CN114262207B - Composite material health-care ceramic tea set and preparation method thereof - Google Patents
Composite material health-care ceramic tea set and preparation method thereof Download PDFInfo
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Abstract
The invention provides a composite material health-care ceramic tea set which comprises the following components in percentage by weight: a pottery blank: 35-50% of kaolin, 10-20% of clay, 12-22% of quartz, 3-5% of magnesia, 10-20% of medical stone, 5-10% of stone needle, 1-3% of barium oxide, 1-2% of titanium oxide and 0.2-0.4% of zirconium oxide; glaze material: 25-35% of medical stone, 10-20% of feldspar, 5-10% of talc, 10-15% of calcite, 15-20% of quartz, 5-10% of stone needle, 5-8% of kaolin, 1-2% of titanium oxide, 2-3% of lanthanide metal oxide and 0.3-0.6% of zirconium oxide. The preparation method of the ceramic tea set also provides a preparation method of the ceramic tea set, which comprises the steps of blank preparation, glaze blending, glazing and firing. Through the improvement of the two aspects of the component formula and the preparation process, after more inorganic silicate and carbonate health-care materials are added into the glaze layer of the ceramic tea set, the equivalent structural strength and the quality of the glaze layer can still be ensured, and simultaneously, more health-care materials are added, so that the health-care materials can be more fully contacted with the contained liquid, and the ceramic tea set has better health-care effect.
Description
Technical Field
The invention relates to the technical field of ceramic tea wares, in particular to a composite material health-care ceramic tea ware and a preparation method thereof.
Background
The silicate and carbonate material of inorganic non-metal mineral has some health preserving and health care functions according to the characteristics of mineral structure and components, and the material is commonly called 'medicinal stone' and also called 'saint stone'. Among them, for example, Maifanitum, Li Shizhen records the following in "compendium of materia Medica": "Maifanshi mountain stream is different in size, such as palm, marigold, or cake, roughly like a cluster of Maifanshi, and has grains such as stone, rice, yellow and white, but it is found in mountain stream. "say again: maifanshi, sweet in smell, warm and non-toxic, is indicated for all kinds of deep rooted carbuncle and dorsal furuncle. Modern research shows that the material has a screen-shaped structure with developed pores, and can dissolve out major elements and trace elements required by a human body; but also has adsorption capacity, and can remove toxic and harmful heavy metals, organic matters, bacteria, viruses and peculiar smell; its extract has biological activity; so that the pH value of the water (liquid) treated by the water treatment agent has bidirectional adjusting capability. The medical stone has the characteristics of dissolution function, adsorption function, automatic bidirectional pH value adjusting function and biological activity. The other mineral is stone needle, the mineral composition is low-magnesium calcite, the chemical composition is calcium carbonate, and the microcrystalline limestone is mostly used as a traditional Chinese medicine physical therapy and health care product.
The silicate material with health preserving and health care functions is added into ceramic raw materials of ceramics, mixed with kaolin, quartz, clay and magnesia soil for use, and fired into the tea set by a ceramic manufacturing process. The tea set has the functions of dissolution, adsorption, automatic bidirectional pH value adjustment and biological activity, and becomes health-care ceramic.
There are many technical processes for adding the above health care materials to ceramics in the prior art, but there are certain problems in the technical processes. In the prior art, silicate materials are mainly added into a ceramic body instead of a glaze layer, so that in actual use, the silicate materials cannot be directly contacted with liquid contained in the ceramic body due to the blocking of the glaze layer, and therefore, the functions of dissolving trace elements, removing heavy metals and organic matters, adjusting pH and the like cannot be effectively performed. If the materials are directly added into the glaze layer, the whole structure of the glaze layer is affected during firing due to the partial carbonate, especially calcium carbonate, so that the glaze layer is easy to foam, and the calcium ions are not easy to form a glassy structure, so that the whole structure strength of the glaze layer is damaged, and the glaze layer is easy to break and fall off after long use. Therefore, a better health-care ceramic tea set is needed.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a composite material health-care ceramic tea set, which solves the problem that the glaze layer does not contain health-care materials in the prior art, so that the final health-care effect is poor, and also solves the problem of structural strength possibly caused by adding the health-care materials in the glaze layer.
According to the embodiment of the invention, the composite material health-care ceramic tea set comprises the following components in percentage by weight:
a pottery blank: 35-50% of kaolin, 10-20% of clay, 12-22% of quartz, 3-5% of magnesia, 10-20% of medical stone, 5-10% of stone needle, 1-3% of barium oxide, 1-2% of titanium oxide and 0.2-0.4% of zirconium oxide;
glaze material: 25-35% of medical stone, 10-20% of feldspar, 5-10% of talc, 10-15% of calcite, 15-20% of quartz, 5-10% of stone needle, 5-8% of kaolin, 1-2% of titanium oxide, 2-3% of lanthanide metal oxide and 0.3-0.6% of zirconium oxide.
Preferably, the lanthanide metal oxide includes cerium oxide and neodymium oxide.
Further, the glaze also comprises 2-5% of barium carbonate by mass.
The invention also provides a preparation method of the composite material health-care ceramic tea set, which comprises the following steps:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, performing ball milling processing in a wet ball mill, and then putting the raw materials into a slurry tank for stirring and storage;
s1.2, pumping the slurry into a filter-pressing mud machine by a slurry pump, performing filter pressing and dehydration, extruding and compacting mud cakes into mud strips in a mud mill after the mud cakes have 25-28% of water, and dragging the mud strips into a mud warehouse for homogenization and ageing for 25-35 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, glaze blending: weighing raw materials according to a ratio, ball-milling in a wet ball mill, and then placing into a glaze slurry tank for stirring and storing;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1-1.5mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating for 10-12h at 1240 and 1260 ℃, cooling and then taking out of the kiln to obtain a finished product.
Preferably, the step S4 is specifically as follows:
and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1240-1260 ℃ for 10-12h, and cooling to obtain a finished product.
Preferably, in the step S1.1, the ball milling process specifically comprises the following steps: ball: the water accounts for 1, (1.5-2) and (0.7-0.9) and the ball milling is carried out for 24 hours, and the milling fineness is 2-4% of ten thousand mesh sieve residue.
Preferably, in step S2, the ball milling process specifically includes: ball: the water accounts for 1 to 1, the proportion of (1.8-2) to (0.5-0.7) is crushed, the ball milling time is 48 hours, and the fineness of the obtained product is 0.2-0.4 percent of ten thousand mesh sieve residue.
The technical principle of the invention is as follows:
according to the invention, titanium oxide and zirconium oxide are added into the glaze layer, so that a perovskite phase can be formed when the glaze layer forms glassy state crystals at high temperature, and the glaze layer has a more stable crystal structure compared with the traditional material; lanthanide metal oxide is added into the glaze layer, and lanthanide metal ions can partially replace vacancies of calcium ions in a crystal structure in the high-temperature sintering process, so that the lattice parameter is increased, and the formed glaze layer has higher density.
Compared with the prior art, the invention has the following beneficial effects:
1. the added titanium oxide and zirconium oxide can form a perovskite phase together with calcium carbonate in the sintering process, and have a more stable crystal structure compared with a silicate hydroxyapatite phase existing in a traditional glaze layer, so that after the calcium carbonate component is added, a stable glassy crystal structure can be still formed while a certain health-care effect is achieved, and a glaze layer with high strength and structural temperature is prepared;
2. lanthanide series metal ions are added in the invention, and can partially replace vacancies of calcium ions in a crystal structure in the high-temperature sintering process, so that the lattice parameter is increased, the density of the formed glaze layer is higher, and the obtained glaze layer is more compact, has higher structural strength and is more tightly connected with a ceramic body;
3. in the preparation process, the raw materials are heated to 660 ℃, then heated to 750 ℃ and finally heated to 1240-1260 ℃, wherein the 660 ℃ is the nucleation temperature of the perovskite phase glass body, and the 750 ℃ is the crystallization temperature of the perovskite phase glass body.
4. Through the improvement of two aspects of component formula and preparation process, after more inorganic silicate and carbonate health-care materials are added into the glaze layer, the ceramic tea set still can ensure equivalent structural strength and glaze layer quality, and simultaneously more health-care materials are added, so that the health-care materials can be more fully contacted with contained liquid, and the ceramic tea set has better health-care effect compared with the prior art.
Detailed Description
The technical solution of the present invention is further illustrated by the following examples.
Example 1:
the raw materials in the example are as follows:
a pottery blank: 50% of kaolin, 10% of clay, 17% of quartz, 3% of magnesia, 10% of medical stone, 5.6% of stone needle, 2% of barium oxide, 2% of titanium oxide and 0.4% of zirconium oxide;
glaze material: 25% of medical stone, 15% of feldspar, 10% of talc, 15% of calcite, 16% of quartz, 5% of stone needle, 5.5% of kaolin, 1% of titanium oxide, 0.5% of zirconium oxide, 5% of barium carbonate, 1% of cerium oxide and 1% of neodymium oxide.
In the embodiment, the composite health-care ceramic tea set is prepared by adopting the following process:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, and in a wet ball mill, mixing the raw materials: ball: ball milling and crushing for 24 hours according to the proportion of 1:1.5:0.7, wherein the fineness of the obtained product is 3% of ten thousand mesh screen residue, and then placing the product into a slurry pool to be stirred and stored;
s1.2, pumping the slurry into a filter-press mud machine by a mud pump, performing filter pressing and dehydration, extruding and compacting a mud cake with 28% of water into mud strips in a pug mill, and dragging the mud strips into a mud warehouse for homogenizing and ageing for 25 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, glaze blending: weighing raw materials according to the proportion, and in a wet ball mill, mixing the raw materials: ball: crushing the mixture according to the proportion of 1:1.9:0.6, ball-milling for 48 hours until the fineness of the obtained product is 0.4% of ten thousand meshes of screen residue, and then placing the product into a glaze slurry pool to be stirred and stored;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1250 ℃ for 12h, cooling and discharging to obtain a finished product.
Example 2:
the raw materials in the example are as follows:
a pottery blank: 38% of kaolin, 20% of clay, 12% of quartz, 5% of magnesia, 15% of medical stone, 7.2% of stone needle, 1% of barium oxide, 1.5% of titanium oxide and 0.3% of zirconium oxide;
glaze material: 28% of medical stone, 10% of feldspar, 8% of talc, 13% of calcite, 20% of quartz, 6% of stone needle, 5.7% of kaolin, 2% of titanium oxide, 0.3% of zirconium oxide, 4% of barium carbonate, 1% of cerium oxide and 2% of neodymium oxide.
In the embodiment, the composite health-care ceramic tea set is prepared by adopting the following process:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, and in a wet ball mill, mixing the raw materials: ball: ball-milling and crushing the mixture for 24 hours according to the proportion of 1:1.8:0.8, wherein the fineness of the obtained product is 4% of ten thousand mesh screen residue, and then placing the product into a slurry tank to be stirred and stored;
s1.2, pumping the slurry into a filter-press mud machine by a mud pump, performing filter pressing and dehydration, extruding and compacting a mud cake with 25% of water into mud strips in a pug mill, and dragging the mud strips into a mud warehouse for homogenization and aging for 30 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, glaze blending: weighing raw materials according to the proportion, and in a wet ball mill, mixing the raw materials: ball: crushing with water in the ratio of 1:2:0.7 for 48 hours until the fineness of the ball is 0.2% of ten thousand holes of screen residue, and then placing the mixture into a glaze slurry pool to be stirred and stored;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1.2mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the step (S3) into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1260 ℃ for 10h, cooling and discharging to obtain a finished product.
Example 3:
the raw materials in the example are as follows:
a pottery blank: 40% of kaolin, 11.8% of clay, 22% of quartz, 4% of magnesia, 10% of medical stone, 8% of stone needle, 3% of barium oxide, 1% of titanium oxide and 0.2% of zirconium oxide;
glaze material: 30% of medical stone, 12% of feldspar, 5% of talc, 10% of calcite, 18% of quartz, 10% of stone needle, 8% of kaolin, 2% of titanium oxide, 0.5% of zirconium oxide, 2% of barium carbonate, 1.5% of cerium oxide and 1% of neodymium oxide.
In the embodiment, the composite health-care ceramic tea set is prepared by adopting the following process:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, and in a wet ball mill, mixing the raw materials: ball: ball-milling and crushing for 24 hours at the ratio of 1:2:0.9 until the fineness of the obtained product is 2% of ten thousand mesh screen residue, and then placing the product into a slurry pool to be stirred and stored;
s1.2, pumping the slurry into a filter-pressing mud machine by a slurry pump, performing filter pressing dehydration, extruding and compacting mud cakes into mud strips in a mud mill after the mud cakes contain 26 percent of water, and dragging the mud strips into a mud warehouse for homogenization and ageing for 35 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, glaze blending: weighing raw materials according to the proportion, and in a wet ball mill, mixing the raw materials: ball: crushing the mixture according to the proportion of 1:1.8:0.5, ball-milling for 48 hours until the fineness of the obtained product is 0.3 percent of ten thousand-hole screen residue, and then placing the product into a glaze slurry pool to be stirred and stored;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1.5mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1240 ℃ for 11h, cooling and discharging to obtain a finished product.
Example 4:
the raw materials in the example are as follows:
a pottery blank: 42% of kaolin, 11% of clay, 13.6% of quartz, 4% of magnesia, 20% of medical stone, 5% of stone needle, 2% of barium oxide, 2% of titanium oxide and 0.4% of zirconium oxide;
glaze material: 35% of medical stone, 11% of feldspar, 6% of talc, 11.4% of calcite, 15% of quartz, 8% of stone needle, 6% of kaolin, 1.5% of titanium oxide, 0.6% of zirconium oxide, 3.5% of barium carbonate, 1.2% of cerium oxide and 0.8% of neodymium oxide.
In the embodiment, the composite health-care ceramic tea set is prepared by adopting the following process:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, and in a wet ball mill, mixing the raw materials: ball: ball-milling and crushing for 24 hours at the ratio of 1:2:0.7 until the fineness of the obtained product is 4% of ten thousand mesh screen residue, and then placing the product into a slurry pool to be stirred and stored;
s1.2, pumping the slurry into a filter-press mud machine by a mud pump, performing filter pressing and dehydration, extruding and compacting a mud cake with 28% of water into mud strips in a pug mill, and dragging the mud strips into a mud warehouse for homogenization and ageing for 28 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, blending glaze: weighing raw materials according to the proportion, and in a wet ball mill, mixing the raw materials: ball: crushing the mixture according to the proportion of 1:1.8:0.7, ball-milling for 48 hours until the fineness of the obtained product is 0.2% of ten thousand meshes of screen residue, and then placing the product into a glaze slurry pool to be stirred and stored;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the step (S3) into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1260 ℃ for 10h, cooling and discharging to obtain a finished product.
Example 5:
the raw materials in the example are as follows:
a pottery blank: 35% of kaolin, 15% of clay, 17% of quartz, 5% of magnesia, 15% of medical stone, 10% of stone needle, 1% of barium oxide, 1.7% of titanium oxide and 0.3% of zirconium oxide;
glaze material: 30% of medical stone, 20% of feldspar, 5.2% of talc, 10.4% of calcite, 15.1% of quartz, 5% of stone needle, 5% of kaolin, 1% of titanium oxide, 0.3% of zirconium oxide, 5% of barium carbonate, 1% of cerium oxide and 2% of neodymium oxide.
In the embodiment, the composite health-care ceramic tea set is prepared by adopting the following process:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, and in a wet ball mill, mixing the raw materials: ball: ball milling and crushing for 24 hours according to the proportion of 1:1.9:0.9, wherein the fineness of the obtained product is 4% of ten thousand mesh screen residue, and then placing the product into a slurry pool to be stirred and stored;
s1.2, pumping the slurry into a filter-press mud machine by a mud pump, performing filter pressing and dehydration, extruding and compacting a mud cake with 28% of water into mud strips in a pug mill, and dragging the mud strips into a mud warehouse for homogenization and ageing for 35 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the mud strips on a rolling forming machine or a blank drawing machine, and then after the mud strips are naturally dried, trimming the mud strips to obtain a finished blank;
s2, glaze blending: weighing raw materials according to the proportion, and in a wet ball mill, mixing the raw materials: ball: crushing with water in the ratio of 1:2:0.7 for 48 hours until the fineness of the ball is 0.2% of ten thousand holes of screen residue, and then placing the mixture into a glaze slurry pool to be stirred and stored;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing and washing the fine blank with clean water once to enable the moisture on the surface of the blank to be adsorbed uniformly;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1.3mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1240 ℃ for 10h, cooling and discharging to obtain a finished product.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.
Claims (7)
1. The composite material health-care ceramic tea set is characterized by comprising the following components in percentage by weight:
a pottery blank: 35-50% of kaolin, 10-20% of clay, 12-22% of quartz, 3-5% of magnesia, 10-20% of medical stone, 5-10% of stone needle, 1-3% of barium oxide, 1-2% of titanium oxide and 0.2-0.4% of zirconium oxide;
glaze material: 25-35% of medical stone, 10-20% of feldspar, 5-10% of talc, 10-15% of calcite, 15-20% of quartz, 5-10% of stone needle, 5-8% of kaolin, 1-2% of titanium oxide, 2-3% of lanthanide metal oxide and 0.3-0.6% of zirconium oxide.
2. The composite material health ceramic tea set as claimed in claim 1, wherein: the lanthanide metal oxides include cerium oxide and neodymium oxide.
3. The composite material health ceramic tea set as claimed in claim 2, wherein: the glaze also comprises barium carbonate with the total mass of 2-5%.
4. A method for preparing the composite material health care ceramic tea set according to claim 1, comprising the steps of:
s1, preparing a blank:
s1.1, weighing raw materials according to a ratio, performing ball milling processing in a wet ball mill, and then putting the raw materials into a slurry tank for stirring and storage;
s1.2, pumping the slurry into a filter-press mud machine by a mud pump, performing filter pressing and dehydration, extruding and compacting a mud cake with 25-28% of water into mud strips in a mud mill, and dragging the mud strips into a mud warehouse for homogenization and ageing for 25-35 days;
s1.3, repeatedly carrying out secondary vacuum-pumping treatment on the homogenized mud strips from the mud warehouse in a vacuum pug mill, and pumping out air in the mud strips to further compact the mud strips and improve plasticity;
s1.4, cutting the mud strips into sheets, mechanically or manually forming the sheets on a rolling forming machine or a blank drawing machine, and then after the sheets are naturally dried, trimming the sheets to obtain finished blanks;
s2, glaze blending: weighing raw materials according to a ratio, ball-milling in a wet ball mill, and then placing into a glaze slurry tank for stirring and storing;
s3, glazing:
s3.1, blowing dust off the dried fine blank, and then brushing the fine blank with clean water once to ensure that the moisture on the surface of the blank is uniformly adsorbed;
s3.2, glazing by using a glaze spraying and glaze dipping method, wherein the concentration of glaze slip is 1.55 baume degrees, the thickness of a glaze layer is 1-1.5mm, and a crude product is obtained and then dried for later use;
s4, sintering: and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating for 10-12h at 1240 and 1260 ℃, cooling and then taking out of the kiln to obtain a finished product.
5. The method for preparing a composite health ceramic tea set as claimed in claim 4, wherein the step S4 is as follows:
and (3) putting the crude product prepared in the S3 into a high-temperature kiln, heating to 660 ℃ for 2h, heating to 750 ℃ for 2h, heating to 1240-1260 ℃ for 10-12h, and cooling to obtain a finished product.
6. The method for preparing the composite material health care ceramic tea set as claimed in claim 4, wherein: in the step S1.1, the ball milling process specifically comprises the following steps: ball: the water accounts for 1, (1.5-2) and (0.7-0.9) and the ball milling is carried out for 24 hours, and the milling fineness is 2-4% of ten thousand mesh sieve residue.
7. The method for preparing the composite material health care ceramic tea set as claimed in claim 4, wherein: in the step S2, the ball milling process specifically comprises the following steps: ball: the water accounts for 1 to 1, the proportion of (1.8-2) to (0.5-0.7) is crushed, the ball milling time is 48 hours, and the fineness of the obtained product is 0.2-0.4 percent of ten thousand mesh sieve residue.
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Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396164A (en) * | 2013-07-25 | 2013-11-20 | 郑州大学 | High-temperature stereoscopic glaze and preparation method thereof |
| CN105016708A (en) * | 2015-08-11 | 2015-11-04 | 林俊生 | Functional live crystal porcelain and preparation method and application thereof |
| CN106430975A (en) * | 2016-10-21 | 2017-02-22 | 青岛首创嘉业工贸有限公司 | Active ceramic inner container and preparation method thereof |
| CN106477892A (en) * | 2016-10-21 | 2017-03-08 | 青岛首创嘉业工贸有限公司 | A kind of active ceramic cup and preparation method thereof |
| CN107382294A (en) * | 2017-09-18 | 2017-11-24 | 淄博华光陶瓷科技文化有限公司 | Beautiful porcelain of China and preparation method thereof |
| CN108751930A (en) * | 2018-05-03 | 2018-11-06 | 方厉远 | A kind of preparation method of artificial stone needle |
| CN109369146A (en) * | 2018-12-26 | 2019-02-22 | 江苏宜翔陶瓷科技有限公司 | A kind of preparation method of light sapphire glaze ceramic vessel |
| CN109574623A (en) * | 2018-11-28 | 2019-04-05 | 紫罗兰家纺科技股份有限公司 | A kind of production method of multi-functional pottery ball |
| CN109619939A (en) * | 2019-01-28 | 2019-04-16 | 福建省德化县陶缘茗陶瓷文化有限公司 | Contain teabowl with a cover, fair cup, filter screen integral type functionality tea set and preparation method |
| CN112159207A (en) * | 2020-10-09 | 2021-01-01 | 福建省德化县晖德陶瓷有限公司 | Pearl white ceramic product and preparation method thereof |
| CN113185128A (en) * | 2021-04-26 | 2021-07-30 | 中国船舶重工集团公司第七一九研究所 | Perovskite zircon glass ceramic curing substrate and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9290409B2 (en) * | 2012-12-23 | 2016-03-22 | King Abdulazia City for Science and Technology (KACST) | Glaze composition, method for manufacturing the glaze composition and methods of glazing |
-
2021
- 2021-12-31 CN CN202111671625.7A patent/CN114262207B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103396164A (en) * | 2013-07-25 | 2013-11-20 | 郑州大学 | High-temperature stereoscopic glaze and preparation method thereof |
| CN105016708A (en) * | 2015-08-11 | 2015-11-04 | 林俊生 | Functional live crystal porcelain and preparation method and application thereof |
| CN106430975A (en) * | 2016-10-21 | 2017-02-22 | 青岛首创嘉业工贸有限公司 | Active ceramic inner container and preparation method thereof |
| CN106477892A (en) * | 2016-10-21 | 2017-03-08 | 青岛首创嘉业工贸有限公司 | A kind of active ceramic cup and preparation method thereof |
| CN107382294A (en) * | 2017-09-18 | 2017-11-24 | 淄博华光陶瓷科技文化有限公司 | Beautiful porcelain of China and preparation method thereof |
| CN108751930A (en) * | 2018-05-03 | 2018-11-06 | 方厉远 | A kind of preparation method of artificial stone needle |
| CN109574623A (en) * | 2018-11-28 | 2019-04-05 | 紫罗兰家纺科技股份有限公司 | A kind of production method of multi-functional pottery ball |
| CN109369146A (en) * | 2018-12-26 | 2019-02-22 | 江苏宜翔陶瓷科技有限公司 | A kind of preparation method of light sapphire glaze ceramic vessel |
| CN109619939A (en) * | 2019-01-28 | 2019-04-16 | 福建省德化县陶缘茗陶瓷文化有限公司 | Contain teabowl with a cover, fair cup, filter screen integral type functionality tea set and preparation method |
| CN112159207A (en) * | 2020-10-09 | 2021-01-01 | 福建省德化县晖德陶瓷有限公司 | Pearl white ceramic product and preparation method thereof |
| CN113185128A (en) * | 2021-04-26 | 2021-07-30 | 中国船舶重工集团公司第七一九研究所 | Perovskite zircon glass ceramic curing substrate and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 固相法合成榍石及作为陶瓷乳浊剂的研究;张童;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20180715(第7期);第B015-214页 * |
| 掺钕钙钛锆石基玻璃陶瓷制备及浸出性能研究;吴浪 等;《原子能科学技术》;20141130;第48卷(第11期);第1943-1948页 * |
| 谈创意在陶瓷设计中的作用;方梦琪;《景德镇陶瓷》;20161231(第6期);第8-9页 * |
| 释放负离子功能材料的研究进展;赵明 等;《陶瓷》;20110831(第8期);第44-47页 * |
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