CN1150231C - 烯属不饱和单体在聚合物上的接枝方法 - Google Patents

烯属不饱和单体在聚合物上的接枝方法 Download PDF

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Publication number
CN1150231C
CN1150231C CNB998103276A CN99810327A CN1150231C CN 1150231 C CN1150231 C CN 1150231C CN B998103276 A CNB998103276 A CN B998103276A CN 99810327 A CN99810327 A CN 99810327A CN 1150231 C CN1150231 C CN 1150231C
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China
Prior art keywords
alkyl
group
phenyl
cycloalkyl
hydrogen
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Expired - Fee Related
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CNB998103276A
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English (en)
Chinese (zh)
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CN1315970A (zh
Inventor
M
M·罗斯
R·普法恩德纳
°
P·尼斯瓦德巴
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BASF Schweiz AG
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Ciba Spezialitaetenchemie Holding AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-propylene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/06—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-propylene-diene terpolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CNB998103276A 1998-09-03 1999-08-23 烯属不饱和单体在聚合物上的接枝方法 Expired - Fee Related CN1150231C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98810877.5 1998-09-03
EP98810877 1998-09-03

Publications (2)

Publication Number Publication Date
CN1315970A CN1315970A (zh) 2001-10-03
CN1150231C true CN1150231C (zh) 2004-05-19

Family

ID=8236298

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998103276A Expired - Fee Related CN1150231C (zh) 1998-09-03 1999-08-23 烯属不饱和单体在聚合物上的接枝方法

Country Status (12)

Country Link
US (1) US6521710B1 (https=)
EP (1) EP1115766B1 (https=)
JP (1) JP4516213B2 (https=)
KR (1) KR100575149B1 (https=)
CN (1) CN1150231C (https=)
AT (1) ATE307150T1 (https=)
AU (1) AU760128B2 (https=)
BR (1) BR9913416A (https=)
CA (1) CA2340689A1 (https=)
DE (1) DE69927839T2 (https=)
ES (1) ES2251225T3 (https=)
WO (1) WO2000014135A1 (https=)

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EP1115765B1 (en) * 1998-09-03 2009-06-24 Ciba Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers
ATE321095T1 (de) * 2000-05-30 2006-04-15 Ciba Sc Holding Ag Molekulargewichtsmodifizierung von thermoplastischen polymeren
TWI225492B (en) † 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
US7514263B2 (en) * 2001-04-02 2009-04-07 3M Innovative Properties Company Continuous process for the production of combinatorial libraries of materials
ES2295356T3 (es) 2001-05-15 2008-04-16 Ciba Specialty Chemicals Holding Inc. Metodo de injerto de derivados de acido carboxilico etilenicamente insaturados en polimeros termoplasticos utilizando esteres de hidroxilamina.
CA2487721A1 (en) * 2002-06-20 2003-12-31 Ciba Specialty Chemicals Holding Inc. Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers
US7157283B2 (en) * 2002-08-02 2007-01-02 3M Innovative Properties Company Continuous process for the production of combinatorial libraries of modified materials
US7632916B2 (en) * 2002-08-02 2009-12-15 3M Innovative Properties Company Process to modify polymeric materials and resulting compositions
AU2003267011A1 (en) 2002-09-04 2004-03-29 Ciba Specialty Chemicals Holding Inc. Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers
ATE481431T1 (de) * 2003-02-05 2010-10-15 Dow Global Technologies Inc Steuerung von teilchengrösse und morphologie in kautschukmodifizierten monovinylidenaromat- polymeren
US6967228B2 (en) * 2003-05-01 2005-11-22 Firestone Polymers, Llc Stable free radical polymers
US20040220345A1 (en) * 2003-05-01 2004-11-04 Firestone Polymers, Llc Stable free radical polymers
US7517934B2 (en) * 2003-07-31 2009-04-14 Basf Corporation Modified anionically polymerized polymers
US7572868B2 (en) * 2003-08-27 2009-08-11 Ciba Specialty Chemicals Corp. Composition and process for the controlled synthesis of block copolymers
US20070078197A1 (en) * 2003-10-07 2007-04-05 Coloplast A/S Adhesive composition and use of such composition
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
CN101180332B (zh) * 2005-05-03 2010-08-04 西巴特殊化学品控股有限公司 从环氧官能化硝酰基醚和阴离子可聚合单体制备梳形嵌段共聚物的方法
US7560509B2 (en) * 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
US7737218B2 (en) 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US8030410B2 (en) * 2006-12-29 2011-10-04 Bridgestone Corporation Method for generating free radical capable polymers using carbonyl-containing compounds
US7396887B1 (en) * 2006-12-29 2008-07-08 Bridgestone Corporation Insitu removal of chelator from anionic polymerization reactions
US20080157641A1 (en) * 2006-12-31 2008-07-03 Rachael Wren Grout Multi-use Free Standing Seating and Storage Unit
WO2009149001A1 (en) * 2008-06-06 2009-12-10 Union Carbide Chemicals & Plastics Technology Llc Method for inhibiting scorch in crosslinkable compositions
EP2995631A1 (en) * 2014-09-12 2016-03-16 Borealis AG Process for producing graft copolymers on polyolefin backbone
CN110938174B (zh) * 2019-11-12 2020-11-13 江苏麒祥高新材料有限公司 一种接枝改性天然橡胶、其制备方法、包含接枝改性天然橡胶的橡胶组合物及其应用
CN114106341B (zh) * 2020-08-28 2025-05-02 广州立邦涂料有限公司 梳状共聚物及其制备方法和应用

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JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
DE3486145T2 (de) * 1983-07-11 1993-09-23 Commw Scient Ind Res Org Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere.
US5322912A (en) 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom
FR2730240A1 (fr) * 1995-02-07 1996-08-09 Atochem Elf Sa Stabilisation d'un polymere par un radical libre stable
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators
HU220138B (hu) 1996-03-29 2001-11-28 The Dow Chemical Co. Szabadgyökös tömbpolimerizálási eljárás kaucsukkal módosított polimerek vinil-aromás monomerekből való előállítására
US5723511A (en) * 1996-06-17 1998-03-03 Xerox Corporation Processes for preparing telechelic, branched and star thermoplastic resin polymers
US5910549A (en) * 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
FR2754535A1 (fr) * 1996-10-16 1998-04-17 Atochem Elf Sa Polymeres greffes a viscosite controlee
FR2768739B1 (fr) * 1997-09-19 2004-08-06 Atochem Elf Sa Polymere vinylaromatique choc obtenu a partir d'un caoutchouc porteur d'un groupement generateur d'un radical libre stable
DE19752394A1 (de) * 1997-11-19 1999-05-20 Basf Ag Verfahren zur Herstellung von Pfropfpolymerisaten
EP1115765B1 (en) * 1998-09-03 2009-06-24 Ciba Holding Inc. Grafting of ethylenically unsaturated monomers onto polymers

Also Published As

Publication number Publication date
WO2000014135A1 (en) 2000-03-16
AU760128B2 (en) 2003-05-08
BR9913416A (pt) 2001-05-22
DE69927839T2 (de) 2006-05-11
JP4516213B2 (ja) 2010-08-04
ES2251225T3 (es) 2006-04-16
CA2340689A1 (en) 2000-03-16
DE69927839D1 (de) 2006-03-02
KR100575149B1 (ko) 2006-04-28
AU5738899A (en) 2000-03-27
EP1115766A1 (en) 2001-07-18
EP1115766B1 (en) 2005-10-19
JP2002524590A (ja) 2002-08-06
CN1315970A (zh) 2001-10-03
KR20010072720A (ko) 2001-07-31
ATE307150T1 (de) 2005-11-15
US6521710B1 (en) 2003-02-18

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Termination date: 20110823