CN114262207B - A kind of composite material health-care ceramic tea set and preparation method thereof - Google Patents

Abstract

The invention provides a composite material health-care ceramic tea set which comprises the following components in percentage by weight: a pottery blank: 35-50% of kaolin, 10-20% of clay, 12-22% of quartz, 3-5% of magnesia, 10-20% of medical stone, 5-10% of stone needle, 1-3% of barium oxide, 1-2% of titanium oxide and 0.2-0.4% of zirconium oxide; glaze material: 25-35% of medical stone, 10-20% of feldspar, 5-10% of talc, 10-15% of calcite, 15-20% of quartz, 5-10% of stone needle, 5-8% of kaolin, 1-2% of titanium oxide, 2-3% of lanthanide metal oxide and 0.3-0.6% of zirconium oxide. The preparation method of the ceramic tea set also provides a preparation method of the ceramic tea set, which comprises the steps of blank preparation, glaze blending, glazing and firing. Through the improvement of the two aspects of the component formula and the preparation process, after more inorganic silicate and carbonate health-care materials are added into the glaze layer of the ceramic tea set, the equivalent structural strength and the quality of the glaze layer can still be ensured, and simultaneously, more health-care materials are added, so that the health-care materials can be more fully contacted with the contained liquid, and the ceramic tea set has better health-care effect.

Description

A kind of composite material health-care ceramic tea set and preparation method thereof

technical field

The invention relates to the technical field of ceramic tea utensils, in particular to a composite material health-care ceramic tea utensil and a preparation method thereof.

Background technique

The silicate and carbonate materials of inorganic non-metallic minerals have some health care functions according to the mineral structure and composition characteristics. Among them, such as the medical stone, Li Shizhen recorded in the "Compendium of Materia Medica": "The medical stone is found everywhere in the mountains and streams, and its size varies, or as a palm, or as a cup, or as a cake, roughly shaped like a reunion Maifan has grains like stones, like rice, and its color is yellow and white, but it is the one who looks for this shape in the granite stones in the streams." He also said: "The Maifan stone is sweet, warm, and non-toxic, and it is mainly used for all pains, gangrene, and back. "Modern research shows that it has a mesh-like structure with developed pores, which can dissolve the macro and trace elements needed by the human body; it also has adsorption capacity, which can remove toxic and harmful heavy metals, organic matter, bacteria, viruses and odors; its The leaching substance has biological activity; it makes the pH value of the water (liquid) treated by it have bidirectional adjustment ability. This is the characteristics of medical stone's dissolution function, adsorption function, self-two-way adjustment of pH value, and biological activity. Another mineral is Bianstone, the mineral composition is low-magnesium calcite, and the chemical composition is calcium carbonate.

The above-mentioned silicate material with health care function is added to the raw materials of ceramic products, mixed with kaolin, quartz, clay and magnesia, and fired into a tea vessel through a ceramic manufacturing process. This tea set has the function of dissolution, adsorption, self-two-way adjustment of pH value, biological activity, and becomes a health care ceramic.

In the prior art, there have been many technical processes for adding the above-mentioned health care materials into ceramics, but this technical process still has certain problems. In the existing process, the silicate material is mainly added to the pottery body, not the glaze layer, so that in actual use, due to the obstruction of the glaze layer, it cannot directly contact with the liquid contained, so trace elements are dissolved. , removal of heavy metals and organic matter, pH adjustment and other functions cannot be carried out effectively. If the above materials are directly added to the glaze layer, because it contains some carbonates, especially calcium carbonate, it will not only affect the overall structure of the glaze layer during firing, making the glaze layer easy to foam, and calcium ions themselves will also It is not easy to form a glassy structure, so that the overall structural strength of the glaze layer is damaged, and it is easy to break and fall off after a long time of use. Therefore, there is a need for a better health-care ceramic tea set.

SUMMARY OF THE INVENTION

Aiming at the deficiencies in the prior art, the present invention provides a composite material health-care ceramic teaware, which solves the problem that the glaze layer does not contain health-care materials in the prior art, resulting in poor health-care effect. At the same time, it also solves the structural strength problem that may be caused by adding health care materials to the glaze layer.

According to an embodiment of the present invention, a composite health-care ceramic tea set includes the following components by weight:

Pottery blanks: kaolin 35-50%, clay 10-20%, quartz 12-22%, magnesia 3-5%, medical stone 10-20%, Bianstone 5-10%, barium oxide 1-3%, Titanium oxide 1-2%, zirconium oxide 0.2-0.4%;

Glaze: Maifan Stone 25-35%, Feldspar 10-20%, Talc 5-10%, Calcite 10-15%, Quartz 15-20%, Bianstone 5-10%, Kaolin 5-8%, Titanium Oxide 1-2%, lanthanide metal oxide 2-3%, zirconia 0.3-0.6%.

Preferably, the lanthanide metal oxides include cerium oxide and neodymium oxide.

Further, the glaze also includes 2-5% of barium carbonate by total mass.

The present invention also proposes a preparation method of the above-mentioned composite material health-care ceramic teaware, comprising the following steps:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, grind them in a wet ball mill, and then put them into a slurry tank for stirring and storage;

S1.2. Use the mud pump to pump the mud to the filter press for dehydration. After the mud cake moisture is 25-28%, it is squeezed and compacted into mud bars in the mud drill, and dragged into the mud silo to homogenize and stale for 25-35%. sky;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: weigh the raw materials according to the proportion, grind them in a wet ball mill, and then put them into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze is applied by spraying glaze and dipping method, the concentration of glaze slurry is 1.55 Baume degree, and the thickness of glaze layer is 1-1.5mm, to obtain a crude product, and then dry it for later use;

S4. Firing: put the crude product obtained in S3 into a high-temperature kiln, heat it at 1240-1260°C for 10-12 hours, and cool it out of the kiln to obtain the finished product.

Preferably, the step S4 is as follows:

The crude product prepared in S3 is put into a high temperature kiln, first heated to 660°C and heated for 2h, then heated to 750°C and heated for 2h, finally heated to 1240-1260°C for 10-12h, and finally cooled out of the kiln to obtain the finished product.

Preferably, in the step S1.1, the ball milling process is specifically ball milled for 24 hours in a ratio of: ball: water = 1: (1.5-2): (0.7-0.9), and the grinding fineness is 10,000-hole sieve 2-4%.

Preferably, in the step S2, the ball milling process is specifically pulverized in the ratio of material: ball: water = 1: (1.8-2): (0.5-0.7), the ball milling time is 48 hours, and the grinding fineness is 10,000-hole sieve 0.2-0.4%.

The technical principle of the present invention is:

In the present invention, titanium oxide and zirconium oxide are added to the glaze layer, so that when the glaze layer forms glassy crystals at high temperature, a perovskite zircon phase can be formed, which has a more stable crystal structure than traditional materials; For lanthanide metal oxides, lanthanide metal ions can partially replace the vacancies of calcium ions in the crystal structure during high-temperature sintering, thereby increasing the lattice parameters and forming a higher density of the glaze layer.

Compared with the prior art, the present invention has the following beneficial effects:

1. The titanium oxide and zirconium oxide added in the present invention can form a perovskite zircon phase together with calcium carbonate during the sintering process, which is more stable than the silicate oxyapatite phase existing in the traditional glaze layer. Therefore, after adding calcium carbonate, it can still form a stable glassy crystal structure while having a certain health care effect, so as to prepare a glaze layer with high strength and structural temperature;

2. In the present invention, lanthanide metal ions are also added, which can partially replace the vacancies of calcium ions in the crystal structure during high-temperature sintering, so that the lattice parameters are increased, and the density of the formed glaze layer is higher. The glaze layer is denser, has higher structural strength, and has a tighter connection with the pottery body;

3. In the preparation process of the present invention, the temperature is first heated to 660°C, then heated to 750°C, and finally heated to 1240-1260°C, wherein 660°C is the nucleation temperature of the perovskite zircon phase glass body, and 750°C ℃ is the crystallization temperature. Through this stepwise heating, the added titanium oxide and zirconium oxide can better form the perovskite zircon phase, so as to avoid its mixing in the silicate oxyapatite phase, which is difficult to form a regular crystal structure , so that the internal crystal form of the prepared glaze layer is more regular and the structural strength is higher.

4. The present invention improves both the ingredient formula and the preparation process, so that the ceramic tea vessel of the present invention can still ensure considerable structural strength and glaze after adding more inorganic silicate and carbonate health care materials into the glaze layer. The quality of the layer is improved, and more health-care materials are added at the same time, so that the health-care materials can be more fully contacted with the contained liquid, and has better health-care effects than the prior art.

Detailed ways

The technical solutions in the present invention are further described below in conjunction with the examples.

Example 1:

In the present embodiment, the proportions of raw materials are as follows:

Pottery blanks: 50% kaolin, 10% clay, 17% quartz, 3% magnesia, 10% medical stone, 5.6% Bianstone, 2% barium oxide, 2% titanium oxide, 0.4% zirconia;

Glaze: Maifan Stone 25%, Feldspar 15%, Talc 10%, Calcite 15%, Quartz 16%, Bianstone 5%, Kaolin 5.5%, Titanium Oxide 1%, Zirconia 0.5%, Barium Carbonate 5%, Oxide Cerium 1%, Neodymium oxide 1%.

In the present embodiment, the following techniques are used to prepare composite health-care ceramic teaware:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, in the wet ball mill, ball mill and pulverize for 24 hours in the ratio of material: ball: water = 1:1.5:0.7, the grinding fineness is 3% of the 10,000-hole sieve, and then put in the material Slurry tank mixing and storage;

S1.2. Use a mud pump to pump the mud to the filter press for dehydration. After the mud cake has a moisture content of 28%, it is squeezed into mud bars in the mud drill, and dragged into the mud silo for homogenization and aging for 25 days;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: Weigh the raw materials according to the proportion. In a wet ball mill, pulverize them in the ratio of material: ball: water = 1: 1.9: 0.6. The ball milling time is 48 hours, and the fineness of the sieve is 0.4%. Then put it into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze by spray glaze and dipping method, the concentration of the glaze slurry is 1.55 Baume degrees, and the thickness of the glaze layer is 1mm to obtain a crude product, which is then dried for later use;

S4. Firing: put the crude product prepared in S3 into a high-temperature kiln, first heated to 660°C and heated for 2h, then heated to 750°C and heated for 2h, finally heated to 1250°C for 12h, and finally cooled out of the kiln to obtain the finished product .

Example 2:

In the present embodiment, the proportions of raw materials are as follows:

Pottery blanks: kaolin 38%, clay 20%, quartz 12%, magnesia 5%, medical stone 15%, Bianstone 7.2%, barium oxide 1%, titanium oxide 1.5%, zirconia 0.3%;

Glaze: Maifan Stone 28%, Feldspar 10%, Talc 8%, Calcite 13%, Quartz 20%, Bianstone 6%, Kaolin 5.7%, Titanium Oxide 2%, Zirconia 0.3%, Barium Carbonate 4%, Oxide Cerium 1%, Neodymium oxide 2%.

In the present embodiment, the following techniques are used to prepare composite health-care ceramic teaware:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, in the wet ball mill, ball mill and pulverize for 24 hours in the ratio of material: ball: water = 1:1.8:0.8, the fineness of the grinding is 4% of the 10,000-hole sieve, and then put in the material Slurry tank mixing and storage;

S1.2. Use the mud pump to pump the mud to the filter press for dehydration. After the mud cake moisture is 25%, it is squeezed into mud sticks in the mud drill, and then dragged into the mud silo for homogenization and aging for 30 days;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: Weigh the raw materials according to the proportion. In a wet ball mill, pulverize them in the ratio of material: ball: water = 1:2:0.7. The ball milling time is 48 hours, and the grinding fineness is 0.2% of the 10,000-hole screen. Then put it into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze by spray glaze and dipping method, the concentration of glaze slurry is 1.55 Baume degree, and the thickness of glaze layer is 1.2mm, to obtain crude product, and then dry it for later use;

S4. Firing: put the crude product prepared in S3 into a high-temperature kiln, first heated to 660 °C and heated for 2 hours, then heated to 750 °C and heated for 2 hours, and finally heated to 1260 °C for 10 hours, and finally cooled out of the kiln to obtain the finished product .

Example 3:

In the present embodiment, the proportions of raw materials are as follows:

Pottery blanks: kaolin 40%, clay 11.8%, quartz 22%, magnesia 4%, medical stone 10%, Bianstone 8%, barium oxide 3%, titanium oxide 1%, zirconia 0.2%;

Glaze: Maifan Stone 30%, Feldspar 12%, Talc 5%, Calcite 10%, Quartz 18%, Bianstone 10%, Kaolin 8%, Titanium Oxide 2%, Zirconia 0.5%, Barium Carbonate 2%, Oxide Cerium 1.5%, Neodymium oxide 1%.

In the present embodiment, the following techniques are used to prepare composite health-care ceramic teaware:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, in the wet ball mill, ball mill and pulverize for 24 hours in the ratio of material: ball: water = 1:2:0.9, the grinding fineness is 2% of the 10,000-hole sieve, and then put the material Slurry tank mixing and storage;

S1.2. Use the mud pump to pump the mud to the filter press for dehydration. After the mud cake has a moisture content of 26%, it is squeezed into mud bars in the mud drill, and dragged into the mud silo for homogenization and aging for 35 days;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: Weigh the raw materials according to the proportion, in a wet ball mill, crush them in the ratio of material: ball: water = 1: 1.8: 0.5, the ball milling time is 48 hours, and the grinding fineness is 0.3% of the 10,000-hole sieve. Then put it into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze is applied by spraying glaze and dipping method, the concentration of glaze slurry is 1.55 Baume degree, and the thickness of glaze layer is 1.5mm to obtain crude product, which is then dried for later use;

S4. Firing: put the crude product prepared in S3 into a high temperature kiln, first heated to 660°C and heated for 2h, then heated to 750°C and heated for 2h, finally heated to 1240°C and heated for 11h, and finally cooled out of the kiln to obtain the finished product .

Example 4:

In the present embodiment, the proportions of raw materials are as follows:

Pottery blanks: kaolin 42%, clay 11%, quartz 13.6%, magnesia 4%, medical stone 20%, Bianstone 5%, barium oxide 2%, titanium oxide 2%, zirconia 0.4%;

Glaze: Maifan Stone 35%, Feldspar 11%, Talc 6%, Calcite 11.4%, Quartz 15%, Bianstone 8%, Kaolin 6%, Titanium Oxide 1.5%, Zirconia 0.6%, Barium Carbonate 3.5%, Oxide Cerium 1.2%, neodymium oxide 0.8%.

In the present embodiment, the following techniques are used to prepare composite health-care ceramic teaware:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, in the wet ball mill, ball mill and pulverize for 24 hours in the ratio of material: ball: water = 1:2:0.7, the fineness of the grinding is 4% of the 10,000-hole sieve, and then put in the material Slurry tank mixing and storage;

S1.2. Use a mud pump to pump the mud to the filter press for dehydration. After the mud cake has a moisture content of 28%, it is squeezed into mud bars in the mud drill, and then dragged into the mud silo for homogenization and aging for 28 days;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: Weigh the raw materials according to the proportion, and crush them in a wet ball mill in the ratio of material: ball: water = 1: 1.8: 0.7, the ball milling time is 48 hours, and the grinding fineness is 0.2% of the 10,000-hole sieve. Then put it into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze by spray glaze and dipping method, the concentration of the glaze slurry is 1.55 Baume degrees, and the thickness of the glaze layer is 1mm to obtain a crude product, which is then dried for later use;

S4. Firing: put the crude product prepared in S3 into a high-temperature kiln, first heated to 660 °C and heated for 2 hours, then heated to 750 °C and heated for 2 hours, and finally heated to 1260 °C for 10 hours, and finally cooled out of the kiln to obtain the finished product .

Example 5:

In the present embodiment, the proportions of raw materials are as follows:

Pottery blanks: kaolin 35%, clay 15%, quartz 17%, magnesia 5%, medical stone 15%, Bianstone 10%, barium oxide 1%, titanium oxide 1.7%, zirconia 0.3%;

Glaze: Maifan Stone 30%, Feldspar 20%, Talc 5.2%, Calcite 10.4%, Quartz 15.1%, Bianstone 5%, Kaolin 5%, Titanium Oxide 1%, Zirconia 0.3%, Barium Carbonate 5%, Oxide Cerium 1%, Neodymium oxide 2%.

In the present embodiment, the following techniques are used to prepare composite health-care ceramic teaware:

S1, blank preparation:

S1.1. Weigh the raw materials according to the proportion, in the wet ball mill, ball mill and pulverize for 24 hours in the ratio of material: ball: water = 1: 1.9: 0.9, the grinding fineness is 4% of the 10,000-hole sieve, and then put in the material Slurry tank mixing and storage;

S1.2. Use a mud pump to pump the mud to the filter press for dehydration. After the mud cake has a moisture content of 28%, it is squeezed and compacted into mud bars in the mud drill, and then dragged into the mud silo for homogenization and aging for 35 days;

S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity;

S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks;

S2. Glaze preparation: Weigh the raw materials according to the proportion. In a wet ball mill, pulverize them in the ratio of material: ball: water = 1:2:0.7. The ball milling time is 48 hours, and the grinding fineness is 0.2% of the 10,000-hole screen. Then put it into the glaze slurry tank for stirring and storage;

S3. Glazing:

S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform;

S3.2. Glaze by spray glaze and glaze dip method, the concentration of glaze slurry is 1.55 Baume degree, and the thickness of glaze layer is 1.3mm to obtain crude product, and then dry for use;

S4. Firing: put the crude product prepared in S3 into a high-temperature kiln, first heated to 660°C and heated for 2h, then heated to 750°C and heated for 2h, finally heated to 1240°C and heated for 10h, and finally cooled out of the kiln to obtain the finished product .

Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and not to limit them. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the technical solutions of the present invention can be Modifications or equivalent substitutions without departing from the spirit and scope of the technical solutions of the present invention should be included in the scope of the claims of the present invention.

Claims (7)

1. a composite material health-care ceramic tea utensil is characterized in that, comprises the following composition by weight percentage: Pottery blanks: kaolin 35-50%, clay 10-20%, quartz 12-22%, magnesia 3-5%, medical stone 10-20%, Bianstone 5-10%, barium oxide 1-3%, Titanium oxide 1-2%, zirconium oxide 0.2-0.4%; Glaze: Maifan Stone 25-35%, Feldspar 10-20%, Talc 5-10%, Calcite 10-15%, Quartz 15-20%, Bianstone 5-10%, Kaolin 5-8%, Titanium Oxide 1-2%, lanthanide metal oxide 2-3%, zirconia 0.3-0.6%. 2 . The composite health-care ceramic teaware of claim 1 , wherein the lanthanide series metal oxides include cerium oxide and neodymium oxide. 3 . 3 . The composite health-care ceramic tea utensil according to claim 2 , wherein the glaze also includes barium carbonate with a total mass of 2-5%. 4 . 4. a preparation method of composite health-care ceramic tea set as claimed in claim 1, is characterized in that, comprises the steps: S1, blank preparation: S1.1. Weigh the raw materials according to the proportion, grind them in a wet ball mill, and then put them into a slurry tank for stirring and storage; S1.2. Use the mud pump to pump the mud to the filter press for dehydration. After the mud cake moisture is 25-28%, it is squeezed and compacted into mud bars in the mud drill, and dragged into the mud silo to homogenize and stale for 25-35%. sky; S1.3. The homogenized mud strips are taken from the mud silo, and the vacuum treatment is repeated twice in the vacuum mud refining machine, and the air in the mud strips is extracted to further densify and improve the plasticity; S1.4. Cut the mud strips into sheets and form them mechanically or manually on a rolling forming machine or a blank drawing machine, and then after they are naturally dried, the blanks are trimmed to obtain refined blanks; S2. Glaze preparation: weigh the raw materials according to the proportion, grind them in a wet ball mill, and then put them into the glaze slurry tank for stirring and storage; S3. Glazing: S3.1. First blow off the dust on the dried fine blank, and then brush it with clean water to make the moisture adsorption on the surface of the blank uniform; S3.2. Glaze is applied by spraying glaze and dipping method, the concentration of glaze slurry is 1.55 Baume degree, and the thickness of glaze layer is 1-1.5mm, to obtain a crude product, and then dry it for later use; S4. Firing: put the crude product obtained in S3 into a high-temperature kiln, heat it at 1240-1260°C for 10-12 hours, and cool it out of the kiln to obtain the finished product. 5. the preparation method of a kind of composite material health-care ceramic tea set as claimed in claim 4, is characterized in that, described step S4 is as follows: The crude product prepared in S3 is put into a high temperature kiln, first heated to 660°C and heated for 2h, then heated to 750°C and heated for 2h, finally heated to 1240-1260°C for 10-12h, and finally cooled out of the kiln to obtain the finished product. 6. the preparation method of a kind of composite material health-care ceramic tea set as claimed in claim 4, is characterized in that: in described step S1.1, ball milling process is specifically with material: ball: water=1:(1.5-2): (0.7-0.9) in a ball mill for 24 hours, and the mill fineness is 2-4% of the 10,000-hole sieve. 7. the preparation method of a kind of composite material health-care ceramic tea set as claimed in claim 4, is characterized in that: in described step S2, ball milling process is concretely with material: ball: water=1:(1.8-2):(0.5 -0.7), the ball milling time is 48 hours, and the grinding fineness is 0.2-0.4% of the 10,000-hole sieve.