KR20180128934A - Granular pesticide composition and method for producing the same - Google Patents
Granular pesticide composition and method for producing the same Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
- A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Abstract
본 발명은 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조 방법에 관한 것이다. 입자 핵과, 상기 입자 핵을 피복하는 외부층을 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하고, 또한, 상기 외층부가, 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진 입상 농약조성물이다. 또한, 상기 입상 농약조성물의 제조 방법에 있어서, 상기 화합물을 포함하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻어진 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조방법이다.The present invention relates to a pesticide composition for agricultural and horticultural use excellent in storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1- ≪ / RTI > 1. A granular pesticide composition having a particle core and an outer layer covering the particle nucleus, wherein the particle core is selected from the group consisting of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole- , 1-dioxide, and the outer layer portion contains a liquid sugar which is a saccharide which is not crystallized at room temperature. The method for producing the granular pesticide composition according to the present invention may further comprise a step of preparing particle nuclei containing the compound and a step of coating the surface of the particle nuclei obtained in the step with a liquid material containing a liquid sugar which is a non- And forming an outer layer portion on the surface of the particle nucleus.
Description
본 발명은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 농원예상 유용한 입상 농약조성물 및 이의 제조방법에 관한 것이다. 특히, 상기 화합물의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조방법에 관한 것이다.The present invention relates to a plant growth-promoting granular pesticide composition containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1- . In particular, the present invention relates to a granular pesticide composition which is excellent in storage stability of the above compound,
현재, 농약제제의 형태로서는, 분제(粉劑), 입제(粒劑), 수화제, 과립수화제, 유동가능(flowable)제, 액제, 유제 등의 제형이 알려져 있다. 그 중에서, 입제는 농약제제를 직접 살포하는 제형이며, 논에서의 수면 시용(施用)이나 육종상자 처리, 밭의 토양 혼합 등의 형태로 사용된다. 농약 처리 작업이 간편하고, 살포용의 물을 필요로 하지 않고, 분립(粉立)에 의한 농약 활성성분의 비산의 우려도 없기 때문에, 일본에서 주류의 제형으로 되고 있다.At present, as the form of pesticide preparation, formulations such as powders, granules, wettable powders, granule wettable powders, flowable powders, liquid powders and emulsions are known. Among them, the granule is a formulation which directly sprayes the pesticide preparation, and is used in the form of sleeping application (application) in paddy field, treatment of breeding box, soil mixture of field. The pesticide treatment operation is simple and does not require water for spraying and there is no fear of scattering of the active ingredient of the pesticide by powdering, so that it is a mainstream formulation in Japan.
입제로 사용되는 입상 농약조성물의 일반적인 형태는, 농약 활성성분과 점토와 탄산 칼슘 등의 고체 담체 등을 혼합하여, 상기한 바와 같이 얻어진 혼합물에 물을 넣어 반죽하고, 소정의 구멍직경을 갖는 다이(die)를 이용하여 압출 조립한 후, 건조하여 제조된 입상물이다. 이러한 입상물에서는, 농약 활성성분과 환경 중의 수분의 접촉이 제한되기 때문에, 농약 활성성분의 용출 거동은, 보다 점진적으로 방출되는 경향의 것으로 되어, 효과의 지속성이 요구되는 농약 활성성분에 적합하다. 또한, 다른 양태로서, 광물질 등을 해쇄 또는 조립함으로써 얻은 적당한 입도를 갖는 입자 핵의 표층에 바인더를 이용하여 농약 활성성분을 피복한 입상물인 입상 농약조성물도 알려져 있다. 이러한 입상물에서는, 농약 활성성분이 환경 중의 수분과 직접 접촉하기 때문에, 농약 활성성분을 보다 빨리 용출시킬 수 있어, 속효성이 요구되는 농약 활성성분에 적합하다. 더욱이, 전자의 입상물을 입자 핵으로 한 후자의 입상물의 형태도 있을 수 있다. 당업자는, 배합하는 농약 활성성분에 요구되는 용출 패턴에 따라서, 각각에 적합한 입제의 형태를 선택하고, 구분할 수 있다.The general form of the granular pesticide composition used as the granule is such that the agrochemical active ingredient, the solid carrier such as clay and calcium carbonate are mixed, the mixture obtained as described above is added with water, kneaded, and a die having a predetermined pore diameter die, and then dried. In such a granular material, since the contact between the agricultural chemical active ingredient and the water in the environment is restricted, the dissolution behavior of the agricultural chemical active ingredient tends to be more gradually released, which is suitable for the agrochemical active ingredient for which persistence of effect is required. In addition, as another aspect, there is also known a granular pesticide composition which is a granular material in which a pesticidal active ingredient is coated with a surface layer of particle nuclei having a suitable particle size obtained by crushing or granulating minerals or the like, with a binder. In such a granular material, the active ingredient of the agricultural chemical is in direct contact with the moisture in the environment, so that the active ingredient of the agricultural chemical can be eluted more quickly, and is suitable for the active ingredient of the agricultural chemical which requires quick effect. Further, there may be a form of the latter granular object made of electron grains as particle nuclei. Those skilled in the art can select and distinguish the form of the granules suitable for each of them according to the elution pattern required for the pesticidal active ingredient to be compounded.
한편, 농약 제제에 있어서의 농원예상의 방제 대상으로는, 병해 이외에 해충, 잡초가 있으며, 그 전부에 대응할 필요가 있지만, 병해 방제 활성성분은 병해 방제에 특화되어 있으며, 통상, 해충이나 잡초에는 충분한 방제 활성을 나타내지 않는다. 마찬가지로, 해충 방제 활성성분과 잡초 방제 활성성분으로 해도, 각각 해충 방제나 잡초 방제에 특화된 것이다. 따라서, 현대의 농업에서는, 병해 방제에는 병해 방제 활성성분을, 해충 방제에는 해충 방제 활성성분을, 잡초 방제에는 잡초 방제 활성성분을 각각 이용하여 농경지 등의 관리가 행해지고 있다. 또한 각각의 병해 방제 활성성분에는 효과적인 병해와 효과적이지 않은 병해가 존재한다. 농경지 등에 발생하는 다수의 방제 대상에 대응하기 위해서, 스펙트럼이 다른 다수의 병해 방제 활성성분이 개발되어 있다. 해충 방제 활성성분과 잡초 방제 활성성분에 있어서도 마찬가지 사정이다. 이러한 배경에서, 최근에는 복수의 입제를 사용 시 혼합하여 사용하거나, 단일의 농약 입제에 복수의 농약 활성성분을 배합한 혼합 농약 입제를 이용하는 것도 행해지고 있다.On the other hand, pesticides and weeds in addition to the disease are required to be controlled in the agricultural chemicals preparation, and it is necessary to cope with all of them. However, the active ingredient for controlling the disease is specialized in controlling the disease and is usually sufficient for pests and weeds It does not show the controlling activity. Likewise, even if they are active ingredients for pest control and weed control, they are specialized for pest control and weed control, respectively. Therefore, in modern agriculture, management of farmland and the like is carried out by using an active ingredient for controlling disease, an active ingredient for controlling insect pest for pest control, and an active ingredient for controlling weed for controlling weeds, respectively. In addition, there is an effective disease and an ineffective disease in each active ingredient. In order to cope with a large number of objects to be controlled such as agricultural land, a large number of pest control active ingredients having different spectra have been developed. The same is true for the pest control active ingredient and the weed control active ingredient. In this background, recently, a mixed agricultural chemical granule in which a plurality of granules are mixed with each other or a single agricultural chemical granule is mixed with a plurality of agricultural chemical active ingredients is also used.
3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드(이하, 본 명세서에 있어서 상기 물질을 가리켜 「화합물 A」라 칭함)는 공지의 농원예용 식물 병해 방제 활성성분으로서, 벼 도열병, 밀병, 오이 병, 오이 탄저병 등의 식물 병해에 대해서 현저한 효과를 나타내는 것이 특허 문헌 1에 개시되어 있다. 이 화합물 A는 농작물 등의 생육에 필요한 오랜 기간에 걸쳐서 식물 병해를 방제하고, 또한 예방하는 것도 기대하는 것이기 때문에, 화합물 A를 입제로 조제하는 경우의 형태로서는, 화합물 A를 고체 담체 등과 함께 입자 내에 반죽(kneaded)한 조립물로 하는 것이 바람직하다 (Hereinafter, referred to as " compound A " in the present specification) and 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole- Disclosed in Patent Document 1 is a known active ingredient for controlling plant disease in agricultural or horticultural plants and exhibits a remarkable effect on plant diseases such as rice blast, mildew, cucumber, and anthracnose. Since Compound A is expected to prevent and prevent plant diseases over a long period of time required for growth of crops and the like, in the case of preparing Compound A as a granule, Compound A is mixed with a solid carrier or the like It is preferable to use a kneaded assembly
그러나, 화합물 A는 화학적으로 다소 불안정한 화합물이며, 다양한 화학 물질과의 공존 하에서 불필요하게 분해가 촉진될 수 있기 때문에, 입상 농약조성물 중에 있어서의 화합물 A의 보존 안정성의 향상이 요구되고 있었다. 특히, 화합물 A와 다른 농약 활성성분을 병용하는 혼합 농약 입제에 있어서는, 의도적으로 여러 화학 물질이 공존하기 때문에, 화합물 A의 분해가 더욱 촉진되어, 보다 불리한 장해가 될 경우가 있으며, 이들 화학 물질의 영향을 받지 않고 화합물 A의 보존 안정성이 우수한 입상 농약조성물을 개발하는 것은 어려웠다.However, Compound A is chemically somewhat unstable, and decomposition can be promoted unnecessarily in the presence of various chemical substances. Therefore, it has been desired to improve the storage stability of Compound A in the granular pesticide composition. Particularly, in the case of the mixed agricultural chemical granules which use the active ingredient of the compound A and the other active ingredients of the agrochemical, the decomposition of the compound A is further promoted because of the intentionally coexistence of the various chemical substances, which may be a more unfavorable obstacle. It has been difficult to develop a granular pesticide composition which is unaffected and has excellent storage stability of Compound A.
따라서, 본 발명의 목적은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조 방법을 제공하는 것이다.Accordingly, an object of the present invention is to provide an agricultural and horticultural composition which is excellent in storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1- And a method for producing the same.
본 발명자들은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한 입상 농약조성물을 개발하기 위해 열심히 검토한 결과, 상기 화합물을 입자 핵에 함유시켜, 그 입자 핵의 표면에 상온(常溫)에서 결정화되지 않는 당류를 이용하여 형성한 외층부를 갖는 입상 농약조성물이 상기 과제를 해결하는 것을 발견하여, 본 발명을 완성하기에 이르렀다.The present inventors have studied hard to develop a granular pesticide composition having excellent storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide As a result, it has been found that the granular pesticide composition having the above-mentioned compound in the particle nucleus and having an outer layer portion formed on the surface of the particle nucleus by using a saccharide which is not crystallized at room temperature solves the above problems, .
즉, 본 발명은, 다음과 같은 내용의 것이다.That is, the present invention has the following contents.
[1] 입자 핵과, 상기 입자 핵을 피복하는 외층부를 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 상기 외층부가 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진, 입상 농약조성물.[1] A granular pesticide composition having particle nuclei and an outer layer portion covering the particle nuclei, wherein the particle nuclei are 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole -1,1-dioxide, wherein the outer layer portion contains a liquid sugar which is a saccharide which is not crystallized at room temperature.
[2] 상기 입자 핵이 압출 조립법에 의해 얻어진 조립물인, 상기 1항에 기재된 입상 농약조성물.[2] The granular pesticide composition according to the above-mentioned 1, wherein the particle nuclei are obtained by extrusion granulation.
[3] 상기 액당이 환원당을 함유하는 전화형 액당인, 상기 1 또는 2항에 기재된 입상 농약조성물.[3] The granular pesticide composition according to the above 1 or 2, wherein the liquid sugar is a dialytic liquid containing a reducing sugar.
[4] 상기 액당의 함유량이 입상 농약조성물 전체에 대해서 0.5 내지 5질량%인, 상기 1 내지 3항 중 어느 한 항에 기재된 입상 농약조성물.[4] The granular pesticide composition according to any one of items 1 to 3, wherein the content per liquid is 0.5 to 5% by mass with respect to the total amount of the granular pesticide composition.
[5] 추가로 농약 활성성분을 상기 외층부에 담지하여 이루어진, 상기 1 내지 4항 중 어느 한 항에 기재된 입상 농약조성물.[5] The granular pesticide composition according to any one of the above-mentioned 1 to 4, which further comprises a pesticidal active ingredient supported on the outer layer part.
[6] 상기 입자 핵이 대략 원기둥형이며, 그 단면 원 직경이 0.3 내지 1.7㎜인, 상기 1 내지 5항 중 어느 한 항에 기재된 입상 농약조성물.[6] The granular pesticide composition according to any one of the above items 1 to 5, wherein the particle nuclei are substantially cylindrically shaped and the cross-sectional circle diameter thereof is 0.3 to 1.7 mm.
[7] 상기 1 내지 6항 중 어느 한 항에 기재된 입상 농약조성물의 제조 방법에 있어서, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조방법.[7] The method for producing a granular pesticide composition according to any one of items 1 to 6, wherein the amount of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole- A process for producing particle nuclei containing 1,1-dioxide, and a process for coating the surface of the particle nuclei obtained in the above process with a liquid material containing liquid sugar, which is a saccharide which is not crystallized at room temperature, Wherein the step of forming the granular pesticide composition comprises the step of forming the granular pesticide composition.
[8] 상기 외층부를 형성시키는 공정 후에, 농약 활성성분을 상기 외층 부에 담지시키는 공정을 더 포함하는, 상기 7항에 기재된 입상 농약조성물의 제조방법.[8] The method for producing a granular pesticide composition according to the above-mentioned 7, further comprising a step of supporting the agrochemical active component on the outer layer portion after the step of forming the outer layer portion.
본 발명에 의하면, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드의 보존 안정성이 우수한, 농원예상 유용한 입상 농약조성물 및 이의 제조방법을 제공할 수 있다.INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a pesticide composition which is excellent in storage stability of 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1- And a method for producing the same can be provided.
본 발명의 입상 농약조성물은, 입자 핵과, 상기 입자 핵을 피복하는 외층부를 갖는 입상 농약조성물로서, 상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 또한, 상기 외층부가 실온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진 것이다. 본 발명의 입상 농약조성물은, 액당을 함유하는 외층부의 존재에 의해, 상기 화합물의 분해를 억제하여, 보존 안정성이 우수하다. 또한, 본 발명의 입상 농약조성물은, 다른 농약 활성성분과의 혼합 농약 입제로서 이용하는 경우에도, 상기 화합물 A의 보존 안정성을 손상시키지 않고 사용할 수 있다. 종전의 입상 농약조성물에서는, 화합물 A를 함유하여 이루어지는 입자 핵에 관용의 바인더를 이용하여 다른 농약 활성성분을 피복하여도, 화합물 A와 다른 농약 활성성분의 접촉 기회가 비교적 적음에도 불구하고, 화합물 A의 보존 안정성이 전부 악화되고 있었다.The granular pesticide composition of the present invention is a granular pesticide composition having particle nuclei and an outer layer portion covering the particle nuclei, wherein the particle nuclei are 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1, 2-benzothiazole-1,1-dioxide, and the outer layer portion is a saccharide which is not crystallized at room temperature. The granular pesticide composition of the present invention suppresses the decomposition of the above compound by the presence of the outer layer portion containing liquid sugar, and is excellent in storage stability. In addition, the granular pesticide composition of the present invention can be used without compromising the storage stability of the compound A even when it is used as a pesticide mixed with other agricultural chemical active ingredients. In the conventional granular pesticide composition, even though the pesticide-active component is coated with a binder for the particle nucleus containing the compound A, even though the contact opportunity between the compound A and the other pesticidal active ingredient is relatively small, the compound A The storage stability of the film was deteriorated.
본 발명의 입상 농약조성물은, 화합물 A를 입자 핵에 함유시키는 것이 중요하다. 화합물 A의 함유량은 특별히 한정되지 않지만, 입상 농약조성물 전체에 대해 0.1 내지 8질량%가 바람직하고, 더욱 바람직하게는 0.2 내지 4질량%이다.It is important that the granular pesticide composition of the present invention contains the compound A in the particle nucleus. The content of the compound A is not particularly limited, but is preferably from 0.1 to 8% by mass, more preferably from 0.2 to 4% by mass, based on the total amount of the granular pesticide composition.
화합물 A를 함유하는 입자 핵, 예를 들면, 화합물 A를 미분형상의 고체 담체와의 혼합물로 하고, 상기 혼합물을 교반 혼합 조립법, 전동 조립법, 압출 조립법, 파쇄 조립법, 유동층 조립법, 압축 조립법, 진공 건조 조립법 등의 공지의 조립 방법에 의해 조립물로 함으로써 제조된다.The particle nuclei containing the compound A, for example, the compound A is mixed with a solid carrier of a fine powder form, and the mixture is subjected to a stirring mixing blending method, a power blending blending blending blending blending blending blending blending blending blending blending method, Or by a known assembling method such as an assembling method.
상기 미분형상의 고체 담체의 구체적인 예로는, 벤토나이트, 점토, 카올린, 세리사이트, 활석, 산성 백토, 경석, 제올라이트, 질석, 펄라이트, 탄산 칼슘, 규사 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Specific examples of the solid particulate solid carrier include bentonite, clay, kaolin, sericite, talc, acidic clay, pumice, zeolite, vermiculite, pearlite, calcium carbonate and silica. These may be used singly or in combination of two or more.
상기 입자 핵의 조립방법은, 특별히 한정되는 것은 아니지만, 입자 핵의 외부층에 농약 활성성분을 담지시키는 경우에는, 각각의 입자 핵에 있어서 담지 가능한 농약 활성성분을 결정하는 입자 핵 표면적의 변동이 적은, 즉, 입도분포가 좁은 조립물을 수율 양호하게 얻을 수 있는 조립방법이 바람직하다. 이 목적에 적합한 방법으로서 특히 압출 조립법이 바람직하며, 압출 조립법에 의해 얻어진 조립물을 입자 핵으로서 이용하는 것이 바람직하다.The method of assembling the particle nuclei is not particularly limited. When the active component of the pesticide is carried on the outer layer of the particle nuclei, the particle nucleus surface area for determining the pesticide active ingredient that can be supported in each particle nucleus is small , That is, an assembly method in which a granular material having a narrow particle size distribution can be obtained in a satisfactory yield is preferable. As a method suitable for this purpose, an extrusion granulation method is particularly preferable, and it is preferable to use the granulation product obtained by the extrusion granulation method as a particle nucleus.
입자의 핵의 형상은, 특별히 한정되지 않지만, 농약입제로서 적당한 입도를 갖는 입상물이 바람직하며, 보다 구체적으로는, 0.1 내지 30㎜의 대략 구형상물이나, 체적 구형상에 상당하며 지름 0.1 내지 30㎜인 부정형물이나, 직경 0.1 내지 5㎜, 길이 1 내지 30㎜, 애스펙트비(길이/직경) 1 내지 10인 대략 원기둥 형상물 등이 적합하게 사용가능하다. 그 중에서도, 직경 0.3 내지 1.7㎜, 길이 0.3 내지 10.2㎜, 애스펙트비 1 내지 6인 대략 원기둥 형상물이 바람직하며, 직경 0.5 내지 1.5㎜, 길이 0.5 내지 7.5㎜, 애스펙트비 1 내지 5인 대략 원기둥 형상물이 보다 바람직하며, 직경 0.8 내지 1.2㎜, 길이 0.8 내지 4.8㎜, 애스펙트비 1 내지 4인 대략 원기둥 형상물이 한층 바람직하다.The shape of the nucleus of the particles is not particularly limited, but a granular material having a suitable particle size as an agricultural chemical granule is preferable. More specifically, it is a substantially spherical material having a diameter of 0.1 to 30 mm or a spherical material having a diameter of 0.1 to 30 Mm or a substantially cylindrical shape having a diameter of 0.1 to 5 mm, a length of 1 to 30 mm, and an aspect ratio (length / diameter) of 1 to 10 can be suitably used. Among them, a substantially cylindrical material having a diameter of 0.3 to 1.7 mm, a length of 0.3 to 10.2 mm and an aspect ratio of 1 to 6 is preferable, and a substantially cylindrical material having a diameter of 0.5 to 1.5 mm, a length of 0.5 to 7.5 mm, and an aspect ratio of 1 to 5 More preferably a substantially cylindrical material having a diameter of 0.8 to 1.2 mm, a length of 0.8 to 4.8 mm and an aspect ratio of 1 to 4 is more preferable.
상기 입자 핵은 필요에 따라서 계면 활성제, 결합제, 윤활제, 착색제 등의 보조 성분을 함유시킬 수도 있다. 또한 본 발명의 입상 농약조성물에는, 필요에 따라서, 화합물 A의 안정성을 해치지 않는 한, 상기 입자 핵 내에 약해경감제나 왁스 류, 수지류, 소수성 물질 등의 용출제어제를 함유시켜도 된다.The particle nuclei may contain an auxiliary component such as a surfactant, a binder, a lubricant, and a colorant, if necessary. In the granular pesticide composition of the present invention, as long as the stability of the compound A is not impaired, a dissolution controlling agent such as a weakly sensitizing agent, a wax, a resin, and a hydrophobic substance may be contained in the particle nucleus.
상기 계면 활성제로는 알킬황산에스터염류, 아릴설폰산염류, 폴리옥시에틸렌글리콜에터류, 다가알코올에스터류, 다이알킬설포숙신산염류, 폴리카복실산류, 폴리옥시에틸렌노닐페닐에터, 리그닌설폰산나트륨 등을 들 수 있다. 이들은 1 종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the surfactant include alkylsulfuric acid ester salts, arylsulfonic acid salts, polyoxyethylene glycol ethers, polyhydric alcohol esters, dialkylsulfosuccinates, polycarboxylic acids, polyoxyethylene nonylphenyl ether, sodium lignin sulfonate . These may be used singly or in combination of two or more.
상기 결합제로는, 전분, 알긴산, 글리세린, 폴리비닐피롤리돈, 폴리우레탄, 폴리에틸렌글리콜, 폴리프로필렌글리콜, 폴리부텐, 폴리비닐알코올, 아라비아검, 유동파라핀, 에틸셀룰로스, 폴리비닐아세테이트 등을 들 수 있다. 이들은 1 종을 단독 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the binder include starch, alginic acid, glycerin, polyvinylpyrrolidone, polyurethane, polyethylene glycol, polypropylene glycol, polybutene, polyvinyl alcohol, gum arabic, liquid paraffin, ethylcellulose, polyvinyl acetate have. These may be used singly or in combination of two or more.
상기 윤활제로는, 스테아르산칼슘, 탤크, 실리카 등을 들 수 있다. 이들은 1 종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the lubricant include calcium stearate, talc, silica and the like. These may be used singly or in combination of two or more.
상기 착색제로는, 염료나 안료 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 임의로 사용해도 된다.Examples of the colorant include a dye and a pigment. These may be used singly or in combination of two or more.
상기 약해경감제로는, 베녹사콜(benoxacor), 푸릴라졸(furilazole), 다이클롤미드(dichlormid), 다이시클로논(dicyclonone), DKA-24(N1,N2-다이알릴-N2-다이클로로아세틸글리신아마이드), AD-67(4-다이클로로아세틸-1-옥사-4-아자스피로[4.5]데칸), PPG-1292(2,2-다이클로로-N-(1,3-다이옥산-2-일메틸)-N-(2-프로페닐)아세트 아마이드), R-29148(3-다이클로로아세틸-2, 2, 5-트라이메틸-1,3-옥사졸리진), 클로퀸트세트-멕실(cloquintcet-mexyl), 나프탈산 무수물(1,8-Naphthalic Anhydride), 메펜필-다이에틸(mefenpyr-diethyl), 메펜필(mefenpyr), 메펜필에틸(mefenpyr-ethyl), 펜클로라졸-O-에틸(fenchlorazole-O-ethyl), 펜클로림(fenclorim), MG-191(2-다이클로로메틸-2-메틸-1,3-다이옥산), 시오메트리닐( cyometrinil), 플루라졸(flurazole), 플룩소페님(fluxofenim), 아이속사디펜(isoxadifen), 아이속사디펜-에틸(isoxadifen-ethyl), MON4660(코드 번호), 옥사베트리닐(oxabetrinil), 시프로설파마이드(cyprosulfamide), 저급 알킬 치환벤조산, TI-35(코드 번호) 또는 N-(2-메톡시벤조일)-4-[(메틸아미노카보닐)아미노]벤젠설폰아마이드(화학명, CAS 등록번호: 129531-12-0) 등을 들 수 있다. 이들은 1종을 단독으로 또는 2종 이상을 조합하여 사용할 수 있다.Examples of the weak relief agent include benzoxacor, furilazole, dichlormide, dicyclonone, DKA-24 (N1, N2-diallyl-N2-dichloroacetyl (4-dichloroacetyl-1-oxa-4-azaspiro [4.5] decane), PPG-1292 (2,2- (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine), cloquintet-mexyl ( cloquintcet-mexyl, 1,8-naphthalic anhydride, mefenpyr-diethyl, mefenpyr, mefenpyr-ethyl, pentrolazol-O-ethyl fenchlorazole-O-ethyl, fenclorim, MG-191 (2-dichloromethyl-2-methyl-1,3-dioxane), cyometrinil, flurazole, But are not limited to, fluxofenim, isoxadifen, isoxadifen-ethyl, MON4660 (code number), jade Oxabetrinil, cyprosulfamide, lower alkyl substituted benzoic acid, TI-35 (code number) or N- (2-methoxybenzoyl) -4 - [(methylaminocarbonyl) amino] benzene Sulfonamide (chemical name, CAS registration number: 129531-12-0). These may be used singly or in combination of two or more.
본 발명의 입상 농약조성물은, 화합물 A를 함유하는 상기 입자 핵을 피복하는 외층부에, 실온에서 결정화되지 않는 당류인 액당을 함유시키는 것도 중요하다. 여기에서 액당으로는, 일반적으로 당밀이라 불리는 것이다. 상기 액당의 종류로서, 설탕의 제조 공정에서 생성되는 사탕수수 당밀, 사탕무 당밀, 정제당최종당밀, 얼음 당밀과 환원당을 함유하는 전화당, 예를 들면 자당을 포도당과 과당으로 가수 분해한 전화당 및 자당 등의 비환원당과 함께 전화당을 포함한 것 등이 열거되는 바, 환원당을 함유하는 전화당, 즉, 환원당을 함유하는 전화형 액당이 바람직하다. 전화형 액당 중에서도, 환원당분을 20% 이상 함유하는 것이 바람직하고, 더욱 바람직한 것은 환원당분을 40% 이상 함유한 것이며, 환원당분을 약 50%, 구체적으로는 45 내지 54% 함유하는 액당이 특히 바람직하다.It is also important that the granular pesticide composition of the present invention contains liquid sugar, which is a saccharide which is not crystallized at room temperature, in the outer layer portion covering the particle nuclei containing Compound A. Here, the liquid sugar is generally called molasses. Examples of the liquid sugar include sugar cane molasses, sugar beet molasses, final molasses per tablet, phosgene containing ice syrup and reducing sugar, such as sucrose and sucrose hydrolyzed with glucose and sucrose, And the like, and a dialyzed liquid containing a reducing sugar, that is, a reducing liquid containing a reducing sugar is preferable. Among the electrolytic liquids, it is preferable to contain the reducing sugar in an amount of 20% or more, more preferably 40% or more in the reducing sugar content, particularly preferably in the liquid sugar containing the reducing sugar in an amount of about 50%, specifically 45 to 54% Do.
상기 액당의 함유량은 특별히 한정되지 않고, 입자 핵에 담지시키는 농약 활성 성분의 양에 의한 것도 있지만, 바람직하게는 입상 농약조성물 전체에 대해서 0.5 내지 5질량%이며, 더욱 바람직하게는 0.8 내지 2질량%이다. 이 액당의 함유량이 부족하면, 화합물 A의 보존 안정성을 해칠 우려와, 혼합 농약입제로서 사용할 경우에 농약 활성성분을 입자 핵 외층부에 담지하는 작용이 불충분해질 우려가 있다. 한편, 액당의 함유량이 과다하면 입상 농약조성물의 고결이 우려된다.The content per liquid is not particularly limited and may be in the range of 0.5 to 5% by mass, more preferably 0.8 to 2% by mass, based on the total amount of the particulate pesticide composition, to be. If the content per the liquid is insufficient, the storage stability of the compound A may be impaired, and when used as a mixed agricultural chemical granule, there is a possibility that the action of supporting the agricultural chemical active ingredient on the particle nuclear outer layer portion becomes insufficient. On the other hand, if the content per liquid is excessive, the granular pesticide composition may become tortuous.
본 발명의 입상 농약조성물에 있어서, 액당을 함유하는 외층부를 형성하는 방법은 특별히 한정되지 않지만, 전형적으로는, 먼저 입자 핵을 콘크리트 믹서, 나우타 믹서 등의 통상의 혼합기를 이용하여 혼합하면서, 여기에 액당을 함유하는 액상물을 투입하여 입자 핵의 표층을 피복하는 방법을 들 수 있다. 본 발명의 입상 농약조성물을 혼합 농약 입제로서 사용하는 경우에는, 다음 농약 활성성분을 투입하여, 입자 핵 외층부에 담지시키면 된다.In the granular pesticide composition of the present invention, the method for forming the outer layer portion containing the liquid sugar is not particularly limited, but typically, the particle nuclei are first mixed using a conventional mixer such as a concrete mixer or a Nauta mixer, And a method in which a liquid material containing a liquid sugar is added to cover the surface layer of the particle nuclei. When the granular agricultural chemical composition of the present invention is used as a mixed agricultural chemical granule, the active ingredient of the following pesticide may be added and carried on the particle core outer layer portion.
그런데, 상기 액당은, 일반적으로 상온에서 꿀 형상의 점성 액체이기 때문에, 이 액당을 함유하는 액상물을 입자 핵의 표층에 피복하는 공정에서 어려운 경우가 있다. 이 점을 해결하는 수단으로서는, 액상물을 가온하여 액당의 점성을 저하시키는 방법과, 액당에 물 등의 용매를 소량 첨가하여 액당의 점성을 저하시키는 방법 등을 들 수 있다. 액당에 물을 첨가하여 액상물로 하는 경우, 물 첨가량은 특별히 한정되지 않지만, 액상물 전량에 대하여 30질량% 정도까지로 하는 것이 적당하다. 물이 과잉, 즉, 희박한 액상물 조성으로 하면, 유효량의 액당으로 입자 핵을 피복하기 위해 다량의 액상물을 첨가할 필요가 생겨, 과잉의 물에 의해 젖은 입자 핵 끼리 응집해 버려서, 본 발명의 입상 농약조성물을 혼합 농약 입제로 사용하기 위해서는 외층부에 농약 활성성분을 담지시키는 경우, 농약 활성성분을 담지시키는 공정에서 지장을 초래할 경우가 있다.However, since the liquid crystal is generally a honey-like viscous liquid at room temperature, it may be difficult in the process of coating the surface layer of the particle nuclei with a liquid material containing the liquid crystal. Examples of means for solving this problem include a method of lowering the viscosity per liquid by heating the liquid material and a method of decreasing the viscosity per liquid by adding a small amount of a solvent such as water to the liquid medium. When water is added to the liquid crystal to prepare a liquid, the amount of water to be added is not particularly limited, but it is suitably adjusted to about 30% by mass based on the total amount of the liquid. When the water is excessively rich, that is, a dilute liquid-phase water composition, it is necessary to add a large amount of liquid material to cover the particle nuclei with an effective amount of liquid, and the wetted particle nuclei are agglomerated by excess water, In order to use the granular pesticide composition as a mixed agricultural chemical granule, when the active ingredient of the agricultural chemical is supported on the outer layer portion, the process of supporting the active ingredient of the agricultural chemical may cause trouble.
본 발명의 입상 농약조성물에 있어서는, 추가로 농약 활성성분을 상기 외층부에 담지시킴으로써 함유시킬 수 있다. 농약 활성성분은 1종만을 외층부에 담지시키는 것도 가능하며, 2종 이상을 동시에 담지시키는 것도 가능하다. 농약 활성성분을 액당의 접착력에 의해 입자 핵의 외층부에 담지시킬 수 있다.In the granular pesticide composition of the present invention, the agrochemical active ingredient may be further contained in the outer layer portion so as to be contained. The active ingredient of the pesticide may be supported on only one outer layer portion, or two or more kinds may be carried on the outer layer portion simultaneously. The active ingredient of the pesticide can be carried on the outer layer portion of the particle nucleus by the adhesive force per liquid.
상기 외층부에 담지시키는 농약 활성성분이 상온에서 고체인 경우에는, 보통 50㎛ 이하, 바람직하게는 10㎛ 이하의 입자 크기로 미분쇄하여, 분체로서 이용하는 것이 바람직하다. 또한, 이 분체는 실리카, 규조토, 규사 등의 분쇄 조제, 리그닌 설폰산염, 아릴설폰산염, 알킬 황산염 등의 계면 활성제, 벤토나이트, 점토, 탄산 칼슘 등의 고체 담체, 알칼리 금속염, 알칼리 토류금속염, 에폭시화 유지류 등의 안정화제, 상기 예시한 약해경감제 등의 보조제를 함유 할 수 있다.When the pesticidal active ingredient to be supported on the outer layer portion is a solid at room temperature, it is preferably pulverized into fine particles having a particle size of usually 50 μm or less, preferably 10 μm or less, and used as a powder. The powders can also be obtained by grinding a mixture of a grinding aid such as silica, diatomaceous earth and silica sand, a surfactant such as lignin sulfonate, aryl sulfonate and alkyl sulfate, a solid carrier such as bentonite, clay and calcium carbonate, an alkali metal salt, an alkaline earth metal salt, Stabilizers such as oils and fats, and auxiliary agents such as the above-mentioned weak inhibitors.
외층부에 담지시키는 농약 활성성분을 미분쇄하는 수단으로서는 공지의 분쇄 장치를 임의로 사용할 수 있으며, 구체적으로는 충격식 분쇄기, 기류식 분쇄기, 습식 분쇄기 등을 사용할 수 있지만, 특별히 한정되지 않는다. 또한, 상기 미분쇄 시, 농약 활성성분만으로 분쇄시켜도 되고, 필요에 따라 미리 상기 보조제와 혼합하여, 함께 분쇄시켜도 된다.As a means for finely pulverizing the pesticidal active ingredient to be supported on the outer layer portion, a known pulverizing device may be used, and specific examples thereof include an impact pulverizer, an air flow pulverizer, a wet pulverizer, and the like. In addition, at the time of fine pulverization, the pulverization may be carried out with only the active ingredient of the pesticide, or may be mixed with the auxiliary agent in advance and pulverized together with the above-mentioned auxiliary agent if necessary.
외층부에 담지시키는 농약 활성성분이 상온에서 액체인 경우에는, 액체 상태에서, 상기 외층부에 담지시켜도 되고, 미리 실리카, 규산염, 목분, 미결정 셀룰로스 등의 흡유성 미분에 흡착시켜 분말을 제조하고, 상기 상온에서 고체 농약 활성성분과 마찬가지로 취급할 수 있다.When the pesticidal active ingredient to be carried on the outer layer portion is a liquid at ordinary temperature, it may be carried on the outer layer portion in a liquid state, adsorbed to absorbable fine powder such as silica, silicate, wood powder or microcrystalline cellulose in advance, It can be handled in the same manner as the solid pesticide active ingredient at the above-mentioned room temperature.
외층부에 담지시킬 수 있는 농약 활성성분의 함유량도 한정되는 것은 아니지만, 입상 농약조성물 전체에 대해서, 농약 활성성분으로서 2종 이상인 경우에는, 그 합계는, 통상 0.05 내지 5질량%, 바람직하게는 0.1 내지 4질량%, 더욱 바람직하게는 0.5 내지 3질량%이다.The content of the agricultural chemical active ingredient which can be carried on the outer layer portion is not limited, but if the total amount of the agricultural chemical active ingredient is two or more as the active ingredient of the granular pesticide, the total amount thereof is usually 0.05 to 5% by mass, preferably 0.1 To 4% by mass, and more preferably from 0.5% to 3% by mass.
또한 농약 활성성분은, 화합물 A의 안정성을 해치지 않는 한에서, 입자 핵 내에 1종 또는 2종 이상을 함유할 수도 있지만, 일반적으로, 입자 핵에 함유시킨 농약 활성성분의 용출 속도는 비교적 완만한 것으로 될 것으로 추측된다. 본 발명의 입상 농약조성물에 속효성인 약효 발현을 기대할 농약 활성성분을 함유시키고자 할 경우에는, 입자 핵 외층부에 담지시키는 설계를 선택하는 것이 합리적이다.The agrochemical active component may contain one or more species in the particle nuclei so long as the stability of the compound A is not impaired. In general, however, the dissolution rate of the agrochemical active component contained in the particle nuclei is relatively slow . When it is desired to include an agrochemical active ingredient which is expected to have a short effective effect on the granular pesticide composition of the present invention and which is expected to exhibit its pharmaceutical efficacy, it is reasonable to select a design to be carried on the particle core outer layer portion.
본 발명의 입상 농약조성물에 있어서, 입자 핵에 함유 또는 외층부에 담지시킬 수 있는 농약 활성성분으로서는, 예들 들면, 하기에 열거한 것을 들 수 있지만, 특별히 한정되는 것은 아니다.In the granular pesticide composition of the present invention, the agricultural chemical active ingredient contained in the particle nuclei or carried on the outer layer portion includes, for example, those listed below, but are not particularly limited.
[제초 활성성분][Herbicidal active ingredient]
아이옥시닐(ioxynil), 아클로니펜(aclonifen), 아크롤레인(acrolein), 아자페니딘(azafenidin), 아시플루오르펜(acifluorfen)(나트륨 등과의 염을 포함함), 아짐설푸론(azimsulfuron), 아술람(asulam), 아세토클로르(acetochlor), 아트라진(atrazine), 아닐로포스(anilofos), 아미카바존(amicarbazone), 아미도설푸론(amidosulfuron), 아미트롤(amitrole), 아미노사이클로피라클로르(aminocyclopyrachlor), 아미노피랄리드(aminopyralid), 아미프로포스·메틸(amiprofos-methyl), 아메트린(ametryn), 알라클로르(alachlor), 알록시딤(alloxydim), 아이소우론(isouron), 아이소옥사클로르톨(isoxachlortole), 아이소옥사플루톨(isoxaflutole), 아이소옥사벤(isoxaben), 아이소프로투론(isoproturon), 이프펜카바존(ipfencarbazone), 이마자퀸(imazaquin), 이마자픽(imazapic)(아민 등과의 염을 포함함), 이마자필(imazapyr)(아이소프로필 아민 등의 염을 포함함), 이마자메타벤즈-메틸(imazamethabenz-methyl), 이마자목스(imazamox), 이마제타피르(imazethapyr), 이마조설푸론(imazosulfuron), 인다지플람(indaziflam), 인다노판(indanofan), 에글리나진·에틸(eglinazine-ethyl), 에스프로카브(esprocarb), 에타메트설푸론·메틸(ethametsulfuron-methyl), 에탈플루랄린(ethalfluralin), 에티디무론(ethidimuron), 에톡시설푸론(ethoxysulfuron), 에톡시펜·에틸(ethoxyfen-ethyl), 에토푸메세이트(ethofumesate), 에토벤자니드(etobenzanid), 엔도탈다이나트륨(endothal-disodium), 옥사다이아존(oxadiazon), 옥사다이아르길(oxadiargyl), 옥사지클로메폰(oxaziclomefone), 옥사설푸론(oxasulfuron) 옥시플루오르펜(oxyfluorfen), 오리잘린(oryzalin), 오쏘설파무론(orthosulfamuron), 오르벤카브(orbencarb), 올레산(oleicacid), 카펜스트롤(cafenstrole), 카펜트라존·에틸(carfentrazone-ethyl), 카부틸레이트(karbutilate), 카베타마이드(carbetamide), 퀴잘로포프·에틸(quizalofop-ethyl), 퀴잘로포프·P·에틸(quizalofop-P-ethyl), 퀴잘로포프·P·테푸릴(quizalofop-P-tefuryl), 퀴노클라민(quinoclamine), 퀸클로락(quinclorac), 퀸메락(quinmerac), 쿠밀루론(cumyluron), 클라사이포스(clacyfos), 글라이포세이트(glyphosate)(나트륨, 칼륨, 암모늄, 아민, 프로필아민, 아이소프로필아민, 다이메틸아민 또는 트라이메시움의 등의 염을 포함함), 글루포시네이트(glufosinate)(아민 또는 나트륨 등의 염을 포함함), 글루포시네이트·P·나트륨염(glufosinate-P-sodium), 클레토딤(clethodim), 클로디나포프·프로파길(clodinafop-propargyl), 클로피랄리드(clopyralid), 클로마존(clomazone), 클로메톡시펜(chlomethoxyfen), 클로메프로프(clomeprop,), 클로란설람·메틸(cloransulam-methyl), 클로람벤(chloramben), 클로리다존(chloridazon), 클로리무론·에틸(chlorimuron-ethyl), 클로르설푸론(chlorsulfuron), 클로르탈·다이메틸(chlorthal-dimethyl), 클로르티아미드(chlorthiamid), 클로르프탈림(chlorphthalim), 클로르플루레놀·메틸(chlorflurenol-methyl), 클로르프로팜(chlorpropham), 클로르브로무론(chlorbromuron), 클로록수론(chloroxuron), 클로로톨루론(chlorotoluron), 케토스피라독스(ketospiradox) (나트륨, 칼슘 또는 암모니아 등의 염을 포함한다.), 사플루페나실(saflufenacil), 살멘틴(sarmentine), 사이아나진(cyanazine), 사이아나마이드(cyanamide), 다이우론(diuron), 다이에타틸·에틸(diethatyl-ethyl), 다이캄바(dicamba)(아민, 다이에틸아민, 아이소프로필아민, 다이글리콜아민, 나트륨 또는 리튬 등의 염을 포함함), 사이클로에이트(cycloate), 사이클록시딤(cycloxydim), 다이클로설람(diclosulam), 사이클로설파무론(cyclosulfamuron), 사이클로피리모레이트(cyclopyrimorate), 다이클로베닐(dichlobenil), 다이클로포프·P·메틸(diclofop-P-methyl), 다이클로포프·메틸(diclofop-methyl), 다이클로르프로프(dichlorprop), 다이클로르프로프-P(dichlorprop-P), 다이쿼트(diquat), 다이티오필(dithiopyr), 시두론(siduron), 다이니트라민(dinitramine), 시니돈·에틸(cinidon-ethyl), 시노설푸론(cinosulfuron), 디노세브(dinoseb), 다이노테르브(dinoterb), 사이할로포프·부틸(cyhalofop-butyl), 다이펜아미드(diphenamid), 다이펜조쿼트(difenzoquat), 다이플루페니칸(diflufenican), 다이플루펜조필(diflufenzopyr), 시마진(simazine), 다이메타클로르(dimethachlor), 다이메타메트린(dimethametryn), 다이메텐아미드(dimethenamid), 다이메텐아미드·P(dimethenamid-P), 시메트린(simetryn), 다이메피페레이트(dimepiperate), 다이메푸론(dimefuron), 신메틸린(cinmethylin), 스웨프(swep), 설코트라이온(sulcotrione), 설펜트라존(sulfentrazone), 설포세이트(sulfosate), 설포설푸론(sulfosulfuron), 설포메투론·메틸(sulfometuron-methyl), 세톡시딤(sethoxydim), 테르바실(terbacil), 다이무론(daimuron), 탁스토민 A(thaxtomin A), 달라폰(dalapon), 티아조필(thiazopyr), 티아페나실(tiafenacil), 티엔카바존(thiencarbazone)(나트륨염, 메틸에스터 등을 포함함), 티오카바질(tiocarbazil), 티오벤카브(thiobencarb), 티다이아지민(thidiazimin), 티펜설푸론-메틸(thifensulfuron-methyl), 데스메디팜(desmedipham), 데스메트린(desmetryne), 테닐클로르(thenylchlor), 테부탐(tebutam), 테부티우론(tebuthiuron), 테프랄록시딤(tepraloxydim), 테푸릴트라이온(tefuryltrione), 템보트라이온(tembotrione), 테르부틸라진(terbuthylazine), 테르부트린(terbutryn), 테르부메톤(terbumeton), 토프라메존(topramezone), 트랄콕시딤(tralkoxydim), 트라이아지플람(triaziflam), 트라이아설푸론(triasulfuron), 트라이아파몬(triafamone), 트라이알레이트(tri-allate), 트라이에타진(trietazine), 트라이클로필(triclopyr), 트라이클로필-부토틸(triclopyr-butotyl), 트라이플루디목사진(trifludimoxazin), 트라이토설푸론(tritosulfuron), 트라이플루설푸론·메틸(triflusulfuron-methyl), 트라이플루랄린(trifluralin), 트라이플록시설푸론나트륨염(trifloxysulfuron-sodium), 트라이베누론·메틸(tribenuron-methyl), 톨피랄레이트(tolpyralate), 납탈람(naptalam)(나트륨 등과의 염을 포함함), 나프로아닐라이드(naproanilide), 나프로파마이드(napropamide), 나프로파마이드-M(napropamide-M), 니코설퓨론(nicosulfuron), 네부론(neburon), 노르플루라존(norflurazon), 베르놀레이트(vernolate), 파라쿼트(paraquat), 할라욱시펜－벤질(halauxifen-benzyl), 할라욱시펜-메틸(halauxifen-methyl), 할록시포프(haloxyfop), 할록시포프·P(haloxyfop-P), 할록시포프-에토틸(haloxyfop-etotyl), 할로사펜(halosafen), 할로설푸론·메틸(halosulfuron-methyl), 피클로람(picloram), 피콜리나펜(picolinafen), 바이사이클로피론(bicyclopyrone), 바이스피리박·나트륨염(bispyribac-sodium), 피녹사덴(pinoxaden), 바이페녹스(bifenox), 피페로포스(piperophos), 피라클로닐(pyraclonil), 피라설포톨(pyrasulfotole), 피라족시펜(pyrazoxyfen), 피라조설푸론·에틸(pyrazosulfuron-ethyl), 피라졸리네이트(pyrazolynate), 바이라나포스(bilanafos), 피라플루펜·에틸(pyraflufen-ethyl), 피리다폴(pyridafol), 피리티오박·나트륨염(pyrithiobac-sodium), 피리데이트(pyridate), 피리프탈리드(pyriftalid), 피리부티카브(pyributicarb), 피리벤족심(pyribenzoxim), 피리미설판(pyrimisulfan), 피리미노박·메틸(pyriminobac-methyl), 피록사설폰(pyroxasulfone), 피록사설람(pyroxsulam), 페니소팜(phenisopham), 페누론(fenuron), 페녹사설폰(fenoxasulfone), 페녹사프롭(fenoxaprop)（메틸, 에틸, 아이소프로필에스터를 포함한다), 페녹사프롭·P(fenoxaprop-P)(메틸, 에틸, 아이소프로필에스터를 포함한다), 펜퀴노트라이온(fenquinotrione), 펜티아프로프·에틸(fenthiaprop-ethyl), 펜트라자마이드(fentrazamide), 펜메디팜(phenmedipham), 포람설푸론(foramsulfuron), 부타클로르(butachlor), 부타페나실(butafenacil), 부타미포스(butamifos), 부틸레이트(butylate), 부텐아클로르(butenachlor), 부트랄린(butralin), 부트록시딤(butroxydim), 플라자설푸론(flazasulfuron), 플람프롭(flamprop)(메틸, 에틸, 아이소프로필 에스터를 포함함), 플람프로프·M(flamprop-M)(메틸, 에틸 및 아이소프로필 에스터를 포함함), 프리미설푸론·메틸(primisulfuron-methyl), 플루아지포프·부틸(fluazifop-butyl), 플루아지포프·P·부틸(fluazifop-P-butyl), 플루아졸레이트(fluazolate), 플루오메투론(fluometuron), 플루오로글리코펜·에틸(fluoroglycofen-ethyl), 플루카바존·나트륨염(flucarbazone-sodium), 플루클로랄린(fluchloralin), 플루세토설푸론(flucetosulfuron), 플루티아세트·메틸(fluthiacet-methyl), 플루필설푸론·메틸·나트륨염(flupyrsulfuron-methyl-sodium), 플루페나세트(flufenacet), 플루펜필·에틸(flufenpyr-ethyl), 플루프로파네이트(flupropanate), 플루폭삼(flupoxame), 플루미옥사진(flumioxazin), 플루미클로락·펜틸(flumiclorac-pentyl), 플루메트설람(flumetsulam), 플루리돈(fluridone), 플루르타몬(flurtamone), 플루록시필(fluroxypyr), 플루로클로리돈(flurochloridone), 프레틸라클로르(pretilachlor), 프로카바존·나트륨염(procarbazone-sodium), 프로다이아민(prodiamine), 프로설퓨론(prosulfuron), 프로설포카브(prosulfocarb), 프로파퀴자포프(propaquizafop), 프로파클로르(propachlor), 프로파진(propazine), 프로파닐(propanil), 프로피자마이드(propyzamide), 프로피소클로르(propisochlor), 프로피리설푸론(propyrisulfuron), 프로팜(propham), 프로플루아졸(profluazol), 프로폭시카바존·나트륨염(propoxycarbazone-sodium), 프로폭시딤(profoxydim), 브로마실(bromacil), 브롬피라존(brompyrazon), 프로메트린(prometryn), 프로메톤(prometon), 브로목시닐(bromoxynil)(부티르산, 옥탄산, 또는 헵탄산 등의 에스터체를 포함함), 브로모페녹심(bromofenoxim), 브로모부타이드(bromobutide), 플로라설람(florasulam), 플로필락시펜(florpyrauxifen), 헥사지논(hexazinone), 페톡사미드(pethoxamid), 베나졸린(benazolin), 페녹스설람(penoxsulam), 헵타말록실로글루칸(heptamaloxyloglucan), 베플루부타미드(beflubutamid), 페불레이트(pebulate), 펠랄르곤산(pelargonicacid), 벤카바존(bencarbazone), 펜디메탈린(pendimethalin), 벤즈펜디존(benzfendizone), 벤설라이드(bensulide), 벤설푸론·메틸(bensulfuron-methyl), 벤조바이사이클론(benzobicyclon), 벤조페납(benzofenap,), 벤타존(bentazone), 펜타노클로르(pentanochlor), 펜톡사존(pentoxazone), 벤플루랄린(benfluralin), 벤푸레세이트(benfuresate), 포사민(fosamine), 포메사펜(fomesafen), 포람설푸론(foramsulfuron), 메코프로프(mecoprop)(나트륨, 칼륨, 아이소프로필아민, 트라이에탄올아민, 다이메틸아민등의 염을 포함함), 메코프로프·P·칼륨염(mecoprop-P-potassium), 메소설푸론·메틸(mesosulfuron-methyl), 메소트라이온(mesotrione), 메타자클로르(metazachlor), 메타조설푸론(metazosulfuron), 메타벤즈티아주론(methabenzthiazuron), 메타미트론(metamitron), 메타미포프(metamifop), DSMA(메탄아르손 2나트륨), 메티오졸린 (methiozolin), 메틸디무론(methyldymuron), 메톡수론(metoxuron), 메토설람(metosulam), 메트설푸론·메틸(metsulfuron-methyl), 메토브로무론(metobromuron), 메토벤주론(metobenzuron), 메톨라클로르(metolachlor), 메트라이부진(metribuzin), 메페나세트(mefenacet), 모노설푸론(monosulfuron)(메틸, 에틸, 아이소프로필에스터를 포함한다), 모놀리누론(monolinuron), 몰리네이트(molinate), 아이오도설푸론(iodosulfuron), 아이오도설푸론·메틸·나트륨염(iodosulfulon-methyl-sodium), 이오펜설푸론(iofensulfuron), 이오펜설푸론·나트륨염(iofensulfuron-sodium), 락토펜(lactofen), 란코트리온(lancotrione), 리누론(linuron), 림설퓨론(rimsulfuron), 레나실(lenacil), TCA(2, 2, 2-트라이클로로아세트산) (나트륨, 칼슘 또는 암모니아 등의 염을 포함한다), 2,3,6-TBA(2,3,6-트라이클로로벤조산), 2,4,5-T(2,4,5-트라이클로로페녹시아세트산), 2,4-D(2,4-다이클로로페녹시아세트산)(아민, 다이에틸아민, 트라이에탄올아민, 아이소프로필아민, 나트륨 또는 리튬 등의 염을 포함함), ACN(2-아미노-3-클로로-1, 4-나프톡시논), MCPA(2-메틸-4-클로로페녹시아세트산), MCPB(2-메틸-4-클로로페녹시부티르산)(나트륨염, 에틸 에스터 등을 포함함), 2,4-DB(4-(2,4-다이클로로페녹시)부티르산, DNOC(4,6-다이니트로-o-크레졸)（아민 또는 나트륨 등의 염을 포함한다), AE-F-150944(코드번호), HW-02(코드번호), IR-6396(코드번호), MCPA-티오에틸(MCPA-thioethyl), SYP-298(코드 번호), SYP-300(코드 번호), EPTC(S-에틸다이프로필티오카밤산염), S-메톨라클로르(S-metolachlor).Acylin, acrolein, azafenidin, acifluorfen (including salts with sodium and the like), azimsulfuron, azine, and the like. At least one compound selected from the group consisting of asulam, acetochlor, atrazine, anilofos, amicarbazone, amidosulfuron, amitrole, aminocyclopyrachlor, Aminopyralid, amiprofos-methyl, ametryn, alachlor, alloxydim, isouron, isoxachlorotole, isoxanthol, ), Isoxaflutole, isoxaben, isoproturon, ipfencarbazone, imazaquin, imazapic (including salts with amines and the like) Imazapyr (including salts such as isopropylamine), and imazapyr Imazamethabenz-methyl, imazamox, imazethapyr, imazosulfuron, indaziflam, indanofan, ethylglycine, ethylglycine, such as eglinazine-ethyl, esprocarb, ethametsulfuron-methyl, ethalfluralin, ethidimuron, ethoxysulfuron, ethoxyphene, But are not limited to, ethoxyfen-ethyl, ethofumesate, etobenzanid, endothal-disodium, oxadiazon, oxadiargyl, oxaziclonefone, oxazulfuron oxyfluorfen, oryzalin, orthosulfamuron, orbencarb, oleicacid, cafenstrole, car (including but not limited to, Carfentrazone-ethyl, carbutilate, carbetamid, de, quizalofop-ethyl, quizalofop-P-ethyl, quizalofop-P-tefuryl, quinoclamine, ), Quinclorac, quinmerac, cumyluron, clacyfos, glyphosate (sodium, potassium, ammonium, amine, propylamine, isopropylamine, Glufosinate (including salts such as amines or sodium salts), glufosinate-P-sodium salts (including salts such as dimethylamine or tri-mesylate), glufosinate The compounds of the present invention may be used in combination with clethodim, clodinafop-propargyl, clopyralid, clomazone, chlomethoxyfen, clomeprop, Cloransulam-methyl, chloramben, chloridazon, chlorimuron-ethyl, chlorsulfur, on, chlorthal-dimethyl, chlorthiamid, chlorphthalim, chlorfluronol-methyl, chlorpropham, chlorbromorone (chlorfluronol-methyl) chlorobromuron, chloroxuron, chlorotoluron, ketospiradox (including salts such as sodium, calcium or ammonia), saflufenacil, sarmentine, , Cyanazine, cyanamide, diuron, diethatyl-ethyl, dicamba (amine, diethylamine, isopropylamine, diglycol Amine, sodium or lithium, etc.), cycloate, cycloxydim, diclosulam, cyclosulfamuron, cyclopyrimorate, diclofenac, Dichlobenyl, diclofenop, pme Diclofop-P-methyl, diclofop-methyl, dichlorprop, dichlorprop-P, diquat, dithiopyr, siduron, dinitramine, cinidon-ethyl, cinosulfuron, dinoseb, dinoterb, cyhalofop, But are not limited to, cyhalofop-butyl, diphenamid, difenzoquat, diflufenican, diflufenzopyr, simazine, dimethachlor, Dimethametryn, dimethenamid, dimethhenamid-P, simetryn, dimepiperate, dimefuron, nephrin, and the like. Such as cinmethylin, swep, sulcotrione, sulfentrazone, sulfosate, sulfosulfuron, sulfo, The compounds of the present invention may be used in combination with other drugs such as sulfometuron-methyl, sethoxydim, terbacil, daimuron, thaxtomin A, dalapon, thiazopyr, Thiocarbazone, thiocarbazil, thiobencarb, thidiazimin, thiencarbazone (including sodium salt, methyl ester, etc.), thiocarbazide, but are not limited to, thifensulfuron-methyl, desmedipham, desmetryne, thenylchlor, tebutam, tebuthiuron, tepraloxydim, But are not limited to, tefuryltrione, tembotrione, terbuthylazine, terbutryn, terbumeton, topramezone, tralkoxydim, But are not limited to, triaziflam, triasulfuron, triafamone, tri-allate, trietazi ne, triclopyr, triclopyr-butotyl, trifludimoxazin, tritosulfuron, triflusulfuron-methyl, Trifluralin, trifloxysulfuron-sodium, tribenuron-methyl, tolpyralate, naptalam (including salts with sodium and the like). ), Naproanilide, napropamide, napropamide-M, nicosulfuron, neburon, norflurazon, But are not limited to, vernolate, paraquat, haluxifen-benzyl, haluxifen-methyl, haloxyfop, haloxyfop, -P), haloxyfop-etotyl, halosafen, halosulfuron-methyl, picloram ( picloram, picolinafen, bicyclopyrone, bispyribac-sodium, pinoxaden, bifenox, piperophos, pyrazole, Pyraclonil, pyasulfotole, pyrazoxyfen, pyrazosulfuron-ethyl, pyrazolynate, bilanafos, pyrafluopen, Pyrafluro-ethyl, pyridafol, pyrithiobac-sodium, pyridate, pyriftalid, pyributicarb, pyrimidine, pyribenzoxim, pyrimisulfan, pyriminobac-methyl, pyroxasulfone, pyroxsulam, phenisopham, fenuron, phenoxysulfone, fenoxaprofen, fenoxasulfone, fenoxaprop (including methyl, ethyl, isopropyl esters), fenoxap prop-P) (including methyl, ethyl and isopropyl esters), fenquinotrione, fenthiaprop-ethyl, fentrazamide, phenmedipham, For example, foramsulfuron, butachlor, butafenacil, butamifos, butylate, butenachlor, butralin, butroxydim Flazasulfuron, flamprop (including methyl, ethyl, isopropyl ester), flamprop-M (including methyl, ethyl and isopropyl ester) Such as primisulfuron-methyl, fluazifop-butyl, fluazifop-P-butyl, fluazolate, fluometuron, , Fluoroglycofen-ethyl, flucarbazone-sodium, fluchloraldehyde, Flucuronin, flucetosulfuron, fluthiacet-methyl, flupyrsulfuron-methyl-sodium, flufenacet, flufenacet, But are not limited to, flufenpyr-ethyl, flupropanate, flupoxame, flumioxazin, flumiclorac-pentyl, flumetsulam, fluridone, flurtamone, fluroxypyr, flurochloridone, pretilachlor, procarbazone-sodium, prodiamine, prodiamine, Proparzamide, prosulfuron, prosulfocarb, propaquizafop, propachlor, propazine, propanil, propyzamide, Propisochlor, propyrisulfuron, propham, profluorescein, Propoxycarbazone-sodium, propoxydim, bromacil, brompyrazon, prometryn, prometon, prometamol, and the like. , Bromoxynil (including esters such as butyric acid, octanoic acid, or heptanoic acid), bromofenoxim, bromobutide, florasulam, but are not limited to, floropyrauxifen, hexazinone, pethoxamid, benazolin, penoxsulam, heptamaloxyloglucan, beflubutamid, pebulate, Pendimethalin, benzfendizone, bensulide, bensulfuron-methyl, benzobicyclo [2.2.1] quinolin-2-yl) benzenesulfonamide, benzobicyclon, benzofenap, bentazone, pentanochlor, Benzoxazin, pentoxazone, benfluralin, benfuresate, fosamine, fomesafen, foramsulfuron, mecoprop (sodium, potassium, Isopropylamine, triethanolamine, dimethylamine, and the like), mecoprop-P-potassium, mesosulfuron-methyl, mesotrione mesotrione, metazachlor, metazosulfuron, methabenzthiazuron, metamitron, metamifop, DSMA (methane arsenic di-sodium), methionine Methoxolin, methyldymuron, metoxuron, metosulam, metsulfuron-methyl, metobromuron, metobenzuron, metobenzuron, Metolachlor, metribuzin, mefenacet, monosulfuron (methyl, ethyl, isobutyl, Iodosulfuron, iodosulfulon-methyl-sodium, iopensulfuron (including iodosulfuron-methyl-sodium), monolinuron, molinate, iodosulfuron, iofensulfuron, iofensulfuron-sodium, lactofen, lancotrione, linuron, rimsulfuron, lenacil, TCA (2, Trichloroacetic acid) (including salts such as sodium, calcium or ammonia), 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,4,5-T (2 , 2,4-dichlorophenoxyacetic acid) (salts of amine, diethylamine, triethanolamine, isopropylamine, Methyl-4-chlorophenoxybutyric acid), ACN (2-amino-3-chloro-1,4-naphthoxynone), MCPA (Sodium salt, ethyl ester DNOC (4,6-dinitro-o-cresol) (including salts such as amines or sodium), 2,4-dichloro- MCPA-thioethyl, SYP-298 (code number), SYP-300 (code number), AE-F-150944 (code number), HW-02 Number), EPTC (S-ethyldipropylthiocarbamate), S-metolachlor.
[살충 활성성분][Insecticidal active ingredient]
아크리나트린(acrinathrin), 아자디라크틴(azadirachtin), 아자메티포스(azamethiphos), 아진포스·에틸(azinphos-ethyl), 아진포스·메틸(azinphos-methyl), 아세퀴노실(acequinocyl), 아세타미프리드(acetamiprid), 아세토프롤(acetoprole), 아세페이트(acephate), 아조사이클로틴(azocyclotin), 아바멕틴(abamectin), 아피도피로펜(afidopyropen), 아폭소레이나(afoxolaner), 아미도플루메트(amidoflumet), 아미트라즈(amitraz), 알라니카브(alanycarb), 알디카브(aldicarb), 알독시카브(aldoxycarb), 알레트린(allethrin)(이의 d-시스-트랜스-체 및 d-트랜스-체를 포함함), 이사조포스(isazophos), 아사미도포스(isamidofos), 이소카보포스(isocarbophos), 이속사티온(isoxathion), 이소펜포스·메틸(isofenphos-methyl), 이소프로카브(isoprocarb), 이베멕틴(ivermectin), 이미시아포스(imicyafos), 이미다클로프리드(imidacloprid), 이미프로트린(imiprothrin), 인독사카브(indoxacarb), 에스펜발레레이트(esfenvalerate), 에티오펜카브(ethiofencarb), 에티온(ethion), 에티프롤(ethiprole), 에틸렌 다이브로마이드(ethylene dibromide), 에톡사졸(etoxazole), 에토펜프록스(etofenrpox), 에토프로포스(ethoprophos), 에트림포스(etrimfos), 에마멕틴 벤조에이트(emamectin benzoate), 엔도설판(endosulfan), 엠펜트린(empenthrin), 옥사밀(oxamyl), 옥시데메톤·메틸(oxydemeton-methyl), 옥시데프로포스(oxydeprofos), 오메토에이트(omethoate), 카두사포스(cadusafos), 카파-테플루트린(kappa-tefluthrin), 카파-바이펜트린(kappa-bifenthrin), 카란진(karanjin), 카탑(cartap), 카바릴(carbaryl), 카보설판(carbosulfan), 카보푸란(carbofuran), 감마-BHC(ga㎜a-BHC), 자일릴카브(xylylcarb), 퀴날포스(quinalphos), 키노프렌(kinoprene), 키노메티오나트(chinomethionat), 쿠마포스(coumaphos), 크리오라이트(cryolite), 클로티아니딘(clothianidin), 클로펜테진(clofentezine), 크로마페노자이드(chromafenozide), 클로란트라닐리프롤(chlorantraniliprole), 클로르에톡시포스(chlorethoxyfos), 클로르덴(chlordane), 클로로피크린(chloropicrin), 클로르피리포스(chlorpyrifos), 클로르피리포스·메틸(chlorpyrifos-methyl), 클로르페나필(chlorfenapyr), 클로르펜빈포스(chlorfenvinphos), 클로르플루아주론(chlorfluazuron), 클로르메포스(chlormephos), 클로로프랄레트린(chloroprallethrin), 사이아노포스(cyanophos), 다이아펜티우론(diafenthiuron), 다이아미다포스(diamidafos), 사이안트라닐리프롤(cyantraniliprole), 디에노클로르(dienochlor), 시에노피라펜(cyenopyrafen), 다이옥사벤조포스(dioxabenzofos), 다이오페놀란(diofenolan), 사이클라닐리프롤(cyclaniliprole), 다이크로토포스(dicrotophos), 다이클로펜티온(dichlofenthion), 사이클로프로트린(cycloprothrin), 다이클로르보스(dichlorvos), 다이클로로메조티아즈(dicoloromezotiaz), 1,3-다이클로로프로펜(1,3-dichloropropene), 다이코폴(dicofol), 다이사이클라닐(dicyclanil), 다이설포톤(disulfoton), 다이노테푸란(dinotefuran), 다이노부톤(dinobuton), 사이할로다이아마이드(cyhalodiamide), 사이할로트린(cyhalothrin)(감마체 및 람다체를 포함함), 사이페노트린(cyphenothrin)((1R)-트랜스-체를 포함함), 사이플루트린(cyfluthrin)(베타-체를 포함함), 다이플루벤주론(diflubenzuron), 사이플루메토펜(cyflumetofen), 다이플로비다진(diflovidazin), 사이헥사틴(cyhexatin), 사이퍼메트린(cypermethrin)(알파-체, 베타-체, 세타-체 및 제타-체를 포함함), 다이메틸빈포스(dimethylvinphos), 다이메플루트린(dimefluthrin), 다이메토에이트(dimethoate), 실라플루오펜(silafluofen), 사이로마진(cyromazine), 스핀토람(spinetoram), 스피노사드(spinosad), 스피로다이클로펜(spirodiclofen), 스피로테트라마트(spirotetramat), 스피로메시펜(spiromesifen), 설코푸론·나트륨염(sulcofuron-sodium), 설플루라미드(sulfluramid), 설폭사플로르(sulfoxaflor), 설포텝(sulfotep), 다이아지논(diazinon), 티아클로프리드(thiacloprid), 티아메톡삼(thiamethoxam), 티옥사자펜(tioxazafen), 티오다이카브(thiodicarb), 티오사이클람(thiocyclam), 티오설탭(thiosultap), 티오나진(thionazin), 티오파녹스(thiofanox), 티오메톤(thiometon), 테트라클로르빈포스(tetrachlorvinphos), 테트라디폰(tetradifon), 테트라닐리프롤(tetraniliprole), 테트라메틸플루트린(tetramethylfluthrin), 테트라메트린(tetramethrin), 테부피림포스(tebupirimfos), 테부페노자이드(tebufenozide), 테부펜피라드(tebufenpyrad), 테플루트린(tefluthrin), 테플루벤주론(teflubenzuron), 데메톤·S·메틸(demeton-S-methyl), 테메포스(temephos), 델타메트린(deltamethrin), 테르부포스(terbufos), 트랄로메트린(tralomethrin), 트랜스플루트린(transfluthrin), 트라이아자메이트(triazamate), 트라이아조포스(triazophos), 트라이클로르폰(trichlorfon), 트라이플루무론(triflumuron), 트라이플루메조피림(triflumezopyrim), 트라이메타카브(trimethacarb), 톨펜피라드(tolfenpyrad), 날레드(naled), 니텐피람(nitenpyram), 노발루론(novaluron), 노비플루무론(noviflumuron), 베르티실륨 레카니이(Verticillium lecanii), 하이드로프렌(hydroprene), 파스퇴리아페네트랜스포자(Pasteuriapenetrans), 바미도티온(vamidothion), 파라티온(parathion), 파라티온-메틸(parathion-methyl), 할펜프록스(halfenprox), 할로페노자이드(halofenozide), 바이오알레트린(bioallethrin), 바이오알레트린 S-사이클로펜테닐(bioallethrin S-cyclopentenyl), 바이오레스메트린(bioresmethrin), 비스트라이플루론(bistrifluron), 하이드라메틸논(hydramethylnon), 비페나제이트(bifenazate), 비펜트린(bifenthrin), 피플루부마이드(pyflubumide), 피페로닐 부톡사이드(piperonyl butoxide), 피메트로진(pymetrozine), 피라클로포스(pyraclofos), 피라플루프롤(pyrafluprole), 피리다펜티온(pyridaphenthion), 피리다벤(pyridaben), 피리달릴(pyridalyl), 피리플루퀴나존(pyrifluquinazon), 피리프롤(pyriprole), 피리프록시펜(pyriproxyfen), 피리미카브(pirimicarb), 피리미디펜(pyrimidifen), 피리미노스트로빈(pyriminostrobin), 피리미포스·메틸(pirimiphos-methyl), 피레트린(pyrethrine), 팜푸르(famphur), 피프로닐(fipronil), 페나자퀸(fenazaquin), 페나미포스(fenamiphos), 페니트로티온(fenitrothion), 페녹시카브(fenoxycarb), 페노티오카브(fenothiocarb), 페노트린(phenothrin)((1R)-트랜스-체를 포함함), 페노부카브(fenobucarb), 펜티온(fenthion), 펜토에이트(phenthoate), 펜발레레이트(fenvalerate), 펜피록시메이트(fenpyroximate), 펜부타틴 옥사이드(fenbutatin oxide), 펜프로파트린(fenpropathrin), 포노포스(fonofos), 플루오린화설푸릴(sulfuryl fluoride), 부토카복심(butocarboxim), 부톡시카복심(butoxycarboxim), 부프로페진(buprofezin), 푸라티오카브(furathiocarb), 프랄레트린(prallethrin), 플루아크리피림(fluacrypyrim), 플루아자인도리진(fluazaindolizine), 플루아주론(fluazuron), 플루엔설폰(fluensulfone), 플루오로아세트산나트륨염(sodium fluoroacetate), 플럭사메타미드(fluxametamide), 플루사이클록수론(flucycloxuron), 플루사이트리네이트(flucythrinate), 플루설파마이드(flusulfamide), 플루발리네이트(fluvalinate)[타우-체를 포함함], 플루피라디푸론(flupyradifurone), 플루피라조포스(flupyrazofos), 플루피프롤(flufiprole), 플루페네림(flufenerim), 플루페녹시스트로빈(flufenoxystrobin), 플루페녹수론(flufenoxuron), 플루헥사폰(fluhexafon), 플루벤다이아마이드(flubendiamide), 플루메트린(flumethrin), 프로트라이펜부트(protrifenbute), 프로티오포스(prothiofos), 프로트라이펜부트(protrifenbute), 플로니카미드(flonicamid), 프로파포스(propaphos), 프로파르가이트(propargite), 프로페노포스(profenofos), 브로플라닐라이드(broflanilide), 프로플루트린(profluthrin), 프로페탐포스(propetamphos), 프로폭수르(propoxur), 플로메토퀸(flometoquin), 브로모프로필레이트(bromopropylate), 헥시티아족스(hexythiazox), 헥사플루무론(hexaflumuron), 패실로마이세스 테누이페스(Paecilomyces tenuipes), 패실로마이세스 푸모소로세우스(Paecilomyces fumosoroceus), 헵타플루트린(heptafluthrin), 헵테노포스(heptenophos), 퍼메트린(permethrin), 벤클로티아즈(benclothiaz), 벤설탭(bensultap), 벤족시메이트(benzoximate), 벤다이오카브(bendiocarb), 벤푸라카브(benfuracarb), 뷰베리아·테넬라(Beauveria tenella), 뷰베리아·바시아나(Beauveria bassiana), 뷰베리아 브롱니아르티이(Beauveria brongniartii), 폭심(phoxim), 포살론(phosalone), 포스티아제이트(fosthiazate), 포스티에탄(fosthietan), 포스파미돈(phosphamidon), 포스메트(phosmet), 폴리낙틴스(polynactins), 포메타네이트(formetanate), 포레이트(phorate), 말라티온(malathion), 밀베멕틴(milbemectin), 메카밤(mecarbam), 메설펜포스(mesulfenfos), 메토프렌(methoprene), 메토밀(methomyl), 메타플루미존(metaflumizone), 메타미도포스(methamidophos), 메탐(metham), 메티오카브(methiocarb), 메티다티온(methidathion), 메틸 아이소티오사이아네이트(methyl isothiocyanate), 메틸 브로마이드(methyl bromide), 메톡시클로르(methoxychlor), 메톡시페노자이드(methoxyfenozide), 메토트린(methothrin), 메토플루트린(metofluthrin), 엡실론－메토플루트린(epsilon-metofluthrin), 메톨카브(metolcarb), 메빈포스(mevinphos), 메펠플루트린(meperfluthrin), 모나크로스포륨 피마토파굼(Monacrosporium phymatophagum), 모노크로토포스(monocrotophos), 몸플루로트린(momfluorothrin), 엡실론－몸플루오로트린(epsilon-momfluorothrin), 리틀루어-A(litlure-A), 리틀루어-B(litlure-B), 인화알루미늄(aluminium phosphide), 인화아연(zinc phosphide), 포스핀(phosphine), 루페누론(lufenuron), 레스칼루어(rescalure), 레스메트린(resmethrin), 레피멕틴(lepimectin), 로테논(rotenone), 펜부타주석 옥사이드(fenbutatin oxide), 사이안화칼슘(calcium cyanide), 황산니코틴(nicotinesulfate), (Z)-11-테트라데세닐=아세테이트, (Z)-11-헥사데세날, (Z)-11-헥세데세닐=아세테이트, (Z)-9,12-테트라데카다이엔일=아세테이트, (Z)-9-테트라데센-1-올, (Z,E)-9,11-테트라데카다이엔일=아세테이트, (Z,E)-9,12-테트라데카다이엔일=아세테이트, 바실러스·포필리애(Bacillus popilliae), 바실러스·서브틸리스(Bacillus subtillis), 바실러스·스패리쿠스(Bacillus sphaericus), 바실러스·투린지엔시스·아종·아이자와이(Bacillus thuringiensis subsp. Aizawai), 바실러스·투린지엔시스·아종·이스라엘렌시스(Bacillus thuringiensis subsp. Israelensis), 바실러스·트린지엔시스·아종·쿠르스타키(Bacillus thuringiensis subsp. Kurstaki), 바실러스·투린지엔시스·아종·테네브리오니스(Bacillus thuringiensis subsp. Tenebrionis), Bt 단백질(Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34/35Ab1), CL900167(코드 번호), DCIP(비스-(2-클로로-1-메틸에틸)에터), DDT(1,1,1-트라이클로로-2,2-비스(4-클로로페닐)에탄), DEP(다이메틸-2,2,2-트라이클로로-1-하이드록시에틸포스포네이트), DNOC(4,6-다이나이트로-o-크레졸), DSP(O,O-다이에틸-O-[4-다이메틸설파모일]페닐)포스포티오에이트), EPN(O-에틸-O-4-(나이트로페닐)페닐포스포노티오에이트), 핵다각체 바이러스 포매체, NA-85(코드 번호), NA-89(코드 번호), NC-515(코드 번호), RU15525(코드 번호), ZDI-2501(코드 번호), XMC, Z-13-에이코센-10-온, ZXI8901(코드 번호), ME5382.Azinphos-ethyl, azinphos-methyl, acequinocyl, acetic acid, acetic acid, acetic acid, acetic acid, acridine, azadirachtin, azamethiphos, azinphos- The use of acetamiprid, acetoprole, acephate, azocyclotin, abamectin, afidopyropen, afoxolaner, amidofluamet, amidoflumet, amitraz, alanycarb, aldicarb, aldoxycarb, allethrin (including its d-cis-trans and d-trans- Isomerophos, isocarbophos, isoxathion, isofenphos-methyl, isoprocarb (including isoprocarb), isoproterenol, ), Ivermectin, imicyafos, imidacloprid, imiprothrin, But are not limited to, indoxacarb, esfenvalerate, ethiofencarb, ethion, ethiprole, ethylene dibromide, etoxazole, etofenrpox, ethoprophos, etrimfos, emamectin benzoate, endosulfan, empenthrin, oxamyl, oxydemethone methyl ( oxydemeton-methyl, oxydeprofos, omethoate, cadusafos, kappa-tefluthrin, kappa-bifenthrin, Carbapenes, carbofuran, gamma-BHC, xylylcarb, quinalphos, caramel, caramel, caramel, , Quinoprene, chinomethionate, coumaphos, cryolite, clothianidin, clovers, But are not limited to, clofentezine, chromafenozide, chlorantraniliprole, chlorethoxyfos, chlordane, chloropicrin, chlorpyrifos, Chlorpyrifos-methyl, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chloroprallethrin, cyanophosphorus, chloramphenicol, cyanophos, diafenthiuron, diamidafos, cyantraniliprole, dienochlor, cyenopyrafen, dioxabenzofos, and the like. Diofenolan, cyclaniliprole, dicrotophos, dichlofenthion, cycloprothrin, dichlorvos, dichloromethane, and the like. Dicoloromezotiaz, 1,3-dichloropropene, dicofol, dicyclanil, disulfoton, dinotefuran, and the like. Cyhalothiamide, cyhalothrin (including gamma and lambda), cyphenothrin ((1R) -trans-sialate), diphosphonic acid, Cyfluthrin (including beta-form), diflubenzuron, cyflumetofen, diflovidazin, cyhexatin, and the like, But are not limited to, cypermethrin (including alpha-, beta-, ceta- and zeta-sieves), dimethylvinphos, dimefluthrin, dimethoate, But are not limited to, silafluofen, cyromazine, spinetoram, spinosad, spirodiclofen, But are not limited to, spirotetramat, spiromesifen, sulcofuron-sodium, sulfluramid, sulfoxaflor, sulfotep, diazinon, Thiacloprid, thiamethoxam, tioxazafen, thiodicarb, thiocyclam, thiosultap, thionazin, thiopyranose, thiopyranose, but are not limited to, thiofanox, thiometon, tetrachlorvinphos, tetradifon, tetraniliprole, tetramethylfluthrin, tetramethrin, Tebupirimfos, tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, demeton-S-methyl, tebufenpyrad, tefluthrin, Such as temephos, deltamethrin, terbufos, tralomethrin, n), transfluthrin, triazamate, triazophos, trichlorfon, triflumuron, triflumezopyrim, trymacarb (triflumuron, trimethicarb, tolfenpyrad, naled, nitenpyram, novaluron, noviflumuron, Verticillium lecanii , hydroprene, ), Pasteuriapenetrans, vamidothion, parathion, parathion-methyl, halfenprox, halofenozide, bioleetrine, bioallethrin, bioallethrin, S-cyclopentenyl, bioresmethrin, bistrifluron, hydramethylnon, bifenazate, , Bifenthrin, But are not limited to, pyruvic acid, pyromellitic acid, pyruvic acid, pyromellitic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyruvic acid, pyridaben, pyridalyl, pyrifluquinazon, pyriprole, pyriproxyfen, pyrimicarb, pyrimidifen, pyriminostrobin (pyrimidine), pyrimidine pyriminostrobin, pirimiphos-methyl, pyrethrine, famphur, fipronil, fenazaquin, fenamiphos, penitrothion ( fenothiocarb, phenothrin (including the (1R) -trans-sieve), fenobucarb, fenthion, pentaerythritol, fenitrothion, fenoxycarb, fenothiocarb, Phenobarbital, phenothiose, fenvalerate, fenpyroximate, fenbutatin oxide, But are not limited to, fenpropathrin, fonofos, sulfuryl fluoride, butocarboxim, butoxycarboxim, buprofezin, furathiocarb, The compounds of the present invention may be used in combination with other drugs such as prallethrin, fluacrypyrim, fluazaindolizine, fluazuron, fluensulfone, sodium fluoroacetate, flumametamide, flucycloxuron, flucythrinate, flusulfamide, fluvalinate [including tau-sieve], flupyradifurone, fluvastatin, fluvastatin, But are not limited to, flupyrazofos, flufiprole, flufenerim, flufenoxystrobin, flufenoxuron, fluhexafon, flubendiamide, , Flumethrin, But are not limited to, protrifenbute, prothiofos, protrifenbute, flonicamid, propaphos, propargite, profenofos, But are not limited to, but are not limited to, bromocriptine, bromocriptine, broflanilide, profluthrin, propetamphos, propoxur, flometoquin, bromopropylate, hexythiazox ), Hexaflumuron, Paecilomyces tenuipes , Paecilomyces fumosoroceus , heptafluthrin, heptenophos, permethrin, < RTI ID = 0.0 & but are not limited to, permethrin, benclothiaz, bensultap, benzoximate, bendiocarb, benfuracarb, Beauveria tenella, Beauveria bassiana, But are not limited to, beauveria brongniartii, phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosmet, polynactins, formetanate, phorate, malathion, milbemectin, mecarbam, mesulfenfos, methoprene, metamil ( methamyl, methamyl, metaflumizone, methamidophos, metham, methiocarb, methidathion, methyl isothiocyanate, methyl bromide methyl bromide, methoxychlor, methoxyfenozide, methothrin, metofluthrin, epsilon-metofluthrin, methocarb (methotrexate), methotrexate metolcarb), mevinphos, meperfluthrin, monacrosporium phimatopag ( Mo nacrosporium phymatophagum , monocrotophos, momfluorothrin , epsilon-momfluorothrin, litlure-A, litlure-B, Aluminum phosphide, zinc phosphide, phosphine, lufenuron, rescalure, resmethrin, lepimectin, rothenone, rotenone, fenbutatin oxide, calcium cyanide, nicotinesulfate, (Z) -11-tetradecenyl acetate, (Z) -11-hexadecenyl, (Z) -9,12-tetradecadienyl acetate, (Z) -9-tetradecen-1-ol, Decadienyl acetate, (Z, E) -9,12-tetradecadienyl acetate, Bacillus popilliae , Bacillus subtillis , Bacillus spicicus , (Bacillu sphaericus), Bacillus thuringiensis subsp. < / RTI & gt ; Aizawai ), Bacillus thuringiensis subsp. Israelensis , Bacillus thuringiensis subsp. Kurstaki , Bacillus thuringiensis subsp. Kurstaki , Bacillus thuringiensis subsp. (Biclonius thuringiensis subsp. Tenebrionis ), Bt protein (Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Ab1), CL900167 Ethyl) ether, DDT (1,1,1-trichloro-2,2-bis (4-chlorophenyl) ethane), DEP (dimethyl-2,2,2-trichloro-1- sulfonate), DNOC (4,6- difluoro- nitro - o - cresol), DSP (O, O- diethyl -O- [4- dimethyl-sulfamoyl] phenyl) phosphite Eight Fourteen O), EPN (O- NA-85 (code number), NA-89 (code number), NC-515 (code number), RU15525 (code number) Code number), ZDI-2501 (code number), XMC , Z-13-Eicosene-10-one, ZXI8901 (code number), ME5382.
［살균활성성분］[Bactericidal active ingredient]
아자코나졸(azaconazole), 아시벤졸라·S·메틸(acibenzolar-S-methyl), 아족시스트로빈(azoxystrobin), 아닐라진(anilazine), 아미설브롬(amisulbrom), 아메톡트라딘(ametoctradin), 알디몰프(aldimorph), 아이소티아닐(isotianil), 아이소피라잠(isopyrazam), 아이소페타미드(isofetamid), 아이소프로티올란(isoprothiolane), 이프코나졸(ipconazole), 이프펜트리플루코나졸(ipfentrifluconazole), 이프로디온(iprodione), 이프로발리카브(iprovalicarb), 이프로벤포스(iprobenfos), 이마잘릴(imazalil), 이미녹타딘-트라이알베실레이트(iminoctadine-trialbesilate), 이미녹타딘트라이아세테이트(iminoctadine-triacetate), 이미벤코나졸(imibenconazole), 에디펜포스(edifenphos), 에타코나졸(etaconazole), 에타복삼(ethaboxam), 에티리몰(ethirimol), 에톡시퀸(ethoxyquin), 에트리디아졸(etridiazole), 에네스트로부린(enestroburin), 에녹사스트로빈(enoxastrobin), 에폭시코나졸(epoxiconazole), 오가닉 오일(organic oil), 옥사딕실(oxadixyl), 옥사진일라졸(oxazinylazole), 옥사티아피프롤린(oxathiapiprolin), 옥시카복신(oxycarboxin), 옥신-구리(oxine-copper), 옥시테트라사이클린(oxytetracycline), 옥스포코나졸-푸말산염(oxpoconazole-fumarate), 옥솔린산(oxolinic acid), 다이옥탄산구리(copper dioctanoate), 옥틸리논(octhilinone), 오푸라세(ofurace), 오리사스트로빈(orysastrobin), o-페닐페놀(o-phenylphenol), 카스가마이신(kasugamycin), 캅타폴(captafol), 카프로파미드(carpropamid), 카벤다짐(carbendazim), 카복신(carboxin), 카르본(carvone), 퀴녹시펜(quinoxyfen), 퀴노푸멜린(quinofumelin), 키노메티오나트(chinomethionat), 캅탄(captan), 퀸코나졸(quinconazole), 퀸토젠(quintozene), 구아자틴(guazatine), 쿠프라넵(cufraneb), 쿠목시스트로빈(coumoxystrobin), 크레속심·메틸(kresoxim-methyl), 클로질라콘(clozylacon), 클로졸리네이트(chlozolinate), 클로로탈로닐(chlorothalonil), 클로로넵(chloroneb), 시아조파마이드(cyazofamid), 다이에토펜카브(diethofencarb), 다이클로시메트(diclocymet), 다이클로플루아니드(dichlofluanid), 다이클로메진(diclomezine), 다이클로란(dicloran), 다이클로로펜(dichlorophen), 다이티아논(dithianon), 다이니코나졸(diniconazole), 다이니코나졸·M(diniconazole-M), 지넵(zineb), 디노캅(dinocap), 다이피메티트론(dipymetitrone), 다이페닐아민(diphenylamine), 다이페노코나졸(difenoconazole), 시플루페나미드(cyflufenamid), 디플루메토림(diflumetorim), 시프로코나졸(cyproconazole), 시프로디닐(cyprodinil), 시메코나졸(simeconazole), 다이메티리몰(dimethirimol), 다이메틸 다이설파이드(dimethyl disulfide), 다이메토몰프(dimethomorph), 시목사닐(cymoxanil), 다이목시스트로빈(dimoxystrobin), 지람(ziram), 실티오팜(silthiofam), 스트렙토마이신(streptomycin), 스피록사민(spiroxamine), 세닥산(sedaxane), 족사마이드(zoxamide), 다조메트(dazomet), 티아디닐(tiadinil), 티아벤다졸(thiabendazole), 티람(thiram), 티오파네이트(thiophanate), 티오페네이트-메틸(thiophanate-methyl), 티플루자마이드(thifluzamide), 테크나젠(tecnazene), 테클로프탈람(tecloftalam), 테트라코나졸(tetraconazole), 데바카브(debacarb), 테부코나졸(tebuconazole), 테부플로퀸(tebufloquin), 터비나핀(terbinafine), 도딘(dodine), 도데몰프(dodemorph), 트라이아디메놀(triadimenol), 트라이아디메폰(triadimefon), 트라이아족사이드(triazoxide), 트라이클라마이드(trichlamide), 트라이클로피리카브(triclopyricarb), 트라이사이클라졸(tricyclazole), 트라이티코나졸(triticonazole), 트라이데몰프(tridemorph), 트라이플루미졸(triflumizole), 트라이플록시스트로빈(trifloxystrobin), 트라이포린(triforine), 톨릴플루아니드(tolylfluanid), 톨클로포스·메틸(tolclofos-methyl), 톨니파나이드(tolnifanide), 톨프로카브(tolprocarb), 나밤(nabam), 나타마이신(natamycin), 나프티핀(naftifine), 니트라피린(nitrapyrin), 니트로탈·아이소프로필(nitrothal-isopropyl), 누아리몰(nuarimol), 노닐 페놀 설폰산 구리(copper nonyl phenol sulphonate), 바실러스·서브틸리스(Bacillus subtilis)(균주: QST 713), 발리다마이신(validamycin), 발리페날레이트(valifenalate), 피카부트라족스(picarbutrazox), 빅사펜(bixafen), 피콕시스트로빈(picoxystrobin), 피디플루메토펜(pydiflumetofen), 비텔타놀(bitertanol), 비나파크릴(binapacryl), 바이페닐(biphenyl), 피페랄린(piperalin), 히멕사졸(hymexazol), 피라옥시스트로빈(pyraoxystrobin), 피라클로스트로빈(pyraclostrobin), 피라지플루미드(pyraziflumid), 피라조포스(pyrazophos), 피라메토스트로빈(pyrametostrobin), 피리오페논(pyriofenone), 피리속사졸(pyrisoxazole), 피리페녹스(pyrifenox), 피리부티카브(pyributicarb), 피리벤카브(pyribencarb), 피리메타닐(pyrimethanil), 피로퀼론(pyroquilon), 빈클로졸린(vinclozolin), 퍼밤(ferbam), 파목사돈(famoxadone), 페나진 옥사이드(phenazine oxide), 페나미돈(fenamidone), 페나민스트로빈(fenaminstrobin), 페나리몰(fenarimol), 페녹사닐(fenoxanil), 페림존(ferimzone), 펜피클로닐(fenpiclonil), 펜피콕사미드(fenpicoxamid), 펜피라자민(fenpyrazamine), 펜부코나졸(fenbuconazole), 펜푸람(fenfuram), 펜프로피딘(fenpropidin), 펜프로피모프(fenpropimorph), 펜헥사미드(fenhexamid), 폴페트(folpet), 프탈라이드(phthalide), 부피리메이트(bupirimate), 부페리다졸(fuberidazole), 블라스티시딘-S(blasticidin-S), 푸라메트필(furametpyr), 푸랄락실(furalaxyl), 푸란카복실산(furancarboxylic acid), 플루아지난(fluazinam), 플루이다필(fluindapyr), 플루옥사스트로빈(fluoxastrobin), 플루오피콜라이드(fluopicolide), 플루오피람(fluopyram), 플루오로이미드(fluoroimide), 플룩사피록사드(fluxapyroxad), 플루퀸코나졸(fluquinconazole), 푸르코나졸(furconazole), 푸르코나졸·시스(furconazole-cis), 플루디옥소닐(fludioxonil), 플루실라졸(flusilazole), 플루설파마이드(flusulfamide), 플루티아닐(flutianil), 플루톨라닐(flutolanil), 플루트리아폴(flutriafol), 플루페녹시스트로빈(flufenoxystrobin), 플루메토버(flumetover), 플루몰프(flumorph), 프로퀴나지드(proquinazid), 프로클로라즈(prochloraz), 프로시미돈(procymidone), 프로티오카브(prothiocarb), 프로티오코나졸(prothioconazole), 브로노폴(bronopol), 프로파모카브·염산염(propamocarb-hydrochloride), 프로피코나졸(propiconazole), 프로피네브(propineb), 프로베나졸(probenazole), 브로무코나졸(bromuconazole), 플로메토퀸(flometoquin), 헥사코나졸(hexaconazole), 베날락실(benalaxyl), 베날락실·M(benalaxyl-M), 베노다닐(benodanil), 베노밀(benomyl), 페푸라조에이트(pefurazoate), 펜코나졸(penconazole), 펜시쿠론(pencycuron), 벤조빈디플루필(benzovindiflupyr), 벤티아졸(benthiazole), 벤티아발리카브·아이소프로필(benthiavalicarb-isopropyl), 펜티오피라드(penthiopyrad), 펜플루펜(penflufen), 보스칼리드(boscalid), 포세틸(fosetyl)(알루미늄, 칼슘, 나트륨), 폴리옥신(polyoxin), 폴리카바메이트(polycarbamate), 보르도액(Bordeaux mixture), 만코제브(mancozeb), 만디프로파미드(mandipropamid), 만데스트로빈(mandestrobin), 만네브(maneb), 미클로부타닐(myclobutanil), 광유(mineral oil), 밀디오마이신(mildiomycin), 메타설포카브(methasulfocarb), 메탐(metam), 메탈락실(metalaxyl), 메탈락실·M(metalaxyl-M), 메티람(metiram), 메트코나졸(metconazole), 메토미노스트로빈(metominostrobin), 메트라페논(metrafenone), 메파니피림(mepanipyrim), 메펜트라이플루코나롤(mefentrifluconazole), 메프틸디노캅(meptyldinocap), 메프로닐(mepronil), 아이오도카브(iodocarb), 라미나린(laminarin), 아인산 및 염(phosphorous acid and salts), 옥시염화구리(copper oxychloride), 은(silver), 산화제일구리(cuprous oxide), 수산화제이구리(copper hydroxide), 중탄산칼륨(potassium bicarbonate), 중탄산나트륨(sodium bicarbonate), 황(sulfur), 황산옥시퀴놀린(oxyquinoline sulfate), 황산구리(copper sulfate), (3,4-다이클로로아이소티아졸-5-일) 메틸-4-(tert-부틸)벤조산에스터(화학명, CAS 등록번호: 1231214-23-5), 3-((3,4-다이클로로아이소티아졸-5-일)메톡시)벤조[d]아이소티아졸-1,1-다이옥사이드(화학명, CAS 등록번호: 957144-77-3), BAF-045(코드 번호), BAG-010(코드 번호), UK-2A(코드 번호), DBEDC(도데실벤젠설폰산 비스에틸렌다이아민 구리[II]염), MIF-1002(코드 번호), TPTA(에세트산 트라이페닐주석), TPTC(트라이페닐주석 클로라이드), TPTH(수산화트라이페닐주석), 비병원성 에르위니아·카로토보라.Azaconazole, acibenzolar-S-methyl, azoxystrobin, anilazine, amisulbrom, ametoctadin, amoxycillin, But are not limited to, aldimorph, isotianil, isopyrazam, isofetamid, isoprothiolane, ipconazole, ipfentrifluconazole, Iprodione, iprovalicarb, iprobenfos, imazalil, iminoctadine-trialbesilate, iminoctadine-triacetate, iminoctadine-triacetate, , Imibenconazole, edifenphos, etaconazole, ethaboxam, ethirimol, ethoxyquin, etridiazole, enethoxazole, etendazole, Enestroburin, enoxastrobin, epoxy Epoxiconazole, organic oil, oxadixyl, oxazinylazole, oxathiapiprolin, oxycarboxin, oxine-copper, Oxytetracycline, oxpoconazole-fumarate, oxolinic acid, copper dioctanoate, octhilinone, ofurace, orisaceous acid, Carboxymethylcellulose, carboxymethylcellulose, carboxymethylcellulose, carboxymethylcellulose, carboxymethylcellulose, carboxymethylcellulose, orisastrobin, o-phenylphenol, kasugamycin, captafol, carpropamid, carbendazim, carnitine, carvone, quinoxyfen, quinofumelin, chinomethionate, captan, quinconazole, quintozene, guazatine, Cufraneb, coumoxystrobin, kresoxim-methyl, clozylacon, clozzoli, Chlozolinate, chlorothalonil, chloroneb, cyazofamid, diethofencarb, diclocymet, dichlofluanid, and the like. Diclonezine, dicloran, dichlorophen, dithianon, diniconazole, diniconazole-M, zineb, and the like. Diazepam, dinocap, dipymetitrone, diphenylamine, difenoconazole, cyflufenamid, diflumetorim, ciproconazole (see, for example, The compounds of the present invention can be used in combination with other cytotoxic agents such as cyproconazole, cyprodinil, simeconazole, dimethirimol, dimethyl disulfide, dimethomorph, cymoxanil, dimoxystrobin, ziram, silthiofam, streptomycin, streptomycin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, yin, thiophanate, thiophanate-methyl, thifluzamide, tecnazene, tecloftalam, tetraconazole, debacarb, te The compounds of the present invention may be used in combination with other therapeutic agents such as tebuconazole, tebufloquin, terbinafine, dodine, dodemorph, triadimenol, triadimefon, triazoxide ), Trichlamycide, triclopyricarb, tricyclazole, triticonazole, tridemorph, triflumizole, trifloxystrobin, trifloxystrobin, triforine, tolylfluanid, Tolclofos-methyl, tolnifanide, tolprocarb, nabam, natamycin, naftifine, nitrapyrin, nitrotamine, Nitrothal-isopropyl, nuarimol, copper nonyl phenol sulphonate, Bacillus subtilis (strain: QST 713), validamycin, But are not limited to, for example, valifenalate, picarbutrazox, bixafen, picoxystrobin, pydiflumetofen, bitertanol, binapacryl, biphenyls, a biphenyl, a piperalin, a hymexazol, pyraoxystrobin, pyraclostrobin, pyraziflumid, pyrazophos, pyrametoste, Pyrametostrobin, pyriofenone, pyrisoxazole, But are not limited to, pyrifenox, pyributicarb, pyribencarb, pyrimethanil, pyroquilon, vinclozolin, ferbam, famoxadone, phenazine oxide, fenamidone, fenaminstrobin, fenarimol, fenoxanil, ferimzone, phenclodonil, fenpicolonil, fenpicoxamid, fenpyrazamine, fenbuconazole, fenfuram, fenpropidin, fenpropimorph, fenhexamid, ), Folpet, phthalide, bupirimate, fuberidazole, blasticidin-S, furametpyr, furalic acid furalaxyl, furancarboxylic acid, fluazinam, fluindapyr, fluoxastrobin, The compounds of the present invention may be selected from the group consisting of fluopicolide, fluopyram, fluoroimide, fluxapyroxad, fluquinconazole, furconazole, furconazole-cis ), Flumioxonil, flusilazole, flusulfamide, flutianil, flutolanil, flutriafol, fluphenoxystrobin (see, for example, prothioconazole, prothiocarb, prothioconazole, prothioconazole, prothiocarb, prothiocarb, prothiocarb, prothioconazole, prothioconazole, ), Branopol, propamocarb-hydrochloride, propiconazole, propineb, probenazole, bromuconazole, flomethasone, Flometoquin, hexaconazole, benalaxyl, benalacil, M benalbumin, benalaxyl-M, benodanil, benomyl, pefurazoate, penconazole, pencycuron, benzovindiflupyr, benthiazole, benthiavalicarb-isopropyl, penthiopyrad, penflufen, boscalid, fosetyl (aluminum, calcium, sodium), poly But are not limited to, polyoxin, polycarbamate, Bordeaux mixture, mancozeb, mandipropamid, mandestrobin, maneb, such as myclobutanil, mineral oil, mildiomycin, methasulfocarb, metam, metalaxyl, metalaxyl-M, metiram, ), Metconazole, metominostrobin, metrafenone, mepanipyrim, mefent rifle, But are not limited to, mefentrifluconazole, meptyldinocap, mepronil, iodocarb, laminarin, phosphorous acid and salts, copper oxychloride Silver, cuprous oxide, copper hydroxide, potassium bicarbonate, sodium bicarbonate, sulfur, oxyquinoline sulfate, sodium bicarbonate, Copper sulfate, (3,4-dichloroisothiazol-5-yl) methyl-4- (tert-butyl) benzoic acid ester (chemical name, CAS registration number: 1231214-23-5) 5-yl) methoxy) benzo [d] isothiazole-1,1-dioxide (chemical name, CAS registration number: 957144-77-3), BAF-045 ), BAG-010 (code number), UK-2A (code number), DBEDC (dodecylbenzenesulfonic acid bisethylenediamine copper [II] salt), MIF-1002 Phenyl tin), TPTC Phenyl tin chloride), TPTH (triphenyl tin hydroxide), non-pathogenic El Winiah, Caro sat look.
［식물생육조정활성성분］[Plant growth regulating active ingredient]
1-메틸사이클로프로펜(1-methylcyclopropene), 1-나프틸아세트아마이드(1-naphthylacetamide), 2,6-다이아이소프로필나프탈렌(2,6-diisopropylnaphthalene), 4-CPA(4-클로로페녹시아세트산), 벤질아미노퓨린(benzylaminopurine), 안시미돌(ancymidol), 아비글리신(aviglycine), 카르본(carvone), 클로르메쿼트(chlormequat), 클로프로프(cloprop), 클록시포낙(cloxyfonac), 클록시포낙·칼륨염(cloxyfonac-potassium), 사이클라닐라이드(cyclanilide), 사이토키닌(cytokinins), 다미노자이드(daminozide), 디케굴락(dikegulac), 디메티핀(dimethipin), 에테폰(ethephon), 에포콜레온(epocholeone), 에티클로제이트(ethychlozate), 플루메트랄린(flumetralin), 플루레놀(flurenol), 플루르프리미돌(flurprimidol), 포르클로르페누론(forchlorfenuron), 지베렐린(gibberellins), 이나벤파이드(inabenfide), 인돌 아세트산(indole acetic acid), 인돌 부티르산(indole butyric acid), 말레산 하이드라자이드(maleic hydrazide), 메플루이다이드(mefluidide), 메피쿼트 클로라이드(mepiquat chloride), n-데칸올(n-decanol), 파클로부트라졸(paclobutrazol), 프로헥사다이온·칼슘염(prohexadione-calcium), 프로하이드로자스몬(prohydrojasmon), 신토펜(sintofen), 티디아주론(thidiazuron), 트라이아콘타놀(triacontanol), 트라이넥사팍·에틸(trinexapac-ethyl), 운아이코나졸(uniconazole), 운아이코나졸-P(uniconazole-P), 4-옥소-4-(2-페닐에틸)아미노부티르(화학명, CAS 등록번호: 1083-55-2), 과산화칼슘.1-methylcyclopropene, 1-naphthylacetamide, 2,6-diisopropylnaphthalene, 4-CPA (4-chlorophenoxyacetic acid Such as benzylaminopurine, ancymidol, aviglycine, carvone, chlormequat, cloprop, cloxyfonac, Such as cloxyfonac-potassium, cycllanilide, cytokinins, daminozide, dikegulac, dimethipin, ethephon, , Epocholeone, ethychlozate, flumetralin, flurenol, flurprimidol, forchlorfenuron, gibberellins, or the like. Inabenfide, indole acetic acid, indole butyric acid, maleic acid, It is also possible to use maleic hydrazide, mefluidide, mepiquat chloride, n-decanol, paclobutrazol, prohexadione-calcium, prohydrojasmon, sintofen, thidiazuron, triacontanol, trinexapac-ethyl, uniconazole, Uniconazole-P, 4-oxo-4- (2-phenylethyl) aminobutyr (CAS registration number: 1083-55-2), calcium peroxide.
본 발명의 입상 농약조성물의 제조방법은, 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및 상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 갖는다. 본 발명의 입상 농약조성물의 제조 방법은, 상기 외층부를 형성시키는 공정 후, 필요에 따라, 농약 활성성분을 상기 외층부에 담지시키는 공정을 더 포함해도 된다.The process for preparing the granular pesticide composition of the present invention comprises the steps of preparing particle nuclei containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1- And a step of coating the surface of the particle nuclei obtained in the above step with a liquid material containing liquid sugar which is a saccharide which is not crystallized at room temperature to form an outer layer portion on the surface of the particle nuclei. The method for producing a granular pesticide composition of the present invention may further comprise, after the step of forming the outer layer portion, a step of supporting the active ingredient of the agricultural chemical on the outer layer portion, if necessary.
본 발명의 입상 농약조성물에 있어서, 상기 화합물 A를 함유하는 입자 핵을 제조하는 공정은, 예를 들면 화합물 A를 미분상 고체 담체와의 혼합물로 하고, 상기 혼합물을 교반 혼합 조립법, 전동 조립법, 압출 조립법, 파쇄 조립법, 유동층 조립법, 압축 조립법, 진공 건조 조립법 등의 공지의 조립 방법에 의해 조립물로 함으로써 행해진다.In the granular pesticide composition of the present invention, the step of producing the particle nuclei containing the compound A may be carried out, for example, by using Compound A as a mixture with a fine powder solid carrier and mixing the mixture by a stirring mixed mixing method, Known granulation methods such as granulation, granulation, fluidized bed granulation, compression granulation, and vacuum drying granulation.
상기 공정에서 얻은 입자 핵의 표면을, 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정은, 전형적으로, 먼저 입자 핵을 콘크리트 믹서나, 나우타 믹서 등의 일반적인 혼합기를 이용하여 혼합하면서, 이에 액당을 함유하는 입상물을 투입하여 입자 핵의 표층을 피복함으로써, 외층부를 형성시킨다. 액당을 함유하는 입상물을 투입하여 입자 핵의 표층을 피복하는 것이 곤란한 경우에는, 미리 액상물을 가온 또는 액당에 물 등의 용매를 약간량 첨가하여 액상물의 점성을 저하시킨 후에 투입해도 된다.The step of coating the surface of the particle nuclei obtained in the above step with a liquid material containing a liquid sugar to form an outer layer portion on the surface of the particle nuclei is typically carried out by using a conventional mixer such as a concrete mixer or a Nauta mixer , Granules containing liquid sugar are added thereto to coat the surface layer of the particle nuclei to form an outer layer portion. In the case where it is difficult to coat the surface layer of the particle nuclei by charging the granular material containing liquid sugar, it may be added after heating the liquid material or adding a small amount of a solvent such as water to the liquid material to lower the viscosity of the liquid material.
다음으로, 외층부에 담지시키는 농약 활성성분을 상기 입자 핵 외층부에 담지시키는 공정에서는, 상기 공정에서 얻은 입자 핵 외층부에 농약 활성성분을 투입하여 상기 외층부에 담지시키면 된다. 외층부에 담지시키는 농약 활성성분은, 그대로 사용해도 되지만, 통상 50㎛ 이하, 바람직하게는 10㎛ 이하의 입자 크기로 미리 미분쇄시켜두는 것이 바람직하다. 이러한 미분쇄 수단으로는 공지의 분쇄 장치를 임의로 사용할 수 있으며, 구체적으로는 충격식 분쇄기, 기류식 분쇄기 등을 사용할 수 있지만, 특별히 한정되지 않는다. 또한, 상기 미분쇄시, 외층부에 담지시키는 농약 활성성분은 단독으로 분쇄시켜도 되고, 필요에 따라 미리 상기 보조제 등과 혼합하여, 함께 분쇄시킬 수 있다. 그리고 또한, 농약 활성성분이 액체인 경우에는, 미리 상기 흡유성 미분에 흡착시켜 분말 형태로 조제해도 된다.Next, in the step of supporting the agricultural chemical active component carried on the outer layer portion on the particle nuclear outer layer portion, the agricultural chemical active ingredient may be added to the particle nuclear outer layer portion obtained in the above step and be carried on the outer layer portion. The pesticidal active ingredient to be carried on the outer layer portion may be used as it is, but it is preferable to preliminarily pulverize it to a particle size of usually 50 μm or less, preferably 10 μm or less. As the fine pulverizing means, a known pulverizing apparatus can be used arbitrarily. Specifically, an impact pulverizer, a gas flow pulverizer and the like can be used, but there is no particular limitation. The agricultural chemical active ingredient to be supported on the outer layer portion at the time of fine pulverization may be pulverized alone, or may be pulverized together with the adjuvant or the like if necessary. In addition, when the agricultural chemical active ingredient is a liquid, it may be previously adsorbed to the oil absorbing fine powder and prepared in powder form.
본 발명의 입상 농약조성물은 농약 시용에 있어서의 모든 경우에 적용 가능하지만, 특히 종자의 발아·발근 또는 어린 묘종의 생육 단계에 시용하는 경우, 이른바 파종 육묘기에 있어서 효과적이다. 예를 들어, 논벼 육묘에 있어서의, 육묘 배토(培土) 혼합할 때, 파종 시 복토 전 또는 복토 후, 발아기에서부터 이식 직전까지의 기간이 파종 육묘 시기에 해당한다. 또한, 최근 이식 동시 시용도 개발되어 있으며, 이 분야에의 적용도 가능하다. 또한, 채소 등의 셀트레이 육묘에 있어서도 마찬가지로, 육묘 배토 혼합 시부터 이식 시까지 적용될 수 있으나, 특히 바람직하게는 파종 시 및 발아기 시용이나, 이식 시에 있어서 식혈(植穴) 처리 등을 들 수 있다. 또한 파종 육묘기에서의 재배는, 통상 육묘 배토가 이용되지만, 육묘 매트나 시트 등, 배토 이외의 재배에 있어서도 적용 가능하다.The granular pesticide composition of the present invention can be applied in all cases in application of pesticides, but is particularly effective in so-called sowing sowing machines when applied to germination and rooting of seeds or growth stages of young seedlings. For example, the period from sowing seedlings to sowing seedlings, from sowing to sowing before sowing, from sowing to sowing, is the seeding time of sowing. In addition, the simultaneous application of transplantation has been developed and can be applied to this field. Also, in the cell tray seedling of vegetables and the like, the seedlings can be applied from the mixing of the seedlings to the transplanting, but particularly preferred is the seedling treatment at the time of sowing and the germination or the planting at the time of transplantation . Cultivation in sowing sowing machines is usually carried out using seedling seedlings, but it is also applicable to cultivation other than clay, such as seedling mat or sheet.
시용 방법으로는, 통상 농약 입제와 마찬가지 방법에 의해서 시용할 수 있으며, 예를 들어, 손으로 직접 산립(散粒)), 인력식 산립기, 전동식 산립기, 등에 메는 형태의 동력식 산립기, 주행형 동력 산립기, 트랙터 탑재형 산립기, 이앙기 탑재형 산립기, 측조 시용용 시약기, 무인 헬기 등의 항공 산립기에 의한 방법 등을 들 수 있다. 또한 논벼 묘종 시용 시에 있어서는, 입상 농약조성물을 소정량 계량해서 취하는 계량 컵으로 퍼내어, 육묘 상자에 뿌리는 방법, 전용의 육묘 상자 살포 용기에 넣고 육묘 상자에 산립하는 방법, 입상 농약조성물의 포장 용기에 형성된 배출구나 구멍 등으로부터 직접 육묘 상자에 산립하는 방법, 동력식 산립기를 이용하여 광범위하게 배치된 다수의 육묘 상자에 산립하는 방법, 파종 작업 시에 전용의 장치에서 육묘 상자에 산립하는 방법, 육묘 토양과 혼합하는 방법 등이 예시된다.As a method of application, it can be practiced in the same manner as in the case of pesticide application. For example, it can be directly powdered by hand), a power type acidifier in the form of a grained acidifier, an electric acidifier, And a method using an airborne fertilizer such as a traveling type power planting machine, a tractor-mounted type acid plant, a rice plant-mounted acid plant, a water treatment reagent, and an unmanned helicopter. In addition, at the time of seedling application of paddy rice, the granular pesticide composition is poured into a measuring cup which is metered in a predetermined amount, and the paddy is poured into a seedling box, a method of putting it in a special seedling box spraying container, A method in which the seedlings are buried in a seedling box directly from a discharge port or a hole formed in the container, a method in which the seedlings are buried in a large number of seedlings placed in a wide range using a power planting machine, And a method of mixing with the seedling soil.
상기 살포를 적정하게 실시하기 위해서는, 본 발명의 입상 농약조성물의 물리성은 다양한 항목에 대해 각각 일정한 범위 내에 있는 것이 바람직하다. 예를 들어, 겉보기 비중은, 농약 공정 검사법에서 0.3 내지 2가 바람직하고, 보다 바람직하게는 0.5 내지 1.5이다. 입자의 경도는 전농 볼밀법(whole farmer ball mill method)에서 20 이하가 바람직하고, 보다 바람직하게는 10 이하이다. 입도는 메시 개구(mesh opening) 1700㎛의 체를 통과하고, 메시 개구 300㎛인 체를 통과하지 못한 입자가 입상 조성물 전체의 90질량% 이상인 것이 바람직하다.In order to appropriately perform the above-described spraying, the physical properties of the granular pesticide composition of the present invention are preferably within a certain range for various items. For example, the apparent specific gravity is preferably from 0.3 to 2, more preferably from 0.5 to 1.5 in the pesticide process test method. The hardness of the particles is preferably 20 or less, more preferably 10 or less in the whole farmer ball mill method. It is preferable that the particle size of particles passing through a sieve having a mesh opening of 1700 탆 and not passing through a sieve having a mesh opening of 300 탆 is 90% by mass or more of the total granular composition.
또한 입상 농약조성물은, 입자 핵의 형상이 대략 원기둥 형상인 경우에는, 단면 원형의 직경은 보통 0.3 내지 1.7㎜, 바람직하게는 0.5 내지 1.5㎜, 보다 바람직하게는 0.8 내지 1.2㎜이다. 원기둥의 높이에 해당하는 입자 길이는, 단면 원 직경에 대해 0.5 내지 6배인 것이 바람직하지만, 파종 작업 시 전용 장치를 이용하여 살포할 경우, 예를 들어 종자상자 시용약제 살포장치(미선제, 모델 KS-25 : 롤러식 산립기)와 종자 상자 시약 호퍼(스즈텍제, 모델 SDP-33S, SDP-103S : 롤러식 산립기), 포트 육묘용 상자 시약 장치(미노루산업주식회사제, 모델 MPA-21 : 롤러식 산립기)에서 살포하는 경우에는, 단면 원 직경에 대해 2.5배 이상의 입자 길이를 갖는 입자가 입상 조성물 전체의 50질량% 이하인 것이 바람직하고, 보다 바람직하게는 40질량% 이하이다.In the case of the granular pesticide composition, when the particle nuclei are substantially cylindrical, the diameter of the circular cross section is usually 0.3 to 1.7 mm, preferably 0.5 to 1.5 mm, and more preferably 0.8 to 1.2 mm. It is preferable that the particle length corresponding to the height of the cylinder is 0.5 to 6 times the diameter of the cross-section circle. However, when spraying using a dedicated device in the seeding work, for example, a spraying device for seed box application Model MPA-21: Roller type granulator), a seed box reagent hopper (Suzutekku, model SDP-33S, SDP-103S: roller type acidifier) The particles having a particle size of not less than 2.5 times the cross-sectional diameter of the cross-sectional circle diameter are preferably not more than 50% by mass, more preferably not more than 40% by mass, of the whole particulate composition.
또한, 본 발명의 입상 농약조성물을 시용할 때의 시용량은, 논이나 밭의 경우, 10아르당 0.1 내지 20kg, 바람직하게는 0.2 내지 5kg이며, 논벼 육묘 상자의 경우, 육묘 상자(일반적으로 0.16㎡) 하나당 10 내지 200g, 바람직하게는 10 내지 100g이다. 또한 셀 트레이에 시용할 때는 셀트레이(128 홀)당 30g 정도의 시용량이면 된다.The application amount of the granular pesticide composition of the present invention is 0.1 to 20 kg, preferably 0.2 to 5 kg, per 10 arcs in rice fields and fields, Is 10 to 200 g, preferably 10 to 100 g. In addition, when applied to a cell tray, a dosage of about 30 g per cell tray (128 holes) is sufficient.
[실시예][Example]
이하, 본 발명의 구체적인 실시예에 대하여 설명하지만, 본 발명은 이러한 실시예에 한정되는 것은 아니다. 또한, 이하의 실시예, 비교예에서 「부」는 질량 부, 「%」는 질량%를 나타낸다. 또한 「단경」은 대략 원기둥 형상 조립물의 단면 원 직경을, 「애스펙트비」는 대략 원기둥 형상 조립물의 입자 길이를 상기 단경으로 나눈 몫을 가리킨다.Hereinafter, specific examples of the present invention will be described, but the present invention is not limited to these examples. In the following Examples and Comparative Examples, "part" means "mass part" and "%" means mass%. The " short diameter " indicates the cross-sectional circle diameter of the substantially cylindrical pellet, and the " aspect ratio " indicates the share obtained by dividing the particle length of the substantially cylindrical pellet by the above-mentioned minor diameter.
[실시예 1][Example 1]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 환원 당분을 약 50% 함유하는 액당(상품명 닛토 하이 슈트 디럭스, 미츠비시 화학푸드사제) 1.2부를 70℃로 가온한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 입자 핵의 표면에 외층부를 형성시킴으로써, 액당으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a substantially cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a liquid sugar (trade name: NITTO HIGH SHUT DELUXE, manufactured by Mitsubishi Chemical Foods Co., Ltd.) containing about 50% of reducing sugar was added to a liquid material heated to 70 DEG C, Thereby forming an outer layer portion on the surface of the particle nuclei to obtain a granular pesticide composition having a particle core outer layer portion coated with a liquid.
[실시예 2][Example 2]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 환원 당분을 약 50% 함유하는 액당(상품명 닛토 하이 슈트 디럭스, 미츠비시 화학푸드사제) 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거해서, 입자 핵의 표면에 외층부를 형성시킴으로써, 액당으로 피복된 상기 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material in which a small amount of water was mixed was added to 1.2 parts of liquid sugar (trade name: NITTO HIGH SHUT DELUXE, manufactured by Mitsubishi Chemical Food Co., Ltd.) containing about 50% of reducing sugar, The surface layer was coated and the water of the liquid material was removed by drying to form an outer layer portion on the surface of the particle nuclei to obtain a granular pesticide composition having the particle core outer layer portion coated with liquid.
[실시예 3][Example 3]
실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류 식 분쇄기로 미분쇄한 메프로닐 3부를 첨가하여 입자 핵 외층부에 담지시킴으로써, 액당으로 피복된 입자 외층부를 가지며, 상기 입자 핵 외층부에 메프로닐을 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 1 was mixed with a Nauta mixer while 3 parts of mesoporil finely pulverized by a gas-phase mill was added and carried on the outer surface of the particle nucleus to have a particle outer layer portion coated with the liquid particle, To obtain a granular pesticide composition carrying on its outer layer mepronil.
[실시예 4][Example 4]
실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 습식 분쇄기로 미분쇄한 피리벤카브 3부를 물 7부의 혼합물인 분산액을 첨가하여 입자 핵 외층부에 담지시키고, 건조에 의해 상기 분산액의 물을 제거함으로써, 액당으로 피복된 입자 외층부를 가지며, 상기 입자 핵 외층부에 피리벤카브를 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 1 was mixed with a Nauta mixer, and 3 parts of finely pulverized pyrimidine compound in a wet pulverizer was added to a dispersion of a mixture of 7 parts of water to carry it on the particle core outer layer portion, Water was removed to obtain a granular pesticide composition having a particle outer layer portion coated with a liquid sugar and carrying a pyridine carbide on the particle nuclear outer layer portion.
[실시예 5][Example 5]
실시예 1에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류식 분쇄기로 미분쇄한 벤티아발리카브·아이소프로필 1.5부와 점토 1.5부의 혼합물을 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 벤티아발리카브·아이소프로필을 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 1 was mixed with a Nauta mixer, and a mixture of 1.5 parts of Bentia valicivoisopropyl and 2 parts of clay, which had been finely pulverized by a gas stream mill, was added to the granular outer layer portion, A granular pesticide composition having a coated particle core outer layer portion and carrying the benthiavalicov isopropyl on the particle core outer layer portion was obtained.
[실시예 6][Example 6]
실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 충격식 분쇄기로 미분쇄한 메파니피림 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 메파니피림을 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 2 was mixed with a Nauta mixer while 3 parts of finely pulverized mephanilipry was added by an impact mill to be carried on the particle core outer layer portion to have a particle outer core portion coated in liquid sugar, To obtain a granular pesticide composition carrying mefenifir in a nuclear outer layer portion.
[실시예 7][Example 7]
실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 이프로벤포스 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 이프로벤포스를 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 2 was mixed with a Nauta mixer while 3 parts of iverobene was added to the outer surface of the particle nucleus outer layer to have a particle outer core layer coated in a liquid phase, A granular pesticide composition was obtained.
[실시예 8][Example 8]
실시예 2에서 얻은 입상 농약조성물 97부를 나우타 믹서로 혼합하면서, 기류식 분쇄기로 미분쇄한 페노티오카브 3부를 첨가해서 입자 핵 외층부에 담지시킴으로써, 액당에서 피복된 입자 핵 외층부를 가지며, 상기 입자 핵 외층부에 펜오티오카브를 담지하는 입상 농약조성물을 얻었다.97 parts of the granular pesticide composition obtained in Example 2 was mixed with a Nauta mixer and 3 parts of finely crushed phenothiocarbine was added by a gas stream mill to be carried on the particle core outer layer portion to have a particle outer core portion coated in liquid sugar, To obtain a granular pesticide composition carrying a pentothiocarb on the nuclear outer layer portion.
[비교예 1][Comparative Example 1]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 리그닌설폰산염 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거함으로써, 리그닌설폰산염으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a substantially cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing 1.2 parts of lignin sulfonate with a small amount of water was added to cover the surface layer of the particle nuclei, and water in the liquid material was removed by drying to obtain lignin sulfone To obtain a granular pesticide composition having a particle core outer layer portion coated with an acid salt.
[비교예 2][Comparative Example 2]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리비닐알코올 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하여, 건조에 의해 상기 액상물의 물을 제거함으로써, 폴리비닐알코올으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing a small amount of water with 1.2 parts of polyvinyl alcohol was added to cover the surface layer of the particle nuclei, and water of the liquid material was removed by drying to obtain polyvinyl To obtain a granular pesticide composition having an outer layer of particle nuclei coated with alcohol.
[비교예 3][Comparative Example 3]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리부타다이엔 폴리올인 액상물 1.2부를 첨가하여 입자 핵의 표층을 피복함으로써, 폴리부타다이엔 폴리올로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a substantially cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.2 parts of a liquid material as a polybutadiene polyol was added to coat the surface layer of the particle nuclei to obtain a granular pesticide composition having a particle core outer layer portion coated with polybutadiene polyol.
[비교예 4][Comparative Example 4]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시알킬렌 알킬 에터 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시알킬렌알킬에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. A granular pesticide composition having a particle core outer layer portion coated with a polyoxyalkylene alkylether by mixing a 95.8 part of the particle nuclei with a Nauta mixer and coating a surface layer of the particle nuclei by adding a liquid material which is 1.2 parts of polyoxyalkylene alkyl ether ≪ / RTI >
[비교예 5][Comparative Example 5]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 프탈산 다이아이소데실 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 프탈산 다이아이소데실로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material as diisodecyl phthalate (1.2 parts) was added to coat the surface layer of the particle nuclei to obtain a granular pesticide composition having a particle outer layer of a particle-coated diisodecyl phthalate.
[비교예 6][Comparative Example 6]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시알킬렌알킬에터인산에스터 1.2부인 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시알킬렌알킬에터인산에스터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, the surface layer of the particle nuclei was coated by adding a liquid material which is 1.2 parts of a polyoxyalkylene alkyl ether phosphate ester to obtain a particle core outer layer coated with a polyoxyalkylene alkyl ether phosphate ester To obtain a granular pesticide composition.
[비교예 7][Comparative Example 7]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 카복시메틸셀룰로스 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 카복시메틸셀룰로스로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing a small amount of water in 1.2 parts of carboxymethyl cellulose was added to cover the surface layer of the particle nuclei, and water of the liquid material was removed by drying to obtain carboxymethyl To obtain a granular pesticide composition having a particle core outer layer portion coated with cellulose.
[비교예 8][Comparative Example 8]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 메틸셀룰로스 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 메틸셀룰로스로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다.A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing a small amount of water in 1.2 parts of methyl cellulose was added to cover the surface layer of the particle nuclei, and water in the liquid material was removed by drying to obtain methyl cellulose To obtain a granular pesticide composition having a coated particle core outer layer portion.
[비교예 9][Comparative Example 9]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 전분 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 전분으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing a small amount of water with 1.2 parts of starch was added to cover the surface layer of the particle nuclei, and water of the liquid material was removed by drying to obtain a starch- A granular pesticide composition having a particle nuclear outer layer portion was obtained
[비교예 10][Comparative Example 10]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 덱스트린 1.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 덱스트린으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material in which 1.2 parts of dextrin was mixed with a small amount of water was added to cover the surface layer of the particle nuclei, and water of the liquid material was removed by drying to obtain dextrin- A granular pesticide composition having a particle nuclear outer layer portion was obtained
[비교예 11][Comparative Example 11]
화합물 A2 부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 글리옥실산 0.2부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복하고, 건조에 의해 상기 액상물의 물을 제거함으로써, 글리옥실산으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to Compound A2, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket re-user equipped with a screen having a hole diameter of 1.2 mm , And the granules were dried to obtain particle nuclei having a substantially cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing 0.2 part of glyoxylic acid with a small amount of water was added to cover the surface layer of the particle nuclei, and water of the liquid material was removed by drying to obtain glyoxyl To obtain a granular pesticide composition having a particle core outer layer portion coated with an acid
[비교예 12][Comparative Example 12]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌알킬아릴에터 1.5부를 첨가하여 입자 핵의 표층을 피복함으로써, 폴리옥시에틸렌알킬아릴에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.5 parts of polyoxyethylene alkylarylether was added to coat the surface layer of the particle nuclei to obtain a granular pesticide composition having a particle core outer layer portion coated with polyoxyethylene alkylarylether
[비교예 13][Comparative Example 13]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌피마자유에터 1.5부를 첨가해서 입자 핵의 표층을 피복함으로써, 폴리옥시에틸렌피마자유에터로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, 1.5 parts of a polyoxyethylene castor oil was added to coat the surface layer of the particle nuclei to obtain a granular pesticide composition having a particle core outer layer portion coated with a polyoxyethylene castor oiler
[비교예 14][Comparative Example 14]
화합물 A 2부, 알킬벤젠설폰산염 0.35부, 알파화 전분 3부 및 점토 90.45부에 소정량의 물을 첨가하여 반죽한 후, 구멍 직경 1.2㎜인 스크린을 장착한 바스켓 리유저를 이용해서 압출 조립하고, 조립물을 건조시켜, 단경 1.2㎜, 애스펙트비 약 3의 대략 원기둥 형상인 입자 핵을 얻었다. 이 입자 핵 95.8부를 나우타 믹서로 혼합하면서, 폴리옥시에틸렌아릴페닐에터황산염 0.61부에 약간량의 물을 혼합한 액상물을 첨가하여 입자 핵의 표층을 피복함으로써, 건조에 의해 상기 액상물의 물을 제거하고, 폴리옥시에틸렌아릴페닐에터황산염으로 피복된 입자 핵 외층부를 갖는 입상 농약조성물을 얻었다A predetermined amount of water was added to 2 parts of Compound A, 0.35 part of alkylbenzenesulfonate, 3 parts of alpha-starch and 90.45 parts of clay, kneaded, and then extruded and assembled using a basket reuser equipped with a screen having a hole diameter of 1.2 mm And the granules were dried to obtain particle nuclei having a roughly cylindrical shape with a minor axis of 1.2 mm and an aspect ratio of about 3. While mixing 95.8 parts of the particle nuclei with a Nauta mixer, a liquid material obtained by mixing a small amount of water with 0.61 part of polyoxyethylene arylphenyl ether sulfate was added to coat the surface layer of the particle nuclei, thereby drying the water of the liquid material To obtain a granular pesticide composition having a particle core outer layer portion coated with polyoxyethylene arylphenyl ether sulfate
[실험예 1][Experimental Example 1]
실시예, 비교예의 입상 농약조성물에 있어서의 화합물 A의 함유율을 고속 액체 크로마토그래피법에 의해 정량하였다. 이어서, 각 조성물을 54℃ 항온에서 14 일간 정치 보관한 후, 마찬가지로 해서 다시 화합물 A의 함유율을 정량하여, 하기 식에 의해 분해율을 구했다. 결과를 표 1에 나타낸다.The content of the compound A in the granular pesticide compositions of the examples and comparative examples was determined by a high-performance liquid chromatography method. Then, after each composition was stored at a constant temperature of 54 DEG C for 14 days, the content of the compound A was similarly measured, and the decomposition rate was determined by the following equation. The results are shown in Table 1.
(%)Decomposition rate
(%)
Claims (8)
상기 입자 핵이 3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하며, 그리고
상기 외층부가 상온에서 결정화되지 않는 당류인 액당을 함유하여 이루어진, 입상 농약조성물.1. A granular pesticide composition having a particle nucleus and an outer layer portion covering the particle nucleus,
Wherein the particle nucleus contains 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide, and
Wherein the outer layer portion contains a liquid sugar which is a saccharide which is not crystallized at room temperature.
상기 입자 핵이 압출 조립법에 의해 얻어진 조립물인, 입상 농약조성물.The method according to claim 1,
Wherein the particle nucleus is an assembly obtained by an extrusion granulation method.
상기 액당이 환원당을 함유하는 전화형 액당인, 입상 농약조성물.3. The method according to claim 1 or 2,
Wherein the liquid sugar is a dialytic liquid containing reducing sugar.
상기 액당의 함유량이 입상 농약조성물 전체에 대해서 0.5 내지 5질량%인, 입상 농약조성물.4. The method according to any one of claims 1 to 3,
Wherein the content per liquid is 0.5 to 5% by mass with respect to the total amount of the granular pesticide composition.
추가로 농약 활성성분을 상기 외층부에 담지하여 이루어진, 입상 농약조성물.5. The method according to any one of claims 1 to 4,
And further comprising a pesticidal active ingredient supported on said outer layer portion.
상기 입자 핵이 대략 원기둥형이며, 그 단면 원 직경이 0.3 내지 1.7㎜인, 입상 농약조성물.6. The method according to any one of claims 1 to 5,
Wherein the particle nuclei are substantially cylindrical and have a cross-sectional diameter of 0.3 to 1.7 mm.
3-(3,4-다이클로로아이소티아졸-5-일메톡시)-1,2-벤조티아졸-1,1-다이옥사이드를 함유하는 입자 핵을 제조하는 공정, 및
상기 공정에서 얻은 입자 핵의 표면을, 상온에서 결정화되지 않는 당류인 액당을 함유하는 액상물로 피복하여, 상기 입자 핵의 표면에 외층부를 형성시키는 공정을 포함하는 것을 특징으로 하는 입상 농약조성물의 제조 방법.A method for producing the granular pesticide composition according to any one of claims 1 to 6,
A process for producing particle nuclei containing 3- (3,4-dichloroisothiazol-5-ylmethoxy) -1,2-benzothiazole-1,1-dioxide, and
A step of coating the surface of the particle nuclei obtained in the above step with a liquid material containing liquid sugar which is a saccharide which is not crystallized at room temperature to form an outer layer portion on the surface of the particle nucleus Way.
상기 외층부를 형성시키는 공정 후에, 농약 활성성분을 상기 외층부에 담지시키는 공정을 더 포함하는, 입상 농약조성물의 제조 방법.8. The method of claim 7,
Further comprising the step of supporting the agrochemical active component on the outer layer portion after the step of forming the outer layer portion.
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| JPH09315903A (en) * | 1996-05-29 | 1997-12-09 | Hokko Chem Ind Co Ltd | Granular agrochemical having improved storage stability |
| JP2002080305A (en) * | 2000-09-06 | 2002-03-19 | Chisso Corp | Agrochemical particle and method for producing the same, and coated agrochemical granule |
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| JP2010100565A (en) * | 2008-10-24 | 2010-05-06 | Kumiai Chem Ind Co Ltd | Fine particulate agrichemical composition and method for producing the same |
| JP2010155807A (en) * | 2008-12-27 | 2010-07-15 | Kumiai Chem Ind Co Ltd | Pest-controlling agent for agriculture and horticulture, and method for controlling pest |
| WO2012165511A1 (en) * | 2011-05-31 | 2012-12-06 | クミアイ化学工業株式会社 | Method for controlling diseases in rice plant |
| JP2015044791A (en) * | 2013-07-29 | 2015-03-12 | クミアイ化学工業株式会社 | Agricultural and horticultural pest control agent and method for controlling pest |
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| US5833733A (en) * | 1995-05-12 | 1998-11-10 | Nihon Bayer Agrochem K.K. | Agrochemical formulations for water surface application |
| JP2001192302A (en) * | 2000-01-06 | 2001-07-17 | Sankyo Co Ltd | Agrochemical granule and its manufacturing method |
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| JPH09315903A (en) * | 1996-05-29 | 1997-12-09 | Hokko Chem Ind Co Ltd | Granular agrochemical having improved storage stability |
| JP2002080305A (en) * | 2000-09-06 | 2002-03-19 | Chisso Corp | Agrochemical particle and method for producing the same, and coated agrochemical granule |
| JP2007129454A (en) | 2005-11-02 | 2007-05-24 | Mitsubishi Electric Corp | Antenna system |
| WO2007129454A1 (en) * | 2006-05-08 | 2007-11-15 | Kumiai Chemical Industry Co., Ltd. | 1,2-benzisothiazole derivative, and agricultural or horticultural plant disease-controlling agent |
| JP2010100565A (en) * | 2008-10-24 | 2010-05-06 | Kumiai Chem Ind Co Ltd | Fine particulate agrichemical composition and method for producing the same |
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| WO2012165511A1 (en) * | 2011-05-31 | 2012-12-06 | クミアイ化学工業株式会社 | Method for controlling diseases in rice plant |
| JP2015044791A (en) * | 2013-07-29 | 2015-03-12 | クミアイ化学工業株式会社 | Agricultural and horticultural pest control agent and method for controlling pest |
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| WO2017170792A1 (en) | 2017-10-05 |
| CN108777966A (en) | 2018-11-09 |
| JPWO2017170792A1 (en) | 2019-02-14 |
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