CN115175889A - 含氟烯烃的制造方法 - Google Patents

含氟烯烃的制造方法 Download PDF

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Publication number
CN115175889A
CN115175889A CN202180016941.2A CN202180016941A CN115175889A CN 115175889 A CN115175889 A CN 115175889A CN 202180016941 A CN202180016941 A CN 202180016941A CN 115175889 A CN115175889 A CN 115175889A
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CN
China
Prior art keywords
group
atom
olefin
carbon atoms
nitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202180016941.2A
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English (en)
Chinese (zh)
Inventor
野崎京子
秋山绿理
森健太
冈添隆
石桥雄一郎
稻田工
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Tokyo NUC
AGC Inc
Original Assignee
Asahi Glass Co Ltd
University of Tokyo NUC
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Filing date
Publication date
Application filed by Asahi Glass Co Ltd, University of Tokyo NUC filed Critical Asahi Glass Co Ltd
Publication of CN115175889A publication Critical patent/CN115175889A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/08—Isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/22—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of halogens; by substitution of halogen atoms by other halogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2637—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions between a compound containing only oxygen and possibly halogen as hetero-atoms and a halogenated hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/37—Preparation of halogenated hydrocarbons by disproportionation of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/56—Ring systems containing three or more rings
    • C07D209/80—[b, c]- or [b, d]-condensed
    • C07D209/82—Carbazoles; Hydrogenated carbazoles
    • C07D209/86—Carbazoles; Hydrogenated carbazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
    • B01J2231/4288—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using O nucleophiles, e.g. alcohols, carboxylates, esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/10—Non-coordinating groups comprising only oxygen beside carbon or hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN202180016941.2A 2020-03-02 2021-02-12 含氟烯烃的制造方法 Pending CN115175889A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2020034736 2020-03-02
JP2020-034736 2020-03-02
JP2020-132483 2020-08-04
JP2020132483 2020-08-04
PCT/JP2021/005343 WO2021177000A1 (ja) 2020-03-02 2021-02-12 含フッ素オレフィンの製造方法

Publications (1)

Publication Number Publication Date
CN115175889A true CN115175889A (zh) 2022-10-11

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CN202180016941.2A Pending CN115175889A (zh) 2020-03-02 2021-02-12 含氟烯烃的制造方法

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US (1) US12590047B2 (https=)
EP (1) EP4116286B1 (https=)
JP (2) JPWO2021177000A1 (https=)
CN (1) CN115175889A (https=)
WO (1) WO2021177000A1 (https=)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240359169A1 (en) * 2021-09-22 2024-10-31 N.E. Chemcat Corporation Organic metal complex catalyst for olefin metathesis reaction

Citations (7)

* Cited by examiner, † Cited by third party
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JP2003089689A (ja) * 2001-09-20 2003-03-28 Nippon Zeon Co Ltd ルテニウム錯体化合物、その製造方法、メタセシス反応用触媒及び水素化反応用触媒
JP2003096167A (ja) * 2001-09-20 2003-04-03 Nippon Zeon Co Ltd 環状オレフィン開環重合体水素化物の製造方法及びジシクロペンタジエン開環重合体水素化物
CN102481557A (zh) * 2009-05-07 2012-05-30 尤米科尔股份公司及两合公司 用于制备具有螯合性亚烷基配体的基于钌的复分解催化剂的方法
CN105517982A (zh) * 2013-09-06 2016-04-20 旭硝子株式会社 含氟烯烃的制造方法
WO2016129606A1 (ja) * 2015-02-09 2016-08-18 旭硝子株式会社 含フッ素重合体の製造方法
CN107108420A (zh) * 2014-12-26 2017-08-29 旭硝子株式会社 烯烃的制造方法
JP2018024600A (ja) * 2016-08-09 2018-02-15 旭硝子株式会社 含フッ素オレフィンの製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1373170A4 (en) * 2001-03-30 2007-03-21 California Inst Of Techn CROSS-METATHESIS REACTION OF FUNCTIONALIZED AND SUBSTITUTED OLEFINS USING GROUP 8 METAL TRANSITION CARBENE COMPLEXES AS METATHESIS CATALYSTS
WO2003027079A1 (en) 2001-09-20 2003-04-03 Zeon Corporation Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymers of cycloolefins and hydrogenation products thereof by using the complexes as catalyst
JP7092619B2 (ja) 2018-08-30 2022-06-28 株式会社キーエンス 拡大観察装置
JP7077991B2 (ja) 2019-02-21 2022-05-31 信越半導体株式会社 Ｃｚシリコン単結晶製造方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003089689A (ja) * 2001-09-20 2003-03-28 Nippon Zeon Co Ltd ルテニウム錯体化合物、その製造方法、メタセシス反応用触媒及び水素化反応用触媒
JP2003096167A (ja) * 2001-09-20 2003-04-03 Nippon Zeon Co Ltd 環状オレフィン開環重合体水素化物の製造方法及びジシクロペンタジエン開環重合体水素化物
CN102481557A (zh) * 2009-05-07 2012-05-30 尤米科尔股份公司及两合公司 用于制备具有螯合性亚烷基配体的基于钌的复分解催化剂的方法
CN105517982A (zh) * 2013-09-06 2016-04-20 旭硝子株式会社 含氟烯烃的制造方法
CN107108420A (zh) * 2014-12-26 2017-08-29 旭硝子株式会社 烯烃的制造方法
WO2016129606A1 (ja) * 2015-02-09 2016-08-18 旭硝子株式会社 含フッ素重合体の製造方法
JP2018024600A (ja) * 2016-08-09 2018-02-15 旭硝子株式会社 含フッ素オレフィンの製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
MICHAEL R. BUCHMEISER ET AL: "Pseudo-Halide and NitrateDerivatives of Grubbs andGrubbs Hoveyda Initiators: Some Structural Features Related to the Alternating Ring-Opening Metathesis Copolymerization of Norborn-2-ene with Cyclic Olefins", 《MACROMOLECULES》, vol. 44, pages 4098 *
YUSUKE TAKAHIRA ET AL: "Ruthenium-Catalyzed Olefin Cross-Metathesis with Tetrafluoroethylene and Analogous Fluoroolefins", 《J. AM. CHEM. SOC.》, vol. 137, 13 May 2015 (2015-05-13), pages 7031 *

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JPWO2021177000A1 (https=) 2021-09-10
JP2025102945A (ja) 2025-07-08
EP4116286B1 (en) 2025-06-18
US20230016405A1 (en) 2023-01-19
EP4116286A1 (en) 2023-01-11
US12590047B2 (en) 2026-03-31
WO2021177000A1 (ja) 2021-09-10
EP4116286A4 (en) 2024-04-03

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Application publication date: 20221011