CN114410394A - Efficient oil stain cleaning preparation and preparation method thereof - Google Patents
Efficient oil stain cleaning preparation and preparation method thereof Download PDFInfo
- Publication number
- CN114410394A CN114410394A CN202210155150.4A CN202210155150A CN114410394A CN 114410394 A CN114410394 A CN 114410394A CN 202210155150 A CN202210155150 A CN 202210155150A CN 114410394 A CN114410394 A CN 114410394A
- Authority
- CN
- China
- Prior art keywords
- parts
- tea saponin
- oil stain
- cleaning agent
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 45
- 238000004140 cleaning Methods 0.000 title claims abstract description 17
- 241001122767 Theaceae Species 0.000 claims abstract description 78
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 78
- 229930182490 saponin Natural products 0.000 claims abstract description 78
- 150000007949 saponins Chemical class 0.000 claims abstract description 78
- 239000012459 cleaning agent Substances 0.000 claims abstract description 63
- 229920005552 sodium lignosulfonate Polymers 0.000 claims abstract description 28
- 239000004367 Lipase Substances 0.000 claims abstract description 27
- 102000004882 Lipase Human genes 0.000 claims abstract description 27
- 108090001060 Lipase Proteins 0.000 claims abstract description 27
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 27
- 235000019421 lipase Nutrition 0.000 claims abstract description 27
- 239000001509 sodium citrate Substances 0.000 claims abstract description 27
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 27
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 26
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001488 sodium phosphate Substances 0.000 claims description 27
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 27
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 27
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 27
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 21
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 17
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 14
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 14
- 239000011347 resin Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003729 cation exchange resin Substances 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000003480 eluent Substances 0.000 claims description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 6
- 239000007938 effervescent tablet Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000001179 sorption measurement Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003921 oil Substances 0.000 description 64
- 235000019198 oils Nutrition 0.000 description 64
- 238000012360 testing method Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000003385 bacteriostatic effect Effects 0.000 description 7
- 239000003599 detergent Substances 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- -1 alkyl ether ester Chemical class 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 235000013736 caramel Nutrition 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000010699 lard oil Substances 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002953 phosphate buffered saline Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000008223 sterile water Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000012809 post-inoculation Methods 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C11D2111/14—
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/204—Keeping clear the surface of open water from oil spills
Abstract
The invention belongs to the technical field of cleaning, and particularly relates to a high-efficiency oil stain cleaning preparation and a preparation method thereof. The efficient oil stain cleaning agent comprises the following components: sodium citrate, sodium lignosulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine and tea saponin. Safe and environment-friendly, is easy to store and transport, and has better effect of removing oil stains.
Description
Technical Field
The invention belongs to the technical field of cleaning, and particularly relates to a high-efficiency oil stain cleaning preparation and a preparation method thereof.
Background
In life, people can wash oil stains, which is a problem that people feel headache, and if the oil stains are not cleaned, the physical and mental health of people is affected. The residual oil stain is generally difficult to clean, the general detergent is difficult to completely clean, the residual detergent is difficult to clean, and some detergents are easy to damage the skin of a user due to frequent use because of containing a large amount of harmful chemical components.
Especially in household kitchens, public dining halls and in the oil industry, where the walls, pipes, windows, cooking fume extractors and various appliances are heavily contaminated by oil smoke. Greasy dirt removal from these metal surfaces is particularly difficult. In the prior art, various oil stain cleaning agents exist, for example, Chinese patent application CN104178373A discloses a kitchen oil stain cleaning agent which is composed of the following raw materials in percentage by weight: 8-10% of alkyl ether ester, 2-3% of dodecyl propyl betaine, 7-9% of fatty alcohol-polyoxyethylene ether, 2-3% of sodium alkyl benzene sulfonate, 1.5-2% of urea, 0.04-0.06% of essence, 1-1.3% of sodium carbonate, 1.2-1.4% of sodium propionate, 1-1.2% of surfactant and deionized water to 100 percent.
Chinese patent application CN 105596231A discloses a domestic oil stain cleaning agent, which comprises the following components in parts by weight: 2-4 parts of potassium chlorate, 1-3 parts of sodium silicate, 3-5 parts of soap lye, 5-9 parts of hydrogen peroxide, 2-6 parts of alkyl glycoside, 2-5 parts of linalyl acetate, 6-8 parts of surfactant, 6-12 parts of biological degerming agent and 22-36 parts of distilled water.
Although the prior art mostly claims to effectively clean heavy oil pollution, the prior cleaning agent has the disadvantages of unclean cleaning, time consumption, labor consumption and high cleaning cost. Meanwhile, most of the oil stain cleaning agents contain organic solvents, sodium hydroxide and the like, so that great potential safety hazards exist in the using and transporting processes, and the transporting cost is greatly increased.
The invention aims to research an efficient oil stain cleaning agent which is safe, environment-friendly, easy to store and transport and has good oil stain removing and bacteriostatic effects.
Disclosure of Invention
In order to overcome the technical problems, the invention provides an efficient oil stain cleaning agent and a preparation method thereof. Safe and environment-friendly, is easy to store and transport, and has better effects of removing oil stains and inhibiting bacteria.
In order to achieve the above purpose, the technical scheme provided by the invention is as follows:
an efficient oil stain cleaning agent comprises the following components: sodium citrate, sodium lignosulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate (complexing agent) and tea saponin.
Preferably, the oil stain cleaning agent comprises the following components in parts by weight:
0.5-3 parts of sodium citrate, 0.5-5 parts of sodium lignosulfonate, 0.1-2 parts of lipase, 1-10 parts of sodium dodecyl sulfate, 1-5 parts of lauric monoglyceride, 0.1-8 parts of cocamidopropyl betaine, 1-10 parts of trisodium phosphate and 0.1-3 parts of tea saponin.
Preferably, the oil stain cleaning agent comprises the following components in parts by weight:
0.5-1 part of sodium citrate, 0.5-1 part of sodium lignosulfonate, 0.1-0.5 part of lipase, 5-10 parts of sodium dodecyl sulfate, 1-2 parts of lauric monoglyceride, 0.1-3 parts of cocamidopropyl betaine, 1-5 parts of trisodium phosphate and 0.1-0.5 part of tea saponin.
Preferably, the tea saponin is modified tea saponin, and the preparation method of the modified tea saponin comprises the following steps:
(1) dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction;
(2) and (2) adding sodium bisulfite into the product obtained in the step (1) for reaction to obtain a product, namely the modified tea saponin.
Preferably, in the step (1), the molar ratio of the tea saponin to the maleic anhydride is 1: 1-5.
Preferably, in step (1), the reaction is treated with a cation exchange resin.
Preferably, the cation exchange resin is a 732 type cation exchange resin.
Preferably, in step (1), the temperature of the reaction is 60-80 ℃.
Preferably, in the step (1), the reaction time is 10-16 h.
Preferably, in the step (2), the molar ratio of the sodium bisulfite to the tea saponin is 3-6: 1.
preferably, in step (2), the temperature of the reaction is 70-90 ℃.
Preferably, the product in the step (2) is subjected to adsorption treatment by macroporous resin.
Preferably, the macroporous resin is an AB-8 type or D101 type macroporous resin.
Preferably, after the macroporous resin is adsorbed, 60-90 wt% of ethanol water solution is used for elution, and the eluent is dried under reduced pressure to obtain the purified modified tea saponin.
The invention also aims to provide a preparation method of the efficient oil stain cleaning agent, which comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and tea saponin or modified tea saponin to obtain the efficient oil stain cleaning agent.
The invention also aims to provide a cleaning preparation containing the efficient oil stain cleaning agent, and the cleaning preparation is a powder preparation, a liquid preparation or a solid effervescent tablet.
The invention also aims to provide a preparation method of the cleaning preparation of the efficient oil stain cleaning agent, which comprises the following steps: adding solvent into the high-efficiency oil stain cleaning agent to prepare a liquid preparation, or adding or not adding auxiliary materials to prepare a powder preparation or a solid effervescent tablet.
Compared with the prior art, the invention has the technical advantages that:
(1) the efficient oil stain cleaning agent provided by the invention is safe and environment-friendly, is easy to store and transport, and has good oil stain removing and bacteriostatic effects.
(2) The oil stain cleaning agent provided by the invention uses sodium lignosulfonate and tea saponin (or modified tea saponin), has a good synergistic effect with other components, can effectively promote the cleaning efficiency of oil stains, and has a good hard water stabilizing effect.
(3) The modified tea saponin is preferably used in the invention, and can remove oil stains more efficiently after interaction with other components. Meanwhile, the cation exchange resin and the macroporous resin are used in the preparation process of the modified tea saponin, so that the reaction efficiency of the tea saponin and the maleic anhydride can be promoted, the purification effect of the modified tea saponin can be improved, and the cleaning effect of the modified tea saponin on oil stains after the modified tea saponin reacts with other components in an oil stain cleaning agent is improved.
Detailed Description
The present invention will be described below with reference to specific examples to make the technical aspects of the present invention easier to understand and grasp, but the present invention is not limited thereto. The experimental methods described in the following examples are all conventional methods unless otherwise specified; the reagents and materials are commercially available, unless otherwise specified.
Example 1
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) taking the molar ratio of 1: 3, dissolving the tea saponin and maleic anhydride in N, N-dimethylformamide to react for 12 hours at the temperature of 70 ℃, and treating by 732 type cation exchange resin in the reaction process;
(2) and (2) adding sodium bisulfite (the molar ratio of the sodium bisulfite to the tea saponin is 4: 1) into the product obtained in the step (1), reacting at 80 ℃, adsorbing the prepared product by AB-8 type macroporous resin, eluting by using 80 wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 2
The efficient oil stain cleaning agent comprises the following components in parts by weight:
0.5 part of sodium citrate, 0.5 part of sodium lignosulfonate, 0.1 part of lipase, 1 part of sodium dodecyl sulfate, 5 parts of lauric monoglyceride, 0.1 part of cocamidopropyl betaine, 10 parts of trisodium phosphate and 0.1 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) taking the molar ratio of 1: dissolving tea saponin and maleic anhydride of 1 in N, N-dimethylformamide for reaction for 10h at 80 deg.C, and treating with 732 type cation exchange resin during the reaction;
(2) and (2) adding sodium bisulfite (the molar ratio of the sodium bisulfite to the tea saponin is 3: 1) into the product obtained in the step (1), reacting at 70 ℃, adsorbing the prepared product by using D101 type macroporous resin, eluting by using 60 wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 3
The efficient oil stain cleaning agent comprises the following components in parts by weight:
3 parts of sodium citrate, 5 parts of sodium lignosulfonate, 2 parts of lipase, 10 parts of sodium dodecyl sulfate, 1 part of lauric monoglyceride, 8 parts of cocamidopropyl betaine, 1 part of trisodium phosphate and 3 parts of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) taking the molar ratio of 1: 5, dissolving the tea saponin and maleic anhydride in N, N-dimethylformamide to react for 16h at the temperature of 60 ℃, and treating by 732 type cation exchange resin in the reaction process;
(2) and (2) adding sodium bisulfite (the molar ratio of the sodium bisulfite to the tea saponin is 6: 1) into the product obtained in the step (1), reacting at 90 ℃, adsorbing the prepared product by AB-8 type macroporous resin, eluting by using 90 wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 4
The difference from example 1 lies in the preparation method of tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) taking the molar ratio of 1: 3, dissolving the tea saponin and the maleic anhydride in N, N-dimethylformamide to react for 12 hours at the reaction temperature of 70 ℃;
(2) and (2) adding sodium bisulfite (the molar ratio of the sodium bisulfite to the tea saponin is 4: 1) into the product obtained in the step (1), reacting at 80 ℃, adsorbing the prepared product by AB-8 type macroporous resin, eluting by using 80 wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 5
The difference from the example 4 lies in the preparation method of the tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) taking the molar ratio of 1: 3, dissolving the tea saponin and the maleic anhydride in N, N-dimethylformamide to react for 12 hours at the reaction temperature of 70 ℃;
(2) and (2) adding sodium bisulfite (the molar ratio of the sodium bisulfite to the tea saponin is 4: 1) into the product obtained in the step (1), reacting at 80 ℃, and drying the obtained product to obtain the purified modified tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 6
Compared with example 1, tea saponin was used directly without modification.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of tea saponin.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric monoglyceride, cocamidopropyl betaine, trisodium phosphate and tea saponin to obtain the efficient oil stain cleaning agent.
Comparative example 1
Compared with example 1, the difference is in the components; the sodium lignosulfonate is replaced by the modified tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 1.5 parts of modified tea saponin.
The preparation method of the modified tea saponin is the same as that of the embodiment 1.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Comparative example 2
Compared with example 1, the difference is in the components; sodium lignosulfonate is used for replacing modified tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1.5 parts of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 3 parts of cocamidopropyl betaine and 5 parts of trisodium phosphate.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine and trisodium phosphate to obtain the efficient oil stain cleaning agent.
Comparative example 3
Compared with example 1, the difference is in the components; trisodium phosphate was used in place of cocamidopropyl betaine.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignosulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric monoglyceride, 8 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin is the same as that of the embodiment 1.
The preparation method of the high-efficiency oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, monolaurin, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
1. Degreasing effect test
The detergency was tested according to the description of "QB/T4348-2012 detergent for kitchen greasy dirt".
Preparing dirt: the formula is as follows: 64g of soybean oil, 8g of ammonia-free caramel pigment, 12g of wheat flour, 8g of lard oil and 2.4g of glyceryl monostearate. Weighing soybean oil, lard oil and glycerin monostearate in a 250ml plastic beaker, and heating and dissolving in water bath at 50 ℃; cooling to 30 deg.C under stirring, adding ammonia-free caramel pigment, stirring at a speed of not less than 1000r/min for 30min, emulsifying, adding wheat flour, stirring for 10min, aging for 24 hr, placing in refrigerator, and recovering to 20-25 deg.C when in use.
Preparation of dirty pieces: selecting a clean test piece (the model of the test piece is 1Cr18Ni9Ti, wire drawing stainless steel); drying in an oven at 120 deg.C for 1h, cooling for 30min, weighing to 0.0002g0. Smearing with a smear area of 35mm × 100mm and a smear amount of 0.01g/cm2. Then placing on a dried porcelain plate, drying at a high temperature of 200 ℃ for 10min, and then placing in an ultraviolet constant-temperature ageing oven at a temperature of 45 ℃ for ultraviolet irradiation for 1.5 h. Adjusting the irradiation position, irradiating for 1.5h again, taking out, and placing in a dryer for aging for 24 h. Then the oil stain-fixed test piece is weighed (weighed to 0.0002g) and is counted as m1。
Carrying out ultrasonic treatment on a cleaning agent to be detected at 35 ℃ for 30min, then hanging the smeared test piece in a cleaning agent beaker which is ultrasonically mixed in advance, completely soaking for 10min, and then cleaning for 5 min; the sample beakers were then rinsed, 210mL of water each poured, and rinsed for 30S. Taking off the test piece, drying the cleaned test piece in a 120 deg.C oven for 45min, cooling in a drier for 30min, and weighing (weighing to 0.0002g) to obtain m2And calculating the detergency. The results are shown in Table 1 below.
The detergency is the mass fraction of the removed oil f, and is calculated according to the following formula: f ═ m1-m2)/(m1-m0)×100％
Wherein m is0Is the mass of the test piece, m1M is the mass of the smear before washing2The quality of the soiled sheet after washing.
According to the method, the high-efficiency oil stain cleaning agents prepared in the examples 1-6 and the comparative examples 1-3 are respectively added into water to respectively prepare cleaning solutions with effective content of 15% as samples to be detected; the detergency test was carried out.
2. Bacteriostatic effect
And (4) evaluating the retention and bacteriostasis effect by referring to an evaluation method of antibacterial and bacteriostasis effects of QB/T2738 and 2012 daily chemical products.
Respectively adding the high-efficiency oil stain cleaning agents prepared in the examples 1-6 and the comparative examples 1-3 into water to respectively prepare cleaning solutions with effective content of 15% as samples to be detected; and (5) evaluating the bacteriostatic effect.
The specific method comprises the following steps: a clean stainless steel table top is selected and divided into 10 areas with equal areas to serve as a preset oil stain table top. The 10 zones correspond to 10 test groups, examples 1-6 and comparative examples 1-3, respectively, and a control group, respectively. Before the experiment, the test sample was washed with a corresponding detergent, and the control group was washed with sterile water. Each group was washed 3 times at 30min intervals.
Continuously inoculating Staphylococcus aureus for 3 generations, and diluting the bacterial suspension to obtain a concentration of about 1 × 108～5×108cfu/ML. Then using a sample adding device to take 10 mu L of the bacterial suspension, inoculating the bacterial suspension to a corresponding cleaned table area, using a disposable sterile inoculating loop to coat the bacterial suspension into a circle, and then using a sterile plastic cup to seal the test area, so that the test area has a distance of 4mm-5mm with the edge of the test area;
after 12h post inoculation at room temperature, the inoculated sealed area was sampled. 1mL of phosphate buffer containing 0.1% AEO-9 (0.03mol/L) was carefully applied to the middle of the test area without touching the edges of the blocking area. At the same time, the coating solution was pipetted into a sterile test tube using a sterile micropipette. Each sample was plated, the sample to be tested was diluted 100-fold with Phosphate Buffered Saline (PBS) (0.03mol/L), 0.1mL was plated on a TSA plate containing 5% goat blood, a glass rod was spread, the plate was cultured in an incubator at 35. + -. 2 ℃ for 48. + -.4 h, and the number of colonies was counted.
The bacteriostatic rate (%) is (I-II)/I × 100%
Wherein, I is the average colony number of a control sample (sterile water); II is the average colony count of the test samples (the cleaning agent samples of examples 1 to 6 of the present invention and comparative examples 1 to 3). The result is an integer retained.
TABLE 1 degreasing and bacteriostatic effect
| Test group | Detergency/% | Inhibition rate/%) |
| Example 1 | 99.5 | 90 |
| Example 2 | 99.6 | 87 |
| Example 3 | 99.3 | 89 |
| Example 4 | 96.8 | 83 |
| Example 5 | 94.5 | 80 |
| Example 6 | 93.2 | 78 |
| Comparative example 1 | 89.7 | 76 |
| Comparative example 2 | 83.9 | 73 |
| Comparative example 3 | 85.4 | 71 |
Therefore, the oil stain cleaning agent provided by the invention has good oil stain removing and bacteriostatic effects. And the specific composition of the antibacterial agent has certain influence on the decontamination effect and the antibacterial effect of the antibacterial agent.
The above detailed description is specific to one possible embodiment of the present invention, and the embodiment is not intended to limit the scope of the present invention, and all equivalent implementations or modifications without departing from the scope of the present invention should be included in the technical scope of the present invention.
Claims (10)
1. An efficient oil stain cleaning agent comprises the following components: sodium citrate, sodium lignosulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and tea saponin.
2. The efficient oil stain cleaning agent as claimed in claim 1, which comprises the following components in parts by weight: 0.5-3 parts of sodium citrate, 0.5-5 parts of sodium lignosulfonate, 0.1-2 parts of lipase, 1-10 parts of sodium dodecyl sulfate, 1-5 parts of lauric monoglyceride, 0.1-8 parts of cocamidopropyl betaine, 1-8 parts of trisodium phosphate and 0.1-3 parts of tea saponin.
3. The efficient oil stain cleaning agent according to claim 1, which comprises the following components in parts by weight: 0.5-1 part of sodium citrate, 0.5-1 part of sodium lignosulfonate, 0.1-0.5 part of lipase, 5-10 parts of sodium dodecyl sulfate, 1-2 parts of lauric monoglyceride, 0.1-3 parts of cocamidopropyl betaine, 1-5 parts of trisodium phosphate and 0.1-0.5 part of tea saponin.
4. The efficient oil stain cleaning agent according to claim 1, wherein the tea saponin is modified tea saponin, and the preparation method of the modified tea saponin comprises the following steps:
(1) dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction;
(2) and (2) adding sodium bisulfite into the product obtained in the step (1) for reaction to obtain a product, namely the modified tea saponin.
5. The efficient oil stain cleaning agent according to claim 4, wherein in the step (1), the molar ratio of the tea saponin to the maleic anhydride is 1: 1-5.
6. The high-efficiency oil stain cleaning agent according to claim 1, wherein in the step (1), the reaction process is treated by cation exchange resin; the cation exchange resin is 732 type cation exchange resin; the temperature of the reaction is 60-80 ℃.
7. The high-efficiency oil stain cleaning agent according to claim 4, wherein in the step (1), the reaction time is 10-16 h; in the step (2), the molar ratio of the sodium bisulfite to the tea saponin is 3-6: 1; in the step (2), the reaction temperature is 70-90 ℃.
8. The high-efficiency oil stain cleaning agent according to claim 4, wherein the product obtained in the step (2) is subjected to adsorption treatment by macroporous resin; the macroporous resin is AB-8 type or D101 type macroporous resin; and after the macroporous resin is adsorbed, eluting by using 60-90 wt% of ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
9. The preparation method of the high-efficiency oil stain cleaning agent as claimed in any one of claims 1 to 8, which comprises the following steps: and sequentially mixing sodium citrate, sodium lignosulphonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate, tea saponin or modified tea saponin to obtain the efficient oil stain cleaning agent.
10. A cleaning preparation containing the high-efficiency oil stain cleaning agent as claimed in any one of claims 1 to 8, wherein the cleaning preparation is a powder preparation, a liquid preparation or a solid effervescent tablet.
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| EP4282943A1 (en) * | 2022-05-24 | 2023-11-29 | Everdrop GmbH | Tablet, powder or granulate for preparing a liquid soap |
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| CN105039002A (en) * | 2015-07-08 | 2015-11-11 | 姚雳 | Antibacterial cleaning fluid for articles of everyday use |
| CN108060028A (en) * | 2017-12-05 | 2018-05-22 | 徐云丽 | Green fruit-vegetable detergent |
| CN109456855A (en) * | 2018-11-28 | 2019-03-12 | 夏勇 | A kind of environment protection clean type greasy dirt detergent and preparation method thereof |
| CN113980750A (en) * | 2021-10-27 | 2022-01-28 | 深圳市洁王精细化工科技有限公司 | Kitchen detergent and preparation method thereof |
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| CN105039002A (en) * | 2015-07-08 | 2015-11-11 | 姚雳 | Antibacterial cleaning fluid for articles of everyday use |
| CN108060028A (en) * | 2017-12-05 | 2018-05-22 | 徐云丽 | Green fruit-vegetable detergent |
| CN109456855A (en) * | 2018-11-28 | 2019-03-12 | 夏勇 | A kind of environment protection clean type greasy dirt detergent and preparation method thereof |
| CN113980750A (en) * | 2021-10-27 | 2022-01-28 | 深圳市洁王精细化工科技有限公司 | Kitchen detergent and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP4282943A1 (en) * | 2022-05-24 | 2023-11-29 | Everdrop GmbH | Tablet, powder or granulate for preparing a liquid soap |
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