CN114533599B

CN114533599B - Frosted hand sanitizer composition, frosted hand sanitizer and application thereof

Info

Publication number: CN114533599B
Application number: CN202210213324.8A
Authority: CN
Inventors: 申达; 程小蓉; 陈丽华
Original assignee: Guangdong Haoshun Oudisi Technology Co ltd
Current assignee: Guangdong Haoshun Oudisi Technology Co ltd
Priority date: 2022-03-01
Filing date: 2022-03-01
Publication date: 2023-10-03
Anticipated expiration: 2042-03-01
Also published as: CN114533599A

Abstract

The application relates to a frosted hand sanitizer composition and a frosted hand sanitizer prepared from the same, wherein the frosted hand sanitizer composition comprises at least 50% of water by mass percent, and further comprises the following components by mass percent: 7-9% of coconut oil fatty acid diethanolamide, 5-10% of emulsifying agent, 4-6% of alcohol solvent, 2-4% of liquid carbomer, 5-15% of plant source solvent and 8-13% of frosted particles. The frosted hand sanitizer provided by the application has extremely strong cleaning force, has double decontamination effects of efficiently removing heavy oil stains and paint, and is particularly suitable for hand cleaning of machine repairmen and steam repairmen.

Description

Frosted hand sanitizer composition, frosted hand sanitizer and application thereof

Technical Field

The application relates to the technical field of chemical industry, in particular to a frosted hand sanitizer composition, a frosted hand sanitizer and application thereof.

Background

There are many products on the market for cleaning hands, such as liquid foam hand cleaners, soaps, common frosted hand cleaners, etc., which can remove common greasy dirt in daily life, but are difficult to remove heavy greasy dirt and paint.

When the automobile repair worker performs operations such as automobile maintenance and renovation, heavy oil stains of mechanical parts are easy to be stained on hands, the heavy oil stains are generally a mixture of lubricating oil, gear oil, engine oil, butter and the like, and the heavy oil stains have extremely strong viscosity after long-time sun exposure and weathering, and are difficult to clean; in the process of spraying or repairing the automobile paint, the automobile paint is easy to be stained with the paint, and the paint is difficult to be removed after being adhered to the skin of a human body.

At present, the existing cleaning mode for heavy oil stains and paint is to clean the heavy oil stains and the paint by adopting a common detergent for a small amount for many times, and the mode is complex in operation and low in efficiency and is easy to cause skin damage. In order to save time, some workers adopt chemical solvents for cleaning, such as oil-melting agents, tenna water and the like, and the chemical solvents have strong cleaning power but strong skin irritation, and volatile inhalable gas in the chemical solvents also has potential health hazard to human bodies.

Based on the above, there is a need to develop a fast, safe and efficient hand cleaner to solve the hand cleaning problem of the automotive repair workers.

Disclosure of Invention

The application aims to provide a frosted hand sanitizer composition, which solves the hand cleaning problem of a steam repair worker.

The application provides a frosted hand sanitizer composition, which comprises at least 50% of water by mass percent and further comprises the following components: 7-9% of coconut oil fatty acid diethanolamide, 5-10% of emulsifying agent, 4-6% of alcohol solvent, 2-4% of liquid carbomer, 5-15% of plant source solvent and 8-13% of frosted particles in percentage by mass;

the abrasive particles are natural inorganic materials.

In some embodiments of the present application, the emulsifier in the hand sanitizer composition is one or both of isomeric alcohol-polyoxyethylene ethers and fatty alcohol-polyoxyethylene ethers; and/or the number of the groups of groups,

the grain diameter of the frosted grains is 80-120 meshes.

In some embodiments of the application, the HBL value of the emulsifier in the abrasive hand sanitizer composition is not less than 12; and/or the number of the groups of groups,

the mass solid content of the liquid carbomer is 29% -31%; and/or the number of the groups of groups,

the frosted particles are one or two of quartz sand and perlite.

In some embodiments of the application, the alcohol solvent in the abrasive hand sanitizer composition is one or both of ethanol and isopropanol; and/or the number of the groups of groups,

the plant source solvent is one or more of D-limonene, turpentine and alcohol ether ester.

In some embodiments of the application, the model of the coconut fatty acid diethanolamide in the hand sanitizer composition is type 1:1; and/or the number of the groups of groups,

the model of the liquid carbomer is ST 1; and/or the number of the groups of groups,

the emulsifier is one or more selected from E-1310 isomerism alcohol polyoxyethylene ether, AEO-9 fatty alcohol polyoxyethylene ether and alkyl glycoside APG.

In some embodiments of the application, the frosted hand sanitizer composition further comprises 1-5% of humectant by mass.

In some embodiments of the application, the moisturizing agent is selected from one or both of 1,2 butanediol and glycerol in the abrasive hand sanitizer composition.

In some embodiments of the present application, the abrasive hand sanitizer composition comprises the following components in percentage by mass:

in a second aspect, the application provides a hand-cleansing composition comprising the hand-cleansing composition of the first aspect.

In a third aspect, the application provides a hand sanitizer composition provided in the first aspect of the application, or the use of a hand sanitizer provided in the second aspect of the application in the decontamination of the hands of a mechanic or steam mechanic.

According to the application, by adopting the frosted particles with proper particle size and proper density as the friction agent, realizing better friction force through proper particle size, controlling the suspension property of the particles through proper density to realize uniform distribution in a mixed system, further matching with the synergistic thickening of coconut fatty acid diethanolamide and liquid carbomer, and matching with proper addition of emulsifying agent, alcohol solvent and plant source solvent, the cleaning performance is comprehensively improved, and the dual decontamination effect of removing heavy oil stains and paint can be realized efficiently.

The frosted hand sanitizer provided by the application has a wide application range, not only can be used for cleaning conventional greasy dirt, but also can be used for cleaning heavy greasy dirt and paint polluted by working environments such as machine repair, steam repair and the like, has high cleaning efficiency and strong cleaning capability, and can be used for rapidly removing the heavy greasy dirt and paint attached to hands (for example, only one time of cleaning is needed, and the scrubbing time is lower than 30 s); the raw materials are biodegradable, green and pollution-free, protect human body and environment safety, and have excellent application prospect.

Detailed Description

The application is further illustrated below in conjunction with the embodiments and examples. It is to be understood that these examples are illustrative of the present application and are not intended to limit the scope of the present application. Furthermore, it is to be understood that various changes and modifications may be made by one skilled in the art after reading the teachings of the application, and such equivalents are intended to fall within the scope of the appended claims.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. The terminology used herein in the description of the application is for the purpose of describing particular embodiments only and is not intended to be limiting of the application.

Terminology

Unless otherwise indicated or contradicted, terms or phrases used herein have the following meanings:

the term "and/or," "and/or," as used herein, includes any one of two or more of the listed items in relation to each other, as well as any and all combinations of the listed items in relation to each other, including any two of the listed items in relation to each other, any more of the listed items in relation to each other, or all combinations of the listed items in relation to each other. It should be noted that, when at least three items are connected by at least two conjunctions selected from the group consisting of "and/or", "and/or", it is to be understood that, in the present application, the technical solutions certainly include technical solutions that all use "logical and" connection, and also certainly include technical solutions that all use "logical or" connection. For example, "a and/or B" includes three parallel schemes A, B and a+b. For another example, the technical schemes of "a, and/or B, and/or C, and/or D" include any one of A, B, C, D (i.e., the technical scheme of "logical or" connection), and also include any and all combinations of A, B, C, D, i.e., any two or three of A, B, C, D, and also include four combinations of A, B, C, D (i.e., the technical scheme of "logical and" connection).

Herein, "preferred", "better", etc. are merely embodiments or examples that describe better results, and it should be understood that they do not limit the scope of the application.

In the present application, "further", "still further", "particularly" and the like are used for descriptive purposes to indicate differences in content but should not be construed as limiting the scope of the application.

In the present application, the terms "first", "second", "third", etc. are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or quantity, nor as implying an importance or quantity of a technical feature being indicated. Moreover, "first," "second," "third," etc. are for non-exhaustive list description purposes only, and it should be understood that no closed limitation on the number is made.

In the application, the technical characteristics described in an open mode comprise a closed technical scheme composed of the listed characteristics and also comprise an open technical scheme comprising the listed characteristics.

In the present application, a numerical range (i.e., a numerical range) is referred to, and optional numerical distributions are considered to be continuous within the numerical range and include two numerical endpoints (i.e., a minimum value and a maximum value) of the numerical range and each numerical value between the two numerical endpoints unless otherwise specified. When a numerical range merely points to integers within the numerical range, both end integers of the numerical range are included, as well as each integer between the two ends, unless expressly stated otherwise. Further, when a plurality of range description features or characteristics are provided, these ranges may be combined. In other words, unless otherwise indicated, the ranges disclosed herein are to be understood to include any and all subranges subsumed therein.

The temperature parameter in the present application is not particularly limited, and may be a constant temperature treatment or may vary within a predetermined temperature range. It should be appreciated that the constant temperature process described allows the temperature to fluctuate within the accuracy of the instrument control. Allows for fluctuations within a range such as + -5 ℃, + -4 ℃, + -3 ℃, + -2 ℃, + -1 ℃.

In the present application, the dimensions, particle diameter and diameter are generally average values, unless otherwise specified.

In the present application, the molecular weight is, but not particularly limited to, an average molecular weight, and further, a number average molecular weight.

In the present application, the particle size range is defined by the number of meshes, and means the maximum and minimum mesh sizes through which particles can pass, for example, the particle size is 80 to 100 mesh, and means that the particles can pass through a 80 mesh screen at the maximum and a 100 mesh screen at the minimum, if not particularly limited.

The first aspect of the application provides a frosted hand sanitizer composition which has strong cleaning capability and can remove industrial heavy greasy dirt and paint; the cleaning efficiency is high, repeated scrubbing is not needed, and skin damage can be reduced; the environment-friendly type water-based paint is environment-friendly, and can be degraded in components without polluting the environment.

Current hand washes are used either for removal of industrial heavy oils only or for removal of paint only, but no report has been found of hand washes that remove industrial heavy oils and paint simultaneously. The inventors have found that this is due to the fact that the main components of the oil stains and the paint are different, which respectively correspond to completely different cleaning schemes, which results in that the respectively corresponding hand sanitizer formulations cannot be used universally. Specifically, the main components of the greasy dirt are grease, oil products, skin grease and the like, and a surfactant is required to be added for emulsification and decontamination, so that the greasy dirt has no effect on paint; the main component of the paint is resin, and the paint needs to be dissolved and decontaminated by adding a solvent, so that the paint has an insignificant effect on greasy dirt; in addition, paint removal products commonly contain large amounts of organic solvents, such as 3M, le, and other brands of hand wash pastes, which have a pungent odor, are not environmentally friendly, and have poor feel in use.

According to the application, by adopting the coconut oil fatty acid diethanolamide with proper addition amount, and matching with liquid carbomer for crosslinking and thickening, and matching with an emulsifier, an alcohol solvent, a plant source solvent and frosted particles with proper particle sizes, the frosted hand sanitizer composition with a relatively simple formula is obtained, the effects of removing heavy oil stains and paint can be simultaneously realized, and the hand sanitizer composition is particularly suitable for hand cleaning of a steam repair worker (the working environment of the steam repair worker needs to be contacted with industrial engine oil and to be subjected to paint spraying operation, and the hands of a worker are easy to be stained with heavy oil stains and paint); the frosted hand sanitizer also has excellent environmental protection.

As used herein, "environmental protection" means that the ingredients of the abrasive hand sanitizer composition of the present application are natural products or non-natural degradable materials, and "degradable" means that the resulting effluent is biodegradable in nature after cleaning with the composition.

In a first aspect of the application, there is provided a hand sanitizer composition comprising at least 50% by weight water, and further comprising: 7-9% of coconut oil fatty acid diethanolamide, 5-10% of emulsifying agent, 4-6% of alcohol solvent, 2-4% of liquid carbomer, 5-15% of plant source solvent and 8-13% of frosted particles in percentage by mass;

the abrasive particles are natural inorganic materials.

Coconut oil fatty acid diethanolamide is a nonionic surfactant which can be added into hand sanitizer to achieve wetting and dispersing properties, but has poor cleaning ability when used alone. According to the application, the coconut oil fatty acid diethanolamide with proper addition is adopted to enable the coconut oil fatty acid diethanolamide to have spontaneous thickening characteristics, and is matched with the liquid carbomer with proper addition to further crosslink and thicken, so that the frosted particles in the components are well supported under the double thickening effect, and are prevented from sedimentation.

In some embodiments of the application, coconut fatty acid diethanolamide is surfactant 6501 or surfactant 6502.

In some embodiments of the application, the model number of coconut oil fatty acid diethanolamide is type 1:1.

In some embodiments of the application, the coconut oil fatty acid diethanolamide is present in an amount of 7% to 9% by mass, and may further be present in an amount of 7% to 8%, such as, for example, 7%, 7.5%, 8%, 8.5%, 9%, and the like, based on 100% by mass of the total composition of the hand sanitizer.

In the present application, the liquid carbomers can be thickened in concert with other components. In some embodiments, the liquid carbomer has a mass solids content of 29-31%, high solubility, and good compatibility with the components of the system.

In some embodiments of the application, the liquid carbomer is model ST 1.

In some embodiments of the application, the liquid carbomer is present in an amount of 2% to 4% by mass, further 2% to 3% by mass, such as 2%, 2.5%, 3%, 3.5%, 4%, etc., based on 100% by mass of the total composition of the abrasive hand sanitizer.

In the application, the abrasive particles with proper addition amount and proper particle size (preferably 80-120 meshes) are adopted to match with other components, so that the abrasive has excellent stability, strong cleaning strength, no stinging and good use feeling.

In some embodiments of the present application, the abrasive particles have a particle size of 80 mesh to 120 mesh, further may be 80 mesh to 100 mesh, such as 80 mesh, 85 mesh, 90 mesh, 95 mesh, 100 mesh, 110 mesh, 120 mesh, and the like.

In some embodiments of the application, the abrasive particles are natural inorganic materials. In some embodiments, the abrasive particles are one or both of quartz sand, perlite. In some embodiments, the abrasive particles are natural perlite.

In some embodiments of the present application, the abrasive particles comprise from 8% to 13% by mass, further from 8% to 10% by mass, such as, for example, 8%, 9%, 10%, 11%, 12%, 13%, etc., based on 100% by mass of the total abrasive hand sanitizer composition.

In the application, the emulsifier emulsifies a plant source solvent (such as turpentine, limonene, alcohol ether ester and the like) into an aqueous system to reach the state of microemulsion, so as to form the oil-in-water microemulsion micelle. The micro emulsion beam generates demulsification in the mechanical friction process of the frosted particles, so that the lipophilic groups are released and compatible with paint, thereby achieving the effect of paint removal.

In some embodiments of the application, the HBL value of the emulsifier is not less than 12, further may be from 12 to 13, such as, for example, 12.1, 12.2, 12.3, 12.4, 12.5, 12.6, 12.7, 12.8, 12.9, 13, etc.

In some embodiments of the application, the emulsifier is one or both of isomeric alcohol polyoxyethylene ethers and fatty alcohol polyoxyethylene ethers.

In some embodiments of the application, the emulsifier is selected from one or more of E-1310 isomeric alcohol polyoxyethylene ethers, AEO-9 fatty alcohol polyoxyethylene ethers, and alkyl glycoside APGs.

In some embodiments of the application, the emulsifier is an isomeric alcohol polyoxyethylene ether, further the isomeric alcohol polyoxyethylene ether is model E-1310.

In some embodiments of the application, the emulsifier is a fatty alcohol-polyoxyethylene ether, further the fatty alcohol-polyoxyethylene ether is model AEO-9.

In some embodiments of the present application, the emulsifier is present in an amount of 5% to 10% by mass, and further may be present in an amount of 8% to 10%, such as, for example, 5%, 6%, 7%, 8%, 9%, 10%, etc., based on 100% by mass of the total composition of the abrasive hand sanitizer.

Alcohol solvents can dissolve most of the oil stains and some of the paint, but alcohol solvents are not sufficient for thorough cleaning. In the application, the alcohol solvent and the plant source solvent (turpentine, or limonene, or alcohol ether esters) are synergistically enhanced, so that heavy oil stains and paint can be thoroughly cleaned.

In some embodiments of the application, the alcoholic solvent is one or both of ethanol and isopropanol. In some embodiments, the alcoholic solvent is ethanol, further, may be absolute ethanol. In some embodiments, the alcoholic solvent is isopropanol. In some embodiments, the alcoholic solvent is a mixture of ethanol and isopropanol.

In some embodiments of the present application, the alcoholic solvent may be present in an amount of 4% to 6% by mass, further 4% to 5% by mass, such as, for example, 4%, 4.5%, 5%, 5.5%, 6%, etc., based on 100% by mass of the total composition of the abrasive hand sanitizer.

The plant source solvent is a degradable organic solvent and can dissolve grease stains, and the plant source solvent is matched with alcohol solvents, emulsifying agents and other components to synergistically improve the cleaning capacity, so that the cleaning capacity is not repeated here.

In some embodiments of the application, the botanical solvent is one or more of D-limonene, turpentine, and an alcohol ether ester. In some embodiments, the botanical solvents are D-limonene and turpentine. In some embodiments, the botanical solvents are D-limonene and alcohol ether esters. In some embodiments, the botanical solvents are turpentine and alcohol ether esters. In some embodiments, the botanical solvent is a mixture of D-limonene, turpentine, and an alcohol ether ester. In some embodiments, the botanical solvent is D-limonene. In some embodiments, the botanical solvent is turpentine. The turpentine has a certain bactericidal effect and is suitable for hand cleaning.

In some embodiments of the present application, the plant-derived solvent may be present in an amount of 5% to 15% by mass, further 5% to 10% by mass, such as 5%, 6%, 8%, 10%, 12%, 15%, etc., based on 100% by mass of the total composition of the abrasive hand sanitizer.

In some embodiments of the application, the abrasive hand sanitizer composition further comprises 1-5% by weight of a humectant. Can avoid the skin from being overdry after cleaning, keep moist and feel good in use.

In some embodiments of the application, the moisturizing agent in the abrasive hand sanitizer composition is one or both of 1,2 butanediol or glycerin. In some embodiments, the humectant is 1,2 butanediol. In some embodiments, the humectant is glycerin. In some embodiments, the humectant is a mixture of 1,2 butanediol and glycerol.

In some embodiments of the present application, the humectant is present in an amount of 0% to 5% by mass, and further may be present in an amount of 1% to 5%, such as, for example, 0, 1%, 2%, 3%, 4%, 5%, etc., based on 100% by mass of the total composition of the abrasive hand sanitizer.

In some embodiments of the present application, the abrasive hand sanitizer compositions include at least 50% water by mass, and further, the water may be present in an amount of 50% to 66% by mass, such as, for example, 50%, 51%, 52%, 55%, 56%, 58%, 60%, 62%, 65%, 66%, and the like.

In some embodiments of the present application, the abrasive hand sanitizer composition comprises the following components in percentage by mass: 7-9% of coconut oil fatty acid diethanolamide, 5-10% of emulsifying agent, 4-6% of alcohol solvent, 2-4% of liquid carbomer, 5-15% of plant source solvent, 8-13% of frosted particles, 0-5% of humectant and at least 50% of water. Wherein, the mass percent of the coconut oil fatty acid diethanolamide independently can be 7% -9%, further can be 7% -8%, such as 7%, 7.5%, 8%, 8.5%, 9%, etc.; the mass percentage of the emulsifier can be 5% -10% independently, and further can be 8% -10%, such as 5%, 6%, 7%, 8%, 9%, 10%, etc.; the mass percentage of the alcohol solvent independently can be 4% -6%, further can be 4% -5%, such as 4%, 4.5%, 5%, 5.5%, 6%, etc.; the mass percentage of the liquid carbomer can independently be 2% -4%, further can be 2% -3%, such as 2%, 2.5%, 3%, 3.5%, 4%, etc.; the mass percentage of the plant source solvent independently can be 5% -15%, further can be 5% -10%, such as 5%, 6%, 8%, 10%, 12%, 15%, etc.; the mass percent of the abrasive particles independently may be 8% to 13%, further may be 8% to 10%, such as 8%, 9%, 10%, 11%, 12%, 13%, etc.; the content of the humectant may be independently 0% to 5%, further 0% to 3%, for example, 0, 1%, 2%, 3%, 4%, 5%, etc.; the water independently may be at least 50% by mass, and may further be 50% to 66% by mass, such as 51%, 52%, 55%, 56%, 58%, 60%, 62%, 65%, 66%, and the like.

In a second aspect, the application provides a hand-cleaning composition comprising the hand-cleaning composition of the first aspect of the application. The hand cleanser has wide applicability, is suitable for cleaning most of greasy dirt, is also suitable for cleaning heavy greasy dirt and paint, is environment-friendly and does not pollute the environment; the use feeling is good, and the skin is not damaged.

In a third aspect, the application provides a hand sanitizer composition provided in the first aspect of the application, or the use of a hand sanitizer provided in the second aspect of the application in the decontamination of the hands of a mechanic or steam mechanic. Heavy oil stains (such as a mixture of lubricating oil, gear oil, engine oil, butter and the like) and paint are often stained on hands of mechanic and automobile repairmen, a common cleaning agent is difficult to clean, most cleaning products are only aimed at one kind of stains, degreasing liquid soap is not suitable for removing paint, the degreasing liquid soap is not suitable for removing oil stains, the cleaning efficiency is low, repeated rubbing and washing are needed, and skin damage is easy to cause.

The frosted hand sanitizer can safely, efficiently and quickly remove paint and greasy dirt. In some embodiments, the cleaning is a simple rub. In some embodiments, the cleaning time is no more than 25 seconds, further may be no more than 20 seconds, and still further may be no more than 15 seconds. In some embodiments, the number of washes does not exceed 1.

The following are some specific examples.

The experimental parameters not specified in the following specific examples are preferentially referred to the guidelines given in the present document, and may also be referred to the experimental manuals in the art or other experimental methods known in the art, or to the experimental conditions recommended by the manufacturer.

The starting materials and reagents referred to in the following specific examples may be obtained commercially or may be prepared by known means by those skilled in the art.

Raw materials:

the starting materials in the following examples were obtained by purchase:

coconut oil fatty acid diethanolamide (6501): the purchasing manufacturer: guangzhou JING field trade Co., ltd;

coconut oil fatty acid diethanolamide (6502): the purchasing manufacturer: guangzhou JING field trade Co., ltd;

fatty acid sodium Methyl Ester Sulfonate (MES): the purchasing manufacturer: yonglong chemical raw materials Co., ltd in Shenzhen City;

fatty alcohol polyoxyethylene ether sodium sulfate (AES): the purchasing manufacturer: shenzhen An Runpu chemical raw materials Co., ltd;

isomeric alcohol polyoxyethylene ether (E1310): the purchasing manufacturer: guangzhou JING field trade Co., ltd;

fatty alcohol polyoxyethylene ether (AEO-9): the purchasing manufacturer: guangzhou JING field trade Co., ltd;

liquid carbomers: the purchasing manufacturer: wanhua chemistry; model ST-1;

perlite: the purchasing manufacturer: zhangzhou Xinqiang Wei Utility company; particle size is 80-100 meshes, 20-40 meshes;

cerium oxide: the purchasing manufacturer: shanghai source nest Utility Co., ltd; particle size is 800-1200 mesh;

d-limonene: the purchasing manufacturer: guangzhou Union Biotechnology Co., ltd;

turpentine oil: the purchasing manufacturer: guangdong automobile products Co., ltd.

Example 1

According to the mass portion, 7 portions of coconut fatty acid diethanoyl (6501), 10 portions of emulsifying agent (isomeric alcohol polyoxyethylene ether E-1310), 5 portions of alcohol solvent (isopropanol), 3 portions of liquid carbomer, 10 portions of plant source solvent (D-limonene), 10 portions of frosted particles (80-100 meshes of perlite) and 55 portions of water are mixed to prepare the frosted hand sanitizer for standby.

Example 2

According to the mass portion, 9 portions of coconut fatty acid diethanoyl (6501), 10 portions of emulsifying agent (isomeric alcohol polyoxyethylene ether E-1310), 6 portions of alcohol solvent (isopropanol), 2 portions of liquid carbomer, 5 portions of plant source solvent (D-limonene), 13 portions of frosted particles (80-100 meshes of perlite) and 55 portions of water are mixed to prepare the frosted hand sanitizer for standby.

Example 3

According to the mass portion, 8 portions of coconut oil fatty acid diethanoyl (6501), 8 portions of emulsifying agent (fatty alcohol polyoxyethylene ether AEO-9), 4 portions of alcohol solvent (absolute ethyl alcohol), 2 portions of liquid carbomer, 5 portions of plant source solvent (D-limonene), 8 portions of frosted particles (80-100 meshes of perlite) and 65 portions of water are mixed to prepare the frosted hand sanitizer for standby.

Example 4

According to the parts by weight, 8 parts of coconut oil fatty acid diethanoyl (6501), 8 parts of an emulsifier (fatty alcohol polyoxyethylene ether AEO-9), 4 parts of an alcohol solvent (absolute ethyl alcohol), 2 parts of liquid carbomer, 5 parts of a plant source solvent (turpentine), 8 parts of frosted particles (80-100 meshes of perlite), 3 parts of a humectant (glycerin) and 62 parts of water are mixed to prepare the frosted hand sanitizer for standby.

Example 5

According to the parts by weight, 7 parts of coconut oil fatty acid diethanoyl (6501), 8 parts of emulsifying agent (isomeric alcohol polyoxyethylene ether E-1310), 4 parts of alcohol solvent (isopropanol), 4 parts of liquid carbomer, 12 parts of plant source solvent (turpentine), 8 parts of frosted particles (80-100 meshes of perlite), 2 parts of humectant (glycerin) and 55 parts of water are mixed to prepare the frosted hand sanitizer for standby.

Example 6

According to the mass portion, 7 portions of coconut fatty acid diethanoyl (6501), 8 portions of emulsifying agent (isomeric alcohol polyoxyethylene ether E-1310), 5 portions of alcohol solvent (isopropanol), 2 portions of liquid carbomer, 8 portions of plant source solvent (D-limonene), 10 portions of frosted particles (80-100 meshes of perlite), 2 portions of humectant (glycerin) and 58 portions of water are mixed to prepare the frosted hand sanitizer for standby.

Example 7

According to the mass portion, 7 portions of coconut fatty acid diethanoyl (6502), 8 portions of emulsifying agent (isomeric alcohol polyoxyethylene ether E-1310), 5 portions of alcohol solvent (isopropanol), 2 portions of liquid carbomer, 8 portions of plant source solvent (D-limonene), 10 portions of frosted particles (80-100 meshes of perlite), 2 portions of humectant (glycerin) and 58 portions of water are mixed to prepare the frosted hand sanitizer for standby.

Comparative example 1

A hand sanitizer was prepared in substantially the same manner as in example 6, except that: the coconut fatty acid diethanolamide was replaced with sodium fatty acid methyl sulfonate (MES) and the remaining parameters and operating procedures were the same as in example 6.

Comparative example 2

A hand sanitizer was prepared in substantially the same manner as in example 6, except that: the emulsifier is sodium fatty alcohol polyoxyethylene ether sulfate (AES), and the rest parameters and operation steps are the same as those of the example 6.

Comparative example 3

A hand sanitizer was prepared in substantially the same manner as in example 6, except that: the alcohol solvent was ethylene glycol, and the other parameters and operation steps were the same as in example 6.

Comparative example 4

A hand sanitizer was prepared in substantially the same manner as in example 6, except that: the amount of D-limonene was 2 parts, and the remaining parameters and operation procedures were the same as in example 6.

Comparative example 5

A hand sanitizer was prepared in substantially the same manner as in example 6, except that: the particle size of the perlite is 20-40 meshes, and the rest parameters and operation steps are the same as in example 6.

Comparative example 6

A hand sanitizer was prepared in substantially the same manner as in example 6, except that the abrasive particles were 80 mesh to 100 mesh cerium oxide, and the remaining parameters and operating procedures were the same as in example 6.

Performance testing

The cleaning ability test was performed on the hand-polishing compositions of examples 1 to 7 and comparative examples 1 to 6, and the test results are shown in table 1.

TABLE 1

In Table 1, "-" means that the resulting hand sanitizer was significantly delaminated, unusable, and the corresponding performance data was empty.

According to the performance data results in Table 1, the frosted hand washing liquid obtained by the test method is used for washing the greasy dirt on hands, the washing mode is simple, the washing efficiency is high, and the heavy greasy dirt and paint can be effectively removed at the same time. The cleaning strength and the cleaning efficiency are reduced by changing the types and the contents of the components in the formula, which is unfavorable for efficiently and rapidly removing oil and paint.

All documents mentioned in this disclosure are incorporated by reference in this disclosure as if each were individually incorporated by reference. Unless otherwise indicated to the contrary by the intent and/or technical aspects of the present application, all references to which this application pertains are incorporated by reference in their entirety for all purposes. When reference is made to a cited document in the present application, the definitions of the relevant technical features, terms, nouns, phrases, etc. in the cited document are also incorporated. In the case of the cited documents, examples and preferred modes of the cited relevant technical features are also incorporated into the present application by reference, but are not limited to being able to implement the present application. It should be understood that when a reference is made to the description of the application in conflict with the description, the application is modified in light of or adaptive to the description of the application.

The technical features of the above-described embodiments and examples may be combined in any suitable manner, and for brevity of description, all of the possible combinations of the technical features of the above-described embodiments and examples are not described, however, as long as there is no contradiction between the combinations of the technical features, they should be considered to be within the scope described in the present specification.

The above examples merely represent a few embodiments of the present application and are not to be construed as limiting the scope of the application. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the application, which are all within the scope of the application. Further, it is understood that various changes and modifications of the present application may be made by those skilled in the art after reading the above teachings, and equivalents thereof are intended to fall within the scope of the present application. It should also be understood that, based on the technical solutions provided by the present application, those skilled in the art obtain technical solutions through logical analysis, reasoning or limited experiments, all of which are within the scope of protection of the appended claims. The scope of the application should, therefore, be determined with reference to the appended claims, along with the full scope of equivalents to which such claims are entitled.

Claims

1. The frosted hand sanitizer composition is characterized by comprising at least 50% of water by mass percent and further comprising the following components: 7-9% of coconut oil fatty acid diethanolamide, 5-10% of emulsifying agent, 4-6% of alcohol solvent, 2-4% of liquid carbomer, 5-15% of plant source solvent and 8-13% of frosted particles;

the emulsifier is one or more selected from E-1310 isomerism alcohol polyoxyethylene ether, AEO-9 fatty alcohol polyoxyethylene ether and alkyl glycoside APG;

the alcohol solvent is one or two of ethanol and isopropanol;

the frosted particles are made of natural inorganic materials; the frosted particles are perlite; the grain diameter of the frosted grains is 80-120 meshes.

2. The abrasive hand sanitizer composition of claim 1, wherein the emulsifier has an HBL value of not less than 12; and/or the number of the groups of groups,

the mass solid content of the liquid carbomer is 29% -31%.

3. The abrasive hand sanitizer composition of claim 1, wherein the botanical solvent is one or more of D-limonene, turpentine, and alcohol ether esters.

4. The abrasive hand sanitizer composition of claim 1, wherein said coconut fatty acid diethanolamide is of type 1:1; and/or the number of the groups of groups,

the liquid carbomer is of type ST 1.

5. The abrasive hand sanitizer composition of claim 1, further comprising 1-5% by mass of a humectant.

6. The abrasive hand sanitizer composition of claim 5, wherein the humectant is selected from one or both of 1,2 butanediol and glycerin.

7. The hand sanitizer composition according to any one of claims 1-6, characterized by comprising the following components in percentage by mass:

coconut oil fatty acid diethanoyl 7% -8%;

8% -10% of an emulsifier;

4% -5% of an alcohol solvent;

2% -4% of liquid carbomer;

5% -10% of a plant source solvent;

8% -10% of frosted particles;

1% -3% of humectant;

50% -66% of water.

8. A hand scrub solution comprising the hand scrub solution composition of any one of claims 1-7.

9. Use of the abrasive hand sanitizer composition of any one of claims 1-7, or the abrasive hand sanitizer of claim 8, for the decontamination of a mechanic, a steam mechanic's hands.