WO2020170655A1 - Pesticide formulation and method for preparing pesticide formulation - Google Patents

Pesticide formulation and method for preparing pesticide formulation Download PDF

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Publication number
WO2020170655A1
WO2020170655A1 PCT/JP2020/000999 JP2020000999W WO2020170655A1 WO 2020170655 A1 WO2020170655 A1 WO 2020170655A1 JP 2020000999 W JP2020000999 W JP 2020000999W WO 2020170655 A1 WO2020170655 A1 WO 2020170655A1
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WIPO (PCT)
Prior art keywords
active ingredient
pesticide
formulation according
granulated product
parts
Prior art date
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PCT/JP2020/000999
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French (fr)
Japanese (ja)
Inventor
龍 田中
Original Assignee
クミアイ化学工業株式会社
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Application filed by クミアイ化学工業株式会社 filed Critical クミアイ化学工業株式会社
Priority to JP2021501689A priority Critical patent/JP7159437B2/en
Priority to KR1020217017063A priority patent/KR20210127913A/en
Publication of WO2020170655A1 publication Critical patent/WO2020170655A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26—Phosphorus; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring

Definitions

  • the present invention relates to a technique for improving the elution property of a poorly water-soluble pesticide active ingredient used in a pesticide formulation having a granulated product as a core.
  • the amount of pesticide active ingredient used in fields and paddy fields is low due to environmental impact, but if the amount used is small, the pesticide active ingredient will be promptly diffused into nursery boxes, fields and paddy fields, and protected immediately. It is difficult to deliver to the target cultivated plant or the pest to be controlled.
  • the pesticide active ingredient when the pesticide active ingredient is sparingly soluble in water, the pesticide active ingredient may not be eluted well and the original effect of the pesticide active ingredient may not be exhibited.
  • Patent Document 2 An improved herbicide composition for paddy fields (Patent Document 2), which contains at least one species, (a) an agrochemical active ingredient having a water solubility of 5 ppm or less at 20° C., and (b) an apparent specific gravity of 0.
  • a water-floating carrier having a particle size of 02 to 0.20, a particle size of 100 to 2000 ⁇ m, and a floating rate of 70% or more after 2 hours, (c) tripolyphosphate, (d) alkylbenzene sulfonate, and (e) others Agricultural chemical granules having improved dissolution in water (Patent Document 3) characterized by containing a carrier of the present invention, and the surface of the granule core is coated with a powder carrier containing water and bentonite using an oily substance as a binder. Techniques such as pesticide granules (Patent Document 4) are proposed.
  • compositions described in Patent Document 2 there is a composition in which silica sand whose particle size is adjusted by sieving is used as a particle nucleus (not a granulated material), and the above compound or the like is attached to it.
  • the particle nucleus is not a granulated product
  • the poorly water-soluble pesticidal active ingredient may not elute well (for example, the compound (6) used in Example 2 of Patent Document 2, ie, pyrazosulfuron-ethyl If).
  • At least one alkali or alkaline earth metal is contained in a solid preparation containing a synthetic pyrethroid and an organic phosphate ester compound as active ingredients and supporting these on a mineral substance carrier.
  • a solid agricultural chemical formulation characterized by containing a weak acid salt of the above is known (Patent Document 5).
  • Patent Document 5 A solid agricultural chemical formulation characterized by containing a weak acid salt of the above is known (Patent Document 5).
  • Patent Document 5 A solid agricultural chemical formulation characterized by containing a weak acid salt of the above is known.
  • the formulation described in Patent Document 5 is obtained by simply mixing and pulverizing each component with a carrier, and improves the stability of the above-mentioned active ingredient when it is used as a wettable powder. It is not a technique for improving the dissolution rate of a poorly water-soluble pesticide active ingredient from a sprayable preparation, particularly a granular preparation.
  • JP-A-62-84004 JP 62-277306 A Japanese Patent Laid-Open No. 2009-79000 JP-A-2015-63467 International publication WO88/06842 pamphlet
  • the present invention uses a wide range of poorly water-soluble pesticidal active ingredients, and is a pesticide formulation such as granules that are easy to spread, and the pesticidal active ingredient can be quickly grown even if the amount used is small. It is intended to provide a technology capable of being diffused in a field or a paddy field and rapidly delivered to a cultivated plant to be protected or a pest to be controlled.
  • the present invention is an agricultural chemical preparation characterized in that a condensed phosphate and a sparingly water-soluble agricultural chemical active ingredient are carried on the surface of a granulated product.
  • the present invention also provides the above-mentioned method for producing a pesticide formulation, which comprises treating the granulated product with a condensed phosphate, a poorly water-soluble pesticidal active ingredient and a binder.
  • the pesticide formulation of the present invention is a pesticide formulation having a granule as a core, so that it is easy to spray, and even if the amount used is small, the pesticide active ingredient is uniformly diffused in nursery boxes, fields or paddy fields. be able to.
  • the agrochemical formulation of the present invention is one in which a condensed phosphate and a sparingly water-soluble agrochemical active ingredient are carried on the surface of a granulated product.
  • poorly water-soluble means that the solubility in water at 20° C. is 500 ppm or less, preferably 100 ppm or less, particularly preferably 20 ppm or less.
  • a pesticidal active ingredient which is slightly soluble in water is better than a completely water-insoluble pesticidal active ingredient, specifically, 0.01 ppm or more, preferably 0.05 ppm or more, particularly preferably 0.1 ppm or more of water.
  • Agrochemical active ingredients with solubility are suitable.
  • the solubility can be measured according to a conventional method using HPLC or the like.
  • particles of the agricultural chemical active ingredient are dispersed in water and shaken to prepare a saturated aqueous solution of the agricultural chemical active ingredient, and high performance liquid chromatography, etc.
  • concentration in water can be obtained by the quantitative analysis of, the method is not limited to the above as long as it is a scientifically valid means, and any means can be used.
  • the phrase "condensed phosphate and poorly water-soluble pesticidal active ingredient are carried on the surface of the granulated product” means that the condensed phosphate and poorly water-soluble pesticidal active component are carried in the form of granules (powder) Or may be supported in a film form.
  • condensed phosphate and the sparingly water-soluble pesticide active ingredient may be carried by physically adhering to the surface of the granulated product, or may be carried by chemically binding the granulated product. It may be supported on a part of the surface of the above, instead of the entire surface.
  • the condensed phosphate used in the agricultural chemical preparation of the present invention is not particularly limited, and examples thereof include lithium pyrophosphate, sodium pyrophosphate, potassium pyrophosphate, ammonium pyrophosphate, lithium tripolyphosphate, sodium tripolyphosphate, potassium tripolyphosphate, and tripolyphosphate. Examples thereof include ammonium acid salts and salts of metaphosphoric acid having a degree of polymerization of 4 or more. Among these condensed phosphates, sodium tripolyphosphate and potassium tripolyphosphate are preferable, and sodium tripolyphosphate is particularly preferable.
  • the amount of the condensed phosphate compounded is 0.01 to 10% by mass (hereinafter simply referred to as “%”) of the agricultural chemical preparation of the present invention, preferably 0.05 to 1%.
  • the poorly water-soluble pesticidal active ingredient used in the pesticide formulation of the present invention is not particularly limited, and examples thereof include cyantraniliprole (14.2 ppm), chlorantraniliprole (1.023 ppm), imidacloprid (480 ppm), and tetranili.
  • the numerical value in parentheses after these poorly water-soluble pesticide active ingredients shows the solubility in water at 20°C. Further, these poorly water-soluble pesticidal active ingredients may be used alone or in combination of two or more, and among them, insecticides and/or fungicides are preferable.
  • the blending amount of these poorly water-soluble pesticidal active ingredients is 0.1 to 10%, preferably 0.3 to 5% of the pesticidal preparation of the present invention.
  • the size of the poorly water-soluble pesticidal active ingredient is not particularly limited as long as it can be carried on the surface of the granulated product, but may be appropriately pulverized if necessary.
  • the mass ratio of the condensed phosphate and the poorly water-soluble pesticide active ingredient is not particularly limited, but is, for example, 1:0.1 to 10, preferably 1:1 to 5.
  • the pesticidal preparation of the present invention may further carry a surfactant.
  • a surfactant is not particularly limited, but examples thereof include alkyl sulfate ester salts, aryl sulfonates, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkyl sulfosuccinates, polycarboxylic acids, polyoxyethylene. Examples thereof include nonyl phenyl ether and sodium lignin sulfonate.
  • the content of the surfactant is 20 to 0.01%, preferably 10 to 0.05% of the pesticide formulation of the present invention.
  • the agricultural chemical formulation of the present invention may further carry other components such as an extender such as clay, calcium carbonate and bentonite, a grinding aid such as silica sand and the like.
  • an extender such as clay, calcium carbonate and bentonite
  • a grinding aid such as silica sand and the like.
  • Granules used in the pesticide formulation of the present invention are not particularly limited as long as they are granulated carriers.
  • the granulated product in the present specification does not include those which have not been granulated, such as those in which the particle size of the original carrier is adjusted by sieving.
  • the pesticide formulation of the present invention the condensed phosphate that is generally used as a disintegrant of the granulated product, does not include in the granulated product, but exerts an effect by supporting it on the surface of the granulated product. is there.
  • the granules used in the pesticide formulation of the present invention may be disintegrating agents containing a disintegrant (disperse disintegrating in water) or non-disintegrating agents containing no disintegrant (not dispersible in water). It doesn't matter which way you choose. However, for example, when the pesticide formulation of the present invention is applied, if the granulated product collapses on the spot due to irrigation or the like, the pesticidal active ingredient will have a high concentration, and the concern for phytotoxicity will increase.
  • the granules used for the pesticide formulation are preferably non-disintegrating ones containing no disintegrant.
  • making the granulated product non-disintegrating is a technique known to those skilled in the art.
  • the carrier is not particularly limited as long as it can be used in a pesticide formulation, and examples thereof include quartz, clay, silica sand, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, minerals such as diatomaceous earth.
  • Organic salts such as inorganic salts such as calcium carbonate and barium carbonate, synthetic silicic acid, synthetic silicate, starch, cellulose, plant powders; plastic carriers such as polyethylene, polypropylene and polyvinylidene chloride; citric acid, succinic acid Organic solid acids such as; sucrose, lactose and other sugars; sodium sulfate, magnesium sulfate, sodium citrate, sodium carbonate, sodium hydrogen carbonate, sodium acetate, ammonium sulfate, ammonium bicarbonate, ammonium nitrate, ammonium chloride, potassium chloride, potassium bitartrate Water-soluble salts such as; urea, alumina, fumed silica (white carbon), and the like.
  • inorganic salts such as calcium carbonate and barium carbonate, synthetic silicic acid, synthetic silicate, starch, cellulose, plant powders
  • plastic carriers such as polyethylene, polypropylene and polyvinylidene chloride
  • clay, kaolinite, bentonite, acid clay, calcium carbonate, starch, ammonium sulfate, potassium chloride and fumed silica are preferable. These carriers may be used alone or in appropriate combination of two or more. When using 2 or more types together, it is preferable to contain at least one or both of clay and calcium carbonate.
  • the method for granulating the above carrier is not particularly limited as long as it is a granulation method used for a pesticide formulation, and examples thereof include extrusion granulation, tumbling granulation, fluidized bed granulation and spray drying granulation.
  • Granulation conditions are also not particularly limited. Of these granulation methods, extrusion granulation is preferred.
  • the extrusion granulation can be performed with an extrusion granulator equipped with a screen or the like. Moreover, you may dry suitably after granulation.
  • this granulated product may contain an agrochemical active ingredient.
  • agrochemical active ingredients include, but are not limited to, those listed below.
  • an agricultural chemical active ingredient may be used together with the carrier when granulating the carrier.
  • [Insecticidal active ingredient] Acrinathrin (acrinathrin), azadirachtin (azadirachtin), azamethiphos (azamethiphos), azinphos-ethyl (azinphos-ethyl), azinphos-methyl (azinphos-methyl), acequinocyl (acequinocyl), acetamiprid (acetamiprid), acetoprole (acetoprole), acephate (Acephate), azocyclotin, abamectin, afidopyropene, afoxolener, amidoflumet alamicarb, alamicarb, alnicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb.
  • allethrin allethrin [d-cis-trans- body, including d-trans- body, isazofos (isazophos), Isamidohosu (Isamidofos), Isokarubohosu (Isocarbophos), isoxathion (isoxathion), isofenphos-methyl ( isofenphos-methyl), isoprocarb (isoprocarb), ivermectin (imvercin), imicyafos (imidaclopriate), imidacloprien phencarbene, imiprothrin phencarbine, indoxacarb (indoxacarb), imiprothrin phenate (indicacarb), imiprothrin phenate, indoxacarb (indoxacarb), indoxacarb.
  • s omethoate, kazusafos, kappa-tefluthrin, kappa-bifenthrin, caranjin, cartanju, carutarp, carlcap, carutarp, cartarp, carutarp, cartarp, carthac carbosulfan), carbofuran (carbofuran), gamma -BHC (gamma-BHC), xylylcarb (xylylcarb), quinalphos (quinalphos), kinoprene (kinoprene), Kinomechioneto (chinomethionat), Coumaphos (coumaphos), cryolite (cryolite), clothianidin ( Clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethorphosphyl, chlorethrophyl, chlorophyrochlor, chlorophyrochlor, chlorophyrochlor, chlorophyrochlor,
  • Cyphenothrin [including (1R)-trans-form], cyfluthrin (including beta-form), diflubenzuron, cyflumethofin (cyflumethofen), hexafluvincid, diflobidine (di), difrovido (di), difrovidazine (di), difrovidin (di), difrovido (dif) Cypermethrin [including alpha-form, beta-form, theta-form, zeta-form], dimethylvinphos, dimefluthrin, dimethoate, siraflurofen (silafluofen) ), spinetoram, spinosad, spirodiclofen, spirotetramat, spiromesifen, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulcofuron-sulfuramid, s
  • Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL90017IP (bis-ethyl), CL90017IP (bis-methyl), CL90017IP (methyl-number), , DDT (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate), DNOC (4,6-dinitro) -O-cresol), DSP(O,O-diethyl-O-[4-(dimethylsulfamoyl)phenyl]-phosphorothionate), EPN(O-ethyl-O-4-(nitrophenyl)phenylphospho) Nothioate), nuclear polyhedrosis virus embedding medium, NA-85 (code number), NA-89 (
  • Isopyrazam isofetamide, isoprothiolane, ipconazole, ipufentrifluconic (ipf), isofetrazole, isofetrazole, isofetramide, isofetamide, isofetamide, isofetamide, isofetamide, isofetamide, isofetamide -Albesylate salt (imoctadine-trialbesilate), iminoctadine-triacetate, imibenconazole, edifenphosmoethriathioxy, ethenexaethoxy, ethenethox, ethenexanthine, ethenax, ethenexanthium, ethenexanthine, ethenexanthine, ethene, ethene, ethene, ethene, ethene, ethene, e
  • nabam natamycin, naftifine, nitrapyrin, nitrothal-isopropyl, nuarimol, nonylphenol sulphonate, nonylphenol sulphonate, nonylphenol sulphonate, copper copter, nonylphenol sulphonate.
  • Bacillus subtilis (strain: QST 713), validamycin, valifenarate, picalbutra Zox (picarbutrazox), bixafen (bixafen), picoxystrobin (picoxystrobin), pidiflumethofen (pydiflumetolphen), bitertanol, binaptanyl, binapacrylyl, binapacryl, biphenyl (biphenyl).
  • furametpyr, furalaxyl, furancarboxylic acid fluazinam, fluindapir (Fluindapyr), fluoxastrobin (fluoxastrobin), fluopicolide (fluopicolide), fluopyram (fluopyram), Furuoruimido (fluoroimide), fluxapyroxad (fluxapyroxad), fluquinconazole (fluquinconazole), fluconazole (furconazole), fluconazole cis (Furconazole-cis), fludioxonil (fludioxonil), flusilazole, flusulfamide, flutianil, flutolanfur (furfuroxyl), flutolanoxy (flutofuronto), flutolanoxy (flutofuronto), flutolanoxy (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto
  • meptyldinocap mepronil, iodocarb, laminarin, phosphorous acid and salts, phosphoric acid silver and salts, basic copper chloride (coperlox, coperlox).
  • [Herbicidal active ingredient] Aioxynil, aclonifen, acrolein, azafenidin, acifluorfen (including salts with sodium), azimsulfuron, ashram-asuram, asula-asula.
  • tefuryl quizalofop-P-tefuryl
  • quinoclamine quinclorac, quinchlorac, quinmerac, cumyluron, cumyluron, clasyphos, clacyloc, clasifo, claflocy, clacylac, clasiflac.
  • chloridazon chloridazon
  • chlorimuron-ethyl chlorimuron-ethyl
  • chlorsulfuron chlorsulfuron
  • Kurorutaru dimethyl chlorlorthal-dimethyl
  • chlorthiamid chlorthiamid
  • Kurorufutarimu Chlorphthalim
  • chloro Hulhule Nord methyl chlorpropham, chlorbromuron, chloroxuron, chlorotoruron, ketospiradox (sodium, calcium or ammonia) including salts such as ketospiradox, sodium, calcium, or ammonia.
  • Saflufenacil Sarumenchin (sarmentine), cyanazine (cyanazine), cyanamide (cyanamide), diuron (diuron), Jietachiru ethyl (diethatyl-ethyl), dicamba (dicamba) (amine, diethylamine, isopropylamine, diglycol amine, sodium or (Including salts such as lithium), cycloate, cycloxydim, diclosulam, cyclosulfamuron, cyclopyrimorate, diclobenyl, dichlobenil.
  • dicamba dicamba
  • diclohop-P-methyl diclohop-methyl, dichlorprop, dichlorprop-P, diquat, dithiomin, dithiurospirone, dithiopirdione, dithiurospirone, dithiopyrrondithion, dithiurospirone, dithiopyrrondithion, dithiurospirone (Dinitramine), cinidone-ethyl, cinosulfuron, dinoseb, dinoterb, cyhalofop cydiafif difenamide (dihafenopide), diphenazodiphenid (diphenamide), diphenamide (diphenamide, diphenamide).
  • diflufenzopyr diflufenzopyr
  • simazine simazine
  • Jimetakuroru difluthachlor
  • dimethametryn dimethametryn
  • dimethenamid dimethenamid ⁇ P
  • simetryn simetryn
  • dimepiperate dimepiperate
  • Jimefuron dimfu ron
  • cinmethylin swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfuronoxy, sulfomethuron-meth-uron, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethro
  • haloxyfop-P haloxyfop-etotyl, halosafen, halosulfuron-methyl, picloram, picolinaphen, cyclolinaphen (picolinafen), picolinaphen (picolinafen), picolinafen (picolinafen) Salt (bispyribac-sodium), pinoxaden (pinoxaden), bifenox (pifenophos), pyraclonil (pyraclonyl), pyrasulfonyl pyrazolone (pyrasulfoyl), pyrazolpyrazolyl (pyrasulfopyr), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy
  • pyrimisulfan pyriminobac-methyl, pyroxasulfone, pyroxsulham, phenisopham, phenuro.
  • Ethyl including isopropyl ester), primisulfuron-methyl, fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluometuron. , Fluoroglycophene-ethyl, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiaset methyl-fluthylactyl-fulthyl-pill.
  • Cyclanilide Cytokinins, Daminozide, Dikegulac, Dimethipin, Ethephonlueflef, Ethephonluefref, Epotheluf, Epotheluf, Epocholefrue, Epocholefrue, Epocholef, Epothele, Epothele, Epothele, Epothele, Epothele, Epothele, Epothele, Epochleol Flurprimidol, forchlorfenuron, gibberellins, inabenfide, indole acetic acid, indolehydric acid, indoleidemic acid, indolehydric acid.
  • Mefluidide mepiquat chloride, n-decyl alcohol, n-decanol, paclobutrazol, prohexadione-calcium, prohydrojamon, prohydrojasmon, prohydrojamon.
  • the size or shape of the granulated product is not particularly limited, but is, for example, 0.3 to 10 mm, preferably 0.8 to 2 mm, and the shape is granular, columnar, columnar, substantially cylindrical, spherical, substantially spherical, ellipsoidal. , Irregular shape, etc., preferably substantially spherical or granular.
  • one or more carriers such as clay, kaolinite, bentonite, acid clay, calcium carbonate, starch, ammonium sulfate, potassium chloride, fumed silica and water, and if necessary auxiliary
  • An example is a granular product obtained by kneading an agent and an agrochemical active ingredient, extruding and kneading the mixture, and drying the granulated product.
  • the pesticide formulation of the present invention can be produced by treating the granulated product with a condensed phosphate, a poorly water-soluble pesticidal active ingredient and a binder. By doing so, the condensed phosphate and the poorly water-soluble pesticidal active ingredient can be supported in the form of particles (powder) on the surface of the granulated product.
  • the binder is not particularly limited, for example, water, lignin sulfonate, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl alcohol/vinyl alkyl ether copolymer, polyacrylamide, polyvinyl pyrrolidone, carboxymethyl cellulose salt, methyl cellulose, ethyl cellulose, ethyl.
  • a liquid substance containing the above is mentioned.
  • these binders liquid paraffin, phthalic acid ester and adipic acid ester are preferable, and liquid paraffin is more preferable.
  • These binders may be contained in the agricultural chemical preparation of the present invention in an amount of 0.5 to 15.0%, preferably 1.0 to 10.0%.
  • the method of treating the granulated product with a condensed phosphate, a sparingly water-soluble pesticidal active ingredient and a binder is not particularly limited, but, for example, after the granulated product is treated with a binder, the condensed phosphate and a sparingly water-soluble pesticidal activity are used.
  • Examples thereof include a method of treating with a component and a method of treating the granulated product with a binder containing a condensed phosphate and a poorly water-soluble pesticide active ingredient.
  • the method of treating the granulated product with a binder and then treating with a condensed phosphate and a poorly water-soluble pesticide active ingredient is preferable.
  • a surfactant it is preferable to use it together with a condensed phosphate and a poorly water-soluble pesticide active ingredient.
  • the granulated product is treated with the binder and then the condensed phosphate and the poorly water-soluble pesticidal active ingredient are used, 80 to 99 parts, preferably 85 to 95 parts of the granulated product and the binder are used.
  • a binder containing a condensed phosphate and a sparingly water-soluble pesticide active ingredient 0.5 to 19.0 parts, preferably 1.0 to 10.0 parts 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts of condensed phosphate and 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts of poor water solubility in binder Pesticide active ingredient, if necessary surfactant 0.01 to 20.0 parts, preferably 0.05 to 10.0 parts, other ingredients 0.01 to 20.0 parts, preferably 0.05 to 10.0
  • this may be mixed with 80 to 99 parts, preferably 85 to 95 parts of the granulated product.
  • the thus-obtained pesticide formulation of the present invention has the condensed phosphate and the sparingly water-soluble pesticide active ingredient supported on the surface of the granulated product. Whether the condensed phosphate and the sparingly water-soluble pesticidal active ingredient of the pesticide formulation of the present invention are carried on the surface of the granulated product can be confirmed by, for example, a scanning electron microscope.
  • the pesticide formulation of the present invention has a property that the dissolution rate of a poorly water-soluble pesticidal active ingredient is improved, and since it can be rapidly delivered to a cultivated plant to be protected or a pest to be controlled, it can be directly sprayed to a treatment target. it can.
  • the pesticide formulation of the present invention can be used for box treatment for seedling raising boxes and the like and for fields and paddy fields, but is preferably used for box treatment for seedling raising boxes and the like.
  • Production example 1 Modified sodium lignin sulfonate (trade name "Pearlex (registered trademark) DP", manufactured by Nippon Paper Industries Co., Ltd.) 10 parts, alkylaryl sulfonate (trade name "New Cargen BX-C", manufactured by Takemoto Yushi Co., Ltd.) 5 Part, precipitated silica (trade name "Carplex (registered trademark) #80", manufactured by DSL Japan Co., Ltd.), 4 parts, silica sand 4 parts, and clay 10.5 parts, and mixed by airflow type powder to obtain powder.
  • Production example 2 0.2 parts of polyoxyethylene alkyl ether sulfate (trade name "Hitenol (registered trademark) NF-13", manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), pregelatinized starch (trade name "Amicol (registered trademark) K", 3 parts of Nippon Starch Chemical Co., Ltd.) and 96.8 parts of clay are mixed, a predetermined amount of water is added and kneaded, and the mixture is extruded from a screen having a hole having a hole diameter of 1.2 mm, dried and granulated into granules I got a thing.
  • polyoxyethylene alkyl ether sulfate trade name "Hitenol (registered trademark) NF-13", manufactured by Daiichi Kogyo Seiyaku Co., Ltd.
  • pregelatinized starch trade name "Amicol (registered trademark) K”
  • Example 1 33.5 parts of the powder of Production Example 1, 51.5 parts of chlorantraniliprole and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco (registered trademark) White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Then, 2.4 parts of clay was added to the mixture and mixed, and further 1.6 parts of the premix was added and mixed to load chlorantraniliprole and sodium tripolyphosphate on the surface of the granulated product. A granular pesticide composition was obtained.
  • liquid paraffin trade name "Moresco (registered trademark) White P-350P"
  • Example 2 33.5 parts of the powder of Production Example 1, 51.5 parts of phenquinotrione and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to prepare a pesticide granular composition having phenquinotrione and sodium tripolyphosphate supported on the surface of the granulated product. Obtained.
  • liquid paraffin trade name "Moresco White P-350P"
  • Example 3 A premix was obtained by mixing 33.5 parts of the powder of Production Example 1, 51.5 parts of bench avalycarb isopropyl, and 15 parts of sodium tripolyphosphate. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix, and then mixed with bench avaricarb isopropyl and sodium tripolyphosphate on the surface of the granulated product. I got a thing.
  • liquid paraffin trade name "Moresco White P-350P"
  • Example 4 33.5 parts of the powder of Production Example 1, 51.5 parts of imidacloprid and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product, and then the mixture 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain an agricultural chemical granular composition in which imidacloprid and sodium tripolyphosphate were supported on the surface of the granulated product. ..
  • liquid paraffin trade name "Moresco White P-350P"
  • Example 5 33.5 parts of the powder of Production Example 1, 51.5 parts of tetraniliprole and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 89.5 parts of the granulated product of Production Example 2 and 5.4 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Thereafter, 2 parts of calcium carbonate was added to the mixture and mixed, and further 3.1 parts of the premix was added and mixed to give tetraniliprole and sodium tripolyphosphate on the surface of the granulated product. A composition was obtained.
  • liquid paraffin trade name "Moresco White P-350P"
  • Comparative Example 1 A premix was obtained by mixing 33.5 parts of the powder of Production Example 1, 51.5 parts of chlorantraniliprole and 15 parts of clay. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition having chlorantraniliprole supported on the surface of the granulated product. ..
  • Comparative example 2 33.5 parts of the powder of Production Example 1, 51.5 parts of phenquinotrione and 15 parts of clay were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition in which phenquinotrione was supported on the surface of the granulated product.
  • liquid paraffin trade name "Moresco White P-350P"
  • Comparative Example 3 A premix was obtained by mixing 33.5 parts of the powder of Production Example 1 with 51.5 parts of bench avalicarb isopropyl and 15 parts of clay. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product, and then the mixture 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition in which bench avaricarb isopropyl was carried on the surface of the granulated product. ..
  • liquid paraffin trade name "Moresco White P-350P"
  • Comparative Example 4 33.5 parts of the powder of Production Example 1, 51.5 parts of imidacloprid and 15 parts of clay were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain an agricultural chemical granular composition in which imidacloprid was supported on the surface of the granulated product.
  • liquid paraffin trade name "Moresco White P-350P"
  • Comparative Example 5 33.5 parts of the powder of Production Example 1, 51.5 parts of tetraniliprole and 15 parts of clay were mixed to obtain a premix. Next, 89.5 parts of the granulated product of Production Example 2 and 5.4 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Thereafter, 2 parts of calcium carbonate was added to the mixture and mixed, and further 3.1 parts of the premix was added and mixed to obtain a pesticide granular composition having tetraniliprole supported on the surface of the granulated product. It was
  • Test example 1 100 mg of the pesticidal granular compositions of Examples 1 to 5 and Comparative Examples 1 to 5 were weighed out, put into 700 mL of 3 degree hard water whose temperature was adjusted to 20° C., and then allowed to stand at 20° C. constant temperature. Water was collected over time, and the concentration of the agrochemical active ingredient in water after a predetermined time was quantified by high performance liquid chromatography under the following conditions. The results are shown in Table 1. It should be noted that none of the pesticide granular compositions disintegrated and dispersed in water, and the shape before being added to water was maintained as it was until the end of the test.
  • Example 6 50 g of the pesticidal granular composition of Example 1 was mechanically sprayed into a nursery box having a length of 30 cm and a width of 60 cm using a chemical application machine. It could be sprayed evenly without any problems.
  • the pesticide formulation of the present invention promotes utilization of a poorly water-soluble pesticide active ingredient for agriculture.

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Abstract

The pesticide formulation uses a wide range of poorly water soluble pesticide active ingredients, and has, as a core, a granule that can be spread easily, the pesticide formulation being characterized in that a condensed phosphate and a pesticidal active ingredient are supported by the surface of the granule. Even when used in a small amount, this pesticide formulation can be delivered to a cultivated plant to be protected or a harmful organism to be controlled by promptly diffusing the pesticidal active ingredient to a seedling box, farmland or a paddy field.

Description

農薬製剤および農薬製剤の製造方法Agrochemical formulation and method for producing agrochemical formulation
　本発明は、造粒物を核とする農薬製剤に用いられる水難溶性農薬活性成分の溶出性を向上させる技術に関する。 The present invention relates to a technique for improving the elution property of a poorly water-soluble pesticide active ingredient used in a pesticide formulation having a granulated product as a core.
　環境への負荷等から畑や水田に対する農薬活性成分の使用量は少ないことが望まれているが、使用量が少ないと速やかに農薬活性成分を育苗箱や畑や水田に拡散させ、速やかに保護対象たる栽培植物や防除対象たる有害生物に送達することは難しい。 It is desired that the amount of pesticide active ingredient used in fields and paddy fields is low due to environmental impact, but if the amount used is small, the pesticide active ingredient will be promptly diffused into nursery boxes, fields and paddy fields, and protected immediately. It is difficult to deliver to the target cultivated plant or the pest to be controlled.
　特に農薬活性成分が水難溶性の場合には、農薬活性成分が上手く溶出されず、農薬活性成分本来の効果を発揮させることができない場合がある。 Especially when the pesticide active ingredient is sparingly soluble in water, the pesticide active ingredient may not be eluted well and the original effect of the pesticide active ingredient may not be exhibited.
　このような問題を解決するため、例えば、Ｓ－（４－クロロベンジル）Ｎ，Ｎ－ジエチルチオールカルバメートおよび２－〔（４，６－ジメトキシピリミジン－２－イル）アミノカルボニルアミノスルホニルメチル〕安息香酸メチルエステルを活性成分として含有する粒状組成物に炭酸カルシウムを添加することを特徴とする改良された除草剤組成物（特許文献１）、（Ａ）ピリミジニルまたはトリアジニルカルバモイルスルファモイル基を有する除草活性化合物、（Ｂ）水溶解度が２０℃で１００ｐｐｍ以下でヒエ科雑草に卓効を示す化合物、（Ｃ）炭酸カルシウムおよび（Ｄ）トリポリリン酸ナトリウム、ピロリン酸ナトリウムまたはピロリン酸カリウムの１種または２種以上を含有することを特徴とする改良された水田用除草剤組成物（特許文献２）、（ａ）２０℃における水溶解度が５ｐｐｍ以下である農薬活性成分、（ｂ）見かけ比重が０．０２～０．２０で、粒度が１００～２０００μｍで且つ２時間後の浮水率が７０％以上である水面浮遊性担体、（ｃ）トリポリリン酸塩、（ｄ）アルキルベンゼンスルホン酸塩および（ｅ）他の担体を含有することを特徴とする水中への溶出性が改善された農薬粒剤（特許文献３）、粒核の表面に、油状物質を結合剤として、水とベントナイトを含む粉末担体を被覆することを特徴とする農薬粒剤（特許文献４）等の技術が提案されている。 In order to solve such a problem, for example, S-(4-chlorobenzyl)N,N-diethylthiol carbamate and 2-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonylaminosulfonylmethyl]benzoic acid Improved herbicidal composition comprising adding calcium carbonate to a granular composition containing methyl ester as an active ingredient (Patent Document 1), (A) pyrimidinyl or triazinylcarbamoylsulfamoyl group-containing herbicidal composition Active compound, (B) a compound having a water solubility of 100 ppm or less at 20° C. and exhibiting excellent effects on grass millet weeds, (C) calcium carbonate and (D) one or two of sodium tripolyphosphate, sodium pyrophosphate or potassium pyrophosphate An improved herbicide composition for paddy fields (Patent Document 2), which contains at least one species, (a) an agrochemical active ingredient having a water solubility of 5 ppm or less at 20° C., and (b) an apparent specific gravity of 0. A water-floating carrier having a particle size of 02 to 0.20, a particle size of 100 to 2000 μm, and a floating rate of 70% or more after 2 hours, (c) tripolyphosphate, (d) alkylbenzene sulfonate, and (e) others Agricultural chemical granules having improved dissolution in water (Patent Document 3) characterized by containing a carrier of the present invention, and the surface of the granule core is coated with a powder carrier containing water and bentonite using an oily substance as a binder. Techniques such as pesticide granules (Patent Document 4) are proposed.
　これらの技術は特定の水難溶性農薬活性成分に関するものが大部分であり、幅広い水難溶性農薬活性成分を用い、かつ、散布も簡単な造粒物を核とするような農薬製剤に関する技術についてのものではない。 Most of these technologies are related to specific sparingly water-soluble pesticide active ingredients, and are related to the technology related to pesticide formulations that use a wide range of sparingly water-soluble pesticide active ingredients and are granulated products that are easy to disperse. is not.
　特に、特許文献２に記載の組成物の中には篩分により粒度を調整した珪砂を粒核（造粒物ではない）とし、これに上記化合物等を付着させたものもあるが、このように粒核が造粒物でない構成では、水難溶性農薬活性成分が上手く溶出しない場合がある（例えば、前記特許文献２の実施例２に使用されている化合物（６）、すなわちピラゾスルフロンエチルの場合等）。 In particular, among the compositions described in Patent Document 2, there is a composition in which silica sand whose particle size is adjusted by sieving is used as a particle nucleus (not a granulated material), and the above compound or the like is attached to it. In the case where the particle nucleus is not a granulated product, the poorly water-soluble pesticidal active ingredient may not elute well (for example, the compound (6) used in Example 2 of Patent Document 2, ie, pyrazosulfuron-ethyl If).
　また、別の技術として、合成ピレスロイドと有機リン酸エステル系化合物とを有効成分として含有し、これらを鉱物質担体に担持してなる固型製剤中に、少なくとも１種のアルカリまたはアルカリ土類金属の弱酸塩を含有してなることを特徴とする農薬固型製剤が知られている（特許文献５）。しかし、この特許文献５に記載の製剤は、単に各成分を担体と共に、混合・粉砕して得られ、それを水和剤にした時の上記有効成分の安定性が向上するものであり、そのまま散布するような製剤、特に粒状製剤からの、水難溶性農薬活性成分の溶出速度を向上させるような技術ではない。 In addition, as another technique, at least one alkali or alkaline earth metal is contained in a solid preparation containing a synthetic pyrethroid and an organic phosphate ester compound as active ingredients and supporting these on a mineral substance carrier. A solid agricultural chemical formulation characterized by containing a weak acid salt of the above is known (Patent Document 5). However, the formulation described in Patent Document 5 is obtained by simply mixing and pulverizing each component with a carrier, and improves the stability of the above-mentioned active ingredient when it is used as a wettable powder. It is not a technique for improving the dissolution rate of a poorly water-soluble pesticide active ingredient from a sprayable preparation, particularly a granular preparation.
特開昭６２－８４００４号公報JP-A-62-84004 特開昭６２－２７７３０６号公報JP 62-277306 A 特開２００９－７９０００号公報Japanese Patent Laid-Open No. 2009-79000 特開２０１５－６３４６７号公報JP-A-2015-63467 国際公開第ＷＯ８８／０６８４２号パンフレットInternational publication WO88/06842 pamphlet
　従って、本発明は幅広い水難溶性農薬活性成分を用い、かつ、散布も簡単な造粒物を核とするような農薬製剤であって、使用量が少なくても速やかに農薬活性成分を育苗箱や畑や水田に拡散させ、速やかに保護対象たる栽培植物や防除対象たる有害生物に送達することのできる技術を提供するものである。 Therefore, the present invention uses a wide range of poorly water-soluble pesticidal active ingredients, and is a pesticide formulation such as granules that are easy to spread, and the pesticidal active ingredient can be quickly grown even if the amount used is small. It is intended to provide a technology capable of being diffused in a field or a paddy field and rapidly delivered to a cultivated plant to be protected or a pest to be controlled.
　本発明者らは上記課題を解決するために鋭意研究した結果、縮合リン酸塩と水難溶性農薬活性成分を、造粒物の表面に担持させることにより、上記課題を解決できることを見出し、本発明を完成させた。 As a result of intensive studies to solve the above problems, the present inventors have found that the above problems can be solved by supporting a condensed phosphate and a sparingly water-soluble pesticide active ingredient on the surface of a granulated product. Was completed.
　すなわち、本発明は、縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されたことを特徴とする農薬製剤である。 That is, the present invention is an agricultural chemical preparation characterized in that a condensed phosphate and a sparingly water-soluble agricultural chemical active ingredient are carried on the surface of a granulated product.
　また、本発明は、造粒物を、縮合リン酸塩、水難溶性農薬活性成分およびバインダーで処理することを特徴とする上記の農薬製剤の製造方法である。 The present invention also provides the above-mentioned method for producing a pesticide formulation, which comprises treating the granulated product with a condensed phosphate, a poorly water-soluble pesticidal active ingredient and a binder.
　本発明の農薬製剤は、造粒物を核とするような農薬製剤であるため散布が簡単であり、しかも、使用量が少なくても均一に農薬活性成分を育苗箱や畑や水田に拡散させることができる。 The pesticide formulation of the present invention is a pesticide formulation having a granule as a core, so that it is easy to spray, and even if the amount used is small, the pesticide active ingredient is uniformly diffused in nursery boxes, fields or paddy fields. be able to.
　本発明の農薬製剤は、縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されたものである。なお、本明細書において水難溶性とは、２０℃の水中で溶解度が５００ｐｐｍ以下、好ましくは１００ｐｐｍ以下、特に好ましくは２０ｐｐｍ以下のものをいう。また、完全に水不溶性の農薬活性成分よりも、僅かながら水に溶解する農薬活性成分がよく、具体的には０．０１ｐｐｍ以上、好ましくは０．０５ｐｐｍ以上、特に好ましくは０．１ｐｐｍ以上の水溶解度を有する農薬活性成分が適する。溶解度の測定はＨＰＬＣ等を用いた常法に従って行うことができ、例えば、水中に農薬活性成分の粒子を分散して振盪するなどし、農薬活性成分飽和水溶液を調整して、高速液体クロマトグラフィー等の定量分析によりその水中濃度を得ることができるが、科学的に妥当な手段であれば前記に限定されず任意の手段を用いることができる。また、縮合リン酸塩と水難溶性農薬活性成分が造粒物の表面に担持されるとは、造粒物の表面に縮合リン酸塩と水難溶性農薬活性成分が粒状（粉状）で担持されていてもよく、被膜状に担持されていてもよい。また、縮合リン酸塩と水難溶性農薬活性成分は、造粒物表面に物理的に付着することにより担持されていてもよく、化学的に結合することにより担持されていてもよく、造粒物の表面全体ではなくその一部に担持されていてもよい。 The agrochemical formulation of the present invention is one in which a condensed phosphate and a sparingly water-soluble agrochemical active ingredient are carried on the surface of a granulated product. In addition, in this specification, poorly water-soluble means that the solubility in water at 20° C. is 500 ppm or less, preferably 100 ppm or less, particularly preferably 20 ppm or less. Further, a pesticidal active ingredient which is slightly soluble in water is better than a completely water-insoluble pesticidal active ingredient, specifically, 0.01 ppm or more, preferably 0.05 ppm or more, particularly preferably 0.1 ppm or more of water. Agrochemical active ingredients with solubility are suitable. The solubility can be measured according to a conventional method using HPLC or the like. For example, particles of the agricultural chemical active ingredient are dispersed in water and shaken to prepare a saturated aqueous solution of the agricultural chemical active ingredient, and high performance liquid chromatography, etc. Although the concentration in water can be obtained by the quantitative analysis of, the method is not limited to the above as long as it is a scientifically valid means, and any means can be used. Further, the phrase "condensed phosphate and poorly water-soluble pesticidal active ingredient are carried on the surface of the granulated product" means that the condensed phosphate and poorly water-soluble pesticidal active component are carried in the form of granules (powder) Or may be supported in a film form. Further, the condensed phosphate and the sparingly water-soluble pesticide active ingredient may be carried by physically adhering to the surface of the granulated product, or may be carried by chemically binding the granulated product. It may be supported on a part of the surface of the above, instead of the entire surface.
　本発明の農薬製剤に用いられる縮合リン酸塩は、特に限定されず、例えば、ピロリン酸リチウム、ピロリン酸ナトリウム、ピロリン酸カリウム、ピロリン酸アンモニウム、トリポリリン酸リチウム、トリポリリン酸ナトリウム、トリポリリン酸カリウム、トリポリリン酸アンモニウム、重合度４以上のメタリン酸の塩等が挙げられる。これらの縮合リン酸塩の中でもトリポリリン酸ナトリウム、トリポリリン酸カリウムが好ましく、特にトリポリリン酸ナトリウムが好ましい。この縮合リン酸塩の配合量は、本発明の農薬製剤の０．０１～１０質量％（以下、単に「％」という）、好ましくは０．０５～１％である。 The condensed phosphate used in the agricultural chemical preparation of the present invention is not particularly limited, and examples thereof include lithium pyrophosphate, sodium pyrophosphate, potassium pyrophosphate, ammonium pyrophosphate, lithium tripolyphosphate, sodium tripolyphosphate, potassium tripolyphosphate, and tripolyphosphate. Examples thereof include ammonium acid salts and salts of metaphosphoric acid having a degree of polymerization of 4 or more. Among these condensed phosphates, sodium tripolyphosphate and potassium tripolyphosphate are preferable, and sodium tripolyphosphate is particularly preferable. The amount of the condensed phosphate compounded is 0.01 to 10% by mass (hereinafter simply referred to as “%”) of the agricultural chemical preparation of the present invention, preferably 0.05 to 1%.
　本発明の農薬製剤に用いられる水難溶性農薬活性成分は、特に限定されず、例えば、シアントラニリプロール（１４．２ｐｐｍ）、クロラントラニリプロール（１．０２３ｐｐｍ）、イミダクロプリド（４８０ｐｐｍ）、テトラニリプロール（１．２ｐｐｍ）、（ＲＳ）－２－クロロ－４－フルオロ－５－［５－（トリフルオロメチルチオ）ペンチルオキシ］フェニル　２，２，２－トリフルオロエチルスルホキシド（０．８１ｐｐｍ）、フルベンジアミド（０．０３ｐｐｍ）、オキサゾスルフィル（１０．８ｐｐｍ）等の殺虫剤、フェンキノトリオン（１７．３ｐｐｍ）、フェノキサスルホン（０．１７ｐｐｍ）、ピロキサスルホン（３．４９ｐｐｍ）等の除草剤、ベンチアバリカルブイソプロピル（１３．１ｐｐｍ）、ペンフルフェン（１１．６７ｐｐｍ）、ピリベンカルブ（６．７６ｐｐｍ）、ジクロベンチアゾクス（０．３６ｐｐｍ）等の殺菌剤等が挙げられる。これら水難溶性農薬活性成分の後の（）内の数値は２０℃の水中での溶解度を示す。また、これら水難溶性農薬活性成分は１種または２種以上を組み合わせてもよいが、これらの中でも殺虫剤および／または殺菌剤が好ましい。これら水難溶性農薬活性成分の配合量は、本発明の農薬製剤の０．１～１０％、好ましくは０．３～５％である。また、これら水難溶性農薬活性成分の大きさは、造粒物の表面に担持できる大きさであれば特に限定されないが、必要であれば適宜粉砕等を行ってもよい。 The poorly water-soluble pesticidal active ingredient used in the pesticide formulation of the present invention is not particularly limited, and examples thereof include cyantraniliprole (14.2 ppm), chlorantraniliprole (1.023 ppm), imidacloprid (480 ppm), and tetranili. Prol (1.2 ppm), (RS)-2-chloro-4-fluoro-5-[5-(trifluoromethylthio)pentyloxy]phenyl 2,2,2-trifluoroethyl sulfoxide (0.81 ppm), fulvene Insecticides such as diamide (0.03 ppm) and oxazosulfyl (10.8 ppm), weeding such as phenquinotrione (17.3 ppm), phenoxasulfone (0.17 ppm) and pyroxasulfone (3.49 ppm) Examples of the agent include bactericides such as benzavalicarb isopropyl (13.1 ppm), penflufen (11.67 ppm), pyribencarb (6.76 ppm) and diclobenazox (0.36 ppm). The numerical value in parentheses after these poorly water-soluble pesticide active ingredients shows the solubility in water at 20°C. Further, these poorly water-soluble pesticidal active ingredients may be used alone or in combination of two or more, and among them, insecticides and/or fungicides are preferable. The blending amount of these poorly water-soluble pesticidal active ingredients is 0.1 to 10%, preferably 0.3 to 5% of the pesticidal preparation of the present invention. The size of the poorly water-soluble pesticidal active ingredient is not particularly limited as long as it can be carried on the surface of the granulated product, but may be appropriately pulverized if necessary.
　本発明の農薬製剤において、上記縮合リン酸塩と水難溶性農薬活性成分の質量比は特に限定されないが、例えば、１：０.１～１０、好ましくは１：１～５である。 In the pesticide formulation of the present invention, the mass ratio of the condensed phosphate and the poorly water-soluble pesticide active ingredient is not particularly limited, but is, for example, 1:0.1 to 10, preferably 1:1 to 5.
　本発明の農薬製剤には、上記縮合リン酸塩、水難溶性農薬活性成分に加えて、更に界面活性剤を担持させてもよい。このような界面活性剤としては特に限定されないが、例えば、アルキル硫酸エステル塩類、アリールスルホン酸塩類、ポリオキシエチレングリコールエーテル類、多価アルコールエステル類、ジアルキルスルホコハク酸塩類、ポリカルボン酸類、ポリオキシエチレンノニルフェニルエーテル、リグニンスルホン酸ナトリウム等が挙げられる。この界面活性剤の配合量は、本発明の農薬製剤の２０～０.０１％、好ましくは１０～０.０５％である。 In addition to the condensed phosphate and the poorly water-soluble pesticidal active ingredient, the pesticidal preparation of the present invention may further carry a surfactant. Such a surfactant is not particularly limited, but examples thereof include alkyl sulfate ester salts, aryl sulfonates, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkyl sulfosuccinates, polycarboxylic acids, polyoxyethylene. Examples thereof include nonyl phenyl ether and sodium lignin sulfonate. The content of the surfactant is 20 to 0.01%, preferably 10 to 0.05% of the pesticide formulation of the present invention.
　本発明の農薬製剤には、上記界面活性剤に加えて、更に、クレー、炭酸カルシウム、ベントナイトなどの増量剤、珪砂などの粉砕助剤等のその他の成分を担持させてもよい。 In addition to the above-mentioned surfactant, the agricultural chemical formulation of the present invention may further carry other components such as an extender such as clay, calcium carbonate and bentonite, a grinding aid such as silica sand and the like.
　本発明の農薬製剤に用いられる造粒物は、担体を造粒したものであれば特に限定されない。なお、当然のことながら本明細書における造粒物とは、担体の原体を篩分等により粒度を整えたもの等の造粒をしていないものは含まない。また、本発明の農薬製剤は、一般的に造粒物の崩壊剤として用いられる縮合リン酸塩を、造粒物に含ませず、造粒物の表面に担持して効果を発揮するものである。そのため、本発明の農薬製剤に用いられる造粒物は、崩壊剤を含む崩壊性のもの（水中で分散崩壊する）でも、崩壊剤を含まない非崩壊性のもの（水中で分散崩壊しない）のどちらでもかまわないと考えられる。しかしながら、例えば、本発明の農薬製剤を施用した場合に、灌水等によりその場で造粒物が崩壊してしまうと、農薬活性成分が高濃度となり、薬害の懸念が大きくなるため、本発明の農薬製剤に用いられる造粒物は、崩壊剤を含まない非崩壊性のものが好ましい。なお、造粒物を非崩壊性にすることは当業者に公知の技術である。 Granules used in the pesticide formulation of the present invention are not particularly limited as long as they are granulated carriers. In addition, as a matter of course, the granulated product in the present specification does not include those which have not been granulated, such as those in which the particle size of the original carrier is adjusted by sieving. Further, the pesticide formulation of the present invention, the condensed phosphate that is generally used as a disintegrant of the granulated product, does not include in the granulated product, but exerts an effect by supporting it on the surface of the granulated product. is there. Therefore, the granules used in the pesticide formulation of the present invention may be disintegrating agents containing a disintegrant (disperse disintegrating in water) or non-disintegrating agents containing no disintegrant (not dispersible in water). It doesn't matter which way you choose. However, for example, when the pesticide formulation of the present invention is applied, if the granulated product collapses on the spot due to irrigation or the like, the pesticidal active ingredient will have a high concentration, and the concern for phytotoxicity will increase. The granules used for the pesticide formulation are preferably non-disintegrating ones containing no disintegrant. In addition, making the granulated product non-disintegrating is a technique known to those skilled in the art.
　担体は、農薬製剤に用いることができるものであれば特に限定されず、例えば、石英、クレー、珪砂、カオリナイト、ピロフィライト、セリサイト、タルク、ベントナイト、酸性白土、アタパルジャイト、ゼオライト、珪藻土などの鉱物類；炭酸カルシウム、炭酸バリウムなどの無機塩類、合成ケイ酸、合成ケイ酸塩、デンプン、セルロース、植物粉末等の有機固体類；ポリエチレン、ポリプロピレン、ポリ塩化ビニリデン等のプラスチック担体；クエン酸、コハク酸などの有機固体酸類；蔗糖、ラクトースなどの糖類；硫酸ナトリウム、硫酸マグネシウム、クエン酸ナトリウム、炭酸ナトリウム、炭酸水素ナトリウム、酢酸ナトリウム、硫酸アンモニウム、重炭酸アンモニウム、硝酸アンモニウム、塩化アンモニウム、塩化カリウム、重酒石酸カリウム等の水溶性塩類；尿素、アルミナ、フュームドシリカ（ｆｕｍｅｄ  ｓｉｌｉｃａ，ホワイトカーボン）等を挙げることができる。前記担体の中でもクレー、カオリナイト、ベントナイト、酸性白土、炭酸カルシウム、デンプン、硫酸アンモニウム、塩化カリウム、フュームドシリカが好ましい。これらの担体は１種を単独で用いてもよいし、適宜２種以上を併用してもよい。２種以上を併用する場合は、少なくともクレーまたは炭酸カルシウムのいずれかまたは両方を含むことが好ましい。 The carrier is not particularly limited as long as it can be used in a pesticide formulation, and examples thereof include quartz, clay, silica sand, kaolinite, pyrophyllite, sericite, talc, bentonite, acid clay, attapulgite, zeolite, minerals such as diatomaceous earth. Organic salts such as inorganic salts such as calcium carbonate and barium carbonate, synthetic silicic acid, synthetic silicate, starch, cellulose, plant powders; plastic carriers such as polyethylene, polypropylene and polyvinylidene chloride; citric acid, succinic acid Organic solid acids such as; sucrose, lactose and other sugars; sodium sulfate, magnesium sulfate, sodium citrate, sodium carbonate, sodium hydrogen carbonate, sodium acetate, ammonium sulfate, ammonium bicarbonate, ammonium nitrate, ammonium chloride, potassium chloride, potassium bitartrate Water-soluble salts such as; urea, alumina, fumed silica (white carbon), and the like. Among the above carriers, clay, kaolinite, bentonite, acid clay, calcium carbonate, starch, ammonium sulfate, potassium chloride and fumed silica are preferable. These carriers may be used alone or in appropriate combination of two or more. When using 2 or more types together, it is preferable to contain at least one or both of clay and calcium carbonate.
　上記担体を造粒する方法は、農薬製剤に用いる造粒法であれば、特に限定されず、例えば、押し出し造粒、転動造粒、流動層造粒、噴霧乾燥造粒等が挙げられる。造粒の条件も特に限定されない。これらの造粒法の中でも押し出し造粒が好ましい。押し出し造粒は、スクリーン等を備えた押し出し造粒機等で行うことができる。また、造粒後は、適宜乾燥を行ってもよい。 The method for granulating the above carrier is not particularly limited as long as it is a granulation method used for a pesticide formulation, and examples thereof include extrusion granulation, tumbling granulation, fluidized bed granulation and spray drying granulation. Granulation conditions are also not particularly limited. Of these granulation methods, extrusion granulation is preferred. The extrusion granulation can be performed with an extrusion granulator equipped with a screen or the like. Moreover, you may dry suitably after granulation.
　上記担体を造粒するにあたり、所望によりアルキル硫酸エステル塩類、アリールスルホン酸塩類、ポリオキシエチレングリコールエーテル類、多価アルコールエステル類、ジアルキルスルホコハク酸塩類、ポリカルボン酸類、ポリオキシエチレンノニルフェニルエーテル、リグニンスルホン酸ナトリウム等の界面活性剤；澱粉、アルギン酸、グリセリン、ポリビニルピロリドン、ポリウレタン、ポリエチレングリコール、ポリプロピレングリコール、ポリブテン、ポリビニルアルコール、アラビアガム、流動パラフィン、エチルセルロース、ポリビニルアセテート等の結合剤；ステアリン酸カルシウム、タルク、シリカ等の滑沢剤；染料や顔料等の着色剤；等の補助剤を用いてもよい。これらの補助剤は１種を単独で用いてもよいし、適宜２種以上を併用してもよい。 In granulating the carrier, if desired, alkyl sulfate ester salts, aryl sulfonates, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkyl sulfosuccinates, polycarboxylic acids, polyoxyethylene nonylphenyl ethers, lignin Surfactants such as sodium sulfonate; starch, alginic acid, glycerin, polyvinylpyrrolidone, polyurethane, polyethylene glycol, polypropylene glycol, polybutene, polyvinyl alcohol, gum arabic, liquid paraffin, ethyl cellulose, polyvinyl acetate, etc. binders; calcium stearate, talc Auxiliary agents such as lubricants such as silica and silica; coloring agents such as dyes and pigments; These auxiliary agents may be used alone or in appropriate combination of two or more kinds.
　また、この造粒物には、農薬活性成分を含ませてもよい。このような農薬活性成分としては、例えば、下記に列挙するものを挙げることができるが、特に限定されるものではない。また、このような農薬活性成分は、上記担体を造粒する際に担体と共に用いればよい。 Also, this granulated product may contain an agrochemical active ingredient. Examples of such agrochemical active ingredients include, but are not limited to, those listed below. Further, such an agricultural chemical active ingredient may be used together with the carrier when granulating the carrier.
［殺虫活性成分］
　アクリナトリン（ａｃｒｉｎａｔｈｒｉｎ）、アザジラクチン（ａｚａｄｉｒａｃｈｔｉｎ）、アザメチホス（ａｚａｍｅｔｈｉｐｈｏｓ）、アジンホス・エチル（ａｚｉｎｐｈｏｓ－ｅｔｈｙｌ）、アジンホス・メチル（ａｚｉｎｐｈｏｓ－ｍｅｔｈｙｌ）、アセキノシル（ａｃｅｑｕｉｎｏｃｙｌ）、アセタミプリド（ａｃｅｔａｍｉｐｒｉｄ）、アセトプロール（ａｃｅｔｏｐｒｏｌｅ）、アセフェート（ａｃｅｐｈａｔｅ）、アゾシクロチン（ａｚｏｃｙｃｌｏｔｉｎ）、アバメクチン（ａｂａｍｅｃｔｉｎ）、アフィドピロペン（ａｆｉｄｏｐｙｒｏｐｅｎ）、アフォキソレイナー（ａｆｏｘｏｌａｎｅｒ）、アミドフルメット（ａｍｉｄｏｆｌｕｍｅｔ）、アミトラズ（ａｍｉｔｒａｚ）、アラニカルブ（ａｌａｎｙｃａｒｂ）、アルジカルブ（ａｌｄｉｃａｒｂ）、アルドキシカルブ（ａｌｄｏｘｙｃａｒｂ）、アレスリン（ａｌｌｅｔｈｒｉｎ）［ｄ－ｃｉｓ－ｔｒａｎｓ－体、ｄ－ｔｒａｎｓ－体を含む］、イサゾホス（ｉｓａｚｏｐｈｏｓ）、イサミドホス（ｉｓａｍｉｄｏｆｏｓ）、イソカルボホス（ｉｓｏｃａｒｂｏｐｈｏｓ）、イソキサチオン（ｉｓｏｘａｔｈｉｏｎ）、イソフェンホス・メチル（ｉｓｏｆｅｎｐｈｏｓ－ｍｅｔｈｙｌ）、イソプロカルブ（ｉｓｏｐｒｏｃａｒｂ）、イベルメクチン（ｉｖｅｒｍｅｃｔｉｎ）、イミシアホス（ｉｍｉｃｙａｆｏｓ）、イミダクロプリド（ｉｍｉｄａｃｌｏｐｒｉｄ）、イミプロトリン（ｉｍｉｐｒｏｔｈｒｉｎ）、インドキサカルブ（ｉｎｄｏｘａｃａｒｂ）、エスフェンバレレート（ｅｓｆｅｎｖａｌｅｒａｔｅ）、エチオフェンカルブ（ｅｔｈｉｏｆｅｎｃａｒｂ）、エチオン（ｅｔｈｉｏｎ）、エチプロール（ｅｔｈｉｐｒｏｌｅ）、エチレンジブロミド（ｅｔｈｙｌｅｎｅ　ｄｉｂｒｏｍｉｄｅ）、エトキサゾール（ｅｔｏｘａｚｏｌｅ）、エトフェンプロックス（ｅｔｏｆｅｎｐｒｏｘ）、エトプロホス（ｅｔｈｏｐｒｏｐｈｏｓ）、エトリムホス（ｅｔｒｉｍｆｏｓ）、エマメクチンベンゾエート（ｅｍａｍｅｃｔｉｎ　ｂｅｎｚｏａｔｅ）、エンドスルファン（ｅｎｄｏｓｕｌｆａｎ）、エンペントリン（ｅｍｐｅｎｔｈｒｉｎ）、オキサゾスルフィル（ｏｘａｚｏｓｕｌｆｙｌ）、オキサミル（ｏｘａｍｙｌ）、オキシジメトン・メチル（ｏｘｙｄｅｍｅｔｏｎ－ｍｅｔｈｙｌ）、オキシデプロホス（ｏｘｙｄｅｐｒｏｆｏｓ）、オメトエート（ｏｍｅｔｈｏａｔｅ）、カズサホス（ｃａｄｕｓａｆｏｓ）、カッパ－テフルトリン（ｋａｐｐａ－ｔｅｆｌｕｔｈｒｉｎ）、カッパ－ビフェントリン（ｋａｐｐａ－ｂｉｆｅｎｔｈｒｉｎ）、カランジン（ｋａｒａｎｊｉｎ）、カルタップ（ｃａｒｔａｐ）、カルバリル（ｃａｒｂａｒｙｌ）、カルボスルファン（ｃａｒｂｏｓｕｌｆａｎ）、カルボフラン（ｃａｒｂｏｆｕｒａｎ）、ガンマ－ＢＨＣ（ｇａｍｍａ－ＢＨＣ）、キシリルカルブ（ｘｙｌｙｌｃａｒｂ）、キナルホス（ｑｕｉｎａｌｐｈｏｓ）、キノプレン（ｋｉｎｏｐｒｅｎｅ）、キノメチオネート（ｃｈｉｎｏｍｅｔｈｉｏｎａｔ）、クマホス（ｃｏｕｍａｐｈｏｓ）、クリオライト（ｃｒｙｏｌｉｔｅ）、クロチアニジン（ｃｌｏｔｈｉａｎｉｄｉｎ）、クロフェンテジン（ｃｌｏｆｅｎｔｅｚｉｎｅ）、クロマフェノジド（ｃｈｒｏｍａｆｅｎｏｚｉｄｅ）、クロラントラニリプロール（ｃｈｌｏｒａｎｔｒａｎｉｌｉｐｒｏｌｅ）、クロルエトキシホス（ｃｈｌｏｒｅｔｈｏｘｙｆｏｓ）、クロルデン（ｃｈｌｏｒｄａｎｅ）、クロルピクリン（ｃｈｌｏｒｏｐｉｃｒｉｎ）、クロルピリホス（ｃｈｌｏｒｐｙｒｉｆｏｓ）、クロルピリホス・メチル（ｃｈｌｏｒｐｙｒｉｆｏｓ－ｍｅｔｈｙｌ）、クロルフェナピル（ｃｈｌｏｒｆｅｎａｐｙｒ）、クロルフェンビンホス（ｃｈｌｏｒｆｅｎｖｉｎｐｈｏｓ）、クロルフルアズロン（ｃｈｌｏｒｆｌｕａｚｕｒｏｎ）、クロルメホス（ｃｈｌｏｒｍｅｐｈｏｓ）、クロロプラレスリン（ｃｈｌｏｒｏｐｒａｌｌｅｔｈｒｉｎ）、シアノホス（ｃｙａｎｏｐｈｏｓ）、ジアフェンチウロン（ｄｉａｆｅｎｔｈｉｕｒｏｎ）、ジアミダホス（ｄｉａｍｉｄａｆｏｓ）、シアントラニリプロール（ｃｙａｎｔｒａｎｉｌｉｐｒｏｌｅ）、ジエノクロル（ｄｉｅｎｏｃｈｌｏｒ）、シエノピラフェン（ｃｙｅｎｏｐｙｒａｆｅｎ）、ジオキサベンゾホス（ｄｉｏｘａｂｅｎｚｏｆｏｓ）、ジオフェノラン（ｄｉｏｆｅｎｏｌａｎ）、シクラニリプロール（ｃｙｃｌａｎｉｌｉｐｒｏｌｅ）、ジクロトホス（ｄｉｃｒｏｔｏｐｈｏｓ）、ジクロフェンチオン（ｄｉｃｈｌｏｆｅｎｔｈｉｏｎ）、シクロプロトリン（ｃｙｃｌｏｐｒｏｔｈｒｉｎ）、ジクロルボス（ｄｉｃｈｌｏｒｖｏｓ）、ジクロロメゾチアズ（ｄｉｃｌｏｒｏｍｅｚｏｔｉａｚ）、１，３‐ジクロロプロペン（１，３－ｄｉｃｈｌｏｒｏｐｒｏｐｅｎｅ）、ジコホル（ｄｉｃｏｆｏｌ）、ジシクラニル（ｄｉｃｙｃｌａｎｉｌ）、ジスルホトン（ｄｉｓｕｌｆｏｔｏｎ）、ジノテフラン（ｄｉｎｏｔｅｆｕｒａｎ）、ジノブトン（ｄｉｎｏｂｕｔｏｎ）、シハロジアミド（ｃｙｈａｌｏｄｉａｍｉｄｅ）、シハロトリン（ｃｙｈａｌｏｔｈｒｉｎ）［ｇａｍｍａ－体，ｌａｍｂｄａ－体を含む］、シフェノトリン（ｃｙｐｈｅｎｏｔｈｒｉｎ）［（１Ｒ）－ｔｒａｎｓ－体を含む］、シフルトリン（ｃｙｆｌｕｔｈｒｉｎ）［ｂｅｔａ－体を含む］、ジフルベンズロン（ｄｉｆｌｕｂｅｎｚｕｒｏｎ）、シフルメトフェン（ｃｙｆｌｕｍｅｔｏｆｅｎ）、ジフロビダジン（ｄｉｆｌｏｖｉｄａｚｉｎ）、シヘキサチン（ｃｙｈｅｘａｔｉｎ）、シペルメトリン（ｃｙｐｅｒｍｅｔｈｒｉｎ）［ａｌｐｈａ－体，ｂｅｔａ－体，ｔｈｅｔａ－体，ｚｅｔａ－体を含む］、ジメチルビンホス（ｄｉｍｅｔｈｙｌｖｉｎｐｈｏｓ）、ジメフルスリン（ｄｉｍｅｆｌｕｔｈｒｉｎ）、ジメトエート（ｄｉｍｅｔｈｏａｔｅ）、シラフルオフェン（ｓｉｌａｆｌｕｏｆｅｎ）、シロマジン（ｃｙｒｏｍａｚｉｎｅ）、スピネトラム（ｓｐｉｎｅｔｏｒａｍ）、スピノサド（ｓｐｉｎｏｓａｄ）、スピロジクロフェン（ｓｐｉｒｏｄｉｃｌｏｆｅｎ）、スピロテトラマト（ｓｐｉｒｏｔｅｔｒａｍａｔ）、スピロメシフェン（ｓｐｉｒｏｍｅｓｉｆｅｎ）、スルコフロン・ナトリウム塩（ｓｕｌｃｏｆｕｒｏｎ－ｓｏｄｉｕｍ）、スルフルラミド（ｓｕｌｆｌｕｒａｍｉｄ）、スルホキサフロル（ｓｕｌｆｏｘａｆｌｏｒ）、スルホテップ（ｓｕｌｆｏｔｅｐ）、ダイアジノン（ｄｉａｚｉｎｏｎ）、チアクロプリド（ｔｈｉａｃｌｏｐｒｉｄ）、チアメトキサム（ｔｈｉａｍｅｔｈｏｘａｍ）、チオキサザフェン（ｔｉｏｘａｚａｆｅｎ）、チオジカルブ（ｔｈｉｏｄｉｃａｒｂ）、チオシクラム（ｔｈｉｏｃｙｃｌａｍ）、チオスルタップ（ｔｈｉｏｓｕｌｔａｐ）、チオナジン（ｔｈｉｏｎａｚｉｎ）、チオファノックス（ｔｈｉｏｆａｎｏｘ）、チオメトン（ｔｈｉｏｍｅｔｏｎ）、テトラクロルビンホス（ｔｅｔｒａｃｈｌｏｒｖｉｎｐｈｏｓ）、テトラジホン（ｔｅｔｒａｄｉｆｏｎ）、テトラニリプロール（ｔｅｔｒａｎｉｌｉｐｒｏｌｅ）、テトラメチルフルスリン（ｔｅｔｒａｍｅｔｈｙｌｆｌｕｔｈｒｉｎ）、テトラメトリン（ｔｅｔｒａｍｅｔｈｒｉｎ）、テブピリムホス（ｔｅｂｕｐｉｒｉｍｆｏｓ）、テブフェノジド（ｔｅｂｕｆｅｎｏｚｉｄｅ）、テブフェンピラド（ｔｅｂｕｆｅｎｐｙｒａｄ）、テフルトリン（ｔｅｆｌｕｔｈｒｉｎ）、テフルベンズロン（ｔｅｆｌｕｂｅｎｚｕｒｏｎ）、デメトン・Ｓ・メチル（ｄｅｍｅｔｏｎ－Ｓ－ｍｅｔｈｙｌ）、テメホス（ｔｅｍｅｐｈｏｓ）、デルタメトリン（ｄｅｌｔａｍｅｔｈｒｉｎ）、テルブホス（ｔｅｒｂｕｆｏｓ）、トラロメトリン（ｔｒａｌｏｍｅｔｈｒｉｎ）、トランスフルトリン（ｔｒａｎｓｆｌｕｔｈｒｉｎ）、トリアザメート（ｔｒｉａｚａｍａｔｅ）、トリアゾホス（ｔｒｉａｚｏｐｈｏｓ）、トリクロルホン（ｔｒｉｃｈｌｏｒｆｏｎ）、トリフルムロン（ｔｒｉｆｌｕｍｕｒｏｎ）、トリフルメゾピリム（ｔｒｉｆｌｕｍｅｚｏｐｙｒｉｍ）、トリメタカルブ（ｔｒｉｍｅｔｈａｃａｒｂ）、トルフェンピラド（ｔｏｌｆｅｎｐｙｒａｄ）、ナレッド（ｎａｌｅｄ）、ニテンピラム（ｎｉｔｅｎｐｙｒａｍ）、ノバルロン（ｎｏｖａｌｕｒｏｎ）、ノビフルムロン（ｎｏｖｉｆｌｕｍｕｒｏｎ）、バーティシリウム　レカニ（Ｖｅｒｔｉｃｉｌｌｉｕｍ　ｌｅｃａｎｉｉ）、ハイドロプレン（ｈｙｄｒｏｐｒｅｎｅ）、パスツーリアペネトランス胞子（Ｐａｓｔｅｕｒｉａｐｅｎｅｔｒａｎｓ）、バミドチオン（ｖａｍｉｄｏｔｈｉｏｎ）、パラチオン（ｐａｒａｔｈｉｏｎ）、パラチオン・メチル（ｐａｒａｔｈｉｏｎ－ｍｅｔｈｙｌ）、ハルフェンプロックス（ｈａｌｆｅｎｐｒｏｘ）、ハロフェノジド（ｈａｌｏｆｅｎｏｚｉｄｅ）、ビオアレスリン（ｂｉｏａｌｌｅｔｈｒｉｎ）、ビオアレスリンＳ－シクロペンテニル（ｂｉｏａｌｌｅｔｈｒｉｎ　Ｓ－ｃｙｃｌｏｐｅｎｔｅｎｙｌ）、ビオレスメトリン（ｂｉｏｒｅｓｍｅｔｈｒｉｎ）、ビストリフルロン（ｂｉｓｔｒｉｆｌｕｒｏｎ）、ヒドラメチルノン（ｈｙｄｒａｍｅｔｈｙｌｎｏｎ）、ビフェナゼート（ｂｉｆｅｎａｚａｔｅ）、ビフェントリン（ｂｉｆｅｎｔｈｒｉｎ）、ピフルブミド（ｐｙｆｌｕｂｕｍｉｄｅ）、ピペロニルブトキシド（ｐｉｐｅｒｏｎｙｌ　ｂｕｔｏｘｉｄｅ）、ピメトロジン（ｐｙｍｅｔｒｏｚｉｎｅ）、ピラクロホス（ｐｙｒａｃｌｏｆｏｓ）、ピラフルプロール（ｐｙｒａｆｌｕｐｒｏｌｅ）、ピリダフェンチオン（ｐｙｒｉｄａｐｈｅｎｔｈｉｏｎ）、ピリダベン（ｐｙｒｉｄａｂｅｎ）、ピリダリル（ｐｙｒｉｄａｌｙｌ）、ピリフルキナゾン（ｐｙｒｉｆｌｕｑｕｉｎａｚｏｎ）、ピリプロール（ｐｙｒｉｐｒｏｌｅ）、ピリプロキシフェン（ｐｙｒｉｐｒｏｘｙｆｅｎ）、ピリミカルブ（ｐｉｒｉｍｉｃａｒｂ）、ピリミジフェン（ｐｙｒｉｍｉｄｉｆｅｎ）、ピリミノストロビン（ｐｙｒｉｍｉｎｏｓｔｒｏｂｉｎ）、ピリミホス・メチル（ｐｉｒｉｍｉｐｈｏｓ－ｍｅｔｈｙｌ）、ピレトリン（ｐｙｒｅｔｈｒｉｎｅ）、ファムフル（ｆａｍｐｈｕｒ）、フィプロニル（ｆｉｐｒｏｎｉｌ）、フェナザキン（ｆｅｎａｚａｑｕｉｎ）、フェナミホス（ｆｅｎａｍｉｐｈｏｓ）、フェニトロチオン（ｆｅｎｉｔｒｏｔｈｉｏｎ）、フェノキシカルブ（ｆｅｎｏｘｙｃａｒｂ）、フェノチオカルブ（ｆｅｎｏｔｈｉｏｃａｒｂ）、フェノトリン（ｐｈｅｎｏｔｈｒｉｎ）［（１Ｒ）－ｔｒａｎｓ－体を含む］、フェノブカルブ（ｆｅｎｏｂｕｃａｒｂ）、フェンチオン（ｆｅｎｔｈｉｏｎ）、フェントエート（ｐｈｅｎｔｈｏａｔｅ）、フェンバレレート（ｆｅｎｖａｌｅｒａｔｅ）、フェンピロキシメート（ｆｅｎｐｙｒｏｘｉｍａｔｅ）、フェンブタンチン・オキシド（ｆｅｎｂｕｔａｔｉｎ　ｏｘｉｄｅ）、フェンプロパトリン（ｆｅｎｐｒｏｐａｔｈｒｉｎ）、フォノホス（ｆｏｎｏｆｏｓ）、フッ化スルフリル（ｓｕｌｆｕｒｙｌ　ｆｌｕｏｒｉｄｅ）、ブトカルボキシム（ｂｕｔｏｃａｒｂｏｘｉｍ）、ブトキシカルボキシム（ｂｕｔｏｘｙｃａｒｂｏｘｉｍ）、ブプロフェジン（ｂｕｐｒｏｆｅｚｉｎ）、フラチオカルブ（ｆｕｒａｔｈｉｏｃａｒｂ）、プラレトリン（ｐｒａｌｌｅｔｈｒｉｎ）、フルアクリピリム（ｆｌｕａｃｒｙｐｙｒｉｍ）、フルアザインドリジン（ｆｌｕａｚａｉｎｄｏｌｉｚｉｎｅ）、フルアズロン（ｆｌｕａｚｕｒｏｎ）、フルエンスルホン（ｆｌｕｅｎｓｕｌｆｏｎｅ）、フルオロ酢酸ナトリウム塩（ｓｏｄｉｕｍ　ｆｌｕｏｒｏａｃｅｔａｔｅ）、フルキサメタミド（ｆｌｕｘａｍｅｔａｍｉｄｅ）、フルシクロクスロン（ｆｌｕｃｙｃｌｏｘｕｒｏｎ）、フルシトリネート（ｆｌｕｃｙｔｈｒｉｎａｔｅ）、フルスルファミド（ｆｌｕｓｕｌｆａｍｉｄｅ）、フルバリネート（ｆｌｕｖａｌｉｎａｔｅ）［ｔａｕ－体を含む］、フルピラジフロン（ｆｌｕｐｙｒａｄｉｆｕｒｏｎｅ）、フルピラゾホス（ｆｌｕｐｙｒａｚｏｆｏｓ）、フルピリミン（ｆｌｕｐｙｒｉｍｉｎ）、フルフィプロール（ｆｌｕｆｉｐｒｏｌｅ）、フルフェネリム（ｆｌｕｆｅｎｅｒｉｍ）
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Acrinathrin (acrinathrin), azadirachtin (azadirachtin), azamethiphos (azamethiphos), azinphos-ethyl (azinphos-ethyl), azinphos-methyl (azinphos-methyl), acequinocyl (acequinocyl), acetamiprid (acetamiprid), acetoprole (acetoprole), acephate (Acephate), azocyclotin, abamectin, afidopyropene, afoxolener, amidoflumet alamicarb, alamicarb, alnicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb, alanicarb. (Aldoxycarb), allethrin (allethrin) [d-cis-trans- body, including d-trans- body, isazofos (isazophos), Isamidohosu (Isamidofos), Isokarubohosu (Isocarbophos), isoxathion (isoxathion), isofenphos-methyl ( isofenphos-methyl), isoprocarb (isoprocarb), ivermectin (imvercin), imicyafos (imidaclopriate), imidacloprien phencarbene, imiprothrin phencarbine, indoxacarb (indoxacarb), imiprothrin phenate (indicacarb), imiprothrin phenate, indoxacarb (indoxacarb), indoxacarb. (Ethion), ethiprole, ethylene dibromide, etoxazole, etofenprox, etofrosinate, ethomophosate, etrimofenate, and ethromphosate. , Empentrin, oxazosulfyl, oxamyl, oxydimethon-methyl, oxydeprophos. s), omethoate, kazusafos, kappa-tefluthrin, kappa-bifenthrin, caranjin, cartanju, carutarp, carlcap, carutarp, cartarp, carutarp, cartarp, carthac carbosulfan), carbofuran (carbofuran), gamma -BHC (gamma-BHC), xylylcarb (xylylcarb), quinalphos (quinalphos), kinoprene (kinoprene), Kinomechioneto (chinomethionat), Coumaphos (coumaphos), cryolite (cryolite), clothianidin ( Clothianidin, clofentezine, chromafenozide, chlorantraniliprole, chlorethorphosphyl, chlorethrophyl, chlorophyrochlor, chlorophyrochlor, chlorophyrochlor, chlorophyrochlor, chlorophyrochlor, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorphenoxyl, chlorophenoxy, chlorphenoxyl, chlorophenoxy, chlorphenoxyl Chlorpyrifos-methyl), chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormelufos chlorophyllophyllophosphine, chlorophyrophleur (chlorophyro), chloropralesulin (chlorophyrin), chloropralesulin (chlorophyrin), chloropralesulin (chlorophyrin), chloropralesulin (chlorophyrin), chloropralesulin (chlorophyrin), chloropraresulin (chlorophyran), chloropralesulin (chlorophyrin). , Diamidafos, cyantraniliprole, dienochlor, cienopyrafen, dioxabenzolylo, diocabionol, diofabranzio, diofabanen, diofabranzio, diofenalan, diofabranzio Diclofenthion, cycloprothrin, dichlorvos, dichloromezotiaz, 1,3-dichloropropene (1, 3-dichloropropene, dicofol, dicyclanil, disulfoton, dinotefuran, dinobuton, dinaboluta, cyhalodiamide, cyhalodiamide, cyhalodiamide, cyhalodiamide, cyhalodiamide, cyhalodiamide, cyhalodiamide. , Cyphenothrin [including (1R)-trans-form], cyfluthrin (including beta-form), diflubenzuron, cyflumethofin (cyflumethofen), hexafluvincid, diflobidine (di), difrovido (di), difrovidazine (di), difrovidin (di), difrovido (dif) Cypermethrin [including alpha-form, beta-form, theta-form, zeta-form], dimethylvinphos, dimefluthrin, dimethoate, siraflurofen (silafluofen) ), spinetoram, spinosad, spirodiclofen, spirotetramat, spiromesifen, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulcofuron-sulfuramid, sulfoxaflor), sulfotep (sulfotep), diazinon (diazinon), thiacloprid (thiacloprid), thiamethoxam (thiamethoxam), Chiokisazafen (tioxazafen), thiodicarb (thiodicarb), thiocyclam (thiocyclam), thiosultap (thiosultap), Chionajin (thionazin), Chiofa Thiofanox, thiomethon, tetrachlorvinphos, tetradiphone, tetraniliprole, tetramethylfluthrin, tetrameth Tetramethrin, tebupirimfos, tebufenozide, tebufenmethrin, tefluthrin, tefluthrin, tefluphenmethrin, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron, teflubenzuron , Terbufos, tralomethrin, transfluthrin, triazamate, triazophos, trichlormethone, trichlorfron, triflourm (triflourm), triflumuron (triflouron) Tolfenpyrad, naled, nitenpyram, novaluron, noviflumuron, verticillium recani, verticillium transcane, hydroprene nepus, hydroprene, hydroprene Vamidothion, parathion, parathion-methyl, halfenprox, halofenozide, bioallethrin-cylocylcylcyl-cyclosyl-, bioallethrin-cyclosalt, bioallethrin-cyclosalt, bioallethrin-cycloallethin, para-thione, parathion-parathion, parathion-methyl, parathion-methyl, parathion-methyl, halfenprox, halofenozide, bioallethrin-cylocylcylcyl, cyclosalt, bioallethrin, bioallethrin. Bioresmethrin, bistrifluron, hydramethylnon, bifenazyr, bifenthropine, phenflubinepyl, phenflubinepyl, pyflubupilep, phenflubinepyl, phenflubupyrup, phenflubupyrup, phenflubupyrup, phenflubupyrup, phenflubupyrup, phenflubupyrup, phenflubupyrup, phenflubupyrup, pyflubupyrup, phenflubupyrup, pyflubupyrup, phenflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupyrup, pyflubupride, pyflubupyrup; Pyrafluprole, Pyridaphenthion, Pyrida Ben (pyridaben), pyridalyl (pyridalyl), pyrifluquinazone (pyrifluquinazon), pyriprole (pyriprole), pyriproxyphen (pyriproxyphens), pyrimidinupin (pyrimirin), pyrimidinofin (pyrimirim), pyrimidifin (pyrimirif) -Methyl), pyrethrin, famfur, fipronil, fenazaquin, fenamiphos, fenitrothion, phenoxythion, phenoxycarbo, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb, phenoxycarb. (Including (1R)-trans-form], phenocarb, fenthion, fenthoate, fenvalerate, fenpyroximate, fenbutanthin phenoxide, fenbutatin phenoxide. (Fenpropathrin), phonofos, sulfuryl fluoride, butocarboxim, butoxycarboxyl fulpurin, buprofezurin, buprofezin, buprofezin, buprofezin, buprofezin, buprofezin, buprofezin, buprofezin, buprofezin, buprofezin, and buprofezin. , Fluazaindolidine, fluazuron, fluensulfone, sodium fluoroacetic acid salt, fluxamethamide fluxurathyl, flucyclofuron flucyl flucylflux, flucuronyl flucylflux, flucylfluxyl, flucuronyl, flucyclonyl flucuron, (Flusulfamide), fluvalinate [including tau-form], flupyrazifurone, flupyrazoz ofos), flupyrimin, flufiprole, flufenerim
, Flufenoxystrobin, flufenoxuron, fluhexafon, flubendiamide, flumethrin, protriphenoprophoprotoprophenobutre, Protophenbute, flonicamid, propaphos, propargite, profenofos, brofuranipurofurompuprophropromuroprom, profurothine, proflutopurofloprom, profurothine, proflunopurofloprom, profurothine, proflutopurofloprom, profurothine, proflunopurofloprom, profurothine, proflunopurofloprom, profurothine, profurothine; bromopropylate (bromopropylate), Hekisachiazokusu (hexythiazox), hexaflumuron (hexaflumuron), Pekiromaisesu tenuipes (Paecilomyces tenuipes), Pekiromaisesu-Fumosoroseusu (Paecilomyces fumosoroceus), hepta full Surin (heptafluthrin), heptenophos (heptenophos), permethrin (permethrin ), benclothiaz, bensultap, benzioximate, bendiocarb, benfuracarbia bouria benaria, beauveriana beria, beauveria berea, beneria bena, beauveria berea, beneria berneria, beauveria berea, beneria berea, beneria berneria, beauveria berea, beneria beneria, benveria bernaria, benveria, benberia, benner (Beauveria brongniartii), phoxim (phoxim), phosalone (phosalone), fosthiazate (fosthiazate), fosthietan (fosthietan), phosphamidon (phosphamidon), phosmet (phosmet), polynactin complex (polynactins), formetanate (formetanate), phorate (phorate ), malathion, milbemectin, mecarbam am), mesulfenfos, mesoprene, methomyl, metaflumizone, methamidophothiate methyl methionate (meth), methithiothiathiol methylate (meth), methithiothiamethionate (meth) methion, methithiothiamethionate (meth), methithiothiamethionate (meth), methothi methionate (meth), methion (meth), methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, methion, and methion. , Methyl bromide, methoxychlor, methoxyphenozide, methothrin, methofluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methfluthrin, methoflutin ), Monacrosporium phymatopagum, monocrotophos, momflurothrin, epsilon-momluluAli (little), and epsilon-momluluAli (little). ), aluminum phosphide, zinc phosphide, zinc phosphine, phosphine, lufenuron, rescarure, resmethrin, lepimectin, lepimectin, lepimentron, lepimentrin, lepimentrin, Fenbutatin oxide, calcium cyanide, nicotine sulfate, (Z)-11-tetradecenyl acetate, (Z)-11-hexadecenal, (Z)-11-hexadecenyl acetate, (Z) )-9,12-Tetradecadienyl acetate, (Z)-9-tetradecen-1-ol, (Z,E)-9,11-tetradecadienyl acetate, (Z,E)-9, 12-tetradecadienyl acetate, Bacillus popillia, Bacillus subtilis (Bacillus subtillis), Bacillus sphaericus, Bacillus thuringiensis subspecies, Aizawai (Bacillus thuringiensis subsp. Aizawai), Bacillus thuringiensis subsp. Israelensis, Bacillus thuringiensis subsp. Kuraschi (Bacillus thuringiensis subillus subsil. thuringiensis subsp. Tenebrionis), Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL90017IP (bis-ethyl), CL90017IP (bis-methyl), CL90017IP (methyl-number), , DDT (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethylphosphonate), DNOC (4,6-dinitro) -O-cresol), DSP(O,O-diethyl-O-[4-(dimethylsulfamoyl)phenyl]-phosphorothionate), EPN(O-ethyl-O-4-(nitrophenyl)phenylphospho) Nothioate), nuclear polyhedrosis virus embedding medium, NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 (code number), XMC, Z-13-icosene -10-one, ZXI8901 (code number), (RS)-2-chloro-4-fluoro-5-[5-(trifluoromethylthio)pentyloxy]phenyl 2,2,2-trifluoroethyl sulfoxide (chemical name , CAS registration number: 1472050-04-6).
［殺菌活性成分］
　アザコナゾール（ａｚａｃｏｎａｚｏｌｅ）、アシベンゾラル・Ｓ・メチル（ａｃｉｂｅｎｚｏｌａｒ－Ｓ－ｍｅｔｈｙｌ）、アゾキシストロビン（ａｚｏｘｙｓｔｒｏｂｉｎ）、アニラジン（ａｎｉｌａｚｉｎｅ）、アミスルブロム（ａｍｉｓｕｌｂｒｏｍ）、アメトクトラジン（ａｍｅｔｏｃｔｒａｄｉｎ）、アルジモルフ（ａｌｄｉｍｏｒｐｈ）、イソチアニル（ｉｓｏｔｉａｎｉｌ）、イソピラザム（ｉｓｏｐｙｒａｚａｍ）、イソフェタミド（ｉｓｏｆｅｔａｍｉｄ）、イソプロチオラン（ｉｓｏｐｒｏｔｈｉｏｌａｎｅ）、イプコナゾール（ｉｐｃｏｎａｚｏｌｅ）、イプフェントリフルコナゾール（ｉｐｆｅｎｔｒｉｆｌｕｃｏｎａｚｏｌｅ）、 イプロジオン（ｉｐｒｏｄｉｏｎｅ）、イプロバリカルブ（ｉｐｒｏｖａｌｉｃａｒｂ）、イプロベンホス（ｉｐｒｏｂｅｎｆｏｓ）、イマザリル（ｉｍａｚａｌｉｌ）、イミノクタジン・アルベシル酸塩（ｉｍｉｎｏｃｔａｄｉｎｅ－ｔｒｉａｌｂｅｓｉｌａｔｅ）、イミノクタジン酢酸塩（ｉｍｉｎｏｃｔａｄｉｎｅ－ｔｒｉａｃｅｔａｔｅ）、イミベンコナゾール（ｉｍｉｂｅｎｃｏｎａｚｏｌｅ）、エジフェンホス（ｅｄｉｆｅｎｐｈｏｓ）、エタコナゾ－ル（ｅｔａｃｏｎａｚｏｌｅ）、エタボキサム（ｅｔｈａｂｏｘａｍ）、エチリモル（ｅｔｈｉｒｉｍｏｌ）、エトキシキン（ｅｔｈｏｘｙｑｕｉｎ）、エトリジアゾール（ｅｔｒｉｄｉａｚｏｌｅ）、エネストロブリン（ｅｎｅｓｔｒｏｂｕｒｉｎ）、エノキサストロビン（ｅｎｏｘａｓｔｒｏｂｉｎ）、エポキシコナゾール（ｅｐｏｘｉｃｏｎａｚｏｌｅ）、オーガニックオイル（ｏｒｇａｎｉｃ　ｏｉｌｓ）、オキサジキシル（ｏｘａｄｉｘｙｌ）、オキサジニラゾール（ｏｘａｚｉｎｙｌａｚｏｌｅ）、オキサチアピプロリン（ｏｘａｔｈｉａｐｉｐｒｏｌｉｎ）、オキシカルボキシン（ｏｘｙｃａｒｂｏｘｉｎ）、オキシキノリン銅（ｏｘｉｎｅ－ｃｏｐｐｅｒ）、オキシテトラサイクリン（ｏｘｙｔｅｔｒａｃｙｃｌｉｎｅ）、オキスポコナゾールフマル酸塩（ｏｘｐｏｃｏｎａｚｏｌｅ－ｆｕｍａｒａｔｅ）、オキソリニック酸（ｏｘｏｌｉｎｉｃ　ａｃｉｄ）、オクタン酸銅（ｃｏｐｐｅｒ　ｄｉｏｃｔａｎｏａｔｅ）、オクチリノン（ｏｃｔｈｉｌｉｎｏｎｅ）、オフラセ（ｏｆｕｒａｃｅ）、オリサストロビン（ｏｒｙｓａｓｔｒｏｂｉｎ）、オルソフェニルフェノール（ｏ－ｐｈｅｎｙｌｐｈｅｎｏｌ）、カスガマイシン（ｋａｓｕｇａｍｙｃｉｎ）、カプタホール（ｃａｐｔａｆｏｌ）、カルプロパミド（ｃａｒｐｒｏｐａｍｉｄ）、カルベンダジム（ｃａｒｂｅｎｄａｚｉｍ）、カルボキシン（ｃａｒｂｏｘｉｎ）、カルボネ（ｃａｒｖｏｎｅ）、キノキシフェン（ｑｕｉｎｏｘｙｆｅｎ）、キノフメリン（ｑｕｉｎｏｆｕｍｅｌｉｎ）、 キノメチオネート（ｃｈｉｎｏｍｅｔｈｉｏｎａｔ）、キャプタン（ｃａｐｔａｎ）、キンコナゾール（ｑｕｉｎｃｏｎａｚｏｌｅ）、キントゼン（ｑｕｉｎｔｏｚｅｎｅ）、グアザチン（ｇｕａｚａｔｉｎｅ）、クフラネブ（ｃｕｆｒａｎｅｂ）、クモキシストロビン（ｃｏｕｍｏｘｙｓｔｒｏｂｉｎ）、クレソキシム・メチル（ｋｒｅｓｏｘｉｍ－ｍｅｔｈｙｌ）、クロジラコン（ｃｌｏｚｙｌａｃｏｎ）、クロゾリネート（ｃｈｌｏｚｏｌｉｎａｔｅ）、クロロタロニル（ｃｈｌｏｒｏｔｈａｌｏｎｉｌ）、クロロネブ（ｃｈｌｏｒｏｎｅｂ）、シアゾファミド（ｃｙａｚｏｆａｍｉｄ）、ジエトフェンカルブ（ｄｉｅｔｈｏｆｅｎｃａｒｂ）、ジクロシメット（ｄｉｃｌｏｃｙｍｅｔ）、ジクロフルアニド（ｄｉｃｈｌｏｆｌｕａｎｉｄ）、ジクロベンチアゾクス（ｄｉｃｈｌｏｂｅｎｔｈｉａｚｏｘ）、ジクロメジン（ｄｉｃｌｏｍｅｚｉｎｅ）、ジクロラン（ｄｉｃｌｏｒａｎ）、ジクロロフェン（ｄｉｃｈｌｏｒｏｐｈｅｎ）、ジチアノン（ｄｉｔｈｉａｎｏｎ）、ジニコナゾール（ｄｉｎｉｃｏｎａｚｏｌｅ）、ジニコナゾール・Ｍ（ｄｉｎｉｃｏｎａｚｏｌｅ－Ｍ）、ジネブ（ｚｉｎｅｂ）、ジノカップ（ｄｉｎｏｃａｐ）、ジピメチトロン（ｄｉｐｙｍｅｔｉｔｒｏｎｅ）、ジフェニルアミン（ｄｉｐｈｅｎｙｌａｍｉｎｅ）、ジフェノコナゾール（ｄｉｆｅｎｏｃｏｎａｚｏｌｅ）、シフルフェナミド（ｃｙｆｌｕｆｅｎａｍｉｄ）、ジフルメトリム（ｄｉｆｌｕｍｅｔｏｒｉｍ）、シプロコナゾール（ｃｙｐｒｏｃｏｎａｚｏｌｅ）、シプロジニル（ｃｙｐｒｏｄｉｎｉｌ）、シメコナゾール（ｓｉｍｅｃｏｎａｚｏｌｅ）、ジメチリモル（ｄｉｍｅｔｈｉｒｉｍｏｌ）、ジメチルジスルフィド（ｄｉｍｅｔｈｙｌ　ｄｉｓｕｌｆｉｄｅ）、ジメトモルフ（ｄｉｍｅｔｈｏｍｏｒｐｈ）、シモキサニル（ｃｙｍｏｘａｎｉｌ）、ジモキシストロビン（ｄｉｍｏｘｙｓｔｒｏｂｉｎ）、ジラム（ｚｉｒａｍ）、シルチオファム（ｓｉｌｔｈｉｏｆａｍ）、ストレプトマイシン（ｓｔｒｅｐｔｏｍｙｃｉｎ）、スピロキサミン（ｓｐｉｒｏｘａｍｉｎｅ）、セダキサン（ｓｅｄａｘａｎｅ）、ゾキサミド（ｚｏｘａｍｉｄｅ）、ダゾメット（ｄａｚｏｍｅｔ）、チアジニル（ｔｉａｄｉｎｉｌ）、チアベンダゾール（ｔｈｉａｂｅｎｄａｚｏｌｅ）、チウラム（ｔｈｉｒａｍ）、チオファネート（ｔｈｉｏｐｈａｎａｔｅ）、チオファネート・メチル（ｔｈｉｏｐｈａｎａｔｅ－ｍｅｔｈｙｌ）、チフルザミド（ｔｈｉｆｌｕｚａｍｉｄｅ）、テクナゼン（ｔｅｃｎａｚｅｎｅ）、テクロフタラム（ｔｅｃｌｏｆｔａｌａｍ）、テトラコナゾール（ｔｅｔｒａｃｏｎａｚｏｌｅ）、デバカルブ（ｄｅｂａｃａｒｂ）、テブコナゾール（ｔｅｂｕｃｏｎａｚｏｌｅ）、テブフロキン（ｔｅｂｕｆｌｏｑｕｉｎ）、テルビナフィン（ｔｅｒｂｉｎａｆｉｎｅ）、ドジン（ｄｏｄｉｎｅ）、ドデモルフ（ｄｏｄｅｍｏｒｐｈ）、トリアジメノール（ｔｒｉａｄｉｍｅｎｏｌ）、トリアジメホン（ｔｒｉａｄｉｍｅｆｏｎ）、トリアゾキシド（ｔｒｉａｚｏｘｉｄｅ）、トリクラミド（ｔｒｉｃｈｌａｍｉｄｅ）、トリクロピリカルブ（ｔｒｉｃｌｏｐｙｒｉｃａｒｂ）、トリシクラゾール（ｔｒｉｃｙｃｌａｚｏｌｅ）、トリチコナゾール（ｔｒｉｔｉｃｏｎａｚｏｌｅ）、トリデモルフ（ｔｒｉｄｅｍｏｒｐｈ）、トリフルミゾール（ｔｒｉｆｌｕｍｉｚｏｌｅ）、トリフロキシストロビン（ｔｒｉｆｌｏｘｙｓｔｒｏｂｉｎ）、トリホリン（ｔｒｉｆｏｒｉｎｅ）、トリルフルアニド（ｔｏｌｙｌｆｌｕａｎｉｄ）、トルクロホス・メチル（ｔｏｌｃｌｏｆｏｓ－ｍｅｔｈｙｌ）、トルニファニド（ｔｏｌｎｉｆａｎｉｄｅ）、トルプロカルブ（ｔｏｌｐｒｏｃａｒｂ）、ナーバム（ｎａｂａｍ）、ナタマイシン（ｎａｔａｍｙｃｉｎ）、ナフティフィン（ｎａｆｔｉｆｉｎｅ）、ニトラピリン（ｎｉｔｒａｐｙｒｉｎ）、ニトロタル・イソプロピル（ｎｉｔｒｏｔｈａｌ－ｉｓｏｐｒｏｐｙｌ）、ヌアリモル（ｎｕａｒｉｍｏｌ）、ノニルフェノールスルホン酸銅（ｃｏｐｐｅｒ　ｎｏｎｙｌ　ｐｈｅｎｏｌ　ｓｕｌｐｈｏｎａｔｅ）、バチルス・ズブチリス（Ｂａｃｉｌｌｕｓ　ｓｕｂｔｉｌｉｓ）（ｓｔｒａｉｎ：ＱＳＴ　７１３）、バリダマイシン（ｖａｌｉｄａｍｙｃｉｎ）、バリフェナレート（ｖａｌｉｆｅｎａｌａｔｅ）、ピカルブトラゾックス（ｐｉｃａｒｂｕｔｒａｚｏｘ）、ビキサフェン（ｂｉｘａｆｅｎ）、ピコキシストロビン（ｐｉｃｏｘｙｓｔｒｏｂｉｎ）、ピジフルメトフェン（ｐｙｄｉｆｌｕｍｅｔｏｆｅｎ）、ビテルタノール（ｂｉｔｅｒｔａｎｏｌ）、ビナパクリル（ｂｉｎａｐａｃｒｙｌ）、ビフェニル（ｂｉｐｈｅｎｙｌ）、ピペラリン（ｐｉｐｅｒａｌｉｎ）、ヒメキサゾール（ｈｙｍｅｘａｚｏｌ）、ピラオキシストロビン（ｐｙｒａｏｘｙｓｔｒｏｂｉｎ）、ピラクロストロビン（ｐｙｒａｃｌｏｓｔｒｏｂｉｎ）、ピラジフルミド（ｐｙｒａｚｉｆｌｕｍｉｄ）、ピラゾホス（ｐｙｒａｚｏｐｈｏｓ）、ピラメトストロビン（ｐｙｒａｍｅｔｏｓｔｒｏｂｉｎ）、ピリオフェノン（ｐｙｒｉｏｆｅｎｏｎｅ）、ピリソキサゾール（ｐｙｒｉｓｏｘａｚｏｌｅ）、ピリフェノックス（ｐｙｒｉｆｅｎｏｘ）、ピリブチカルブ（ｐｙｒｉｂｕｔｉｃａｒｂ）、ピリベンカルブ（ｐｙｒｉｂｅｎｃａｒｂ）、ピリメタニル（ｐｙｒｉｍｅｔｈａｎｉｌ）、ピロキロン（ｐｙｒｏｑｕｉｌｏｎ）、ビンクロゾリン（ｖｉｎｃｌｏｚｏｌｉｎ）、ファーバム（ｆｅｒｂａｍ）、ファモキサドン（ｆａｍｏｘａｄｏｎｅ）、フェナジンオキシド（ｐｈｅｎａｚｉｎｅ　ｏｘｉｄｅ）、フェナミドン（ｆｅｎａｍｉｄｏｎｅ）、フェナミンストロビン（ｆｅｎａｍｉｎｓｔｒｏｂｉｎ）、フェナリモル（ｆｅｎａｒｉｍｏｌ）、フェノキサニル（ｆｅｎｏｘａｎｉｌ）、フェリムゾン（ｆｅｒｉｍｚｏｎｅ）、フェンピクロニル（ｆｅｎｐｉｃｌｏｎｉｌ）、フェンピコキサミド（ｆｅｎｐｉｃｏｘａｍｉｄ）、 フェンピラザミン（ｆｅｎｐｙｒａｚａｍｉｎｅ）、フェンブコナゾール（ｆｅｎｂｕｃｏｎａｚｏｌｅ）、フェンフラム（ｆｅｎｆｕｒａｍ）、フェンプロピジン（ｆｅｎｐｒｏｐｉｄｉｎ）、フェンプロピモルフ（ｆｅｎｐｒｏｐｉｍｏｒｐｈ）、フェンヘキサミド（ｆｅｎｈｅｘａｍｉｄ）、フォルペット（ｆｏｌｐｅｔ）、フサライド（ｐｈｔｈａｌｉｄｅ）、ブピリメート（ｂｕｐｉｒｉｍａｔｅ）、フベリダゾール（ｆｕｂｅｒｉｄａｚｏｌｅ）、ブラストサイジン－Ｓ（ｂｌａｓｔｉｃｉｄｉｎ－Ｓ）、フラメトピル（ｆｕｒａｍｅｔｐｙｒ）、フララキシル（ｆｕｒａｌａｘｙｌ）、フランカルボン酸（ｆｕｒａｎｃａｒｂｏｘｙｌｉｃ　ａｃｉｄ）、フルアジナム（ｆｌｕａｚｉｎａｍ）、フルインダピル（ｆｌｕｉｎｄａｐｙｒ）、フルオキサストロビン（ｆｌｕｏｘａｓｔｒｏｂｉｎ）、フルオピコリド（ｆｌｕｏｐｉｃｏｌｉｄｅ）、フルオピラム（ｆｌｕｏｐｙｒａｍ）、フルオルイミド（ｆｌｕｏｒｏｉｍｉｄｅ）、フルキサピロキサド（ｆｌｕｘａｐｙｒｏｘａｄ）、フルキンコナゾール（ｆｌｕｑｕｉｎｃｏｎａｚｏｌｅ）、フルコナゾール（ｆｕｒｃｏｎａｚｏｌｅ）、フルコナゾール・シス（ｆｕｒｃｏｎａｚｏｌｅ－ｃｉｓ）、フルジオキソニル（ｆｌｕｄｉｏｘｏｎｉｌ）、フルシラゾール（ｆｌｕｓｉｌａｚｏｌｅ）、フルスルファミド（ｆｌｕｓｕｌｆａｍｉｄｅ）、フルチアニル（ｆｌｕｔｉａｎｉｌ）、フルトラニル（ｆｌｕｔｏｌａｎｉｌ）、フルトリアホール（ｆｌｕｔｒｉａｆｏｌ）、フルフェノキシストロビン（ｆｌｕｆｅｎｏｘｙｓｔｒｏｂｉｎ）、フルメトベル（ｆｌｕｍｅｔｏｖｅｒ）、フルモルフ（ｆｌｕｍｏｒｐｈ）、プロキナジド（ｐｒｏｑｕｉｎａｚｉｄ）、プロクロラズ（ｐｒｏｃｈｌｏｒａｚ）、プロシミドン（ｐｒｏｃｙｍｉｄｏｎｅ）、プロチオカルブ（ｐｒｏｔｈｉｏｃａｒｂ）、プロチオコナゾール（ｐｒｏｔｈｉｏｃｏｎａｚｏｌｅ）、ブロノポール（ｂｒｏｎｏｐｏｌ）、プロパモカルブ塩酸塩（ｐｒｏｐａｍｏｃａｒｂ－ｈｙｄｒｏｃｈｌｏｒｉｄｅ）、プロピコナゾール（ｐｒｏｐｉｃｏｎａｚｏｌｅ）、プロピネブ（ｐｒｏｐｉｎｅｂ）、プロベナゾール（ｐｒｏｂｅｎａｚｏｌｅ）、ブロムコナゾール（ｂｒｏｍｕｃｏｎａｚｏｌｅ）、フロメトキン（ｆｌｏｍｅｔｏｑｕｉｎ）、ヘキサコナゾール（ｈｅｘａｃｏｎａｚｏｌｅ）、ベナラキシル（ｂｅｎａｌａｘｙｌ）、ベナラキシル・Ｍ（ｂｅｎａｌａｘｙｌ－Ｍ）、ベノダニル（ｂｅｎｏｄａｎｉｌ）、ベノミル（ｂｅｎｏｍｙｌ）、ペフラゾエート（ｐｅｆｕｒａｚｏａｔｅ）、ペンコナゾール（ｐｅｎｃｏｎａｚｏｌｅ）、ペンシクロン（ｐｅｎｃｙｃｕｒｏｎ）、ベンゾビンジフルピル（ｂｅｎｚｏｖｉｎｄｉｆｌｕｐｙｒ）、ベンチアゾール（ｂｅｎｔｈｉａｚｏｌｅ）、ベンチアバリカルブイソプロピル（ｂｅｎｔｈｉａｖａｌｉｃａｒｂ－ｉｓｏｐｒｏｐｙｌ）、ペンチオピラド（ｐｅｎｔｈｉｏｐｙｒａｄ）、ペンフルフェン（ｐｅｎｆｌｕｆｅｎ）、ボスカリド（ｂｏｓｃａｌｉｄ）、ホセチル（ｆｏｓｅｔｙｌ）（ａｌｍｉｎｉｕｍ，　ｃａｌｃｉｕｍ，　ｓｏｄｉｕｍ）、ポリオキシン（ｐｏｌｙｏｘｉｎ）、ポリカーバメート（ｐｏｌｙｃａｒｂａｍａｔｅ）、ボルドー液（Ｂｏｒｄｅａｕｘ　ｍｉｘｔｕｒｅ）、
マンコゼブ（ｍａｎｃｏｚｅｂ）、マンジプロパミド（ｍａｎｄｉｐｒｏｐａｍｉｄ）、マンデストロビン（ｍａｎｄｅｓｔｒｏｂｉｎ）、マンネブ（ｍａｎｅｂ）、ミクロブタニル（ｍｙｃｌｏｂｕｔａｎｉｌ）、ミネラルオイル（ｍｉｎｅｒａｌ　ｏｉｌｓ）、ミルディオマイシン（ｍｉｌｄｉｏｍｙｃｉｎ）、メタスルホカルブ（ｍｅｔｈａｓｕｌｆｏｃａｒｂ）、メタム（ｍｅｔａｍ）、メタラキシル（ｍｅｔａｌａｘｙｌ）、メタラキシル・Ｍ（ｍｅｔａｌａｘｙｌ－Ｍ）、メチラム（ｍｅｔｉｒａｍ）、メトコナゾール（ｍｅｔｃｏｎａｚｏｌｅ）、メトミノストロビン（ｍｅｔｏｍｉｎｏｓｔｒｏｂｉｎ）、メトラフェノン（ｍｅｔｒａｆｅｎｏｎｅ）、メパニピリム（ｍｅｐａｎｉｐｙｒｉｍ）、メフェントリフルコナゾール（ｍｅｆｅｎｔｒｉｆｌｕｃｏｎａｚｏｌｅ）、 メプチルジノカップ（ｍｅｐｔｙｌｄｉｎｏｃａｐ）、メプロニル（ｍｅｐｒｏｎｉｌ）、ヨードカルブ（ｉｏｄｏｃａｒｂ）、ラミナリン（ｌａｍｉｎａｒｉｎ）、亜リン酸および塩（ｐｈｏｓｐｈｏｒｏｕｓ　ａｃｉｄ　ａｎｄ　ｓａｌｔｓ）、塩基性塩化銅（ｃｏｐｐｅｒ　ｏｘｙｃｈｌｏｒｉｄｅ）、銀（ｓｉｌｖｅｒ）、酸化第一銅（ｃｕｐｒｏｕｓ　ｏｘｉｄｅ）、水酸化第二銅（ｃｏｐｐｅｒ　ｈｙｄｒｏｘｉｄｅ）、炭酸水素カリウム（ｐｏｔａｓｓｉｕｍ　ｂｉｃａｒｂｏｎａｔｅ）、炭酸水素ナトリウム（ｓｏｄｉｕｍ　ｂｉｃａｒｂｏｎａｔｅ）、硫黄（ｓｕｌｆｕｒ）、硫酸オキシキノリン（ｏｘｙｑｕｉｎｏｌｉｎｅ　ｓｕｌｆａｔｅ）、硫酸銅（ｃｏｐｐｅｒ　ｓｕｌｆａｔｅ）、（３，４－ジクロロイソチアゾール－５－イル）メチル　４－（ｔｅｒｔ－ブチル）安息香酸エステル（化学名、ＣＡＳ登録番号：１２３１２１４－２３－５）、ＢＡＦ－０４５（コード番号）、ＢＡＧ－０１０（コード番号）、ＵＫ－２Ａ(コード番号)、ＤＢＥＤＣ（ドデシルベンゼンスルホン酸ビスエチレンジアミン銅錯塩［ＩＩ］）、ＭＩＦ－１００２（コード番号）、ＴＰＴＡ（酢酸トリフェニルスズ）、ＴＰＴＣ（トリフェニルチンクロライド）、ＴＰＴＨ（水酸化トリフェニルスズ）、非病原性エルビニア・カロトボーラ。 [Bactericidal active ingredient]
Azaconazole, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbromylanistilisomorphyl, amethoctrazine, amethoctiradin, amethodecyl, and amethoctrazine. , Isopyrazam, isofetamide, isoprothiolane, ipconazole, ipufentrifluconic (ipf), isofetrazole, isofetrazole, isofetramide, isofetamide, isofetamide, isofetamide, isofetamide, isofetamide -Albesylate salt (imoctadine-trialbesilate), iminoctadine-triacetate, imibenconazole, edifenphosmoethriathioxy, ethenexaethoxy, ethenethox, ethenexanthine, ethenax, ethenexanthium, ethenexanthine, ethenexanthine, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethene, ethical, ethene, ethical, ethoxyquin, etridiazole, enestrobrin, enoxastrobin, epoxiconazole, organic oils, oxazylyl, oxazylyl, oxazylyl Thiapiproline, oxycarboxin, oxyquinoline copper, oxytetracycline, oxpoconazole octanoic acid, oxpoconazole oxo-fumarate. Copper dioctanoate, octilinone, ofurace, orysastrobin, orthophenylphenol (o) -Phenylphenol), kasugamycin, captafol, carpropamide, carbendazinate, quinoquinoquinoquinoquinoquinophen, carbonine, carboxine, quinoxyphen, quinoxyphen, quinoxyphen, quinoxyphen, quinoxyphen, quinoxyphen, quinoxyphene , captan (captan), Kinkonazoru (quinconazole), quintozene (quintozene), guazatine (guazatine), Kufuranebu (cufraneb), spider azoxystrobin (coumoxystrobin), kresoxim-methyl (kresoxim-methyl), Kurojirakon (clozylacon), chlozolinate (Chlorozolonate), chlorothalonil, chloroneb, chloroneb, cyazofamide, dietofencarb, diclosimethine diclozilox, diclozilozilozilozilozilozilozilo, dichlodiclodi, dichlodichloro, dichlorodichloro, chlorothalonil. (Dicloran), dichlorophen, dithianon, diniconazole, diniconazole-M, zineb, zineph, dinocapine, dipinodiamine, dipinemethine, dipinemethine, dipinemethine, dipinemethine. (difenoconazole), cyflufenamid (cyflufenamid), diflumetorim (diflumetorim), cyproconazole (cyproconazole), cyprodinil (cyprodinil), simeconazole (simeconazole), Jimechirimoru (dimethirimol), dimethyl disulfide (dimethyl dISULFIDE), dimethomorph (dimethomorph), cymoxanil ( cymoxanil), dimoxystrobin, ziram, silthiofam (Silthiofam), streptomycin (streptomycin), spiroxamine (spiroxamine), sedaxane (sedaxane), zoxamide (zoxamide), dazomet (dazomet), triazinyl (tiadinil), thiabendazole (thiabendazole), thiram (thiram), thiophanate (thiophanate), thiophanate -Methyl (thiophanate-methyl), thifluzamide (thifluzamide), technazene (tecnazene), teclophthalam (tecloftalamin), tetraconabolte buburate (debacarb), debacarb (debacarb), tebuconabu, tebuconabu (debucaron) Dodine, dodemorph, triadimenol, triadimefon, triazoxide, trichlamicol, triclopyricol, triclopyricarc, triclopyricarc, triclopyricarb, triclopyricarb, triclopyricarc, triclopyricarc, triclopyricarb, triclopyricarc, triclopyricarc, triclopyricarc , Tridemorph, triflumizole, trifloxystrobin, triforine, tolylfuranide, tolylfuranid, tolylfuranid, tolylfuranidofl, tolfloflantofurnito, tolfloflantoflnito, tolflofanid, tolflofanid, tolflofanto, and tolfloflantofurnito (nito). ), nabam, natamycin, naftifine, nitrapyrin, nitrothal-isopropyl, nuarimol, nonylphenol sulphonate, nonylphenol sulphonate, nonylphenol sulphonate, copper copter, nonylphenol sulphonate. Bacillus subtilis (strain: QST 713), validamycin, valifenarate, picalbutra Zox (picarbutrazox), bixafen (bixafen), picoxystrobin (picoxystrobin), pidiflumethofen (pydiflumetolphen), bitertanol, binaptanyl, binapacrylyl, binapacryl, biphenyl (biphenyl). , Pyraoxystrobin, pyraclostrobin, pyraziflumid, pyrazophos, pyramethostrobin, pyriofoxeox, pyriophyroxenopyrone, pyriophyroxenopyronex, pyriophyroxenopyrone, pyriophyroxenopyrone, pyriophyroxenopyronex pyributicarb (pyributicarb), pyribencarb (pyribencarb), pyrimethanil (pyrimethanil), pyroquilon (pyroquilon), vinclozolin (vinclozolin), Fabamu (ferbam), famoxadone (famoxadone), phenazine oxide (phenazine oxide), fenamidone (fenamidone), phenazine Minsuto robin (Fenaminestrobin), fenarimol, fenoxanil, ferimzone, fenpiclonil, fenpicoxenfamine, fenpycofenamphen, fenpycofenamide, fenpyroxaphen, fenpycofenamide, fenpicrone, fenpicrone, fenpicrone, fenpicrone, fenpicrone, fenpiconyl Propidine (fenpropidin), fenpropimorph (fenpropimorph), fenhexamide (fenhexamide), folpet (phthalide), bupirimate (bupirimate), fuberidazolide (fuberidazole-s), blasticidin-s. ), furametpyr, furalaxyl, furancarboxylic acid, fluazinam, fluindapir (Fluindapyr), fluoxastrobin (fluoxastrobin), fluopicolide (fluopicolide), fluopyram (fluopyram), Furuoruimido (fluoroimide), fluxapyroxad (fluxapyroxad), fluquinconazole (fluquinconazole), fluconazole (furconazole), fluconazole cis (Furconazole-cis), fludioxonil (fludioxonil), flusilazole, flusulfamide, flutianil, flutolanfur (furfuroxyl), flutolanoxy (flutofuronto), flutolanoxy (flutofuronto), flutolanoxy (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofuronto), flutolanto (flutofurinto), flutolanto (flutofuronto), flutolanto (flutofuronto), and flutolanto (flutofuronto). , Flumorph, proquinazid, prochloraz, procymidone, prothiocarbe, prothioconaproburopromoprobyl-proroconopronacoloproproconol, bronopol, bronopol, bronopol. (Propiconazole), propineb (propineb), probenazole (probenazole), bromconazole (blomuconazole), flometoquin (flometoquine), hexaconazole (hexaconazole), benalaxyl (benalaxyl, benalaxyl (ben), benalaxyl (ben, benalax). ), benomyl, pefurazoate, penconazole, pencycuron, benzovindiflupyrupyl, benzazolypyl isopropylate, benchiazolybyl benzyl benchhiazolyb, benchiazolyb, benzyl avaliate ), penflufen, boscalid, fosetyl (alminium, calcium, sodiu) m), polyoxin (polyoxin), polycarbamate (polycarbamate), Bordeaux solution (Bordeaux mix),
Mancozeb, mandipropamide, mandestrobin, maneb, microbutanil, mineral oil, mineral oil, mineral oil, mineral oil, meldiometa sulphate, mildiomycin sulfa metam), metalaxyl, metalaxyl-M, metiram, metconazol metominofenfoline (metamefenifornefornefrin), metorafenil (metraminofroniprin), metorafenol (metraminofroniprin), metorafenil (metraminoforniprin), metorafenil (metraminoforniprin), metorafenil (metraminoforniprin), metorafenil (metraminoforniprin), metrafenone (metramenfni), metrafenopren (metrafenor), metorafenil (metrafenil). ), meptyldinocap, mepronil, iodocarb, laminarin, phosphorous acid and salts, phosphoric acid silver and salts, basic copper chloride (coperlox, coperlox). , Cuprous oxide, cupric hydroxide, potassium hydrogencarbonate (potassium bicarbonate), sodium hydrogencarbonate (sodium bicarbonate), sulfur (sulfur), oxyquinoline sulfate (oxysulfinate), Copper sulphate, (3,4-dichloroisothiazol-5-yl)methyl 4-(tert-butyl)benzoate (Chemical name, CAS Registry Number: 1231214-23-5), BAF-045 (code No.), BAG-010 (code number), UK-2A (code number), DBEDC (dodecylbenzenesulfonic acid bisethylenediamine copper complex salt [II]), MIF-1002 (code number), TPTA (triphenyltin acetate), TPTC (triphenyltin chloride), TPTH (triphenyltin hydroxide), non-pathogenic Erwinia carotovora.
［除草活性成分］
　アイオキシニル（ｉｏｘｙｎｉｌ）、アクロニフェン（ａｃｌｏｎｉｆｅｎ）、アクロレイン（ａｃｒｏｌｅｉｎ）、アザフェニジン（ａｚａｆｅｎｉｄｉｎ）、アシフルオルフェン（ａｃｉｆｌｕｏｒｆｅｎ）（ナトリウムなどとの塩を含む）、アジムスルフロン（ａｚｉｍｓｕｌｆｕｒｏｎ）、アシュラム（ａｓｕｌａｍ）、アセトクロ－ル（ａｃｅｔｏｃｈｌｏｒ）、アトラジン（ａｔｒａｚｉｎｅ）、アニロホス（ａｎｉｌｏｆｏｓ）、アミカルバゾン（ａｍｉｃａｒｂａｚｏｎｅ）、アミドスルフロン（ａｍｉｄｏｓｕｌｆｕｒｏｎ）、アミトロール（ａｍｉｔｒｏｌｅ）、アミノシクロピラクロル（ａｍｉｎｏｃｙｃｌｏｐｙｒａｃｈｌｏｒ）、アミノピラリド（ａｍｉｎｏｐｙｒａｌｉｄ）、アミプロホス・メチル（ａｍｉｐｒｏｆｏｓ－ｍｅｔｈｙｌ）、アメトリン（ａｍｅｔｒｙｎ）、アラクロール（ａｌａｃｈｌｏｒ）、アロキシジム（ａｌｌｏｘｙｄｉｍ）、イソウロン（ｉｓｏｕｒｏｎ）、イソキサクロルトール（ｉｓｏｘａｃｈｌｏｒｔｏｌｅ）、イソキサフルトール（ｉｓｏｘａｆｌｕｔｏｌｅ）、イソキサベン（ｉｓｏｘａｂｅｎ）、イソプロツロン（ｉｓｏｐｒｏｔｕｒｏｎ）、イプフェンカルバゾン（ｉｐｆｅｎｃａｒｂａｚｏｎｅ）、イマザキン（ｉｍａｚａｑｕｉｎ）、イマザピク（ｉｍａｚａｐｉｃ）（アミンなどとの塩を含む）、イマザピル（ｉｍａｚａｐｙｒ）（イソプロピルアミンなどの塩を含む）、イマザメタベンズ・メチル（ｉｍａｚａｍｅｔｈａｂｅｎｚ－ｍｅｔｈｙｌ）、イマザモックス（ｉｍａｚａｍｏｘ）、イマゼタピル（ｉｍａｚｅｔｈａｐｙｒ）、イマゾスルフロン（ｉｍａｚｏｓｕｌｆｕｒｏｎ）、インダジフラム（ｉｎｄａｚｉｆｌａｍ）、インダノファン（ｉｎｄａｎｏｆａｎ）、エグリナジン・エチル（ｅｇｌｉｎａｚｉｎｅ－ｅｔｈｙｌ）、エスプロカルブ（ｅｓｐｒｏｃａｒｂ）、エタメトスルフロン・メチル（ｅｔｈａｍｅｔｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、エタルフルラリン（ｅｔｈａｌｆｌｕｒａｌｉｎ）、エチジムロン（ｅｔｈｉｄｉｍｕｒｏｎ）、エトキシスルフロン（ｅｔｈｏｘｙｓｕｌｆｕｒｏｎ）、エトキシフェン・エチル（ｅｔｈｏｘｙｆｅｎ－ｅｔｈｙｌ）、エトフメセート（ｅｔｈｏｆｕｍｅｓａｔｅ）、エトベンザニド（ｅｔｏｂｅｎｚａｎｉｄ）、エンドタール二ナトリウム塩（ｅｎｄｏｔｈａｌ－ｄｉｓｏｄｉｕｍ）、オキサジアゾン（ｏｘａｄｉａｚｏｎ）、オキサジアルギル（ｏｘａｄｉａｒｇｙｌ）、オキサジクロメホン（ｏｘａｚｉｃｌｏｍｅｆｏｎｅ）、オキサスルフロン（ｏｘａｓｕｌｆｕｒｏｎ）、オキシフルオルフェン（ｏｘｙｆｌｕｏｒｆｅｎ）、オリザリン（ｏｒｙｚａｌｉｎ）、オルトスルファムロン（ｏｒｔｈｏｓｕｌｆａｍｕｒｏｎ）、オルベンカルブ（ｏｒｂｅｎｃａｒｂ）、オレイン酸（ｏｌｅｉｃ　ａｃｉｄ）、カフェンストロール（ｃａｆｅｎｓｔｒｏｌｅ）、カルフェントラゾン・エチル（ｃａｒｆｅｎｔｒａｚｏｎｅ－ｅｔｈｙｌ）、カルブチレート（ｋａｒｂｕｔｉｌａｔｅ）、カルベタミド（ｃａｒｂｅｔａｍｉｄｅ）、キザロホップ（ｑｕｉｚａｌｏｆｏｐ－ｅｔｈｙｌ）、キザロホップ・Ｐ・エチル（ｑｕｉｚａｌｏｆｏｐ－Ｐ－ｅｔｈｙｌ）、キザロホップ・Ｐ・テフリル（ｑｕｉｚａｌｏｆｏｐ－Ｐ－ｔｅｆｕｒｙｌ）、キノクラミン（ｑｕｉｎｏｃｌａｍｉｎｅ）、キンクロラック（ｑｕｉｎｃｌｏｒａｃ）、キンメラック（ｑｕｉｎｍｅｒａｃ）、クミルロン（ｃｕｍｙｌｕｒｏｎ）、クラシホス（ｃｌａｃｙｆｏｓ）、グリホサート（ｇｌｙｐｈｏｓａｔｅ）（ナトリウム、カリウム、アンモニウム、アミン、プロピルアミン、イソプロピルアミン、ジメチルアミンまたはトリメシウムなどの塩を含む）、グルホシネート（ｇｌｕｆｏｓｉｎａｔｅ）（アミンまたはナトリウムなどの塩を含む）、グルホシネート・Ｐ・ナトリウム塩（ｇｌｕｆｏｓｉｎａｔｅ－Ｐ－ｓｏｄｉｕｍ）、クレトジム（ｃｌｅｔｈｏｄｉｍ）、クロジナホップ・プロパルギル（ｃｌｏｄｉｎａｆｏｐ－ｐｒｏｐａｒｇｙｌ）、クロピラリド（ｃｌｏｐｙｒａｌｉｄ）、クロマゾン（ｃｌｏｍａｚｏｎｅ）、クロメトキシフェン（ｃｈｌｏｍｅｔｈｏｘｙｆｅｎ）、クロメプロップ（ｃｌｏｍｅｐｒｏｐ）、クロランスラム・メチル（ｃｌｏｒａｎｓｕｌａｍ－ｍｅｔｈｙｌ）、クロランベン（ｃｈｌｏｒａｍｂｅｎ）、クロリダゾン（ｃｈｌｏｒｉｄａｚｏｎ）、クロリムロン・エチル（ｃｈｌｏｒｉｍｕｒｏｎ－ｅｔｈｙｌ）、クロルスルフロン（ｃｈｌｏｒｓｕｌｆｕｒｏｎ）、クロルタル・ジメチル（ｃｈｌｏｒｔｈａｌ－ｄｉｍｅｔｈｙｌ）、クロルチアミド（ｃｈｌｏｒｔｈｉａｍｉｄ）、クロルフタリム（ｃｈｌｏｒｐｈｔｈａｌｉｍ）、クロルフルレノール・メチル（ｃｈｌｏｒｆｌｕｒｅｎｏｌ－ｍｅｔｈｙｌ）、クロルプロファム（ｃｈｌｏｒｐｒｏｐｈａｍ）、クロルブロムロン（ｃｈｌｏｒｂｒｏｍｕｒｏｎ）、クロロクスロン（ｃｈｌｏｒｏｘｕｒｏｎ）、クロロトルロン（ｃｈｌｏｒｏｔｏｌｕｒｏｎ）、ケトスピラドックス（ｋｅｔｏｓｐｉｒａｄｏｘ）（ナトリウム、カルシウムまたはアンモニアなどの塩を含む）、サフルフェナシル（ｓａｆｌｕｆｅｎａｃｉｌ）、サルメンチン（ｓａｒｍｅｎｔｉｎｅ）、シアナジン（ｃｙａｎａｚｉｎｅ）、シアナミド（ｃｙａｎａｍｉｄｅ）、ジウロン（ｄｉｕｒｏｎ）、ジエタチル・エチル（ｄｉｅｔｈａｔｙｌ－ｅｔｈｙｌ）、ジカンバ（ｄｉｃａｍｂａ）（アミン、ジエチルアミン、イソプロピルアミン、ジグリコールアミン、ナトリウムまたはリチウムなどの塩を含む）、シクロエート（ｃｙｃｌｏａｔｅ）、シクロキシジム（ｃｙｃｌｏｘｙｄｉｍ）、ジクロスラム（ｄｉｃｌｏｓｕｌａｍ）、シクロスルファムロン（ｃｙｃｌｏｓｕｌｆａｍｕｒｏｎ）、シクロピリモレート（ｃｙｃｌｏｐｙｒｉｍｏｒａｔｅ）、ジクロベニル（ｄｉｃｈｌｏｂｅｎｉｌ）、ジクロホップ・Ｐ・メチル（ｄｉｃｌｏｆｏｐ－Ｐ－ｍｅｔｈｙｌ）、ジクロホップ・メチル（ｄｉｃｌｏｆｏｐ－ｍｅｔｈｙｌ）、ジクロルプロップ（ｄｉｃｈｌｏｒｐｒｏｐ）、ジクロルプロップ－Ｐ（ｄｉｃｈｌｏｒｐｒｏｐ－Ｐ）、ジクワット（ｄｉｑｕａｔ）、ジチオピル（ｄｉｔｈｉｏｐｙｒ）、シデュロン（ｓｉｄｕｒｏｎ）、ジニトラミン（ｄｉｎｉｔｒａｍｉｎｅ）、シニドン・エチル（ｃｉｎｉｄｏｎ－ｅｔｈｙｌ）、シノスルフロン（ｃｉｎｏｓｕｌｆｕｒｏｎ）、ジノゼブ（ｄｉｎｏｓｅｂ）、ジノテルブ（ｄｉｎｏｔｅｒｂ）、シハロホップ・ブチル（ｃｙｈａｌｏｆｏｐ－ｂｕｔｙｌ）、ジフェナミド（ｄｉｐｈｅｎａｍｉｄ）、ジフェンゾコート（ｄｉｆｅｎｚｏｑｕａｔ）、ジフルフェニカン（ｄｉｆｌｕｆｅｎｉｃａｎ）、ジフルフェンゾピル（ｄｉｆｌｕｆｅｎｚｏｐｙｒ）、シマジン（ｓｉｍａｚｉｎｅ）、ジメタクロール（ｄｉｍｅｔｈａｃｈｌｏｒ）、ジメタメトリン（ｄｉｍｅｔｈａｍｅｔｒｙｎ）、ジメテナミド（ｄｉｍｅｔｈｅｎａｍｉｄ）、ジメテナミド・Ｐ（ｄｉｍｅｔｈｅｎａｍｉｄ－Ｐ）、シメトリン（ｓｉｍｅｔｒｙｎ）、ジメピペレート（ｄｉｍｅｐｉｐｅｒａｔｅ）、ジメフロン（ｄｉｍｅｆｕｒｏｎ）、シンメチリン（ｃｉｎｍｅｔｈｙｌｉｎ）、スエップ（ｓｗｅｐ）、スルコトリオン（ｓｕｌｃｏｔｒｉｏｎｅ）、スルフェントラゾン（ｓｕｌｆｅｎｔｒａｚｏｎｅ）、スルホサート（ｓｕｌｆｏｓａｔｅ）、スルホスルフロン（ｓｕｌｆｏｓｕｌｆｕｒｏｎ）、スルホメツロン・メチル（ｓｕｌｆｏｍｅｔｕｒｏｎ－ｍｅｔｈｙｌ）、セトキシジム（ｓｅｔｈｏｘｙｄｉｍ）、ターバシル（ｔｅｒｂａｃｉｌ）、ダイムロン（ｄａｉｍｕｒｏｎ）、タキストミン・Ａ（ｔｈａｘｔｏｍｉｎ　Ａ）、ダラポン（ｄａｌａｐｏｎ）、チアゾピル（ｔｈｉａｚｏｐｙｒ）、チアフェナシル（ｔｉａｆｅｎａｃｉｌ）、チエンカルバゾン（ｔｈｉｅｎｃａｒｂａｚｏｎｅ）（ナトリウム塩、メチルエステルなどを含む）、チオカルバジル（ｔｉｏｃａｒｂａｚｉｌ）、チオベンカルブ（ｔｈｉｏｂｅｎｃａｒｂ）、チジアジミン（ｔｈｉｄｉａｚｉｍｉｎ）、チフェンスルフロン・メチル（ｔｈｉｆｅｎｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、デスメディファム（ｄｅｓｍｅｄｉｐｈａｍ）、デスメトリン（ｄｅｓｍｅｔｒｙｎｅ）、テニルクロール（ｔｈｅｎｙｌｃｈｌｏｒ）、テブタム（ｔｅｂｕｔａｍ）、テブチウロン（ｔｅｂｕｔｈｉｕｒｏｎ）、テプラロキシジム（ｔｅｐｒａｌｏｘｙｄｉｍ）、テフリルトリオン（ｔｅｆｕｒｙｌｔｒｉｏｎｅ）、テムボトリオン（ｔｅｍｂｏｔｒｉｏｎｅ）、テルブチラジン（ｔｅｒｂｕｔｈｙｌａｚｉｎｅ）、テルブトリン（ｔｅｒｂｕｔｒｙｎ）、テルブメトン（ｔｅｒｂｕｍｅｔｏｎ）、トプラメゾン（ｔｏｐｒａｍｅｚｏｎｅ）、トラルコキシジム（ｔｒａｌｋｏｘｙｄｉｍ）、トリアジフラム（ｔｒｉａｚｉｆｌａｍ）、トリアスルフロン（ｔｒｉａｓｕｌｆｕｒｏｎ）、トリアファモン（ｔｒｉａｆａｍｏｎｅ）、トリアレート（ｔｒｉ－ａｌｌａｔｅ）、トリエタジン（ｔｒｉｅｔａｚｉｎｅ）、トリクロピル（ｔｒｉｃｌｏｐｙｒ）、トリクロピル－ブトティル（ｔｒｉｃｌｏｐｙｒ－ｂｕｔｏｔｙｌ）、トリフルジムオキサジン（ｔｒｉｆｌｕｄｉｍｏｘａｚｉｎ）、トリトスルフロン（ｔｒｉｔｏｓｕｌｆｕｒｏｎ）、トリフルスルフロン・メチル（ｔｒｉｆｌｕｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、トリフルラリン（ｔｒｉｆｌｕｒａｌｉｎ）、トリフロキシスルフロンナトリウム塩（ｔｒｉｆｌｏｘｙｓｕｌｆｕｒｏｎ－ｓｏｄｉｕｍ）、トリベニュロン・メチル（ｔｒｉｂｅｎｕｒｏｎ－ｍｅｔｈｙｌ）、トルピラレート（ｔｏｌｐｙｒａｌａｔｅ）、ナプタラム（ｎａｐｔａｌａｍ）（ナトリウムなどとの塩を含む）、ナプロアニリド（ｎａｐｒｏａｎｉｌｉｄｅ）、ナプロパミド（ｎａｐｒｏｐａｍｉｄｅ）、ナプロパミド－Ｍ（ｎａｐｒｏｐａｍｉｄｅ－Ｍ）、ニコスルフロン（ｎｉｃｏｓｕｌｆｕｒｏｎ）、ネブロン（ｎｅｂｕｒｏｎ）、ノルフルラゾン（ｎｏｒｆｌｕｒａｚｏｎ）、バーナレート（ｖｅｒｎｏｌａｔｅ）、パラコート（ｐａｒａｑｕａｔ）、ハルキシフェン－ベンジル（ｈａｌａｕｘｉｆｅｎ－ｂｅｎｚｙｌ）、ハルキシフェン－メチル（ｈａｌａｕｘｉｆｅｎ－ｍｅｔｈｙｌ）、ハロキシホップ（ｈａｌｏｘｙｆｏｐ）、ハロキシホップ・Ｐ（ｈａｌｏｘｙｆｏｐ－Ｐ）、ハロキシホップ－エトティル（ｈａｌｏｘｙｆｏｐ－ｅｔｏｔｙｌ）、ハロサフェン（ｈａｌｏｓａｆｅｎ）、ハロスルフロン・メチル（ｈａｌｏｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、ピクロラム（ｐｉｃｌｏｒａｍ）、ピコリナフェン（ｐｉｃｏｌｉｎａｆｅｎ）、ビシクロピロン（ｂｉｃｙｃｌｏｐｙｒｏｎｅ）、ビスピリバック・ナトリウム塩（ｂｉｓｐｙｒｉｂａｃ－ｓｏｄｉｕｍ）、ピノキサデン（ｐｉｎｏｘａｄｅｎ）、ビフェノックス（ｂｉｆｅｎｏｘ）、ピペロホス（ｐｉｐｅｒｏｐｈｏｓ）、ピラクロニル（ｐｙｒａｃｌｏｎｉｌ）、ピラスルホトール（ｐｙｒａｓｕｌｆｏｔｏｌｅ）、ピラゾキシフェン（ｐｙｒａｚｏｘｙｆｅｎ）、ピラゾスルフロン・エチル（ｐｙｒａｚｏｓｕｌｆｕｒｏｎ－ｅｔｈｙｌ）、ピラゾリネート（ｐｙｒａｚｏｌｙｎａｔｅ）、ビラナホス（ｂｉｌａｎａｆｏｓ）、ピラフルフェン・エチル（ｐｙｒａｆｌｕｆｅｎ－ｅｔｈｙｌ）、ピリダフォル（ｐｙｒｉｄａｆｏｌ）、ピリチオバック・ナトリウム塩（ｐｙｒｉｔｈｉｏｂａｃ－ｓｏｄｉｕｍ）、ピリデート（ｐｙｒｉｄａｔｅ）、ピリフタリド（ｐｙｒｉｆｔａｌｉｄ）、ピリブチカルブ（ｐｙｒｉｂｕｔｉｃａｒｂ）、ピリベンゾキシム（ｐｙｒｉｂｅｎｚｏｘｉｍ）、ピリミスルファン（ｐｙｒｉｍｉｓｕｌｆａｎ）、ピリミノバック・メチル（ｐｙｒｉｍｉｎｏｂａｃ－ｍｅｔｈｙｌ）、ピロキサスルホン（ｐｙｒｏｘａｓｕｌｆｏｎｅ）、ピロクススラム（ｐｙｒｏｘｓｕｌａｍ）、フェニソファム（ｐｈｅｎｉｓｏｐｈａｍ）、フェニュロン（ｆｅｎｕｒｏｎ）、フェノキサスルホン（ｆｅｎｏｘａｓｕｌｆｏｎｅ）、フェノキサプロップ（ｆｅｎｏｘａｐｒｏｐ）（メチル、エチル
、イソプロピルエステルを含む）、フェノキサプロップ・Ｐ（ｆｅｎｏｘａｐｒｏｐ－Ｐ）（メチル、エチル、イソプロピルエステルを含む）、フェンキノトリオン（ｆｅｎｑｕｉｎｏｔｒｉｏｎｅ）、フェンチアプロップ・エチル（ｆｅｎｔｈｉａｐｒｏｐ－ｅｔｈｙｌ）、フェントラザミド（ｆｅｎｔｒａｚａｍｉｄｅ）、フェンメディファム（ｐｈｅｎｍｅｄｉｐｈａｍ）、ブタクロール（ｂｕｔａｃｈｌｏｒ）、ブタフェナシル（ｂｕｔａｆｅｎａｃｉｌ）、ブタミホス（ｂｕｔａｍｉｆｏｓ）、ブチレート（ｂｕｔｙｌａｔｅ）、ブテナクロール（ｂｕｔｅｎａｃｈｌｏｒ）、ブトラリン（ｂｕｔｒａｌｉｎ）、ブトロキシジム（ｂｕｔｒｏｘｙｄｉｍ）、フラザスルフロン（ｆｌａｚａｓｕｌｆｕｒｏｎ）、フラムプロップ（ｆｌａｍｐｒｏｐ）（メチル、エチル、イソプロピルエステルを含む）、フラムプロップ・Ｍ（ｆｌａｍｐｒｏｐ－Ｍ）（メチル、エチル、イソプロピルエステルを含む）、プリミスルフロン・メチル（ｐｒｉｍｉｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、フルアジホップ・ブチル（ｆｌｕａｚｉｆｏｐ－ｂｕｔｙｌ）、フルアジホップ・Ｐ・ブチル（ｆｌｕａｚｉｆｏｐ－Ｐ－ｂｕｔｙｌ）、フルアゾレート（ｆｌｕａｚｏｌａｔｅ）、フルオメツロン（ｆｌｕｏｍｅｔｕｒｏｎ）、フルオログリコフェン・エチル（ｆｌｕｏｒｏｇｌｙｃｏｆｅｎ－ｅｔｈｙｌ）、フルカルバゾン・ナトリウム塩（ｆｌｕｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、フルクロラリン（ｆｌｕｃｈｌｏｒａｌｉｎ）、フルセトスルフロン（ｆｌｕｃｅｔｏｓｕｌｆｕｒｏｎ）、フルチアセット・メチル（ｆｌｕｔｈｉａｃｅｔ－ｍｅｔｈｙｌ）、フルピルスルフロン・メチル・ナトリウム塩（ｆｌｕｐｙｒｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ－ｓｏｄｉｕｍ）、フルフェナセット（ｆｌｕｆｅｎａｃｅｔ）、フルフェンピル・エチル（ｆｌｕｆｅｎｐｙｒ－ｅｔｈｙｌ）、フルプロパネート（ｆｌｕｐｒｏｐａｎａｔｅ）、フルポキサム（ｆｌｕｐｏｘａｍｅ）、フルミオキサジン（ｆｌｕｍｉｏｘａｚｉｎ）、フルミクロラック・ペンチル（ｆｌｕｍｉｃｌｏｒａｃ－ｐｅｎｔｙｌ）、フルメツラム（ｆｌｕｍｅｔｓｕｌａｍ）、フルリドン（ｆｌｕｒｉｄｏｎｅ）、フルルタモン（ｆｌｕｒｔａｍｏｎｅ）、フルロキシピル（ｆｌｕｒｏｘｙｐｙｒ）、フルロクロリドン（ｆｌｕｒｏｃｈｌｏｒｉｄｏｎｅ）、プレチラクロール（ｐｒｅｔｉｌａｃｈｌｏｒ）、プロカルバゾン・ナトリウム塩（ｐｒｏｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、プロジアミン（ｐｒｏｄｉａｍｉｎｅ）、プロスルフロン（ｐｒｏｓｕｌｆｕｒｏｎ）、プロスルホカルブ（ｐｒｏｓｕｌｆｏｃａｒｂ）、プロパキザホップ（ｐｒｏｐａｑｕｉｚａｆｏｐ）、プロパクロール（ｐｒｏｐａｃｈｌｏｒ）、プロパジン（ｐｒｏｐａｚｉｎｅ）、プロパニル（ｐｒｏｐａｎｉｌ）、プロピザミド（ｐｒｏｐｙｚａｍｉｄｅ）、プロピソクロール（ｐｒｏｐｉｓｏｃｈｌｏｒ）、プロピリスルフロン（ｐｒｏｐｙｒｉｓｕｌｆｕｒｏｎ）、プロファム（ｐｒｏｐｈａｍ）、プロフルアゾール（ｐｒｏｆｌｕａｚｏｌ）、プロポキシカルバゾン・ナトリウム塩（ｐｒｏｐｏｘｙｃａｒｂａｚｏｎｅ－ｓｏｄｉｕｍ）、プロホキシジム（ｐｒｏｆｏｘｙｄｉｍ）、ブロマシル（ｂｒｏｍａｃｉｌ）、ブロムピラゾン（ｂｒｏｍｐｙｒａｚｏｎ）、プロメトリン（ｐｒｏｍｅｔｒｙｎ）、プロメトン（ｐｒｏｍｅｔｏｎ）、ブロモキシニル（ｂｒｏｍｏｘｙｎｉｌ）（酪酸、オクタン酸またはヘプタン酸などのエステル体を含む）、ブロモフェノキシム（ｂｒｏｍｏｆｅｎｏｘｉｍ）、ブロモブチド（ｂｒｏｍｏｂｕｔｉｄｅ）、フロラスラム（ｆｌｏｒａｓｕｌａｍ）、フロルピラキシフェン（ｆｌｏｒｐｙｒａｕｘｉｆｅｎ） 、ヘキサジノン（ｈｅｘａｚｉｎｏｎｅ）、ペトキサミド（ｐｅｔｈｏｘａｍｉｄ）、ベナゾリン（ｂｅｎａｚｏｌｉｎ）、ペノキススラム（ｐｅｎｏｘｓｕｌａｍ）、ヘプタマロキシログルカン（ｈｅｐｔａｍａｌｏｘｙｌｏｇｌｕｃａｎ）、ベフルブタミド（ｂｅｆｌｕｂｕｔａｍｉｄ）、ペブレート（ｐｅｂｕｌａｔｅ）、ペラルゴン酸（ｐｅｌａｒｇｏｎｉｃ ａｃｉｄ）、ベンカルバゾン（ｂｅｎｃａｒｂａｚｏｎｅ）、ペンジメタリン（ｐｅｎｄｉｍｅｔｈａｌｉｎ）、ベンズフェンジゾン（ｂｅｎｚｆｅｎｄｉｚｏｎｅ）、ベンスリド（ｂｅｎｓｕｌｉｄｅ）、ベンスルフロン・メチル（ｂｅｎｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、ベンゾビシクロン（ｂｅｎｚｏｂｉｃｙｃｌｏｎ）、ベンゾフェナップ（ｂｅｎｚｏｆｅｎａｐ）、ベンタゾン（ｂｅｎｔａｚｏｎｅ）、ペンタノクロール（ｐｅｎｔａｎｏｃｈｌｏｒ）、ペントキサゾン（ｐｅｎｔｏｘａｚｏｎｅ）、ベンフルラリン（ｂｅｎｆｌｕｒａｌｉｎ）、ベンフレセート（ｂｅｎｆｕｒｅｓａｔｅ）、ホサミン（ｆｏｓａｍｉｎｅ）、ホメサフェン（ｆｏｍｅｓａｆｅｎ）、ホラムスルフロン（ｆｏｒａｍｓｕｌｆｕｒｏｎ）、メコプロップ（ｍｅｃｏｐｒｏｐ）（ナトリウム、カリウム、イソプロピルアミン、トリエタノールアミン、ジメチルアミンなどの塩を含む）、メコプロップ・Ｐ・カリウム塩（ｍｅｃｏｐｒｏｐ－Ｐ－ｐｏｔａｓｓｉｕｍ）、メソスフロン・メチル（ｍｅｓｏｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、メソトリオン（ｍｅｓｏｔｒｉｏｎｅ）、メタザクロール（ｍｅｔａｚａｃｈｌｏｒ）、メタゾスルフロン（ｍｅｔａｚｏｓｕｌｆｕｒｏｎ）、メタベンズチアズロン（ｍｅｔｈａｂｅｎｚｔｈｉａｚｕｒｏｎ）、メタミトロン（ｍｅｔａｍｉｔｒｏｎ）、メタミホップ（ｍｅｔａｍｉｆｏｐ）、ＤＳＭＡ（メタンアルソン酸二ナトリウム）、メチオゾリン（ｍｅｔｈｉｏｚｏｌｉｎ）、メチルダイムロン（ｍｅｔｈｙｌｄｙｍｕｒｏｎ）、メトキスロン（ｍｅｔｏｘｕｒｏｎ）、メトスラム（ｍｅｔｏｓｕｌａｍ）、メトスルフロン・メチル（ｍｅｔｓｕｌｆｕｒｏｎ－ｍｅｔｈｙｌ）、メトブロムロン（ｍｅｔｏｂｒｏｍｕｒｏｎ）、メトベンズロン（ｍｅｔｏｂｅｎｚｕｒｏｎ）、メトラクロール（ｍｅｔｏｌａｃｈｌｏｒ）、メトリブジン（ｍｅｔｒｉｂｕｚｉｎ）、メフェナセット（ｍｅｆｅｎａｃｅｔ）、モノスルフロン（ｍｏｎｏｓｕｌｆｕｒｏｎ）（メチル、エチル、イソプロピルエステルを含む）、モノリニュロン（ｍｏｎｏｌｉｎｕｒｏｎ）、モリネート（ｍｏｌｉｎａｔｅ）、ヨードスルフロン（ｉｏｄｏｓｕｌｆｕｒｏｎ）、ヨードスルフロンメチルナトリウム塩（ｉｏｄｏｓｕｌｆｕｌｏｎ－ｍｅｔｈｙｌ－ｓｏｄｉｕｍ）、ヨーフェンスルフロン（ｉｏｆｅｎｓｕｌｆｕｒｏｎ）、ヨーフェンスルフロン・ナトリウム塩（ｉｏｆｅｎｓｕｌｆｕｒｏｎ－ｓｏｄｉｕｍ）、ラクトフェン（ｌａｃｔｏｆｅｎ）、ランコトリオン（ｌａｎｃｏｔｒｉｏｎｅ）、 リニュロン（ｌｉｎｕｒｏｎ）、リムスルフロン（ｒｉｍｓｕｌｆｕｒｏｎ）、レナシル（ｌｅｎａｃｉｌ）、ＴＣＡ（２，２，２－トリクロロ酢酸）（ナトリウム、カルシウム又はアンモニアなどの塩を含む）、２，３，６－ＴＢＡ（２，３，６－トリクロロ安息香酸）、２，４，５－Ｔ（２，４，５－トリクロロフェノキシ酢酸）、２，４－Ｄ（２，４－ジクロロフェノキシ酢酸）（アミン、ジエチルアミン、トリエタノールアミン、イソプロピルアミン、ナトリウム又はリチウムなどの塩を含む）、ＡＣＮ（２－アミノ－３－クロロ－１，４－ナフトキノン）、ＭＣＰＡ（２－メチル－４－クロロフェノキシ酢酸）、ＭＣＰＢ（２－メチル－４－クロロフェノキシ酪酸）（ナトリウム塩、エチルエステルなどを含む）、２，４－ＤＢ（４－（２，４－ジクロロフェノキシ）酪酸）、ＤＮＯＣ（４，６－ジニトロ－Ｏ－クレゾール）（アミン又はナトリウムなどの塩を含む）、ＡＥ－Ｆ‐１５０９４４（コード番号）、ＨＷ－０２（コード番号）、ＩＲ－６３９６（コード番号）、ＭＣＰＡ・チオエチル（ＭＣＰＡ－ｔｈｉｏｅｔｈｙｌ）、ＳＹＰ－２９８（コード番号）、ＳＹＰ－３００（コード番号）、ＥＰＴＣ（Ｓ－エチルジプロピルチオカーバメート）、Ｓ－メトラクロール（Ｓ－ｍｅｔｏｌａｃｈｌｏｒ）。 [Herbicidal active ingredient]
Aioxynil, aclonifen, acrolein, azafenidin, acifluorfen (including salts with sodium), azimsulfuron, ashram-asuram, asula-asula. (Acetochlor), atrazine, anilofos, amicarbazone, amidosulfuron, amitrole, aminocyclopyrachloriola(aminocyclopyrola), aminocyclopyrachloriola(a), aminocyclopyrachlor(aminocyclopyrola), aminocyclopyrachlor(a) methyl), ametrine, alaclor, alloxydim, isouron, isoxachlortorole, isoxafurutole, isoxaproton, isoxapron Ipfencarbazone, imazaquin, imazapic (including salts with amines), imazapyr (including salts such as isopropylamine), imazametazmethime-imazaz, imazaquine Imazamox, imazethapyr, imazosulfuron, indazifram-indeploef, indanofuron, ethenefur, and indanofron ethresulfur, indanoflame, indanofuran, indanofuran, indanofuran, indanofuran, ethenefur, and indanofuran, ethenefur, Ethalfluralin, ethidimuron, ethoxysulfuron, ethoxyphen-ethyl, ethofumesate, etobendo sodium salt, etobendenid sodium salt. dium, oxadiazon, oxadiagyl, oxadichromene, oxasulfuron, oxyfluorfen, oryzalfuron, oryzalfuron, oryzaluron, oryzaluron, oryzaluron, oryzaluron, oryzaluron, oryzalin Oleic acid, cafenstrol, carfentrazone-ethyl, carbutilate, carbetamide, quizalofop-ethyl-Puroyl, quizalofop-ethyl-Puroyl, quizalofop-ethyl-furo-P. Ethyl), quizalofop P. tefuryl (quizalofop-P-tefuryl), quinoclamine, quinclorac, quinchlorac, quinmerac, cumyluron, cumyluron, clasyphos, clacyloc, clasifo, claflocy, clacylac, clasiflac. Potassium, ammonium, amine, propylamine, isopropylamine, dimethylamine or trimesium salts, etc., glufosinate (including amine or sodium salts, etc.), glufosinate P sodium salt (glufosinate-P-sodium) ), clethodym, clodinafop-propargyl, clopyralid, cromazone, clometholam, clomethranyl, chloromelan, clomethranyl, clomethranyl, clomethranyl, clomethranyl, clomethranyl, clomethranyl, clomethran, clomethranyl, clomethran, clomethran, clomethranyl, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, clomethran, and clomethran. ), chloridazon (chloridazon), chlorimuron-ethyl (chlorimuron-ethyl), chlorsulfuron (chlorsulfuron), Kurorutaru dimethyl (chlorthal-dimethyl), chlorthiamid (chlorthiamid), Kurorufutarimu (Chlorphthalim), chloro Hulhule Nord methyl (ch lorflurenol-methyl, chlorpropham, chlorbromuron, chloroxuron, chlorotoruron, ketospiradox (sodium, calcium or ammonia) including salts such as ketospiradox, sodium, calcium, or ammonia. Saflufenacil), Sarumenchin (sarmentine), cyanazine (cyanazine), cyanamide (cyanamide), diuron (diuron), Jietachiru ethyl (diethatyl-ethyl), dicamba (dicamba) (amine, diethylamine, isopropylamine, diglycol amine, sodium or (Including salts such as lithium), cycloate, cycloxydim, diclosulam, cyclosulfamuron, cyclopyrimorate, diclobenyl, dichlobenil. diclohop-P-methyl), diclohop-methyl, dichlorprop, dichlorprop-P, diquat, dithiomin, dithiurospirone, dithiopirdione, dithiurospirone, dithiopyrrondithion, dithiurospirone, dithiopyrrondithion, dithiurospirone (Dinitramine), cinidone-ethyl, cinosulfuron, dinoseb, dinoterb, cyhalofop cydiafif difenamide (dihafenopide), diphenazodiphenid (diphenamide), diphenamide (diphenamide, diphenamide). ), diflufenzopyr (diflufenzopyr), simazine (simazine), Jimetakuroru (dimethachlor), dimethametryn (dimethametryn), dimethenamid (dimethenamid), dimethenamid · P (dimethenamid-P), simetryn (simetryn), dimepiperate (dimepiperate), Jimefuron (Dimfu ron), cinmethylin, swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfuronoxy, sulfomethuron-meth-uron, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, sulfomethrone, and sulfomethrone. sethoxydim), terbacil, daimuron, tachystomin A, dalapon, thiazopyr, thiafenacyl salt, etc., and thienphencarbazone (thiencarbone), thiencarbazone (thienc ar), thiencarbazone (thienc). , Thiocarbazil, thiobencarb, thidiazimin, thifensulfuron-methyl, desmedutram (desmediphram), desmethrin (desmetern), desmethrin (desmetern) (Tebuthiuron), tepraloxydim (tepraloxydim), tefuryltrione (tefuryltrione), tembotrion (tembutrione), terbutylazion ziruzionem (terbuthlazone zrombole), terbutryon (terbutryn), terbutrime (terbumerin), terbumethon (terbumeton) triaziflam), triasulfuron (triasulfuron), Toriafamon (triafamone), thoria rate (tri-allate), Torietajin (trietazine), triclopyr (triclopyr), triclopyr - Butotiru (triclopyr-butotyl), triflupromazine Jim benzoxazine (trifludimoxazin), Toritosuru CFCs, triflusulfuron-methyl, trifluralin, trifloxysulfuron-sodium, tris. Benuron-methyl, tolpyralate, naptalam (including salts with sodium, etc.), naproanilide, napropamide, napropamide-M, nipropamip-M, napromamide-M, napromap-m, napromamide-M, napramide (Nicosfurfuron), nebulon, norflurazon, vernolate, paraquat, halaxifen-benoxy, halxifen-benoxyl, halaxiflo-haloxyl, haloxiflo, haloxiflo-halo, haloxiflo-halo, haloxiflo-halo, haloxiflo-hop. P (haloxyfop-P), haloxyfop-etotyl, halosafen, halosulfuron-methyl, picloram, picolinaphen, cyclolinaphen (picolinafen), picolinaphen (picolinafen), picolinafen (picolinafen) Salt (bispyribac-sodium), pinoxaden (pinoxaden), bifenox (pifenophos), pyraclonil (pyraclonyl), pyrasulfonyl pyrazolone (pyrasulfoyl), pyrazolpyrazolyl (pyrasulfopyr), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazoloxy (pyrazol), pyrazolpyronyl (pyrazol), pyrazoloxy (pyr), pyrazolynate, bilanafos, pyraflufen-ethyl, pyridafor, pyrithiobacurib-bilibutybium-pyributyb, pyridate, pyriflate-pyributyb, pyridate, pyriflate-pyributyb, pyriflate-pyributyrate, pyridate, pyrifurate-pyributyrate, pyridate, pyrifurate-pyributyrate, pyridate, pyridate, pyrifurate-pyributyrate, pyridate, pyrifurate-pyributyrate, pyridate, pyridate, pyridate, pyridate, pyridate, pyridate, pyridate, pyridate, pyridate, pyridate. ), pyrimisulfan, pyriminobac-methyl, pyroxasulfone, pyroxsulham, phenisopham, phenuro. Fenuron, fenoxasulfone, fenoxaprop (including methyl, ethyl, isopropyl ester), fenoxaprop-P (including methyl, ethyl, isopropyl ester), Fenquinotrione, fenthiaprop-ethyl, fentrazamide, phenmedipham, butachlorate, butaphenate, butaphenate, butaphenate, butaphenate, butaphenate, butafenate, butaphenate Butenachlor, butralin, butroxydim, flazasulfuron, flamprop (including methyl, ethyl, isopropyl ester), flamprop M (flamprop-M) (methyl). Ethyl, including isopropyl ester), primisulfuron-methyl, fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluometuron. , Fluoroglycophene-ethyl, flucarbazone-sodium, fluchloralin, flucetosulfuron, fluthiaset methyl-fluthylactyl-fulthyl-pill. Sodium salt (flupyrsulfuron-methyl-sodium), flufenacet, flufenpyr-ethyl, flupropanate, flupoxamyl, flumioxazin (flumioxax), flumioxazin (flumioz) flumiclorac-pentyl), flumetslam, fluridone , Flutamone, fluroxypyr, flurochloridone, pretilachlor, procarbazone sodium salt (procarbazolone-produrofurone), prodiamine (prodrofurone, prodiamine) ), propaquizahop, propachlor, propazine, propanil, propyzamide, propisochlors, propyrosfuron, propyrosfuron, propyrosfuron, propyrosulfur, propyrosulfur, propylosulfur, propyrisfuron, propyrosulfur, propyrisfuron, propyrisfuron, propyrisfuron, propyrofur, propyrisulfur, propyrisfuron, propyrosulfur, propyrisfuron, propysulfur, propysulfur, propysulfur, propysulfur, propysulfur, propyrisulfur Fluazole, propoxycarbazone-sodium salt, propoxydim, bromacil, brompyrazone brompyron (promethoron), promethrin (promethoron), promethrin (promethoron) (Including ester forms such as octanoic acid or heptanoic acid), bromophenoxim, bromobutide, florasulam, florpyrauxifene, hexazinonep, hexazinone, petoxamide. benazolin), penoxsulam (penoxsulam), hepta Malo xyloglucan (heptamaloxyloglucan), Befurubutamido (beflubutamid), Pebureto (pebulate), pelargonic acid (pelargonic acid), Benkarubazon (bencarbazone), pendimethalin (pendimethalin), benz phen di hydrazone (benzfendizone) , Benzulide, bensulfuron-methyl, benzobicyclon, benzophenap, benzazone, pentazane Pentanochlor, Pentoxazone, Benfluralin, Benfuresate, Fosamine, Fomesamine, Fomesaphen, Sodium, Folamsulfuron, Foramesopropro, Sodium, Folamsulfuron (Including salts of ethanolamine, dimethylamine, etc.), mecoprop-P-potassium salt, mesoprofuron-methyl, mesotrione, metazachlors, metazosulflon , Metabenzthiazuron, metamitron, metamihop, DSMA (disodium methanearsonate), methiozolin, methyldymurons, metylxuron, metxuron, methomuron, methomuron, methomuron, methomuron, methomuron, metoxiron. Methosulfuron-methyl, metobromuron, metobenzuron, metolachlor, metribuzin, methenafuron, mefenacet, monosulfur, monosulfuron, monosulfuron, monosulfuron, monosulfuron, monosulfuron, and monosulfuron. Monolinuron, molinate, iodosulfuron, iodosulfuron-methyl sodium salt (iodosulfulon-methyl-sodium), yofensulfuron (iofensulfuron), iofensulfuron-enul sodium salt. Lactofen, lancotrione, linuron, rimsulfuron, lenacil, TCA (2,2,2-trichloroacetic acid) (including salts such as sodium, calcium or ammonia) , 2, 3, 6- TBA (2,3,6-trichlorobenzoic acid), 2,4,5-T (2,4,5-trichlorophenoxyacetic acid), 2,4-D (2,4-dichlorophenoxyacetic acid) (amine, diethylamine , Triethanolamine, isopropylamine, salts such as sodium or lithium), ACN (2-amino-3-chloro-1,4-naphthoquinone), MCPA (2-methyl-4-chlorophenoxyacetic acid), MCPB ( 2-Methyl-4-chlorophenoxybutyric acid) (including sodium salt, ethyl ester, etc.), 2,4-DB (4-(2,4-dichlorophenoxy)butyric acid), DNOC (4,6-dinitro-O- Cresol) (including salts such as amine or sodium), AE-F-150944 (code number), HW-02 (code number), IR-6396 (code number), MCPA/thioethyl (MCPA-thioethyl), SYP- 298 (code number), SYP-300 (code number), EPTC (S-ethyldipropylthiocarbamate), S-metolachlor (S-metolachlor).
［植物生育調整活性成分］
　１－メチルシクロプロペン（１－ｍｅｔｈｙｌｃｙｃｌｏｐｒｏｐｅｎｅ）、１－ナフチルアセトアミド（１－ｎａｐｈｔｈｙｌａｃｅｔａｍｉｄｅ）、２，６－ジイソプロピルナフタレン（２，６－ｄｉｉｓｏｐｒｏｐｙｌｎａｐｈｔｈａｌｅｎｅ）、４－ＣＰＡ（４－クロロフェノキシ酢酸）、ベンジルアミノプリン（ｂｅｎｚｙｌａｍｉｎｏｐｕｒｉｎｅ）、アンシミドール（ａｎｃｙｍｉｄｏｌ）、アビグリシン（ａｖｉｇｌｙｃｉｎｅ）、カルボネ（ｃａｒｖｏｎｅ）、クロルメコート（ｃｈｌｏｒｍｅｑｕａｔ）、クロプロップ（ｃｌｏｐｒｏｐ）、クロキシホナック（ｃｌｏｘｙｆｏｎａｃ）、クロキシホナック・カリウム塩（ｃｌｏｘｙｆｏｎａｃ－ｐｏｔａｓｓｉｕｍ）、シクラニリド（ｃｙｃｌａｎｉｌｉｄｅ）、サイトカイニン（ｃｙｔｏｋｉｎｉｎｓ）、ダミノジット（ｄａｍｉｎｏｚｉｄｅ）、ジケグラック（ｄｉｋｅｇｕｌａｃ）、ジメチピン（ｄｉｍｅｔｈｉｐｉｎ）、エテホン（ｅｔｈｅｐｈｏｎ）、エポコレオン（ｅｐｏｃｈｏｌｅｏｎｅ）、エチクロゼート（ｅｔｈｙｃｈｌｏｚａｔｅ）、フルメトラリン（ｆｌｕｍｅｔｒａｌｉｎ）、フルレノール（ｆｌｕｒｅｎｏｌ）、フルルプリミドール（ｆｌｕｒｐｒｉｍｉｄｏｌ）、ホルクロルフェニュロン（ｆｏｒｃｈｌｏｒｆｅｎｕｒｏｎ）、ジベレリン（ｇｉｂｂｅｒｅｌｌｉｎｓ）、イナベンフィド（ｉｎａｂｅｎｆｉｄｅ）、インドール酢酸（ｉｎｄｏｌｅ　ａｃｅｔｉｃ　ａｃｉｄ）、インドール酪酸（ｉｎｄｏｌｅ　ｂｕｔｙｒｉｃ　ａｃｉｄ）、マレイン酸ヒドラジド（ｍａｌｅｉｃ　ｈｙｄｒａｚｉｄｅ）、メフルイジド（ｍｅｆｌｕｉｄｉｄｅ）、メピコート・クロリド（ｍｅｐｉｑｕａｔ　ｃｈｌｏｒｉｄｅ）、ｎ－デシルアルコール（ｎ－ｄｅｃａｎｏｌ）、パクロブトラゾール（ｐａｃｌｏｂｕｔｒａｚｏｌ）、プロヘキサジオン・カルシウム塩（ｐｒｏｈｅｘａｄｉｏｎｅ－ｃａｌｃｉｕｍ）、プロヒドロジャスモン（ｐｒｏｈｙｄｒｏｊａｓｍｏｎ）、シントフェン（ｓｉｎｔｏｆｅｎ）、チジアズロン（ｔｈｉｄｉａｚｕｒｏｎ）、トリアコンタノール（ｔｒｉａｃｏｎｔａｎｏｌ）、トリネキサパック・エチル（ｔｒｉｎｅｘａｐａｃ－ｅｔｈｙｌ）、ウニコナゾール（ｕｎｉｃｏｎａｚｏｌｅ）、ウニコナゾール－Ｐ（ｕｎｉｃｏｎａｚｏｌｅ－Ｐ）、４－オキソ－４－（２－フェニルエチル）アミノ酪酸（化学名、ＣＡＳ登録番号：１０８３－５５－２）、過酸化カルシウム。 [Plant growth regulating active ingredient]
1-methylcyclopropene, 1-naphthylacetamide, 2,6-diisopropylnaphthalene, 2-CPA (4-chlorophenoxyacetic acid), benzylaminopurine (1) Benzylaminopurine, ancymidol, abiglycine, carbonone, chlormequat, clopropop, cloxyphonac, cloxyfonac, cloxyhonac. Cyclanilide, Cytokinins, Daminozide, Dikegulac, Dimethipin, Ethephonlueflef, Ethephonluefref, Epotheluf, Epotheluf, Epocholefrue, Epocholefrue, Epocholef, Epothele, Epothele, Epothele, Epothele, Epothele, Epothele, Epothele, Epothele, Epochleol Flurprimidol, forchlorfenuron, gibberellins, inabenfide, indole acetic acid, indolehydric acid, indoleidemic acid, indolehydric acid. Mefluidide, mepiquat chloride, n-decyl alcohol, n-decanol, paclobutrazol, prohexadione-calcium, prohydrojamon, prohydrojasmon, prohydrojamon. Sintofen, thidiazuron, triacontanol, trinexapac-ethyl, uniconazole, uniconazole-P, 4-oxo-4-(4-oxo-4) -Phenylethyl)ami Nobutyric acid (chemical name, CAS registration number: 1083-55-2), calcium peroxide.
　これら造粒物の中でも担体を押し出し造粒したものが好ましい。 Of these granules, those obtained by extruding a carrier and granulating are preferable.
　造粒物の大きさや形状は特に限定されないが、例えば、０．３～１０ｍｍ、好ましくは０．８～２ｍｍで、形状は粒状、柱状、円柱状、略円柱状、球状、略球状、楕球状、不定形状等、好ましくは略球状、粒状である。 The size or shape of the granulated product is not particularly limited, but is, for example, 0.3 to 10 mm, preferably 0.8 to 2 mm, and the shape is granular, columnar, columnar, substantially cylindrical, spherical, substantially spherical, ellipsoidal. , Irregular shape, etc., preferably substantially spherical or granular.
　造粒物の特に好ましい態様としては、クレー、カオリナイト、ベントナイト、酸性白土、炭酸カルシウム、デンプン、硫酸アンモニウム、塩化カリウム、フュームドシリカ等の担体の１種または２種以上と水、必要により、補助剤、農薬活性成分を混練し、これを押し出し造粒で造粒したものを乾燥させた粒状のものが挙げられる。 As a particularly preferred embodiment of the granulated product, one or more carriers such as clay, kaolinite, bentonite, acid clay, calcium carbonate, starch, ammonium sulfate, potassium chloride, fumed silica and water, and if necessary auxiliary An example is a granular product obtained by kneading an agent and an agrochemical active ingredient, extruding and kneading the mixture, and drying the granulated product.
　本発明の農薬製剤は、造粒物を、縮合リン酸塩、水難溶性農薬活性成分およびバインダーで処理することにより製造できる。こうすることにより造粒物の表面に、縮合リン酸塩と水難溶性農薬活性成分を粒状（粉状）で担持させることができる。 The pesticide formulation of the present invention can be produced by treating the granulated product with a condensed phosphate, a poorly water-soluble pesticidal active ingredient and a binder. By doing so, the condensed phosphate and the poorly water-soluble pesticidal active ingredient can be supported in the form of particles (powder) on the surface of the granulated product.
　上記バインダーは、特に限定されないが、例えば、水、リグニンスルホン酸塩、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルアルコール／ビニルアルキルエーテル共重合体、ポリアクリルアミド、ポリビニルピロリドン、カルボキシメチルセルロース塩、メチルセルロース、エチルセルロース、エチルメチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ブドウ糖、乳糖、果糖、マニトール、蔗糖、可溶性デンプン、デキストリン、ゼラチン、コラーゲン、カゼイン、カゼイン石灰、キトサン、アラビアガム、キサンタンガム、トラガントガム、グアーガム、カラギーナン、アルギン酸またはその塩、ポリ（メタ）アクリル酸の塩またはエステル（それらの共重合体であるものを含む）、ポリ塩化ビニル、塩化ビニリデン、ポリ酢酸ビニル、ポリスチレン、エチレン／酢酸ビニル共重合体、酢酸ビニル／アクリル酸エステル共重合体、スチレン／イソプレンブロック共重合体、フェノール樹脂、常温で結晶化しない糖類、ポリエチレングリコール、ポリプロピレングリコール、ポリエチレンオキシド、ポリプロピレンオキシド、流動パラフィン、シリコーン、フタル酸エステル、アジピン酸エステル、動物油、植物油、鉱物油、植物系ワックス、動物系ワックス、鉱物系ワックス、石油系ワックス、合成ワックス、変性ワックス、バイオディーゼル、ポリカルボン酸型アニオン系界面活性剤、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルキルアリールエーテル、ポリオキシアルキレンアルキルエーテル硫酸塩、ポリオキシアルキレンアルキルエーテルリン酸塩、ポリオキシアルキレンアルキルアリールエーテル硫酸塩、ポリオキシアルキレンアルキルアリールエーテルリン酸塩からなる群から選ばれる１種または２種以上を含む液状物が挙げられる。これらバインダーの中でも、流動パラフィン、フタル酸エステル、アジピン酸エステルが好ましく、流動パラフィンがより好ましい。これらバインダーは本発明の農薬製剤に０.５～１５.０％、好ましくは１.０～１０.０％で含有させればよい。 The binder is not particularly limited, for example, water, lignin sulfonate, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl alcohol/vinyl alkyl ether copolymer, polyacrylamide, polyvinyl pyrrolidone, carboxymethyl cellulose salt, methyl cellulose, ethyl cellulose, ethyl. Methylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, glucose, lactose, fructose, mannitol, sucrose, soluble starch, dextrin, gelatin, collagen, casein, casein lime, chitosan, gum arabic, xanthan gum, tragacanth gum, guar gum, carrageenan, alginic acid or its Salts, salts or esters of poly(meth)acrylic acid (including those which are copolymers thereof), polyvinyl chloride, vinylidene chloride, polyvinyl acetate, polystyrene, ethylene/vinyl acetate copolymers, vinyl acetate/acrylic Acid ester copolymer, styrene/isoprene block copolymer, phenol resin, sugars that do not crystallize at room temperature, polyethylene glycol, polypropylene glycol, polyethylene oxide, polypropylene oxide, liquid paraffin, silicone, phthalic acid ester, adipic acid ester, animal oil , Vegetable oil, mineral oil, vegetable wax, animal wax, mineral wax, petroleum wax, synthetic wax, modified wax, biodiesel, polycarboxylic acid type anionic surfactant, polyoxyalkylene alkyl ether, polyoxyalkylene 1 type or 2 types selected from the group consisting of alkyl aryl ether, polyoxyalkylene alkyl ether sulfate, polyoxyalkylene alkyl ether phosphate, polyoxyalkylene alkyl aryl ether sulfate, and polyoxyalkylene alkyl aryl ether phosphate. A liquid substance containing the above is mentioned. Among these binders, liquid paraffin, phthalic acid ester and adipic acid ester are preferable, and liquid paraffin is more preferable. These binders may be contained in the agricultural chemical preparation of the present invention in an amount of 0.5 to 15.0%, preferably 1.0 to 10.0%.
　造粒物を、縮合リン酸塩、水難溶性農薬活性成分およびバインダーで処理する方法としては、特に限定されないが、例えば、造粒物をバインダーで処理した後、縮合リン酸塩と水難溶性農薬活性成分で処理する方法、造粒物を、縮合リン酸塩と水難溶性農薬活性成分とを含むバインダーで処理する方法等が挙げられる。これらの方法の中でも造粒物をバインダーで処理した後、縮合リン酸塩と水難溶性農薬活性成分で処理する方法が好ましい。なお、上記方法において、界面活性剤を用いる場合には、縮合リン酸塩と水難溶性農薬活性成分と共に用いることが好ましい。 The method of treating the granulated product with a condensed phosphate, a sparingly water-soluble pesticidal active ingredient and a binder is not particularly limited, but, for example, after the granulated product is treated with a binder, the condensed phosphate and a sparingly water-soluble pesticidal activity are used. Examples thereof include a method of treating with a component and a method of treating the granulated product with a binder containing a condensed phosphate and a poorly water-soluble pesticide active ingredient. Among these methods, the method of treating the granulated product with a binder and then treating with a condensed phosphate and a poorly water-soluble pesticide active ingredient is preferable. In the above method, when a surfactant is used, it is preferable to use it together with a condensed phosphate and a poorly water-soluble pesticide active ingredient.
　具体的に、造粒物をバインダーで処理した後、縮合リン酸塩と水難溶性農薬活性成分で処理する方法では、８０～９９部、好ましくは８５～９５部の造粒物と、バインダーを０.５～１９.０部、好ましくは１.０～１０.０部を混合し、造粒物を湿潤させた後、縮合リン酸塩０.０５～５.０部、好ましくは０.１～２.０部、水難溶性農薬活性成分０.０５～５.０部、好ましくは０.１～２.０部、必要により界面活性剤０.０１～２０.０部、好ましくは０.０５～１０．０部、その他の成分０.０１～２０.０部、好ましくは０.０５～１０．０部を予め混合したものと混合するか、造粒物を湿潤させた後、縮合リン酸塩、水難溶性農薬活性成分、必要により界面活性剤、その他の成分を適宜添加して混合すればよい。 Specifically, in the method in which the granulated product is treated with the binder and then the condensed phosphate and the poorly water-soluble pesticidal active ingredient are used, 80 to 99 parts, preferably 85 to 95 parts of the granulated product and the binder are used. After mixing 0.5 to 19.0 parts, preferably 1.0 to 10.0 parts and moistening the granulated material, condensed phosphate 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts, poorly water-soluble pesticidal active ingredient 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts, if necessary a surfactant 0.01 to 20.0 parts, preferably 0.05 to 10.0 parts and other components, 0.01 to 20.0 parts, preferably 0.05 to 10.0 parts are mixed with a premixed product, or after moistening the granulated product, condensed phosphate , A poorly water-soluble pesticide active ingredient, a surfactant if necessary, and other ingredients may be appropriately added and mixed.
　また、具体的に造粒物を、縮合リン酸塩と水難溶性農薬活性成分とを含むバインダーで処理する方法では、０.５～１９．０部、好ましくは１．０～１０．０部のバインダーに、０．０５～５．０部、好ましくは０．１～２．０部の縮合リン酸塩と０．０５～５．０部、好ましくは０．１～２．０部の水難溶性農薬活性成分、必要により界面活性剤０．０１～２０．０部、好ましくは０．０５～１０．０部、その他の成分０．０１～２０．０部、好ましくは０．０５～１０．０部を混合させた後、これを８０～９９部、好ましくは８５～９５部の造粒物と混合すればよい。 Further, specifically, in the method of treating the granulated product with a binder containing a condensed phosphate and a sparingly water-soluble pesticide active ingredient, 0.5 to 19.0 parts, preferably 1.0 to 10.0 parts 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts of condensed phosphate and 0.05 to 5.0 parts, preferably 0.1 to 2.0 parts of poor water solubility in binder Pesticide active ingredient, if necessary surfactant 0.01 to 20.0 parts, preferably 0.05 to 10.0 parts, other ingredients 0.01 to 20.0 parts, preferably 0.05 to 10.0 After mixing the parts, this may be mixed with 80 to 99 parts, preferably 85 to 95 parts of the granulated product.
　上記のようにして造粒物を、縮合リン酸塩、水難溶性農薬活性成分およびバインダーで処理した後は、更に、除粉等の処理を行ってもよい。 After treating the granulated product with the condensed phosphate, the sparingly water-soluble pesticidal active ingredient and the binder as described above, further treatment such as powder removal may be performed.
　斯くして得られる本発明の農薬製剤は、縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されたものとなる。本発明の農薬製剤が縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されているかどうかは、例えば、走査型電子顕微鏡等で確認することができる。 The thus-obtained pesticide formulation of the present invention has the condensed phosphate and the sparingly water-soluble pesticide active ingredient supported on the surface of the granulated product. Whether the condensed phosphate and the sparingly water-soluble pesticidal active ingredient of the pesticide formulation of the present invention are carried on the surface of the granulated product can be confirmed by, for example, a scanning electron microscope.
　本発明の農薬製剤は、水難溶性農薬活性成分の溶解速度が向上するという性質を有し、速やかに保護対象たる栽培植物や防除対象たる有害生物に送達できることから、そのまま処理対象へ散布することができる。具体的に本発明の農薬製剤は、育苗箱等への箱処理や畑や水田に用いることができるが、育苗箱等への箱処理に用いることが好ましい。 The pesticide formulation of the present invention has a property that the dissolution rate of a poorly water-soluble pesticidal active ingredient is improved, and since it can be rapidly delivered to a cultivated plant to be protected or a pest to be controlled, it can be directly sprayed to a treatment target. it can. Specifically, the pesticide formulation of the present invention can be used for box treatment for seedling raising boxes and the like and for fields and paddy fields, but is preferably used for box treatment for seedling raising boxes and the like.
　具体的に、本発明の農薬製剤で箱処理を行う場合、例えば、育苗箱１ｍ２あたり、本発明の農薬製剤６０～６００ｇ、好ましくは１００～３００ｇを散粒機等の適当な施薬機で機械散布すればよい。また、本発明の農薬製剤を畑や水田に拡散させる場合、圃場１０アールあたり、本発明の農薬製剤０．１～１０ｋｇ、好ましくは１～４ｋｇを背負式動力散布等の適当な散布機で機械散布すればよい。 When carrying out box treatment with the pesticide formulation of the present invention, for example, 60 to 600 g, preferably 100 to 300 g of the pesticide formulation of the present invention per 1 m 2 of a nursery box is machined by an appropriate drug dispenser such as a granulator. Just scatter. When the agricultural chemical formulation of the present invention is diffused in a field or a paddy field, 0.1 to 10 kg, preferably 1 to 4 kg of the agricultural chemical formulation of the present invention per 10 ares of a field is machined by an appropriate spreader such as a backpack type power sprayer. Just scatter.
　以下、本発明を実施例を挙げて詳細に説明するが、本発明はこれら実施例に何ら限定されるものではない。 Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to these examples.
製造例１
　変性リグニンスルホン酸ナトリウム（商品名「パールレックス（登録商標）ＤＰ」、日本製紙株式会社製）１０部、アルキルアリールスルホン酸塩（商品名「ニューカルゲンＢＸ－Ｃ」、竹本油脂株式会社製）５部、沈降性シリカ（商品名「カープレックス（登録商標）＃８０」、ＤＳＬ．ジャパン株式会社製）４部、硅砂４部、クレー１０．５部を混合し、気流式粉砕して、粉体を得た。 Production example 1
Modified sodium lignin sulfonate (trade name "Pearlex (registered trademark) DP", manufactured by Nippon Paper Industries Co., Ltd.) 10 parts, alkylaryl sulfonate (trade name "New Cargen BX-C", manufactured by Takemoto Yushi Co., Ltd.) 5 Part, precipitated silica (trade name "Carplex (registered trademark) #80", manufactured by DSL Japan Co., Ltd.), 4 parts, silica sand 4 parts, and clay 10.5 parts, and mixed by airflow type powder to obtain powder. Got
製造例２
　ポリオキシエチレンアルキルエーテル硫酸塩（商品名「ハイテノール（登録商標）ＮＦ－１３」、第一工業製薬株式会社製）０．２部、アルファー化澱粉（商品名「アミコール（登録商標）Ｋ」、日澱化学株式会社製）３部およびクレー９６．８部を混合し、所定量の水を加えて混練し、孔径１．２ｍｍの穴を開けたスクリーンから押し出し、乾燥して、粒状の造粒物を得た。 Production example 2
0.2 parts of polyoxyethylene alkyl ether sulfate (trade name "Hitenol (registered trademark) NF-13", manufactured by Daiichi Kogyo Seiyaku Co., Ltd.), pregelatinized starch (trade name "Amicol (registered trademark) K", 3 parts of Nippon Starch Chemical Co., Ltd.) and 96.8 parts of clay are mixed, a predetermined amount of water is added and kneaded, and the mixture is extruded from a screen having a hole having a hole diameter of 1.2 mm, dried and granulated into granules I got a thing.
実施例１
　製造例１の粉体３３．５部とクロラントラニリプロール５１．５部およびトリポリリン酸ナトリウム１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコ（登録商標）ホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、クロラントラニリプロールとトリポリリン酸ナトリウムを造粒物の表面に担持させた農薬粒状組成物を得た。 Example 1
33.5 parts of the powder of Production Example 1, 51.5 parts of chlorantraniliprole and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco (registered trademark) White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Then, 2.4 parts of clay was added to the mixture and mixed, and further 1.6 parts of the premix was added and mixed to load chlorantraniliprole and sodium tripolyphosphate on the surface of the granulated product. A granular pesticide composition was obtained.
実施例２
　製造例１の粉体３３．５部とフェンキノトリオン５１．５部およびトリポリリン酸ナトリウム１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、フェンキノトリオンとトリポリリン酸ナトリウムを造粒物の表面に担持させた農薬粒状組成物を得た。 Example 2
33.5 parts of the powder of Production Example 1, 51.5 parts of phenquinotrione and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to prepare a pesticide granular composition having phenquinotrione and sodium tripolyphosphate supported on the surface of the granulated product. Obtained.
実施例３
　製造例１の粉体３３．５部とベンチアバリカルブイソプロピル５１．５部およびトリポリリン酸ナトリウム１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、ベンチアバリカルブイソプロピルとトリポリリン酸ナトリウムを造粒物の表面に担持させた農薬粒状組成物を得た。 Example 3
A premix was obtained by mixing 33.5 parts of the powder of Production Example 1, 51.5 parts of bench avalycarb isopropyl, and 15 parts of sodium tripolyphosphate. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix, and then mixed with bench avaricarb isopropyl and sodium tripolyphosphate on the surface of the granulated product. I got a thing.
実施例４
　製造例１の粉体３３．５部とイミダクロプリド５１．５部およびトリポリリン酸ナトリウム１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、イミダクロプリドとトリポリリン酸ナトリウムを造粒物の表面に担持させた農薬粒状組成物を得た。 Example 4
33.5 parts of the powder of Production Example 1, 51.5 parts of imidacloprid and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product, and then the mixture 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain an agricultural chemical granular composition in which imidacloprid and sodium tripolyphosphate were supported on the surface of the granulated product. ..
実施例５
　製造例１の粉体３３．５部とテトラニリプロール５１．５部およびトリポリリン酸ナトリウム１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物８９．５部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）５．４部を混合して造粒物の表面を湿潤させた後、該混合物に炭酸カルシウム２部を加えて混合し、更に前記プレミックス３．１部を加えて混合することにより、テトラニリプロールとトリポリリン酸ナトリウムを造粒物の表面に担持させた農薬粒状組成物を得た。 Example 5
33.5 parts of the powder of Production Example 1, 51.5 parts of tetraniliprole and 15 parts of sodium tripolyphosphate were mixed to obtain a premix. Next, 89.5 parts of the granulated product of Production Example 2 and 5.4 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Thereafter, 2 parts of calcium carbonate was added to the mixture and mixed, and further 3.1 parts of the premix was added and mixed to give tetraniliprole and sodium tripolyphosphate on the surface of the granulated product. A composition was obtained.
比較例１
　製造例１の粉体３３．５部とクロラントラニリプロール５１．５部およびクレー１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、クロラントラニリプロールを造粒物の表面に担持させた農薬粒状組成物を得た。 Comparative Example 1
A premix was obtained by mixing 33.5 parts of the powder of Production Example 1, 51.5 parts of chlorantraniliprole and 15 parts of clay. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition having chlorantraniliprole supported on the surface of the granulated product. ..
比較例２
　製造例１の粉体３３．５部とフェンキノトリオン５１．５部およびクレー１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、フェンキノトリオンを造粒物の表面に担持させた農薬粒状組成物を得た。 Comparative example 2
33.5 parts of the powder of Production Example 1, 51.5 parts of phenquinotrione and 15 parts of clay were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition in which phenquinotrione was supported on the surface of the granulated product.
比較例３
　製造例１の粉体３３．５部とベンチアバリカルブイソプロピル５１．５部およびクレー１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、ベンチアバリカルブイソプロピルを造粒物の表面に担持させた農薬粒状組成物を得た。 Comparative Example 3
A premix was obtained by mixing 33.5 parts of the powder of Production Example 1 with 51.5 parts of bench avalicarb isopropyl and 15 parts of clay. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product, and then the mixture 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain a pesticide granular composition in which bench avaricarb isopropyl was carried on the surface of the granulated product. ..
比較例４
　製造例１の粉体３３．５部とイミダクロプリド５１．５部およびクレー１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物９０部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）６部を混合して造粒物の表面を湿潤させた後、該混合物にクレー２．４部を加えて混合し、更に前記プレミックス１．６部を加えて混合することにより、イミダクロプリドを造粒物の表面に担持させた農薬粒状組成物を得た。 Comparative Example 4
33.5 parts of the powder of Production Example 1, 51.5 parts of imidacloprid and 15 parts of clay were mixed to obtain a premix. Next, 90 parts of the granulated product of Production Example 2 and 6 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) are mixed to wet the surface of the granulated product, and then the mixture is mixed. 2.4 parts of clay was added to and mixed with 1.6 parts of the premix to obtain an agricultural chemical granular composition in which imidacloprid was supported on the surface of the granulated product.
比較例５
　製造例１の粉体３３．５部とテトラニリプロール５１．５部およびクレー１５部を混合して、プレミックスを得た。次いで、製造例２の造粒物８９．５部と流動パラフィン（商品名「モレスコホワイトＰ－３５０Ｐ」、株式会社ＭＯＲＥＳＣＯ製）５．４部を混合して造粒物の表面を湿潤させた後、該混合物に炭酸カルシウム２部を加えて混合し、更に前記プレミックス３．１部を加えて混合することにより、テトラニリプロールを造粒物の表面に担持させた農薬粒状組成物を得た。 Comparative Example 5
33.5 parts of the powder of Production Example 1, 51.5 parts of tetraniliprole and 15 parts of clay were mixed to obtain a premix. Next, 89.5 parts of the granulated product of Production Example 2 and 5.4 parts of liquid paraffin (trade name "Moresco White P-350P", manufactured by MORESCO Co., Ltd.) were mixed to wet the surface of the granulated product. Thereafter, 2 parts of calcium carbonate was added to the mixture and mixed, and further 3.1 parts of the premix was added and mixed to obtain a pesticide granular composition having tetraniliprole supported on the surface of the granulated product. It was
試験例１
　実施例１～５および比較例１～５の農薬粒状組成物１００ｍｇを秤取し、２０℃に調温した３度硬水７００ｍＬ中に投入した後、２０℃恒温にて静置した。経時的に採水を行い、所定時間後の農薬活性成分の水中濃度を下記条件による高速液体クロマトグラフィーにて定量した。結果を表１に示す。なお、いずれの農薬粒状組成物も水中で崩壊分散することはなく、試験終了に至るまで、水に投入する前の形状をそのまま維持した。 Test example 1
100 mg of the pesticidal granular compositions of Examples 1 to 5 and Comparative Examples 1 to 5 were weighed out, put into 700 mL of 3 degree hard water whose temperature was adjusted to 20° C., and then allowed to stand at 20° C. constant temperature. Water was collected over time, and the concentration of the agrochemical active ingredient in water after a predetermined time was quantified by high performance liquid chromatography under the following conditions. The results are shown in Table 1. It should be noted that none of the pesticide granular compositions disintegrated and dispersed in water, and the shape before being added to water was maintained as it was until the end of the test.
（高速液体クロマトグラフィー条件）
　下記の絶対検量線法により測定した。
カラム　　：表面を疎水基修飾した化学結合型多孔性球状シリカゲル充填カラム
カラム温度：４０℃
溶離液　　：アセトニトリル、メタノール、リン酸水溶液の混合液 (High performance liquid chromatography conditions)
It was measured by the following absolute calibration curve method.
Column: Chemical bonding type porous spherical silica gel packed column with surface modified with hydrophobic group Column temperature: 40°C
Eluent: A mixture of acetonitrile, methanol, phosphoric acid aqueous solution
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
　実施例１～５の農薬粒状組成物は、縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されているため、水難溶性農薬活性成分しか造粒物の表面に担持されていない比較例１～５の農薬粒状組成物と比較して、水中での溶解性が顕著に向上していた。 In the pesticidal granular compositions of Examples 1 to 5, since the condensed phosphate and the poorly water-soluble pesticidal active ingredient are carried on the surface of the granulated product, only the poorly water-soluble pesticidal active ingredient is carried on the surface of the granulated product. The solubility in water was remarkably improved as compared with the pesticide granular compositions of Comparative Examples 1 to 5 which were not prepared.
実施例６
　実施例１の農薬粒状組成物５０ｇを縦３０ｃｍ×横６０ｃｍ育苗箱に施薬機を用いて機械散布した。問題なく均一に散布できた。 Example 6
50 g of the pesticidal granular composition of Example 1 was mechanically sprayed into a nursery box having a length of 30 cm and a width of 60 cm using a chemical application machine. It could be sprayed evenly without any problems.
　本発明の農薬製剤は、水難溶性農薬活性成分の農業への利用を促進する。 The pesticide formulation of the present invention promotes utilization of a poorly water-soluble pesticide active ingredient for agriculture.

Claims (17)

  1. 　縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持されたことを特徴とする農薬製剤。 An agrochemical formulation characterized in that a condensed phosphate and a sparingly water-soluble agrochemical active ingredient are carried on the surface of a granulated product.
  2. 　更に、界面活性剤が担持されたものである請求項１記載の農薬製剤。 The pesticide formulation according to claim 1, further comprising a surfactant.
  3. 　縮合リン酸塩が、トリポリリン酸ナトリウムである請求項１または２記載の農薬製剤。 The agricultural chemical preparation according to claim 1 or 2, wherein the condensed phosphate is sodium tripolyphosphate.
  4. 　水難溶性農薬活性成分が、２０℃の水中で溶解度が１００ｐｐｍ以下の農薬活性成分である請求項１～３の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 3, wherein the poorly water-soluble pesticide active ingredient has a solubility of 100 ppm or less in water at 20°C.
  5. 　造粒物が農薬活性成分を含むものである請求項１～４の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 4, wherein the granulated product contains a pesticide active ingredient.
  6. 　水難溶性農薬活性成分が、殺虫剤および／または殺菌剤である請求項１～５の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 5, wherein the poorly water-soluble pesticide active ingredient is an insecticide and/or a bactericide.
  7. 　造粒物が、担体を造粒したものである請求項１～６の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 6, wherein the granulated product is a granulated carrier.
  8. 　造粒が、押し出し造粒である請求項７記載の農薬製剤。 The pesticide formulation according to claim 7, wherein the granulation is extrusion granulation.
  9. 　造粒物が、非崩壊性のものである請求項１～８の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 8, wherein the granulated product is non-disintegrating.
  10. 　箱処理用である請求項１～９の何れかに記載の農薬製剤。 The pesticide formulation according to any one of claims 1 to 9, which is for box processing.
  11. 　造粒物を、縮合リン酸塩、水難溶性農薬活性成分およびバインダーで処理することを特徴とする縮合リン酸塩と水難溶性農薬活性成分が、造粒物の表面に担持された農薬製剤の製造方法。 Production of an agrochemical formulation in which a condensed phosphate and a sparingly water-soluble pesticidal active ingredient are treated on the surface of the granulated product, which is characterized by treating the granulated material with a condensed phosphate, a sparingly water-soluble pesticidal active ingredient and a binder. Method.
  12. 　造粒物をバインダーで処理した後、縮合リン酸塩と水難溶性農薬活性成分で処理するものである請求項１１記載の農薬製剤の製造方法。 The method for producing a pesticide formulation according to claim 11, wherein the granulated product is treated with a binder and then treated with a condensed phosphate and a sparingly water-soluble pesticide active ingredient.
  13. 　縮合リン酸塩と水難溶性農薬活性成分と共に、界面活性剤を用いるものである請求項１１または１２記載の農薬製剤の製造方法。 The method for producing an agricultural chemical formulation according to claim 11 or 12, wherein a surfactant is used together with the condensed phosphate and the sparingly water-soluble agricultural chemical active ingredient.
  14. 　バインダーが、水、リグニンスルホン酸塩、ポリビニルアルコール、ポリビニルメチルエーテル、ポリビニルアルコール／ビニルアルキルエーテル共重合体、ポリアクリルアミド、ポリビニルピロリドン、カルボキシメチルセルロース塩、メチルセルロース、エチルセルロース、エチルメチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシプロピルメチルセルロース、ブドウ糖、乳糖、果糖、マニトール、蔗糖、可溶性デンプン、デキストリン、ゼラチン、コラーゲン、カゼイン、カゼイン石灰、キトサン、アラビアガム、キサンタンガム、トラガントガム、グアーガム、カラギーナン、アルギン酸またはその塩、ポリ（メタ）アクリル酸の塩またはエステル（それらの共重合体であるものを含む）、ポリ塩化ビニル、塩化ビニリデン、ポリ酢酸ビニル、ポリスチレン、エチレン／酢酸ビニル共重合体、酢酸ビニル／アクリル酸エステル共重合体、スチレン／イソプレンブロック共重合体、フェノール樹脂、常温で結晶化しない糖類、ポリエチレングリコール、ポリプロピレングリコール、ポリエチレンオキシド、ポリプロピレンオキシド、流動パラフィン、シリコーン、フタル酸エステル、アジピン酸エステル、動物油、植物油、鉱物油、植物系ワックス、動物系ワックス、鉱物系ワックス、石油系ワックス、合成ワックス、変性ワックス、バイオディーゼル、ポリカルボン酸型アニオン系界面活性剤、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルキルアリールエーテル、ポリオキシアルキレンアルキルエーテル硫酸塩、ポリオキシアルキレンアルキルエーテルリン酸塩、ポリオキシアルキレンアルキルアリールエーテル硫酸塩、ポリオキシアルキレンアルキルアリールエーテルリン酸塩からなる群から選ばれる１種または２種以上を含む液状物である請求項１１～１３の何れかに記載の農薬製剤の製造方法。 The binder is water, lignin sulfonate, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl alcohol/vinyl alkyl ether copolymer, polyacrylamide, polyvinyl pyrrolidone, carboxymethyl cellulose salt, methyl cellulose, ethyl cellulose, ethyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl. Methylcellulose, glucose, lactose, fructose, mannitol, sucrose, soluble starch, dextrin, gelatin, collagen, casein, casein lime, chitosan, gum arabic, xanthan gum, tragacanth gum, guar gum, carrageenan, alginic acid or its salt, poly(meth)acrylic acid Salts or esters (including those which are copolymers thereof), polyvinyl chloride, vinylidene chloride, polyvinyl acetate, polystyrene, ethylene/vinyl acetate copolymers, vinyl acetate/acrylic ester copolymers, styrene/ Isoprene block copolymer, phenol resin, sugar that does not crystallize at room temperature, polyethylene glycol, polypropylene glycol, polyethylene oxide, polypropylene oxide, liquid paraffin, silicone, phthalate ester, adipate ester, animal oil, vegetable oil, mineral oil, plant system Wax, animal wax, mineral wax, petroleum wax, synthetic wax, modified wax, biodiesel, polycarboxylic acid type anionic surfactant, polyoxyalkylene alkyl ether, polyoxyalkylene alkyl aryl ether, polyoxyalkylene alkyl A liquid material containing one or more selected from the group consisting of ether sulfates, polyoxyalkylene alkyl ether phosphates, polyoxyalkylene alkyl aryl ether sulfates, and polyoxyalkylene alkyl aryl ether phosphates. Item 14. A method for producing an agricultural chemical formulation according to any one of Items 11 to 13.
  15. 　造粒物として、担体を造粒したものを用いる請求項１１～１４の何れかに記載の農薬製剤の製造方法。 The method for producing an agrochemical formulation according to any one of claims 11 to 14, wherein a granulated carrier is used as the granulated material.
  16. 　造粒が、押し出し造粒である請求項１５記載の農薬製剤の製造方法。 The method for producing an agricultural chemical formulation according to claim 15, wherein the granulation is extrusion granulation.
  17. 　造粒物として、非崩壊性のものを用いる請求項１１～１６の何れかに記載の農薬製剤の製造方法。
          The method for producing an agrochemical formulation according to any one of claims 11 to 16, wherein a non-disintegrating granule is used as the granule.
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JP2009079000A (en) * 2007-09-26 2009-04-16 Kyoyu Agri Kk Agrochemical granule improved with elution property into water
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WO1988006842A1 (en) * 1987-03-13 1988-09-22 Sumitomo Chemical Company, Limited Stable solid pesticidal preparation
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