CN114935610B - 一种用气相色谱同时测定酸性气中含硫含醇组分含量的方法及其系统 - Google Patents
一种用气相色谱同时测定酸性气中含硫含醇组分含量的方法及其系统 Download PDFInfo
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- CN114935610B CN114935610B CN202210352504.4A CN202210352504A CN114935610B CN 114935610 B CN114935610 B CN 114935610B CN 202210352504 A CN202210352504 A CN 202210352504A CN 114935610 B CN114935610 B CN 114935610B
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- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000002253 acid Substances 0.000 title claims abstract description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 24
- 239000011593 sulfur Substances 0.000 title claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000004817 gas chromatography Methods 0.000 title claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 104
- 238000002347 injection Methods 0.000 claims abstract description 85
- 239000007924 injection Substances 0.000 claims abstract description 85
- 238000004458 analytical method Methods 0.000 claims abstract description 24
- 239000012159 carrier gas Substances 0.000 claims abstract description 24
- 238000001514 detection method Methods 0.000 claims abstract description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000004868 gas analysis Methods 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 8
- 238000005070 sampling Methods 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 125000006850 spacer group Chemical group 0.000 claims description 7
- 229910001220 stainless steel Inorganic materials 0.000 claims description 7
- 239000010935 stainless steel Substances 0.000 claims description 7
- 238000004587 chromatography analysis Methods 0.000 claims description 6
- 239000003463 adsorbent Substances 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- 238000011088 calibration curve Methods 0.000 claims description 3
- 238000004891 communication Methods 0.000 claims description 3
- 238000013500 data storage Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 2
- 238000009423 ventilation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
Abstract
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CN202210352504.4A CN114935610B (zh) | 2022-04-05 | 2022-04-05 | 一种用气相色谱同时测定酸性气中含硫含醇组分含量的方法及其系统 |
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CN114935610A CN114935610A (zh) | 2022-08-23 |
CN114935610B true CN114935610B (zh) | 2023-12-22 |
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CN116973524A (zh) * | 2023-09-25 | 2023-10-31 | 上海良薇机电工程有限公司 | 一种纯度分析装置、方法及半导体工艺系统 |
CN117130297B (zh) * | 2023-10-25 | 2023-12-29 | 北京豪思生物科技股份有限公司 | 一种液相色谱仪的上位机控制方法、装置及设备 |
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US4293308A (en) * | 1978-10-13 | 1981-10-06 | Carlo Erba Strumentazione S.P.A. | Method and apparatus for the analysis of sulphur contents in samples |
US4587834A (en) * | 1985-03-07 | 1986-05-13 | General Electric Company | Method and apparatus for analyzing gases dissolved in a liquid sample |
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CN102706996A (zh) * | 2012-06-27 | 2012-10-03 | 中国科学院地质与地球物理研究所兰州油气资源研究中心 | 气相色谱法一次进样分析大气中Ar+O2、N2、CO2、N2O |
CN102879490A (zh) * | 2012-09-21 | 2013-01-16 | 中国科学院地质与地球物理研究所兰州油气资源研究中心 | 气相色谱法一次进样分析大气中Ar+O2、N2、CH4、CO2、N2O |
CN103792299A (zh) * | 2013-06-05 | 2014-05-14 | 中国石油天然气股份有限公司 | 一种油田火驱产出气组分的气相色谱分析方法及装置 |
JP2020127935A (ja) * | 2019-02-08 | 2020-08-27 | 大阪瓦斯株式会社 | 二酸化炭素を主成分とするガス中の硫黄酸化物の除去方法 |
CN112461969A (zh) * | 2020-11-19 | 2021-03-09 | 必睿思(杭州)科技有限公司 | 一种人体呼出气七种气体气相色谱分析方法 |
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US7269991B2 (en) * | 2003-02-14 | 2007-09-18 | Air Liquide America L.P. | Permeation calibrator |
RU2404362C2 (ru) * | 2005-12-29 | 2010-11-20 | Шлюмбергер Текнолоджи Б.В. | Кабельный внутрискважинный газовый хроматограф и способ внутрискважинной газовой хроматографии |
WO2020071107A1 (ja) * | 2018-10-04 | 2020-04-09 | 日本碍子株式会社 | ガス分離方法およびガス分離装置 |
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2022
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US4293308A (en) * | 1978-10-13 | 1981-10-06 | Carlo Erba Strumentazione S.P.A. | Method and apparatus for the analysis of sulphur contents in samples |
US4587834A (en) * | 1985-03-07 | 1986-05-13 | General Electric Company | Method and apparatus for analyzing gases dissolved in a liquid sample |
BR0006272A (pt) * | 2000-12-22 | 2002-08-13 | Maria Cristina Marcucc Ribeiro | Processo de identificação de tipagens da própolis brasileira |
CN102706996A (zh) * | 2012-06-27 | 2012-10-03 | 中国科学院地质与地球物理研究所兰州油气资源研究中心 | 气相色谱法一次进样分析大气中Ar+O2、N2、CO2、N2O |
CN102879490A (zh) * | 2012-09-21 | 2013-01-16 | 中国科学院地质与地球物理研究所兰州油气资源研究中心 | 气相色谱法一次进样分析大气中Ar+O2、N2、CH4、CO2、N2O |
CN103792299A (zh) * | 2013-06-05 | 2014-05-14 | 中国石油天然气股份有限公司 | 一种油田火驱产出气组分的气相色谱分析方法及装置 |
JP2020127935A (ja) * | 2019-02-08 | 2020-08-27 | 大阪瓦斯株式会社 | 二酸化炭素を主成分とするガス中の硫黄酸化物の除去方法 |
CN112461969A (zh) * | 2020-11-19 | 2021-03-09 | 必睿思(杭州)科技有限公司 | 一种人体呼出气七种气体气相色谱分析方法 |
Non-Patent Citations (8)
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Conversion of carbonyl sulfide using a low-temperature discharge approach;Cheng hsien tsai et al;《Aerosol and air quality research》;第7卷(第2期);全文 * |
中华人民共和国国家质量监督检验检疫总局中国国家标准化管理委员会.《GB/T 8984-2008》.2008,全文. * |
多阀多柱气相色谱技术在工业用气体分析中的应用;王静;郝艳红;白雨萍;;汽车工艺与材料(05);全文 * |
气相色谱在煤气热值成分分析中的应用;杨四川;;上海煤气(04);全文 * |
气相色谱法一次进样分析氩、甲烷、一氧化碳、硫化氢、二硫化碳、一氧化二氮等十一组分;潘旭;《全国生物医药色谱学术交流会(2010景德镇)论文集》;全文 * |
气相色谱法测定克劳斯酸性气中的CS_2;唐晓峰;罗金涛;;神华科技(03);全文 * |
煤制甲醇净化气中微量硫化氢、羰基硫色谱操作条件研究;罗金涛;唐晓峰;;神华科技(10);全文 * |
神华煤直接液化工艺气体微量硫的测定;刘新颖;《化学生物与环保》;全文 * |
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Inventor after: Wang Yongjun Inventor after: Dong Zhizhi Inventor after: Hu Jinlian Inventor after: He Shenglong Inventor after: Liu Xinli Inventor after: Wang Cheng Inventor after: Dong Shubin Inventor after: Qi Kai Inventor before: Wang Yongjun Inventor before: Hu Jinlian Inventor before: Dong Zhizhi Inventor before: He Shenglong Inventor before: Liu Xinli Inventor before: Wang Cheng Inventor before: Dong Shubin Inventor before: Qi Kai |
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