CN108633885A - A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin - Google Patents
A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin Download PDFInfo
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- CN108633885A CN108633885A CN201810362944.1A CN201810362944A CN108633885A CN 108633885 A CN108633885 A CN 108633885A CN 201810362944 A CN201810362944 A CN 201810362944A CN 108633885 A CN108633885 A CN 108633885A
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- fertilizer
- fludioxonil
- fluoxastrobin
- fertilizer granules
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of fertilizer granules containing fludioxonil and Fluoxastrobin and its application, which is made of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.The group of each ingredient becomes fludioxonil 0.01 15%, Fluoxastrobin 0.01 15%, fertilizer 10 50% and pesticidal preparations auxiliary element surplus.The fertilizer granules have the purposes of prevention soil-borne disease, especially have good control effect to watermelon/droop, potato/tar spot, lawn/brown spot.
Description
Technical field
The invention belongs to agrochemical fertilizer technical field, it is related to fertilizer granules containing fludioxonil and Fluoxastrobin and in soil-borne disease
Application in evil has both the double effects of sterilization and Fertilizer nutrient.
Background technology
Medicine fertilizer be pesticide and fertilizer are mixed, and by process fertilizer and pesticide are stable in specific compound system by
The mixture of formation is a new technology using in agricultural in recent years, refers to desinsection, weeding, bactericidal effect and effect life
Two or more functions in long adjusting, and nutrition can be provided for crops or had simultaneously and nutrition and raising fertilizer and agriculture are provided
The multi-Functional Fertilizers of medicine utilization rate.Medicine fertilizer has agreed with the new demand of modern agriculture to a certain extent.Medicine and fertilizer are combined into one, will
Labour is integrated into primary labour twice for fertilising and laxative, is conducive to improve labor efficiency, and it is raw to reduce agricultural by liberating rural labour
Produce the constantly surging pressure of cost.Therefore, it develops and novel has both pesticide and the medicine fertilizer of fertilizer is of great significance.
Fludioxonil：English common name：Fludioxonil, chemical name：4- (2,2- bis- fluoro- 1,3- benzos dioxy -4-
Base) pyrroles's -3- nitriles, molecular formula：C12H6F2N2O2。
Structural formula：
Fludioxonil is a kind of novel non-internal-absorting phenylpyrrole series bactericidal agent developed by Syngenta Co., Ltd, has antibacterial and sterilization
Effect mainly by inhibiting transfer related with glucose phosphorylated, and then inhibits the growth of fungal mycelium, eventually leads to disease
Bacterium is dead, does not have cross resistance with existing fungicide.
Fludioxonil has many good characteristics：First, low toxicity is a kind of wide-spectrum bactericide, to basidiomycetes, sac fungus efficiently
There is good preventive effect with many pathogens such as Fungi Imperfecti；Second, safety is good, to crop safety, without poisoning；Third, holding effect
Phase is long, and up to 4 months or more, stable and lasting guard circle is formed in crop root；4th, tolerance is good, under suitable condition
Seed can be stored 3 years and not influence germination percentage.
Fluoxastrobin：English common name：Azoxystrobin, chemical name：(E)-[[6- (2- cyano-benzene oxygens) is phonetic by 2-
Pyridine -4- bases oxygen] phenyl] -3- methoxy-methyl acrylates, molecular formula：C22H17N3O5。
Structural formula：
Fluoxastrobin is mitochondrial respiratory inhibitor, i.e., by cytochrome b and c1Between electronics transfer inhibit line grain
The breathing of body.Extranuclear mitochondria mainly for cell provides energy (ATP) by breathing, if mitochondrial respiratory by
Resistance, cannot generate ATP, and cell will be dead.It is suitable for cereal crop, peanut, grape, potato, vegetables, coffee, fruit tree
（Citrus, apple, banana, peach, pears etc.）, lawn etc..To nearly all Mycophytes（Ascomycetes, load mattress guiding principle, Oomycete and half
Perfect fungus）Caused disease（Such as tens of kinds of diseases of powdery mildew, rust, glume blight, net blotch, scab, downy mildew, rice blast
Evil）There is good activity.Fluoxastrobin be new and effective fungicide, have protect, treat, rooting out, permeating, systemic activity and extensively
The bactericidal activity of spectrum.It can be used for cauline leaf spraying, seed treatment, can also carry out soil treatment.
Inventor has found bactericidal composition fludioxonil and phonetic bacterium by the verification of a large amount of indoor biometrics and field control effectiveness test
Ester is combined application with fertilizer, can not only play the double effects of sterilization and fertilizer, and than being used alone after the two compounding
Chemical fertilizer is compared with pesticide, no matter is all increased significantly in terms of bactericidal effect, crop yield, and use cost, section medicine can be reduced
Section fertilizer saves labor cost and to crop safety height.The research of fludioxonil and Fluoxastrobin bactericidal composition and fertilizer compounding,
So far, there is not yet relevant report.
Invention content
The purpose of the present invention is to propose to it is a kind of with synergistic function, sterilization and fertilizer can be played double effects,
Use cost, section medicine section fertilizer are reduced, saves labor cost and to a kind of high of crop safety containing fludioxonil and Fluoxastrobin
Fertilizer granules and its application.
The technical scheme is that：
A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin, it is characterised in that：It is described to contain fludioxonil and Fluoxastrobin
Fertilizer granules be made of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.
The fertilizer granules, it is characterised in that：The pesticide activity component is fludioxonil and Fluoxastrobin.
The fertilizer granules, it is characterised in that：The fertilizer is macroelement fertilizer, secondary nutrients, micro-
Secondary element fertilizer, organic fertilizer, amino acid fertilizer or combinations thereof.
The fertilizer granules, it is characterised in that：Auxiliary element in the Pesticide formulation is binder, carries
Body or combinations thereof.
The fertilizer granules, it is characterised in that：The group of each ingredient becomes fludioxonil 0.01-15%, Fluoxastrobin
0.01-15%, fertilizer 10-50% and pesticidal preparations auxiliary element surplus.
The fertilizer granules have the purposes of prevention soil-borne disease, especially to watermelon/droop, potato/black mole
Disease, lawn/brown spot have good control effect.
Purposes of the fertilizer granules for volume increase.
The present invention has the advantage that：
The first, the present invention provides a kind of fertilizer granules containing fludioxonil and Fluoxastrobin and its applications, by fludioxonil, phonetic bacterium
Ester, fertilizer and auxiliary agent are prepared.
The second, the present invention is initiative compounds fludioxonil, Fluoxastrobin and fertilizer, forms fertilizer granules, is that will apply fertilizer
It is combined with sterilization, while having haved the function that sterilization, volume increase.
Third, fertilizer granules provided by the present invention are easy to use, are also applied fertilizer, are reduced while dispenser
Labor intensity achievees the purpose that time and labour saving.
4th, after fertilizer granules provided by the present invention application, the growth of crop is promoted, improves the immune of crop
Power enhances the ability for resisting pest and disease damage, improves control effect indirectly.
5th, the slow releasing function of fertilizer granules provided by the present invention extends the lasting period, reduces entire breeding time
Pesticide dosage can reach and reduce environmental pollution, and reduce use cost.
6th, there is directionality, drift is small, and environmental pollution is small when fertilizer granules dispenser provided by the present invention；
It is not attached on the cauline leaf of plant, avoids direct contact with and generate poisoning etc..
Specific implementation mode
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Implementation of an application example one：Pesticide activity component fludioxonil, Fluoxastrobin and fertilizer compound product example of formulations（Contain below
Amount is folding percentage composition）, but the present invention is not limited to the proportional region in following embodiment.
It is sufficiently mixed after pesticide activity component fludioxonil, Fluoxastrobin and binder are crushed, so that pesticide is fully adsorbed on viscous
It ties in agent, is crushed by pulverizer；When fertilizer is crushed to certain fineness, fludioxonil, Fluoxastrobin and carrier after crushing is added,
It is granulated after being sufficiently mixed, you can fludioxonil Fluoxastrobin fertilizer granules are made.
1 0.05% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 0.01%, macroelement fertilizer 35%, binder 6%, supplies surplus at Fluoxastrobin 0.04%.
2 0.4% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 0.2%, macroelement fertilizer 30%, binder 5%, supplies surplus at Fluoxastrobin 0.2%.
3 0.9% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 0.6%, a great number of elements 40%, trace element 15%, binder 6%, supplies surplus at Fluoxastrobin 0.3%.
4 1.5% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 0.5%, a great number of elements 40%, moderate-element 15%, binder 7%, supplies surplus at Fluoxastrobin 1.0%.
5 6% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 1.5%, trace element 7%, amino acid 1 0%, binder 5%, supplies surplus at Fluoxastrobin 4.5%.
6 12% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 2%, amino acid 35%, binder 7%, supplies surplus at Fluoxastrobin 10%.
7 16% fludioxonil Fluoxastrobin fertilizer granules of embodiment
Fludioxonil 4%, humic acid 40%, binder 9%, supplies surplus at Fluoxastrobin 12%.
Implementation of an application example two：
The field control effectiveness test of pesticide activity component fludioxonil, Fluoxastrobin and fertilizer compounding
Field information embodiment 1 prevents the field control effectiveness test of watermelon blight
Test site：This test arrangement chooses the heavier plot of disease in Shanxi Province Linyi County.
Subjects：Watermelon blight
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, each cell minimum 40
m2, 4 repetitions are often handled, using the processing of equivalent clear water as blank control.Method of administration is to spread fertilizer over the fields.
Investigation and statistical method：
Throughout reason area takes at 3 points at random, i.e., 3 regions before, during and after field.After emergence, every takes 120 plants, totally 360 plants, investigation
Emergence situation；Post flowering, every takes 10 plants, totally 30 plants, investigates plant height；When harvest, every takes 30 plants, totally 90 plants, investigation diseased plant,
Output condition；Calculate emergence rate, disease index, control effect, effective output.
Emergence rate（%）=（Number of emerging/sowing number）×100；
Diseased plant rate（%）=（Diseased plant number/investigation total strain number）×100；
Control effect（%）=[（Blank district diseased plant rate-treatment region diseased plant rate）/ blank district diseased plant rate] × 100;
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100.
As can be known from Table 1, fludioxonil of embodiment of the present invention Fluoxastrobin fertilizer granules preventive effect on prevention watermelon blight
Significantly, preventive effect is above 96%, and preventive effect is up to 96.32% ~ 98.33%；It is notable to increasing yield of water melons, rate of growth up to 21.02% ~ 28.16%,
And the rate of growth of fertilizer is 5.93% ~ 8.12%.Field test results fully show fludioxonil Fluoxastrobin fertilizer granules to west
The double effects that cucurbit wilt has synergistic function, can play sterilization and fertilizer, it is right within the scope of this experiment dosage
Watermelon safety, has no adverse effects.
Field information embodiment 2 prevents the field control effectiveness test of black scurf of potato
Test site：This test arrangement chooses the heavier plot of disease in Shanxi Province Linyi County.
Subjects：Black scurf of potato
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, each cell minimum
40m2, 4 repetitions are often handled, using the processing of equivalent clear water as blank control.Method of administration is to spread fertilizer over the fields.
Investigation and statistical method：
Throughout reason area takes at 3 points at random, i.e., 3 regions before, during and after field.After emergence, every takes 120 plants, totally 360 plants, investigation
Emergence situation；Post flowering, every takes 10 plants, totally 30 plants, investigates plant height；When harvest, every takes 30 plants, totally 90 plants, the sick potato of investigation,
Output condition；Calculate emergence rate, disease index, control effect, effective output.
Black scurf of potato stem tuber grade scale：
0 grade：Disease-free spot in potato wedge；
1 grade：Sick portion's area accounts for 5% or less entire potato wedge area；
2 grades：Sick portion's area accounts for the 6% -10% of entire potato wedge area；
3 grades：Sick portion's area accounts for the 11%-25% of entire potato wedge area；
4 grades：Sick portion's area accounts for the 26%-50% of entire potato wedge area；
5 grades：Sick portion's area accounts for the 51%-75% of entire potato wedge area；
6 grades：Sick portion's area accounts for the 76%-100% of entire potato wedge area.
Emergence rate（%）=（Number of emerging/sowing number）×100；
Disease index（%）=[（Disease potato numbers at different levels × opposite value of series）/（Investigate total potato number × 6）] ×100；
Control effect（%）=（Disease index/blank district disease index after 1- treatment region medicines）×100；
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100.
As can be known from Table 2, fludioxonil of embodiment of the present invention Fluoxastrobin fertilizer granules are prevented in prevention black scurf of potato
Effect is notable, and preventive effect is above 96%, and preventive effect is up to 96.92% ~ 98.94%；To potato increase yield significantly, rate of growth up to 31.25% ~
36.92%, and the rate of growth of fertilizer is 7.19% ~ 9.02%.Field test results fully show fludioxonil Fluoxastrobin medicine fertilizer particle
The double effects that agent has synergistic function to black scurf of potato, can play sterilization and fertilizer, in this experiment dosage
In range, to potato safety, have no adverse effects.
Field information embodiment 3 prevents the field control effectiveness test of Brown patch disease
Test site：This test arrangement chooses the heavier plot of disease in Shanxi Province Linyi County.
Subjects：Brown patch disease
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, each cell minimum
40m2, 4 repetitions are often handled, using the processing of equivalent clear water as blank control.Method of administration is to spread fertilizer over the fields.
Investigation and statistical method：
It investigates within ten days after spreading fertilizer over the fields, takes per cell diagonal line at 5 points, 150 plants of lawns are investigated in every 30 plants of continuous sampling altogether, and record is total
Strain number, diseased plant number and sick series.
Brown patch disease grade scale（As unit of strain）：
0 grade：Complete stool is disease-free；
1 grade：The following leaf sheath of 4 leaves, blade morbidity（With blade center for the 1st blade）；
3 grades：The following leaf sheath of 3 leaves or blade morbidity；
5 grades：The following leaf sheath of 2 leaves or blade morbidity；
7 grades：The following leaf sheath of lobus cardiacus or blade morbidity；
9 grades：Complete stool morbidity is simultaneously withered.
Disease index（%）=\* MERGEFORMAT （Diseased plant numbers at different levels × opposite value of series）/（Investigation total strain number ×
9）×100；
Control effect（%）=（Blank district disease index-chemicals treatment district disease index）/ blank district disease index ×
100。
As can be known from Table 3, fludioxonil of embodiment of the present invention Fluoxastrobin fertilizer granules preventive effect on prevention Brown patch disease
Significantly, preventive effect is above 95%, and preventive effect is up to 95.41% ~ 97.76%.Field test results fully show fludioxonil Fluoxastrobin medicine fertilizer
Granule, which has Brown patch disease, assists good control effect, within the scope of this experiment dosage, to lawn safety, without bad
It influences.
In conclusion fludioxonil Fluoxastrobin fertilizer granules of the present invention, to soil-borne disease watermelon/droop, horse
The double effects that bell potato/tar spot has synergistic function, can play sterilization and fertilizer, there is preferably Brown patch disease
Control effect.
Claims (7)
1. a kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin, it is characterised in that：It is described to contain fludioxonil and phonetic bacterium
The fertilizer granules of ester are made of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.
2. fertilizer granules according to claim 1, it is characterised in that：The pesticide activity component is fludioxonil and phonetic
Bacterium ester.
3. according to the fertilizer granules described in claim 1 to 2, it is characterised in that：The fertilizer be macroelement fertilizer, in
Secondary element fertilizer, trace-element fertilizer, organic fertilizer, amino acid fertilizer or combinations thereof.
4. the fertilizer granules according to claims 1 to 3, it is characterised in that：Auxiliary in the Pesticide formulation
Ingredient is binder, carrier or combinations thereof.
5. the fertilizer granules according to Claims 1-4, it is characterised in that：The group of each ingredient becomes fludioxonil 0.01-
15%, Fluoxastrobin 0.01-15%, fertilizer 10-50% and pesticidal preparations auxiliary element surplus.
6. have the purposes of prevention soil-borne disease according to the fertilizer granules described in claim 1 to 5, especially to watermelon/withered
Disease, potato/tar spot, lawn/brown spot have good control effect.
7. the purposes according to the fertilizer granules described in claim 1 to 6 for volume increase.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810362944.1A CN108633885A (en) | 2018-04-21 | 2018-04-21 | A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810362944.1A CN108633885A (en) | 2018-04-21 | 2018-04-21 | A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109678605A (en) * | 2019-02-15 | 2019-04-26 | 赵德洲 | A kind of Chinese anise medicine fertilizer integrated transfusion agent |
| CN114605200A (en) * | 2021-11-29 | 2022-06-10 | 济南约克农化有限公司 | Medicinal fertilizer composition and preparation thereof |
| CN114831123A (en) * | 2022-06-08 | 2022-08-02 | 安徽丰乐农化有限责任公司 | Pesticide fertilizer composition and application thereof |
| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
| WO2023023815A1 (en) * | 2021-08-25 | 2023-03-02 | Adama Australia Pty Limited | Highly loaded fludioxonil formulations |
| WO2023099486A1 (en) * | 2021-12-01 | 2023-06-08 | Syngenta Crop Protection Ag | Post-harvest fungicidal uses |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109678605A (en) * | 2019-02-15 | 2019-04-26 | 赵德洲 | A kind of Chinese anise medicine fertilizer integrated transfusion agent |
| CN115104612A (en) * | 2021-08-24 | 2022-09-27 | 汝阳自强生物科技有限公司 | Granular formulation for treating melon wilt and preparation method and application thereof |
| CN115104612B (en) * | 2021-08-24 | 2023-10-27 | 汝阳自强生物科技有限公司 | Granule for treating melon wilt and preparation method and application thereof |
| WO2023023815A1 (en) * | 2021-08-25 | 2023-03-02 | Adama Australia Pty Limited | Highly loaded fludioxonil formulations |
| CN114605200A (en) * | 2021-11-29 | 2022-06-10 | 济南约克农化有限公司 | Medicinal fertilizer composition and preparation thereof |
| WO2023099486A1 (en) * | 2021-12-01 | 2023-06-08 | Syngenta Crop Protection Ag | Post-harvest fungicidal uses |
| CN114831123A (en) * | 2022-06-08 | 2022-08-02 | 安徽丰乐农化有限责任公司 | Pesticide fertilizer composition and application thereof |
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