CN115106132A - 一种类三明治结构的选择性阴离子交换膜的制备方法 - Google Patents
一种类三明治结构的选择性阴离子交换膜的制备方法 Download PDFInfo
- Publication number
- CN115106132A CN115106132A CN202210718588.9A CN202210718588A CN115106132A CN 115106132 A CN115106132 A CN 115106132A CN 202210718588 A CN202210718588 A CN 202210718588A CN 115106132 A CN115106132 A CN 115106132A
- Authority
- CN
- China
- Prior art keywords
- anion exchange
- exchange membrane
- solution
- membrane
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003011 anion exchange membrane Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 37
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 20
- GPNNOCMCNFXRAO-UHFFFAOYSA-N 2-aminoterephthalic acid Chemical compound NC1=CC(C(O)=O)=CC=C1C(O)=O GPNNOCMCNFXRAO-UHFFFAOYSA-N 0.000 claims abstract description 16
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims abstract description 16
- 238000004528 spin coating Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000011065 in-situ storage Methods 0.000 claims abstract description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 46
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 238000005303 weighing Methods 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 8
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 7
- 238000004090 dissolution Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- RVPAGRVOSVAXSH-UHFFFAOYSA-N n,n-dimethylmethanamine;ethanol Chemical compound CCO.CN(C)C RVPAGRVOSVAXSH-UHFFFAOYSA-N 0.000 claims description 4
- 238000005956 quaternization reaction Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 abstract description 19
- 150000002500 ions Chemical class 0.000 abstract description 17
- 239000012621 metal-organic framework Substances 0.000 abstract description 8
- 206010013496 Disturbance in attention Diseases 0.000 abstract description 4
- 239000002356 single layer Substances 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 28
- 238000012360 testing method Methods 0.000 description 12
- 150000001450 anions Chemical class 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 8
- 238000000926 separation method Methods 0.000 description 7
- 239000002131 composite material Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000013207 UiO-66 Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000000909 electrodialysis Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 239000003014 ion exchange membrane Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 238000005571 anion exchange chromatography Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/13—Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210718588.9A CN115106132B (zh) | 2022-06-23 | 2022-06-23 | 一种类三明治结构的选择性阴离子交换膜的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202210718588.9A CN115106132B (zh) | 2022-06-23 | 2022-06-23 | 一种类三明治结构的选择性阴离子交换膜的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN115106132A true CN115106132A (zh) | 2022-09-27 |
CN115106132B CN115106132B (zh) | 2024-07-02 |
Family
ID=83327708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202210718588.9A Active CN115106132B (zh) | 2022-06-23 | 2022-06-23 | 一种类三明治结构的选择性阴离子交换膜的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN115106132B (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115569638A (zh) * | 2022-10-11 | 2023-01-06 | 中国人民解放军军事科学院防化研究院 | 一种Zr-MOF复合膜防护材料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008007545A (ja) * | 2006-06-27 | 2008-01-17 | Astom:Kk | 複合アニオン交換膜及びその製造方法 |
CN107441952A (zh) * | 2017-08-07 | 2017-12-08 | 中国科学技术大学 | MOFs复合膜、其制备方法及其应用 |
CN110898861A (zh) * | 2019-12-09 | 2020-03-24 | 中国科学技术大学先进技术研究院 | 双极膜的制备方法以及双极膜 |
-
2022
- 2022-06-23 CN CN202210718588.9A patent/CN115106132B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008007545A (ja) * | 2006-06-27 | 2008-01-17 | Astom:Kk | 複合アニオン交換膜及びその製造方法 |
CN107441952A (zh) * | 2017-08-07 | 2017-12-08 | 中国科学技术大学 | MOFs复合膜、其制备方法及其应用 |
CN110898861A (zh) * | 2019-12-09 | 2020-03-24 | 中国科学技术大学先进技术研究院 | 双极膜的制备方法以及双极膜 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115569638A (zh) * | 2022-10-11 | 2023-01-06 | 中国人民解放军军事科学院防化研究院 | 一种Zr-MOF复合膜防护材料及其制备方法 |
CN115569638B (zh) * | 2022-10-11 | 2024-04-19 | 中国人民解放军军事科学院防化研究院 | 一种Zr-MOF复合膜防护材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN115106132B (zh) | 2024-07-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Tricoli et al. | Zeolite–Nafion composites as ion conducting membrane materials | |
CA2814701C (en) | Process for making a monomer solution for making cation exchange membranes | |
CN104282923B (zh) | 全钒液流电池用阳/增强/阴两性复合膜及其制备方法 | |
CN102181069A (zh) | 两性离子交换膜的制备方法 | |
Che et al. | Anion exchange membranes based on long side-chain quaternary ammonium-functionalized poly (arylene piperidinium) s for vanadium redox flow batteries | |
CN104311857A (zh) | 一种双季铵侧长链型阴离子交换膜的制备方法 | |
CN109939572B (zh) | 一种具有多重交联结构的阴离子交换膜的制备方法 | |
CN113457448B (zh) | 一种基于不同层间距的双层MXene膜的制备方法 | |
CN115106132A (zh) | 一种类三明治结构的选择性阴离子交换膜的制备方法 | |
CN104941468B (zh) | 一种半互穿网络型阴离子交换膜及其制备方法 | |
Xiao et al. | Self‐Assembled Nanoporous Metal–Organic Framework Monolayer Film for Osmotic Energy Harvesting | |
Han et al. | Thin and defect-free ZIF-8 layer assisted enhancement of the monovalent perm-selectivity for cation exchange membrane | |
CN110694698B (zh) | 高阴离子透过性高离子选择性阴离子交换膜及其制备方法与应用 | |
Sun et al. | Covalent organic framework-based membrane improved the performance of reverse electrodialysis under Na+/Mg2+ mixed solution | |
CN106268381B (zh) | 一种耐碱解阴离子交换膜材料及其制备方法和应用 | |
CN109161927B (zh) | 一种以多孔阳膜为基材的双极膜及其制备方法 | |
Zhang et al. | Two‐Dimensional MFI‐Type Zeolite Flow Battery Membranes | |
Fan et al. | Solid-state synthesis of intrinsically proton-conducting covalent organic framework membrane | |
Zhang et al. | Room‐Temperature Synthesis of a COFs Membrane Via LBL Self‐Assembly Strategy for Energy Harvesting | |
Zhang et al. | Preparation of porous polymer electrolyte by a microwave assisted effervescent disintegrable reaction | |
Godino et al. | Influence of the cationic form of an ion-exchange membrane in the permeability and solubility of methanol/water mixtures | |
CN114471177A (zh) | 阴离子交换驱动的阳离子选择性分离杂化膜及制备和应用 | |
CN106268984A (zh) | 一种失效的聚乙烯亚胺改性的阳离子交换膜的再生方法 | |
Xie et al. | Facile surface modification of cation exchange membranes via Debus-Radziszewski in-situ cross-linking for lithium extraction from salt-lakes | |
LU503451B1 (en) | A preparation method of a polymer of intrinsic microporosity anion exchange membrane |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20231221 Address after: 5 / F, building 1, No. 2159-1, yuhangtang Road, Wuchang Street, Yuhang District, Hangzhou City, Zhejiang Province Applicant after: ZHEJIANG ENERGY R & D INSTITUTE Co.,Ltd. Applicant after: JIANG University OF TECHNOLOGY Applicant after: Zhejiang Baimahu Laboratory Co.,Ltd. Address before: 5 / F, building 1, No. 2159-1, yuhangtang Road, Wuchang Street, Yuhang District, Hangzhou City, Zhejiang Province Applicant before: ZHEJIANG ENERGY R & D INSTITUTE Co.,Ltd. Applicant before: JIANG University OF TECHNOLOGY |
|
GR01 | Patent grant |