CN114395332A - Rosin-based metal complex and application thereof - Google Patents
Rosin-based metal complex and application thereof Download PDFInfo
- Publication number
- CN114395332A CN114395332A CN202210110755.1A CN202210110755A CN114395332A CN 114395332 A CN114395332 A CN 114395332A CN 202210110755 A CN202210110755 A CN 202210110755A CN 114395332 A CN114395332 A CN 114395332A
- Authority
- CN
- China
- Prior art keywords
- rosin
- metal complex
- based metal
- reaction
- complex according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 title claims abstract description 67
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 title claims abstract description 67
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 150000004696 coordination complex Chemical class 0.000 title claims abstract description 35
- 239000003513 alkali Substances 0.000 claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000012055 fruits and vegetables Nutrition 0.000 claims abstract description 4
- 239000000375 suspending agent Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 19
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000376 reactant Substances 0.000 claims description 9
- 239000012295 chemical reaction liquid Substances 0.000 claims description 8
- 238000012545 processing Methods 0.000 claims description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- -1 alkyl naphthalene sulfonate Chemical compound 0.000 claims description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 239000004563 wettable powder Substances 0.000 claims description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 3
- 235000011148 calcium chloride Nutrition 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 235000011147 magnesium chloride Nutrition 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims 3
- 239000002585 base Substances 0.000 claims 1
- 206010042496 Sunburn Diseases 0.000 abstract description 7
- 239000000516 sunscreening agent Substances 0.000 description 20
- 235000020971 citrus fruits Nutrition 0.000 description 17
- 241000207199 Citrus Species 0.000 description 16
- 235000013399 edible fruits Nutrition 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 10
- 238000010586 diagram Methods 0.000 description 10
- 230000000475 sunscreen effect Effects 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- XVYHFPMIBWTTLH-UHFFFAOYSA-N [Zn].[Mg].[Ca] Chemical compound [Zn].[Mg].[Ca] XVYHFPMIBWTTLH-UHFFFAOYSA-N 0.000 description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 description 5
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 5
- 239000003292 glue Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000008149 soap solution Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000037072 sun protection Effects 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000003640 drug residue Substances 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000029553 photosynthesis Effects 0.000 description 2
- 238000010672 photosynthesis Methods 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- HLPHHOLZSKWDAK-UHFFFAOYSA-M sodium;formaldehyde;naphthalene-1-sulfonate Chemical compound [Na+].O=C.C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HLPHHOLZSKWDAK-UHFFFAOYSA-M 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F1/00—Obtaining purification, or chemical modification of natural resins, e.g. oleo-resins
- C09F1/04—Chemical modification, e.g. esterification
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the field of fruit and vegetable anti-sunburn complexes, in particular to a rosin-based metal complex, which comprises the following components in percentage by mass: 10-30% of rosin, 1-10% of alkali, 5-20% of metal salt, 5-10% of dispersing agent and 30-55% of water. The invention provides a rosin-based metal complex and application thereof, which are convenient to use, have good adhesion and can effectively prevent sunburn.
Description
Technical Field
The invention relates to the field of fruit and vegetable sunburn preventing complexes, in particular to a rosin-based metal complex and application thereof.
Background
China is one of the important native areas of citrus, and the citrus has abundant resources, various excellent varieties and more than 4000 years of cultivation history. In recent years, the citrus planting area of China is enlarged year by year, and the annual rate of growth is close to 3%.
In the southwest citrus producing area of China, the damage of sunscald diseases rises year by year under the influence of high-temperature weather, particularly in the noon and afternoon of the high-temperature weather, the local temperature of citrus trees directly irradiated by sunlight rises sharply, when the temperature rises to be more than 40 ℃, chlorophyll of leaves is gradually decomposed, the color of the leaves becomes light or yellow, a large amount of leaves fall after rain, and if the local temperature is too high and air is dried and evaporated too fast, local cell death leaves can generate a local scorching phenomenon. The fruit surface has abnormal color, such as scorched yellow or browned color, and the color change part has sunken peel and hardened. The sunscald seriously affects the appearance of citrus fruits and even causes serious consequences such as fruit drop.
At present, in the actual production process, the sun protection agent is mainly used for preventing the sunscald of the citrus in the modes of manual bagging or smearing a whitening agent (mostly calcium carbonate) and the like, the time and the labor are wasted, and the good sun protection effect is difficult to obtain. In the prior art 1, the citrus sun-proof and sun-proof material is prepared from light calcium carbonate, an ultraviolet blocking agent, surfactant, paraffin oil and the like, and the formula of the material contains a large amount of light calcium carbonate, and the material is easy to precipitate and agglomerate due to high density of the light calcium carbonate, so that the use is influenced; in the prior art 2, a sodium polyacrylate solution and sodium carbonate are mixed, a calcium chloride aqueous solution, a polyacrylic acid component in a formula and the ordinary industrial glue are added, and the material is used for sun protection of oranges, is difficult to completely decolor in the later period, and the surfaces of the oranges often have white residues which are difficult to remove, so that the appearance and the quality of the oranges are seriously influenced.
At present, more manual bagging or whitewashing agent smearing modes are adopted to prevent sunburn, and all other types of whitewashing agents also appear, so that the problems that time and labor are wasted, the adhesion of the glue whitewashing agent is strong, the washing is not easy and the like exist, the appearance of the fruit is influenced, and further the income is influenced.
Disclosure of Invention
In order to solve the above problems, the present invention provides a rosin-based metal complex which is convenient to use, has good adhesion, and can effectively prevent sunburn, and use thereof.
The invention adopts the following technical scheme:
the rosin-based metal complex comprises the following components in percentage by mass: 10-30% of rosin, 1-10% of alkali, 5-20% of metal salt, 5-10% of dispersing agent and 30-45% of water.
The technical proposal is further improved in that the rosin is one or a mixture of any more of gum rosin, hydrogenated rosin and disproportionated rosin.
The technical proposal is further improved in that the alkali is one or a mixture of any more of sodium hydroxide, potassium hydroxide and ethanolamine.
The technical proposal is further improved in that the metal salt is one or a mixture of any more of magnesium sulfate, zinc chloride, calcium chloride and magnesium chloride.
The technical scheme is further improved in that the dispersing agent is one or a mixture of any more of sodium naphthalene sulfonate formaldehyde condensate, alkyl naphthalene sulfonate polycondensate, nonylphenol polyoxyethylene ether, sodium styrene sulfonate, acrylic acid, castor oil polyoxyethylene ether and sodium lignin sulfonate.
The technical proposal is further improved in that the reaction of the rosin-based metal complex is carried out in a reaction kettle, the reaction temperature is controlled at 80-95 ℃, and the reaction time is 3-8 h.
The technical proposal is further improved in that the rosin-based metal complex can be processed into one of suspending agents, wettable powder and dry suspending agents for preparation application.
The technical proposal is further improved in that the rosin-based metal complex is processed into the suspending agent, and the processing technology comprises the following steps:
s1, adding alkali into the reaction kettle, adding part of water for dissolving, adding rosin into the dissolved alkali liquor, heating to 80-90 ℃, reacting for 1.5-3h, and completely saponifying to obtain soap liquid;
s2, adding metal salt into the soap liquid obtained in the step S1, keeping the temperature at 90-93 ℃, and reacting for 2-3 hours to obtain a reaction liquid;
s3, adding the prepared dispersing agent into the reaction liquid in the step S2, keeping the reaction dimension at 85-90 ℃, and reacting for 0.5-1.5h to obtain a reactant;
s4, cooling the reactant obtained in the step S3, adding sericite or lithopone when the temperature is reduced to be below 40 ℃, discharging, and processing through a colloid mill and a sand mill to obtain the rosin-based metal complex suspending agent.
The technical scheme is further improved in that the rosin-based metal complex suspending agent comprises the following components in percentage by mass: 10-25% of rosin, 2-8% of alkali, 10-20% of metal salt, 5-10% of dispersing agent, 10-12% of sericite or lithopone and 30-45% of water.
The application of the rosin-based metal complex is to prevent fruits and vegetables from being sunburned.
The invention has the beneficial effects that:
the rosin-based metal complex disclosed by the invention has the characteristics of good adhesiveness, high whiteness and rain wash resistance, can supplement various metal elements such as calcium and magnesium required by citrus at a later stage, effectively improves the quality of fruits, and is suitable for preventing sunscald of citrus in summer.
Drawings
FIG. 1 is a diagram showing a state before the treatment of applying a sunscreen agent of comparative example 1 of the present invention;
FIG. 2 is a view showing a state after the treatment of applying a sunscreen agent of comparative example 1 of the present invention;
FIG. 3 is a state diagram before the sunscreen treatment of comparative example 2 of the present invention;
FIG. 4 is a state diagram after the sunscreen treatment of comparative example 2 of the present invention;
FIG. 5 is a diagram showing a state before treatment of the rosin-based calcium magnesium zinc complex of example 1 of the present invention;
FIG. 6 is a diagram showing a state after treatment of the rosin-based calcium magnesium zinc complex of example 1 of the present invention;
FIG. 7 is a diagram showing a state before the treatment of applying a sunscreen agent of comparative example 3 of the present invention;
FIG. 8 is a view showing a state after the treatment of applying a sunscreen agent of comparative example 3 of the present invention;
FIG. 9 is a state diagram before treatment of the sunscreen agent of comparative example 4 of the present invention;
FIG. 10 is a state diagram after the sunscreen treatment of comparative example 4 of the present invention;
FIG. 11 is a state diagram before the treatment with the suspending agent of example 2 of the present invention;
FIG. 12 is a diagram showing a state after the treatment with the suspending agent of example 2 of the present invention.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings, and it should be understood that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The rosin-based metal complex comprises the following components in percentage by mass: 10-30% of rosin, 1-10% of alkali, 5-20% of metal salt, 5-10% of dispersing agent and 30-45% of water.
Preferably, the rosin is one or a mixture of any more of gum rosin, hydrogenated rosin and disproportionated rosin.
Preferably, the alkali is one or a mixture of any several of sodium hydroxide, potassium hydroxide and ethanolamine.
Preferably, the metal salt is one or a mixture of any several of magnesium sulfate, zinc chloride, calcium chloride and magnesium chloride.
Preferably, the dispersing agent is one or a mixture of any more of sodium salt of naphthalene sulfonic acid-formaldehyde condensate, alkyl naphthalene sulfonate polycondensate, nonylphenol polyoxyethylene ether, sodium styrene sulfonate, acrylic acid, castor oil polyoxyethylene ether and sodium lignin sulfonate.
Preferably, the reaction of the rosin-based metal complex is carried out in a reaction kettle, the reaction temperature is controlled to be 80-95 ℃, and the reaction time is 3-8 h.
Preferably, the rosin-based metal complex can be further processed into one of a suspending agent, a wettable powder and a dry suspending agent for preparation application.
Preferably, the rosin-based metal complex is processed into a suspending agent by a processing process comprising the following steps:
s1, adding alkali into the reaction kettle, adding part of water for dissolving, adding rosin into the dissolved alkali liquor, heating to 80-90 ℃, reacting for 1.5-3h, and completely saponifying to obtain soap liquid;
s2, adding metal salt into the soap liquid obtained in the step S1, keeping the temperature at 90-93 ℃, and reacting for 2-3 hours to obtain a reaction liquid;
s3, adding the prepared dispersing agent into the reaction liquid in the step S2, keeping the reaction dimension at 85-90 ℃, and reacting for 0.5-1.5h to obtain a reactant;
s4, cooling the reactant obtained in the step S3, adding sericite or lithopone when the temperature is reduced to be below 40 ℃, discharging, and processing through a colloid mill and a sand mill to obtain the rosin-based metal complex suspending agent.
Preferably, the suspending agent of the rosin-based metal complex comprises the following components in percentage by mass: 10-25% of rosin, 2-8% of alkali, 10-20% of metal salt, 5-10% of dispersing agent, 10-20% of sericite or lithopone and 30-45% of water.
The application of the rosin-based metal complex is to prevent citrus from sunburning.
The rosin-based metal complex disclosed by the invention is simple in preparation process, does not need to additionally introduce other solvents or other adhesives in the process, particularly a preparation process of a suspending agent, can be obtained through one-step reaction, and is time-saving and labor-saving.
On the basis of the process of the suspending agent, the complex can also be processed into wettable powder or dry suspending agent for use.
The prepared complex product is used for preventing and treating sunscald of citrus, is convenient to use, can supplement various metal elements necessary for the later period of citrus, and has a good effect of improving the quality of fruits.
Example 1
A preparation method of a rosinyl calcium magnesium zinc complex suspending agent comprises the following steps:
s1, adding 30 kg of potassium hydroxide into 450 kg of water for dissolving, adding 200 kg of rosin into the dissolved potassium hydroxide solution, heating to 85 ℃, reacting for 3h, and completely saponifying to obtain a soap solution;
s2, adding 20 kg of magnesium chloride, 100 kg of calcium chloride and 50 kg of zinc sulfate into the soap solution obtained in the step (1), keeping the temperature at 93 ℃, and reacting for 3 hours to obtain a reaction solution;
s3, adding 20 kg of sodium naphthalenesulfonate formaldehyde condensate and 30 kg of sodium dodecyl benzene sulfonate into the reaction liquid obtained in the step S2, keeping the reaction dimension at 85 ℃, and reacting for 1 hour to obtain a reactant;
and S4, cooling the reactant in the step S3, adding 100 kilograms of lithopone when the temperature is reduced to be below 40 ℃, discharging, and processing the mixture into the suspending agent of the rosin calcium-magnesium-zinc complex through a colloid mill and a sand mill.
Comparative example 1
Conventional sunscreens are used.
Comparative example 2
Commercially available plant sunscreens against intense light are used.
When the rosin-based calcium-magnesium-zinc complex obtained in example 1, and the comparative examples 1 and 2 are used for controlling citrus sunscald, the complex obtained in example 1 has a better effect than the conventional control agents. The specific test protocol and conclusions are as follows:
1. test reagents and treatment:
| numbering | Pharmaceutical and treatment | Application method |
| A | Manual application of sunscreen agent (conventional) | Application of the composition |
| B | Anti-glare plant sunscreen (commercially available) | Diluting by 20 times |
| C | Rosin-based calcium-magnesium complex of example 1 | Diluting by 20 times |
2. And (3) test crops: wo gan, tree age three years, tree vigor middle-high; test time: 10/7/2021-9/15/2021.
3. As is apparent from the figures 1-2, the sun-screening agent is manually applied to prevent sunburn, but the sun-screening agent is difficult to clean in the later period, so that the quality of fruits is seriously influenced, the photosynthesis of fruit trees is complemented, the color is changed, the nutrition is accumulated and complemented, and the flavor is influenced.
As is obvious from the graphs in figures 3-4, the sunscreen agents sold in the market are generally components of glue mixed with calcium oxide, after 2 tests for more than 2 months, almost no sunscreen effect is achieved after repeated rain wash, and a plurality of 'sun fruits' are found during investigation, namely, the peel of the direct sunlight part is damaged, oil bubbles are broken, and even the fruit cracking phenomenon occurs, so that the yield and the income are seriously influenced.
It is obvious from fig. 5-6 that the rosin-based calcium-magnesium complex obtained in example 1, after being treated, can be uniformly colored on the surface of citrus trees and has excellent adhesiveness, and after 2 months of weather, the sun-screening effect can still be kept well, and the formula contains abundant calcium and magnesium elements, so that the rosin-based calcium-magnesium complex has a good protection effect on the toughness of the pericarp. Upon investigation, it was found that most fruits had good appearance and quality except for a few minor burns and without excessive drug residue.
Example 2
A preparation method of a rosin-based calcium-magnesium complex mixed sericite suspending agent comprises the following steps:
(1) adding 23 kg of potassium hydroxide into 400 kg of water for dissolving, adding 180 kg of rosin into the dissolved potassium hydroxide solution, heating to 85 ℃, reacting for 2.5h, and completely saponifying;
(2) respectively adding 30 kg of magnesium chloride and 80 kg of calcium chloride into the soap solution obtained in the step (1), keeping the temperature at 93 ℃, and reacting for 2.5 hours;
(3) adding 25 kg of alkyl naphthalene sulfonate polycondensate, 30 kg of sodium dodecyl benzene sulfonate and 32 kg of sodium lignin sulfonate into the reaction liquid obtained in the step (2), keeping the reaction dimension at 85 ℃, and reacting for 40 min;
(4) and (3) cooling the reactant in the reaction (3), adding 200 kg of sericite when the temperature is reduced to below 40 ℃, stirring for 1h, discharging, and processing into the rosin calcium magnesium complex mixed sericite suspending agent by a colloid mill and a sand mill.
The suspending agent is used for preventing and treating sunscald of citrus, and has the advantages of environmental protection, labor and time saving, outstanding effect and the like compared with the conventional commonly used preventing and treating agents. The specific test protocol and conclusions are as follows:
1, test agent and treatment:
| numbering | Pharmaceutical and treatment | Application method |
| Comparative example 3 | Manual application of sunscreen agent (conventional) | Application of the composition |
| Comparative example 4 | Anti-glare plant sunscreen (commercially available) | 20 times of |
| Example 2 | Suspending agent | 30 times of |
2, test crop: and Wo gan, three years old, middle-high tree vigor.
3, test time: 7/15/2021-9/15/2021.
4, as is apparent from fig. 7-8, the sun-screening agent is applied manually, which can better resist sunburn, but the sun-screening agent is difficult to clean in the later period, which seriously affects the quality of the fruit, also causes the photosynthesis complement of the fruit tree, causes color change and nutrient accumulation complement, and affects the flavor.
As is obvious from the graphs of FIGS. 9-10, most of the sunscreen agents sold in the market are acrylic acid glue mixed calcium carbonate and the like, after 2 tests for more than 2 months, almost no sunscreen effect is achieved after repeated rain wash, and a plurality of 'sunfruits', namely, the peel of the direct sunlight part is damaged, oil bubbles are broken, and even the phenomenon of fruit cracking is caused, so that the yield and the income are seriously influenced.
It is obvious from fig. 11-12 that the suspending agent obtained in example 2 can be uniformly colored on the surface of citrus trees after being treated, has excellent adhesiveness, can still keep a good sunscreen effect after 2 months of weather, and has a good protection effect on the toughness of the peel due to the fact that the formula contains abundant calcium and magnesium elements. And because of the addition of sericite, the fruit peel has better reflection and absorption effects on ultraviolet rays in sunlight, and effectively reduces the temperature of the surface of the fruit peel when the sunlight is directly irradiated. Upon investigation, it was found that most fruits had good appearance and quality except for a few minor burns and without excessive drug residue.
The above examples only show some embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the present invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. The rosin-based metal complex is characterized by comprising the following components in percentage by mass: 10-30% of rosin, 1-10% of alkali, 5-20% of metal salt, 5-10% of dispersing agent and 30-55% of water.
2. The rosin-based metal complex according to claim 1, wherein the rosin is one or a mixture of any of gum rosin, hydrogenated rosin, and disproportionated rosin.
3. The rosin-based metal complex according to claim 1, wherein the base is one or a mixture of any of sodium hydroxide, potassium hydroxide and ethanolamine.
4. The rosin-based metal complex according to claim 1, wherein the metal salt is one or a mixture of any of magnesium sulfate, zinc chloride, calcium chloride and magnesium chloride.
5. The rosin-based metal complex according to claim 1, wherein the dispersant is one or a mixture of any of a sodium salt of a naphthalene sulfonic acid-formaldehyde condensate, a polycondensate of an alkyl naphthalene sulfonate, nonylphenol polyoxyethylene ether, sodium styrene sulfonate, acrylic acid, castor oil polyoxyethylene ether, and sodium lignin sulfonate.
6. The rosin-based metal complex according to claim 1, wherein the reaction of the rosin-based metal complex is carried out in a reaction kettle, and the reaction temperature is controlled to be 80-95 ℃ and the reaction time is 3-8 h.
7. The rosin-based metal complex according to claim 1, further comprising a step of processing the rosin-based metal complex into one of a suspension, a wettable powder and a dry suspension.
8. The rosin-based metal complex according to claim 7, being processed into a suspension by a process comprising the steps of:
s1, adding alkali into the reaction kettle, adding part of water for dissolving, adding rosin into the dissolved alkali liquor, heating to 80-90 ℃, reacting for 1.5-3h, and completely saponifying to obtain soap liquid;
s2, adding metal salt into the soap liquid obtained in the step S1, keeping the temperature at 90-93 ℃, and reacting for 2-3 hours to obtain a reaction liquid;
s3, adding the prepared dispersing agent into the reaction liquid in the step S2, keeping the reaction dimension at 85-90 ℃, and reacting for 0.5-1.5h to obtain a reactant;
s4, cooling the reactant obtained in the step S3, adding sericite or lithopone when the temperature is reduced to be below 40 ℃, discharging, and processing through a colloid mill and a sand mill to obtain the rosin-based metal complex suspending agent.
9. The rosin-based metal complex according to claim 8, wherein the suspending agent comprises the following components in parts by mass: 10-25% of rosin, 2-8% of alkali, 10-20% of metal salt, 5-10% of dispersing agent, 10-20% of sericite or lithopone and 30-45% of water.
10. Use of a rosin-based metal complex according to any one of claims 1 to 9 for sunscald protection of fruits and vegetables.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210110755.1A CN114395332B (en) | 2022-01-29 | 2022-01-29 | Rosin-based metal complex and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210110755.1A CN114395332B (en) | 2022-01-29 | 2022-01-29 | Rosin-based metal complex and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114395332A true CN114395332A (en) | 2022-04-26 |
| CN114395332B CN114395332B (en) | 2024-01-26 |
Family
ID=81232423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210110755.1A Active CN114395332B (en) | 2022-01-29 | 2022-01-29 | Rosin-based metal complex and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114395332B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278889A (en) * | 2000-02-18 | 2008-10-08 | Basf公司 | Cosmetic or dermatological sunscreens |
| CN104530985A (en) * | 2014-12-23 | 2015-04-22 | 中国海洋大学 | Rosin metal salt resin as well as preparation method and application thereof |
| CN107324988A (en) * | 2017-07-11 | 2017-11-07 | 山东亿嘉农化有限公司 | The preparation method of resin acid zinc, the resin acid zinc prepared and application |
| CN108587473A (en) * | 2018-04-13 | 2018-09-28 | 周文辽 | The synthetic method of modified chlorofluorination lithium base disproportionated rosin and its application in metal working fluid |
| US20180333347A1 (en) * | 2017-05-16 | 2018-11-22 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Photochemically stable, non-leaching sunscreens from epoxide-based silane coupling agents and uv absorbing chromophores |
| CN112047830A (en) * | 2020-09-22 | 2020-12-08 | 广西茂源科技有限公司 | Preparation method and application of calcium rosinate |
| US20210212250A1 (en) * | 2016-07-06 | 2021-07-15 | Crop Enhancement, Inc. | Nontoxic coating concentrates for agricultural uses |
-
2022
- 2022-01-29 CN CN202210110755.1A patent/CN114395332B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278889A (en) * | 2000-02-18 | 2008-10-08 | Basf公司 | Cosmetic or dermatological sunscreens |
| CN104530985A (en) * | 2014-12-23 | 2015-04-22 | 中国海洋大学 | Rosin metal salt resin as well as preparation method and application thereof |
| US20210212250A1 (en) * | 2016-07-06 | 2021-07-15 | Crop Enhancement, Inc. | Nontoxic coating concentrates for agricultural uses |
| US20180333347A1 (en) * | 2017-05-16 | 2018-11-22 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Photochemically stable, non-leaching sunscreens from epoxide-based silane coupling agents and uv absorbing chromophores |
| CN107324988A (en) * | 2017-07-11 | 2017-11-07 | 山东亿嘉农化有限公司 | The preparation method of resin acid zinc, the resin acid zinc prepared and application |
| CN108587473A (en) * | 2018-04-13 | 2018-09-28 | 周文辽 | The synthetic method of modified chlorofluorination lithium base disproportionated rosin and its application in metal working fluid |
| CN112047830A (en) * | 2020-09-22 | 2020-12-08 | 广西茂源科技有限公司 | Preparation method and application of calcium rosinate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114395332B (en) | 2024-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101238806B (en) | Fruit tree protection glue for preventing fruit tree disease scar and wound generated by pruning from rot | |
| CN108467631B (en) | Neutral white paint containing drug carrier and preparation method thereof | |
| CN111838155B (en) | Cell signal guide fruit colorant | |
| DE2745893A1 (en) | METHOD FOR MANUFACTURING A PHTHALOCYANINE PIGMENT | |
| CN104291977A (en) | Method for producing fruit leaf fertilizer by utilizing sisal hemp waste water | |
| CN104030813A (en) | Active controlled-release composite fertilizer containing wine cellar mud | |
| CN104446918A (en) | Method for manufacturing soilless culture substrate by utilizing apple tree fruit drop | |
| EP2546310A1 (en) | New sustainable range of sulfur dyes for textile and paper dyeing | |
| CN114395332B (en) | Rosin-based metal complex and application thereof | |
| CN113698249A (en) | Preparation method of organic amino acid liquid calcium fertilizer | |
| CN104030783B (en) | A kind of organic-inorganic compound slow-release fertilizer strengthening soil activation | |
| CN105850415A (en) | Planting method for pollution-free peppers | |
| CN104030784B (en) | A kind of long-acting slow-release compound fertilizers being rich in organic matter | |
| CN104151071A (en) | Slow-release composite fertilizer capable of preventing crop premature senility and pest and disease damage | |
| CN107410351B (en) | Regulating agent for grapes | |
| CN102715481A (en) | Method for processing salted mustard | |
| KR101751427B1 (en) | Textile dyeing method using fermentation and dyeing textile | |
| CN114009435B (en) | Flower thinning agent for apple trees and preparation method thereof | |
| CN110301447B (en) | Composition for improving fruit setting rate of fruit trees and application thereof | |
| CN109328822A (en) | The cultural method of tea shoot yellow | |
| CN112997780A (en) | Orange sun-proof and sun-proof material | |
| CN114736562B (en) | Method for preventing sunscald and whitening of citrus | |
| CN108658676A (en) | A kind of vegetable growth upgrading agent and preparation method thereof | |
| CN104186271A (en) | Method for cultivating grapes | |
| CN110734324A (en) | Cow dung organic fertilizer and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |