CN107318853A - Fertilizer granules and application containing metconazole - Google Patents

Fertilizer granules and application containing metconazole Download PDF

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Publication number
CN107318853A
CN107318853A CN201710523511.5A CN201710523511A CN107318853A CN 107318853 A CN107318853 A CN 107318853A CN 201710523511 A CN201710523511 A CN 201710523511A CN 107318853 A CN107318853 A CN 107318853A
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CN
China
Prior art keywords
metconazole
fertilizer
fertilizer granules
auxiliary agent
percentage
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710523511.5A
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Chinese (zh)
Inventor
孙鹏
罗水凌
赵萍
景辉
张美翠
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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SHAANXI BIAOZHENG CROPS SCIENCE CO Ltd
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Priority to CN201710523511.5A priority Critical patent/CN107318853A/en
Publication of CN107318853A publication Critical patent/CN107318853A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12Powders or granules
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00Other organic fertilisers
    • C05F11/02Other organic fertilisers from peat, brown coal, and similar vegetable deposits
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to technical field of pesticide preparations, it is related to a kind of fertilizer granules containing metconazole and application, being somebody's turn to do the fertilizer granules containing metconazole is prepared from by metconazole, fertilizer agent and auxiliary agent.There is obvious sterilization getting fat effect, poisoning is not likely to produce and medicament residual exceeded fertilizer granules and application containing metconazole can be prevented effectively from the invention provides a kind of.

Description

Fertilizer granules and application containing metconazole
Technical field
The invention belongs to technical field of pesticide preparations, it is related to a kind of fertilizer granules containing Fungicidal compounds and application, More particularly to a kind of fertilizer granules containing metconazole and application.
Background technology
Though root of the crop stem disease is more without leaf diseases species, the crop also more seriously caught an illness occurs in recent years Died down in Seedling Stage growing way, it is dead when serious.The loss that root of the crop stem disease has serious consequences to agricultural production.
Metconazole is a kind of triazole type ergosterol biosynthesis inhibitor, includes the higher cis-isomer of antibacterial activity (1RS, 5SR) and the relatively low transisomer of activity, metconazole has higher inhibitory activity to sickle-like bacteria mycelial growth, mainly By suppressing ergosterol biosynthesis, destruction fungal cell's membrane permeability and membrane structure, strong inhibition Fungal hyphal growth.So And, the intracellular metconazole acceptor Cyt.P450 of different plant pathogenic fungis not only has structure diversity, but also exists many Regulation and control and physiological mechanism of flying up and down are planted, so that different fungies show different sensitiveness.Apply to cereal crops shell in metconazole field Pin spore, fusarium and handle rest fungus, which plant disease, excellent effect.Inquired about by Chinese agricultural chemicals Information Network, the country does not have metconazole correlation system Agent or the registration of active compound and use.Metconazole is compared with conventional sterilants, and dosage is extremely low and prevents and treats cereal and plants sick scope very extensively, Environment prospect is good, has stronger application value to the research of metconazole.In traditional proportion of crop planting, fertilising and dispenser are point Drive into capable, so considerably increase the burden and workload of peasant.Fertilizing management and dispenser prevention and control do not have specific aim, easily lead Cause fertilising uneven not good with diseases control.
The content of the invention
In order to solve above-mentioned technical problem present in background technology, the invention provides one kind there is obvious sterilization to increase Fertilizer acts on, is not likely to produce poisoning and can be prevented effectively from medicament and remains exceeded fertilizer granules and application containing metconazole.
To achieve these goals, the present invention is adopted the following technical scheme that:
A kind of fertilizer granules containing metconazole, it is characterised in that:The fertilizer granules containing metconazole be by Metconazole, fertilizer agent and auxiliary agent are prepared from.
It is above-mentioned have metconazole fertilizer granules be 0.005%-12% by percentage by weight metconazole, 50%- 85% fertilizer and surplus is prepared from for auxiliary agent.
It is above-mentioned have metconazole fertilizer granules be 0.005%-10% by percentage by weight metconazole, 50%- 85% fertilizer and surplus is prepared from for auxiliary agent.
It is above-mentioned have metconazole fertilizer granules be 0.005%%-2% by percentage by weight metconazole, 50%- 85% fertilizer and surplus is prepared from for auxiliary agent.
Above-mentioned fertilizer is macroelement fertilizer, secondary nutrients, trace-element fertilizer, organic fertilizer, amino acid fertilizer Or its combination.
Above-mentioned auxiliary agent is binding agent, sustained release agent and carrier.
It is a kind of to prevent and treat Septoria, fusarium, handle rest fungus based on the fertilizer granules containing metconazole as previously described And/or application during snag shell bacterium.
Fertilizer granules containing metconazole preventing and treating wheat septoria leaf blight, wheat glume blotch, barley powdery mildew or Application during sigatoka.
It is an advantage of the invention that:
The invention provides a kind of fertilizer granules containing metconazole and application, by Fungicidal compounds metconazole, fertilizer Agent and auxiliary agent are prepared from.Of the invention initiative compounds Fungicidal compounds metconazole and fertilizer, forms fertilizer granules, It is to be combined fertilising and diseases prevention, while having reached the effect of diseases prevention, getting fat;Meanwhile, fertilizer granules provided by the present invention In, the content of agricultural chemicals is relatively low, is not likely to produce poisoning, does not result in the problem of medicament residual is exceeded;Fertilizer granules are used It is convenient, also applied fertilizer while dispenser, reduce labor intensity, reach the purpose of time and labour saving, medicine fertilizer is administered simultaneously, Increase operation rate, reach the purpose for reducing dosage and fertilizer application amount, it is only necessary to which dispenser once, reaches reduction labor intensity, time saving The purpose of saving of labor;After fertilising, the growth of crop is promoted, the immunity of crop is improved, the ability for resisting disease is enhanced, Connect and improve protection effect;The slow releasing function of granule, extends the lasting period, has directionality during dispenser, drift is small, to environment Pollution is small;It is not attached on the cauline leaf of plant, it is to avoid directly contact produces poisoning etc..
Embodiment
Of the invention initiative provides a kind of fertilizer granules containing metconazole and application, the medicine fertilizer containing metconazole Granule is prepared from by Fungicidal compounds metconazole, fertilizer agent and auxiliary agent.It is of the invention by bactericide active ingredient and fertile Material compounding, forms fertilizer granules, is to be combined fertilising and diseases prevention, while having reached the effect of diseases prevention, getting fat.Meanwhile, make For preferred, the leaf bacterium that it is 0.005%-12% by percentage by weight that Fungicidal compounds fertilizer granules provided by the present invention, which are, The auxiliary agent of azoles, 50%-85% fertilizer agent and surplus is prepared from according to conventional preparation technology.Of course, it is possible to according to this Composition and proportioning in the fertilizer granules containing metconazole provided is provided, other formulations are made according to existing process.
Wherein:Fungicidal compounds of the present invention are metconazoles;Fertilizer agent is macroelement fertilizer, moderate-element fertilizer Material, trace-element fertilizer, organic fertilizer, amino acid fertilizer or its combination;Auxiliary agent includes but is not limited to conventional binding agent, sustained release Agent and carrier.
In addition, the present invention further discloses the sterilization chemical combination while Fungicidal compounds fertilizer granules are provided Application of the thing fertilizer granules when preventing and treating Septoria, fusarium, handle rest fungus, snag shell bacterium, especially in preventing and treating wheat leaf Application when rot, wheat glume blotch, wheat rust, barley powdery mildew or sigatoka.
Example of formulations
The metconazole fertilizer granules of embodiment 1 0.005%
By percentage by weight be 0.005% metconazole, percentage by weight be 5% binding agent crush after be sufficiently mixed, make Agricultural chemicals is fully adsorbed on binding agent, is crushed by pulverizer;It is that 80% macroelement fertilizer is crushed to one by percentage by weight When determining fineness, the metconazole and balance carriers added after crushing is granulated after being sufficiently mixed, and the final final concentration that obtains is 0.005% metconazole fertilizer granules.
The metconazole fertilizer granules of embodiment 2 0.5%
Metconazole content (percentage by weight) 0.5%, macroelement fertilizer content (percentage by weight) 50%, trace element Fertilizer content (percentage by weight) 20%, auxiliary agent content (percentage by weight) 29.5%, final concentration is made according to extruder grain method It is 0.5% metconazole fertilizer granules.
The metconazole fertilizer granules of embodiment 3 1%
Metconazole content (percentage by weight) 1%, humic acid content (percentage by weight) 80%, auxiliary agent content (weight hundred Divide ratio) 19%, it is 1% metconazole fertilizer granules that final concentration, which is made, according to absorption comminution granulation.
The metconazole fertilizer granules of embodiment 4 5%
Metconazole content (percentage by weight) 5%, amino acid fertilizer content (percentage by weight) 50%, secondary nutrients (percentage by weight) 30%, auxiliary agent content supply 100%, and it is 5% metconazole medicine fertilizer that final concentration, which is made, according to extruder grain method Granula.
The metconazole fertilizer granules of embodiment 5 12%
Metconazole content (percentage by weight) 12%, macroelement fertilizer (percentage by weight) 30%, humic acid content (weight Measure percentage) 30%, amino acid fertilizer content (percentage by weight) 10%, auxiliary agent content (percentage by weight) 18%, according to suction It is 12% metconazole fertilizer granules that final concentration, which is made, in attached comminution granulation.
Biological Examples
Choose a kind of Fungicidal compounds metconazole 0.005%-12%, fertilizer (macroelement fertilizer, secondary nutrients, Trace-element fertilizer, organic fertilizer and amino acid fertilizer) 50%-85%, auxiliary agent (conventional binders, sustained release agent and carrier) 10%-50%, 0.005% metconazole fertilizer granules, 0.5% metconazole fertilizer granules, 1% are prepared according to coating pelletizing method Metconazole fertilizer granules, 5% metconazole fertilizer granules, 12% metconazole fertilizer granules, are respectively intended to prevent and treat wheat leaf Rot, wheat glume blotch, wheat rust, barley powdery mildew and sigatoka.Prevention effect see the table below:Wherein in table 1:From See that there is preferable prevention effect, preparation consumption to wheat leaf blight using 0.005% metconazole fertilizer granules in drug effect 90kg/ mus of preventive effects have reached 91.82%.Medicament containing equivalent weight is compared for 90kg/ mus with identical preparation consumption, 0.005% metconazole fertilizer granules preventive effect 85.33% compares 0.005% metconazole granule preventive effect apparently higher than single dose 74.11%;In terms of yield, using the humic acid fertilizer of equal consumption compared with 0.005% metconazole fertilizer granules, apply The rate of growth of 0.005% metconazole fertilizer granules is significantly greater than the rate of growth of control fertilizer, and in process of the test, does not find There is poisoning to wheat and succession crop.
The metconazole fertilizer granules of table 1 0.005% prevent and treat wheat leaf blight
Processing Preparation consumption (kg/ mus) Preventive effect (%) Rate of growth (%)
0.005% metconazole fertilizer granules 70 78.81 15.3
0.005% metconazole fertilizer granules 90 85.33 19.1
0.005% metconazole fertilizer granules 110 91.82 20.4
CK:0.005% metconazole granule 90 74.11 /
Humic acid fertilizer 110 / 11.7
The metconazole fertilizer granules of table 2 0.5% prevent and treat wheat glume blotch
Processing Preparation consumption (kg/ mus) Preventive effect (%) Rate of growth (%)
0.5% metconazole fertilizer granules 8 79.11 13.4
0.5% metconazole fertilizer granules 9 84.86 17.5
0.5% metconazole fertilizer granules 10 91.79 20.4
0.5% metconazole granule 9 75.69 /
A great number of elements+trace element 10 / 10.5
Wherein in table 2:From drug effect, have using 0.5% metconazole fertilizer granules to wheat glume blotch excellent Prevention effect, preventive effect is all higher than more than 79%, better than comparison medicament;From wheat yield, during using equivalent fertilizer, apply The rate of growth of 0.5% leaf bacterium ester fertilizer granules effectively raises the income of peasant household higher than the rate of growth for only applying fertilizer.
The metconazole fertilizer granules of table 3 1% prevent and treat wheat rust
Processing Preparation consumption (kg/ mus) Preventive effect (%) Rate of growth (%)
1% metconazole fertilizer granules 5 78.93 16.3
1% metconazole fertilizer granules 6 86.28 17.8
1% metconazole fertilizer granules 7 92.09 20.5
1% metconazole granule 7 74.59 /
Moderate-element+trace element 7 / 10.7
Wherein in table 3:From drug effect, there is excellent preventing and treating to wheat rust using 1% metconazole fertilizer granules Effect, preventive effect is all higher than more than 78%, hence it is evident that better than comparison medicament;From wheat yield, when the fertile particle of 1% metconazole medicine of administration The rate of growth of agent is significantly larger than the rate of growth for only applying moderate-element+trace-element fertilizer.
The metconazole fertilizer granules of table 4 5% prevent and treat barley powdery mildew
Processing Preparation consumption (kg/ mus) Preventive effect (%) Rate of growth (%)
5% metconazole fertilizer granules 3 79.25 18.1
5% metconazole fertilizer granules 4 84.77 19.4
5% metconazole fertilizer granules 5 90.89 21.5
5% metconazole granule 4 76.23 /
A great number of elements+amino acid+humic acid 5 / 12.5
Wherein in table 4:From drug effect, have using 5% metconazole fertilizer granules to barley powdery mildew excellent anti- Effect is controlled, preventive effect is all higher than more than 79%;Under the close dosage of comparison medicament, the preventive effect of fertilizer granules is higher than comparison medicament Preventive effect;From barley production, it is significantly larger than using the rate of growth of fertilizer granules and only applies fertilizer (a great number of elements+amino acid+corruption Phytic acid) rate of growth, be that peasant household brings more excellent economic benefit.
The metconazole fertilizer granules of table 5 12% prevent and treat sigatoka
Processing Preparation consumption (kg/ mus) Preventive effect (%) Rate of growth (%)
12% metconazole fertilizer granules 10 80.11 15.8
12% metconazole fertilizer granules 15 86.45 18.6
12% metconazole fertilizer granules 20 91.12 19.6
12% metconazole granule 15 79.01 /
Amino acid+moderate-element 20 / 12.7
Wherein in table 5:From drug effect, have using 12% metconazole fertilizer granules to sigatoka excellent anti- Effect is controlled, preventive effect is all higher than under more than 80%, dosage close with comparison medicament, and preventive effect is higher than comparison medicament;From banana production, Using the rate of growth of fertilizer granules higher than the rate of growth for only applying fertilizer.
Above-mentioned table of field test results is bright, and a kind of fertilizer granules of fungicide compound of the invention, which spread fertilizer over the fields, to be used, with Control treatment compares, and has higher prevention effect to disease.Except controlling disease, also there is fertilising, using this After the fertile particle of the medicine of invention, crop growing state is vigorous, and leaf color is dark green, and respectively processing is higher than control group yield for embodiment.
From interpretation of result, on the one hand fertilizer granules of the invention have played the effect of fertilizer, have improved crop yield, On the other hand the prevention effect to disease is enhanced, it is only necessary to which dispenser once, reaches the purpose of time and labour saving.
In summary, the fertilizer granules that the present invention is provided, active height, good drug efficacy, fertilizer efficiency are notable, possess medicine, fertilizer Double effects, can give full play to the effect of sterilization, getting fat, the features such as being not likely to produce resistance, and to crop safety, using letter Just, dosage is few, and the lasting period is long, has effectively saved the Productive statistics of peasant, has improved crop yield, is protected beneficial to environment Shield, benefit is more preferable.
It should be pointed out that above embodiment is only illustrative of the invention and is not intended to limit the scope of the invention, this The protection domain of invention should be defined by claim limited range.Come for those skilled in the art Say, do not departing from the spirit and scope of the present invention, some improvement can also be made, these improvement also should be regarded as the protection of the present invention Scope.

Claims (8)

1. a kind of fertilizer granules containing metconazole, it is characterised in that:The fertilizer granules containing metconazole are by leaf Bacterium azoles, fertilizer agent and auxiliary agent are prepared from.
2. the fertilizer granules according to claim 1 containing metconazole, it is characterised in that:The medicine for having metconazole is fertile Granule be by percentage by weight be 0.005%-12% metconazole, 50%-85% fertilizer and surplus be auxiliary agent prepare Form.
3. the fertilizer granules according to claim 2 containing metconazole, it is characterised in that:The medicine for having metconazole is fertile It by percentage by weight is 0.005%-5% metconazole, 50%-85% fertilizer and surplus for auxiliary agent is prepared that granule, which is, Into.
4. the fertilizer granules according to claim 3 containing metconazole, it is characterised in that:The medicine for having metconazole is fertile It by percentage by weight is 0.005%-3% metconazole, 50%-85% fertilizer and surplus for auxiliary agent is prepared that granule, which is, Into.
5. the fertilizer granules containing metconazole according to claim 1 or 2 or 3 or 4, it is characterised in that:The fertilizer It is macroelement fertilizer, secondary nutrients, trace-element fertilizer, organic fertilizer, amino acid fertilizer or its combination.
6. the fertilizer granules according to claim 5 containing metconazole, it is characterised in that:The auxiliary agent be binding agent, Sustained release agent and carrier.
7. a kind of preventing and treating Septoria, fusarium, handle based on the fertilizer granules containing metconazole as claimed in claim 6 Application when rest fungus and/or snag shell bacterium.
8. the fertilizer granules according to claim 7 containing metconazole are in preventing and treating wheat septoria leaf blight, wheat grain husk Application when rot barley powdery mildew or sigatoka.
CN201710523511.5A 2017-06-30 2017-06-30 Fertilizer granules and application containing metconazole Withdrawn CN107318853A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963924A (en) * 2017-11-23 2018-04-27 陕西嘉益蓝德生物工程有限公司 A kind of Bactericide fertilizer granule containing metconazole
CN108651473A (en) * 2018-06-19 2018-10-16 陕西标正作物科学有限公司 The effectively fertilizer granules of prevention soil-borne disease and plant disease
CN108911839A (en) * 2018-07-03 2018-11-30 陕西标正作物科学有限公司 Fertilizer granules containing bactericidal composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102669101A (en) * 2012-05-17 2012-09-19 广东中迅农科股份有限公司 Azoxystrobin-containing bactericide fertilizer granules
CN102669137A (en) * 2012-05-17 2012-09-19 广东中迅农科股份有限公司 Sterilization medical fertilizer granules
CN104756993A (en) * 2014-11-04 2015-07-08 江苏辉丰农化股份有限公司 Bactericidal composition containing metconazole

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102669101A (en) * 2012-05-17 2012-09-19 广东中迅农科股份有限公司 Azoxystrobin-containing bactericide fertilizer granules
CN102669137A (en) * 2012-05-17 2012-09-19 广东中迅农科股份有限公司 Sterilization medical fertilizer granules
CN104756993A (en) * 2014-11-04 2015-07-08 江苏辉丰农化股份有限公司 Bactericidal composition containing metconazole

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963924A (en) * 2017-11-23 2018-04-27 陕西嘉益蓝德生物工程有限公司 A kind of Bactericide fertilizer granule containing metconazole
CN108651473A (en) * 2018-06-19 2018-10-16 陕西标正作物科学有限公司 The effectively fertilizer granules of prevention soil-borne disease and plant disease
CN108911839A (en) * 2018-07-03 2018-11-30 陕西标正作物科学有限公司 Fertilizer granules containing bactericidal composition

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