CN114410394B - Efficient oil stain cleaning preparation and preparation method thereof - Google Patents
Efficient oil stain cleaning preparation and preparation method thereof Download PDFInfo
- Publication number
- CN114410394B CN114410394B CN202210155150.4A CN202210155150A CN114410394B CN 114410394 B CN114410394 B CN 114410394B CN 202210155150 A CN202210155150 A CN 202210155150A CN 114410394 B CN114410394 B CN 114410394B
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- CN
- China
- Prior art keywords
- parts
- tea saponin
- sodium
- cleaning agent
- oil stain
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- 238000002360 preparation method Methods 0.000 title claims abstract description 39
- 238000004140 cleaning Methods 0.000 title claims abstract description 15
- 241001122767 Theaceae Species 0.000 claims abstract description 77
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 77
- 229930182490 saponin Natural products 0.000 claims abstract description 77
- 150000007949 saponins Chemical class 0.000 claims abstract description 77
- 239000012459 cleaning agent Substances 0.000 claims abstract description 62
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims abstract description 27
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004367 Lipase Substances 0.000 claims abstract description 26
- 102000004882 Lipase Human genes 0.000 claims abstract description 26
- 108090001060 Lipase Proteins 0.000 claims abstract description 26
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 26
- 235000019421 lipase Nutrition 0.000 claims abstract description 26
- 239000001509 sodium citrate Substances 0.000 claims abstract description 26
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 26
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract description 25
- 239000001488 sodium phosphate Substances 0.000 claims description 26
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 26
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 26
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 26
- 238000006243 chemical reaction Methods 0.000 claims description 22
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 21
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 14
- 239000004289 sodium hydrogen sulphite Substances 0.000 claims description 14
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 11
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000003729 cation exchange resin Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003480 eluent Substances 0.000 claims description 6
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000007938 effervescent tablet Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims 3
- 239000012669 liquid formulation Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 239000003921 oil Substances 0.000 description 48
- 235000019198 oils Nutrition 0.000 description 48
- 238000012360 testing method Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 230000001580 bacterial effect Effects 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- -1 alkyl ether ester Chemical class 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 235000013736 caramel Nutrition 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 229940075507 glyceryl monostearate Drugs 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 2
- 239000008055 phosphate buffer solution Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000008223 sterile water Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- 238000009210 therapy by ultrasound Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000010699 lard oil Substances 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C11D2111/14—
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
- Y02A20/204—Keeping clear the surface of open water from oil spills
Abstract
The invention belongs to the technical field of cleaning, and particularly relates to a high-efficiency oil stain cleaning preparation and a preparation method thereof. The efficient oil stain cleaning agent comprises the following components: sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, and tea saponin. Safe and environment-friendly, easy to store and transport and good in greasy dirt removing effect.
Description
Technical Field
The invention belongs to the technical field of cleaning, and particularly relates to a high-efficiency oil stain cleaning preparation and a preparation method thereof.
Background
In life, people can clean greasy dirt, which is a headache problem, and if the greasy dirt is not cleaned, the physical and mental health of people is very affected. The residual greasy dirt is generally very difficult to clean, the general detergent is difficult to clean completely, the residual cleaning agent is difficult to clean, and some cleaning agents contain a large amount of harmful chemical components and are often used, so that the skin of a user is easily damaged.
Especially wall surfaces, pipelines, windows, kitchen ventilators and various appliances which are seriously polluted by oil smoke in household kitchens, public canteens and oil-eating industry. Degreasing of these metal surfaces is particularly difficult. In the prior art, a plurality of greasy dirt cleaning agents exist, for example, chinese patent application CN104178373A discloses a kitchen greasy dirt cleaning agent which is composed of the following raw materials in percentage by weight: 8 to 10 percent of alkyl ether ester, 2 to 3 percent of dodecyl propyl betaine, 7 to 9 percent of fatty alcohol polyoxyethylene ether, 2 to 3 percent of sodium alkyl benzene sulfonate, 1.5 to 2 percent of urea, 0.04 to 0.06 percent of essence, 1 to 1.3 percent of sodium carbonate, 1.2 to 1.4 percent of sodium propionate, 1 to 1.2 percent of surfactant and deionized water added to 100.
Chinese patent application CN 105596231A discloses a cleaner for domestic greasy dirt, which comprises the following components in parts by weight: 2-4 parts of potassium chlorate, 1-3 parts of sodium silicate, 3-5 parts of soap solution, 5-9 parts of hydrogen peroxide, 2-6 parts of alkyl glycoside, 2-5 parts of linalyl acetate, 6-8 parts of surfactant, 6-12 parts of biological degerming agent and 22-36 parts of distilled water.
Although the prior art can be used for effectively cleaning heavy oil pollution, the prior cleaning agent has the defects of incomplete pollution removal, time and labor consumption and high cleaning cost. Meanwhile, most of the greasy dirt cleaning agents contain organic solvents, sodium hydroxide and the like, so that great potential safety hazards exist in the using and transporting processes, and the transporting cost is greatly increased.
The invention aims to research an efficient oil stain cleaning agent, which is safe and environment-friendly, is easy to store and transport, and has good effects of removing oil stains and inhibiting bacteria.
Disclosure of Invention
In order to overcome the technical problems, the invention provides a high-efficiency oil stain cleaning agent and a preparation method thereof. Safe and environment-friendly, easy to store and transport, and has better effects of removing greasy dirt and inhibiting bacteria.
In order to achieve the above object, the technical scheme provided by the invention is as follows:
an efficient oil stain cleaning agent comprises the following components: sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate (complexing agent), and tea saponin.
Preferably, the greasy dirt cleaning agent comprises the following components in parts by weight:
0.5-3 parts of sodium citrate, 0.5-5 parts of sodium lignin sulfonate, 0.1-2 parts of lipase, 1-10 parts of sodium dodecyl sulfate, 1-5 parts of lauric acid monoglyceride, 0.1-8 parts of cocamidopropyl betaine, 1-10 parts of trisodium phosphate and 0.1-3 parts of tea saponin.
Preferably, the greasy dirt cleaning agent comprises the following components in parts by weight:
0.5-1 part of sodium citrate, 0.5-1 part of sodium lignin sulfonate, 0.1-0.5 part of lipase, 5-10 parts of sodium dodecyl sulfate, 1-2 parts of lauric acid monoglyceride, 0.1-3 parts of cocamidopropyl betaine, 1-5 parts of trisodium phosphate and 0.1-0.5 part of tea saponin.
Preferably, the tea saponin is modified tea saponin, and the preparation method of the modified tea saponin comprises the following steps:
(1) Dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction;
(2) And (3) adding sodium bisulphite into the product obtained in the step (1) to react, wherein the obtained product is the modified tea saponin.
Preferably, in the step (1), the molar ratio of the tea saponin to the maleic anhydride is 1:1-5.
Preferably, in step (1), the reaction is treated with a cation exchange resin.
Preferably, the cation exchange resin is a 732 type cation exchange resin.
Preferably, in step (1), the temperature of the reaction is 60-80 ℃.
Preferably, in step (1), the reaction time is 10 to 16 hours.
Preferably, in the step (2), the molar ratio of the sodium bisulphite to the tea saponin is 3-6:1.
preferably, in step (2), the temperature of the reaction is 70-90 ℃.
Preferably, the product in the step (2) is subjected to adsorption treatment by macroporous resin.
Preferably, the macroporous resin is AB-8 type or D101 type macroporous resin.
Preferably, after the macroporous resin is adsorbed, 60-90wt% ethanol aqueous solution is used for eluting, and the eluent is decompressed and dried to obtain the purified modified tea saponin.
The invention also aims to provide a preparation method of the efficient oil stain cleaning agent, which comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and tea saponin or modified tea saponin to obtain the efficient oil stain cleaning agent.
The invention also aims to provide a cleaning preparation containing the efficient oil stain cleaning agent, wherein the cleaning preparation is a powder preparation, a liquid preparation or a solid effervescent tablet.
The invention also aims at providing a preparation method of the cleaning preparation of the efficient oil stain cleaning agent, which comprises the following steps: adding solvent into the efficient oil stain cleaning agent to prepare a liquid preparation, or adding or not adding auxiliary materials to prepare a powder preparation or a solid effervescent tablet.
Compared with the prior art, the invention has the technical advantages that:
(1) The invention provides a high-efficiency oil stain cleaning agent, which is safe and environment-friendly, is easy to store and transport, and has good effects of removing oil stains and inhibiting bacteria.
(2) The oil stain cleaning agent provided by the invention uses sodium lignin sulfonate and tea saponin (or modified tea saponin), has a better synergistic effect with other components, can effectively promote the cleaning efficiency of oil stains, and has a better hard water stabilizing effect.
(3) The invention preferably uses the modified tea saponin, and can remove greasy dirt more efficiently after interaction with other components. Meanwhile, the cation exchange resin and the macroporous resin are used in the preparation process of the modified tea saponin, so that the reaction efficiency of the tea saponin and the maleic anhydride can be promoted, the purification effect of the modified tea saponin can be improved, and the cleaning effect of the modified tea saponin on greasy dirt after the modified tea saponin acts with other components in the greasy dirt cleaning agent can be improved.
Detailed Description
The present invention will be described by way of specific examples, to facilitate understanding and grasping of the technical solution of the present invention, but the present invention is not limited thereto. The experimental methods described in the following examples are all conventional methods unless otherwise specified; the reagents and materials, unless otherwise specified, are commercially available.
Example 1
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) Taking a molar ratio of 1:3, dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction for 12 hours, wherein the reaction temperature is 70 ℃, and treating the tea saponin and maleic anhydride by 732 type cation exchange resin in the reaction process;
(2) Adding sodium bisulphite (the molar ratio of the sodium bisulphite to the tea saponin is 4:1) into the product of the step (1), reacting at 80 ℃, adsorbing the prepared product by using AB-8 type macroporous resin, eluting by using 80wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 2
The efficient oil stain cleaning agent comprises the following components in parts by weight:
sodium citrate 0.5 parts, sodium lignin sulfonate 0.5 parts, lipase 0.1 parts, sodium dodecyl sulfate 1 part, lauric acid monoglyceride 5 parts, cocamidopropyl betaine 0.1 parts, trisodium phosphate 10 parts, and modified tea saponin 0.1 parts.
The preparation method of the modified tea saponin comprises the following steps:
(1) Taking a molar ratio of 1:1, dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction for 10 hours, wherein the reaction temperature is 80 ℃, and treating the tea saponin and maleic anhydride by 732 type cation exchange resin in the reaction process;
(2) Adding sodium bisulphite (the molar ratio of the sodium bisulphite to the tea saponin is 3:1) into the product of the step (1), reacting at 70 ℃, adsorbing the prepared product by using D101 macroporous resin, eluting by using 60wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 3
The efficient oil stain cleaning agent comprises the following components in parts by weight:
3 parts of sodium citrate, 5 parts of sodium lignin sulfonate, 2 parts of lipase, 10 parts of sodium dodecyl sulfate, 1 part of lauric acid monoglyceride, 8 parts of cocamidopropyl betaine, 1 part of trisodium phosphate and 3 parts of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) Taking a molar ratio of 1:5, dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction for 16 hours, wherein the reaction temperature is 60 ℃, and treating the tea saponin and maleic anhydride by 732 type cation exchange resin in the reaction process;
(2) Adding sodium bisulphite (the molar ratio of the sodium bisulphite to the tea saponin is 6:1) into the product of the step (1), reacting at 90 ℃, adsorbing the prepared product by AB-8 type macroporous resin, eluting by using 90wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 4
The difference from example 1 is the process for preparing tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) Taking a molar ratio of 1:3, dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction for 12 hours, wherein the reaction temperature is 70 ℃;
(2) Adding sodium bisulphite (the molar ratio of the sodium bisulphite to the tea saponin is 4:1) into the product of the step (1), reacting at 80 ℃, adsorbing the prepared product by using AB-8 type macroporous resin, eluting by using 80wt% ethanol water solution, and drying the eluent under reduced pressure to obtain the purified modified tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 5
The difference from example 4 is the process for preparing tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin comprises the following steps:
(1) Taking a molar ratio of 1:3, dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction for 12 hours, wherein the reaction temperature is 70 ℃;
(2) And (3) adding sodium bisulphite (the molar ratio of the sodium bisulphite to the tea saponin is 4:1) into the product of the step (1), reacting at 80 ℃, and drying the obtained product to obtain the purified modified tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Example 6
In comparison with example 1, tea saponin was used as it is without modification.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 0.5 part of tea saponin.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and tea saponin to obtain the efficient oil stain cleaning agent.
Comparative example 1
In comparison with example 1, the difference is the composition; and replacing sodium lignin sulfonate with modified tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine, 5 parts of trisodium phosphate and 1.5 parts of modified tea saponin.
The preparation method of the modified tea saponin is the same as that of the embodiment 1.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
Comparative example 2
In comparison with example 1, the difference is the composition; sodium lignin sulfonate is used for replacing modified tea saponin.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1.5 parts of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 3 parts of cocamidopropyl betaine and 5 parts of trisodium phosphate.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine and trisodium phosphate to obtain the efficient oil stain cleaning agent.
Comparative example 3
In comparison with example 1, the difference is the composition; trisodium phosphate was used in place of cocamidopropyl betaine.
The efficient oil stain cleaning agent comprises the following components in parts by weight:
1 part of sodium citrate, 1 part of sodium lignin sulfonate, 0.5 part of lipase, 5 parts of sodium dodecyl sulfate, 2 parts of lauric acid monoglyceride, 8 parts of trisodium phosphate and 0.5 part of modified tea saponin.
The preparation method of the modified tea saponin is the same as that of the embodiment 1.
The preparation method of the efficient oil stain cleaning agent comprises the following steps: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, trisodium phosphate and modified tea saponin to obtain the efficient oil stain cleaning agent.
1. Degreasing effect test
The detergency test was performed with reference to the description of QB/T4348-2012 kitchen oil stain remover.
Preparation of dirt: the formula comprises the following components: 64g of soybean oil, 8g of ammonia-free caramel pigment, 12g of wheat flour, 8g of lard oil and 2.4g of glyceryl monostearate. Weighing soybean oil, lard and glyceryl monostearate in a 250ml plastic beaker, and heating in water bath at 50 ℃ to dissolve; stirring, cooling to 30deg.C, adding ammonia-free caramel pigment, stirring at a speed of not less than 1000r/min for 30min, emulsifying, adding wheat flour, stirring for 10min, aging for 24 hr, and storing in refrigerator refrigerating chamber for use, and recovering to 20-25deg.C.
Preparation of the pollution tablet: selecting a clean test piece (the model of the test piece is 1Cr18Ni9Ti, and the stainless steel is drawn); drying in an oven at 120deg.C for 1 hr, cooling for 30min, weighing (0.0002 g), and counting as m 0 . Smearing was carried out with a smearing area of 35 mm. Times.100 mm and a smearing amount of 0.01g/cm 2 . Then placing on a dried porcelain plate, and drying at 200deg.C for 10minThen, the mixture was put into a 45-degree ultraviolet constant temperature aging oven and irradiated with ultraviolet light for 1.5 hours. Adjusting the irradiation position, irradiating for 1.5h again, and taking out and placing in a dryer for ageing for 24h. The greasy dirt-fixed test piece was then weighed (to 0.0002 g) and measured as m 1 。
Ultrasonic treatment is carried out on a cleaning agent to be detected for 30min at 35 ℃, then a smeared test piece is hung in a cleaning agent beaker which is uniformly mixed in advance by ultrasonic treatment, the cleaning agent is completely soaked for 10min, and then the cleaning agent is cleaned for 5min; the sample beakers were then rinsed, each poured with 210mL of water, and rinsed for 30S. The test piece was removed, and the cleaned test piece was dried in an oven at 120℃for 45 minutes, cooled in a desiccator for 30 minutes, and then weighed (0.0002 g) to give a measurement of m 2 Detergency was calculated. The results are shown in Table 1 below.
The detergency is the mass fraction of the removed oil stain f, and is calculated according to the following formula: f= (m 1 -m 2 )/(m 1 -m 0 )×100％
Wherein m is 0 For the mass of the test piece, m 1 M is the quality before washing of the dirt piece 2 The quality of the washed dirt tablet is improved.
According to the method, the high-efficiency oil stain cleaning agents prepared in the examples 1-6 and the comparative examples 1-3 are respectively added into water to prepare cleaning agents with the effective content of 15% as samples to be tested; the detergency test was performed.
2. Antibacterial effect
And (3) evaluating the detention and bacteriostasis effects by referring to a method for evaluating the antibacterial and bacteriostasis effects of QB/T2738-2012 daily chemical products.
The high-efficiency oil stain cleaning agents prepared in the examples 1-6 and the comparative examples 1-3 are respectively added into water to prepare cleaning agents with the effective content of 15% as samples to be tested; and (5) evaluating the antibacterial effect.
The specific method comprises the following steps: a clean stainless steel table top is selected and divided into 10 areas with equal area and is used as a preset oil stain table top. The 10 areas correspond to 10 test groups, examples 1-6 and comparative examples 1-3 and one control group, respectively. Before the experiment, cleaning is carried out by using the corresponding cleaning agents, and the control group is cleaned by using sterile water. Each group was washed 3 times at 30min intervals.
Continuously inoculating Staphylococcus aureus for 3 generations, and diluting the bacterial suspension to obtain bacterial suspension concentration of about 1×10 8 ～5×10 8 cfu/ML. Then using a sample injector to take 10 mu L of the bacterial suspension, inoculating the bacterial suspension to a corresponding cleaned table surface area, using a disposable sterile inoculating loop to coat the bacterial suspension into a circle, and then using a sterile plastic cup to seal an inspection area so that the distance between the bacterial suspension and the edge of the inspection area is 4mm-5 mm;
12h after room temperature inoculation, the inoculated sealing area was sampled. 1mL of a phosphate buffer containing 0.1% AEO-9 (0.03 mol/L) was carefully applied to the middle of the test zone without touching the edges of the closed zone. Simultaneously, the coating solution was aspirated into a sterile test tube with a sterile micropipette. Plating is carried out on each sample, the sample to be tested is diluted 100 times by Phosphate Buffer Solution (PBS) (0.03 mol/L), 0.1mL is inoculated on the surface of a TSA plate containing 5% of sheep blood, the plate is uniformly coated by a glass bent rod, and the plate is cultured in an incubator at the temperature of (35+/-2) DEG C for (48+/-4) h, and the colony number is counted.
Antibacterial ratio (%) = (I-II)/ix100%
Wherein I is the average colony count of a control sample (sterile water); II is the average colony count of test samples (cleaning agent samples of examples 1 to 6 and comparative examples 1 to 3 of the present invention). The result retains integers.
TABLE 1 degreasing and antibacterial effects
| Test group | Detergency/% | Bacteriostatic rate/% |
| Example 1 | 99.5 | 90 |
| Example 2 | 99.6 | 87 |
| Example 3 | 99.3 | 89 |
| Example 4 | 96.8 | 83 |
| Example 5 | 94.5 | 80 |
| Example 6 | 93.2 | 78 |
| Comparative example 1 | 89.7 | 76 |
| Comparative example 2 | 83.9 | 73 |
| Comparative example 3 | 85.4 | 71 |
Therefore, the greasy dirt cleaning agent provided by the invention has good greasy dirt removing and antibacterial effects. And the specific composition has a certain influence on the decontamination effect and the bacteriostasis effect.
The foregoing detailed description is directed to one of the possible embodiments of the present invention, which is not intended to limit the scope of the invention, but is to be accorded the full scope of all such equivalents and modifications so as not to depart from the scope of the invention.
Claims (4)
1. The greasy dirt cleaning agent comprises the following components in parts by weight: 0.5-3 parts of sodium citrate, 0.5-5 parts of sodium lignin sulfonate, 0.1-2 parts of lipase, 1-10 parts of sodium dodecyl sulfate, 1-5 parts of lauric acid monoglyceride, 0.1-8 parts of cocamidopropyl betaine, 1-8 parts of trisodium phosphate and 0.1-3 parts of modified tea saponin; the preparation method of the modified tea saponin comprises the following steps:
(1) Dissolving tea saponin and maleic anhydride in N, N-dimethylformamide for reaction; the molar ratio of the tea saponin to the maleic anhydride is 1:1-5;
(2) Adding sodium bisulphite into the product obtained in the step (1) to react to obtain a product, namely modified tea saponin;
in the step (1), cation exchange resin is treated in the reaction process; the cation exchange resin is 732 type cation exchange resin; the product in the step (2) is adsorbed by macroporous resin; the macroporous resin is AB-8 type or D101 type macroporous resin;
after the macroporous resin is adsorbed, eluting by using 60-90wt% ethanol water solution, and drying eluent under reduced pressure to obtain purified modified tea saponin;
in the step (1), the reaction time is 10-16h; the temperature of the reaction is 60-80 ℃;
in the step (2), the molar ratio of the sodium bisulphite to the tea saponin is 3-6:1, a step of; in the step (2), the temperature of the reaction is 70-90 ℃.
2. The oil stain cleaning agent according to claim 1, which comprises the following components in parts by weight: 0.5-1 part of sodium citrate, 0.5-1 part of sodium lignin sulfonate, 0.1-0.5 part of lipase, 5-10 parts of sodium dodecyl sulfate, 1-2 parts of lauric acid monoglyceride, 0.1-3 parts of cocamidopropyl betaine, 1-5 parts of trisodium phosphate and 0.1-0.5 part of modified tea saponin.
3. A method of preparing the oil stain cleaner of any of claims 1-2, comprising the steps of: and sequentially mixing sodium citrate, sodium lignin sulfonate, lipase, sodium dodecyl sulfate, lauric acid monoglyceride, cocamidopropyl betaine, trisodium phosphate and modified tea saponin to obtain the greasy dirt cleaning agent.
4. A cleaning formulation comprising the greasy dirt cleaning agent of any one of claims 1 to 2, the cleaning formulation being a powder formulation, a liquid formulation or a solid effervescent tablet.
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