CN114835520A - Biological pesticide fertilizer and preparation method and application thereof - Google Patents
Biological pesticide fertilizer and preparation method and application thereof Download PDFInfo
- Publication number
- CN114835520A CN114835520A CN202210349444.0A CN202210349444A CN114835520A CN 114835520 A CN114835520 A CN 114835520A CN 202210349444 A CN202210349444 A CN 202210349444A CN 114835520 A CN114835520 A CN 114835520A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- biological
- parts
- potassium
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 84
- 239000000575 pesticide Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 240000008067 Cucumis sativus Species 0.000 claims abstract description 64
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 35
- -1 compound amino acid Chemical class 0.000 claims abstract description 31
- 238000000227 grinding Methods 0.000 claims abstract description 30
- 235000009849 Cucumis sativus Nutrition 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 21
- 239000003814 drug Substances 0.000 claims abstract description 19
- 239000003899 bactericide agent Substances 0.000 claims abstract description 17
- 235000013311 vegetables Nutrition 0.000 claims abstract description 17
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 14
- 239000011707 mineral Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 12
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 59
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 42
- 235000001014 amino acid Nutrition 0.000 claims description 34
- 229940024606 amino acid Drugs 0.000 claims description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 30
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical group O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 25
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 25
- 229940080314 sodium bentonite Drugs 0.000 claims description 25
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 24
- 230000001737 promoting effect Effects 0.000 claims description 23
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 22
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- 239000002202 Polyethylene glycol Substances 0.000 claims description 21
- 229920001223 polyethylene glycol Polymers 0.000 claims description 21
- 239000002518 antifoaming agent Substances 0.000 claims description 20
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 19
- 239000000230 xanthan gum Substances 0.000 claims description 19
- 235000010493 xanthan gum Nutrition 0.000 claims description 19
- 229920001285 xanthan gum Polymers 0.000 claims description 19
- 229940082509 xanthan gum Drugs 0.000 claims description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 18
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 16
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 16
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 16
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 16
- QFMDFTQOJHFVNR-UHFFFAOYSA-N 1-[2,2-dichloro-1-(4-ethylphenyl)ethyl]-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1C(C(Cl)Cl)C1=CC=C(CC)C=C1 QFMDFTQOJHFVNR-UHFFFAOYSA-N 0.000 claims description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
- 150000001413 amino acids Chemical class 0.000 claims description 13
- 235000010755 mineral Nutrition 0.000 claims description 13
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 11
- 239000005869 Pyraclostrobin Substances 0.000 claims description 11
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 11
- 239000004202 carbamide Substances 0.000 claims description 11
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 11
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 11
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 11
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- 239000011574 phosphorus Substances 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- 239000011591 potassium Substances 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 8
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 8
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 8
- 239000005857 Trifloxystrobin Substances 0.000 claims description 7
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 7
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 7
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 7
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 7
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 7
- 239000002562 thickening agent Substances 0.000 claims description 7
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims description 7
- 239000004475 Arginine Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 229960003067 cystine Drugs 0.000 claims description 6
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 5
- 229940092782 bentonite Drugs 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 239000002917 insecticide Substances 0.000 claims description 5
- 239000004323 potassium nitrate Substances 0.000 claims description 5
- 235000010333 potassium nitrate Nutrition 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 5
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims description 4
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 claims description 4
- 241000607479 Yersinia pestis Species 0.000 claims description 4
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 4
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 239000001103 potassium chloride Substances 0.000 claims description 4
- 235000011164 potassium chloride Nutrition 0.000 claims description 4
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 claims description 4
- 230000002786 root growth Effects 0.000 claims description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 claims description 2
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims description 2
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 claims description 2
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims description 2
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 claims description 2
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000009582 asparagine Nutrition 0.000 claims description 2
- 229960001230 asparagine Drugs 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000018417 cysteine Nutrition 0.000 claims description 2
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 239000010459 dolomite Substances 0.000 claims description 2
- 229910000514 dolomite Inorganic materials 0.000 claims description 2
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 claims description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 claims description 2
- 238000003973 irrigation Methods 0.000 claims description 2
- 230000002262 irrigation Effects 0.000 claims description 2
- 239000003077 lignite Substances 0.000 claims description 2
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 claims description 2
- 239000002367 phosphate rock Substances 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 235000015097 nutrients Nutrition 0.000 abstract description 13
- 230000012010 growth Effects 0.000 abstract description 9
- 208000035143 Bacterial infection Diseases 0.000 abstract description 4
- 208000031888 Mycoses Diseases 0.000 abstract description 4
- 241000894006 Bacteria Species 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 27
- 239000000243 solution Substances 0.000 description 26
- CSGLCWIAEFNDIL-UHFFFAOYSA-O azanium;urea;nitrate Chemical compound [NH4+].NC(N)=O.[O-][N+]([O-])=O CSGLCWIAEFNDIL-UHFFFAOYSA-O 0.000 description 15
- 239000012452 mother liquor Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 239000002131 composite material Substances 0.000 description 12
- 229920002545 silicone oil Polymers 0.000 description 12
- 201000010099 disease Diseases 0.000 description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 210000000582 semen Anatomy 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- LEVWYRKDKASIDU-IMJSIDKUSA-N L-cystine Chemical compound [O-]C(=O)[C@@H]([NH3+])CSSC[C@H]([NH3+])C([O-])=O LEVWYRKDKASIDU-IMJSIDKUSA-N 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 5
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 4
- 235000003704 aspartic acid Nutrition 0.000 description 4
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 4
- 208000015181 infectious disease Diseases 0.000 description 4
- 235000013877 carbamide Nutrition 0.000 description 3
- 125000003636 chemical group Chemical group 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000012055 fruits and vegetables Nutrition 0.000 description 2
- 239000000413 hydrolysate Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 240000008669 Hedera helix Species 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 244000303847 Lagenaria vulgaris Species 0.000 description 1
- 235000009797 Lagenaria vulgaris Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 229910000281 calcium bentonite Inorganic materials 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010413 mother solution Substances 0.000 description 1
- 238000009336 multiple cropping Methods 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 235000021048 nutrient requirements Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000002054 transplantation Methods 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to the field of fertilizers, in particular to a biological medicinal fertilizer, and a preparation method and application thereof. The preparation method of the biological pesticide fertilizer comprises the following steps: mixing bactericide, mineral, emulsifying dispersant, anticrystallizing agent, nitrogen-phosphorus-potassium raw material and compound amino acid, and grinding. The biological pesticide fertilizer can be used for planting vegetables, particularly cucumbers. The biological medicine fertilizer provided by the invention can provide nutrients for the growth of crops, can prevent and treat bacteria and fungal diseases, has strong pertinence, can promote the growth of cucumbers, promote the growth of root systems of the crops, improve the yield of the crops, enhance the stress resistance of the crops, is more labor-saving and labor-saving when in use, can reduce the labor cost, and can enhance the absorption of the crops to the nutrients.
Description
Technical Field
The invention relates to the field of fertilizers, in particular to a biological pesticide fertilizer and a preparation method and application thereof.
Background
In China, the planting area of cucumbers is large, and the problems of increasing soil-borne diseases, high incidence of plant diseases and insect pests and the like continuously appear in cucumber farmlands planted regularly. The reasons for these problems can be summarized as poor plant growth, decreased resistance and the like due to unbalanced nutrient addition. Firstly, the cucumber multiple cropping index is high, and more chemical fertilizer is added, so that the microbial detonation effect is obvious, and the organic matter consumption of soil in season is intensified. The developed root system of the cucumber can reach 50-60cm, and the cucumber has larger nutrient demand. Meanwhile, the cucumber vaccine has strong variability aiming at common diseases of cucumbers, such as brown spot, blight, southern blight and the like, and is easy to generate drug resistance to common chemical bactericides and difficult to radically cure.
The soil obstacle and disease problems in the cucumber planting process can be solved by increasing the organic matter input, adjusting the fertilizer nutrient distribution ratio, selecting biological pesticides which are not easy to generate drug resistance and the like. However, the prior art only solves the problem of cucumber planting obstacle from one direction, and cannot comprehensively solve the problems of soil and diseases through a single way. In addition, the pesticide selected in the prior art has poor effect and is easy to remain. Meanwhile, the conventional cucumber fertilizer is only considered from the viewpoint of meeting the nutrient requirements of cucumbers, and does not have the effect of improving the growth stress resistance of the cucumbers, so that chemical industrial raw materials and microbial agents still need to be added if the root promoting and stress resisting functions are needed, so that the cucumber planting price is relatively high, and the environmental pollution risk is possibly caused.
Disclosure of Invention
In view of the above-mentioned disadvantages of the prior art, the present invention aims to provide a biological fertilizer, a preparation method and a use thereof, which are used for solving the problems in the prior art.
In order to achieve the above objects and other related objects, the present invention provides a biological medical fertilizer, which comprises a bactericide, minerals, an emulsifying dispersant, an anti-crystallizing agent, nitrogen, phosphorus and potassium raw materials, and compound amino acids.
Preferably, the biological medicine fertilizer comprises the following substances in parts by weight:
the invention also provides a preparation method of the biological medicine fertilizer, which is characterized by comprising the following steps: mixing and grinding the bactericide, the mineral substances, the emulsifying dispersant, the anti-crystallizing agent, the nitrogen, phosphorus and potassium raw materials and the compound amino acid to obtain the biological medicine fertilizer.
The invention also provides application of the biological pesticide fertilizer in vegetable planting.
The invention also provides a cucumber planting method, which comprises the step of applying the biological medicine fertilizer to cucumbers.
As mentioned above, the biological pesticide fertilizer and the preparation method and the application thereof have the following beneficial effects: the pesticide and the fertilizer are combined through the compound auxiliary agent, and the respective stability of the pesticide and the fertilizer is kept, so that the pesticide and the fertilizer are more labor-saving and labor-saving when in use, and the labor cost is reduced. And according to common fungus or bacterial diseases such as brown spot, blight and southern blight in the growth constitution of cucumbers, biopesticides with strong pertinence and low biohazard are selected, and a certain active substance amino acid is added, so that the nutrient absorption of crops can be enhanced, the root growth of the crops can be promoted, and the yield of the crops can be increased. According to the invention, by limiting the use ratio of the composite bactericide, the sodium bentonite, the emulsifying dispersant, the anti-crystallizing agent, the composite amino acid, the pH regulator, the nitrogen phosphorus potassium raw material, the defoaming agent and the thickening agent, the cucumber growth nutrient is guaranteed, and meanwhile, the bacterial and fungal diseases are prevented and treated, the cucumber growth is promoted, and the stress resistance of the cucumber is enhanced.
Detailed Description
The invention provides a compound biological pesticide fertilizer aiming at the problems that in the prior art, pesticides and fertilizers are often applied separately in the production of vegetables such as cucumbers, the labor cost is increased, and few medicaments designed aiming at diseases are easy to occur in the production process of the vegetables, wherein the biological pesticide fertilizer comprises a bactericide, mineral substances, an emulsifying dispersant, an anti-crystallizing agent, a nitrogen-phosphorus-potassium raw material and compound amino acid.
In one embodiment, the biological medicine fertilizer comprises the following substances in parts by weight:
the bactericide is selected from a composite bactericide or a single bactericide. In one embodiment, the biocide is a composite biocide. The composite bactericide is selected from one or more of pyraclostrobin, trifloxystrobin, shenqinmycin, acephate, fenitrothion and dimethylformamide.
The ratio between the various bactericides in the composite bactericide is not particularly limited.
In one embodiment, the amount of the bactericide is selected from the group consisting of 2 to 3 parts, 3 to 4 parts, 4 to 5 parts, 5 to 6 parts and 7 to 8 parts by weight.
The mineral is one or more selected from dolomite, ground phosphate rock, turfy soil, bentonite or lignite.
In one embodiment, the mineral is bentonite. Preferably, the mineral is calcium bentonite and/or sodium bentonite. More preferably, the mineral is sodium bentonite.
In one embodiment, the mineral is present in an amount of 2 to 3 parts, 3 to 4 parts, 4 to 5 parts, or 5 to 6 parts by weight.
The emulsifying dispersant is selected from one or more of WLNO UK, sodium hexametaphosphate, sodium tripolyphosphate, Morwet D-500, Agrilan 752, Ethylan NS-500lq, YUS-EP60P and YUS-FS7 PG. Preferably, the emulsifying dispersant is a composite emulsifying dispersant.
In one embodiment, the emulsifying dispersant is 2 to 3 parts by weight or 3 to 4 parts by weight.
The anti-crystallizing agent is one or more selected from ethylene glycol, glycerol and polyethylene glycol;
the nitrogen raw material in the nitrogen, phosphorus and potassium raw materials is selected from one or more of urea ammonium nitrate solution (UAN), urea and ammonium dihydrogen phosphate. The urea ammonium nitrate solution, also known as nitrogen solution (N solution), is made up of urea, ammonium nitrate and water. In the urea ammonium nitrate solution, the content of nitrate nitrogen is generally 6.5-7.5%, the content of ammonium nitrogen is 6.5-7.5%, and the content of amide nitrogen is 14-17%.
The potassium raw material in the nitrogen, phosphorus and potassium raw materials is one or more selected from potassium nitrate, potassium chloride, potassium dihydrogen phosphate and potassium pyrophosphate.
The phosphorus in the nitrogen phosphorus potassium raw material is selected from one or more of potassium dihydrogen phosphate, ammonium polyphosphate and ammonium dihydrogen phosphate.
The ratio of nitrogen, phosphorus and potassium in the nitrogen-phosphorus-potassium raw material is not particularly limited.
The compound amino acid is hydrolysate of hydrolyzed waste keratin such as bird feather and animal hair, and the hydrolysate is rich in amino acids such as cystine, leucine, tyrosine, arginine, histidine, tyrosine, cysteine, asparagine, etc. The total amino acid content in the compound amino acid is 15-20% (by mass), namely 110-150 g/L amino acid content.
In one embodiment, the biological drug fertilizer further comprises any one or more of a pH adjuster, a defoaming agent, and a thickener.
In one embodiment, the pH regulator is 1 to 2 parts by weight.
The pH regulator is selected from one or more of formic acid, propionic acid, citric acid, ammonia water, sodium carbonate and sodium hydroxide.
In one embodiment, the defoamer is present in an amount of 1 to 2 parts by weight.
The defoaming agent is one or more of organic silicon defoaming agent, octanol, Tween80 and tributyl phosphate.
In one embodiment, the thickener is 1 to 2 parts by weight.
The thickening agent is one or more of FL-100, PVA, sodium carboxymethylcellulose, xanthan gum, Arabic gum, white carbon black and magnesium aluminum silicate.
The biological pesticide fertilizer is a liquid fertilizer.
The biological pesticide fertilizer has the effects of promoting root growth and resisting stress. The biological pesticide fertilizer has an inhibiting effect on bacterial or fungal diseases such as brown spot, blight or southern blight, and the like, and has a root-promoting and stress-resisting effect on promoting the growth of plant root systems.
The biological pesticide fertilizer is a special biological pesticide fertilizer for vegetables. In one embodiment, the biological medicine fertilizer is a special biological medicine fertilizer for cucumbers.
The invention also provides a preparation method of the biological medicine fertilizer, which comprises the following steps: mixing bactericide, mineral, emulsifying dispersant, anticrystallizing agent, nitrogen-phosphorus-potassium raw material and compound amino acid, and grinding.
In one embodiment, the grinding step comprises: grinding for 5-10 minutes at 12000r/min 8000-.
In one embodiment, the preparation method further comprises adding a pH regulator into the ground system, and adjusting the pH to 6.5-7.0 to obtain the biological medicinal fertilizer.
The invention also provides application of the biological pesticide fertilizer in vegetable planting.
In one embodiment, the biological pesticide fertilizer is used for controlling vegetable pests, promoting roots and increasing yield.
The vegetable diseases and insect pests include anthracnose, brown spot, blight, powdery mildew, rust disease, gray mold, southern blight and the like.
The root promotion is to promote the root length or dry weight of the vegetable.
The vegetables are fruits and vegetables. The fruit and vegetable is selected from Capsici fructus, fructus Cucurbitae Moschatae, golden silk fructus Cucurbitae Moschatae, fructus Benincasae, fructus Momordicae Charantiae, fructus Cucumidis Sativi, fructus Luffae, fructus Cucumidis Sativi, bottle gourd, fructus Cucurbitae Moschatae, fructus Lycopersici Esculenti, fructus Solani Melongenae, semen Phaseoli vulgaris, semen Vignae sinensis, semen Pisi Sativi, frame bean, semen Canavaliae, semen lablab album, semen Phaseoli vulgaris, herba Vignae Cylindricae, herba Viburni Cylindricae, and sweet semen Maydis. In one embodiment, the vegetable is cucumber.
The invention also provides a cucumber planting method, which comprises the step of applying the biological medicine fertilizer to cucumbers.
In one embodiment, the application amount is 40-60 g biological insecticide fertilizer/mu/time.
In one embodiment, the dilution is 500-.
In one embodiment, the application is started 10 to 35 days after the cucumber is transplanted into the field. The composition is applied once every 6 to 15 days, and 4 to 6 times in total. The specific application time and times can be adjusted according to the planting condition. For example, the cucumber fertilizer can be applied after the cucumber is transplanted to the field for 10 to 15 days, 15 to 20 days, 20 to 25 days, 25 to 30 days or 30 to 35 days. The composition is applied once every 6-8 days, 8-10 days, 10-12 days and 12-15 days, and is applied for 4-6 times in total.
In one embodiment, the method of application is selected from spray application, root irrigation.
The embodiments of the present invention are described below with reference to specific embodiments, and other advantages and effects of the present invention will be easily understood by those skilled in the art from the disclosure of the present specification. The invention is capable of other and different embodiments and of being practiced or of being carried out in various ways, and its several details are capable of modification in various respects, all without departing from the spirit and scope of the present invention.
Before the present embodiments are further described, it is to be understood that the scope of the invention is not limited to the particular embodiments described below; it is also to be understood that the terminology used in the examples is for the purpose of describing particular embodiments, and is not intended to limit the scope of the present invention; in the description and claims of the present application, the singular forms "a", "an" and "the" include plural referents unless the context clearly dictates otherwise.
When numerical ranges are given in the examples, it is understood that both endpoints of each of the numerical ranges and any value therebetween can be selected unless the invention otherwise indicated. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In addition to the specific methods, devices, and materials used in the examples, any methods, devices, and materials similar or equivalent to those described in the examples may be used in the practice of the invention in addition to the specific methods, devices, and materials used in the examples, in keeping with the knowledge of one skilled in the art and with the description of the invention.
Example 1
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 2 parts of pyraclostrobin, 2 parts of trifloxystrobin, 4 parts of sodium bentonite, 1 part of sodium hexametaphosphate, 1 part of sodium tripolyphosphate, 3 parts of glycerol, 3 parts of polyethylene glycol, 6 parts of urea, 4 parts of potassium nitrate, 5 parts of monopotassium phosphate, 63.5 parts of composite amino acid mother liquor (containing cystine, aspartic acid and arginine and having a total amino acid content of 120g/L), 0.5 part of formic acid, 1 part of ammonia water, 2 parts of an organic silicon defoamer, 1 part of sodium carboxymethylcellulose and 1 part of xanthan gum.
Pyraclostrobin (B): shandong kang Qiao Biotech Co., Ltd
Trifloxystrobin: special agricultural chemical company of Hunan, agricultural and sea
Sodium bentonite: great industry and trade company Limited of Renshouxing, Sichuan province
Sodium hexametaphosphate: chongqing Chuandong chemical industry (group) Co Ltd
Sodium tripolyphosphate: hubei Xingsheng chemical group corporation
Glycerol: henan Shengkun chemical products Co Ltd
Polyethylene glycol: "Haian" petrochemical plant of Jiangsu province
Urea: tianjin Chengyuan chemical reagent Co., Ltd
Potassium nitrate: youlide chemical Co.Ltd
Potassium dihydrogen phosphate: limited liability company of chemical engineering of Sichuan Jiuhe
Cystine: hebei Wangyou Biotechnology Co., Ltd
Aspartic acid: hebei Wangyou Biotechnology Co., Ltd
Arginine: hebei Wangyou Biotechnology Co., Ltd
Formic acid: qingdao Jilong chemical Co Ltd
Ammonia water: beijing Zeping technologies, Limited liability company
Organic silicon defoamer: dongguan Tianyu chemical Co., Ltd
Sodium carboxymethylcellulose: chongqing force macro fine chemical industry Co Ltd
Xanthan gum: zhongxuan Biochemical Co., Ltd, Ordos
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 5 parts of sodium bentonite, 2 parts of Ethylan NS-500lq, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 65 parts of water, 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoaming agent, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Sodium bentonite: great industry and trade company Limited of Renshouxing, Sichuan province
Ethylan NS-500 lq: south Beijing Jirun science and technology Co Ltd
Agrilan 752: south Beijing Jirun science and technology Co Ltd
Polyethylene glycol: "Haian" petrochemical plant of Jiangsu province
Ethylene glycol: torpos chemical technology (Beijing) Ltd
Urea ammonium nitrate solution (UAN): shandong province Shandong province Shandong province
Potassium pyrophosphate: hubei Xingsheng chemical group corporation
Ammonium polyphosphate: zhengzhou Zhuo Chuang chemical products Co Ltd
Sodium carbonate: tianjin Bohai chemical industry products Ltd
Tributyl phosphate: sanuo chemical Co Ltd
And (3) organic silicone oil defoaming agent: dongguan Tianyu chemical Co., Ltd
Xanthan gum: zhongxuan Biochemical Co., Ltd, Ordos
Magnesium aluminum silicate: henan Liaotao chemical Co Ltd
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 2 parts of shenqinmycin, 2 parts of pyraclostrobin, 5 parts of sodium bentonite, 5 parts of Ethylan NS-500lq2 parts, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 59 parts of compound amino acid mother liquor (cystine, aspartic acid and arginine, the content of total amino acids is 125g/L), 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoamer, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Shenqinmycin: shanghai Nongle biological products GmbH
Pyraclostrobin (B): shandong kang Qiao Biotech Co., Ltd
Sodium bentonite: great industry and trade company Limited of Renshouxing, Sichuan province
Ethylan NS-500 lq: south Beijing Jirun science and technology Co Ltd
Agrilan 752: south Beijing Jirun science and technology Co Ltd
Polyethylene glycol: "Haian" petrochemical plant of Jiangsu province
Ethylene glycol: torpos chemical technology (Beijing) Ltd
Urea ammonium nitrate solution (UAN): shandong province Shandong province Shandong province
Potassium pyrophosphate: hubei Xingsheng chemical group corporation
Ammonium polyphosphate: zhengzhou Zhuo Chuang chemical products Co Ltd
Cystine: hebei Wangyou Biotechnology Co., Ltd
Aspartic acid: hebei Wangyou Biotechnology Co., Ltd
Arginine: hebei Wangyou Biotechnology Co., Ltd
Sodium carbonate: tianjin Bohai chemical industry products Ltd
Tributyl phosphate: sanuo chemical Co Ltd
And (3) organic silicone oil defoaming agent: dongguan Tianyu chemical Co., Ltd
Xanthan gum: zhongxuan Biochemical Co., Ltd, Ordos
Magnesium aluminum silicate: henan Liaotao chemical Co Ltd
Mixing pyraclostrobin, trifloxystrobin, sodium bentonite, sodium hexametaphosphate, sodium tripolyphosphate, glycerol, polyethylene glycol, urea, potassium nitrate, monopotassium phosphate and compound amino acid mother liquor in a reaction kettle according to a proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding an organic silicon defoaming agent, sodium carboxymethylcellulose and xanthan gum, and then grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; formic acid and ammonia water are added into the ground product, the pH value is adjusted to 6.64, and the liquid biological bactericidal pesticide fertilizer special for cucumbers with the root promoting and stress resisting functions is prepared.
Example 2
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 3 parts of shenqinmycin, 2 parts of acephate, 4 parts of sodium bentonite, 4 parts of sodium hexametaphosphate, 3 parts of glycerol, 5 parts of ethylene glycol, 5 parts of urea, 6 parts of potassium chloride, 5 parts of monopotassium phosphate, 60 parts of compound amino acid mother liquor, 1 part of ammonia water, 2 parts of octanol and 2 parts of xanthan gum.
Mixing shenqinmycin, acephate, sodium bentonite, sodium hexametaphosphate, WLNO UK, glycerol, glycol, urea, potassium chloride, monopotassium phosphate and compound amino acid mother liquor in a reaction kettle according to a proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-; and adding ammonia water into the ground product, adjusting the pH value to 6.84, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Example 3
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 3 parts of shenqinmycin, 2 parts of dimethylformamide, 5 parts of sodium bentonite, Yus-EP60P 2 parts, Yus-FS7PG 2 parts, 3 parts of polyethylene glycol, 5 parts of ethylene glycol, 5 parts of urea, 7 parts of monopotassium phosphate, 3 parts of ammonium dihydrogen phosphate, 57 parts of composite amino acid mother liquor, 1 part of ammonia water, 2 parts of octanol, 1 part of Arabic gum and 1 part of magnesium aluminum silicate.
Mixing shenqinmycin, an ethoxy imidazoline compound, dimethylformamide, sodium bentonite, YUS-EP60P, YUS-FS7PG, polyethylene glycol, ethylene glycol, urea, potassium dihydrogen phosphate, ammonium dihydrogen phosphate and compound amino acid mother liquor in a reaction kettle according to a proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine (a 3 KW-75 KW mechanical factory, a De Sheng plastics, Li Zhou) under the condition of 8000-12000r/min, then adding octanol, Arabic gum and magnesium aluminum silicate, and grinding for 30-40 minutes by using a grinding machine under the condition of 500-1000 r/min; and adding ammonia water into the ground product, adjusting the pH value to 6.64, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Example 4
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 2 parts of dimethylformamide, 1 part of shenqinmycin, 2 parts of trifloxystrobin, 5 parts of sodium bentonite, 2 parts of Ethylan NS-500lq, 2 parts of YUS-EP60P 2, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 8 parts of ammonium dihydrogen phosphate, 3 parts of potassium pyrophosphate, 3 parts of ammonium polyphosphate, 59 parts of composite amino acid mother liquor, 1 part of ammonia water, 2 parts of tributyl phosphate, 1 part of sodium carboxymethylcellulose and 1 part of magnesium aluminum silicate.
Mixing dimethylformamide, shenqinmycin, trifloxystrobin, sodium bentonite, Ethylan NS-500lq, YUS-EP60P, polyethylene glycol, ethylene glycol, ammonium dihydrogen phosphate, potassium pyrophosphate, ammonium polyphosphate and compound amino acid mother liquor in a reaction kettle according to a proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding tributyl phosphate, sodium carboxymethylcellulose and magnesium aluminum silicate, and then grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; and adding ammonia water into the ground product, adjusting the pH value to 6.78, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Example 5
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 2 parts of ethoxy imidazoline compound, 2 parts of shenqinmycin, 2 parts of pyraclostrobin, 5 parts of sodium bentonite, 2 parts of Ethylan NS-500lq, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 59 parts of compound amino acid mother liquor, 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoaming agent, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Mixing an ethoxy imidazoline compound, shenqinmycin, pyraclostrobin, sodium bentonite, Ethylan NS-500lq, Agrilan 752, polyethylene glycol, ethylene glycol, a urea ammonium nitrate solution (UAN), potassium pyrophosphate, ammonium polyphosphate and a compound amino acid mother solution in a reaction kettle according to a proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding an organic silicone oil defoaming agent, xanthan gum and magnesium aluminum silicate, and grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; adding sodium carbonate into the ground product, adjusting the pH value to 6.83, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Comparative example 1
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 5 parts of sodium bentonite, 500lq2 parts of Ethylan NS-5, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 65 parts of water, 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoaming agent, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Mixing sodium bentonite, Ethylan NS-500lq, Agrilan 752, polyethylene glycol, ethylene glycol, urea ammonium nitrate solution (UAN), potassium pyrophosphate, ammonium polyphosphate, water, sodium carbonate, tributyl phosphate, organic silicon oil defoamer, xanthan gum and magnesium aluminum silicate in a reaction kettle according to a ratio; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding an organic silicone oil defoaming agent, xanthan gum and magnesium aluminum silicate, and grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; adding sodium carbonate into the ground product, adjusting the pH value to 6.68, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Comparative example 2
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 2 parts of ethoxy imidazoline compound, 2 parts of shenqinmycin, 2 parts of pyraclostrobin, 5 parts of sodium bentonite, 500lq2 parts of Ethylan NS-500, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 59 parts of compound amino acid mother liquor, 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoaming agent, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Mixing an ethoxy imidazoline compound, shenqinmycin, pyraclostrobin, sodium bentonite, Ethylan NS-500lq, Agrilan 752, polyethylene glycol, ethylene glycol, a urea ammonium nitrate solution (UAN), potassium pyrophosphate, ammonium polyphosphate and water in a reaction kettle in proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding an organic silicone oil defoaming agent, xanthan gum and magnesium aluminum silicate, and grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; adding sodium carbonate into the ground product, adjusting the pH value to 6.88, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Comparative example 3
A special biological bactericidal pesticide fertilizer for cucumber with root promoting and stress resisting effects comprises the following components in parts by weight: 5 parts of sodium bentonite, 5 parts of ethyllan NS-500lq2 parts, 7522 parts of Agrilan, 5 parts of polyethylene glycol, 3 parts of ethylene glycol, 5 parts of urea ammonium nitrate solution (UAN), 4 parts of potassium pyrophosphate, 4 parts of ammonium polyphosphate, 59 parts of composite amino acid mother liquor, 1 part of sodium carbonate, 1 part of tributyl phosphate, 1 part of organic silicone oil defoaming agent, 1 part of xanthan gum and 1 part of magnesium aluminum silicate.
Mixing sodium bentonite, Ethylan NS-500lq, Agrilan 752, polyethylene glycol, ethylene glycol, urea ammonium nitrate solution (UAN), potassium pyrophosphate, ammonium polyphosphate and compound amino acid mother liquor in a reaction kettle in proportion; firstly, grinding for 5-10 minutes by using an ultramicro emulsion cutting dispersion machine under the conditions of 8000-12000r/min, then adding an organic silicone oil defoaming agent, xanthan gum and magnesium aluminum silicate, and grinding for 30-40 minutes by using a grinding machine under the conditions of 500-1000 r/min; adding sodium carbonate into the ground product, adjusting the pH value to 6.69, and preparing the liquid biological bactericidal pesticide fertilizer special for the cucumbers and having the root promoting and stress resisting effects.
Application example 1
Setting cucumber water culture test. Selecting seedlings with similar growth vigor, taking Hoagland nutrient solution as basic nutrient solution, adding different examples and comparative examples, and measuring root length and root dry weight.
The test was carried out for 15 days, and the nutrient solution was changed on days 1, 4,7,10 and 13, respectively. The culture solution is prepared at 1/3Hoagland nutrient solution concentration on the 1 st day, and no light is applied for 24 hours for seedling recovery, and the nutrient solution is prepared at 1/2Hoagland nutrient solution concentration on the 4 th, 7 th, 10 th and 13 th days, and different examples and comparative examples are added to prepare 0.2g/L treatment solution, light is applied for 14 hours each day, and dark treatment is applied for 10 hours. Each treatment contained 2 replicate pots, 3.3L nutrient solution per pot, 5 cucumber seedlings. And sampling on the 15 th day, and taking the root system to measure the root length and the dry weight of the root. The root length is measured when sampling, and the dry weight of the root is measured after de-enzyming at 105 ℃ for 30min and then drying at 60 ℃ for 3 days. The root length and the rate of increase in dry weight were calculated by the following formula:
the root length increase rate%
Percent dry root weight increase [% ] (dry root weight increase/treated root length of control example 1) [% 100%
The experimental data are shown in table 1 and table 2, and the comparative examples 1 and 2 do not have a significant promotion effect on the growth of the root system because the compound amino acid mother liquor is not added. Comparative example 3 has a certain effect on root length and root dry weight due to the addition of the composite amino acid mother liquor. Examples 1-5 significantly increased root length and dry root weight, particularly in terms of dry root weight.
TABLE 1 Effect on root Length improvement
| Numbering | Treatment of g/L | Root length increase rate% |
| Example 1 | 0.2 | 14％ |
| Example 2 | 0.2 | 13％ |
| Example 3 | 0.2 | 15％ |
| Example 4 | 0.2 | 16％ |
| Example 5 | 0.2 | 13％ |
| Comparative example 1 | 0.2 | — |
| Comparative example 2 | 0.2 | 4％ |
| Comparative example 3 | 0.2 | 12％ |
TABLE 2 Effect on the increase of root Dry weight
Application example 2:
the test was carried out in a large cucumber cultivation base, Shouguang, Shandong province, with 8 treatments, each applied with the fertilizers of examples 1-5 and comparative examples 1-3. The treatments are sprayed and applied according to 50 g/mu/time by diluting 500-fold and 1000-fold. The cucumber is applied after 1 month from transplanting to the field, and is applied once every 7 days for 5 times. The disease infection rate and the yield increase rate are respectively determined 30 days, 45 days, 60 days, 75 days and 90 days after the transplantation and at the cucumber harvesting stage. The infection rate and yield increase rate were calculated by the following formula:
the infection rate is (infected strain number/non-infected strain number) × 100%
Percent yield increase (cucumber yield under treatment conditions/control example 1 yield) × 100%
The experimental data are shown in table 3, and it can be seen from table 3 that comparative example 1 and comparative example 3 have weak resistance to anthracnose, brown spot and the like in the cucumber treated by the additive agent, but comparative example 2 has obviously increased resistance to cucumber but less yield increase due to the additive agent. In examples 1 to 5, cucumber disease resistance was high, and productivity was significantly increased.
TABLE 3 influence of different fertilizers on cucumber infection rate and cucumber yield
The above examples are intended to illustrate the disclosed embodiments of the invention and are not to be construed as limiting the invention. In addition, various modifications of the invention set forth herein, as well as variations of the methods of the invention, will be apparent to persons skilled in the art without departing from the scope and spirit of the invention. While the invention has been specifically described in connection with various specific preferred embodiments thereof, it should be understood that the invention should not be unduly limited to such specific embodiments. Indeed, various modifications of the above-described embodiments which are obvious to those skilled in the art to which the invention pertains are intended to be covered by the scope of the present invention.
Claims (15)
1. The biological medicine fertilizer is characterized by comprising a bactericide, mineral substances, an emulsifying dispersant, an anti-crystallizing agent, a nitrogen-phosphorus-potassium raw material and compound amino acid.
2. The biological pesticide fertilizer as claimed in claim 1, which comprises the following substances in parts by weight:
3. the biological insecticide fertilizer as claimed in claim 1, further comprising any one or more of the following features:
1) the bactericide is selected from one or more of pyraclostrobin, trifloxystrobin, shenqinmycin, acephate, fenitrothion and dimethylformamide;
2) the mineral is selected from one or more of dolomite, ground phosphate rock, turfy soil, bentonite or lignite; preferably, the mineral is bentonite; more preferably, the bentonite is sodium bentonite;
3) the emulsifying dispersant is selected from one or more of WLNO UK, sodium hexametaphosphate, sodium tripolyphosphate, Morwet D-500, Agrilan 752, Ethylan NS-500lq, YUS-EP60P and YUS-FS7 PG;
4) the anti-crystallizing agent is one or more selected from ethylene glycol, glycerol and polyethylene glycol;
5) the compound amino acid comprises cystine, leucine, tyrosine, arginine, histidine, tyrosine, cysteine and/or asparagine; preferably, the mass fraction of the total amino acids in the compound amino acids is 15-25%.
4. The biological insecticide fertilizer as claimed in claim 1, further comprising any one or more of the following features:
1) the nitrogen raw material in the nitrogen, phosphorus and potassium raw materials is selected from one or more of urea and ammonium nitrate solution, urea and ammonium dihydrogen phosphate;
2) the potassium raw material in the nitrogen, phosphorus and potassium raw materials is one or more selected from potassium nitrate, potassium chloride, potassium dihydrogen phosphate and potassium pyrophosphate;
3) the phosphorus raw material in the nitrogen phosphorus potassium raw material is one or more selected from potassium dihydrogen phosphate, ammonium polyphosphate and ammonium dihydrogen phosphate.
5. The biological insecticide-fertilizer according to claim 1, wherein said biological insecticide-fertilizer further comprises any one or more of a pH regulator, an antifoaming agent, and a thickening agent.
6. The biological insecticide fertilizer as claimed in claim 5, further comprising any one or more of the following features:
1) the weight part of the pH regulator is 1-2 parts; preferably, the pH regulator is selected from one or more of formic acid, propionic acid, citric acid, ammonia water, sodium carbonate and sodium hydroxide;
2) the defoaming agent accounts for 1-2 parts by weight; preferably, the defoaming agent is one or more of an organic silicon defoaming agent, octanol, Tween80 and tributyl phosphate;
3) 1-2 parts of a thickening agent; preferably, the thickener is one or more of FL-100, PVA, sodium carboxymethylcellulose, xanthan gum, Arabic gum, white carbon black and magnesium aluminum silicate.
7. The biological pesticide fertilizer as claimed in claim 1, wherein the biological pesticide fertilizer is a biological pesticide fertilizer special for vegetables; preferably, the biological medicine fertilizer is a special biological medicine fertilizer for cucumbers.
8. The method for preparing the biological medicine fertilizer as claimed in any one of claims 1 to 7, which is characterized by comprising the following steps: mixing and grinding the bactericide, the mineral substances, the emulsifying dispersant, the anti-crystallizing agent, the nitrogen, phosphorus and potassium raw materials and the compound amino acid to obtain the biological medicine fertilizer.
9. The method for preparing a biological medicine fertilizer as claimed in claim 8, wherein the grinding step comprises: grinding for 5-10 minutes at 12000r/min 8000-.
10. The method for preparing the biological medicine fertilizer as claimed in claim 9, wherein the method further comprises adding a pH regulator into the ground system to adjust the pH to 6.5-7.0.
11. Use of the biological fertilizer of any one of claims 1-7 in vegetable planting.
12. The use according to claim 11, wherein the biological pesticide fertilizer is used for controlling vegetable pests, promoting root growth and increasing yield.
13. Use according to claim 11, characterized in that the vegetables are fruit vegetables; preferably, the vegetable is cucumber.
14. A method for planting cucumbers, which comprises applying the biological fertilizer as defined in any one of claims 1 to 7 to the cucumbers.
15. Use according to claim 14, further comprising any one or more of the following features:
1) the application amount is 40-60 g of biological insecticide fertilizer per mu per time;
2) diluting 500 times and applying 1000 times;
3) starting to apply the cucumber after the cucumber is transplanted to the field for 25 to 35 days;
4) the fertilizer is applied once every 6 to 8 days for 4 to 6 times;
5) the application method is selected from spraying and root irrigation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210349444.0A CN114835520A (en) | 2022-04-01 | 2022-04-01 | Biological pesticide fertilizer and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210349444.0A CN114835520A (en) | 2022-04-01 | 2022-04-01 | Biological pesticide fertilizer and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114835520A true CN114835520A (en) | 2022-08-02 |
Family
ID=82564819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210349444.0A Pending CN114835520A (en) | 2022-04-01 | 2022-04-01 | Biological pesticide fertilizer and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114835520A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103798248A (en) * | 2014-01-27 | 2014-05-21 | 山东潍坊润丰化工股份有限公司 | Fungicidal composition containing azoxystrobin and tebuconazole and application of fungicidal composition |
| CN103833459A (en) * | 2012-11-23 | 2014-06-04 | 深圳市高杰斯科技有限公司 | Drug fertilizer composition for preventing and treating green turf diseases and application thereof |
| CN105622272A (en) * | 2016-02-15 | 2016-06-01 | 中国农业大学 | Suspension-type bactericide liquid medicine fertilizer and preparation method thereof |
| CN108059547A (en) * | 2018-01-22 | 2018-05-22 | 中国农业大学 | A kind of growth-promoting anti-insect type amino acid Water soluble fertilizer and preparation method thereof |
| CN109206198A (en) * | 2017-07-04 | 2019-01-15 | 山东京九肥料化工有限公司 | A kind of anti-continuous cropping, disease resistance, multi-functional a great number of elements water-soluble fertilizer (microelement type) and preparation method |
-
2022
- 2022-04-01 CN CN202210349444.0A patent/CN114835520A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833459A (en) * | 2012-11-23 | 2014-06-04 | 深圳市高杰斯科技有限公司 | Drug fertilizer composition for preventing and treating green turf diseases and application thereof |
| CN103798248A (en) * | 2014-01-27 | 2014-05-21 | 山东潍坊润丰化工股份有限公司 | Fungicidal composition containing azoxystrobin and tebuconazole and application of fungicidal composition |
| CN105622272A (en) * | 2016-02-15 | 2016-06-01 | 中国农业大学 | Suspension-type bactericide liquid medicine fertilizer and preparation method thereof |
| CN109206198A (en) * | 2017-07-04 | 2019-01-15 | 山东京九肥料化工有限公司 | A kind of anti-continuous cropping, disease resistance, multi-functional a great number of elements water-soluble fertilizer (microelement type) and preparation method |
| CN108059547A (en) * | 2018-01-22 | 2018-05-22 | 中国农业大学 | A kind of growth-promoting anti-insect type amino acid Water soluble fertilizer and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 范永强: "《现代桃树栽培》", 29 February 2020, 山东科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104276882B (en) | Combined fertilizer synergist containing polyglutamic acid, phosphate solubilizing bacteria and potassium solubilizing bacteria, and preparation method and application thereof | |
| CN103396232B (en) | Biological fertilizer | |
| CN105039210B (en) | A kind of composite bacteria agent and its Water soluble fertilizer and application | |
| CN101492323B (en) | Phosphite complex fertilizer for concurrently treating soil-borne disease of tobacco | |
| CN111777446A (en) | Mineral source potassium fulvate water-soluble fertilizer and preparation method thereof | |
| CN105248209A (en) | Pollution-free paddy rice planting method | |
| CN101172903A (en) | Plant source disease-resistant foliage fertilizer and method for producing the same | |
| Bindhu | Effect of Azolla extract on growth performance of Pisum sativum | |
| CN110343001A (en) | A kind of molten fertilizer of Landscape image | |
| CN111233578A (en) | Composition and method for biologically controlling orobanche coerulescens | |
| CN105503391A (en) | Functional foliage fertilizer for preventing and controlling powdery mildew of tomatoes and cucumbers and application | |
| CN111138231A (en) | Humic acid-containing high-concentration liquid water-soluble fertilizer and preparation method thereof | |
| CN103539564B (en) | Seedling raising fertilizer | |
| CN115124376A (en) | Compound biological fertilizer and preparation method thereof | |
| CN103708970B (en) | Special compound biological fertilizer for tobacco | |
| CN107488079A (en) | Amino acid microbial envelope fertilizer and preparation method thereof | |
| CN108863592B (en) | Multiple-effect cotton seedling emergence nutrient composition in saline-alkali land, preparation method and application method | |
| CN114835520A (en) | Biological pesticide fertilizer and preparation method and application thereof | |
| Alam et al. | Effect of organic and inorganic phosphorous on growth of roselle (Hibiscus sabdariffa L.) | |
| CN104987259A (en) | Special fertilizer for banana and preparation method thereof | |
| KR20050072654A (en) | Farm produce production agricultural techniques that contain organic matter germanium | |
| CN112753508B (en) | Prevention and treatment method for panax notoginseng root rot | |
| CN107417366A (en) | A kind of stem of noble dendrobium complex microorganism function liquid fertilizer | |
| CN114149292A (en) | Water-soluble fertilizer, preparation method thereof and application thereof in eucalyptus additional manuring | |
| CN107285828A (en) | Bion tree body transfusion bottle nutrient solution and its production technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220802 |
|
| RJ01 | Rejection of invention patent application after publication |