethyl), tetrafluoro propionic acid (flupropanate), flupoxam (flupoxame), flumioxazin (flumioxazin), fluorine Alkene oxalic acid (flumiclorac-pentyl), Flumetsulam (flumetsulam), fluridone (fluridone), flurtamone (flurtamone), fluroxypyr (fluroxypyr), fluorochloridone (flurochloridone), pretilachlor (pretilachlor), procarbazone sodium (procarbazone-sodium), prodiamine (prodiamine), prosulfocarb (prosulfocarb), oxalic acid (propaquizafop), propachlor (propachlor), propazine (propazine), enemy Barnyard grass (propanil), propyzamide (propyzamide), propisochlor (propisochlor), promazine Sulfometuron Methyl (propyrisulfuron), Chem hoe (propham), profluazol (profluazol), procarbazone (propoxycarbazone-sodium), clefoxidim (profoxydim), bromacil (bromacil), bromine grass are quick (brompyrazon), prometryn (prometryn), prometon (prometon), Brominal (bromoxynil) (including with fourth The ester of acid, octanoic acid or enanthic acid etc.), bromofenoxim (bromofenoxim), bromobutide (bromobutide), florasulam (florasulam), pethoxamid (pethoxamid), benazolin (benazolin), penoxsuam (penoxsulam), amine benzene Pyrrole bacterium ketone (heptamaloxyloglucan), beflubutamid (beflubutamid), pebulate (pebulate), benzene azoles sulphur Grand (bencarbazone), pendimethalin (pendimethalin), benzfendizone (benzfendizone), bensulide (bensulide), bensulfuron-methyl (bensulfuron-methyl), benzobicylon (benzobicyclon), benzofenap (benzofenap), bentazone (bentazone), pentanochlor (pentanochlor), Huan Wu Evil humulones (pentoxazone), benfluralin (benfluralin), benfuresate (benfuresate), creeping weed phosphorus (fosamine), fluorine sulphur Amine grass ether (fomesafen), Vi par (mecoprop) (including with sodium, potassium, isopropylamine, triethanolamine, dimethylamine etc. Salt), mecopropP (mecoprop-P-potassium), mesosulfuron (mesosulfuron-methyl), methyl sulphur Humulone (mesotrione), metazachlor (metazachlor), piperazine pyrazosulfuron (metazosulfuron), methabenzthiazuron (methabenzthiazuron), metamitron (metamitron), metamifops (metamifop), Methiozolin, Methyldymron (methyldymuron), metoxuron (metoxuron), metosulam (metosulam), metobromuron (metobromuron), metobenzuron (metobenzuron), isopropyl methoxalamine (metolachlor), metribuzin (metribuzin), mefenacet (mefenacet), afesin (monolinuron), molinate (molinate), iodine first Sulphur grand (iodosulfuron), iodosulfuron-methyl-sodium (iodosulfulon-methyl-sodium), Iofensulfuron, Iofensulfuron-sodium, lactofen (lactofen), linuron (linuron), lenacil (lenacil), grass Bud fear (2,3,6-TBA), 2,4,5 trichlorophenoxyacetic acid (2,4,5-T), 2,4 dichlorophenoxyacetic acid (2,4-D) (including with amine, The salt of diethylamine, triethanolamine, isopropylamine, sodium or lithium etc.), 2,4- Embutoxs (2,4-DB), AE-F-150944 (code name), two Nitre phenol (DNOC) (including salt with amine or sodium etc.), herbicide (EPTC), 2 first, 4 chlorine (MCPA), 2 first, 4 chlorine thioethyl ester (MCPA- Thioethyl), Thistrol (MCPB) (including sodium salt, ethyl ester etc.), SYP-298 (code name), SYP-300 (code name), essence are different Methoxalamine (S-metolachlor), 2,2,2- trichloroacetic acids (TCA) (including salt with sodium, calcium or ammonia etc.).
[active insecticidal components]
Acrinathrin (acrinathrin), nimbin (azadirachtin), Jia Ji Bi Evil phosphorus (azamethiphos), Azinphos ethyl (azinphos-ethyl), azinphos-methyl (azinphos-methyl), acequinocyl (acequinocyl), Acetamiprid (acetamiprid), acetyl worm nitrile (acetoprole), orthene (acephate), azacyclotin (azocyclotin), Avermectin (abamectin), Afidopyropen, sulfanilamide (SN) mite ester (amidoflumet), Amitraz (amitraz), alanycarb (alanycarb), Aldicarb (aldicarb), aldoxycarb (aldoxycarb), allethrin (allethrin) [including d- Cis-trans-type, d- be trans-type], isazofos (isazophos), Isamidofos, isocarbophos (isocarbophos), Oxazole phosphorus (isoxathion), Isofenphos methyl (isofenphos-methyl), Mobucin (isoprocarb), ivermectin (ivermectin), new cigarette phosphorus (imicyafos), imidacloprid (imidacloprid), Imiprothrin (imiprothrin), indenes Worm prestige (indoxacarb), S- fenvalerates (esfenvalerate), ethiofencarb (ethiofencarb), Ethodan (ethion), ethiprole (ethiprole), Bromofume (ethylene dibromide), etoxazole (etoxazole), ether Chrysanthemum ester (etofenprox), phonamiphos (ethoprophos), etrimfos (etrimfos), emamectin benzoate benzoic acid Salt (emamectin benzoate), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), empenthrin (empenthrin), oxamyl (oxamyl), oxydemeton_methyl (oxydemeton-methyl), Thiometan (oxydeprofos), omethoate (omethoate), sulphur line Phosphorus (cadusafos), Tefluthrin (Kappa-tefluthrin), Biphenthrin (Kappa-bifenthrin), karanjin (karanjin), cartap (cartap) (including hydrochloride etc.), carbaryl (carbaryl), carbosulfan (carbosulfan), carbofuran (carbofuran), lindane (gamma-BHC), Meobal (xylylcarb), quinalphos (quinalphos), kinoprene (kinoprene), chinomethionat (chinomethionat), Resistox (coumaphos), ice Spar (cryolite), clothianidin (clothianidin), clofentezine (clofentezine), ring tebufenozide (chromafenozide), Rynaxypyr (chlorantraniliprole), chlorethoxyfos (chlorethoxyfos), chlorine Red (chlordane), chloropicrin (chloropicrin), chlopyrifos (chlorpyrifos), chlorpyrifos-methyl (chlorpyrifos-methyl), capillary (chlorfenapyr), chlorfenviphos (chlorfenvinphos), chlorfluazuron (chlorfluazuron), chlormephos (chlormephos), cynock (cyanophos), diafenthiuron (diafenthiuron), Nellite (diamidafos), cyanogen insect amide (cyantraniliprole), everywhere gram (dienochlor), nitrile pyrrole mite ester (cyenopyrafen), salithion (dioxabenzofos), difenolan (diofenolan), Ring bromine insect amide (cyclaniliprole), Carbicron (dicrotophos), dichlofenthion (dichlofenthion), second cyanogen chrysanthemum Ester (cycloprothrin), DDVP (dichlorvos), Dicloromezotiaz, 1,3- d-d mixture (1,3- Dichloropropene), dicofol (dicofol), CGA 183893 (dicyclanil), disulfoton (disulfoton), furan Worm amine (dinotefuran), dinobuton (dinobuton), lambda-cyhalothrin (cyhalothrin) [including γ-type, λ-type], Cyphenothrin (cyphenothrin) [including (1R)-trans-type], cyfloxylate (cyfluthrin) [including β-type], Diflubenzuron (diflubenzuron), cyflumetofen (cyflumetofen), flufenzine (diflovidazin), plictran (cyhexatin), cypermethrin (cypermethrin) [including α-type, β-type, θ-type, ζ-type], dimethylvinphos (dimethylvinphos), dimefluthrin (dimefluthrin), Rogor (dimethoate), silafluofene (silafluofen), cyromazine (cyromazine), ethyl pleocidin (spinetoram), multiple killing teichomycin (spinosad), Envidor (spirodiclofen), spiral shell worm ethyl ester (spirotetramat), Spiromesifen (spiromesifen), sulphur phenylate are grand Sodium (sulcofuron-sodium), sulfluramid (sulfluramid), sulfoxaflor (sulfoxaflor), sulfotep (sulfotep), diazinon (diazinon), thiacloprid (thiacloprid), Diacloden (thiamethoxam), Tioxazafen, thiodicarb (thiodicarb), thiocyclam (thiocyclam), dimehypo (thiosultap), thionazin (thionazin), thiofanox (thiofanox), thiometon (thiometon), Ravap (tetrachlorvinphos), tetradiphon (tetradifon), fluorine cyanogen insect amide (tetraniliprole), tetrafluoro ether Chrysanthemum ester (tetramethylfluthrin), tetramethrin (tetramethrin), butyl pyrimidine phosphorus (tebupirimfos), worm acyl Hydrazine (tebufenozide), tebufenpyrad (tebufenpyrad), Tefluthrin (tefluthrin), fluorobenzene urea (teflubenzuron), demeton-methyl (demeton-S-methyl), Swebate (temephos), decis (deltamethrin), terbufos (terbufos), tralomethrin (tralomethrin), transfluthrin (transfluthrin), triaguron (triazamate), Hostathion (triazophos), metrifonate (trichlorfon), kill Bell urea (triflumuron), trifluoro-benzene pyrimidine (triflumezopyrim), Landrin (trimethacarb), Tolfenpyrad (tolfenpyrad), 2-dichloroethylk dimethyl phosphate (naled), Nitenpyram (nitenpyram), novaluron (novaluron), noviflumuron (noviflumuron), Verticillium lecanii (Verticilliumlecanii), hydroprene (hydroprene), puncture gemma Bacillus (Pasteuriapenetrans), vamidothion (vamidothion), parathion (parathion), parathion-methyl (parathion-methyl), halfenprox (halfenprox), chlorine tebufenozide (halofenozide), bioallethrin (bioallethrin), 2- cyclopentenyls bioallethrin (bioallethrinS-cyclopentenyl), biological benzyl furan chrysanthemum Ester (bioresmethrin), double two flufenoxurons (bistrifluron), hydramethylnon (hydramethylnon), Bifenazate (bifenazate), Biphenthrin (bifenthrin), Pyflubumide, Butacide (piperonylbutoxide), pyrrole aphid Ketone (pymetrozine), pyraclofos (pyraclofos), pyrazine ethiprole (pyrafluprole), pyridaphethione (pyridaphenthion), pyridaben (pyridaben), pyridine worm ether (pyridalyl), Pyrifluquinazon, Pyriprole, Nylar (pyriproxyfen), Aphox (pirimicarb), pyrimidifen (pyrimidifen), pyriminostrobin (pyriminostrobin), pirimiphos-methyl (pirimiphos-methyl), pyrethrin (pyrethrine), famphur (famphur), ethiprole (fipronil), fenazaquin (fenazaquin), fenamiphos (fenamiphos), fenifrothion (fenitrothion), fenoxycarb (fenoxycarb), fenothiocarb (fenothiocarb), phenothrin (phenothrin) [including (1R)-trans-type], Bassa (fenobucarb), Entex (fenthion), phenthoate dimephenthoate cidial (phenthoate), cyanogen Valerate (fenvalerate), fenpyroximate (fenpyroximate), fenbutatin oxide (fenbutatin oxide), Fenpropathrin (fenpropathrin), Fonofos (fonofos), vikane (sulfuryl fluoride), butocarboxim (butocarboxim), butanone sulfone prestige (butoxycarboxim), Buprofezin (buprofezin), furathiocarb (furathiocarb), prallethrin (prallethrin), fluacrypyrim (fluacrypyrim), fluazuron (fluazuron), fluorine sulfone (fluensulfone), Fratol (sodiumfluoroacetate), flucycloxuron are joined (flucycloxuron), flucythrinate (flucythrinate), flusulfamide (flusulfamide), taufluvalinate (fluvalinate) [including tau- types], fluorine pyrrole furanone (flupyradifurone), Flupyrazofos-containpesticide (flupyrazofos), Butene-fipronil (flufiprole), phonetic worm amine (flufenerim), fluorine bacterium mite ester (flufenoxystrobin), flufenoxuron (flufenoxuron), Fluhexafon, Flubendiamide (flubendiamide), flumethrin (flumethrin), propyl benzene Hydrocarbon chrysanthemum ester (protrifenbute), Toyodan (prothiofos), flonicamid (flonicamid), Kayaphos (propaphos), propargite (propargite), Profenofos (profenofos), Broflanilide, the third Flumethrin (profluthrin), propetamphos (propetamphos), arprocarb (propoxur), Flometoquin, fenisobromolate (bromopropylate), Hexythiazox (hexythiazox), flubenzuron (hexaflumuron), thin foot Paecilomyces varioti (Paecilomycestenuipes), paecilomyces fumosoroseus (Paecilomycesfumosoroceus), Heptafluthrin, Heptenophos (heptenophos), Permethrin (permethrin), Benclothiaz, bensultap (bensultap), Citrazon (benzoximate), ficams (bendiocarb), Benfuracard micro (benfuracarb), beauveria tenella (Beauveriatenella), silkworm muscardine (Beauveria bassiana), muscardine (Beauveria Brongniartii), phoxim (phoxim), Phosalone (phosalone), lythidathion (fosthiazate), fosthietan (fosthietan), phosphamidon (phosphamidon), phosmet (phosmet), macro tetrolide (polynactins), cut down worm Amidine (formetanate), thimet (phorate), malathion (malathion), milbemectin (milbemectin), go out Aphid phosphorus (mecarbam), first oxydemeton_methyl (mesulfenfos), Methomyl (methomyl), metaflumizone (metaflumizone), acephatemet (methamidophos), metham-sodium (metham), methiocarb (methiocarb), kill and flutter Phosphorus (methidathion), enemy's line ester (methyl isothiocyanate), bromomethane (methylbromide), methoxy drop drop Tears (methoxychlor), methoxyfenozide (methoxyfenozide), methothrin (methothrin), methoxy benzyl fluorine chrysanthemum Ester (metofluthrin), methoprene (methoprene), MTMC (metolcarb), Menite (mevinphos), chlorine fluorine Ethofenprox (meperfluthrin), Monacrosporiumphymatophagum, Azodrin (monocrotophos), Momfluorothrin, litlure-A, litlure-B, aluminum phosphate (aluminium phosphide), zinc phosphide (zinc Phosphide), hydrogen phosphide (phosphine), lufenuron (lufenuron), Rescalure, resmethrin (resmethrin), rayperidin (lepimectin), rotenone (rotenone), fenbutatin oxide (fenbutatin oxide), Cyanogas (calcium cyanide), nicotine sulphate (nicotine sulfate), (Z) -11- tetradecenes=acetic acid esters, (Z) 16 carbon aldehyde of -11-, (Z) -11- hexadecenes=acetic acid esters, 14 carbon diene of (Z) -9,12-=acetic acid esters, (Z) -9- ten Four carbene -1- alcohol, 14 carbon diene of (Z, E) -9,11-=acetic acid esters, 14 carbon diene of (Z, E) -9,12-=acetic acid esters, Japan Beetle bacillus (Bacillus popilliae), bacillus subtilis (Bacillus subtillis), spherical gemma bar Bacterium (Bacillus sphaericus), bacillus thuringiensis strain (Bacillus thuringiensis Subsp.Aizawai), bacillus thuringiensis subsp israelensis bacterial strain (Bacillus thuringiensis Subsp.Israelensis), bacillus thuringiensis Plutarch sp. strain (Bacillus thuringiensis Subsp.Kurstaki), bacillus thuringiensis intends walking first sp. strain (Bacillus thuringiensis Subsp.Tenebrionis), Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL900167 (code name), nemamort (DCIP), DDT (DDT), three chloro- 1- of dimethyl -2,2,2- Hydroxyethyl phosphonate (DEP), Chemox PE (DNOC), O, O- diethyl-O- [4- (DimethylsuIfamoyl) phenyl]-D2EHDTPA Ester (DSP), thiophosphin (EPN), nuclear polyhedrosis virus embedding body, NA-85 (code name), NA-89 (code name), NC-515 (generations Number), RU15525 (code name), ZDI-2501 (code name), XMC, Z-13- eicosylene -10- ketone, ZXI8901 (code name), ME5382。
[fungicide active ingredient]
Oxygen ring azoles (azaconazole), Acibenzolar (acibenzolar-S-methyl), Fluoxastrobin (azoxystrobin), anilazine (anilazine), amisulbrom (amisulbrom), azoles mepanipyrim (ametoctradin), Chinese mugwort enemy's morpholine (aldimorph), isotianil (isotianil), isopyrazam (isopyrazam), isopropyl metsulfovax (isofetamid), Isoprothiolane (isoprothiolane), kind bacterium azoles (ipconazole), iprodione (iprodione), iprovalicarb (iprovalicarb), different rice blast net (iprobenfos), suppression are mould Azoles (imazalil), three octyl benzene sulfonate (iminoctadine-trialbesilate) of biguanides, iminoctadine triacetate (iminoctadine-triacetate), glyoxalin (imibenconazole), edifenphos (edifenphos), etaconazole (etaconazole), Guardian (ethaboxam), ethirimol (ethirimol), ethoxyquin (ethoxyquin), native bacterium Clever (etridiazole), Enestroburin (enestroburin), Enoxastrobin, epoxiconazole (epoxiconazole), have Machine oil (organicoils), Evil frosts clever (oxadixyl), Oxazinylazole, fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin), oxycarboxin (oxycarboxin), copper 8-hydroxyquinolinate (oxine-copper), terramycin (oxytetracycline), Evil imidazoles (oxpoconazole-fumarate), oxolinic acide (oxolinicacid), cupric octoate (copper dioctanoate), octhilinone (octhilinone), ofurace (ofurace), orysastrobin (orysastrobin), o-phenyl phenol (o-phenyl phenol), kasugarnycin (kasugamycin), difoltan (captafol), ring propionyl bacterium amine (carpropamid), carbendazim (carbendazim), carboxin (carboxin), Sheep's-parsley Ketone (carvone), quinoxyfen (quinoxyfen), chinomethionat (chinomethionat), captan (captan), Quinconazole, pentachloronitrobenzene (quintozene), double pungent guanamines (guazatine), cufraneb (cufraneb), cloves Bacterium ester (coumoxystrobin), kresoxim-methyl (kresoxim-methyl), Clozylacon, chlozolinate (chlozolinate), Bravo (chlorothalonil), chloroneb (chloroneb), cyazofamid (cyazofamid), diethofencarb (diethofencarb), double chlorine zarilamid (diclocymet), dichlofluanid (dichlofluanid), diclomezin (diclomezine), botran (dicloran), antiphen (dichlorophen), dithianon (dithianon), alkene azoles Alcohol (diniconazole), R- olefin conversions (diniconazole-M), zineb (zineb), dinitrocrotonate (dinocap), Dipymetitrone, diphenylamines (diphenylamine), difenoconazole (difenoconazole), ring fluorine Benzyl acid amides (cyflufenamid), fluorine mepanipyrim (diflumetorim), ciproconazole (cyproconazole), cyprodinil (cyprodinil), simeconazoles (simeconazole), dimethirimol (dimethirimol), dimethyl disulfide (dimethyldisulfide), dimethomorph (dimethomorph), cymoxanil (cymoxanil), dimoxystrobin (dimoxystrobin), ziram (ziram), Silthiopham (silthiofam), streptomysin (streptomycin), loop coil Bacterium amine (spiroxamine), fluorine azoles ring bacterium amine (sedaxane), zoxamide (zoxamide), dazomet (dazomet), thiophene acyl Bacterium amine (tiadinil), probenazole (thiabendazole), thiram (thiram), thiophanate (thiophanate), methyl Thiophanate (thiophanate-methyl), thiophene fluorine bacterium amine (thifluzamide), tecnazene (tecnazene), leaf are withered Phthalein (tecloftalam), tetraconazole (tetraconazole), debacarb (debacarb), Tebuconazole (tebuconazole), Tebufloquin, Terbinafine (terbinafine), dodine (dodine), dodemorph (dodemorph), Triadimenol (triadimenol), triazolone (triadimefon), triazoxide (triazoxide), bigcatkin willow bacterium Amine (trichlamide), chlorine nalidixic bacterium ester (triclopyricarb), tricyclazole (tricyclazole), triticonazole (triticonazole), tridemorph (tridemorph), fluorine bacterium azoles (triflumizole), trifloxystrobin (trifloxystrobin), triforine (triforine), Tolylfluanid (tolylfluanid), tolelofos-methyl (tolclofos-methyl), first flusulfamide (tolnifanide), Tolprocarb, Dithane A40 (nabam), natamycin (natamycin), Naftifine (naftifine), trichloromethyl pyridine (nitrapyrin), nitrothalisopropyl (nitrothal- Isopropyl), nuarimol (nuarimol), nonyl benzene copper phenolsulfonate (copper nonyl phenol Sulphonate), bacillus subtilis (Bacillus subtilis) (bacterial strain：QST713), jinggangmeisu (validamycin), figured silk fabrics bacterium amine (valifenalate), Picarbutrazox, biphenyl pyrrole bacterium amine (bixafen), ZEN 90160 (picoxystrobin), bitertanol (bitertanol), binapacryl (binapacryl), biphenyl (biphenyl), disease flower Clever (piperalin), hymexazos (hymexazol), pyraoxystrobin (pyraoxystrobin), pyraclostrobin (pyraclostrobin), Pyraziflumid, pyrazophos (pyrazophos), azoles amine bacterium ester (pyrametostrobin), Pyriofenone, oxazole (pyrisoxazole), pyrifenox (pyrifenox), pyributicarb (pyributicarb), pyrrole Bacterium benzene prestige (pyribencarb), pyrimethanil (pyrimethanil), pyroquilon (pyroquilon), vinclozolin (vinclozolin), fervam (ferbam), famoxadones (famoxadone), phenazine oxide (phenazineoxide), imidazoles Bacterium ketone (fenamidone), alkene oxime amine (fenaminstrobin), Fenarimol (fenarimol), fenoxanil (fenoxanil), ferimzone (ferimzone), fenpiclonil (fenpiclonil), amine benzene pyrrole bacterium ketone (fenpyrazamine), Benzoxazole (fenbuconazole), fenfuram (fenfuram), fenpropidin (fenpropidin), butadiene morpholine (fenpropimorph), fenhexamid (fenhexamid), folpet (folpet), Rabcide (phthalide), second are phonetic Sulfocarbolate (bupirimate), furidazol (fuberidazole), blasticidin-S (blasticidin-S), furametpyr (furametpyr), furalaxyl (furalaxyl), furancarboxylic acid (furancarboxylic acid), fluazinam (fluazinam), fluoxastrobin (fluoxastrobin), fluopicolide (fluopicolide), fluopyram (fluopyram), fluoromide (fluoroimide), fluxapyroxad (fluxapyroxad), Fluquinconazole (fluquinconazole), furconazole (furconazole), furconazole_cis (furconazole-cis), fludioxonil (fludioxonil), Flusilazole (flusilazole), flusulfamide (flusulfamide), fluorine thiophene bacterium net (flutianil), fluorine Acid amides (flutolanil), Flutriafol (flutriafol), fluorine bacterium mite ester (flufenoxystrobin), fluorine acyl bacterium amine (flumetover), flumorph (flumorph), the third oxygen quinoline (proquinazid), Prochloraz (prochloraz), procymidone (procymidone), prothiocarb (prothiocarb), prothioconazoles (prothioconazole), bronopol (bronopol), Propamocarb (propamocarb-hydrochloride), propiconazole (propiconazole), Propineb (propineb), probenazole (probenazole), bromuconazole (bromuconazole), hexaconazole (hexaconazole), M 9834 (benalaxyl), smart M 9834 (benalaxyl-M), benodanil (benodanil), benzene bacterium Clever (benomyl), pefurazoate (pefurazoate), penconazole (penconazole), Pencycuron (pencycuron), benzo alkene Fluorine bacterium azoles (benzovindiflupyr), benthiozole (benthiazole), benzene metsulfovax ester (benthiavalicarb- Isopropyl), pyrrole metsulfovax (penthiopyrad), fluorine azoles bacterium aniline (penflufen), niacinamide (boscalid), three second Phosphonic acids (fosetyl) (aluminium, calcium, sodium), polyoxin (polyoxin), Polycarbamate (polycarbamate), Bordeaux mixture (bordeaux mixture), Mancozeb (mancozeb), mandipropamid (mandipropamid), Mandestrobin, Maneb (maneb), nitrile bacterium azoles (myclobutanil), machine oil (mineral oils), midolthromycin (mildiomycin), Methasulfocarb (methasulfocarb), metham-sodium (metam), metalaxyl (metalaxyl), Metalaxyl-M (metalaxyl-M), Carbatene (metiram), metconazole (metconazole), SSF 126 (metominostrobin), metrafenone (metrafenone), mepanipyrim (mepanipyrim), dinitrocrotonate (meptyldinocap), mebenil (mepronil), iodo propinyl butyl methylamine acid esters (iodocarb), laminarin (laminarin), phosphorous acid and salt (phosphorous acid and salts), Cupravit (copper oxychloride), silver-colored (silver), cuprous oxide (cuprous oxide), Kocide SD (copper hydroxide), saleratus (potassium bicarbonate), carbon Sour hydrogen sodium (sodium bicarbonate), sulphur (sulfur), hydroxyquinoline sulfate (oxyquinoline sulfate), sulfuric acid (chemical name, CAS are logged in for copper (copper sulfate), 4- (tert-butyl group) benzoic acid (3,4- bis- chloroisothiazole -5- bases) methyl esters Number：1231214-23-5), 3- ((bis- chloroisothiazole -5- bases of 3,4-) methoxyl group) benzo [d] isothiazole -1,1- dioxide (is changed Scientific name, CAS accession number：957144-77-3), the double second two of BAF-045 (code name), BAG-010 (code name), dodecyl benzene sulfonic acid Amine copper complex salt [II] (DBEDC), MIF-1002 (code name), fentin acetate (TPTA), triphenyl tin chloride (TPTC), triphen Base stannic hydroxide (TPTH), avirulence carrot Erwinia (Erwinia carotovora).
[plant growth regulating activity component]
1- methyl cyclopropenes (1-methylcyclopropene), 1- naphthyl acetamides (1-naphthyl Acetamide), 2,6- diisopropyl naphthalenes (2,6-diisopropyl naphthalene), 4-chlorophenoxyacetic acid (4-CPA), benzyl Base adenine phosphate (benzylaminopurine), ancymidol (ancymidol), Ai Wei hormones (aviglycine), Sheep's-parsley Ketone (carvone), cycocel (chlormequat), adjust tartaric acid (cloprop), cloxyfonac (cloxyfonac), acid potassium salt of bearing fruit (cloxyfonac-potassium), ring malonamic acid (cyclanilide), the basic element of cell division (cytokinins), daminozide (daminozide), dikegulac (dikegulac), dimethipin (dimethipin), ethephon (CEPHA),2-(chloroethyl) phosphonic acid (ethephon), propionyl rape element Lactone (epocholeone), 'Inshuzhi ' (ethychlozate), flumetralim (flumetralin), flurenol (flurenol), Flurprimidol (flurprimidol), chloropyuril (forchlorfenuron), gibberellin (gibberellin), inabenfide (inabenfide), heteroauxin (indole aceticacid), indolebutyric acid (indole butyric acid), maleic hydrazide (maleic hydrazide), mefluidide (mefluidide), first piperazine (mepiquat chloride), Decanol (n- Decanol), paclobutrazol (paclobutrazol), Prohexadione calcium (prohexadione-calcium), jasmone (prohydrojasmon), sintofen (sintofen), Thidiazuron (thidiazuron), triacontanol (triacontanol), TrinexAN_SNacethyl (trinexapac-ethyl), uniconazole P (uniconazole), smart uniconazole P (uniconazole-P) or 4- oxygen Generation -4- (2- phenylethyls) aminobutyric acid (chemical name, CAS accession number：1083-55-2), calper calcium peroxide.
In above-mentioned pesticide activity component, from be adapted to it is used for ponds from the viewpoint of, preferably using azimsulfuron, phonetic bacterium Ester, anilofos, Isoprothiolane, three azole amides, imazosulfuron, imidacloprid, indanofan, ethiprole, ethoxysulfuron, the third alkynes Evil grass Tong, oxaziclomefones, cafenstrole, cartap hydrochloride, carfentrazoneethyl, quinoclamine, cumyluron, clomeprop, cyanogen insect amide, ring Third Sulfometuron Methyl, cycloprothrin, dinotefuran, cyhalofop-butyl, isoamyl are net, sulfoxaflor, daimuron, P DimethenamidP, special chaff ester ketone, Fluorine ketone sulphur grass amine, tricyclazole, trifluoro-benzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazoxyfen, pyrazosulfuron, pyrazolate, cyclic ester Careless ether, pyributicarb, Pyrimisulfan, KIH 6127, pyroquilon, Fenoxasulfone, Fenquinotrione, tetrazolium acyl grass It is amine, butachlor, flucetosulfuron, pretilachlor, promazine Sulfometuron Methyl, probenazole, bromobutide, bensultap, bensulfuron-methyl, double Ring sulphur humulone, benzofenap, benthiocarb, Huan Wu Evil humulones, piperazine pyrazosulfuron, SSF 126 and mefenacet, particularly can be more Preferably using imazosulfuron, ethiprole, oxaziclomefones, cafenstrole, clomeprop, dinotefuran, sulfoxaflor, special chaff ester Ketone, fluorine ketone sulphur grass amine, trifluoro-benzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazosulfuron, Pyrimisulfan, KIH 6127, cough up Quinoline ketone, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, bensulfuron-methyl, benzobicylon, Benzofenap, Huan Wu Evil humulones, SSF 126 and mefenacet, extraordinarily can further preferably use ethiprole, cafenstrole, chlorine Formyl grass amine, dinotefuran, sulfoxaflor, special chaff ester ketone, pyraclonil, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, benzobicylon, benzofenap, Huan Wu Evil humulones, SSF 126 and Mefenacet.
These pesticide activity components may be used alone or in combination two or more.The conjunction of the proportioning of pesticide activity component Meter is not particularly limited, even it is an advantage of the present invention that coordinate the granular agrichemical composition of substantial amounts of pesticide activity component, Also can be disintegrated on the water surface within 30 minutes, i.e. disintegrative is good, specifically, using the total amount of granular agrichemical composition as base Standard, its use level can be suitably more than 8 mass %, more preferably more than 16 mass %, more than 24 mass %, 30 mass % with Upper, more than 36 mass %.Certainly, the granular agrichemical composition of 8 mass parts, the present invention are less than even with pesticide activity component Granular agrichemical composition disintegrative it is also good.On the other hand, total upper limit of the proportioning of pesticide activity component does not have yet Particular determination, it is contemplated that the cooperation leeway of the other compositions such as surfactant described later, pesticide activity component can be at most 80 Quality % or so, preferably at most 75 mass %, more preferably up to 70 mass %.
The inventors of the present invention are even in the developmental research of the granular agrichemical composition to containing pesticide activity component with high concentration So find, using without fine above-mentioned pesticide activity component as a result, unexpectedly improving granular agrichemical composition In the disintegrative of the water surface.The inventors of the present invention are based on opinion in-depth study repeatedly, finally found that, with more than particle diameter 3mm Particle account in more than 80% size distribution and the granular agrichemical composition for the property swum on the water surface, by using particle diameter Thick pesticide activity component, its disintegrative on the water surface are good.
The above-mentioned trial for ignoring conventional general knowledge is not accounted for originally as the motivation, rapid of Crushing of Ultrafine pesticide activity component The aspect of the effect of pesticide activity component is played, for not by for the fine granular agrichemical composition of pesticide activity component, Delay that effect shows and the low worry of effect are there are certainly, but further, it is surprising that in above-mentioned composition (feature) Granular agrichemical composition in the test of pesticide effectiveness of Tian Puzhong, show with conventional, i.e., except by pesticide activity component micro mist There is the equal drug effect above of granular agrichemical composition of identical composition (feature) beyond broken.Also, it was found that in this experiment, with Toward granular agrichemical composition be disintegrated on the water surface and need the long period, during which influenced by being gathered by wind, on the wind of Tian Pu Side is not sufficiently effective, and poisoning occurs on the downside of the wind of Tian Pu, in contrast to this, the granular agriculture containing the thick pesticide activity component of particle diameter Drug composition has given play to desired diffusivity since the disintegrative on the water surface is good, is presented on whole Tian Pu uniform and good Good drug effect.
On making granular agrichemical composition become in the disintegrative of the water surface by using the thick pesticide activity component of particle diameter The reasons why good and the reasons why do not find delay and low effect that effect shows in the granular agrichemical composition, the present invention People etc., on the latter, as an inference, can be construed to following reason also without clearly theory：The present invention is so Granular agrichemical composition be possess be disintegrated while swimming on the water surface it is property, have dynamic key element pesticidal preparations. The property that the composition pesticide traditional as granula etc. does not have, water floating granular agrichemical composition after treatment will not It is detained in situ, but the gradually diffusion on one side of pesticide activity component one side automatic moving, result, it is believed that there are pesticide activity component Itself concentration of surrounding is maintained at low state, the possibility without fine pesticide activity component also dissolution quickly.This hair The bright constraint from above-mentioned hypothesis correctness, in any case, it is generally recognized that the particle diameter of pesticide activity component show with effect The correlation of speed has obtained the confirmation of the huge knowledge based on past various research report, and in contrast above-mentioned Phenomenon is considered as specific to the water floating granular agrichemical composition as the present invention.
In the present invention, the particle diameter of workable pesticide activity component for more than 10 μm, preferably more than 20 μm and 30 μm with On.The pesticide activity component in granulation and granular agrichemical composition during in view of needing to make manufacture granular agrichemical composition contains Amount uniformly etc., for the upper limit of the particle diameter, suitably use less than the 1/10, preferably 300 μm of the granular agrichemical composition minor axis with Under, more preferably less than 100 μm of pesticide activity component.Hand as the pesticide activity component for the particle diameter for obtaining being suitable for the present invention Section, can be using well known to a person skilled in the art method.That is, when the particle diameter of pesticide activity component is less than above range, such as By recrystallization after being temporarily dissolved in organic solvent etc., the big pesticide activity component of particle diameter can be made, when pesticide activity into When the particle diameter divided is more than above range, broken rear screening is solved by using the mixer with shearing force or impact grinder etc., It can obtain it is expected the pesticide activity component of granularity.
In addition, in the granular agrichemical composition of the present invention, in order to make particle be disintegrated on the water surface, make pesticide activity component Spread in water, can be with matching surface activating agent.As workable surfactant, can use general in composition pesticide The surfactant used.
As the example of specific surfactant, can enumerate polyethylene glycol high-grade aliphatic ester, polyoxyethylene alkyl ether, Polyoxyethylene alkylaryl ether, polyoxyethylene aryl phenyl ether, sorbitan monoalkyl ester, acetylene alcohol and acetylenediol, with And the nonionic surfactant such as their alkylene oxide addition product；Alkylaryl sulfonates, dialkyl group sulfonate, sulfomethylated lignin Hydrochlorate, naphthalene sulfonate and its condensation product, alkyl sulfate salt, alkyl phosphate salt, alkyl aryl sulfate salt, alkylaryl phosphorus Acid esters salt, polyoxyethylene alkyl ether sulfuric acid, polyoxyethylene alkylaryl ether sulfuric acid, polyoxyethylene aryl phenyl ether sulphur The anionic surfactants such as acid esters salt, polyocarboxy acid type high molecular reactive agent；Tetraalkylammonium salt, alkylamine, alkyl The cationic surfactants such as salt；The both sexes tables such as alkyl betaine, alkyl amine oxide, alkyl imidazoline glycine betaine, amino acid Face activating agent；And silicone based surfactants, fluorine system surfactant etc..It is explained, is at normal temperatures the table of liquid Face activating agent is adsorbable to be used in the oil absorption material such as white carbon or diatomite.
Above-mentioned surfactant may be used alone or in combination two or more.In addition, the proportioning of these surfactants It is total be not particularly limited, on the basis of the total amount of granular agrichemical composition, be usually 0.1~15 mass %, be preferably 0.5 ~12.5 mass %, more preferably 1~10 mass %.
The granular agrichemical composition of the present invention must swim on the water surface.Water surface floating is assigned as to granular agrichemical composition The method of trip property, such as can enumerate and be allowed to the method containing following material：The perlite that is made of perlite or obsidian, by white The foaming white sand of sand composition, the fillite (Off ィ ラ イ ト) formed by aluminosilicate system sintering, send out sodium metasilicate or borax Steep microballoon, float stone, granular diatomite, granular active carbon, wood powder, cork powder, bluish dogbane piece, the benzene being made of phenolic resin formed Phenol microballoon, the ecology ball being made of epoxy resin, the polyurethane foam being made of polyurethane series resin, by polyacrylonitrile based resin The microballoon of composition, as thermal power generation when ash and flying dust for producing etc. has the ducted bodies of one or more independent gas chambers；With And be allowed to the method containing the lyophobic dust such as stearic acid and its salt, hydrophabic silica, more preferably the former be allowed to containing tool Have the method for the ducted body of one or more independent gas chambers, due to as the ducted body using thermal plastic high polymer as wall material Baton round is on the basis of the total amount of granular composition, to be a small amount of less than 5 mass %, it can thus be ensured that granular agrichemical composition Water floating, and also act and improve the pair of granulation when by raw material kneaded material extruding pelletization and come into force fruit, from these From the aspect of be particularly preferred.
As the thermal plastic high polymer of the wall material as above-mentioned baton round, hard or soft polyvinyl chloride can be enumerated, gathered The ethene such as vinylidene chloride or polyvinyl alcohol system macromolecule；Polystyrene, high density, polyethylene, the second of Midst density or low-density The polystyrene macromolecule such as alkene/vinyl acetate copolymer；Non-modified polypropylene；The polyacetals system of homopolymer or copolymer Macromolecule；The acrylic acid series macromolecules such as polymethyl methacrylate, methacrylic acid/styrol copolymer；Cellulose acetate；It is poly- Carbonic ester；The Polyester macromolecule such as polyethylene terephthalate；The polyamide-based macromolecule such as nylon 6, nylon66 fiber；Thermoplasticity Polyurethane；Chlorotrifluoroethylene, tetrafluoroethene, tetrafluoroethylene/hexafluoropropylene copolymer, tetrafluoroethylene/perfluoro alkoxy vinyl are total to Fluorine-based polymers such as polymers, tetrafluoroethylene/ethylene copolymer, vinylidene fluoride etc., preferably comprise acrylonitrile as monomeric unit Polyacrylonitrile or polyacrylonitrile based copolymer.As polyacrylonitrile based copolymer, it can specifically enumerate styrene/acrylonitrile and be total to Polymers, phenylethylene/butadiene/acrylonitrile copolymer, vinylidene chloride/methyl methacrylate/acrylonitrile copolymer, methyl-prop E pioic acid methyl ester/acrylonitrile/methacrylonitrile copolymers, methyl methacrylate/acrylonitrile copolymer, acrylonitrile/metering system Nitrile/itaconic acid copolymer etc..The particle diameter of the ducted body is not particularly limited, and is usually 1-600 μm, is preferably 3-300 μm, more excellent Elect 5-100 μm as.
As long as the use level of these ducted bodies can make the amount of granular agrichemical composition acquisition water floating, just without spy It is different to limit, but when being engaged to more than necessary amount, there is the particle for becoming crisp, in preservation, transport when or when use crush, or system Dust yield when making such as increases at the undesirable situation, thus it is expected to coordinate necessary minimum.Therefore, with granular pesticide group On the basis of the total amount of compound, the upper limit of the use level of ducted body body generally can be at most 30 mass % or so, be preferably 15 Below quality %, more preferably below 5 mass %.In the case where ducted body is baton round, even if matching somebody with somebody with below 5 mass % Resultant, granular agrichemical composition can also obtain water floating.In addition, the lower limit of the use level of above-mentioned ducted body is 0.3 matter % is measured, is preferably more than 0.5 mass %.Under the proportioning less than 0.3 mass %, granular agrichemical composition does not show the water surface sometimes Floatability.
And then in the granular agrichemical composition of the present invention, solid carrier can be coordinated.As solid carrier, can make With water-solubility carrier or non aqueous carrier, they can also be applied in combination.Water-solubility carrier can for example enumerate ammonium sulfate, carbon The organic or nothings such as sour hydrogen ammonium, ammonium nitrate, ammonium chloride, potassium chloride, sodium sulphate, magnesium sulfate, sodium citrate, sodium carbonate, sodium acid carbonate The carbohydrates such as the organic acids such as machine Barbiturates, citric acid, butanedioic acid, sucrose, lactose, urea etc..In addition, non aqueous carrier is general Using mineral matter micro mist, such as clay class, calcium carbonate, bentonite, talcum, diatomite, calcium stearate, white carbon etc. can be enumerated.
Above-mentioned solid carrier may be used alone or in combination two or more.In addition, the conjunction of the proportioning of these solid carriers Meter is not particularly limited, and is usually 0.1~91.3 mass % on the basis of the total amount of granular agrichemical composition, preferably 10~ 70 mass %.
In the granular agrichemical composition of the present invention, as other compositions, adjuvant can be coordinated as needed.It is any as this The example of the adjuvant of component, can enumerate the poisoning palliative of pesticide activity component, antidegradant, adhesive, disintegration auxiliary agent etc..
As the concrete example of the poisoning palliative of pesticide activity component, benoxacor (benoxacor), Xie Cao oxazoles can be enumerated (furilazole), dichlormide (dichlormid), Dicyclonone, N1, N2- diallyl-N2- dichloro-acetyls Glycine amide (DKA-24), Xie Caoda (AD-67), bis- chloro- N- of 2,2- (1,3- dioxane -2- ylmethyls)-N- (2- acrylic) Acetamide (PPG-1292), 3- dichloro-acetyl -2,2,5- trimethyl -1,3- oxazolidines (R-29148), cloquitocet_mexyl (cloquintcet-mexyl), naphthalic anhydride (1,8-Naphthalic Anhydride), mefenpyrdiethyl (mefenpyr- Diethyl), pyrazoles solution oxalic acid (mefenpyr), Mefenpyr-ethyl, fenchlorazole (fenchlorazole-O-ethyl), solution Careless pyridine (fenclorim), oxalane (MG-191), cyometrinil (cyometrinil), the careless amine (flurazole) of solution, fluxofenim (fluxofenim), isoxadifen (isoxadifen), isoxadifen ethyl ester (isoxadifen-ethyl), MON4660 (code name), oxabetrinil (oxabetrinil), cyclopropyl-sulfonylamide (cyprosulfamide), low alkyl group substitution benzoic acid, (chemical name, CAS are logged in for TI-35 (code name) or N- (2- methoxybenzoyls) -4- [(amino-carbonyl) amino] benzsulfamide Number：129531-12-0) etc..
As the concrete example of the antidegradant of pesticide activity component, zeolite, quick lime, dry as magnesia can be enumerated The antioxidants such as agent, oxybenzene compound, amine compounds, sulphur compound, phosphate cpd, salicylic acid compound, benzophenone Ultra-violet absorbers such as compound etc..
As the concrete example of adhesive, sanlose, dextrin, water soluble starch, xanthans, Guar can be enumerated Bean gum, sucrose, polyvinylpyrrolidone, polyvinyl alcohol, polyacrylic acid sodium salt, the poly- second two of average molecular weight 6000~20000 Alcohol etc..
As the concrete example of disintegrant, can enumerate sodium tripolyphosphate, calgon, Metallic stearates, cellulose powder, Dextrin, methacrylate ester copolymer, polyvinylpyrrolidone, polyaminocarboxylic acid type chelant compounds, sulfonated phenylethylene- Isobutyiene-maieic anhydride copolymer, S-PAN graft copolymer etc..
Above-mentioned each adjuvant can individually using or be mixed with two or more.In addition, coordinating these adjuvants When, on the basis of the total amount of granular agrichemical composition, the total of the proportioning of adjuvant is usually 0.1-20 mass % or so, preferably For 0.5-10 mass %.
The granular agrichemical composition of the present invention is typically the grain to swim on the water surface formed containing component described above Shape composition, above-mentioned each component and use level are adjusted to causing：When the composition that particle diameter is more than 3mm is made, in water Disintegration time on face is within 30 minutes, preferably within 20 minutes, more preferably within 15 points.Disintegration time is more than 30 points Zhong Shi, gets together without preferred since wind blows granular agrichemical composition.In order to further reduce the influence gathered by wind, phase Prestige is swum when on the water surface with granular agrichemical composition, the part exposed the surface account for the 40% of granular agrichemical composition total amount with Under, preferably less than 20% mode, adjust the use level of above-mentioned each component.
The manufacturing process of the granular agrichemical composition of the present invention can carry out according to known method.That is, by by following Step, can obtain the granular agrichemical composition of the present invention.
[a] mixing forms whole raw materials of granular agrichemical composition, the step of obtaining mixture；
The step of water of addition ormal weight in the mixture that [b] is obtained to above-mentioned steps [a], kneaded mixture；
The kneaded material that [c] obtains above-mentioned steps [b] uses extruding granulator, from the discharge of the sieve of more than aperture 3mm The step of granulation；
The step of granules that [d] dry above-mentioned steps [c] obtain；With
The step of drying-granulating thing that [e] screening above-mentioned steps [d] obtain.
In step [a], mixing includes pesticide activity component, surfactant, ducted body and solid carrier, composition grain Whole raw materials of shape composition pesticide.During mixing, mixer known to Nauta mixer, vertical mixer etc. can be used.It is logical The time as defined in being mixed in above-mentioned mixer is spent whole raw materials, obtains mixture.As pesticide activity component, using normal In the case of the lower pesticide activity component for liquid of temperature, mixed in advance with oil absorption material, be allowed to absorption carriage in oil absorption material After on material, then mix with other raw materials.
Then, water is added in the mixture obtained to above-mentioned steps [a] to be mediated (step [b]).During kneading, it can make The kneader known to kneader, ribbon blender, vertical mixer etc..The amount of the water of addition is not particularly limited, and is being mixed Usually added in thing by 10-15 mass % or so of exterior ratio.By the way that the mixture is mediated in above-mentioned kneader The defined time, obtain kneaded material.
The kneaded material is arranged using extruding granulator from the sieve of more than aperture 3mm, preferably 3-10mm, more preferably 3-8mm Go out and be granulated (step [c]).The minor axis of granular agrichemical composition 1 and the ratio of major diameter of the present invention is preferably 1-3, more Preferably 1-2.Minor axis is preferably 3-10mm, more preferably 3-8mm.And it is preferred that with the shape being made of curved surface, pass through choosing Such shape is selected, in transporting granular pesticide combination and using power spreading machine when being spread, can prevent granular agriculture Abrasion between drug composition and produce micro mist because of collision.As the means that above-mentioned shape is assigned to granular agrichemical composition, Such as can enumerate and the granules that above-mentioned steps [c] obtain are cut into desired length, in the rotary drum that load level is placed, make to turn Drum rotates and rolls granules until it becomes the method for the shape being made of curved surface, and specifically, it is preferable to become granules The shape that the periphery of at least top and bottom of cylinder is chamfered, more preferably makes granules further become hemisphere as top and bottom The ellipsoid of the curved surfaces such as shape or even the shape of sphere.
In addition, by making the compression intensity of disintegration of every 1 of granular agrichemical composition for more than 0.1kgf, preferably 0.3kgf More than, it is possibility to have effect prevents the generation of above-mentioned micro mist.The compression intensity of disintegration is to be applied to 1 with certain acceleration of gravity During load, load value during intragranular disintegration.The compression intensity of disintegration of every 1 can use usual commercially available load test machine or Compression and Expansion testing machine etc. measures.
Then, the granules (step [d]) being dried to obtain.In addition, drying temperature during drying-granulating thing does not have special limit It is fixed, it is 40-95 DEG C or so, for remaining moisture, on the basis of the total amount of granular agrichemical composition, usual drying is extremely 0.3-3 mass % or so, the preferably moisture of 0.3-1.5 mass % or so., can be at the same time when moisture is in such scope Suppress the dusting of granular agrichemical composition and tacky.Its proportion is not particularly limited, but from water floating, packaging easiness and It is preferably 0.3-1 from the viewpoint of ensuring grain number, more preferably 0.3-0.5.
Finally, the granules dried are sieved, filter out the drying-granulating thing for it is expected granularity, the granular agriculture of the present invention is made Drug composition (step [e]).The necessary key element of granular agrichemical composition of the present invention is：It is more more than 3mm containing particle diameter Particle, i.e. with more than particle diameter 3mm particle account for more than 80% size distribution, and then, the grain of 3~10mm of preferable particle size Son accounts for more than 80%, and the particle of particularly preferred 3~8mm of particle diameter accounts for more than 80%.By the way that preparation is set in above-mentioned granularity point Cloth, in the case of being spread from dike side, in the distance from dike side to more than 1m, can be readily derived the paddy field gross area 5~50% area of dispersion.It is explained, as particle diameter to be set as to the raw effect of the pair of more than 3mm, can enumerates following excellent Point：Granula largely is applied containing seedling cultivation of rice case of the usual particle diameter for the particle of 0.8mm or so due to can easily differentiate, from And it can prevent from misapplying.Assuming that in the case where noticing misuse after handling seedling cultivation of rice case, can also by together with The nursery box is immersed in the water and only floats on the surface of the water the preparation of the present invention together, so as to which the infringement of misuse is reduced to minimum journey Degree.
As the example of the preferable composition of the granular agrichemical composition of the present invention, such as can enumerate containing 8 mass % More than the active ingredient with effect used for ponds as component, its particle diameter be 3-8mm, proportion 0.3-0.5, minor axis and length The ratio in footpath is 1-2, there is the shape of particle surface including curved surface, be dispersed on the water surface after the composition that is disintegrated within 20 points.
As the method being dispersed in the granular agrichemical composition of present invention mentioned above on the waters surface such as paddy field, without spy Different limitation, such as following methods can be enumerated：Granular agrichemical composition is held by the method thrown with vinyl gloves, one While water is introduced while the method handled with a small amount of granular agrichemical composition the mouth of a river, continuous using power spreading machine to paddy field The method that ground is sprayed and spread from nozzle, or moment opening and closing shutter tune bar, the method for intermittently spraying and spreading, uses wooden dipper The method of throwing, vibration cylindrical container using the method for hand-rail type shot machine, and use wireless remotecontrol come the method put into Helicopter is with strip or the method for spotted.Alternatively, can also be by the ormal weight of obtained granular agrichemical composition with poly- second The water-solubility membranes such as enol are packed, and in the form of so-called large-scale preparation, are put into together with the package body in paddy field etc..
In the past, in the rice in paddy field makees, in the case of the so-called early maturity culture of transplanting morning in period, even if after the transfer 1 The granular agrichemical composition of water floating is partly spread in a period of~2 weeks, algae, agriculture are also nearly free from paddy field The diffusivity of medicine active ingredient is good, obtains intended effect.But it is 5 months later so-called common phases in transplanting period In cultivation, water temperature rises, and in the suitable phase that pesticide is spread, algae can be generally produced, since the algae significantly hinders pesticide activity The diffusion of component, thus the situation that cannot get desired pesticidal effects is in the majority.The water particularly got together in algae by wind Tian Shang, in the case of local dissemination water floating granular agrichemical composition, algae is blown the part got together almost Less than the effect of pesticide, this is truth.In addition, after several weeks are transplanted, the growth of rice carries out, and is locally dissipated after rice strain becomes larger In the case of cloth water surface floatability composition pesticide, the diffusion of pesticide activity component is also hindered.As it can be seen that using local dissemination as The laborsaving dispersal type composition of premise is the composition spread when rice strain is small.
In this regard, the granular agrichemical composition of the present invention can be described as growing in the paddy field for producing algae or in rice strain To in a degree of paddy field, the diffusion of pesticide activity component is also good, can obtain the water floating of desired pesticidal effects Granular agrichemical composition, by being dispersed in the specific position and specific area in paddy field, can almost without prejudice to Uniformly distributed pesticide activity component in the case of labor-saving when pesticide is spread.That is, by by the present invention particle diameter for 3mm with On the particle diffusivity granular pesticide that accounts for more than 80%, swim on the water surface and be disintegrated in 30 minutes on the water surface Composition with the distance from the dike side in water-filled paddy field (field side) to more than 1m, preferably from dike side to more than 2m away from Dissipated from, 5~50% area of the gross area in paddy field, on preferably 10~50% area and spread and spread, can be in paddy field Pesticide activity component is spread evenly.
It is explained, does not also have even if the granular agrichemical composition of the present invention is dispersed in more than the 50% of the paddy field gross area Problem, but this purpose spread from labour-saving pesticide considers it is nonsensical, is preferably dispersed on less than 50% area.Into And certainly, in the small paddy field in the paddy field before not producing the paddy field of algae, transplant and rice strain, granular pesticide group of the invention The diffusion of the pesticide activity component of compound is also good, can obtain desired pesticidal effects.
Embodiment
Hereinafter, by embodiment, the present invention will be described in detail, but the present invention is from any restrictions of these embodiments.Said Bright, below in an example, part represents mass parts.
[embodiment 1]
Mix the pesticide activity of 12 parts of 2 parts of Pyrimisulfan, 12 parts of Fenquinotrione and fentrazamide into Divide mixture (20.2 μm of particle diameter), 5 parts of aryl sulfonate formaldehyde condensates, 3 parts of arylsulphonate, 3 parts of polyacrylate, phosphoric acid 34 parts of 5 parts of crosslinked starch, 2 parts of polyoxy alkylidene alkynyl glycol ethers, 2 parts of baton round, 15 parts of diatomite, 5 parts of bentonite and clay, After the water of addition ormal weight is mediated, while by the sieve extruding pelletization of mesh diameter 3mm, while being cut into about with scraper The length of 6mm.Obtained granules are put into horizontal positioned rotary drum, make drum rotating and roll granules until its into For the shape being made of curved surface, then sieved after heated-air drying, obtain the minor axis 3mm's containing 26 mass % of pesticide activity component Granular agrichemical composition.Particle of the granular agrichemical composition with more than particle diameter 3mm accounts for more than 80% size distribution, has Swim the property on the water surface, and the ratio with minor axis and major diameter is about 2 and particle surface includes the shape of curved surface, it is in water Disintegration on face needs 2 minutes.
[embodiment 2]
Mix the pesticide activity component of 12 parts of 2 parts of Pyrimisulfan, 8 parts of Fenoxasulfone and benzobicylon Mixture (14.1 μm of particle diameter), 2 parts of arylsulphonate, 2 parts of polyacrylate, 1 part of carboxymethyl cellulose salt, phosphoric acid crosslinked starch 5 parts, it is 2 parts of polyoxy alkylidene alkynyl glycol ethers, 3 parts of polyalkylene glycol, 2 parts of baton round, 15 parts of diatomite, 5 parts of bentonite, viscous Soil 41 parts, add ormal weight water mediated after, while by the sieve extruding pelletization of mesh diameter 5mm, while using scraper It is cut into the length of about 10mm.Obtained granules are put into horizontal positioned rotary drum, make drum rotating and roll granules Move until it becomes the shape being made of curved surface, then heated-air drying, obtains the minor axis containing 22 mass % of pesticide activity component The granular agrichemical composition of 5mm.Particle of the granular agrichemical composition with more than particle diameter 3mm accounts for more than 80% granularity point Cloth, has the property on the water surface of swimming, and the ratio with minor axis and major diameter is about 2 and particle surface includes the outer of curved surface Shape, its disintegration on the water surface need 6 minutes.
[embodiment 3]
Mix 48 parts of pyroquilon (17.7 μm of particle diameter), 8 parts of arylsulphonate, 1 part of polyoxy alkylidene aryl ether sulfate, poly- 1 part of oxyalkylene alkyl ether, 2 parts of polyoxy alkylidene alkynyl glycol ethers, 3 parts of bentonite, 1 part of urea, 3 parts of dextrin, 1 part of baton round With 32 parts of calcium carbonate, add ormal weight water mediated after, while pass through the sieve extruding pelletization of mesh diameter 5mm, on one side The length of about 10mm is cut into scraper.Obtained granules are put into horizontal positioned rotary drum, make drum rotating and make to make Grain thing rolls until it becomes the shape being made of curved surface, and then heated-air drying, obtains containing 48 mass % of pesticide activity component Minor axis 5mm granular agrichemical composition.Particle of the granular agrichemical composition with more than particle diameter 3mm accounts for more than 80% grain Degree distribution, has the property on the water surface of swimming, and the ratio with minor axis and major diameter is about 2 and particle surface includes curved surface Shape, its disintegration on the water surface need 15 minutes.
[embodiment 4]
Pesticide activity component is set as 48 parts of pyroquilon (84.5 μm of particle diameter), in addition, is grasped similarly to Example 3 Make, obtain the granular agrichemical composition of the minor axis 5mm containing 48 mass % of pesticide activity component.The granular agrichemical composition has The particle of more than particle diameter 3mm accounts for more than 80% size distribution, has the property on the water surface of swimming, and have minor axis and length The ratio in footpath is about 2 and particle surface includes the shape of curved surface, its disintegration on the water surface needs 3 minutes.
[embodiment 5]
Pesticide activity component is set as 48 parts of pyroquilon (10 μm of particle diameter), in addition, is operated similarly to Example 3, Obtain the granular agrichemical composition of the minor axis 5mm containing 48 mass % of pesticide activity component.The granular agrichemical composition has grain The particle of more than footpath 3mm accounts for more than 80% size distribution, has the property on the water surface of swimming, and have minor axis and major diameter Ratio be about 2 and particle surface includes the shape of curved surface, its disintegration on the water surface needs 11 minutes.
[comparative example 1]
It is made and pesticide activity component is set as 2 parts of Pyrimisulfan, 12 parts of Fenquinotrione and tetrazolium acyl The pesticide activity component mixture (3.2 μm of particle diameter) of careless 12 parts of amine, in addition, operates, obtains containing agriculture similarly to Example 1 The granular agrichemical composition of the minor axis 3mm of 26 mass % of medicine active ingredient.The granular agrichemical composition has more than particle diameter 3mm Particle accounts for more than 80% size distribution, has and swims the property on the water surface, and the ratio with minor axis and major diameter be about 2 and Particle surface includes the shape of curved surface, its disintegration on the water surface needs more than 30 minutes.
[comparative example 2]
It is made and pesticide activity component is set as 2 parts of Pyrimisulfan, 8 parts of Fenoxasulfone and bicyclic sulphur grass The pesticide activity component mixture (2.6 μm of particle diameter) of 12 parts of ketone, in addition, operates, obtains containing pesticide similarly to Example 2 The granular agrichemical composition of the minor axis 5mm of 22 mass % of active ingredient.The granular agrichemical composition has the grain of more than particle diameter 3mm Son accounts for more than 80% size distribution, has the property on the water surface of swimming, and the ratio with minor axis and major diameter is about 2 and grain Sublist face includes the shape of curved surface, its disintegration on the water surface needs more than 30 minutes.
[comparative example 3]
Pesticide activity component is set as 48 parts of pyroquilon (8.0 μm of particle diameter), in addition, is operated similarly to Example 3, Obtain the granular agrichemical composition of the minor axis 5mm containing 48 mass % of pesticide activity component.The granular agrichemical composition has grain The particle of more than footpath 3mm accounts for more than 80% size distribution, has the property on the water surface of swimming, and have minor axis and major diameter Ratio be about 2 and particle surface includes the shape of curved surface, it splits into substantial amounts of fritter at most 25 minutes on the water surface, but its Disintegration on the water surface needs more than 30 minutes.
[comparative example 4]
Pesticide activity component is set as 48 parts of pyroquilon (6.2 μm of particle diameter), in addition, is operated similarly to Example 3, Obtain the granular agrichemical composition of the minor axis 5mm containing 48 mass % of pesticide activity component.The granular agrichemical composition has grain The particle of more than footpath 3mm accounts for more than 80% size distribution, has the property on the water surface of swimming, and have minor axis and major diameter Ratio be about 2 and particle surface includes the shape of curved surface, it is not disintegrated on the water surface.
[test example 1] diffusivity tests
With each 1 (about 75mg) processing water surface of the granular agrichemical composition of embodiment 1 and comparative example 1.Then, to processing ground Point and the water in place away from place 4m through when sample, using the fentrazamide concentration in the water of the sampling as index, evaluate grain The diffusivity of shape composition pesticide.The results are shown in table 1.
[table 1]
Pesticide activity component is promptly sent to away from processing place by the granular agrichemical composition of embodiment from processing place Position, show the diffusivity more excellent than the granular agrichemical composition of comparative example.
[test example 2] drug effect phytotoxicity test
The Tian Pu of arable land 0.25m × 8m, sowing firefly Lin (イ ヌ ホ タ Le イ (Scirpus juncoides Roxb.var.ohwianus T.Koyama)) seed, then the rice seedling of 2.1 leaf phases is transplanted, then fill water to depth of water 4cm, afterwards Depth of water 4cm is maintained until off-test.It is above-mentioned with embodiment 2 and the processing of the total amount of the granular agrichemical composition 250mg of comparative example 2 The waterside on unilateral 1 side of the short side of Tian Pu.Investigated after being handled 7 days with granular agrichemical composition, after 14 days and after 21 days, At each distance in distance processing place, according to 101 etc. of index 0 (no drug effect or without poisoning) to index 100 (completely withered) Level is come with the degree of poisoning (growth inhibition) of the index assessment to the drug effect (herbicidal effect) of firefly Lin and to rice.The results are shown in table 2 and table 3.
[table 2]
[table 3]
The granular agrichemical composition of embodiment even in processing place nearby also show that with comparative example it is equal more than remove Careless effect, and until the position away from processing place can also play herbicidal effect.In addition, though found near processing place The symptom of poisoning, but the poisoning degree of the granular agrichemical composition of embodiment is slighter than the granular agrichemical composition of comparative example.
Industrial applicability
According to the present invention, for be characterized in that containing pesticide activity component, with more than particle diameter 3mm particle account for 80% with On size distribution and swim the property on the water surface and the granular agrichemical composition that was disintegrated in 30 minutes on the water surface comes Say, the diffusivity of disintegrative and pesticide activity component when being applied on the water surface significantly improves, therefore can be in extensive scope Inside equably show drug effect.Particularly to as the dense type pesticide group for improving the pesticide activity component content in composition pesticide For the above-mentioned granular agrichemical composition of compound, disintegrative good, easy to manufacture can be provided, hygroscopicity is low, easily spreads Granular agrichemical composition.

Claims (9)

1. granular agrichemical composition, it is characterised in that its be containing pesticide activity component, surfactant, particle diameter be 1-600 μm Ducted body and solid carrier, the particle with more than particle diameter 3mm account for more than 80% size distribution and swim on the water surface and The granular agrichemical composition for the property being disintegrated in 30 minutes on the water surface, wherein, the particle diameter of above-mentioned pesticide activity component is More than 10 μm and 1/10 of minor axis less than granular agrichemical composition.
2. the granular agrichemical composition described in claim 1, wherein, the particle diameter of pesticide activity component is 10-300 μm.
3. the granular agrichemical composition described in claim 1 or 2, wherein, on the basis of the total amount of granular agrichemical composition, pesticide The proportioning of active ingredient adds up to more than 8 mass %.
4. claim 1-3 any one of them granular agrichemical compositions, wherein, using the total amount of granular agrichemical composition as base Standard, the proportioning of pesticide activity component add up to more than 16 mass %.
5. claim 1-4 any one of them granular agrichemical compositions, wherein, pesticide activity component contains selected from the phonetic sulphur of tetrazolium Grand, Fluoxastrobin, anilofos, Isoprothiolane, three azole amides, imazosulfuron, imidacloprid, indanofan, ethiprole, ethoxysulfuron, Oxadiargyl, oxaziclomefones, cafenstrole, cartap hydrochloride, carfentrazoneethyl, quinoclamine, cumyluron, clomeprop, cyanogen Insect amide, cypromisulfuron, cycloprothrin, dinotefuran, cyhalofop-butyl, isoamyl are net, sulfoxaflor, daimuron, P DimethenamidP, Special chaff ester ketone, fluorine ketone sulphur grass amine, tricyclazole, trifluoro-benzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazoxyfen, pyrazosulfuron, pyrrole Azoles spy, pyriftalid, pyributicarb, Pyrimisulfan, KIH 6127, pyroquilon, Fenoxasulfone, Fenquinotrione, Fentrazamide, butachlor, flucetosulfuron, pretilachlor, promazine Sulfometuron Methyl, probenazole, bromobutide, bensultap, benzyl In Sulfometuron Methyl, benzobicylon, benzofenap, benthiocarb, Huan Wu Evil humulones, piperazine pyrazosulfuron, SSF 126 and mefenacet It is one kind or two or more.
6. claim 1-4 any one of them granular agrichemical compositions, wherein, pesticide activity component contains selected from the phonetic sulphur of azoles pyrrole Grand, ethiprole, oxaziclomefones, cafenstrole, clomeprop, dinotefuran, sulfoxaflor, special chaff ester ketone, fluorine ketone sulphur grass amine, three Fluorobenzene pyrimidine, halosulfuronmethyl, pyraclonil, pyrazosulfuron, Pyrimisulfan, KIH 6127, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, bensulfuron-methyl, benzobicylon, pyrrole grass It is one kind or two or more in ketone, Huan Wu Evil humulones, SSF 126 and mefenacet.
7. claim 1-4 any one of them granular agrichemical compositions, wherein, pesticide activity component contain selected from ethiprole, Cafenstrole, clomeprop, dinotefuran, sulfoxaflor, special chaff ester ketone, pyraclonil, pyroquilon, Fenoxasulfone, Fenquinotrione, fentrazamide, bromobutide, benzobicylon, benzofenap, Huan Wu Evil humulones, SSF 126 and It is one kind or two or more in mefenacet.
8. claim 1-7 any one of them granular agrichemical compositions, wherein, the ratio of minor axis and major diameter is 1-3.
9. claim 1-8 any one of them granular agrichemical compositions, it includes the shape of curved surface with particle surface.
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