CN102669101A - Azoxystrobin-containing bactericide fertilizer granules - Google Patents
Azoxystrobin-containing bactericide fertilizer granules Download PDFInfo
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- CN102669101A CN102669101A CN2012101525239A CN201210152523A CN102669101A CN 102669101 A CN102669101 A CN 102669101A CN 2012101525239 A CN2012101525239 A CN 2012101525239A CN 201210152523 A CN201210152523 A CN 201210152523A CN 102669101 A CN102669101 A CN 102669101A
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Abstract
The invention relates to azoxystrobin-containing bactericide fertilizer granules. The bactericidal active ingredient is azoxystrobin; and based on the total weight of the bactericide fertilizer granules, the bactericide fertilizer granules comprise the following components: 0.01-10% of azoxystrobin, 30-60% of carrier fertilizer, 0.5-3% of dispersing aid, 0.1-2% of sustained-release agent, 0.1-5% of binder and the balance of packing. The bactericide fertilizer granules provided by the invention are mainly used for preventing and curing the diseases of the watermelon, cucumber, hot pepper and cotton at the seedling stage, wherein the diseases include fusarium wilt and damping off. The bactericide fertilizer granules provided by the invention are of great significance to effectively, scientifically and reasonably utilize the resources and protect the environment, and realize positive promotion effects on reducing the agricultural input and increasing both production and income of the agriculture.
Description
Technical field
The present invention relates to a kind of fertilizer granular formulation, specifically a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin.
Background technology
Fusarium (
Fusarium) claim Fusarium again, saprophytic, weak parasitism or parasitism, symptom such as cause wilting, rot.Cause root rot like straight beak sickle spore, the multiple different specialized forms of fusarium oxysporum cause the fusarium wilt of different plants.Fusarium oxysporum is typical soil inhabitant; Can survive in soil or in the invalid body 5～6 years by chlamydospore; The fusarium oxysporum bacterium mainly through propagation such as farming operation, rainwater, soil insect, nematodes, also can carry out long-distance communications through infected seed and nursery stock in the field.This type disease is popular for many years easily, carries out soil disinfection through chemical mode, and the generation that the bacterium amount accumulation in the control soil could effectively prevent and reduce this disease is popular.
Silk nuclear genus (
Rhizoctonia) claim Rhizoctonia again, modal is the Rhizoctonia solani Kuhn that causes various plants damping off and banded sclerotial blight, and some kind also can cause the plant damping off, and harm is serious.
Pythium (
Pythium), Phytophthora (
Phytophthora) fungi, belonging to Oomycete pythiaceae Peronosporales fungi, some kind causes that easily melon and fruit rots and the damping off of various plants.
Fusarium wilt, damping off, damping off are the main sprout term diseases of crop such as watermelon, cucumber, capsicum, cotton.At present, the agricultural chemicals Zhu that is used to prevent and treat these diseases in the production is Yaoed You hymexazo, carbendazim, thiophanate-methyl, tpn, tmtd, sulphur, Kocide SD, pcnb etc.
Fluoxastrobin is a kind of in the methoxy acrylic bactericide, and above-mentioned fusarium wilt, damping off, damping off are had good control efficiency, and present commercial formulation mainly contains suspending agent, water dispersible granules etc., and method for using is mainly the cauline leaf spraying and handles.
In the traditional agricultural production technology, applying fertilizer and above-mentioned bactericide separate, and twice or repeatedly use the way of above-mentioned bactericide and fertilizer, have increased peasant's labour intensity and work number of times, unfavorable agricultural development.The fertilizer granules applied once can be accomplished fertilising and sterilization two procedures simultaneously, avoided dispenser in the past and the situation that fertilising can not take into account, save time and manual work, improve production efficiency.
Fluoxastrobin is combined to process the bactericide fertilizer granular formulation still do not have report with fertilizer.
Summary of the invention
Technical problem to be solved: the present invention is directed to the prior art deficiency; A kind of bactericide fertilizer granular formulation that provides a kind of Fluoxastrobin to combine and developed with the science of fertilizer; Applied once both can apply fertilizer in agricultural production; Can effectively prevent and treat fusarium wilt, damping off, damping off again, overcome the way of wanting twice or repeatedly use bactericide and fertilizer under the prior art condition.
Technical scheme: a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin, fungicide active ingredient is a Fluoxastrobin; In the fertilizer granules gross weight, wherein: Fluoxastrobin 0.01%～10%, carrier fertilizer 30%～60%, dispersing aid 0.5%～3%, sustained release agent 0.1%～2%, binding agent 0.1%～5%, all the other are filler.
Described carrier fertilizer is one or more the mixing in ammonium chloride, ammonium sulfate, urea, potassium chloride, potassium sulphate, MAP, monohydrate zinc sulphate, the borax; Its N element nutrient content is 5%～25% of a bactericide fertilizer granular formulation gross weight; The P constituent content is 1%～10% of a bactericide fertilizer granular formulation gross weight; The K constituent content is 1%～10% of a bactericide fertilizer granular formulation gross weight; Zinc element content is 0.5%～2% of bactericide fertilizer granular formulation gross weight, and boron content is 0.5%～2% of a bactericide fertilizer granular formulation gross weight.
Described sustained release agent is polyvinyl alcohol or gum Arabic.Binding agent is polyethylene glycol or industrial gelatine.Dispersing aid is corn starch or sweet potato starch.Filler is calcium bicarbonate and white kaolinic mixture.
Bactericide fertilizer granular formulation of the present invention is used to prevent and treat fusarium wilt, damping off, the damping off of crops such as watermelon, cucumber, capsicum, cotton.
The present invention combines a kind of fertilizer granules of developing through the microbiocidal composition Fluoxastrobin with the science of fertilizer; Adopt current up-to-date slow release method to guarantee that effectively the science of agricultural chemicals, fertilizer discharges; Prolong the lasting period of product, guarantee sterilization, fertilising double effects, improve drug effect and agricultural chemicals availability; Reduce the waste of agricultural chemicals, fertilizer; Effectively, science, make rational use of resources, the protection environment is had great significance, the agricultural input that reduces the user and the increasing both production and income of agricultural are also played positive impetus.
Specifically, granule of the present invention has the following advantages:
1, fertilizer granules of the present invention directly spreads fertilizer over the fields as base manure; Can effectively prevent the generation of the fungus-caused sprout term disease of pathogen (fusarium wilt, damping off, damping off); Avoid that dispenser can't reach desirable control efficiency after morbidity, cause the dead seedling of crops, the underproduction; Satisfied the requirement of base manure again, got twice the result with half the effort.
2, the present invention adopts the modern mechanical processing technology, and active ingredient is evenly distributed in product, and the preparation method operates easily.Product in use need not be mixed soil, directly spreads fertilizer over the fields, and medicament can be distributed in the field uniformly, more helps absorbing of active ingredient, has overcome the inconsistent phenomenon of drug effect, fertilizer efficiency that artificial pesticide-clay mixture method is prone in the field.
3, behind the applied once, play the double action of sterilization and fertilising, save the dispenser cost.
After the Fluoxastrobin fertilizer granules is used, can effectively prevent and treat the pathogen fungi and cause sprout term disease, play the effect of basal dressing simultaneously again, save auxiliary agent and packing cost that bactericide and fertilizer are used in independent gradation, save labor cost.At present, coastal area labours such as Guangdong, Zhejiang are in short supply, and this product can effectively be saved labor cost for the plantation family.
4, fertilizer granules belongs to the environmental protection formulation, and the release of granule can reduce the usage amount of wetting powder, and regular dosage forms such as use cost and wetting powder are suitable.
5, the common granule that does not contain fertilizer of the present invention can satisfy the fertilising of needs or the needs soil disinfection be not that the field piece of fertilising spreads fertilizer over the fields or spreads manuer in holes, save labor cost.
Compare common formulations such as wetting powder, no dust pollution in this process of producing product.Simultaneously, this product all can use at each growth period of crops, use this product after, generally no longer need use other common fungicides to prevent and treat soil-borne diseases such as damping off, damping off, fusarium wilt.The cost aspect, because the fertilizer granules product, has been saved the auxiliary agent cost of a cover packing material and wetting powder with respect to twice use of bactericide and fertilizer, so the use cost of fertilizer granules and wetting powder basically identical, can not increase use cost.
In order better to verify practical application effect of the present invention, the field control effectiveness test effect of bactericide fertilizer granular formulation of the present invention is described with the field efficacy instance below.
Supply the reagent agent: (1) test medicine: 0.4% Fluoxastrobin fertilizer granules.
(2) contrast medicament: 25% Fluoxastrobin suspending agent.
(3) controlling object: the sprout term disease of watermelon, cucumber, capsicum, cotton (fusarium wilt, damping off, damping off).
(4) application method: 0.4% Fluoxastrobin fertilizer granules directly spreads fertilizer over the fields as base manure, preparation dosage 2500 gram/mus; Contrast medicament 25% Fluoxastrobin suspending agent mixes soil before kind of transplantation of seedlings, mix fertilizer spreads fertilizer over the fields, and 40 gram/mus are transplanted seedling after the dispenser.
Can find out from result of the test table 1; Fluoxastrobin fertilizer granules of the present invention is to the good control efficiency of the sprout term disease (fusarium wilt, damping off, damping off) of watermelon, cucumber, capsicum, cotton; To watermelon safety; Drug effect is superior to contrasting medicament 25% Fluoxastrobin missible oil under the identical effective dose situation, and effect of increasing production is obvious.
Table 1, prevent and treat fusarium wilt, damping off, damping off field control effectiveness test statistical form.
Fertilizer granules preparation method's of the present invention production technology is ripe, can produce according to product standard up-to-standard, the fertilizer granules of effect stability.Be checking constant product quality property, we have carried out the heat storage stability test of product: under 54 ℃ ± 2 ℃ conditions, stored 14 days the resolution ratio of mensuration active ingredient, moisture, pH value etc.The result of the test table shows that constant product quality property is good, and each item index meets standard-required (result of the test is seen table 2).
Table 2,0.4% Fluoxastrobin fertilizer granules heat storage stability result of the test.
Description of drawings
Fig. 1 is the production technology figure of bactericide fertilizer granular formulation of the present invention.
Embodiment
Embodiment 1:Bactericide fertilizer granular formulation of the present invention is made up of following raw material: Fluoxastrobin, carrier fertilizer, dispersing aid, sustained release agent, binding agent, filler.In bactericide fertilizer granular formulation gross weight, wherein: Fluoxastrobin 0.01%, carrier fertilizer 30%, dispersing aid 0.5%, sustained release agent 0.1%, binding agent 0.1%, all the other are filler.
As shown in Figure 1; In airtight compounding kettle, mix Fluoxastrobin, dispersing aid, sustained release agent, binding agent, carrier fertilizer and surplus filler, the granulation of coating method is dried to the particle water content less than 3% under 110 ℃～120 ℃ conditions; Screening; Particle size range 2000 μ m～4000 μ m through after the assay was approved, promptly obtain required bactericide fertilizer granular formulation; The powder sieving thing is back to agitator tank after crushed to be mixed again; Defective work is back to agitator tank after the check analysis reason mixes again; Mix to adopt the method for fractional steps, raw material elder generation's mixed and dispersed auxiliary agent that constituent content is lower or filler again with other mixing of materials, to guarantee the uniformity of product content; Baking temperature is at 110 ℃～120 ℃, and variation of temperature and fluctuation are controlled in strictness.
Described sustained release agent is a polyvinyl alcohol.Binding agent is a polyethylene glycol.Dispersing aid is a corn starch.Filler is calcium bicarbonate and white kaolinic mixture.
Described carrier fertilizer is ammonium sulfate; Its N element nutrient content is 5%～25% of a bactericide fertilizer granular formulation gross weight; The P constituent content is 1% of a bactericide fertilizer granular formulation gross weight; The K constituent content is 1% of a bactericide fertilizer granular formulation gross weight, and zinc element content is 0.5% of bactericide fertilizer granular formulation gross weight, and boron content is 0.5% of a bactericide fertilizer granular formulation gross weight.
Embodiment 2:Bactericide fertilizer granular formulation of the present invention is made up of following raw material: Fluoxastrobin, carrier fertilizer, dispersing aid, sustained release agent, binding agent, filler.In bactericide fertilizer granular formulation gross weight, wherein: Fluoxastrobin 10%, carrier fertilizer 60%, dispersing aid 3%, sustained release agent 2%, binding agent 5%, all the other are filler.
Described sustained release agent is a gum Arabic.Binding agent is an industrial gelatine.Dispersing aid is a sweet potato starch.Filler is calcium bicarbonate and white kaolinic mixture.The preparation method is identical with embodiment 1.
Described carrier fertilizer is urea; Its N element nutrient content is 25% of a bactericide fertilizer granular formulation gross weight; The P constituent content is 10% of a bactericide fertilizer granular formulation gross weight; The K constituent content is 10% of a bactericide fertilizer granular formulation gross weight, and zinc element content is 2% of bactericide fertilizer granular formulation gross weight, and boron content is 2% of a bactericide fertilizer granular formulation gross weight.
Embodiment 3:Bactericide fertilizer granular formulation of the present invention is made up of following raw material: Fluoxastrobin, carrier fertilizer, dispersing aid, sustained release agent, binding agent, filler.In bactericide fertilizer granular formulation gross weight, wherein: Fluoxastrobin 5%, carrier fertilizer 35%, dispersing aid 2%, sustained release agent 1%, binding agent 3%, all the other are filler.
Described sustained release agent is a polyvinyl alcohol.Binding agent is an industrial gelatine.Dispersing aid is a sweet potato starch.Filler is calcium bicarbonate and white kaolinic mixture.The preparation method is identical with embodiment 1.
Described carrier fertilizer is that ammonium chloride, urea mix; Its N element nutrient content is 15% of a bactericide fertilizer granular formulation gross weight; The P constituent content is 5% of a bactericide fertilizer granular formulation gross weight; The K constituent content is 4% of a bactericide fertilizer granular formulation gross weight, and zinc element content is 1% of bactericide fertilizer granular formulation gross weight, and boron content is 1.5% of a bactericide fertilizer granular formulation gross weight.
Claims (8)
1. bactericide fertilizer granular formulation that contains Fluoxastrobin, it is characterized in that: fungicide active ingredient is a Fluoxastrobin; In the fertilizer granules gross weight, wherein: Fluoxastrobin 0.01%～10%, carrier fertilizer 30%～60%, dispersing aid 0.5%～3%, sustained release agent 0.1%～2%, binding agent 0.1%～5%, all the other are filler.
2. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 1; It is characterized in that: described carrier fertilizer is one or more the mixing in ammonium chloride, ammonium sulfate, urea, potassium chloride, potassium sulphate, MAP, monohydrate zinc sulphate, the borax; Its N element nutrient content is 5%～25% of a bactericide fertilizer granular formulation gross weight; The P constituent content is 1%～10% of a bactericide fertilizer granular formulation gross weight; The K constituent content is 1%～10% of a bactericide fertilizer granular formulation gross weight, and zinc element content is 0.5%～2% of bactericide fertilizer granular formulation gross weight, and boron content is 0.5%～2% of a bactericide fertilizer granular formulation gross weight.
3. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 1, it is characterized in that: described sustained release agent is polyvinyl alcohol or gum Arabic.
4. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 1, it is characterized in that: described binding agent is polyethylene glycol or industrial gelatine.
5. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 1, it is characterized in that: described dispersing aid is corn starch or sweet potato starch.
6. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 1 is characterized in that: described filler is calcium bicarbonate and white kaolinic mixture.
7. according to each described a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin of claim 1～6, it is characterized in that: be used to prevent and treat the crops seedling stage disease: fusarium wilt, damping off, damping off.
8. a kind of bactericide fertilizer granular formulation that contains Fluoxastrobin according to claim 7, it is characterized in that: described crop is watermelon, cucumber, capsicum, cotton.
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| CN201210152523.9A CN102669101B (en) | 2012-05-17 | 2012-05-17 | A kind of Bactericide fertilizer granule containing Fluoxastrobin |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039447A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Enestroburin bactericidal granules and preparation method thereof |
| CN103058766A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Weeding fertilizer granules of penoxsulam and preparation method thereof |
| CN103058767A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Flubendiamide drug fertilizer granules and preparation method thereof |
| CN106554218A (en) * | 2015-09-24 | 2017-04-05 | 周保东 | Bactericide fertilizer emulsifiable granula and preparation method thereof |
| CN107318853A (en) * | 2017-06-30 | 2017-11-07 | 陕西标正作物科学有限公司 | Fertilizer granules and application containing metconazole |
| CN107637590A (en) * | 2017-09-20 | 2018-01-30 | 陕西嘉益蓝德生物工程有限公司 | A kind of SYP-3375 granule and its application |
| CN107963924A (en) * | 2017-11-23 | 2018-04-27 | 陕西嘉益蓝德生物工程有限公司 | A kind of Bactericide fertilizer granule containing metconazole |
| CN108633885A (en) * | 2018-04-21 | 2018-10-12 | 王章修 | A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin |
| CN112825861A (en) * | 2021-02-04 | 2021-05-25 | 四川眉山凯尔化工有限公司 | Compound pesticide herbicide |
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| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
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Patent Citations (3)
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| US20030130119A1 (en) * | 2001-06-14 | 2003-07-10 | Clifford Watrin | Composition and method for improving plant growth |
| CN102276356A (en) * | 2011-07-11 | 2011-12-14 | 广西田园生化股份有限公司 | Stable controlled release particle pesticide-containing fertilizer |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039447A (en) * | 2012-12-27 | 2013-04-17 | 广东中迅农科股份有限公司 | Enestroburin bactericidal granules and preparation method thereof |
| CN103058766A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Weeding fertilizer granules of penoxsulam and preparation method thereof |
| CN103058767A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Flubendiamide drug fertilizer granules and preparation method thereof |
| CN106554218A (en) * | 2015-09-24 | 2017-04-05 | 周保东 | Bactericide fertilizer emulsifiable granula and preparation method thereof |
| CN107318853A (en) * | 2017-06-30 | 2017-11-07 | 陕西标正作物科学有限公司 | Fertilizer granules and application containing metconazole |
| CN107637590A (en) * | 2017-09-20 | 2018-01-30 | 陕西嘉益蓝德生物工程有限公司 | A kind of SYP-3375 granule and its application |
| CN107963924A (en) * | 2017-11-23 | 2018-04-27 | 陕西嘉益蓝德生物工程有限公司 | A kind of Bactericide fertilizer granule containing metconazole |
| CN108633885A (en) * | 2018-04-21 | 2018-10-12 | 王章修 | A kind of fertilizer granules and its application containing fludioxonil and Fluoxastrobin |
| CN112825861A (en) * | 2021-02-04 | 2021-05-25 | 四川眉山凯尔化工有限公司 | Compound pesticide herbicide |
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| CN102669101B (en) | 2015-11-18 |
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Effective date of registration: 20161027 Address after: 610300 Sichuan Province, Chengdu District of Qingbaijiang City Industrial Development Zone Tongji Road No. 903 Patentee after: Chengdu Kelilong Biochemical Co.,Ltd. Address before: 516000 Guangdong province Huizhou Zhongkai hi tech Development Zone No. 24 District Patentee before: Guangdong Zhongxun Agricultural Technology Co., Ltd. |