CN114617781A - Cooling and moisturizing spray and preparation method thereof - Google Patents
Cooling and moisturizing spray and preparation method thereof Download PDFInfo
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- CN114617781A CN114617781A CN202111024336.8A CN202111024336A CN114617781A CN 114617781 A CN114617781 A CN 114617781A CN 202111024336 A CN202111024336 A CN 202111024336A CN 114617781 A CN114617781 A CN 114617781A
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- Prior art keywords
- cooling
- liquid material
- spray
- moisturizing spray
- isomeric
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- 239000007921 spray Substances 0.000 title claims abstract description 49
- 238000001816 cooling Methods 0.000 title claims abstract description 33
- 230000003020 moisturizing effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000011344 liquid material Substances 0.000 claims description 39
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 24
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical class CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 19
- -1 fatty acid ester Chemical class 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 239000003974 emollient agent Substances 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000003995 emulsifying agent Substances 0.000 claims description 16
- 229920005862 polyol Polymers 0.000 claims description 14
- 150000003077 polyols Chemical class 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 13
- 229910021641 deionized water Inorganic materials 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000003755 preservative agent Substances 0.000 claims description 6
- 230000002335 preservative effect Effects 0.000 claims description 6
- 239000003906 humectant Substances 0.000 claims description 5
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 3
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 2
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical class CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical class CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 claims description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical class CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 3
- 238000000889 atomisation Methods 0.000 abstract description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 30
- 239000001273 butane Substances 0.000 description 15
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 15
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 15
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 15
- 239000001294 propane Substances 0.000 description 15
- 229940083957 1,2-butanediol Drugs 0.000 description 11
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 11
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 11
- 235000019437 butane-1,3-diol Nutrition 0.000 description 11
- 229960005323 phenoxyethanol Drugs 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 238000011049 filling Methods 0.000 description 8
- 238000005507 spraying Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 5
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 5
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000006260 foam Substances 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 241001411320 Eriogonum inflatum Species 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical group CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 230000036555 skin type Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 229940100515 sorbitan Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/24—Thermal properties
- A61K2800/244—Endothermic; Cooling; Cooling sensation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention provides a cooling and moisturizing spray and a preparation method thereof. The spray prepared by the invention is fresh and cool in texture, not greasy, uniform and fine in fog, good in atomization effect, quick in volatilization and obvious in skin cooling feeling when in use.
Description
Technical Field
The invention belongs to the field of A61Q19/00, and particularly relates to cooling and moisturizing spray and a preparation method thereof.
Background
The spray product has a large proportion in cosmetics and skin care products, and liquid is sprayed out in the form of ultrafine liquid drops under the action of high-pressure gas so as to achieve various effects of cooling, moisturizing, cleaning and the like. However, the spray products commonly used in the market for cooling contain a certain amount of ethanol, for example, Chinese patent CN108186398B discloses an aerosol, the raw material of the product contains 1-10% by mass of ethanol, the ethanol easily causes irritation to the skin, and the sensitive skin has the risks of allergy and acne.
Based on the above, the application provides the cooling and moisturizing spray and the preparation method thereof, the raw materials do not contain ethanol, and the cooling and moisturizing spray is suitable for various skins.
Disclosure of Invention
The invention provides a cooling and moisturizing spray, which comprises the following raw materials in percentage by volume (7-12): 3.
in a preferred embodiment, the volume ratio of the booster to the liquid material is 7: 3.
In a preferred embodiment, the boosting agent is selected from at least one of propane, butane, propane and butane, nitrogen and dimethyl ether.
In a preferred embodiment, the boosting agent is propane-butane.
In a preferred embodiment, the liquid material is prepared from 5-20% of liquid polyol, 0.05-0.5% of emulsifier, 0.5-5% of emollient, 0.05-0.8% of preservative, and the balance deionized water.
In a preferred embodiment, the preparation raw materials comprise, by mass, 5-15% of liquid polyol, 0.05-0.2% of emulsifier, 0.5-2% of emollient, 0.05-0.5% of preservative, and the balance deionized water.
In a preferred embodiment, the liquid polyol is selected from at least one of butylene glycol, glycerol, propylene glycol, 1, 2-hexanediol, 1, 6-hexanediol, dipropylene glycol, and ethylhexylglycerin.
In a preferred embodiment, the butanediol is selected from at least one of 1, 2-butanediol, 1, 3-butanediol, 1, 4-butanediol.
In a preferred embodiment, the butanediol is a combination of 1, 2-butanediol and 1, 3-butanediol.
In a preferred embodiment, the mass ratio of 1, 2-butanediol and 1, 3-butanediol is (0.1-0.5): (3-6).
In a preferred embodiment, the emollient is selected from at least one of isoparaffin, alkyl alcohol, fatty acid ester, and glyceride.
In a preferred embodiment, the isoparaffin is selected from at least one of the isomeric hexadecanes, isomeric dodecanes, isomeric tridecanes, isomeric tetradecanes, and isomeric eicosanes.
In a preferred embodiment, the alkyl alcohol is selected from at least one of octyldodecanol, lauryl alcohol, hexyldecanol, and isomeric tridecanols.
In a preferred embodiment, the emollient is the isomeric hexadecanes.
In a preferred embodiment, the emulsifier is selected from at least one of propylene glycol fatty acid ester, alkyl glycoside, glyceryl monostearate, hydrogenated lecithin, polysorbate, and sorbitan fatty acid ester.
In a preferred embodiment, the emulsifier is a sorbitan fatty acid ester.
In a preferred embodiment, the sorbitan fatty acid ester has a hydroxyl value of 190-220 mgKOH/g.
In a preferred embodiment, the mass ratio of the liquid polyol to the emulsifier to the emollient is (2.5-5): (0.05-0.2): 1.
in a preferred embodiment, the mass ratio of the liquid polyol to the emulsifier to the emollient is (4-5): (0.05-0.1): 1.
in a preferred embodiment, the mass ratio of the liquid polyol to the emulsifier to the emollient is 5:0.1: 1.
In the present application, the applicant found that the preparation of a spray by using a specific liquid polyol, emulsifier and emollient in a mass ratio of 5:0.1:1 can improve the stability of the spray and the uniformity of the spray particles. The applicant finds that when other emulsifiers such as Tween series products are selected, the emulsifying capacity is not matched with the system, so that the foaming phenomenon of the spray during use is caused, and the use feeling is influenced. In addition, the applicant also found that changing the mass ratio of the liquid polyol, the emulsifier and the emollient, and increasing the content of the emulsifier and the emollient, results in a decrease in the spray angle of the spray, resulting in a decrease in the uniformity of the particles.
In addition, the applicant also found in the experimental process that the mist sprayed on the skin surface brings about the feeling of foam breaking and increases the feeling of temperature reduction in the mist volatilization and temperature reduction process, and supposedly, the applicant probably causes that tiny liquid drops in the form of oil-in-water are formed in the system, and when the mist is sprayed on the skin surface, the liquid drops break due to the difference of the internal and external volatilization capacities of the liquid drops, so that the feeling of temperature reduction is increased.
In a preferred embodiment, the liquid material further comprises 0-5% by mass of a humectant.
In a preferred embodiment, the humectant accounts for 1.5% of the total mass of the liquid material.
In a preferred embodiment, the humectant is selected from at least one of trehalose, mannose, glycerol, betaine.
In a preferred embodiment, the humectant is mannose.
In a preferred embodiment, the preservative is selected from at least one of methyl paraben, propyl paraben, phenoxyethanol, menthol, sorbic acid and its sodium salt.
In a preferred embodiment, the preservative is phenoxyethanol.
The second aspect of the invention provides a preparation method of cooling and moisturizing spray, which comprises the following steps:
(1) uniformly mixing the preparation raw materials to obtain a liquid material;
(2) and filling the liquid material into a container, and filling a boosting agent to obtain the spray product.
In a preferred embodiment, the preparation method comprises the following steps:
(1) adding butanediol, isomeric hexadecane and sorbitan fatty acid ester into a stirring container, stirring uniformly to a transparent state, adding phenoxyethanol and deionized water, and homogenizing at a rotation speed of 2000r/min for 3-5min to obtain a liquid material;
(2) and filling the liquid material into a container, sealing and filling propane and butane to obtain the spray product.
Compared with the prior art, the invention has the following beneficial effects:
1. the spray prepared by the invention is mild and non-irritating after the raw materials contact the skin, does not contain ethanol, and is suitable for various skin types.
2. According to the spray prepared by the invention, the liquid polyol, the emollient and the emulsifier which are in a specific proportion and a specific type are added, the micro oil-in-water droplets are formed in the system through homogenization, and as the booster is sprayed on the surface of the skin, substances in the droplets are volatilized quickly, the water layer on the outer layer of the booster is broken, so that the feeling of foam breakage is generated on the surface of the skin, and the use feeling and the cooling feeling are enhanced; the added emollient forms a moisturizing film layer on the surface of the skin after the spray volatilization, so that the water volatilization on the surface of the skin is reduced, and the skin drying condition after the spray volatilization is avoided.
3. The spray prepared by the invention is fresh and cool in texture, not greasy, uniform and fine in fog and good in atomization effect, avoids the condition that obvious and large-area foams are generated on the surface of the skin when the spray is sprayed out, is sprayed on the surface of the skin, is quick in volatilization, has obvious skin cooling feeling when being used, and is particularly suitable for being used in high-temperature days.
Detailed Description
Example 1
The invention provides a cooling and moisturizing spray, which comprises raw materials of propane and butane and a liquid material, wherein the volume ratio of the propane and the butane to the liquid material is 7: 3.
The preparation raw materials of the liquid material comprise, by mass, 10% of butanediol, 2% of isomeric hexadecane, 0.2% of sorbitan fatty acid ester, 0.5% of phenoxyethanol and the balance of deionized water.
Wherein the butanediol is a compound substance of 1, 2-butanediol and 1, 3-butanediol, and the mass ratio of the 1, 2-butanediol to the 1, 3-butanediol is 1: 9.
The sorbitan fatty acid ester has a hydroxyl value of 190-220mgKOH/g, and is available from West Virginia trade company, Inc. of Guangzhou under the model number Lonzest SMO-20.
The second aspect of the invention provides a preparation method of cooling and moisturizing spray, which comprises the following steps:
(1) adding butanediol, isomeric hexadecane and sorbitan fatty acid ester into a stirring container, stirring uniformly to a transparent state, adding phenoxyethanol and deionized water, and homogenizing at a rotation speed of 2000r/min for 5min to obtain a liquid material;
(2) and transferring the liquid material into a container, sealing and filling propane and butane to obtain the spray product.
Example 2
The invention provides a cooling and moisturizing spray, which comprises raw materials of propane and butane and a liquid material, wherein the volume ratio of the propane and the butane to the liquid material is 7: 3.
The preparation raw materials of the liquid material comprise, by mass, 10% of butanediol, 2% of isomeric hexadecane, 0.2% of sorbitan fatty acid ester, 1.5% of trehalose, 0.5% of phenoxyethanol and the balance of deionized water.
Wherein the butanediol is a compound substance of 1, 2-butanediol and 1, 3-butanediol, and the mass ratio of the 1, 2-butanediol to the 1, 3-butanediol is 1: 9.
The sorbitan fatty acid ester has a hydroxyl value of 190-220mgKOH/g, and is purchased from Nantong Kendao chemical Co., Ltd, and the model is S-80.
The second aspect of the invention provides a preparation method of cooling and moisturizing spray, which comprises the following steps:
(1) adding butanediol, isomeric hexadecane, sorbitan fatty acid ester and trehalose into a stirring container, stirring uniformly to a transparent state, adding phenoxyethanol and deionized water, and homogenizing at a rotation speed of 2000r/min for 5min to obtain a liquid material;
(2) and transferring the liquid material into a container, sealing and filling propane and butane to obtain the spray product.
Example 3
The invention provides a cooling and moisturizing spray, which comprises raw materials of propane and butane and a liquid material, wherein the volume ratio of the propane and the butane to the liquid material is 7: 3.
The liquid material is prepared from the raw materials of, by mass, 10% of butanediol, 2% of isomeric hexadecane, tween-800.2%, 1.5% of trehalose, 0.5% of phenoxyethanol and the balance of deionized water.
Wherein the butanediol is a compound substance of 1, 2-butanediol and 1, 3-butanediol, and the mass ratio of the 1, 2-butanediol to the 1, 3-butanediol is 1: 9.
Tween 80 was purchased from south tomaya chemical limited.
The second aspect of the invention provides a preparation method of cooling and moisturizing spray, which comprises the following steps:
(1) adding butanediol, isomeric hexadecane and sorbitan fatty acid ester into a stirring container, stirring uniformly to a transparent state, adding phenoxyethanol and deionized water, and homogenizing at a rotation speed of 2000r/min for 5min to obtain a liquid material;
(2) and transferring the liquid material into a container, sealing and filling propane and butane to obtain the spray product.
Example 4
The invention provides a cooling and moisturizing spray, which comprises raw materials of propane and butane and a liquid material, wherein the volume ratio of the propane and the butane to the liquid material is 7: 3.
The preparation raw materials of the liquid material comprise, by mass, 10% of butanediol, 4% of isomeric hexadecane, 0.4% of sorbitan fatty acid ester, 1.5% of trehalose, 0.5% of phenoxyethanol and the balance of deionized water.
Wherein the butanediol is a compound substance of 1, 2-butanediol and 1, 3-butanediol, and the mass ratio of the 1, 2-butanediol to the 1, 3-butanediol is 1: 9.
The sorbitan fatty acid ester has a hydroxyl value of 190-220mgKOH/g, and is purchased from Nantong Kendao chemical Co., Ltd, and the model is S-80.
The second aspect of the invention provides a preparation method of cooling and moisturizing spray, which comprises the following steps:
(1) adding butanediol, isomeric hexadecane and sorbitan fatty acid ester into a stirring container, stirring uniformly to a transparent state, adding phenoxyethanol and deionized water, and homogenizing at a rotation speed of 2000r/min for 5min to obtain a liquid material;
(2) and transferring the liquid material into a container, sealing, and filling propane and butane to obtain the spray product.
Performance test
And (4) carrying out stability test on the prepared liquid material. And testing the cooling capacity and volatilization time of the prepared spray product.
1. Stability test
And the stability test is carried out on the prepared liquid material by referring to the national standard GB/T14449-. (1) Respectively standing the liquid material at 48 deg.C, 40 deg.C, 8 deg.C, 18 deg.C, and room temperature for 30 days, and observing stability; (2) placing the liquid material in a circulating incubator (the circulating temperature is 40 ℃ to-8 ℃, and the circulating period is 48 hours) for 30 days, and observing the stability; (3) and (3) respectively placing the liquid material in a simulated lamp box and under natural illumination for 30 days, and observing the stability.
2. Cooling capacity
Under the same test condition, vertically placing a thermometer which is constant in temperature of 35 ℃ into a glass container which is constant in temperature of 35 ℃ and is provided with a bottle stopper, enabling a glass bulb of the thermometer to be in contact with the inner bottom of the glass container, quickly spraying 10 times of spraying products to the inner bottom of the glass container, covering the bottle stopper, and recording the temperature drop of the thermometer after waiting for 1 min.
3. Time of volatilization
Under the same test conditions, spraying a certain amount of spraying product at the bottom in an open glass container with the constant temperature of 35 ℃, observing the volatilization condition of the spraying product, and recording the time for completely volatilizing the spraying product.
TABLE 1
Claims (10)
1. The cooling and moisturizing spray is characterized in that the raw materials comprise a boosting agent and a liquid material, wherein the volume ratio of the boosting agent to the liquid material is (7-12): 3.
2. the cooling and moisturizing spray according to claim 1, wherein the liquid material is prepared from, by mass, 5-20% of liquid polyol, 0.05-0.5% of emulsifier, 0.5-5% of emollient, 0.05-0.8% of preservative, and the balance deionized water.
3. The cooling and moisturizing spray as claimed in claim 2, wherein the preparation raw materials comprise, by mass, 5-15% of liquid polyol, 0.05-0.2% of emulsifier, 0.5-2% of emollient, 0.05-0.5% of preservative, and the balance deionized water.
4. The cooling and moisturizing spray of claim 2, wherein the liquid polyol is at least one selected from the group consisting of butylene glycol, glycerol, propylene glycol, 1, 2-hexanediol, 1, 6-hexanediol, dipropylene glycol, and ethylhexylglycerin.
5. The cooling and moisturizing spray of claim 2, wherein the emollient is selected from at least one of isoparaffin, alkyl alcohol, fatty acid ester, and glyceride.
6. The cooling and moisturizing spray of claim 5, wherein the isoparaffin is selected from at least one of the isomeric hexadecanes, isomeric dodecanes, isomeric tridecanes, isomeric tetradecanes, and isomeric eicosanes.
7. The cooling and moisturizing spray according to any one of claims 2-3, wherein the mass ratio of the liquid polyol to the emulsifier to the emollient is (2.5-5): (0.05-0.2): 1.
8. the cooling and moisturizing spray according to claim 7, wherein the mass ratio of the liquid polyol to the emulsifier to the emollient is (4-5): (0.05-0.1): 1.
9. the cooling and moisturizing spray according to any one of claims 2 to 3, wherein the liquid material further comprises 0 to 5% by mass of a humectant.
10. A method for preparing a cooling and moisturizing spray according to any one of claims 2 to 9, comprising the steps of:
(1) uniformly mixing the preparation raw materials to obtain a liquid material;
(2) the liquid material is filled into a container, and the boosting agent is filled into the container to obtain the spray.
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