JP6501133B2 - Granular pesticide composition and method for producing the same - Google Patents

Description

  The present invention relates to an agricultural and horticulturally useful granular agricultural chemical composition containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide and a process for producing the same. In particular, the present invention relates to an agricultural and horticulturally useful particulate pesticide composition which is excellent in storage stability of the compound, and a method for producing the same.

  At present, as forms of agrochemical preparations, dosage forms such as powders, granules, wettable powders, water dispersible granules, flowables, solutions and emulsions are known. Among them, granules are a dosage form in which a pesticide preparation is directly sprayed, and are used in the aspect of water surface application in a paddy field, breeding box treatment, soil mixing in upland, and the like. It is a mainstream formulation in Japan because pesticide treatment is simple, it does not require water for spraying, and there is no concern about scattering of pesticide active ingredients due to dusting.

  In a general aspect of the particulate agrochemical composition used as granules, the agrochemical active ingredient and a solid carrier such as clay or calcium carbonate are mixed, water is added to the mixture obtained above, and the mixture is kneaded to obtain a predetermined pore size. After extrusion granulation using a die having, it is a granular material manufactured by drying. In such particulate matter, since the contact between the agrochemical active ingredient and the environmental moisture is limited, the dissolution behavior of the agrochemical active ingredient tends to be more controlled release, and the agrochemical activity for which sustainability of the effect is required Suitable for ingredients. Moreover, as another embodiment, there is also provided a granular agricultural chemical composition which is a granular material obtained by coating a pesticidally active component with a surface layer of a particle nucleus having a suitable particle size obtained by crushing or granulating mineral substances and the like. Are known. In such a particulate matter, since the agrochemical active ingredient is in direct contact with the environmental moisture, the agrochemical active ingredient can be eluted faster, and it is suitable for agrochemical active ingredient which requires a rapid action. Furthermore, there may also be an aspect of the latter particulate having the former particulate as a grain core. Those skilled in the art can select and appropriately select granules according to the elution pattern required for the agrochemical active ingredient to be blended.

  On the other hand, there are pests and weeds in addition to diseases as pest control targets in agricultural and horticulture in pesticide formulations, and it is necessary to cope with all of them, but the disease control active ingredient is specialized for disease control and And weeds do not show sufficient control activity. Similarly, pest control active ingredients and weed control active ingredients are specialized for pest control and weed control, respectively. Therefore, in modern agriculture, management of agricultural land, etc. is carried out by fully utilizing the disease control active ingredient for disease control, the pest control active ingredient for pest control, and the weed control active ingredient for weed control. There is. In addition, each disease control active ingredient has an effective disease and a disease that is considered to be weak. In order to cope with a large number of control objects occurring on agricultural land and the like, a large number of disease control active ingredients having different spectrums have been developed. The same applies to pest control active ingredients and weed control active ingredients. From such a background, in recent years, it is also practiced to use a plurality of granules mixed at the time of use, or to use a mixed pesticide granule in which a plurality of pesticide active ingredients are mixed in a single pesticide granule.

  3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide (hereinafter, the same substance may be referred to as “compound A” in the present specification) Is a known active ingredient for controlling agricultural and horticultural plant diseases, and it is known that it has a remarkable effect on plant diseases such as rice blast, wheat downy mildew, cucumber downy mildew and cucumber anthracnose. It is disclosed. Since Compound A is expected to control and prevent plant diseases over a long period required for the growth of agricultural products and the like, Compound A can be used as an embodiment in the case of formulating Compound A in granules. It is preferable to use as a granulated material which is kneaded into the particles together with a solid carrier and the like.

  However, since Compound A is a chemically somewhat unstable compound and the decomposition may be promoted unnecessarily in the presence of various chemical substances, the storage stability of Compound A in the particulate agrochemical composition is possible. Improvement was desired. In particular, in the case of the mixed pesticide granules in which Compound A and other pesticidal active ingredients are used in combination, the decomposition of Compound A may be further promoted, which may be a more disadvantageous obstacle, since a plurality of chemical substances intentionally coexist. It was difficult to develop a granular pesticide composition having excellent storage stability of Compound A without being affected by these chemicals.

WO 2007/129454

  Therefore, an object of the present invention is to provide an agriculturally and horticulturally useful particulate having excellent storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide. It is providing a pesticide composition and its manufacturing method.

  The present inventors are keen to develop a granular pesticide composition excellent in storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazol-1,1-dioxide As a result of investigation, it was found that the particulate pesticide composition having the outer layer part formed by using the above-mentioned compound in the grain core and using the saccharide which does not crystallize at normal temperature on the surface of the grain nucleus solves the above problem. Came to complete.

  That is, the present invention is as follows.

[1] A particulate agricultural chemical composition having a grain core and an outer layer part covering the grain core, wherein the grain core is 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzo A particulate agrochemical composition comprising thiazole-1,1-dioxide, and wherein the outer layer part contains liquid sugar which is a saccharide which does not crystallize at normal temperature.

[2] The granular agricultural chemical composition according to the above 1, wherein the grain core is a granulated product obtained by an extrusion granulation method.

[3] The granular pesticide composition according to 1 or 2, wherein the liquid sugar is a converted liquid sugar containing reducing sugar.

[4] The granular pesticide composition according to any one of [1] to [3], wherein the content of the liquid sugar is 0.5 to 5% by mass with respect to the whole particulate pesticide composition.

[5] The particulate agrochemical composition according to any one of the above 1 to 4, further comprising an agrochemical active ingredient supported on the outer layer portion.

[6] The granular agricultural chemical composition according to any one of the above 1 to 5, wherein the grain core is substantially cylindrical and the cross-sectional circular diameter is 0.3 to 1.7 mm.

[7] In the method for producing a granular pesticide composition according to any one of 1 to 6 above, 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazol-1,1-dioxide A step of producing a grain core containing L, and the surface of the grain core obtained in the above step is covered with a liquid substance containing liquid sugar which is a saccharide which does not crystallize at normal temperature, and an outer layer is formed on the surface of the grain core Forming a part, and a method of producing a particulate pesticide composition.

[8] The manufacturing method of the granular agrochemical composition of the said 7 which has a process which further carries an agrochemical active ingredient on the said outer layer part after the process of forming the said outer layer part.

  According to the present invention, an agricultural and horticulturally useful granular pesticide composition having excellent storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide Articles and methods for their manufacture.

  The particulate agrochemical composition of the present invention is a particulate agrochemical composition having a grain core and an outer layer part covering the grain core, wherein the grain nucleus is 3- (3,4-dichloroisothiazol-5-ylmethoxy) And -1, 2-benzothiazole-1, 1-dioxide, and the said outer-layer part contains liquid sugar which is saccharides which do not crystallize at normal temperature. The granular agrochemical composition of the present invention suppresses the decomposition of the compound due to the presence of the liquid sugar-containing outer layer, and is excellent in storage stability. Moreover, the granular agrochemical composition of this invention can be used, without impairing the storage stability of the said compound A, also when using it as an agrochemical granule mixed with another agrochemical active ingredient. In the conventional granular pesticide composition, even if the particle core comprising compound A is coated with other pesticidal active ingredients using a conventional binder, there is relatively little chance of contact of compound A with other pesticidal active ingredients. Nevertheless, the storage stability of Compound A was significantly degraded.

  In the particulate pesticide composition of the present invention, it is important that the compound A be contained in the grain nuclei. The content of the compound A is not particularly limited, but is preferably 0.1 to 8% by mass, and more preferably 0.2 to 4% by mass with respect to the whole particulate agrochemical composition.

  The particle nucleus containing compound A uses, for example, compound A as a mixture with a finely divided solid carrier, and the mixture is subjected to a stirring mixing granulation method, a tumbling granulation method, an extrusion granulation method, a crushing granulation method, a fluidized bed structure It manufactures by using as granulation thing by well-known granulation methods, such as a granule method, a compression granulation method, and a vacuum-drying granulation method.

  Specific examples of the finely divided solid carrier include bentonite, clay, kaolin, sericite, talc, acid clay, pumice, zeolite, vermiculite, perlite, calcium carbonate, silica sand and the like. These may be optionally used singly or in combination of two or more.

  Although the granulation method of the said grain nucleus is not specifically limited, When making an outer layer part of a grain nucleus carry an agrochemical active ingredient, the grain nucleus surface area which determines the amount of agrochemical active ingredients which can carry in each grain nucleus A granulation method is preferable which can obtain a granulated product having a small fluctuation in particle size distribution, that is, a narrow particle size distribution. The extrusion granulation method is particularly preferable as a method suitable for this purpose, and it is preferable to use the granular material obtained by the extrusion granulation method as a particle core.

  The shape of the grain core is not particularly limited, but a granular material having a particle size suitable as a pesticide grain is preferable, and more specifically, a substantially spherical material having a diameter of 0.1 to 30 mm, or a volume sphere equivalent diameter of 0.1 to 10 An amorphous material of 30 mm, and a substantially cylindrical product having a diameter of 0.1 to 5 mm, a length of 1 to 30 mm, and an aspect ratio (length / diameter) of 1 to 10 can be suitably used. Among them, a substantially cylindrical material having a diameter of 0.3 to 1.7 mm, a length of 0.3 to 10.2 mm, and an aspect ratio of 1 to 6 is preferable, and a diameter of 0.5 to 1.5 mm and a length of 0.5 to 7 A substantially cylindrical article having an aspect ratio of 1 to 5 mm is more preferable, and a substantially cylindrical article having a diameter of 0.8 to 1.2 mm, a length of 0.8 to 4.8 mm, and an aspect ratio of 1 to 4 is more preferable.

  The grain nuclei may optionally contain auxiliary components such as surfactants, binders, lubricants and colorants. Furthermore, in the particulate agrochemical composition of the present invention, if desired, the release control of a safener, wax, resin, hydrophobic substance and the like in the particle nucleus is carried out as long as the stability of the compound A is not impaired. An agent may be contained.

  Examples of the surfactant include alkyl sulfate salts, aryl sulfonates, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkyl sulfosuccinates, polycarboxylic acids, polyoxyethylene nonylphenyl ether, lignin sulfonate sodium Etc. These may be optionally used singly or in combination of two or more.

  Examples of the binder include starch, alginic acid, glycerin, polyvinyl pyrrolidone, polyurethane, polyethylene glycol, polypropylene glycol, polybutene, polyvinyl alcohol, gum arabic, liquid paraffin, ethyl cellulose, polyvinyl acetate and the like. These may be optionally used singly or in combination of two or more.

  Examples of the lubricant include calcium stearate, talc, silica and the like. These may be optionally used singly or in combination of two or more.

  Examples of the colorant include dyes and pigments. These may be optionally used singly or in combination of two or more.

  Examples of the safeners include benoxacor, berilazole (furilazole), dichlormid (dichlormid), dicyclonone (dicyclonone), DKA-24 (N1, N2-diallyl-N2-dichloroacetylglycinamide), AD-67 (4) -Dichloroacetyl-1-oxa-4-azaspiro [4.5] decane), PPG-1292 (2,2-dichloro-N- (1,3-dioxane-2-ylmethyl) -N- (2-propenyl) Acetamide), R-29 148 (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine), cloquintoset-mexyl (cloquintcet-mexyl), naphthalic anhydride (1,8-Naphthalic Anhydri) e) Mefenpyr-diethyl, mefenpyr, mefenpyr-ethyl, fenchlorazole-O-ethyl, fenclorim, MG-191 (2) -Dichloromethyl-2-methyl-1,3-dioxane), ciometrinyl (cyometrinil), flurazole (flurazole), fluxophenim (fluxofenim), isoxadifen (isoxadifen), isoxadifen-ethyl (isoxadifen-ethyl), MON 4660 (code number), Oxabetrinil (oxabetrinil), cyprosulfamide (cyprosul (lower), lower alkyl substituted benzoic acid, TI-35 (code number) or N- (2-methoxybenzoyl) -4-[(methylaminocarbonyl) amino] benzenesulfonamide (chemical name, CAS registration number: 129531-12) -0) and the like. These can be used singly or in combination of two or more.

  It is also important that the granular agricultural chemical composition of the present invention contains liquid sugar, which is a saccharide that does not crystallize at normal temperature, in the outer layer part covering the above-mentioned grain core containing Compound A. Here, liquid sugar is generally called molasses. Types of the liquid sugar include sugar molasses molasses, beet molasses molasses, refined sugar final molasses, glacial molasses and invert sugar containing reducing sugar such as sucrose, which is produced in the sugar manufacturing process, such as sucrose hydrolysed to glucose and fructose Examples of sugars and non-reducing sugars such as sucrose include those containing invert sugar, and preferred are invert sugars containing reducing sugars, that is, inverted liquid sugars containing reducing sugars. Among the invert type liquid sugars, those containing 20% or more of reducing sugars are preferable, and those containing 40% or more of reducing sugars are more preferable, and about 50%, specifically 45 to 54% containing reducing sugars. Liquid sugar is particularly preferred.

  The content of the liquid sugar is not particularly limited, and it depends on the amount of the agrochemical active ingredient to be supported on the grain nuclei, but preferably 0.5 to 5% by mass with respect to the whole particulate agrochemical composition, Preferably it is 0.8-2 mass%. If the content of the liquid sugar is insufficient, there is a possibility that the storage stability of the compound A may be impaired, or the function of supporting the agrochemical active ingredient in the particle nucleus outer layer part may be insufficient when used as a mixed agrochemical granule. On the other hand, if the content of liquid sugar is excessive, caking of the granular pesticide composition is concerned.

  In the particulate agrochemical composition of the present invention, the method of forming the outer layer portion containing liquid sugar is not particularly limited, but typically, first, grain kernels are mixed using a common mixer such as a concrete mixer or nauta mixer. While, a liquid substance containing liquid sugar is added to this to coat the surface layer of the grain core. When the particulate agrochemical composition of the present invention is used as a mixed agrochemical granule, the agrochemical active ingredient may then be added and supported on the grain outer core part.

  By the way, since the above-mentioned liquid sugar is usually a honey-like viscous liquid at normal temperature, it may be difficult in the step of covering the liquid substance containing this liquid sugar on the surface layer of the grain core. As a means to solve this point, a method of heating the liquid to lower the viscosity of the liquid sugar, a method of adding a slight amount of a solvent such as water to the liquid sugar, and the like to lower the viscosity of the liquid sugar be able to. When water is added to liquid sugar to make a liquid, the addition amount of water is not particularly limited, but it is appropriate to set the amount to about 30% by mass with respect to the total amount of liquid. If the liquid composition has an excessive amount of water, that is, a dilute liquid composition, it is necessary to add a large amount of liquid to coat the grain nuclei with an effective amount of liquid sugar, and the excess water agglomerates the grain nuclei wet with each other. When the agrochemical active ingredient is carried on the outer layer portion in order to use the particulate agrochemical composition of the present invention as a mixed agrochemical granule, problems may occur in the step of carrying the agrochemical active ingredient.

  In the particulate agrochemical composition of the present invention, the agrochemical active ingredient can be further contained by being carried on the outer layer portion. Only one kind of agricultural chemical active ingredient can be carried on the outer layer part, or two or more kinds can be carried simultaneously. The agrochemical active ingredient can be supported on the outer layer portion of the grain core by the adhesion of liquid sugar.

  When the agrochemical active ingredient to be supported on the outer layer part is solid at normal temperature, it is desirable to use it as a powder after finely pulverizing to a particle size of usually 50 μm or less, preferably 10 μm or less. In addition, the powder includes grinding aids such as silica, diatomaceous earth, silica sand, surfactants such as lignin sulfonate, aryl sulfonate, alkyl sulfate, solid carriers such as bentonite, clay, calcium carbonate, alkali Auxiliary agents such as stabilizers such as metal salts, alkaline earth metal salts, epoxidized fats and oils, and the above-mentioned safeners can be blended.

  As means for finely pulverizing the agrochemical active ingredient to be supported on the outer layer, any known pulverizer can be used. Specifically, an impact crusher, a pneumatic crusher, a wet crusher or the like may be used. There is no particular limitation. Moreover, in the case of the said pulverization, you may grind | pulverize only with an agrochemical active component, and it may mix with the said adjuvant previously and co-grind if desired.

  When the agrochemical active ingredient to be supported on the outer layer portion is liquid at normal temperature, the liquid may be supported on the outer layer portion as it is, or it may be preliminarily absorbed on an oil absorbing fine powder such as silica, silicate, wood powder, microcrystalline cellulose and the like. The powder can be prepared by adsorption and handled in the same manner as the agrochemical active ingredient which is solid at the above normal temperature.

  The content of the agrochemical active ingredient which can be carried in the outer layer part is not limited either, but in the case of two or more kinds as the agrochemical active ingredient with respect to the whole particulate agrochemical composition, the total is usually 0 The content is from 0.5 to 5% by mass, preferably from 0.1 to 4% by mass, and more preferably from 0.5 to 3% by mass.

  In addition, one or two or more types of agrochemical active ingredients can be blended in the grain nuclei as long as the stability of the compound A is not impaired, but generally, the agrochemical active ingredients contained in the grain nuclei The dissolution rate of is expected to be relatively slow. When it is desired that the particulate agrochemical composition of the present invention contains an agrochemical active ingredient which is expected to exhibit a rapid drug efficacy, it is rational to select a design to be supported on the grain outer core part.

  In the particulate agrochemical composition of the present invention, examples of the agrochemical active ingredients which can be contained in the grain nuclei or supported in the outer layer portion include, for example, those listed below, but are not particularly limited.

[Herbicidal active ingredient]
Aioxynil (ioxynil), acronifene (aclonin), acrolein (acrolein), azaphenidin (azafenidin), acifluorfen (acifluorfen) (including salts with sodium etc.), azimlsulfuron (azimsulfuron), asulam, acetocloro (Acetochlor), atrazine (atrazine), anilophos (anilofos), amicarbazone (amicarbazone), amidosulfuron (amidosulfuron), amitrole (amitrole), aminocyclopyrachlor (aminocyclopyrachlor), aminopyralid (aminopyralid), amiprofos methyl (amip) ofos-methyl), ametrine (ametryn), alachlor (alachlor), alloxydim (alloxydim), isouron (isouron), isoxachlortol (isoxachlortole), isoxafultole (isoxaflate), isoxaben (isoxaben), isoproturon (isoproturon) ), Ipfencarbazone, imazaquin, imazapic (including salts with amines), imazapyr (including salts such as isopropylamine), imazamethabenz methyl (imazamethabenz-methyl). ), Imazamox (imazamox), Imazeta Le (imazethapyr), imazosulfuron (imazosulfuron), indazifram (indaziflam), indanofan (indanofan), eglinadine-ethyl (eglinazine-ethyl), esprocarb (esprocarb), etamethsulfuron-methyl, etalfurlaline ), Ethidimuron, ethoxysulfuron, ethoxyphen-ethyl, ethofumesate, etobenzanide, endothal disodium salt (endothal-diso). , oxadiazon (oxadiazon), oxadiclomefone (oxaziclomefone), oxasulfuron (oxasulfuron), oxyfluorfen (oxyfluorfen), oryzalin (oryzalin), orthosulfamuron (orthosulfamuron), orbencarb, orencarb Acid (oleic acid), cafentrol (cafenstrole), carfentrazone-ethyl, carbutrate (karbutilate), carbetamid (carbetamide), quizaroph (quizalofop-ethyl), quizarophop P. et al. (Quizalofop-p-ethyl), quizalohop p. Tefuryl (quizalofop-p- tefuryl), quinoclamine (quinoclamine), quinclorac, quinmerac, quiny curm, cumyluron, clacyfos, glyphosate (Glyphosate) (including salts such as sodium, potassium, ammonium, amines, propylamine, isopropylamine, dimethylamine or trimesium), glufosinate (including salts such as amines or sodium), glufosinate P sodium salt (Glufosinate-P-sodium), clethodim, black Nahopop propargyl (clodinafop-propargyl), clopyralid (clopyralid), clomazone (clomazone), clomethoxyphen (chlomethoxyphen), clomeprop (clomeprop), cloransulam methyl (cloransulam-methyl), chloramben (chloramben), chloridazon (chloridazon), Chlorimuron ethyl (chlorimuron-ethyl), chlorsulfuron (chlorsulfuron), chlorthal dimethyl (chlorothal-dimethyl), chlorthiamid (chlorthiamide), chlorophthalim (chloroththalim), chlorfurrenol methyl (ch orflurenol-methyl), chlorpropham (chlorpropham), chlorbromuron, chloroxuron, chlorotoluron, ketospiradox (containing salts such as sodium, calcium or ammonia), saflufenacil ( saflufenacil), salmentine (sarmentine), cyanazine (cyanazine), cyanamide (cyanamide), diuron (diuron), diethyl ethyl (diethatyl-ethyl), dicamba (amine, diethylamine, isopropylamine, diglycolamine, sodium or The (Including salts such as lithium), cycloate (cycloate), cycloxydim, diclosulam, cyclosulfamuron, cyclopyrimorate, cyclopyrimorate, diclobenil, diclohop-P-methyl ( diclofop-P-methyl), diclofop-methyl, dichlorprop, dichlorprop-p, diquat, dithiopyr, dithiopyr, siduron, dinitramine (Dinitramine), sinidon ethyl (cinidon ethyl), cinosulfuron (cinosulfuron), dinoseb, dinoterb, cyhalofop-butyl, diphenamide, diphenzoquat, diflufenican, diflufenzopyr, Simazine (simazine), dimethachlor (dimethachlor), dimethamethryn (dimethametryn), dimethenamid (dimethenamid), dimethenamid P (dimethenamid-P), simetryn (similarity), dimepiperate (dimepiperate), dimefuronate (dimefu) on, cinmethylin, swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfurate, sulfosulfuron, sulfometuron-methyl, cetoxidim sethoxydim), terbacil (terbacil), daimuron (daimuron), tachytomin A (thaxtomin A), dalapon (dalapon), thiazopyr (thiazopyr), thiafenacil (tiafenacil), thiencarbazone (including sodium salt, methyl ester etc.) , Thiocal basil tiocarbazil), thiobencarb, thidiazimin, thifensulfuron-methyl, desmedipham, desmetryne, thenylchlor, thetychlor, tebutiumon (tebutiulon) , Tepraloxydim, tefuryltrione, tembotrione, tembotrione, terbutylazine, terbutrin, terbumeton, topramezon (topramezon) e) Tralkoxydim, triaziflam, triasulfuron, triafamone, tri-allate, tri-etalate, triclozine, triclopyr, triclopyr-butytyl , Trifludimuxazin, tritosulfuron (tritosulfuron), triflusulfuron-methyl, triflurallin, trifloxysulfuron sodium salt (trifloxosulfuron-sodium), tribe Julen methyl (tribenuron-methyl), tolpyralate, naptalam (including salts with sodium etc.), naproanilide (naproanilide), napropamide (napropamide), napropamide-M (napropamide-M), nicosulfuron (Nicosulfuron), nebron (neburon), norflurazon (norflurazon), burnerate (vernolate), paraquat (paraquat), halxifene-benzyl (halauxifen-benzyl), halxifene-methyl (halauxifen-methyl), haloxyfop, haloxyfop. P (halo yfop-P), haloxifop-halt (haloxyfop-etotyl), halosaphene (halosafen), halosulfuron-methyl (halosulfuron-methyl), picloram (picloram), picorinaphen (picolinafen), bicyclopyrone (bicyclopyrone), bispyribac sodium salt ( bispyribac-sodium), pinoxaden, bifenox,
Piperophos, pyraclonil, pyrasulfotole, pyrazoxyfen, pyrazosulfurfur-ethyl, pyrazolynate, bilanaphos, biranafos, pyraflufen-ethyl, Pyridafol, pyrithiobac sodium salt, pyridate, pyriftalid, pyributicarb, pyribenzoxim, pyrimisulfan isulfan), pyriminobac-methyl, pyroxasulfone, pyroxsulfone, pyroxsulam, phenisopham, phenuron, fenoxasulfone, phenoxaprop (methyl, Ethyl, including isopropyl ester), fenoxaprop-P (including methyl, ethyl and isopropyl ester), fenquinotrione, fenthiaprop-ethyl, and fentrazamide ), Fen medifem phenmedipham), foramsulfuron (foramsulfuron), butachlor (butachlor), butaphenacil (butafenacil), butamifos (butamifos), butyrate (butylate), butenachlor (butenachlor), butraline (butralin), butroxydim (butroxydim), pharazsulfuron (falizasulfuron) ), Flamprop (including methyl, ethyl and isopropyl ester), flamprop and M (flamprop-M) (including methyl, ethyl and isopropyl ester), primisulfuron-methyl, fluazifop・ Butyl (fluazifo p-butyl), fluazifop-p-butyl, fluazolate, fluometuron, fluoroglycofen-ethyl, flucarbazone-sodium, fluchlorin (Fluchloralin), flucetosulfuron (flucetosulfuron), fluthiaset methyl (fluthiacet-methyl), flupyrsulfuron methyl sodium salt (flupyrsulfuron-methyl-sodium), flufenacet (flufenacet), flufenpyr-ethyl (flufenpyr- (flufenpyr-) eth l), flupropanate, flupoxame, flumioxazin, flumiclorac-penyl, flumetsulam, fluridone, flurtamone, fluroxypyr ), Flurochloridone, pretilachlor, procarbazone-sodium, prodiamine, prosulfuron, prosulfocarb, propaquihop propaquizafop), propachlor (propachlor), propadine (propazine), propanil (propanil), propyzamide (propyzamide), propisochlor (propisochlor), propyrisulfuron (propyrisulfuron), profam (propham), profluazole (profluazol), Propoxycarbazone sodium salt (propoxycarbazone-sodium), propoxydim (profoxydim), bromacil (bromacil), brompyrazone (brompyrazon), promethrin (prometryn), prometon (prometon), bromoxynil (bromoxynil) (butyric acid, ock Containing esters such as tannic acid or heptanoic acid), bromophenoxim, bromobutide, florasulam, florpyraxifen, hexaazinone, hexoxinone, petoxamide, benazoline benazolin), penoxsulam, heptamaloxyloglucan, beflubutamide, beblubutamid, pebulate, pelargonic acid, pélargonic acid, bencarbazone, bencarbazone, pendimethalin, benzf Enzizone (benzfendizone), benzurido (bensulide), bensulfuron methyl (bensulfuron-methyl), benzobicyclone (benzobicyclon), benzophenap (benzofenap), bentazone (pentazone), pentanochlor (pentanochlor), pentoxazone (pentoxazone) , Benfluralin (benfluralin), benfuresate (benfuresate), fosamine (fosamine), fomesafen (fomesafen), foramsulfuron (foramsulfuron), mecoprop (mecoprop) (sodium, potassium, isopropylamine, triethanolamine, dimethylamine etc. (Including salts), mecoprop P potassium (mecoprop-P-potassium), mesosulfuron-methyl, mesotrione, metazachlor, metazosulfuron, metabenzthiazolone (including salts) methabenzithazuron), metamitron, metamifop, DSMA (disodium methanoarsonate), methiozolin, methyldymuron, methyldymuron, metoxuron, metosulam, methsulfuron-methyl ethyl), metobromuron, metobenzuron, metolachlor, metolavzine, metribuzin, mefenacet, monosulfuron (including methyl, ethyl and isopropyl ester), monolinuron, monolinuron (Molinate), iodosulfuron (iodosulfuron), iodosulfuron methyl sodium salt (iodosulfulon-methyl-sodium), iofensulfuron (iofensulfuron), iofensulfuron sodium salt (iofensulfuron-sodium), lactofen (Lactofen), lancotrione, lanuron, linuron, rimsulfuron, rimsulfuron, lenacil, TCA (2,2,2-trichloroacetic acid) (including salts such as sodium, calcium or ammonia), 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,4,5-T (2,4,5-trichlorophenoxyacetic acid), 2,4-D (2,4-dichlorophenoxy) Acetic acid (including salts such as amines, diethylamine, triethanolamine, isopropylamine, sodium or lithium), ACN (2-amino-3-chloro-1,4-naphthoquinone), MCPA (2-methyl-4-chloro) Phenoxyacetic acid), MCPB (2-methyl-4-chlorophenoxy) Acid (including sodium salt, ethyl ester etc.), 2,4-DB (4- (2,4-dichlorophenoxy) butyric acid), DNOC (4,6-dinitro-O-cresol) (such as amine or sodium) Salts), AE-F-150944 (code number), HW-02 (code number), IR-6396 (code number), MCPA.thioethyl (MCPA-thioethyl), SYP-298 (code number), SYP- 300 (code number), EPTC (S-ethyl dipropyl thiocarbamate), S-metolachlor (S-metolachlor).

[Pesticidal active ingredient]
Acrinathrin (acrinathrin), azadirachtin (azadirachtin), azamethiphos (azamethiphos), azinphos-ethyl (azinphos-ethyl), azinphos-methyl, acequinocyl, acetamiprid (acetamiprid), acetoprole (acetoprole) (Acephate), azocyclotin (azocyclotin), abamectin (abamectin), afidopyropene (afidopyropen), afoxoreiner (afoxolaner), amidoflumet (amidoflumet), amitraz (amitraz), alaniccarb (alanycarb) Aldicarb (aldicarb), aldoxycarb (aldoxycarb), allethrin (allethrin) (including d-cis-trans- and d-trans-form), isazophos (isazophos), isamidophos (isamidofos), isocarbophos (isocarbophos) and isoxathion (Isoxathion), isofenphos-methyl, isoprocarb, isvermectin, ivermectin, imiciaphos (imicyafos), imidacloprid, imiprothrin, imyprothrin, indoxacarb, esfenvalerate (esfenv) lethio), ethiophencarb, ethion, ethiprole, ethylene dibromide, ethoxazole, etoxazole, etofenprox, etophrophos, etrimfos, emamitate benzoate (Emamectin benzoate), endosulfan (endosulfan), enpentrin (empenthrin), oxamyl (oxamyl), oxydimeton methyl (oxydemeton-methyl), oxydeprofos (oxydeprofos), omethoate, omethaate Cadusafos, kappa-tefluthrin, kappa-bifenthrin, karanjin, karapjin, cartap, carbaryl, carbosulfan, carbofuran, carbofuran, carbofuran Gamma-BHC (gamma-BHC), xylylcarb (xylylcarb), quinalphos (quinalphos), kinoprene (kinoprene), kinomethionate (chinomethionat), coumaphos (coumaphos), cryolite, crothiidin (clothianidin), clofentezin ), Chromafenozide, chlorantraniliprole, chlorethoxyphos (chlorethoxyfos), chlordane (chlordane), chlorpicrin (chloropicrin), chlorpyrifos (chloropirifos), chlorpyrifos-methyl (chlorpyrifos-methyl) ), Chlorfenvinphos (chlorfenvinphos), chlorfluazuron (chlorfluazuron), chlormephos (chlormephos), chloropraleslin (chloroprallethrin), cyanophos (cyanophos), diafenthiuron (Diafenthiuron), diamidafos (diamidafos), cyantraniliriprole (cyantraniliprole), dienochlor (dienochlor), cienopyraphen (cyenopyrafen), dioxabenzophos (dioxabenzofos), diofenolan (diofenolan), cyclaniliprole (cycliliposol), dicrotophos), dichlofenthion, cycloprothrin, dichlorvos, dichloromezotiaz, 1,3-dichloropropene (1,3-dichloropropene), dicophor icofol), dicyclanyl (dicyclanil), disulfoton (disulfoton), dinotefuran (dinotefuran), dinobuton (dinobuton), cyhalodiamide (cyhalodiamide), cyhalothrin [gamma-body, including lambda-body], cifenothrin [cyphenothrin] (1R) -trans-form], cyfluthrin [including beta-form], diflubenzuron (diflubenzuron), ciflumethofen (cyflumetofen), diflovidazine (diflovidazin), cyhexatin (cyhexatin), cypermethrin (cypermethrin) [alphaperoxide] -Body beta-body, theta-body, zeta-body], dimethylvinphos (dimethylvinphos), dimefluthrin (dimefluthrin), dimethoate (dimethoate), silafluofen (silafluofen), cyromazine (cyromazine), spinetram (spinetoram), spinosad (spinosad) ), Spirodiclofen (spirodiclofen), spirotetramat (spirotetramat), spiromesifen (spiromesifen), sulcofuron sodium salt (sulcofuron-sodium), sulfluramid (sulfluramid), sulfoxafolol (sulfofaflor), sulfotep (sulfotep), Diazinon (diazinon), thiacloprid, thiamethoxam, tiozazafen (tioxazafen), thiodicarb (thiodicarb), thiocyclam (thiocyclam), thiosultap (thiosultap), thionazine (thionazin), thiophanox (thiofanto), ), Tetrachlorvinphos (tetrachlorovinphos), tetradiphone (tetradifon), tetranilyprole (tetraniliprole), tetramethylfluthrin (tetramethylfluthrin), tetramethrin (tetramethrin), tebupilimphos (te upirimfos), tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, temetho-S-methyl, temephos (temephos), deltamethrin (deltamethrin), Tralomethrin, transfluthrin, triazamate, triazophos, trichlorphos, trichlorfon, triflumuron, triflumezopyr (triflumezopyr) m) trimethacarb (trimethacarb), tolfenpyrad (tolfenpyrad), nared (nited), nitenpyram (nitenpyram), novaluron (novaluron), noviflumuron, novoflumurium, verticillium lecanii, hydroprene (hydroprene), Liapene transspores (Pasteuriapenetrans), vamidothion, parathion, parathion, parathion-methyl, halfenprox, halfenprox, halofenozide, bioallethrin (bioalleth) in), bioallethrin S-cyclopentenyl (bioallethrin S-cyclopentenyl), bioresmethrin (bioresmethrin), bistrifluron (bistrifluron), hydramethylnon (hydramethylnon), bifenazate, bifenthrin, bifluthumide (pyflubumide), Piperonyl butoxide, pyrometrozine, pyraclofos, pyrafluprole, pyridaphenthion, pyridaben, pyridalal (pyridalal) yl), pyrifluquinazon (pyrifluquinazon), pyriprole (pyriprole), pyriproxyfen (pyriproxyfen), pyrimicarb (pirimicarb), pyrimidifen (pyrimidifen), pyriminostrobin, pyrimiphos-methyl (pyrimiphos-methyl), pyrethrine (pyrethrine) ), Femfur (famphur), fipronil (fipronil), fenazaquin (fenazaquin), fenamiphos (fenamiphos), fenitrothion (fenitrothion),
Phenoxycarb (fenoxycarb), Phenothiocarb (fenothiocarb), Phenothrin (phenothrin) (including (1R) -trans-form), Fenocarb (fenobucarb), Fenthion (fenthion), Phenthoate (phenthoate), Fenvalerate (fenvalerate), Fenpiroxmate (Fenthiocarb) fenpyroximate), fenbutatin oxide, fenpropathrin, fonofos, fonofos, sulfuryl fluoride, butocarboxim, butoxycarboxim Buprofezin (buprofezin), furathiocarb, prallethrin, fluacripyrim, fluazaindolizine, fluazuron, fluensulfone, fluoroacetic acid sodium salt (sodium thioacetate) fluxatamide, flucycloxuron, flucythrinate, flusulfamide, fluvalinate (including tau-form), flupyradione (flupyra) ifulone), flupyrazophos, flufiprole, flufenerim, flufenoxystrobin, flufenoxuron, fluhexafon, flubendiamide, flumethrin (fulmethrin) flumethrin, protrifenbute, prothiofos, protrifenbute, pronifenbute, flonicamid, flopamid, propaphos, propargite, profenofos (profenof) s) broflanilide (broflanilide), profluthrin (propluthrin), propetamphos (propetamphos), propoxur, promethoquine, flometoquin, bromopropylate, bromopropylate, hexythiazolox, hexaflumuron, hexaflumurone (Paecilomyces tenuipes), Pequilomyces fumosoroceus, heptafluthrin, heptenophos (heptenophos), permethrin (permethrin), benclothias (benclot) iaz), bensultap, benzoximate, bendiocarb, benfuracarb, benfuracarb, beuvelia tenella, beubelia bassiana, beuvelia bronniati (beueveria brongeartii) , Phoxim, phosalone (fosalone), fosthiazate (fosthiazate), fosthietan (fosthietan), phosphamidon (phosphamidon), phosmet (phosmet), polynactin complexes (polynactins), formetan (formetan) te), phorate (phorate), malathion (malathion), milbemectin (milbemectin), mecarbam (mecarbam), mesulfenphos (mesulfenfos), methoprene (methoprene), methofyl (methhomyl), metaflumizone (metaflumizone), methamidophos (methamidophos) metham), methiocarb, methidathion, methyl isothiocyanate, methyl bromide, methoxychloro, methoxyfenozide, Tothrin (methothrin), metfluthrin (metofluthrin), epsilon-methoflthrin (epsilon-metofluthrin), metolcarb (metolcarb), mevinphos (mevinphos), meperfluthrin (meperfluthrin), monaculosporium phymatopagum (Monacrosporium phytophygolate) Momfluorothrin, epsilon-mom fluorothrin, Little A (litlure-A), Little A B (litlure-B), Aluminum phosphide ), Zinc phosphide (zinc phosphide), hydrogen phosphine (phosphine), lufenuron (lufenuron), rescalure (rescalure), resmethrin (resmethrin), lepimectin (lepimectin), rotenone (rotenone), fenbutatin oxide oxide, lime Nitrogen (calcium cyanide), Nicotine sulfate, (Z) -11-tetradecenyl acetate, (Z) -11-hexadecenal, (Z) -11-hexadecenyl acetate, (Z) -9,12-tetradecade Dienyl = acetate, (Z) -9-tetradecen-1-ol, (Z, E) -9,11-tetradecadienyl acetate, (Z, ) -9,12-Tetradecadienyl acetate, Bacillus popilliae, Bacillus subtilis, Bacillus sphaericus, Bacillus thuringiensis subspecies, Bacillus thuringiensis subsp. . Aizawai), Bacillus thuringiensis subspecies Islaelensis, Bacillus thuringiensis subsp. Kurstaki, Bacillus thuringiensis subspecies Bacillus sp. Subsp. Teneburionis (Bacillus) thuringiensis subsp. Tenebrionis), Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Ab, Cry3Bb, Cry34 / 35Ab1), CL 900167 (code number), DCIP (bis- (2-chloro-1-methylethyl) ether) , DDT (1, 1 1-trichloro-2,2-bis (4-chlorophenyl) ethane), DEP (dimethyl-2,2,2-trichloro-1-hydroxyethyl phosphonate), DNOC (4,6-dinitro-o-cresol), DSP (O, O-diethyl-O- [4- (dimethylsulfamoyl) phenyl] -phosphorothioate), EPN (O-ethyl-O-4- (nitrophenyl) phenylphosphonothioate), nuclear polyhedra Disease virus embedding body, NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 (code number), ZDI-2501 (code number), XMC, Z-13 -3 Ikosen-10-on, ZXI8901 (code number), ME5382.

[Bactericidal active ingredient]
Azaconazole (azaconazole), acibenzolar-S-methyl, azoxystrobin (azoxystrobin), anilazine (anilazine), amisulblom (amisulbrom), ametoctradin (ametoctradin), aldimorph (aldimorph), isotianil (isotianil) , Isopyrazam, isofetamide, isoprothiolane, isoprothiolane, ipconazole, ipfentrifluconazole, iprodione, iprovaricarb (iprovalic) rb), iprobenphos (iprobenfos), imazalil (imazalil), iminoctatain albesylate (iminoctadine-trialbesilate), iminoctadine acetate (iminoctadine-triacetate), imibenconazole (imibenconazole), edifenphos (edifenphos), etaconazole ), Ethaboxam, ethylimol (ethirimol), ethoxyquin (ethoxyquin), etridiazole (etridiazole), enestrobulin (enestroburin), enoxastrobin (enoxastrobin), epoxyconazole (epoxiconazol) ), Organic oils (organic oils), oxadixyl (oxadixyl), oxazinilazole (oxazinylazole), oxathiapiproline (oxathiapiprolin), oxycarboxin (oxycarboxin), oxyquinoline copper (oxine-copper), oxytetracycline (oxytetracycline) ), Oxpoconazole fumarate (oxpoconazole-fumarate), oxolinic acid (oxolinic acid), copper octatanoate (copper dioctanoate), octilinone (octhilinone), ofurace (ofurace), orisastrobin (orysastrobin), orthophenylphenol (o) -Ph enylphenol), kasugamycin (kasugamycin), captaphor (captafol), carpropamid (carpropamid), carbendazim (carbendazim), carboxin (carboxin), carbonone (carvone), quinoxyphene (quinoxyfen), quinofumelin (quinofumelin), quinomethionate (chinomethionate) Captan, quinconazole (quinconazole), quintozene, guazatine, guafrane, cufraneb, coumoxystrobin, kresoxim-methyl, clozime Conyl (clozylacon), clozolinate (chlozolinate), chlorothalonil, chloroneb (chloroneb), ciazophamide (cyazofamid), dietofencarb (diethofencarb), diclocymet (diclocymet), dichlofluanid (dichlofluanid), ), Dichlorophen (dichlorophen), dithianone (dithianon), diniconazole (diniconazole), diniconazole M (diniconazole-M), zineb (zineb), dinocap (dinocap), dipimethone (dipymeti) rone), diphenylamine (diphenylamine), difenoconazole (difenoconazole), cyflufenamide (cyflufenamid), diflumetrim (diflumetorim), cyproconazole (cyproconazole), cyprodinil (cyprodinil), simeconazole (simeconazole), dimethy ol water ), Dimethomorph, shimoxanil, dimoxystrobin, diram (ziram), silthiofam (silthiofam), streptomycin c n) Spiroxamine (Spiroxamine), Sedaxane (sedaxane), Zoxamide (zoxamide), Dazomet (dazomet), Thiadiendil (tiadinil), Thiabendazole (thiabendazole), Thiuram (thiram), Thiophanate (Thiophanate), Thiophanate Methyl (thiophanate-methyl) ), Thifluzamide, tecnazene, tecloftalam, tetraconazole, tetraconazole, debacarb, tebuconazole, tebufloquin, terbinafine (terbina) fine), dodine, dodemorph, triadimenol, triadimefon, triazimefon, triazide, trichlamide, triclopyricarb, tricycliazole, triticolazole (Triticonazole), tridemorph (tridemorph), triflumizole (triflumizole), trifloxystrobin (trifloxystrobin), trifolin (triforine), tolyl fluanide (tolylfluanid), tolclophos methyl (tolclofos-methyl), Phenide (Tolnifanide), Tolprocarb (Tolprocarb), Nabam, Natamycin (Natamycin), Naftifine, Nitrapirin, Nitropyr-Isopropyl, Niarimol, Nonylphenol Sulfonate copper nonyl phenol sulphonate, Bacillus subtilis (strain: QST 713), validamycin (validamycin), varifenalate (valifenalate), picalbutorazox (picarbutrazox), bixafen (bixafen), pipi Coxystrobin (picoxystrobin), pydiflumetofen (pydiflumetofen), bitertanol (bitertanol), biapacryl (binapacryl), biphenyl (biphenyl), piperaline (piperalin), hymexazole (hymexazol), pyraoxystrobin (pyraoxystrobin), pyraclost Robin (pyraclostrobin), pyraziflumid (pyraziphumid), pyrazophos (pyrazophos), pyrametostrobin (pyrametostrobin), pyriophenone (pyriofenone), pyrisoxazole (pyrisoxazole), pyrifenox (pyrifenox), pyributycarb yributicarb), pyribencarb, pyrimethanil, pyroquilon, pycloquilon, vinclozolin, ferbam, famoxadone, phenazine oxide, fenamidone, ), Fenarimol (fenarimol), phenoxanyl (fenoxanil), ferimsone (ferimzone), fenpiclonil (fenpiclonil), fenpicoxamide (fenpicoxamide), fenpyrazamine (fenpyrazamine), fenbuconazo Le (fenbuconazole), fenfuram (fenfuram), fenpropidin (fenpropidin), fenpropimorph (fenpropimorph), fenhexamid (fenhexamid), folpet, folpet, phthalide, bupirimate (bupirimate), fuberidazole (fuberidazole) ), Blasticidin-S, furametopyr, furalaxyl, furancarboxylic acid, fluazinam, fluindapyr, fluoxastrobin, Luopicolide (fluopicolide), fluopyram (fluopyram), fluorimide (fluroimide), fluxapirokado (fluxapyroxad), fluquinonazole (fluquinconazole), fluconazole (furconazole), fluconazole cis (furconazole-cis), fludioxonil (fludioxonil) (Flusilazole), flusulfamide (flusulfamide), flutianil (flutianil), flutolanil (flutolanil), flutriaphor (flutriafol), fluphenoxystrobin (flufenoxystrobin), flumetover (flumetover) , Flumorph, proquinazid, prochloraz, procymidone, prothiocarb, prothioconazole, prothioconazole, bronopol, propamocarb hydrochloride (propamocarb-hydrochloride) (Propiconazole), propineb (propineb), probenazole (probenazole), bromuconazole (bromuconazole), flomethoquin (flometoquin), hexaconazole (hexaconazole), benalaxyl (benalaxyl), benalaxyl M. (Benalaxyl-M), benodanyl (benodanil), benomyl (benomyl), peflazoate (pefurazoate), penconazole (penconazole), pencyclone (pencycuron), benzobin diflupyr (benzovidiflupyr), benchiazole (benthiazole), bencha bla carb Isopropyl (benthiavalicarb-isopropyl), penthiopyrad (penthiopyrad), penflufen (penflufen), boscalid (boscalid), fosetyl (fosetyl) (alminium, calcium,
sodium), polyoxin (polyoxin), polycarbamate (polycarbamate), Bordeaux solution (Bordeaux mixture), mancozeb (mancozeb), mandipropamide (mandipropamid), mandestorobin (mandestrobin), manneb (maneb), microbutanil (myclobutanil), mineral oil ( mineraloids), mildiomycin, methasulfocarb, metam, metalaxyl, metalaxyl, metalaxyl-M, metiram, metconazole, metminostrob (Metominostrobin), metraphenone (metrafenone), mepanipyrim (mepanipyrim), mefentrifluconazole (mefentrifluconazole), meptyldino cup, mepronil (mepronil), iodocarb (iodocarb), laminarin (laminarin) and salts (Phosphorous acid and salts), basic copper chloride (copper oxychloride), silver (silver), cuprous oxide (cuprous oxide), cupric hydroxide (copper hydroxide), potassium hydrogen carbonate (potassium bicarbonate), hydrogen carbonate Sodium (sodium icarbonate), sulfur, oxyquinoline sulfate, copper sulfate, (3,4-dichloroisothiazol-5-yl) methyl 4- (tert-butyl) benzoate (chemical name) , CAS Registry Number: 1231214-23-5), 3-((3,4-Dichloroisothiazol-5-yl) methoxy) benzo [d] isothiazole-1,1-dioxide (chemical name, CAS Registry Number: 957144-77-3), BAF-045 (code number), BAG-010 (code number), UK-2A (code number), DBEDC (dodecylbenzenesulfonic acid bisethylenediamine copper complex [II]), MIF-1002 (code number) Code number), TPTA (triphenyl acetate) Rutin), TPTC (triphenyltin chloride), TPTH (triphenyltin hydroxide), nonpathogenic Erwinia carotobola.

[Plant growth regulating active ingredient]
1-methylcyclopropene (1-methylcyclopropene), 1-naphthylacetamide (1-naphthylactamide), 2,6-diisopropylnaphthalene (2,6-diisopropylnaphthalene), 4-CPA (4-chlorophenoxyacetic acid), benzylaminopurine benzylaminopurine), ancimidol (ancymidol), aviglycine (aviglycine), carbonone (carvone), chlormecoat (chlormequat), cloprop (cloprop), cloxifonac (cloxyfonac), cloxyfonac potassium salt (cloxyfonac-potassium), Cyclanilide, cyno Kainin (cytokinins), daminozide (daminozide), dikegulac (dikegulac), dimethipine (dimethipin), ethephon (ethephon), epocholeone (epocholeone), ethychlozate, flumetralin (flumetralin), flurenol (fluritolol) ), Chlorchlorphenuron (forchlorfenuron), gibberellins (gibberellins), inabenfide (inabenfide), indole acetic acid (indoletic acid), indole butyric acid (indol butyric acid), maleic acid hydrazide (maleic h ydrazide), mefluidide, mepiquat chloride, n-decanol (n-decanol), paclobutrazol (paclobutrazol), prohexadione calcium salt (prohexadione-calcium), prohydrojasmone (prohexadione) prohydrojasmon), sintofen, thidiazuron, triacontanol, trinexapac-ethyl, uniconazole, uniconazol-P, 4-oxo-4 -(2-phenylethyl) aminobutyric acid ( Chemical name, CAS registration number: 1083-55-2), calcium peroxide.

  The process for producing the particulate pesticide composition of the present invention comprises the steps of producing grain nuclei containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazol-1,1-dioxide, And the process of covering the surface of the particle nucleus obtained at the said process with the liquid containing liquid sugar which is saccharides which is not crystallized at normal temperature, and forming an outer layer part in the surface of the said particle nucleus is included. The method for producing the particulate agrochemical composition of the present invention may further include a step of supporting the agrochemical active ingredient on the outer layer portion, if desired, after the step of forming the outer layer portion.

  In the particulate agrochemical composition of the present invention, in the step of producing the grain core containing the compound A, for example, the compound A is mixed with a finely divided solid carrier, and the mixture is stirred and granulated, tumbling granulation method The granulation is carried out by using known granulation methods such as extrusion granulation method, crushing granulation method, fluidized bed granulation method, compression granulation method, vacuum drying granulation method and the like.

  In the step of covering the surface of the grain core obtained in the above step with a liquid containing liquid sugar and forming the outer layer portion on the surface of the grain core, typically, first, the grain core is a concrete mixer, Nauta While mixing using a common mixer such as a mixer, the outer layer portion is formed by charging the liquid sugar-containing particles into this to coat the surface layer of the grain core. If it is difficult to coat the surface layer of the grain core by adding granular material containing liquid sugar, heat the liquid material beforehand or add a slight amount of solvent such as water to the liquid sugar to make the viscosity of the liquid material It may be introduced after lowering it.

  Next, in the step of supporting the agrochemical active ingredient to be carried on the outer layer part on the above-mentioned particle core outer layer part, the agrochemical active ingredient may be added to the outer particle part obtained in the above step and carried on the above outer layer part. . The agrochemical active ingredient to be supported on the outer layer may be used as it is, but it is desirable to finely mill it to a particle size of usually 50 μm or less, preferably 10 μm or less. As means for such pulverization, any known pulverizer can be used. Specifically, an impact type pulverizer, an air flow type pulverizer or the like can be used, but it is not particularly limited. Further, at the time of the fine pulverization, the agrochemical active ingredient to be supported on the outer layer portion may be pulverized alone or, if desired, it may be previously mixed with the above-mentioned auxiliary and the like and co-crushed. Furthermore, when the agrochemical active ingredient is a liquid, it may be previously absorbed in the oil-absorbing fine powder to prepare it in powder form.

  The particulate agrochemical composition of the present invention is applicable to all situations in agrochemical application, but is particularly effective in the case of application at a germination / rooting of a seed or a growing stage of a seedling, so-called seeding and raising stage. For example, at the time of seedling culture soil mixing in rice box box raising, before seeding covered soil or after soil covering, a period from a sprouting period to just before transplantation corresponds to a seeding and raising seedling period. Furthermore, in recent years, transplant simultaneous application has also been developed, and application to this field is also possible. In addition, in the case of cell tray breeding of vegetables etc., it can be applied similarly from the time of mixing of the growing medium to the time of transplanting, but particularly preferably application at sowing time and emergence period, planting hole treatment at the time of transplanting, etc. In addition, although cultivation in the seedling and raising stage usually uses seedling culture soil, it is also applicable to cultivation other than culture soil, such as a seedling mat and sheet.

  As the method of application, it can be applied by the same method as ordinary pesticide granules, for example, direct powdering by hand, human-powered type powdering machine, electric type powdering machine, back-to-back type power type powdering machine Examples of such methods include a traveling type power spreader, a tractor mounted type spreader, a rice transplanter mounted type spreader, a medicator for side streak application, and a method using an air spreader such as an unmanned helicopter. In addition, in rice seedling nursery box application, a method of sprinkling the granular agrochemical composition with a measuring cup which can measure a predetermined amount, sprinkling it on a nursery box, placing it in a special nursery box scattering container and dispersing it in a nursery box, granular pesticide A method of dispersing seeds directly into the nursery box from a discharge port or a hole or the like applied to the packaging container of the composition, a method of dispersing into a large number of nursery boxes placed widely using a power type granulator, special purpose at the time of sowing A method of dispersing the seedling into a nursery box with an apparatus of the above, a method of mixing with the nursery soil, and the like are exemplified.

  In order to properly carry out the application, the physical properties of the particulate agrochemical composition of the present invention are preferably within a certain range for various items. For example, the apparent specific gravity is preferably 0.3 to 2, and more preferably 0.5 to 1.5 in the pesticide inspection method. The hardness of the particles is preferably 20 or less, and more preferably 10 or less in the all-purpose ball milling method. The particle size is preferably 90% by mass or more of the whole of the particulate composition after passing through a sieve having an opening of 1700 μm and not passing through a sieve having an opening of 300 μm.

  In the granular pesticide composition, when the shape of the grain nuclei is substantially cylindrical, the diameter of the cross-sectional circle is usually 0.3 to 1.7 mm, preferably 0.5 to 1.5 mm, more preferably 0. It is 8 to 1.2 mm. The grain length corresponding to the height of the cylinder is preferably 0.5 to 6 times the cross-sectional circle diameter, but when spraying using a dedicated device at the time of sowing work, for example, Made good, model KS-25: roller type granulating machine, seedling box dosing hopper (made by Suzutec, model SDP-33S, SDP-103S: roller type granulating machine), pot dispensing system for seedling nursery (Minoru Sangyo Co., Ltd. Made, type MPA-21: When it spreads with a roller-type powdering machine, it is 50 mass% or less of the grain which has a grain length 2.5 times or more with respect to a section circle diameter to the whole granular composition Is preferable, and more preferably 40% by mass or less.

The application rate when applying the granular pesticide composition of the present invention is 0.1 to 20 kg per 10 ares, preferably 0.2 to 5 kg per 10 ares in case of paddy field or upland, and in case of rice seedling nursery box, raising seedlings It is 10 to 200 g, preferably 10 to 100 g per box (usually 0.16 m ² ). Moreover, when applying to a cell tray, the application amount may be about 30 g per cell tray (128 holes).

  EXAMPLES Specific examples of the present invention will be described below, but the present invention is not limited to these examples. In addition, "part" in a following example and a comparative example represents a mass part, and "%" represents mass%. Further, “short diameter” refers to the cross-sectional circular diameter of the substantially cylindrical granulated product, and “aspect ratio” refers to the quotient obtained by dividing the particle length of the substantially cylindrical granulated product by the short diameter.

Example 1
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with Nauta mixer, 1.2 parts of liquid sugar (trade name Nitto High Sweet Deluxe, manufactured by Mitsubishi Chemical Foods Co., Ltd.) containing about 50% reduced sugar content was heated to 70 ° C. A liquid was added to coat the surface layer of the grain core to form an outer layer portion on the surface of the grain core, thereby obtaining a granular pesticide composition having a grain core outer layer portion covered with liquid sugar.

Example 2
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain kernel with a Nauta mixer, a little amount of water is mixed with 1.2 parts of liquid sugar (trade name Nitto High Sweet Deluxe, manufactured by Mitsubishi Chemical Foods Co., Ltd.) containing about 50% of reduced sugar. The liquid substance is added to coat the surface layer of the grain core, and the water of the liquid substance is removed by drying to form the outer layer part on the surface of the grain core, whereby the grain core outer layer part covered with liquid sugar is obtained. The granular agrochemical composition which it has is obtained.

[Example 3]
While mixing 97 parts of the particulate agrochemical composition obtained in Example 1 with a Nauta mixer, 3 parts of mepronil finely pulverized by an air flow crusher is added and supported on a grain core outer layer part, thereby being covered with liquid sugar There was obtained a granular pesticide composition having a grain outer core part and carrying mepronil in the grain core outer part.

Example 4
While mixing 97 parts of the particulate agrochemical composition obtained in Example 1 with a Nauta mixer, a dispersion liquid which is a mixture of 3 parts of pyribencarb finely pulverized with a wet crusher and 7 parts of water is added and carried on the grain outer layer By removing the water of the dispersion liquid by drying and drying, a granular pesticide composition having a liquid sugar-coated outer particle nucleus part of a particle and carrying pyribencarb on the outer particle part of the particle nucleus was obtained.

[Example 5]
While mixing 97 parts of the particulate agrochemical composition obtained in Example 1 with a Nauta mixer, a mixture of 1.5 parts of bencha bacteriobu isopropyl finely ground with an air flow crusher and 1.5 parts of clay is added A granular agrochemical composition having a liquid sugar-coated outer particle nucleus part and carrying a benchabacillus isopropyl on the outer particle nucleus part was obtained by supporting the outer particle part in the outer appearance of the particle nucleus.

[Example 6]
While mixing 97 parts of the particulate agrochemical composition obtained in Example 2 with a Nauta mixer, 3 parts of mepanipyrim finely pulverized with an impact crusher is added and supported on a grain outer core part, thereby being covered with liquid sugar There was obtained a granular agricultural chemical composition having a grain outer core part and carrying mepanipyrim in the grain core outer part.

[Example 7]
While mixing 97 parts of the particulate agrochemical composition obtained in Example 2 with a Nauta mixer, 3 parts of Iprobenphos is added and supported on the grain outer core part, thereby having a liquid sugar coated grain core outer part The granular agrochemical composition which carries iprobenphos in the grain outer layer part was obtained.

[Example 8]
While being mixed with 97 parts of the particulate agrochemical composition obtained in Example 2 with a Nauta mixer, 3 parts of phenothiocarb finely pulverized with an air flow crusher is added and supported on a grain outer layer, thereby covering with liquid sugar There was obtained a granular agrochemical composition having a grain outer core part and carrying phenothiocarb in the grain core outer part.

Comparative Example 1
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a nauta mixer, add a liquid obtained by mixing a little amount of water with 1.2 parts of lignin sulfonate to coat the surface layer of the grain core, and then dry the liquid substance by drying. By removing the water of the above, a granular pesticidal composition having a lignin sulfonate-coated grain outer core portion was obtained.

Comparative Example 2
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a Nauta mixer, add a liquid obtained by mixing a slight amount of water with 1.2 parts of polyvinyl alcohol to coat the surface layer of the grain core, and then the water of the liquid substance is dried. Were removed to obtain a granular pesticide composition having a polyvinyl alcohol-coated outer core portion of grains.

Comparative Example 3
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a Nauta mixer, 1.2 parts of liquid which is a polybutadiene polyol is added to coat the surface layer of the grain core, thereby the grain core outer layer part coated with polybutadiene polyol is obtained. The granular agrochemical composition which it has is obtained.

Comparative Example 4
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the grain nuclei with a Nauta mixer, a liquid substance which is 1.2 parts of a polyoxyalkylene alkyl ether is added to coat the surface of the grain nuclei, thereby being coated with a polyoxyalkylene alkyl ether. A granular agrochemical composition having a grain outer core part was obtained.

Comparative Example 5
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. A particle core outer layer coated with diisodecyl phthalate is formed by coating the surface of the particle core by adding a liquid which is 1.2 parts of diisodecyl phthalate while mixing 95.8 parts of the particle core with Nauta mixer A granular pesticide composition having a part was obtained.

Comparative Example 6
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. A polyoxyalkylene alkyl ether is obtained by adding a liquid which is 1.2 parts of a polyoxyalkylene alkyl ether phosphate ester while mixing 95.8 parts of the grain nuclei with a Nauta mixer to coat the surface of the grain nuclei. A particulate agrochemical composition having an outer part of grain core coated with phosphoric acid ester was obtained.

Comparative Example 7
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with Nauta mixer, add a liquid obtained by mixing a certain amount of water with 1.2 parts of carboxymethyl cellulose to coat the surface layer of the grain core, and the water of the liquid substance is dried by drying. Were removed to obtain a granular pesticide composition having a carboxymethylcellulose-coated outer core of granules.

Comparative Example 8
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with Nauta mixer, add a liquid obtained by mixing a little amount of water with 1.2 parts of methyl cellulose to coat the surface layer of the grain core, and then dry the liquid water by drying. By removing, the granular agrochemical composition which has a granule outer layer part covered with methylcellulose was obtained.

Comparative Example 9
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a Nauta mixer, add a liquid obtained by mixing some amount of water with 1.2 parts of starch to coat the surface layer of the grain core, and dry the liquid water by drying. By removing, the granular agrochemical composition which has the granule core outer layer part coat | covered with starch was obtained.

Comparative Example 10
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a Nauta mixer, add a liquid obtained by mixing a certain amount of water with 1.2 parts of dextrin to coat the surface layer of the grain core, and then dry the liquid water by drying. By removing, a granular pesticide composition having a dextrin-coated outer part of the granule core was obtained.

Comparative Example 11
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with a Nauta mixer, add a liquid obtained by mixing a slight amount of water with 0.2 part of glyoxylic acid to coat the surface layer of the grain core, and dry the liquid water by drying. To obtain a granular pesticide composition having a glyoxylic acid-coated outer core of granules.

Comparative Example 12
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. Grains coated with polyoxyethylene alkyl aryl ether are obtained by adding 1.5 parts of polyoxyethylene alkyl aryl ether while mixing 95.8 parts of this grain core with Nauta mixer to coat the surface of the grain core. The granular agrochemical composition which has a nuclear outer layer part was obtained.

Comparative Example 13
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with Nauta mixer, 1.5 parts of polyoxyethylene castor oil ether is added to coat the surface layer of the grain core, thereby the grain outer layer coated with polyoxyethylene castor oil ether A granular pesticide composition having a part was obtained.

Comparative Example 14
A predetermined amount of water is added to 2 parts of compound A, 0.35 parts of alkylbenzene sulfonate, 3 parts of pregelatinized starch and 90.45 parts of clay, and the mixture is kneaded, and then a basket raiser equipped with a screen with a pore size of 1.2 mm is used The mixture was extruded and granulated, and the granulated product was dried to obtain a substantially cylindrical granular nucleus having a minor diameter of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of this grain core with Nauta mixer, add a liquid obtained by mixing a certain amount of water with 0.61 part of polyoxyethylene aryl phenyl ether sulfate to coat the surface layer of grain core The water of the liquid substance was removed by drying to obtain a granular agricultural chemical composition having an outer core portion of grains coated with polyoxyethylene arylphenyl ether sulfate.

[Test Example 1]
The content of Compound A in the granular pesticide compositions of Examples and Comparative Examples was quantified by high performance liquid chromatography. Subsequently, each composition was stored still at a constant temperature of 54 ° C. for 14 days, and the content of Compound A was quantified again in the same manner, and the decomposition rate was determined by the following formula. The results are shown in Table 1.

Claims (8)

A particulate agrochemical composition having a grain core and an outer layer covering the grain core,
The grain nuclei contain 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazol-1,1-dioxide, and
A particulate agrochemical composition, wherein the outer layer part contains liquid sugar which is a saccharide which does not crystallize at normal temperature.   The granular agrochemical composition according to claim 1, wherein the grain core is a granulated product obtained by an extrusion granulation method.   The particulate agrochemical composition according to claim 1 or 2, wherein the liquid sugar is a converted liquid sugar containing reducing sugar.   The granular agrochemical composition as described in any one of Claims 1-3 whose content of the said liquid sugar is 0.5-5 mass% with respect to the granular agrochemical composition whole.   Furthermore, the agrochemical active ingredient is carry | supported by the said outer layer part, The granular agrochemical composition as described in any one of Claims 1-4.   The granular agrochemical composition as described in any one of Claims 1-5 whose said particle | grain nucleus is substantially cylindrical shape and whose cross-sectional circular diameter is 0.3-1.7 mm. In the manufacturing method of the granular agrochemical composition as described in any one of Claims 1-6,
Producing a grain core containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide, and
Covering the surface of the grain core obtained in the above step with a liquid containing liquid sugar which is a saccharide that does not crystallize at normal temperature, and forming an outer layer portion on the surface of the grain core;
A method for producing a particulate agrochemical composition, characterized in that it comprises: The manufacturing method of the granular agrochemical composition of Claim 7 which has the process of making the said outer layer part carry | support an agrochemical active ingredient further after the process of forming the said outer layer part.