CN114605200A - Medicinal fertilizer composition and preparation thereof - Google Patents

Medicinal fertilizer composition and preparation thereof Download PDF

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Publication number
CN114605200A
CN114605200A CN202111436854.0A CN202111436854A CN114605200A CN 114605200 A CN114605200 A CN 114605200A CN 202111436854 A CN202111436854 A CN 202111436854A CN 114605200 A CN114605200 A CN 114605200A
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parts
fertilizer composition
pesticide
fertilizer
preparation
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CN202111436854.0A
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李建民
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York Agrochemicals Co ltd
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York Agrochemicals Co ltd
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Priority to CN202111436854.0A priority Critical patent/CN114605200A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/40Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting fertiliser dosage or release rate; for affecting solubility
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/50Surfactants; Emulsifiers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12Granules or flakes

Abstract

The invention provides a pesticide-fertilizer composition and a preparation thereof, wherein the pesticide-fertilizer composition comprises 0.2-0.9 part of azoxystrobin, 0.03-0.15 part of fludioxonil, 54.07-69.65 parts of microalgal powder, 20-30 parts of humic acid and 10-15 parts of sodium dodecyl sulfate; the microalgae powder is granule of 50-120 meshes. The preparation is columnar granule. In the pesticide-fertilizer composition, two sterilization compounds, namely fludioxonil and azoxystrobin, are used in a matching manner, so that the sterilization effect of the pesticide-fertilizer composition can be effectively improved; the degerming compound and the fertilizer are prepared into columnar particles, so that the release speed of the degerming compound and the fertilizer is delayed, the pesticide and fertilizer composition preparation can achieve long-acting bacteriostasis and nutrient substance supply, the application times are reduced, and the labor intensity is reduced on the premise of ensuring the bacteriostasis, sterilization effects and fertilizer efficiency.

Description

Medicinal fertilizer composition and preparation thereof
Technical Field
The invention relates to the technical field of pesticides, and particularly relates to a pesticide-fertilizer composition and a preparation thereof.
Background
The pathogenic bacteria are microorganisms existing all the time in the growth process of crops, and the pathogenic bacteria can be enriched in soil in continuous cropping planting or rotation planting, so that the pathogenic bacteria are more obvious in continuous cropping planting. Although the enrichment of pathogenic bacteria of the same species is slightly less, the species of pathogenic bacteria are more. The pathogens present on crops are in large part derived from the soil and therefore treatment of soil pathogens is of considerable interest in preventing pathogens from harming crops.
Fludioxonil is a common compound for preventing and treating crop pathogens, and inhibits the transfer of glucose phosphorylation and the growth of mycelium by influencing the activity of histidine kinase related to an osmotic pressure regulation signal, thereby causing the death of pathogens.
Azoxystrobin is a broad-spectrum pesticide and is common in compound pesticides. Researches show that azoxystrobin can inhibit mitochondrial respiration to cause death of cell nucleus and further generate bacteriostatic action, so that azoxystrobin has the advantage of wide action range.
The two using modes of the existing degerming pesticide are generally two, namely foliage spraying and tree smearing, and are characterized in that the degerming pesticide is prepared into liquid for use, and is attached to the surfaces of leaves or trees to further act on pathogenic bacteria; both modes can not effectively act on pathogenic bacteria of crop roots, so that the effect is poor in the aspect of preventing crop diseases.
Fertilizers have irreplaceable effects during the growth of crops, and can affect not only the yield of crops, but also the structure of soil. The humic acid is an organic substance which is obtained by fermenting remains of animals and plants and widely exists in the nature, can provide a large amount of organic matters for the growth of crops, and is beneficial to the absorption and utilization of the crops. In addition, humic acid can improve soil structure and can act for a long time as compared with chemical raw materials, and thus, in recent years, humic acid has been increasingly used.
The degerming pesticide is generally used as a quick-acting bactericide when being used, so the degerming pesticide has the characteristic of short action time in the current use mode, is usually required to be used for multiple times, is difficult to act on pathogenic bacteria in soil for a long time if the current degerming pesticide is applied to the soil, and obviously has the defects of time and labor waste when being applied to the soil by multiple times of slotting, so the pesticide charge composition which is synchronously applied with fertilization and can inhibit bacteria for a long time has important significance.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides the pesticide-fertilizer composition and the preparation thereof, and the two sterilization compounds of fludioxonil and azoxystrobin are matched for use in the pesticide-fertilizer composition, so that the sterilization effect of the pesticide-fertilizer composition can be effectively improved; the degerming compound and the fertilizer are prepared into columnar particles, so that the release speed of the degerming compound and the fertilizer is delayed, the pesticide and fertilizer composition preparation can achieve long-acting bacteriostasis and nutrient substance supply, the application times are reduced, and the labor intensity is reduced on the premise of ensuring the bacteriostasis, sterilization effects and fertilizer efficiency.
The technical scheme of the invention is as follows:
the pesticide-fertilizer composition comprises the following components in parts by weight:
0.2-0.9 part of azoxystrobin, 0.03-0.15 part of fludioxonil, 54.07-69.65 parts of microalgal powder, 20-30 parts of humic acid and 10-15 parts of sodium dodecyl sulfate;
wherein the microalgae powder is granule of 50-120 meshes.
Further, the seed insecticide-fertilizer composition comprises the following components in parts by weight:
0.5 part of azoxystrobin, 0.1 part of fludioxonil, 62.4 parts of microalgal powder, 25 parts of humic acid and 12 parts of sodium dodecyl sulfate;
the microalgae powder is granule of 70-80 meshes.
Furthermore, 3-5 parts of seaweed extract is added into the pesticide-fertilizer composition in order to improve the fertilizer efficiency of the pesticide-fertilizer composition.
Further, the pesticide-fertilizer composition comprises the following components in parts by weight:
0.5 part of azoxystrobin, 0.1 part of fludioxonil, 58.4 parts of microalgal powder, 25 parts of humic acid, 12 parts of sodium dodecyl sulfate and 4 parts of seaweed essence;
the microalgae powder is granule of 90-100 meshes.
Further, the preparation prepared by using the pharmaceutical composition is specifically columnar granules.
Further, the preparation method of the preparation comprises the following steps:
(1) placing microalgae powder with humidity of 7-8% in a mixer, adding fludioxonil and azoxystrobin, mixing for 15-20min to obtain mixture A;
(2) adding sodium dodecyl sulfate into the mixture A, and continuously mixing for 5-10min to obtain a mixture B; adding ethanol into the mixture B, continuously mixing for 5min, adding the rest components, and mixing for 10-15min to obtain mixture C;
(3) and putting the mixture C into a granulator to prepare columnar granules, namely the pesticide-fertilizer composition preparation.
Further, in the step (2), the mass ratio of the ethanol to the mixture B is 1-3: 100.
Further, in the step (2), the mass ratio of the ethanol to the mixture B is 2: 100.
In the invention, the microalgae powder is used as a framework material, fludioxonil and azoxystrobin are distributed in gaps of the microalgae powder firstly, the fludioxonil and the azoxystrobin are combined more uniformly by mixing, and the fertilizer is mainly positioned on the surface of the microalgae powder by using the sodium dodecyl sulfate and the ethanol, so that the fertilizer is beneficial to direct absorption when crops grow; because the fertilizer and the pharmaceutical compound are released simultaneously after the fertilizer and the pharmaceutical compound are actually applied to the soil, the bacteriostatic action is continuously generated in the growth process of crops. In addition, the particle size of the microalgae powder is limited, so that the release speed of the fertilizer and the pharmaceutical compound can be controlled, and meanwhile, after the microalgae powder is released and neutralized, the preparation can continuously maintain a certain shape in the presence of the microalgae powder, so that the air permeability and the water retention of soil are improved, and the growth of crop roots can be promoted.
Compared with the prior art, the invention has the beneficial effects that:
1. in the pesticide-fertilizer composition provided by the invention, when two sterilization compounds of fludioxonil and azoxystrobin are used in a matching way, the fludioxonil and the azoxystrobin have mutual assistance by acting on the cell activity of pathogenic bacteria, so that the sterilization effect of the pesticide-fertilizer composition is improved, and meanwhile, after the fludioxonil and the azoxystrobin are applied to soil together with a fertilizer, the compounds are continuously released, so that the aim of long-acting sterilization is fulfilled.
2. According to the pesticide-fertilizer composition preparation provided by the invention, the sterilization compound and the fertilizer are prepared into columnar particles, so that the release speed of the sterilization compound and the fertilizer is delayed, the pesticide-fertilizer composition preparation can realize long-acting bacteriostasis and nutrient substance supply, the application frequency is reduced, and the labor intensity is reduced on the premise of ensuring the bacteriostasis, sterilization effect and fertilizer effect.
Detailed Description
In order to make those skilled in the art better understand the technical solutions in the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The pesticide fertilizer composition comprises the following components in parts by weight per 100 kg:
0.5kg of azoxystrobin, 0.1kg of fludioxonil, 62.4kg of microalgal powder, 25kg of humic acid and 12kg of sodium dodecyl sulfate;
the microalgae powder is granule of 70-80 meshes.
The preparation method of the preparation comprises the following steps:
(1) placing microalgae powder with humidity of 8% in a mixer, adding fludioxonil and azoxystrobin, mixing for 15min to obtain mixture A for later use;
(2) adding sodium dodecyl sulfate into the mixture A, and continuously mixing for 7min to obtain a mixture B; adding ethanol into the mixture B, continuously mixing for 5min, adding humic acid, and mixing for 15min to obtain a mixture C;
(3) and putting the mixture C into a granulator to prepare columnar granules, namely the pesticide-fertilizer composition preparation.
Example 2
The pesticide fertilizer composition comprises the following components in parts by weight per 100 kg:
0.2kg of azoxystrobin, 0.15kg of fludioxonil, 69.65kg of microalgal powder, 20kg of humic acid and 10kg of sodium dodecyl sulfate;
wherein the microalgae powder is granule of 50-80 meshes.
Example 3
The pesticide fertilizer composition comprises the following components in parts by weight per 100 kg:
0.9kg of azoxystrobin, 0.03kg of fludioxonil, 54.07kg of microalgal powder, 30kg of humic acid and 15kg of sodium dodecyl sulfate;
wherein the microalgae powder is granule of 90-110 meshes.
Example 4
The pesticide fertilizer composition comprises the following components in parts by weight per 100 kg:
0.5kg of azoxystrobin, 0.1kg of fludioxonil, 58.4kg of microalgal powder, 25kg of humic acid, 12kg of sodium dodecyl sulfate and 4kg of seaweed essence;
the microalgae powder is granule of 90-100 meshes.
Comparative example 1
The difference from example 1 is that fludioxonil was not added.
Comparative example 2
The difference from example 1 is that azoxystrobin was not added.
Comparative example 3
The difference from example 1 is that the microalgal flour is undersize that has passed through a 120 mesh sieve.
Comparative example 4
The difference from example 1 is that the microalgal flour is undersize that has passed through a 50 mesh sieve.
Comparative example 5
The difference from example 1 is that sodium lauryl sulfate was not added.
Comparative example 6
The difference from example 1 is that the preparation method of the preparation comprises the following steps:
(1) placing microalgae powder with humidity of 8% in a mixer, adding humic acid, and mixing for 15min to obtain mixture A;
(2) adding sodium dodecyl sulfate into the mixture A, and continuously mixing for 7min to obtain a mixture B; adding ethanol into the mixture B, continuously mixing for 5min, adding fludioxonil and azoxystrobin, and mixing for 15min to obtain a mixture C;
(3) and (4) putting the mixture C into a granulator to prepare columnar granules, namely the pesticide-fertilizer composition preparation.
Experiment 1:
the formulations of the fertilizer compositions of examples 1 to 4 and comparative examples 1 to 6 were subjected to the release time test, which was as follows:
200ml of water is placed in a beaker, a sample is put into the beaker at the temperature of 25 ℃, fludioxonil and azoxystrobin in the water in the beaker are detected every other day, the release condition of the pesticide-fertilizer composition preparation is judged, when the cumulative release amount of fludioxonil and azoxystrobin reaches more than 93%, the total release time is recorded, the state of the pesticide-fertilizer composition preparation is observed, and the result is shown in table 1.
TABLE 1 Release time statistics
Figure BDA0003380469580000061
Figure BDA0003380469580000071
Experiment 2:
the pesticide-fertilizer composition preparations of examples 1 to 4 and comparative examples 1 to 6 are respectively applied to the melon plants during planting and applied to soil during seedling transplanting;
the pathogenic bacteria of the root rot disease of the melon are respectively put into the soil, and the following experimental settings are carried out:
experimental group 1 the formulation of the insecticide-fertilizer composition of example 1 was applied; experimental group 2 the formulation of the insecticide-fertilizer composition of example 2 was applied; experimental group 3 the formulation of the insecticide-fertilizer composition of example 3 was applied; experimental group 4 the formulation of the insecticide-fertilizer composition of example 4 was applied; comparative group 1 was applied with the formulation of the insecticide-fertilizer composition of comparative example 1; comparative group 2 was applied with the formulation of the insecticide-fertilizer composition of comparative example 2; comparative group 3 was applied with the formulation of the insecticide-fertilizer composition of comparative example 3; comparative group 4 was applied with the formulation of the insecticide-fertilizer composition of comparative example 4; comparative group 5 was applied with the formulation of the insecticide-fertilizer composition of comparative example 5; comparative group 6 was applied with the formulation of the insecticide-fertilizer composition of comparative example 6; meanwhile, the pesticide-fertilizer composition preparations of examples 1 to 4 and comparative examples 1 to 6 are not used as a control group; 20 pots are arranged in each group, and after 30 days of planting, the disease state of the melons and the root system state of the melons are recorded, and the results are shown in table 2.
TABLE 2 onset of melon disease
Figure BDA0003380469580000072
Figure BDA0003380469580000081
The combination of the table 1 and the table 2 shows that the preparation provided by the invention can realize long-acting bacteriostasis and fertility enhancement, and the root system of the crop can fully grow in the process of using the preparation, so that the foundation is laid for the yield increase of the crop.
Although the present invention has been described in detail by referring to the preferred embodiments, the present invention is not limited thereto. Various equivalent modifications or substitutions can be made on the embodiments of the present invention by those skilled in the art without departing from the spirit and scope of the present invention, and these modifications or substitutions are within the scope of the present invention/any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.

Claims (8)

1. The pesticide fertilizer composition is characterized by comprising the following components in parts by weight:
0.2-0.9 part of azoxystrobin, 0.03-0.15 part of fludioxonil, 54.07-69.65 parts of microalgal powder, 20-30 parts of humic acid and 10-15 parts of sodium dodecyl sulfate;
wherein the microalgae powder is granule of 50-120 meshes.
2. The pesticide fertilizer composition as claimed in claim 1, which comprises the following components in parts by weight:
0.5 part of azoxystrobin, 0.1 part of fludioxonil, 62.4 parts of microalgal powder, 25 parts of humic acid and 12 parts of sodium dodecyl sulfate;
the microalgae powder is granule of 70-80 meshes.
3. The insecticide-fertilizer composition according to claim 1, wherein 3 to 5 parts of seaweed extract are added to the insecticide-fertilizer composition.
4. The pesticide fertilizer composition as claimed in claim 3, which comprises the following components in parts by weight:
0.5 part of azoxystrobin, 0.1 part of fludioxonil, 58.4 parts of microalgal powder, 25 parts of humic acid, 12 parts of sodium dodecyl sulfate and 4 parts of seaweed essence;
the microalgae powder is granule of 90-100 meshes.
5. A formulation prepared using the insecticide-fertilizer composition of any one of claims 1 to 4, wherein the formulation is in the form of a columnar granule.
6. The formulation of the insecticide-fertilizer composition of claim 5, wherein the preparation method comprises:
(1) placing microalgae powder with humidity of 7-8% in a mixer, adding fludioxonil and azoxystrobin, mixing for 1520min to obtain mixture A;
(2) adding sodium dodecyl sulfate into the mixture A, and continuously mixing for 5-10min to obtain a mixture B; adding ethanol into the mixture B, continuously mixing for 5min, adding the rest components, and mixing for 1015min to obtain a mixture C;
(3) and putting the mixture C into a granulator to prepare columnar granules, namely the pesticide-fertilizer composition preparation.
7. The pesticide-fertilizer composition preparation as claimed in claim 6, wherein in the step (2), the mass ratio of the ethanol to the mixed material B is 1-3: 100.
8. The formulation of the insecticide-fertilizer composition as claimed in claim 7, wherein in step (2), the mass ratio of ethanol to the mixed material B is 2: 100.
CN202111436854.0A 2021-11-29 2021-11-29 Medicinal fertilizer composition and preparation thereof Pending CN114605200A (en)

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CN115886018A (en) * 2022-08-10 2023-04-04 济南约克农化有限公司 Thifluzamide azoxystrobin granules and preparation method thereof

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