CN114654830A - 一种远红外石墨烯热辐射恒温复合铝板及其制备方法 - Google Patents
一种远红外石墨烯热辐射恒温复合铝板及其制备方法 Download PDFInfo
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- CN114654830A CN114654830A CN202110357222.9A CN202110357222A CN114654830A CN 114654830 A CN114654830 A CN 114654830A CN 202110357222 A CN202110357222 A CN 202110357222A CN 114654830 A CN114654830 A CN 114654830A
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- aluminum plate
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Abstract
本发明涉及铝板领域，尤其涉及一种远红外石墨烯热辐射恒温复合铝板及其制备方法，所述复合铝板由上至下依次为隔热涂层‑铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。本发明所提供的远红外石墨烯热辐射恒温复合铝板通过隔热涂层‑铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层的结合，尤其是发热线层中石墨烯材料以特定量的添加，赋予了复合铝板良好的发热性能和保温性能。
Description
技术领域
本发明涉及铝板领域，尤其涉及一种远红外石墨烯热辐射恒温复合铝板及其制备方法。
背景技术
石墨烯是一种以sp2杂化连接的碳原子紧密堆积成单层二维蜂窝状晶格结构的新材料，因良好的光学、电学、力学特性，在材料学、能源、生物医学和药物传递等方面具有重要的应用前景，被认为是一种未来革命性的材料。将石墨烯材料应用于传统的铝板制作工艺中，不仅可以提高铝板的力学性能，还能够赋予铝板良好的保温功能，可以广泛地应用于室内装修、移动板房、楼体保温等各个领域。
现有技术中，将石墨烯材料协同其他膜层良好的运用于铝板材料仍属于技术空白，本发明所提供的一种远红外石墨烯热辐射恒温复合铝板及其制备方法弥补了本领域的技术空白。
发明内容
本发明的第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
作为一种优选的实施方式，隔热涂层-铝板复合层的厚度为2-4mm、发热线层的厚度为0.4-0.8mm、反射铝箔层的厚度为0.2-1.0mm、保温发泡层的厚度为1-5cm、铝板层的厚度为1-3mm。
作为一种优选的实施方式，所述隔热涂层的制备原料包括：按重量份计，树脂乳液30-40份，亲水助剂3-4份，钛白粉10-15份。
优选的，所述树脂乳液所述树脂乳液包括丙烯酸树脂乳液、水性环氧树脂乳液、水性酚醛环氧树脂乳液、萜烯树脂乳液、水性有机硅树脂乳液、水性聚氨酯树脂乳液、聚丙烯酸树脂乳液。
优选的，所述亲水助剂包括硅氧烷亲水助剂。
优选的，所述亲水助剂包括聚醚硅氧烷共聚物、二羟基聚二甲基硅氧烷、聚二甲基硅氧烷、八甲基环四硅氧烷、六苯基二硅氧烷、六甲基环三硅氧烷、巯丙基甲基二甲氧基硅烷、羟基封端聚二甲基硅氧烷。
作为一种优选的实施方式，所述发热线层的制备原料包括：按重量份计，高密度聚合物300-400份，石墨烯50-60份，碳材料30-40份。
优选的，所述碳材料包括碳纳米管，碳纳米纤维，纳米碳球。
作为一种优选的实施方式，所述保温发泡层的制备原料包括：聚氨酯30-40份，聚乙烯20-30份，三甲基磷酸酯10-15份，镁粉5-10份，沸水20-40份。
本发明的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法：将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为300-350℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。
与现有技术相比，本发明具有以下有益效果：
1.本发明所提供的远红外石墨烯热辐射恒温复合铝板将石墨烯材料协同其他膜层良好的运用于铝板材料中，弥补了本领域的技术空白。
2.本发明所提供的远红外石墨烯热辐射恒温复合铝板通过五层材料搭配复合，克服了现有技术中单一铝板的力学性能较弱的问题，并创造性的结合了含有石墨烯材料的发热线层，赋予了复合铝板良好的耐冲击性。
3.本发明所提供的远红外石墨烯热辐射恒温复合铝板通过隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层的结合，尤其是发热线层中石墨烯材料以特定量的添加，赋予了复合铝板良好的发热性能和保温性能。
4.本发明所提供的远红外石墨烯热辐射恒温复合铝板含有石墨烯材料，加热后能够发射出远红外射线，有较强的渗透能力，有良好的控温效果。
5.本发明所提供的远红外石墨烯热辐射恒温复合铝板通过添加特定比例的石墨烯，既可以做到在短时间内通过石墨烯导电而快速升温，同时又不会因为石墨烯的添加量过多而导致温度过高，能够避免高温引起保温材料燃烧等意外情况，通过外层保温层和反射铝箔层的共同作用，赋予了复合铝板的长效恒温和长效保温的效果。
6.本发明所提供的远红外石墨烯热辐射恒温复合铝板能够广泛应用于室内装修、移动板房、楼体保温等领域，不仅有良好的力学性能，长时间使用对人体健康很有益处。
具体实施方式
为了解决上述技术问题，本发明的第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
作为一种优选的实施方式，隔热涂层-铝板复合层的厚度为2-4mm、发热线层的厚度为0.4-0.8mm、反射铝箔层的厚度为0.2-1.0mm、保温发泡层的厚度为1-5cm、铝板层的厚度为1-3mm。
作为一种优选的实施方式，所述隔热涂层的制备原料包括：按重量份计，树脂乳液30-40份，亲水助剂3-4份，钛白粉10-15份。
优选的，所述树脂乳液包括丙烯酸树脂乳液、水性环氧树脂乳液、水性酚醛环氧树脂乳液、萜烯树脂乳液、水性有机硅树脂乳液、水性聚氨酯树脂乳液、聚丙烯酸树脂乳液中的至少一种。
优选的，所述树脂乳液为丙烯酸树脂乳液。
优选的，所述亲水助剂包括硅氧烷亲水助剂。
优选的，所述亲水助剂包括聚醚硅氧烷共聚物、二羟基聚二甲基硅氧烷、聚二甲基硅氧烷、八甲基环四硅氧烷、六苯基二硅氧烷、六甲基环三硅氧烷、巯丙基甲基二甲氧基硅烷、羟基封端聚二甲基硅氧烷中的至少一种。
优选的，所述亲水助剂为聚醚硅氧烷共聚物。
隔热涂层的制备方法为：
1.准确称取树脂乳液30-40份，亲水助剂3-4份，钛白粉10-15份混合并搅拌均匀，置于分散机中300-400r/min低速分散30-40min后2500-3000r/min高速分散25-35min，得到分散液。
2.将分散液喷涂在市售铝板上，分散液厚度为0.5-0.9μm，制得隔热涂层-铝板复合层。
申请人发现，如果直接以市售铝板作为复合铝板的第一层会造成内部温度发散较快，不能维持复合铝板的恒温效果，而当以树脂乳液、亲水助剂、钛白粉以特定比例复配时，可以赋予复合铝板良好的保温效果，这可能是因为市售铝板本身是良好的导热体，易于热量的导出，而在表面涂以上述隔热层后会在市售铝板表明形成致密的交联状的膜层，将热量牢牢地锁住不扩散。
作为一种优选的实施方式，所述发热线层的制备原料包括：按重量份计，高密度聚合物300-400份，石墨烯50-60份，碳材料30-40份。
优选的，所述高密度聚合物包括高密度聚乙烯、高密度聚丙烯、高密度聚氯乙烯、高密度聚氟乙烯、高密度聚苯乙烯中的至少一种。
优选的，所述高密度聚合物为高密度聚丙烯。
优选的，所述碳材料包括碳纳米管，碳纳米纤维，纳米碳球中的至少一种。
优选的，所述碳材料选自纳米碳球。
发热线的制备方法为：
1.准确称取高密度聚合物300-400份，石墨烯50-60份，碳材料30-40份，机械搅拌均匀，放入线材挤出机，挤出温度为180-220℃，发热线直径为0.1-2mm。
2.将得到的发热线立即抽真空保存。
申请人发现，现有技术中传统的用于室内装修的铝板不仅难于保温，而且自身不能作为发热体对建筑物进行供热，针对这一问题，申请人意外的通过加入含有石墨烯的发热线层后发现，在通电后，石墨烯不但可以发出热量使得复合铝板升温，还可以发射出远红外线，被人体吸收后，远红外线可使体内水分子产生共振而活化，增强其分子间的结合力，从而活化蛋白质等生物大分子，使生物体细胞处于最高振动能级，将远红外热能传递到人体皮下较深的部分，深层温度上升，产生的温热由内向外散发，使毛细血管扩张，促进血液循环，强化各组织之间的新陈代谢，增加组织的再生能力，提高机体的免疫能力，调节精神的异常兴奋状态，对人体健康有良好的帮助。
现有技术中的发热材料中很容易出现局部过热而出现短路或烧毁的现象，而本申请中制备的发热线通过特定量石墨烯的添加，并同纳米碳球协同作用，提高了发热线的韧性和导电性，且发热线具有自限温功能，在达到设定温度后可自动断电保温，既达到了恒温的效果，又避免了因过热引起意外情况。
作为一种优选的实施方式，所述反射铝箔层为基础铝箔，厚度为0.2-1.0mm。
作为一种优选的实施方式，所述保温发泡层的制备原料包括：按重量份计，聚氨酯30-40份，聚乙烯20-30份，三甲基磷酸酯10-15份，镁粉5-10份，沸水20-40份。
保温发泡层的制备方法为：
1.准确量取聚氨酯30-40份，聚乙烯20-30份置于密闭容器，80-90℃加热60-90min。
2.准确量取三甲基磷酸酯10-15份至密闭容器中，80-90℃继续加热60-90min，制得聚合物。
3.反应结束后冷却至室温，聚合物置于发泡模具中，加入镁粉5-10份，迅速机械搅拌均匀并淋入20-40份沸水，等待发泡成型。
4.发泡成型后从模具中取出，切割成适当尺寸作为保温发泡层使用。
申请人发现，发热线层发出的热量如果直接接触市售铝板则极易散发掉，需要持续的通电，而申请人创造性的发现当发热线层与空隙较大的保温发泡层结合后，热量会很大程度上锁在保温发泡层，提高复合铝板的经济效益，这可能是因为将镁粉投入到保温发泡体系中后，迅速与氧气剧烈反应从而在柔软的聚氨酯、聚乙烯、三甲基磷酸酯中间产生大量的气泡，随着温度冷却后，这些气泡留在了体系内，当后续发热线层加热后能将热量留存在气泡内，赋予复合铝板恒温的效果。
作为一种优选的实施方式，所述铝板层为市售铝板，厚度为1-3mm。
本发明的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法：将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为300-350℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。
所述发热线层为一根发热线以“Z”形排列平铺在隔热涂层-铝板复合层和反射铝箔层中间，平铺的发热线的间距为0.1-3cm。
下面通过实施例对本发明进行具体描述。有必要在此指出的是，以下实施例只用于对本发明作进一步说明，不能理解为对本发明保护范围的限制，该领域的专业技术人员根据上述本发明的内容做出的一些非本质的改进和调整，仍属于本发明的保护范围。
丙烯酸树脂乳液购买自山东摩尔化工有限公司
聚醚硅氧烷共聚物购买自佛山市顺德区三升贸易有限公司
钛白粉购买自济南富浩化工有限公司
高密度聚丙烯购买自深圳市金宸塑化科技有限公司
石墨烯购买自青岛岩海碳材料有限公司
纳米碳球购买自清河县安迪金属材料有限公司
聚氨酯购买自邢台宏迪聚氨酯材料有限公司
聚乙烯购买自东莞博瑞华特种材料科技有限公司
三甲基磷酸酯CAS#:64249-01-0
镁粉购买自营口恒龙耐火材料有限公司
环氧树脂购买自廊坊涂鑫防腐材料有限公司
另外，如果没有其它说明，所用原料都是市售得到的。
实施例
实施例1
实施例1第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
所述隔热涂层-铝板复合层的制备原料包括：按重量份计，丙烯酸树脂乳液30份，聚醚硅氧烷共聚物3份，钛白粉10份，市售铝板。
隔热涂层-铝板复合层的制备方法为：
1.准确称取丙烯酸树脂乳液30份，聚醚硅氧烷共聚物3份，钛白粉10份混合并搅拌均匀，置于分散机中300r/min低速分散30min后2500r/min高速分散25min，得到分散液。
2.将分散液喷涂在市售铝板上，分散液厚度为0.5μm，制得隔热涂层-铝板复合层。市售铝板厚度为1mm，购买自上海瞬升铝业有限公司。
所述发热线层的制备原料包括：按重量份计，高密度聚丙烯300份，石墨烯50份，纳米碳球30份。
发热线的制备方法为：
1.准确称取高密度聚丙烯300份，石墨烯50份，纳米碳球30份，机械搅拌均匀，放入线材挤出机，挤出温度为180℃，发热线直径为0.1mm。
2.将得到的发热线立即抽真空保存。
所述反射铝箔层为基础铝箔，厚度为0.4mm，购买自山东贺航金属材料有限公司。
所述保温发泡层的制备原料包括：按重量份计，聚氨酯30份，聚乙烯20份，三甲基磷酸酯10份，镁粉5份。
保温发泡层的制备方法为：
1.准确量取聚氨酯30份，聚乙烯20份，混合均匀置于密闭容器，80℃加热60min。
2.准确量取三甲基磷酸酯10份至密闭容器中，80℃继续加热60min，制得聚合物。
3.反应结束后冷却至室温，聚合物置于发泡模具中，加入镁粉5份，迅速机械搅拌均匀并淋入20份沸水，等待发泡成型。
4.发泡成型后从模具中取出，切割成适当尺寸作为保温发泡层使用。
所述铝板层厚度为1mm，购买自上海瞬升铝业有限公司。
实施例1的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，包括如下步骤：
将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为300℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。所述发热线层为一根发热线以“Z”形排列平铺在隔热涂层-铝板复合层和反射铝箔层中间，平铺的发热线的间距为1cm。
实施例2
实施例2第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
所述隔热涂层-铝板复合层的制备原料包括：按重量份计，丙烯酸树脂乳液40份，聚醚硅氧烷共聚物4份，钛白粉15份，市售铝板。
隔热涂层-铝板复合层的制备方法为：
1.准确称取丙烯酸树脂乳液40份，聚醚硅氧烷共聚物4份，钛白粉15份混合并搅拌均匀，置于分散机中400r/min低速分散40min后3000r/min高速分散35min，得到分散液。
2.将分散液喷涂在市售铝板上，分散液厚度为0.9μm，制得隔热涂层-铝板复合层。市售铝板厚度为3mm，购买自上海瞬升铝业有限公司。
所述发热线层的制备原料包括：按重量份计，高密度聚丙烯400份，石墨烯60份，纳米碳球40份。
发热线的制备方法为：
1.准确称取高密度聚丙烯400份，石墨烯60份，纳米碳球40份，机械搅拌均匀，放入线材挤出机，挤出温度为220℃，发热线直径为0.6mm。
2.将得到的发热线立即抽真空保存。
所述反射铝箔层为基础铝箔，厚度为0.6mm，购买自山东贺航金属材料有限公司。
所述保温发泡层的制备原料包括：按重量份计，聚氨酯40份，聚乙烯30份，三甲基磷酸酯15份，镁粉10份。
保温发泡层的制备方法为：
1.准确量取聚氨酯40份，聚乙烯30份，混合均匀置于密闭容器，90℃加热90min。
2.准确量取三甲基磷酸酯15份至密闭容器中，90℃继续加热90min，制得聚合物。
3.反应结束后冷却至室温，聚合物置于发泡模具中，加入镁粉10份，迅速机械搅拌均匀并淋入40份沸水，等待发泡成型。
4.发泡成型后从模具中取出，切割成适当尺寸作为保温发泡层使用。
所述铝板层厚度为3mm，购买自上海瞬升铝业有限公司。
实施例2的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，包括如下步骤：
将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为350℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。所述发热线层为一根发热线以“Z”形排列平铺在隔热涂层-铝板复合层和反射铝箔层中间，平铺的发热线的间距为1cm。
实施例3
实施例3第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
所述隔热涂层-铝板复合层的制备原料包括：按重量份计，丙烯酸树脂乳液40份，聚醚硅氧烷共聚物4份，钛白粉15份，市售铝板。
隔热涂层-铝板复合层的制备方法为：
1.准确称取丙烯酸树脂乳液35份，聚醚硅氧烷共聚物3.5份，钛白粉13份混合并搅拌均匀，置于分散机中350r/min低速分散35min后2700r/min高速分散30min，得到分散液。
2.将分散液喷涂在市售铝板上，分散液厚度为0.7μm，制得隔热涂层-铝板复合层。市售铝板厚度为2mm，购买自上海瞬升铝业有限公司。
所述发热线层的制备原料包括：按重量份计，高密度聚丙烯260份，石墨烯55份，纳米碳球35份。
发热线的制备方法为：
1.准确称取高密度聚丙烯260份，石墨烯55份，纳米碳球35份，机械搅拌均匀，放入线材挤出机，挤出温度为200℃，发热线直径为0.3mm。
2.将得到的发热线立即抽真空保存。
所述反射铝箔层为基础铝箔，厚度为0.5mm，购买自山东贺航金属材料有限公司。
所述保温发泡层的制备原料包括：按重量份计，聚氨酯35份，聚乙烯25份，三甲基磷酸酯13份，镁粉8份。
保温发泡层的制备方法为：
1.准确量取聚氨酯35份，聚乙烯25份，混合均匀置于密闭容器，85℃加热70min。
2.准确量取三甲基磷酸酯13份至密闭容器中，85℃继续加热70min，制得聚合物。
3.反应结束后冷却至室温，聚合物置于发泡模具中，加入镁粉8份，迅速机械搅拌均匀并淋入32mL份，等待发泡成型。
4.发泡成型后从模具中取出，切割成适当尺寸作为保温发泡层使用。
所述铝板层厚度为2mm，购买自上海瞬升铝业有限公司。
实施例2的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，包括如下步骤：
将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为330℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。所述发热线层为一根发热线以“Z”形排列平铺在隔热涂层-铝板复合层和反射铝箔层中间，平铺的发热线的间距为1cm。
对比例1
对比例1第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述复合铝板由上至下依次为铝板层、发热线层、反射铝箔层、保温发泡层、铝板层。
对比例1的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
对比例2
对比例2第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述发热线层的制备原料不含碳纳米管。
对比例2的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
对比例3
对比例3第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述发热线层的制备原料用环氧树脂代替高密度聚丙烯。
对比例3的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
对比例4
对比例4第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述发热线层的制备原料无石墨烯。
对比例4的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
对比例5
对比例5第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、保温发泡层、铝板层。
对比例5的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
对比例6
对比例6第一个方面提供了一种远红外石墨烯热辐射恒温复合铝板，具体实施同实施例3，不同之处在于，所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、铝板层。
对比例6的第二个方面提供了一种远红外石墨烯热辐射恒温复合铝板的制备方法，具体实施同实施例3。
性能测试：
耐冲击性测试标准：GB/T1732，将复合铝板隔热涂层-铝板复合层面朝上放在铁砧上，受冲击部分距边缘不少于15mm，每个冲击点的边缘距离不少于15mm，重锤于2m高度自由落下至上，用四倍放大镜观察复合铝板表面有无裂纹、皱纹、脱落现象。
发热性测试标准：保持实验室温度在3.0±1℃之间，将远红外石墨烯热辐射恒温复合铝板的隔热涂层-铝板复合层面朝外侧立于墙面，在距离复合铝板1.2m处取CH1、CH2两个测温点，在距离复合铝板0.6m处取CH3、CH4、CH5三个测温点，在复合铝板正面中心取CH6测温点，在复合铝板背面中心取CH7测温点，在墙外取CH8测温点模拟室外环境，加热铝板，每小时检测铝板表面温度和各个测温点温度。
以上所述，仅是本发明的较佳实施例而已，并非是对发明作其他形式的限制，任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或更改为等同变化的等效实施例，但是凡是未脱离本发明技术方案内容，依据本发明的技术实质对以上实施例所作的任何简单修改，等同变化与改型，仍属于本发明技术方案的保护范围。
Claims (10)
1.一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述复合铝板由上至下依次为隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层。
2.根据权利要求1所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：隔热涂层-铝板复合层的厚度为2-4mm、发热线层的厚度为0.4-0.8mm、反射铝箔层的厚度为0.2-1.0mm、保温发泡层的厚度为1-5cm、铝板层的厚度为1-3mm。
3.根据权利要求1所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述隔热涂层的制备原料包括：按重量份计，树脂乳液30-40份，亲水助剂3-4份，钛白粉10-15份。
4.根据权利要求3所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述树脂乳液包括丙烯酸树脂乳液、水性环氧树脂乳液、水性酚醛环氧树脂乳液、萜烯树脂乳液、水性有机硅树脂乳液、水性聚氨酯树脂乳液、聚丙烯酸树脂乳液。
5.根据权利要求3所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述亲水助剂包括硅氧烷亲水助剂。
6.根据权利要求3所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述亲水助剂包括聚醚硅氧烷共聚物、二羟基聚二甲基硅氧烷、聚二甲基硅氧烷、八甲基环四硅氧烷、六苯基二硅氧烷、六甲基环三硅氧烷、巯丙基甲基二甲氧基硅烷、羟基封端聚二甲基硅氧烷中的至少一种。
7.根据权利要求1所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述发热线层的制备原料包括：按重量份计，高密度聚合物300-400份，石墨烯50-60份，碳材料30-40份。
8.根据权利要求7所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述碳材料包括碳纳米管，碳纳米纤维，纳米碳球。
9.根据权利要求1所述的一种远红外石墨烯热辐射恒温复合铝板，其特征为：所述保温发泡层的制备原料包括：聚氨酯30-40份，聚乙烯20-30份，三甲基磷酸酯10-15份，镁粉5-10份，沸水20-40份。
10.一种根据权利要求1-9任一项所述的远红外石墨烯热辐射恒温复合铝板的制备方法，其特征为：将隔热涂层-铝板复合层、发热线层、反射铝箔层、保温发泡层、铝板层按照由上至下的顺序在温度为300-350℃下热轧贴合，制得远红外石墨烯热辐射恒温复合铝板。
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