CN116814345A - Household degerming cleaning agent and preparation method thereof - Google Patents
Household degerming cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN116814345A CN116814345A CN202310805016.9A CN202310805016A CN116814345A CN 116814345 A CN116814345 A CN 116814345A CN 202310805016 A CN202310805016 A CN 202310805016A CN 116814345 A CN116814345 A CN 116814345A
- Authority
- CN
- China
- Prior art keywords
- household
- preparation
- cleaning agent
- parts
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 46
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 42
- 239000000843 powder Substances 0.000 claims abstract description 42
- 241000237536 Mytilus edulis Species 0.000 claims abstract description 40
- 235000020638 mussel Nutrition 0.000 claims abstract description 40
- 239000003899 bactericide agent Substances 0.000 claims abstract description 36
- 238000004140 cleaning Methods 0.000 claims abstract description 32
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 239000002738 chelating agent Substances 0.000 claims abstract description 20
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 19
- 230000001954 sterilising effect Effects 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 239000013530 defoamer Substances 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 67
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 27
- 238000002791 soaking Methods 0.000 claims description 19
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 18
- 238000001816 cooling Methods 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 238000007873 sieving Methods 0.000 claims description 18
- 238000005406 washing Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 11
- XPLSDXJBKRIVFZ-UHFFFAOYSA-L copper;prop-2-enoate Chemical compound [Cu+2].[O-]C(=O)C=C.[O-]C(=O)C=C XPLSDXJBKRIVFZ-UHFFFAOYSA-L 0.000 claims description 10
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 claims description 9
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 9
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 9
- IFQSXNOEEPCSLW-DKWTVANSSA-N L-cysteine hydrochloride Chemical compound Cl.SC[C@H](N)C(O)=O IFQSXNOEEPCSLW-DKWTVANSSA-N 0.000 claims description 9
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 9
- 238000001354 calcination Methods 0.000 claims description 9
- 239000012153 distilled water Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 9
- 235000013372 meat Nutrition 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 238000010298 pulverizing process Methods 0.000 claims description 9
- 235000015170 shellfish Nutrition 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- NVNLLIYOARQCIX-MSHCCFNRSA-N Nisin Chemical compound N1C(=O)[C@@H](CC(C)C)NC(=O)C(=C)NC(=O)[C@@H]([C@H](C)CC)NC(=O)[C@@H](NC(=O)C(=C/C)/NC(=O)[C@H](N)[C@H](C)CC)CSC[C@@H]1C(=O)N[C@@H]1C(=O)N2CCC[C@@H]2C(=O)NCC(=O)N[C@@H](C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(NCC(=O)N[C@H](C)C(=O)N[C@H](CC(C)C)C(=O)N[C@H](CCSC)C(=O)NCC(=O)N[C@H](CS[C@@H]2C)C(=O)N[C@H](CC(N)=O)C(=O)N[C@H](CCSC)C(=O)N[C@H](CCCCN)C(=O)N[C@@H]2C(N[C@H](C)C(=O)N[C@@H]3C(=O)N[C@@H](C(N[C@H](CC=4NC=NC=4)C(=O)N[C@H](CS[C@@H]3C)C(=O)N[C@H](CO)C(=O)N[C@H]([C@H](C)CC)C(=O)N[C@H](CC=3NC=NC=3)C(=O)N[C@H](C(C)C)C(=O)NC(=C)C(=O)N[C@H](CCCCN)C(O)=O)=O)CS[C@@H]2C)=O)=O)CS[C@@H]1C NVNLLIYOARQCIX-MSHCCFNRSA-N 0.000 claims description 7
- 108010053775 Nisin Proteins 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 235000010297 nisin Nutrition 0.000 claims description 7
- 239000004309 nisin Substances 0.000 claims description 7
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 235000013628 Lantana involucrata Nutrition 0.000 claims description 4
- 235000006677 Monarda citriodora ssp. austromontana Nutrition 0.000 claims description 4
- 240000007673 Origanum vulgare Species 0.000 claims description 4
- 239000000341 volatile oil Substances 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 claims description 2
- 238000004821 distillation Methods 0.000 claims description 2
- 108700004121 sarkosyl Proteins 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 14
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 13
- 102000004190 Enzymes Human genes 0.000 abstract description 11
- 108090000790 Enzymes Proteins 0.000 abstract description 11
- 241000894006 Bacteria Species 0.000 abstract description 8
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract description 4
- 230000001580 bacterial effect Effects 0.000 abstract description 3
- 230000004071 biological effect Effects 0.000 abstract description 2
- 231100000956 nontoxicity Toxicity 0.000 abstract description 2
- 235000016709 nutrition Nutrition 0.000 abstract description 2
- 230000035764 nutrition Effects 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 230000006870 function Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 3
- 241000209490 Nymphaea Species 0.000 description 3
- 235000016791 Nymphaea odorata subsp odorata Nutrition 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 231100000209 biodegradability test Toxicity 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 238000012258 culturing Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000237509 Patinopecten sp. Species 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000006072 paste Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000020637 scallop Nutrition 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical group O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- ZRALSGWEFCBTJO-UHFFFAOYSA-N guanidine group Chemical group NC(=N)N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000013642 negative control Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 230000002633 protecting effect Effects 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 210000003705 ribosome Anatomy 0.000 description 1
- 229940083037 simethicone Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the field of cleaning agents, in particular to a household degerming cleaning agent and a preparation method thereof; the invention adopts the builder, the chelating agent, the surfactant, the defoamer, the bactericide, the antibacterial agent and the mussel shell powder to prepare the household degerming cleaning agent; the sulfhydryl in the bactericide can react with enzymes in bacteria, so that the conformation of the bacterial enzymes is changed, and the biological activity and the function of the bacteria are influenced; the reaction can lead bacteria to be in a state of lack of nutrition and growth, thereby achieving the aim of sterilization; the mussel shell powder is added, the shell is natural, green, cheap and easy to obtain, and the surface of the shell powder has a plurality of micropore structures and has good adsorption performance; the household degerming cleaning agent prepared by the invention has the advantages of high-efficiency cleaning effect, safety, no toxicity, no pungent smell, good sterilizing and fresh-keeping cleaning effect and good biodegradability.
Description
Technical Field
The invention relates to the field of cleaning agents, in particular to a household degerming cleaning agent and a preparation method thereof.
Background
Household cleaners are classified into acidic cleaners, medium cleaners, and alkaline cleaners according to their ph.
Acidic cleaners the acidic cleaners have a ph of less than 7 and are mostly liquid. The detergent has certain sterilizing and deodorizing effects, and can remove alkaline dirt on the surface of objects, such as lime dirt, cement dirt, scale, refractory urine dirt and oxidized metal dirt. In household cleaning, acidic detergents are mainly used for cleaning toilets.
Neutral cleaners have a ph of about 7 and include liquids, powders, pastes, and the like. The detergent has the functions of decontamination and cleaning. It is widely used in households because it does not corrode and damage anything, but the removal of stubborn stains is not ideal. Neutral cleaners commonly used in households include multifunctional cleaners for daily cleaning.
Alkaline cleaner the alkaline cleaner has a ph greater than 7 and the air conditioner is fluorinated, including liquids, powders, emulsions, pastes, and the like. The cleaning agent can well remove various acidic dirt, mechanical oil stains and animal and plant oil stains on the surface of an object. It is mainly used for kitchen cleaning in household cleaning. Alkaline detergents commonly used in the home include alkaline washing powder, alkaline flour, detergents, glass cleaners, and the like. Glass water is in fact a hard surface cleaner. The formula is simple, the appearance is similar to that of water, and most of colors are different. The glass water only removes some dust and water stains, so the effect of removing other oil or dirt is not obvious.
Chinese patent CN201310039935.6: the invention provides a vegetable and fruit degerming cleaning agent and a preparation method thereof, wherein the degerming cleaning agent comprises the following raw materials in parts by weight: 2-4 parts of oyster shell, 3-5 parts of variegated clam shell, 2-4 parts of scallop shell, 7-9% of active carbon accounting for the total weight of the material and 4-6% of chitin accounting for the total weight of the material; the oyster shell, the variegated clamshell and the scallop shell are selected from the sea as raw materials, so that the problems of social environmental protection and waste utilization by physical treatment are solved, the environment-friendly antibacterial, fresh-keeping and cleaning agent can clean mold, coliform bacteria and residues left on the surface of tableware, can clean and degerming pesticide residues on melons, fruits and vegetables in a short time, achieves the effects of fresh keeping and corrosion prevention, and solves the problems that the cleaning agent in the prior art only can remove oil stains and stains, but does not have the functions of disinfection and sterilization and pollutes the environment.
Chinese patent CN201310447840.8: the biological water lily tableware cleaning agent is prepared through compounding the water lily embryo soaking liquid as sterilizing component with foaming agent and through special technological process, and is used mainly in eliminating and sterilizing tableware, drinking set and kitchen stain. The invention has the following advantages: (1) The biological tableware degerming cleaning agent is prepared by compounding natural animal and plant extract components by adopting essence of edible water lily as main decontamination and degerming components, has no stimulation to human bodies and has no pollution to the environment; (2) The biological active ingredient has high activity and small dosage, and saves resources; (3) The sterilization and the cleaning of the tableware are completed in one step, the tableware is not required to be disinfected after being washed, and the use is convenient; (4) The animal and plant components have moisturizing and protecting effects on hand skin of a user.
Chinese patent CN201611134777.2: the invention discloses a biological enzyme sterilization cleaning agent for a washing tank and a preparation method thereof, wherein the biological enzyme sterilization cleaning agent for the washing tank comprises the following components in parts by weight: 22-41% of alkaline inorganic cleaning agent, 20-30% of oxidation bleaching agent, 10-20% of builder, 5-10% of surfactant, 1-5% of enzyme stabilizer, 2-10% of metal corrosion inhibition protector, 1-5% of oxidation bleaching activator, 1-5% of complex enzyme preparation, 1-5% of hard water chelating agent and 1-5% of anti-fouling redeposition agent. When the biological enzyme sterilization cleaning agent for the washing tank is used for cleaning the washing tank of the washing machine, the complex enzyme preparation, the surfactant and various auxiliary agents are synergistic, various stubborn stains in the washing tank are quickly removed, the cleaning effect is good, the dissolving speed is high, no residues exist after cleaning, the perception effect is strong and hot, new stains and substances which are unfavorable for subsequent procedures are not generated, the washing tank is basically corrosion-free, and meanwhile, the biological enzyme sterilization cleaning agent has the functions of sterilization, mite removal and peculiar smell removal.
The cleaning agent prepared by the above patent and the prior art uses a large amount of industrial acid and alkali such as caustic soda, nitric acid and the like, so that the produced industrial wastewater is easy to cause burden on the environment and does not accord with the green standard; in addition, chlorine-containing disinfectants are often used in the cleaning agent, so that the problem of pathogen pollution can be solved in the cleaning process, but the chlorine-containing disinfectants also volatilize the irritating unpleasant smell with chlorine.
Disclosure of Invention
The invention aims to provide a household degerming cleaning agent and a preparation method thereof, which have the advantages of high-efficiency cleaning effect, safety, no toxicity, no pungent smell, good sterilization, fresh-keeping and cleaning effects and good biodegradability.
In order to achieve the above purpose, the present invention provides the following technical solutions:
a preparation method of a household degerming cleaning agent comprises the following steps:
s1: adding 100-150 parts of deionized water into a reaction kettle, heating to 60-70 ℃, continuously adding 7-10 parts of builder and 7-10 parts of chelating agent, and stirring until the components are completely dissolved;
s2: then adding 1-2 parts of surfactant, stirring until no solid exists, adding 0.1-0.4 part of defoamer, and stirring uniformly;
s3: adding 50-100 parts of deionized water, continuously stirring, cooling to room temperature, adding 0.1-0.5 part of bactericide, 0.1-0.5 part of antibacterial agent and 10-20 parts of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5-8 to obtain the household sterilizing cleaning agent.
Preferably, the builder is sodium carbonate.
Preferably, the chelating agent is EDTA.
Preferably, the stirring speed is 300-500rpm.
Preferably, the surfactant is one or a mixture of anionic surfactant sodium fatty acid methyl sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate and lauroyl sarcosine sodium, nonionic surfactant alkyl polyglucoside and amphoteric surfactant dodecyl dimethyl betaine.
Preferably, the defoamer is simethicone.
A preparation method of the bactericide comprises the following steps:
according to parts by weight, replacing air in a closed stirring kettle by adopting nitrogen, then adding 40-50 parts of L-cysteine ethyl ester hydrochloride, 10-16 parts of vinylguanamine, 12-15 parts of copper acrylate, 300-530 parts of DMF (dimethyl formamide), 0.5-3 parts of tetramethylguanidine, stirring at 60-70 ℃ for 60-130 minutes, adding 0.5-3 parts of benzoyl peroxide, stirring at 60-70 ℃ for 90-180 minutes, and removing DMF by reduced pressure distillation to obtain the bactericide.
Preferably, the antibacterial agent is one or more mixtures of nisin and oregano essential oil.
Preferably, the pH regulator is citric acid.
A preparation method of mussel shell powder comprises the following steps:
s1: cleaning the waste mussel shells, removing a small amount of shellfish meat remained in the shells, soaking the mussel shells in 0.5-1% dilute hydrochloric acid for 20-40min, and removing impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2-4 hours at 900-1000 ℃, and cooling to obtain mussel shell powder.
Reaction mechanism:
according to the invention, through the thiol addition reaction of L-cysteine ethyl ester hydrochloride with vinylguanamine and copper acrylate respectively, the addition product is polymerized by free radicals due to the copper acrylate having two double bonds, so that the high molecular bactericide is obtained.
The technical effects are as follows:
compared with the prior art, the household degerming cleaning agent and the preparation method thereof have the following remarkable effects:
1. the sterilization capability is enhanced: the sulfhydryl group in the high molecular bactericide can react with the enzyme in bacteria, thereby changing the conformation of the bacterial enzyme and affecting the biological activity and the function. This reaction allows bacteria to be in a state of lack of nutrition and growth, thereby achieving the purpose of sterilization.
2. Improving the cleaning effect: the structure of the high molecular bactericide contains a large amount of hydrophilic groups and aliphatic groups, and the groups can combine water and oil, so that the aim of cleaning is fulfilled. Meanwhile, the polymer bactericide can clean dirt, paint and other substances on the surface while sterilizing.
3. Increase antibacterial performance: thiol groups in polymeric bactericides, guanidine groups can react with proteins and ribosomes within bacteria, thereby altering their structure and function. This reaction can disable the ability of the bacteria to live and prevent them from regrowing.
In short, the polymer bactericide can improve the bactericidal effect, the cleaning effect and the antibacterial performance through the sulfhydryl addition reaction and the free radical polymerization reaction, and is expected to be an effective bactericide for a long time.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below in connection with the embodiments of the present invention. It will be apparent that the described embodiments are only some, but not all, embodiments of the invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: adding 100g of deionized water into a reaction kettle, heating to 60 ℃, continuously adding 7g of builder and 7g of chelating agent, and stirring until the mixture is completely dissolved;
s2: then adding 1g of surfactant, stirring until no solid exists, adding 0.1g of defoamer, and stirring uniformly;
s3: adding 50g of deionized water, continuing stirring, cooling to room temperature, adding 0.1g of bactericide, 0.1g of antibacterial agent and 10g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 300rpm.
The surfactant is anionic surfactant sodium fatty acid methyl sulfonate.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 40g of L-cysteine ethyl ester hydrochloride, 10g of vinylguanamine, 12g of copper acrylate, 300g of DMF,0.5g of tetramethylguanidine, stirring at 60℃for 60 minutes, further 0.5g of benzoyl peroxide, stirring at 60℃for 90 minutes, and DMF was distilled off under reduced pressure to obtain a bactericide.
The antibacterial agent is nisin.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.5% dilute hydrochloric acid for 20min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2 hours at 900 ℃, and cooling to obtain mussel shell powder.
Example 2
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: 110g of deionized water is added into a reaction kettle, the temperature is raised to 65 ℃, 8g of builder and 8g of chelating agent are continuously added, and the mixture is stirred until the mixture is completely dissolved;
s2: then adding 1.5g of surfactant, stirring until no solid exists, adding 0.2g of defoamer, and stirring uniformly;
s3: adding 60g of deionized water, continuing stirring, cooling to room temperature, adding 0.2g of bactericide, 0.12g of antibacterial agent and 14g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 400rpm.
The surfactant is anionic surfactant fatty alcohol polyoxyethylene ether sodium sulfate.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 44g of L-cysteine ethyl ester hydrochloride, 12g of vinylguanamine, 13g of copper acrylate, 400g of DMF,1g of tetramethylguanidine were added, stirring was carried out at 65℃for 80 minutes, then 1g of benzoyl peroxide was added, stirring was carried out at 65℃for 120 minutes, and DMF was distilled off under reduced pressure to obtain a bactericide.
The antibacterial agent is nisin.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.6% dilute hydrochloric acid for 25min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 3 hours at 940 ℃, and cooling to obtain the mussel shell powder.
Example 3
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: 140g of deionized water is added into a reaction kettle, the temperature is raised to 65 ℃, 9g of builder and 9g of chelating agent are continuously added, and the mixture is stirred until the mixture is completely dissolved;
s2: then adding 1.5g of surfactant, stirring until no solid exists, adding 0.3g of defoamer, and stirring uniformly;
s3: adding 90g of deionized water, continuing stirring, cooling to room temperature, adding 0.4g of bactericide, 0.4g of antibacterial agent and 18g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 8 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 400rpm.
The surfactant is nonionic surfactant alkyl polyglucoside.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 48g of L-cysteine ethyl ester hydrochloride, 14g of vinylguanamine, 14g of copper acrylate, 500g of DMF,2g of tetramethylguanidine were added, stirred at 65℃for 100 minutes, then 2g of benzoyl peroxide was added, stirred at 65℃for 150 minutes, and DMF was distilled off under reduced pressure to obtain a bactericide.
The antibacterial agent is oregano essential oil.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.8% dilute hydrochloric acid for 35min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 3 hours at 980 ℃, and cooling to obtain the mussel shell powder.
Example 4
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: 150g of deionized water is added into a reaction kettle, the temperature is raised to 70 ℃,10g of builder and 10g of chelating agent are continuously added, and the mixture is stirred until the mixture is completely dissolved;
s2: then adding 2g of surfactant, stirring until no solid exists, adding 0.4g of defoamer, and stirring uniformly;
s3: adding 100g of deionized water, continuing stirring, cooling to room temperature, adding 0.5g of bactericide, 0.5g of antibacterial agent and 20g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 8 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 500rpm.
The surfactant is a zwitterionic surfactant dodecyl dimethyl betaine.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 50g of L-cysteine ethyl ester hydrochloride, 16g of vinylguanamine, 15g of copper acrylate, 530g of DMF,3g of tetramethylguanidine, stirring at 70℃for 130 minutes, further 3g of benzoyl peroxide, stirring at 70℃for 180 minutes, and distilled under reduced pressure to remove DMF to obtain a bactericide.
The antibacterial agent is oregano essential oil.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 1% dilute hydrochloric acid for 40min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 4 hours at 1000 ℃, and cooling to obtain the mussel shell powder.
Comparative example 1
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: adding 100g of deionized water into a reaction kettle, heating to 60 ℃, continuously adding 7g of builder and 7g of chelating agent, and stirring until the mixture is completely dissolved;
s2: then adding 1g of surfactant, stirring until no solid exists, adding 0.1g of defoamer, and stirring uniformly;
s3: adding 50g of deionized water, continuing stirring, cooling to room temperature, adding 0.1g of bactericide, 0.1g of antibacterial agent and 10g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 300rpm.
The surfactant is anionic surfactant sodium fatty acid methyl sulfonate.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 10g of vinylguanamine, 12g of copper acrylate, 300g of DMF,0.5g of tetramethylguanidine were added, stirred at 60℃for 60 minutes, then 0.5g of benzoyl peroxide was added, stirred at 60℃for 90 minutes, and DMF was distilled off under reduced pressure to give a bactericide.
The antibacterial agent is nisin.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.5% dilute hydrochloric acid for 20min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2 hours at 900 ℃, and cooling to obtain mussel shell powder.
Comparative example 2
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: adding 100g of deionized water into a reaction kettle, heating to 60 ℃, continuously adding 7g of builder and 7g of chelating agent, and stirring until the mixture is completely dissolved;
s2: then adding 1g of surfactant, stirring until no solid exists, adding 0.1g of defoamer, and stirring uniformly;
s3: adding 50g of deionized water, continuing stirring, cooling to room temperature, adding 0.1g of bactericide, 0.1g of antibacterial agent and 10g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 300rpm.
The surfactant is anionic surfactant sodium fatty acid methyl sulfonate.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 40g of L-cysteine ethyl ester hydrochloride, 12g of copper acrylate, 300g of DMF,0.5g of tetramethylguanidine were added, stirring was carried out at 60℃for 60 minutes, 0.5g of benzoyl peroxide was added, stirring was carried out at 60℃for 90 minutes, and DMF was distilled off under reduced pressure to obtain a bactericide.
The antibacterial agent is nisin.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.5% dilute hydrochloric acid for 20min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2 hours at 900 ℃, and cooling to obtain mussel shell powder.
Comparative example 3
A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: adding 100g of deionized water into a reaction kettle, heating to 60 ℃, continuously adding 7g of builder and 7g of chelating agent, and stirring until the mixture is completely dissolved;
s2: then adding 1g of surfactant, stirring until no solid exists, adding 0.1g of defoamer, and stirring uniformly;
s3: adding 50g of deionized water, continuing stirring, cooling to room temperature, adding 0.1g of bactericide, 0.1g of antibacterial agent and 10g of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5 to obtain the household degerming cleaning agent.
The builder is sodium carbonate.
The chelating agent is EDTA.
The stirring speed was 300rpm.
The surfactant is anionic surfactant sodium fatty acid methyl sulfonate.
The defoaming agent is dimethyl silicone oil.
The preparation method of the bactericide comprises the following steps:
in a closed stirred tank, air was replaced with nitrogen, then 40g of L-cysteine ethyl ester hydrochloride, 10g of vinylguanamine, 300g of DMF,0.5g of tetramethylguanidine were added, stirring was carried out at 60℃for 60 minutes, 0.5g of benzoyl peroxide was added, stirring was carried out at 60℃for 90 minutes, and DMF was distilled off under reduced pressure to obtain a bactericide.
The antibacterial agent is nisin.
The pH regulator is citric acid.
The preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the abandoned mussel shells, removing a small amount of shellfish meat remained in the shells, and then soaking the shells in 0.5% dilute hydrochloric acid for 20min to remove impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2 hours at 900 ℃, and cooling to obtain mussel shell powder.
The above examples and comparative examples were subjected to a cleaning test, a biodegradability test and a zone of inhibition test, respectively, and the test results are shown in the following table.
1. Cleaning experiment:
firstly, inserting a stainless steel sheet loaded with dirt into a cleaning tank, placing the stainless steel sheet into a beaker with the specification of 500mL, and then placing the beaker on a heating stirrer; the heating stirrer is turned on, the cleaning agent with the concentration of 1% is prepared by preheating to 40 ℃, the rotating speed is set to 500rmin-1, and the cleaning is carried out for 10min.
The testing method comprises the following steps: taking out the cleaned stainless steel sheets, placing the stainless steel sheets in a fume hood for 4 hours, weighing after airing, repeating the experiment for 3 times on each stainless steel sheet, and obtaining an average value as the final mass.
2. Biodegradability test:
biodegradability tests of the cleaning agents were determined using the foam volume method of appendix F in GB/T15818-2018. After adding 5mL of sludge suspension into a culture flask, putting the sludge suspension into an oscillation culture machine with the set temperature of (25+/-3) DEG C, carrying out oscillation culture at the speed of 200rmin-1, taking out after 72 hours, and carrying out acclimatization for 72 hours to finish inoculation.
Adding 500mL of basic nutrient solution and 5mL of domestication solution into a degradation bottle, putting the degradation bottle into a shaking culture machine with the set temperature of 25 ℃, shaking and culturing at the speed of 200rmin-1, taking out after 30min, transferring 50mL into a cylinder with a plug, shaking for 50 times at the same force at the speed of 2 times/second after the piston is tightly covered, standing for 30s, measuring the foam height of the degradation test solution, repeating the test twice, and obtaining the average value as the final foam volume.
3. And (3) bacteriostasis circle experiment:
and (3) aseptically sucking 100 μl of the bacterial suspension in a biosafety cabinet, uniformly spreading on the surface of a solid culture plate, respectively sucking 30 μl of cleaning agent with a concentration of 3mg/mL, dripping the cleaning agent on an aseptic circular paper sheet with a diameter of 7mm, and then placing the cleaning agent in the center of the solid culture dish, wherein a negative control is a solid culture dish on which the aseptic ultrapure water circular paper sheet is dripped. Placing the dried and inverted cover into an incubator at 37 ℃, laying 3 parallel experiments and 1 control experiment in each group, placing the inverted cover into the incubator at 37 ℃, culturing E.coli for 12h, culturing S.aureus for 24h, accurately measuring 3 times of antibacterial diameter by using a crisscross method, and obtaining an average value as a final diameter.
In conclusion, through the data analysis of the above examples and comparative examples, the invention has better cleaning effect and biodegradability, and has strong sterilization capability and antibacterial performance.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. A household degerming cleaning agent and a preparation method thereof are provided, and the operation steps are as follows:
s1: adding 100-150 parts of deionized water into a reaction kettle, heating to 60-70 ℃, continuously adding 7-10 parts of builder and 7-10 parts of chelating agent, and stirring until the components are completely dissolved;
s2: then adding 1-2 parts of surfactant, stirring until no solid exists, adding 0.1-0.4 part of defoamer, and stirring uniformly;
s3: adding 50-100 parts of deionized water, continuously stirring, cooling to room temperature, adding 0.1-0.5 part of bactericide, 0.1-0.5 part of antibacterial agent and 10-20 parts of mussel shell powder, uniformly stirring, and finally adding a pH regulator to regulate the pH to 7.5-8 to obtain the household sterilizing cleaning agent.
2. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the builder is sodium carbonate.
3. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the chelating agent is EDTA.
4. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the stirring speed is 300-500rpm.
5. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the surfactant is one or a mixture of more of anionic surfactant sodium fatty acid methyl sulfonate, fatty alcohol polyoxyethylene ether sodium sulfate and lauroyl sarcosine sodium, nonionic surfactant alkyl polyglucoside and zwitterionic surfactant dodecyl dimethyl betaine.
6. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the defoaming agent is dimethyl silicone oil.
7. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the preparation method of the bactericide comprises the following steps:
according to parts by weight, replacing air in a closed stirring kettle by adopting nitrogen, then adding 40-50 parts of L-cysteine ethyl ester hydrochloride, 10-16 parts of vinylguanamine, 12-15 parts of copper acrylate, 300-530 parts of DMF (dimethyl formamide), 0.5-3 parts of tetramethylguanidine, stirring at 60-70 ℃ for 60-130 minutes, adding 0.5-3 parts of benzoyl peroxide, stirring at 60-70 ℃ for 90-180 minutes, and removing DMF by reduced pressure distillation to obtain the bactericide.
8. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the antibacterial agent is one or more of nisin and oregano essential oil.
9. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the pH regulator is citric acid.
10. The household degerming cleaning agent and the preparation method thereof as claimed in claim 1, wherein: the preparation method of the mussel shell powder comprises the following steps:
s1: cleaning the waste mussel shells, removing a small amount of shellfish meat remained in the shells, soaking the mussel shells in 0.5-1% dilute hydrochloric acid for 20-40min, and removing impurities on the surfaces of the shells;
s2: washing with distilled water after soaking, drying in an oven, taking out, crushing shell into small pieces, pulverizing in a multifunctional high-speed pulverizer, taking out, and sieving with 100 mesh sieve;
s3: and (3) placing the shell powder after sieving into a muffle furnace, calcining for 2-4 hours at 900-1000 ℃, and cooling to obtain mussel shell powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310805016.9A CN116814345A (en) | 2023-07-03 | 2023-07-03 | Household degerming cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310805016.9A CN116814345A (en) | 2023-07-03 | 2023-07-03 | Household degerming cleaning agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116814345A true CN116814345A (en) | 2023-09-29 |
Family
ID=88129001
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310805016.9A Pending CN116814345A (en) | 2023-07-03 | 2023-07-03 | Household degerming cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116814345A (en) |
-
2023
- 2023-07-03 CN CN202310805016.9A patent/CN116814345A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105255601A (en) | Coconut oil fruit and vegetable cleaning agent | |
| CN107937171B (en) | Low-foam green CIP (CIP) sterilization concentrated cleaning agent | |
| CN105132208A (en) | Ocean micro-nano fruit and vegetable washing detergent and preparation method thereof | |
| CN109055031B (en) | Special detergent composition with anti-filming and anti-spotting effects for automatic dish-washing machine | |
| CN105586187A (en) | Melon, fruit and vegetable cleaning liquid and preparation method and application thereof | |
| CN108359543A (en) | The aerobic foam washing compound powder of environment-friendly highly efficient decontamination that safe pro-skin, profession are sterilized | |
| CN112625809A (en) | Liquid detergent composition for dishwasher and preparation method thereof | |
| JP2007031608A (en) | Composition for washing and bacteria-elimination, and its use | |
| CN108559651B (en) | High-temperature-resistant and low-foam protein dirt alkaline cleaning agent and preparation method thereof | |
| CN103666797B (en) | A kind of washing machine tank antibacterial cleanser and preparation method thereof | |
| WO2022092902A1 (en) | Antibacterial cleansing composition | |
| CN116814345A (en) | Household degerming cleaning agent and preparation method thereof | |
| CN113943611A (en) | Fragrant floor scrubber effervescent cleaning tablet with sterilization effect | |
| KR102488475B1 (en) | Multipurpose Water-Based Cleaner Composition | |
| CN114410394B (en) | Efficient oil stain cleaning preparation and preparation method thereof | |
| CN107312645A (en) | A kind of ozone laundry sheet and preparation method thereof | |
| TW202210620A (en) | Detergent formula having biological shell calcium oxide component and preparation method thereof wherein the detergent formula includes natural biological shell calcium oxide, a moisturizing agent, purified water, a surfactant, an emulsifier, a thickener by weight or an acid-base regulator | |
| KR20170056910A (en) | Natural Detergent Composition Mixed from Baking Cinnamon Powder, Soda Powder and Sodium Citrate P0wer and Cleaning Method Using thereof | |
| CN1796521A (en) | Purificant dedicated to barrel type washing machine | |
| CN110257191A (en) | A kind of cleaning agent that can effectively remove pesticide residue, aflatoxin and harmful bacteria | |
| CN111349529A (en) | Natural clothing sterilization detergent containing mulberry leaf and sweet wormwood herb extracting solution and preparation method | |
| CN1073203A (en) | Cleaning agent for fruit and vegetable | |
| CN109022174B (en) | Kitchen heavy oil detergent containing plant essential oil and preparation process thereof | |
| CN114854506B (en) | Green composite CIP cleaning agent and preparation method and use method thereof | |
| CN103013708A (en) | Fabric grease mark removing sterilization cleaning agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |