CN114469785A - Long-acting moisture lipstick for makeup and preparation method thereof - Google Patents

Long-acting moisture lipstick for makeup and preparation method thereof Download PDF

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Publication number
CN114469785A
CN114469785A CN202210138969.XA CN202210138969A CN114469785A CN 114469785 A CN114469785 A CN 114469785A CN 202210138969 A CN202210138969 A CN 202210138969A CN 114469785 A CN114469785 A CN 114469785A
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parts
lipstick
long
weight
emollient
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曹波
刘慎忠
张欢
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Guangdong Bailichen Biotechnology Co ltd
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Guangdong Bailichen Biotechnology Co ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63Steroids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/001Preparations for care of the lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions
    • A61K2800/5922At least two compounds being classified in the same subclass of A61K8/18

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Abstract

The invention discloses a long-acting make-up-holding moisturizing lipstick and a preparation method thereof, wherein the long-acting make-up-holding moisturizing lipstick comprises a solvent, a film forming agent, an emollient, a thickening agent, a filler, an antioxidant, a humectant and a coloring agent; the solvent comprises isododecane accounting for 10-20% of the lipstick by weight; the film forming agent comprises hydrogenated (styrene/methyl styrene/indene) copolymer accounting for 6-15% of the weight of the lipstick; the emollient comprises C10-30 acid cholesterol/lanosterol mixed ester 1-3 wt% of lipstick, and white chingma seed oil 0.5-2 wt% of lipstick; the filling agent comprises polymethylsilsesquioxane accounting for 1-3% of the weight of the lipstick. The long-acting moisturizing lipstick provided by the invention is easy to apply, not easy to remove, comfortable, not tight after use, moisturizing, simple in preparation method process and convenient to operate.

Description

Long-acting moisture lipstick for makeup and preparation method thereof
Technical Field
The invention relates to the technical field of cosmetics, in particular to a long-acting moisturizing lipstick for long-term makeup and a preparation method thereof.
Background
Lipstick is an important color cosmetic product, and can increase the color and fullness of lips when being applied to the lips. Lipsticks generally include base ingredients, waxes, fats and oils, emollients, colorants, humectants, fragrances, and the like. For example, patent 202110403523.0 discloses a moisturizing and long-lasting lipstick prepared from microcrystalline wax, bis-behenyl alcohol/isostearyl alcohol/phytosterol dimer linoleate, polyglyceryl-2 isostearate/dimer linoleate copolymer, diisostearyl malate, dipentaerythritol tri-polyhydroxystearate, hydrogenated (styrene/methylstyrene/indene) copolymer, dipalmitoyl hydroxyproline, olive oil unsaponifiable, and moisturizers. The patent achieves a synergistic effect by compounding the substances, so that the lipstick can be moistened and can keep excellent persistence, and the moistening and lasting effects are achieved. However, in order to provide a lipstick product with longer lasting makeup, better moisture retention and better comfort, continuous research and development in this field are necessary.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention aims to provide the long-acting moisturizing lipstick which is easy to apply, difficult to remove makeup, comfortable, not tight after use, and capable of moisturizing.
The second purpose of the invention is to provide a preparation method of the long-acting make-up-holding moistening lipstick, which has simple process and convenient operation.
One of the purposes of the invention is realized by adopting the following technical scheme:
a long-acting moistening lipstick for long-term makeup comprises solvent, film forming agent, emollient, thickener, filler, antioxidant, humectant and colorant; the solvent comprises isododecane accounting for 10-20% of the lipstick by weight; the film forming agent comprises hydrogenated (styrene/methyl styrene/indene) copolymer which accounts for 6-15 percent of the weight of the lipstick; the emollient comprises C10-30 acid cholesterol/lanosterol mixed ester accounting for 1-3 percent of the lipstick by weight and chinaroot greenbrier seed oil accounting for 0.5-2 percent of the lipstick by weight; the filling agent comprises polymethylsilsesquioxane accounting for 1-3% of the lipstick by weight.
The lipstick adopts isododecane as a solvent and isododecane as a hydrogen carbon compound, so that the lipstick is fresh and cool in texture and easy to apply, and the water loss of lip skin can be reduced. Hydrogenated (styrene/methyl styrene/indene) copolymer is used as a film forming agent, so that a tough protective film can be formed to prevent lipstick from being removed, tight feeling is not generated, and the comfort level is high. The C10-30 acid cholesterol/lanosterol mixed ester is used as an emollient, so that the skin is nourished and lubricated with high strength, dry skin can be repaired, and better gloss can be given to lipstick. The meadowrue root-bark (limnanthelba) seed oil is used as the emollient, so that the stability of lipstick can be increased, the shelf life is prolonged, the meadowrue root-bark (limnanthelba) seed oil has a special moisturizing effect, the skin moisture loss can be effectively prevented, the high moisturizing effect is achieved, the greasiness is avoided, the dispersibility of toner can be improved, the cosmetic effect is better, and rich and full texture is provided. The polymethylsilsesquioxane is used as a filler, so that the ductility and smoothness of lipstick can be enhanced, the gloss is increased, and a film formed by matching the polymethylsilsesquioxane and a hydrogenated (styrene/methyl styrene/indene) copolymer is more flexible and skin-adherent, so that the waterproof and oilproof performance, the durability and the toner migration resistance of lipstick can be improved, the skin elasticity can be improved to a certain extent, and comfortable and not tight skin feeling experience is given.
In addition, the proportion of isododecane, hydrogenated (styrene/methyl styrene/indene) copolymer, C10-30 acid cholesterol/lanosterol mixed ester, chinaroot flower seed oil and polymethylsilsesquioxane in lipstick is reasonably controlled, the whole formula is reasonably matched to form a stable system, and the lipstick is moist and moisturized, not easy to decolor, full in luster, moist and moisturized, not greasy and not tight, and is a lipstick product with better performance.
Further, the long-acting moist lipstick for long-lasting makeup comprises the following components in parts by weight: 10-20 parts of solvent, 6-15 parts of film forming agent, 20-45 parts of emollient, 9-20 parts of thickening agent, 4-10 parts of filler, 0.05-0.1 part of antioxidant, 0.05-0.1 part of humectant and 4-9 parts of colorant. The components are reasonably matched, and the optimal performance of the lipstick is ensured.
Further, the emollients include isononyl isononanoate, diisostearyl malate, cetyl ethylhexanoate, polyglyceryl-2 isostearate/dimerized linoleate copolymer, cholesterol/lanosterol mixed ester of C10-30 acids, meadowfoam seed oil and tocopherols.
Isononyl isononanoate can make lipstick easier to be smeared, and can moisten skin without greasy feeling; the diisostearyl malate has the advantages of moistening and lasting performance and good pigment dispersibility; the cetyl ethylhexanoate can moisten and soften skin, is not sticky, has excellent waterproof performance and good air permeability and spreadability; the polyglycerol-2 isostearate/dilinoleate copolymer has good moisturizing effect, can endow lipstick with better luster and glittering effect, is full and plump, can also ensure good pigment dispersibility, keeps good adhesiveness and achieves excellent and lasting effect; tocopherol, moisture retention, oxidation resistance and high safety coefficient.
Further, the emollient comprises, in parts by weight in the lipstick: 8-12 parts of isononyl isononanoate, 6-12 parts of diisostearyl malate, 6-10 parts of cetyl ethyl hexanoate, 1-3 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1-3 parts of C10-30 cholesterol/lanosterol mixed ester, 0.5-2 parts of white pond flower seed oil and 0.1-0.5 part of tocopherol. The components and the dosage of the emollient are reasonably matched, so that the emollient can nourish and lubricate the skin of lips, does not generate greasy and sticky feeling, and avoids discomfort.
Further, the thickening agent includes synthetic waxes and microcrystalline waxes; the filler comprises silica, polymethylsilsesquioxane and mica; the antioxidant comprises pentaerythritol tetrakis (bis-tert-butyl hydroxyhydrocinnamate); the humectant comprises 1, 2-hexanediol; the colorant includes toner.
The synthetic wax can improve the texture and luster of the lipstick; microcrystalline wax can increase the fullness of the lipstick. Silica has slight reverie power, and can increase skin smoothness; mica can enhance the glittering visual effect of lipstick. Pentaerythritol tetra (di-tert-butyl hydroxyhydrocinnamate) ester can eliminate free radicals, has antioxidant effect, and can prevent aging. The 1, 2-hexanediol is small molecular alcohol, and has a good moisturizing effect.
Further, the thickener comprises 5-10 parts of synthetic wax and 4-9 parts of microcrystalline wax by weight in the lipstick; the filler comprises 2-4 parts of silica, 1-3 parts of polymethylsilsesquioxane and 1-3 parts of mica; the antioxidant comprises 0.05-0.1 part of pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester; the humectant comprises 0.05-0.1 part of 1, 2-hexanediol; the colorant comprises 4-9 parts of toner.
Further, the coating comprises the following components in parts by weight:
solvent: 10-20 parts of isododecane;
film-forming agent: 6-15 parts of hydrogenated (styrene/methyl styrene/indene) copolymer;
and (3) an emollient: 8-12 parts of isononyl isononanoate, 6-12 parts of diisostearyl malate, 6-10 parts of cetyl ethyl hexanoate, 1-3 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1-3 parts of C10-30 cholesterol/lanosterol mixed ester, 0.5-2 parts of white pond flower seed oil and 0.1-0.5 part of tocopherol;
thickening agent: 5-10 parts of synthetic wax and 4-9 parts of microcrystalline wax;
filling agent: 2-4 parts of silica, 1-3 parts of polymethylsilsesquioxane and 1-3 parts of mica;
antioxidant: pentaerythritol tetra (di-tert-butyl hydroxyhydrocinnamate) 0.05-0.1 part;
humectant: 0.05-0.1 part of 1, 2-hexanediol;
colorant: 4-9 parts of toner.
Further, the coating comprises the following components in parts by weight:
solvent: 12-18 parts of isododecane;
film-forming agent: 8-12 parts of hydrogenated (styrene/methyl styrene/indene) copolymer;
and (3) an emollient: 9-10 parts of isononyl isononanoate, 8-10 parts of diisostearyl malate, 7-9 parts of cetyl ethylhexanoate, 1.5-2.5 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1.5-2.5 parts of C10-30 cholesterol/lanosterol mixed ester, 1-1.5 parts of white pond flower seed oil and 0.2-0.4 part of tocopherol;
thickening agent: 6-9 parts of synthetic wax and 5-8 parts of microcrystalline wax;
filling agent: 2.5-3.5 parts of silica, 1.5-2.5 parts of polymethylsilsesquioxane and 1.5-2.5 parts of mica;
antioxidant: pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester 0.07-0.09 part;
humectant: 0.07-0.09 part of 1, 2-hexanediol;
colorant: 5-8 parts of toner.
The second purpose of the invention is realized by adopting the following technical scheme:
a preparation method of a long-acting moist lipstick for long-lasting make-up comprises the following steps: mixing the colorant with part of the emollient, grinding, and stirring uniformly to form color paste; then mixing the solvent, the film forming agent, the thickening agent, the filler, the antioxidant, the humectant and the other part of the emollient with the formula ratio, heating, stirring uniformly, then adding the color paste, and mixing uniformly to obtain the finished product.
Compared with the prior art, the invention has the beneficial effects that:
(1) according to the long-acting moisturizing type lipstick for long-lasting makeup, the hydrogenated (styrene/methyl styrene/indene) copolymer can provide a tough protective film in an oil wax system, isododecane is used as a solvent, the lipstick is coated on the lips, after the isododecane volatilizes, the toner can be more durable on the lips under the protection of the film forming agent, and the C10-30 cholesterol/lanosterol mixed ester and other oil can provide excellent moistening degree, so that the lips are not too dry. In addition, the proportion of the key components in the lipstick is reasonably controlled, so that the lipstick is easy to smear and difficult to remove makeup, is comfortable and not tight after use, is moist and moisturized, and is beautiful and full.
(2) The preparation method of the long-acting make-up-holding moisturizing lipstick provided by the invention is simple in process and convenient to operate.
Detailed Description
The present invention is further described below with reference to specific embodiments, and it should be noted that, without conflict, any combination between the embodiments or technical features described below may form a new embodiment. The raw materials, equipments and the like used in the following examples are commercially available unless otherwise specified.
Examples 1 to 5
A long-acting moist lipstick for long-lasting make-up is prepared from a solvent, a film-forming agent, an emollient, a thickening agent, a filler, an antioxidant, a humectant and a colorant: the solvent is isododecane; the film-forming agent is a hydrogenated (styrene/methylstyrene/indene) copolymer; the emollient is isononyl isononanoate, diisostearyl malate, cetyl ethylhexanoate, polyglyceryl-2 isostearate/dilinoleate copolymer, C10-30 cholesterol/lanosterol mixed ester, white chinlon oil and tocopherol; the thickening agent is synthetic wax and microcrystalline wax; the filler is silica, polymethylsilsesquioxane and mica; the antioxidant is pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester; the humectant is 1, 2-hexanediol; the colorant is toner. The specific formulation is shown in table 1 below.
Table 1 formulations of examples 1-5
Figure BDA0003505747010000061
Figure BDA0003505747010000071
The long-lasting moisturizing lipsticks of examples 1-5 were prepared as follows: mixing the colorant with the emollient diisostearyl malate, grinding, and stirring to obtain color paste; then mixing the solvent, the film forming agent, the thickening agent, the filler, the antioxidant, the humectant and the rest of the emollient agent according to the formula ratio, heating, stirring uniformly, then adding the color paste, and mixing uniformly to obtain the finished product.
Comparative example 1
Comparative example 1 differs from example 1 in that: the solvent isododecane was replaced with dipropylene glycol. The rest is the same as in example 1.
Comparative example 2
Comparative example 2 differs from example 1 in that: the film former was replaced by a hydrogenated (styrene/methylstyrene/indene) copolymer, which was replaced by trimethylsiloxysilicate. The rest is the same as in example 1.
Comparative example 3
Comparative example 3 differs from example 1 in that: the C10-30 acid cholesterol/lanosterol mixed ester was omitted and the procedure was as in example 1.
Comparative example 4
Comparative example 4 differs from example 1 in that: the meadowfoam seed oil was omitted and the rest was the same as in example 1.
Comparative example 5
Comparative example 4 differs from example 1 in that: the polymethylsilsesquioxane was omitted and the rest was the same as in example 1.
Comparative example 6
Comparative example 6 differs from example 1 in that: the same procedure as in example 1 was repeated except that 25 parts of isododecane and 18 parts of hydrogenated (styrene/methylstyrene/indene) copolymer were used.
Comparative example 7
Comparative example 7 differs from example 1 in that: the same procedure as in example 1 was repeated except that the amount of C10-30 acid cholesterol/lanosterol mixed ester was adjusted to 4 parts and the amount of Poissa japonica seed oil was adjusted to 3 parts.
Comparative example 8
Comparative example 8 differs from example 1 in that: the amount of polymethylsilsesquioxane was adjusted to 5 parts, and the rest was the same as in example 1.
Comparative example 9
Taking example 1 in patent moisturizing and lasting lipstick (application number CN202110403523.0) as a comparative example, the moisturizing and lasting lipstick comprises the following components in parts by weight: 1 part of microcrystalline wax, 12 parts of bis-behenyl alcohol/isostearyl alcohol/phytosterol dioleyl alcohol dilinoleate, 2 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 14 parts of diisostearyl malate, 11.12 parts of dipentaerythritol tri-polyhydroxystearate, 3 parts of hydrogenated (styrene/methylstyrene/indene) copolymer, 0.3 part of dipalmitoyl hydroxyproline, 0.5 part of olive oil unsaponifiable matter, 0.3 part of humectant, thickener, emollient, antioxidant, skin conditioner, colorant and preservative; the humectant consists of the following components: the weight ratio of the sodium hyaluronate to the castor oil to the hydrogenated castor oil is as follows: castor oil: hydrogenated castor oil 6:11: 1; the thickener comprises the following components in parts by weight: 2.5 parts of synthetic wax, 1 part of candelilla wax, 2 parts of ethylene/acrylic acid copolymer and 2.5 parts of beeswax; the emollient comprises the following components in parts by weight: 8 parts of polyglycerol-2 triisostearate, 4 parts of cetyl polydimethylsiloxane, 3 parts of 2-ethylhexanoic acid glyceride, 15 parts of tridecyl alcohol trimellitate and 0.2 part of glycerol caprylate; the antioxidant is pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester 0.1 weight part; the skin conditioner comprises the following components in parts by weight: 0.08 part of o-cymene-5-alcohol, 0.2 part of bisabolol and 0.1 part of tocopherol acetate; the colorant comprises the following components in parts by weight: 3.6 parts of a colorant A, 6.5 parts of a colorant B and 1.8 parts of a colorant C, wherein the colorant A comprises the following components: CI77120, CI15850 and rosin, wherein the weight ratio of CI77120 to CI15850 to rosin is CI 77120: CI 15850: rosin is 55:38: 7; the colorant B consists of CI15985 and aluminum hydroxide, and the weight ratio of CI15985 to aluminum hydroxide is CI 15985: aluminum hydroxide 9: 17; colorant C is CI 77891; 0.2 part of preservative, wherein the preservative consists of phenoxyethanol and ethylhexyl glycerol. The preparation method is consistent with that described in the patent.
Effect verification
The lipstick of the embodiment and the comparative example of the invention is subjected to efficacy verification according to an experimental method of a moistening and lasting lipstick (application number CN202110403523.0), and mainly comprises the following steps: sensory evaluation, wiping condition evaluation and moisturizing effect evaluation.
1. Sensory evaluation
70 female volunteers with healthy lip skin were selected, aged 25-28 years, and each sample was subjected to a usage test in 5 volunteers. The using method comprises the following steps: each volunteer respectively coats the test sample on the lips, tries the test sample once a day, evaluates the test sample after one week, scores the moistening degree, the smearing property, the persistence degree, the plumpness and the comfort, the score range is 1-10 points, the higher the score is, the better the evaluation is, totals the total score of each sample of evaluators, calculates the average value of the total score, and records the average value in the table 2.
The test indexes are defined as follows:
moistening degree: moistening and moisturizing, covering dry lines of lips, improving the water content of the lips, and keeping the lips from drying;
coating property: the coating is easy to spread and extend, and the coloring is uniform;
the persistence degree is as follows: the color is not easy to fade, and the maintenance effect is good;
fullness degree: the glossiness is good, and the product is full and beautiful;
comfort: is not greasy, sticky, dry and tight.
TABLE 2 sensory test results recording sheet
Group of Moistening degree Spreadability Durability Degree of fullness Comfort level
Example 1 9.6 9.3 9.4 9.0 9.3
Example 2 9.4 9.0 9.1 9.2 9.2
Example 3 9.0 8.9 9.1 9.1 9.1
Example 4 9.5 9.2 9.0 9.2 9.3
Example 5 9.3 9.1 9.3 9.1 9.2
Comparative example 1 9.6 8.4 9.0 8.9 8.5
Comparative example 2 9.0 8.9 8.3 8.4 8.0
Comparative example 3 8.5 9.0 8.6 8.3 8.4
Comparative example 4 8.4 8.7 8.9 8.2 8.8
Comparative example 5 8.3 8.0 8.3 7.5 8.2
Comparative example 6 8.2 8.0 8.2 8.4 8.6
Comparative example 7 8.4 8.6 8.3 8.5 8.3
Comparative example 8 8.5 8.3 7.8 8.0 8.0
Comparative example 9 8.2 8.5 8.2 7.1 8.6
Comparative example 1 the solvent was replaced with dipropylene glycol, and the moisturizing effect of lipstick remained high, but spreadability, fullness and comfort were all reduced, and the feedback of volunteers was somewhat sticky.
Comparative example 2 replacement of the film former with trimethylsiloxysilicate severely affected the durability, fullness and comfort of the lipstick.
Comparative example 3 omitting the C10-30 acid cholesterol/lanosterol mixed ester, the moistness, persistence, fullness and comfort were greatly affected.
Comparative example 4 in which the meadowfoam seed oil was omitted, the wettability and plumpness were much reduced.
Comparative example 5 omitting the polymethylsilsesquioxane, without the polymethylsilsesquioxane in combination with the hydrogenated (styrene/methylstyrene/indene) copolymer, the moistness, spreadability, durability, fullness and comfort of the lipstick were greatly affected.
Comparative example 6 adjusting the amount of isododecane to 25 parts and the amount of hydrogenated (styrene/methylstyrene/indene) copolymer to 18 parts reduced the wettability, spreadability, durability, fullness and comfort.
Comparative example 7 the amount of C10-30 acid cholesterol/lanosterol mixed ester was adjusted to 4 parts, the amount of Poissa alba seed oil was adjusted to 3 parts, and the moisturizing degree, spreadability, durability, plumpness and comfort were all reduced.
Comparative example 8 the amount of polymethylsilsesquioxane was adjusted to 5 parts, and the wettability, spreadability, durability, fullness and comfort were all reduced.
Comparative example 9 uses a prior art formulation with less moisturization, spreadability, durability, fullness, and comfort than the inventive examples.
Thus, in the examples of the present invention, isododecane is used as a solvent, and a hydrogenated (styrene/methylstyrene/indene) copolymer is used as a film-forming agent; the emollient comprises C10-30 acid cholesterol/lanosterol mixed ester and white chinlon oil; the filling agent comprises polymethylsilsesquioxane, the proportion of isododecane, hydrogenated (styrene/methyl styrene/indene) copolymer, C10-30 acid cholesterol/lanosterol mixed ester, chinaroot greenbrier seed oil and polymethylsilsesquioxane in lipstick is reasonably controlled, the whole formula is reasonably matched to form a stable system, and the lipstick is easy to coat, difficult to decolor, full in gloss, moist and moisture-retaining, not greasy and not tight, and is a lipstick product with better performance.
2. Evaluation of wiping Condition
3 female volunteers with healthy skin were selected, each volunteer tested on the lipstick samples of the examples and comparative examples, the lipstick samples were applied to the inside of the arm, left to stand for 5 minutes, wiped with a cosmetic cotton until completely wiped off, the number of wiping completely wiped off was recorded, each lipstick sample was tested 3 times repeatedly, and finally an average of 9 total times was taken for each sample of 3 volunteers. The results of the experiment are shown in table 3 below.
Table 3 wiping results table
Group of Number of times of wiping Group of Number of times of wiping Group of Number of times of wiping
Example 1 9 Comparative example 1 7 Comparative example 6 7
Example 2 8 Comparative example 2 6 Comparative example 7 7
Example 3 8 Comparative example 3 7 Comparative example 8 7
Example 4 9 Comparative example 4 7 Comparative example 9 6
Example 5 8 Comparative example 5 7
As can be seen from table 3, the number of wiping times in the examples of the present invention is more, which indicates that the lipstick provided by the examples of the present invention has longer durability and is not easy to discolor after being made up.
3. Evaluation of moisturizing Effect
Selecting 70 female volunteers with healthy lip skin, wherein the age is 25-28 years old, each sample corresponds to 5 volunteers for use and test, smearing lipstick samples on the volunteers once a day, testing the water content of the lip skin after 10 days, and measuring the water content of the outer layer of the cuticle membrane by using a skin moisture tester. The results for each sample were averaged over 5 volunteers and the results are shown in table 4 below.
Table 4 moisture retention results table
Figure BDA0003505747010000121
Figure BDA0003505747010000131
As can be seen from the record in table 4, the lipstick provided in the example of the present invention can increase the moisture content of the skin of the lips to a greater extent than the lipstick sample of the comparative example, which indicates that the lipstick provided in the example of the present invention has a better moisturizing effect.
The above embodiments are only preferred embodiments of the present invention, and the protection scope of the present invention is not limited thereby, and any insubstantial changes and substitutions made by those skilled in the art based on the present invention are within the protection scope of the present invention.

Claims (10)

1. A long-acting moist lipstick for long-lasting make-up is characterized by comprising a solvent, a film forming agent, an emollient, a thickening agent, a filler, an antioxidant, a humectant and a colorant; the solvent comprises isododecane accounting for 10-20% of the lipstick by weight; the film forming agent comprises hydrogenated (styrene/methyl styrene/indene) copolymer which accounts for 6-15 percent of the weight of the lipstick; the emollient comprises C10-30 acid cholesterol/lanosterol mixed ester accounting for 1-3 percent of the lipstick by weight and chinaroot greenbrier seed oil accounting for 0.5-2 percent of the lipstick by weight; the filling agent comprises polymethylsilsesquioxane accounting for 1-3% of the lipstick by weight.
2. The long-lasting moisturizing lipstick according to claim 1, comprising the following components in parts by weight: 10-20 parts of solvent, 6-15 parts of film forming agent, 20-45 parts of emollient, 9-20 parts of thickening agent, 4-10 parts of filler, 0.05-0.1 part of antioxidant, 0.05-0.1 part of humectant and 4-9 parts of colorant.
3. The long-lasting makeup-sustaining emollient lipstick according to claim 1, wherein said emollient comprises isononyl isononanoate, diisostearyl malate, cetyl ethylhexanoate, polyglyceryl-2 isostearate/dilinoleate copolymer, cholesterol/lanosterol mixed ester C10-30, meadowfoam seed oil and tocopherol.
4. The long-lasting makeup-retaining moisturizing lipstick according to claim 3, wherein said emollient comprises, in parts by weight in said lipstick: 8-12 parts of isononyl isononanoate, 6-12 parts of diisostearyl malate, 6-10 parts of cetyl ethyl hexanoate, 1-3 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1-3 parts of C10-30 cholesterol/lanosterol mixed ester, 0.5-2 parts of white pond flower seed oil and 0.1-0.5 part of tocopherol.
5. The long-lasting moisturizing lipstick according to claim 1, wherein said thickening agent comprises synthetic wax and microcrystalline wax; the filler comprises silica, polymethylsilsesquioxane and mica; the antioxidant comprises pentaerythritol tetrakis (bis-tert-butyl hydroxyhydrocinnamate); the humectant comprises 1, 2-hexanediol; the colorant includes toner.
6. The long-lasting moisturizing lipstick according to claim 5, wherein said thickener comprises 5-10 parts by weight of synthetic wax and 4-9 parts by weight of microcrystalline wax; the filler comprises 2-4 parts of silica, 1-3 parts of polymethylsilsesquioxane and 1-3 parts of mica; the antioxidant comprises 0.05-0.1 part of pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester; the humectant comprises 0.05-0.1 part of 1, 2-hexanediol; the colorant comprises 4-9 parts of toner.
7. The long-lasting moisturizing lipstick according to claim 1, comprising the following components in parts by weight:
solvent: 10-20 parts of isododecane;
film-forming agent: 6-15 parts of hydrogenated (styrene/methyl styrene/indene) copolymer;
and (3) an emollient: 8-12 parts of isononyl isononanoate, 6-12 parts of diisostearyl malate, 6-10 parts of cetyl ethyl hexanoate, 1-3 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1-3 parts of C10-30 cholesterol/lanosterol mixed ester, 0.5-2 parts of white pond flower seed oil and 0.1-0.5 part of tocopherol;
thickening agent: 5-10 parts of synthetic wax and 4-9 parts of microcrystalline wax;
filling agent: 2-4 parts of silica, 1-3 parts of polymethylsilsesquioxane and 1-3 parts of mica;
antioxidant: pentaerythritol tetra (di-tert-butyl hydroxyhydrocinnamate) 0.05-0.1 part;
humectant: 0.05-0.1 part of 1, 2-hexanediol;
colorant: 4-9 parts of toner.
8. The long-lasting moisturizing lipstick according to claim 1, comprising the following components in parts by weight:
solvent: 12-18 parts of isododecane;
film-forming agent: 8-12 parts of hydrogenated (styrene/methyl styrene/indene) copolymer;
and (3) an emollient: 9-10 parts of isononyl isononanoate, 8-10 parts of diisostearyl malate, 7-9 parts of cetyl ethylhexanoate, 1.5-2.5 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 1.5-2.5 parts of C10-30 cholesterol/lanosterol mixed ester, 1-1.5 parts of white pond flower seed oil and 0.2-0.4 part of tocopherol;
thickening agent: 6-9 parts of synthetic wax and 5-8 parts of microcrystalline wax;
filling agent: 2.5-3.5 parts of silica, 1.5-2.5 parts of polymethylsilsesquioxane and 1.5-2.5 parts of mica;
antioxidant: pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamic acid) ester 0.07-0.09 part;
humectant: 0.07-0.09 part of 1, 2-hexanediol;
colorant: 5-8 parts of toner.
9. The long-lasting moisturizing lipstick according to claim 1, comprising the following components in parts by weight:
solvent: 15 parts of isododecane;
film-forming agent: 10 parts of hydrogenated (styrene/methylstyrene/indene) copolymer;
and (3) an emollient: 10 parts of isononyl isononanoate, 9 parts of diisostearyl malate, 8 parts of cetyl ethyl hexanoate, 2 parts of polyglycerol-2 isostearate/dilinoleate copolymer, 2 parts of C10-30 cholesterol/lanosterol mixed ester, 1.2 parts of white chingma seed oil and 0.3 part of tocopherol;
thickening agent: 7 parts of synthetic wax and 6 parts of microcrystalline wax;
filling agent: 3 parts of silica, 2 parts of polymethylsilsesquioxane and 2 parts of mica;
antioxidant: pentaerythritol tetrakis (bis-tert-butylhydroxyhydrocinnamate) 0.08 parts;
humectant: 0.08 part of 1, 2-hexanediol;
colorant: 6 parts of toner.
10. A method for preparing the long-lasting makeup moisturizing lipstick according to any one of claims 1-9, comprising the steps of: mixing the colorant with part of the emollient, grinding, and stirring uniformly to form color paste; then mixing the solvent, the film forming agent, the thickening agent, the filler, the antioxidant, the humectant and the other part of the emollient with the formula ratio, heating, stirring uniformly, then adding the color paste, and mixing uniformly to obtain the finished product.
CN202210138969.XA 2022-02-15 2022-02-15 Long-acting moisture lipstick for makeup and preparation method thereof Pending CN114469785A (en)

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