CN114159330A - Oil-control and dandruff-removing hair care composition and preparation method thereof - Google Patents
Oil-control and dandruff-removing hair care composition and preparation method thereof Download PDFInfo
- Publication number
- CN114159330A CN114159330A CN202110869768.2A CN202110869768A CN114159330A CN 114159330 A CN114159330 A CN 114159330A CN 202110869768 A CN202110869768 A CN 202110869768A CN 114159330 A CN114159330 A CN 114159330A
- Authority
- CN
- China
- Prior art keywords
- oil
- dandruff
- care composition
- hair care
- removing hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/008—Preparations for oily skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/51—Chelating agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Abstract
The invention provides an oil-control and dandruff-removing hair care composition which comprises, by weight, 0.3-0.8% of phytosterol ester, 0.01-0.1% of hexamidine di (isethionate), 0.01-0.15% of monohydric alcohol, 0.5-0.8% of an auxiliary agent, 0.05-0.2% of a chelating agent, 12-19% of an anionic surfactant, 1-5% of a zwitterionic surfactant, 1.5-2% of a cationic surfactant, 1-2% of a viscosity regulator, 0.01-0.05% of a pH regulator, 0.2-0.7% of a conditioner and the balance of water. The composition has high stability, antibacterial property and strong cleaning capability, can effectively play the oil control and dandruff removing effects of the shampoo, has a simple preparation method, and can be used for the production of products such as the shampoo and the like.
Description
Technical Field
The invention belongs to the field of daily chemical products, and particularly relates to an oil-control and dandruff-removing hair care composition and a preparation method thereof.
Background
With the increasing pace of life and the increasing working pressure, more and more people are worried about scurf, and the scurf problem becomes the second biggest hair health problem which is only secondary to alopecia and troubles consumers. When the scalp excessively secretes sebum, the excessive sebum is acted by microorganisms to produce fatty acid, so that the scalp is stimulated to produce inflammation, the skin adipose tissue density is reduced, and the skin barrier function is influenced. When hair follicles are blocked, sebaceous glands cannot normally discharge sebum, the reduction of oxygen content causes anaerobic propionibacterium to excessively breed, when water and oil of scalp are unbalanced, the pH value of a sebaceous membrane is changed, scalp oil is exuberant to secrete, bacteria are bred and metabolized to generate free fatty acid, scalp stimulation is caused, excessive proliferation of scalp cuticle is promoted, and dandruff is increased, so that the market demand of the dandruff removing shampoo is increased, but the effect of the oil-control dandruff removing shampoo on the market at present is not ideal.
Disclosure of Invention
In order to solve the problems, the invention provides an oil-control and dandruff-removal hair care composition which comprises, by weight, 0.3-0.8% of phytosterol ester, 0.01-0.1% of hexamidine di (isethionic acid) salt, 0.01-0.15% of monohydric alcohol, 0.5-0.8% of an auxiliary agent, 0.05-0.2% of a chelating agent, 12-19% of an anionic surfactant, 1-5% of a zwitterionic surfactant, 1.5-2% of a cationic surfactant, 1-2% of a viscosity regulator, 0.01-0.05% of a pH regulator, 0.2-0.7% of a conditioner and the balance of water.
Preferably, it is characterized in that: the cationic surfactant comprises hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride and/or polyquaternary ammonium salt.
Preferably, the polyquaternium is one or more of polyquaternium-7, polyquaternium-52, polyquaternium-6 and polyquaternium-10.
Preferably, the phytosterol ester is phytosterol/octyldodecanol lauroyl glutamate.
Preferably, the monohydric alcohol is selected from at least one of ethanol, isopropanol and dichlorobenzyl alcohol.
Preferably, the auxiliary agent is selected from one or more of phenoxyethanol, benzyl alcohol and benzoic acid.
Preferably, the anionic surfactant is sodium laureth sulfate and the zwitterionic surfactant is cocamidopropyl hydroxysultaine.
Preferably, the conditioner is avocado oil PEG-11 esters, and the chelating agent is disodium EDTA.
Preferably, the viscosity modifier is cocamide methyl MEA and the pH modifier is citric acid.
The invention also provides a preparation method of the hair care composition for controlling oil and removing dandruff,
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring to disperse, adding chelating agent, and continuing stirring;
(2) adding anionic surfactant and zwitterionic surfactant, heating, stirring to dissolve completely, and cooling;
(3) adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt, a conditioning agent, phytosterol ester, an auxiliary agent and monohydric alcohol, and stirring;
(4) the pH value is adjusted by a pH regulator, and the viscosity is adjusted by a viscosity regulator.
Compared with the prior art, the invention has the advantages and beneficial effects that:
(1) the composition obtained by compounding various components has high stability, antibacterial property and strong cleaning capability, can effectively play the oil-controlling and dandruff-removing functions of shampoo when being added into the shampoo, has a simple preparation method, and can be used for the production of products such as the shampoo and the like.
(2) According to the invention, by selecting a proper auxiliary agent type, the oil control and anti-dandruff effects of the composition are improved, and the stability and synergistic effect of the rest components in the system are improved. According to the invention, the foaming performance of the composition is improved by compounding the phytosterol/octyl dodecanol lauroyl glutamate with the auxiliary agent, the dispersibility of the phytosterol/octyl dodecanol lauroyl glutamate in a system is improved, a more stable dispersed solution is formed, the effect of the phytosterol/octyl dodecanol lauroyl glutamate in the traditional shampoo is improved, and the using effect of the shampoo is improved.
Detailed Description
The invention will be further understood by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions provided herein, the definition of the term provided herein controls.
The invention provides an oil-control and dandruff-removing hair care composition which comprises, by weight, 0.3-0.8% of phytosterol ester, 0.01-0.1% of hexamidine di (isethionate), 0.01-0.15% of monohydric alcohol, 0.5-0.8% of an auxiliary agent, 0.05-0.2% of a chelating agent, 12-19% of an anionic surfactant, 1-5% of a zwitterionic surfactant, 1.5-2% of a cationic surfactant, 1-2% of a viscosity regulator, 0.01-0.05% of a pH regulator, 0.2-0.7% of a conditioner and the balance of water.
In a preferred embodiment, the method is characterized in that: the cationic surfactant comprises hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride and/or polyquaternary ammonium salt.
In a preferred embodiment, the polyquaternium is one or more of polyquaternium-7, polyquaternium-52, polyquaternium-6 and polyquaternium-10.
In a preferred embodiment, the polyquaternium is polyquaternium-7.
In a preferred embodiment, the weight ratio of the hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride to the polyquaternium-7 is 1: 5-10.
The inventor finds that when the weight ratio of the hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride to the polyquaternium-7 is 1: 5-10, the product has good foam property and strong cleaning force. The inventors speculate that: the anionic surfactant and the cationic surfactant are subjected to charge interaction to generate flocculation rapidly, the water-insoluble flocculent gel is easy to adsorb on hair in the hair washing process, the anionic surfactant in the flocculent gel is washed away, and the hydroxypropyl guar hydroxypropyl trimonium chloride and the polyquaternium-7 effectively help active ingredients in the hair washing water to be adsorbed and deposited on hair fibers, so that the cleaning power is improved.
In a preferred embodiment, the phytosterol ester is phytosterol/octyldodecanol lauroyl glutamate.
In a preferred embodiment, the monohydric alcohol is selected from at least one of ethanol, isopropanol, dichlorobenzyl alcohol.
In a preferred embodiment, the monohydric alcohol is selected from dichlorobenzyl alcohols.
In a preferred embodiment, the weight ratio of the polyquaternium to the monohydric alcohol is 10-20: 1.
the quaternary ammonium salt cationic surfactant has surface activity, and can make hair care composition gather on the surface of thallus to influence the metabolism of thallus, change the permeability of thallus membrane and kill thallus after being added into the system. However, quaternary ammonium salts generally take a long time to act, and when the shampoo products are formulated, if calcium and magnesium ions are contained in water, the quaternary ammonium salts are sensitive to the calcium and magnesium ions, and low-solubility compounds are formed, which affect the activity of the surfactant. The inventor finds that the hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride and the quaternary ammonium salt are compounded, so that the synergistic bactericidal effect is achieved, and the weight ratio of the quaternary ammonium salt to the alcohol compound is 10-20: 1, the effect is best. The inventors speculate that the combination of the alcohol and the quaternary ammonium salt shortens the action time of the quaternary ammonium salt and the cell surface, reduces the influence of the water on the action of the quaternary ammonium salt, and prolongs the action time of the alcohol on the sterilization.
In a preferred embodiment, the auxiliary agent is selected from one or more of phenoxyethanol, benzyl alcohol and benzoic acid.
In a preferred embodiment, the adjuvant comprises phenoxyethanol, benzyl alcohol and benzoic acid.
In a preferred embodiment, the auxiliary agent comprises phenoxyethanol, benzyl alcohol and benzoic acid in a weight ratio of 1-5: 1: 1.
The auxiliary agent comprises phenoxyethanol, benzyl alcohol and benzoic acid, so that the oil control and anti-dandruff effects of the composition are improved.
In a preferred embodiment, the mass ratio of the phytosterol/octyldodecanol lauroyl glutamate to the auxiliary agent is 1: 1-1.5.
The phytosterol/octyl dodecanol lauroyl glutamate increases foaming performance of the cleaning product, reduces potential irritation of the product, and improves use effect of the product. The inventor finds that the foaming performance of the composition is improved by compounding the phytosterol/octyl dodecanol lauroyl glutamate with the auxiliary agent, and the inventor supposes that the auxiliary agent improves the dispersibility of the phytosterol/octyl dodecanol lauroyl glutamate in a system to form a more stable dispersed solution.
In a preferred embodiment, the anionic surfactant is sodium laureth sulfate and the zwitterionic surfactant is cocamidopropyl hydroxysultaine.
In a preferred embodiment, the conditioning agent is a PEG-11 ester of avocado oil and the chelating agent is disodium EDTA.
In a preferred embodiment, the viscosity modifier is cocamide methyl MEA and the pH modifier is citric acid.
In a preferred embodiment, the composition further comprises 0.3-0.7% of sodium benzoate and 0.4-0.8% of essence by mass fraction.
The invention also provides a preparation method of the hair care composition for controlling oil and removing dandruff,
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring to disperse, adding chelating agent, and continuing stirring;
(2) adding anionic surfactant and zwitterionic surfactant, heating, stirring to dissolve completely, and cooling;
(3) adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt, a conditioning agent, phytosterol ester, an auxiliary agent and monohydric alcohol, and stirring;
(4) the pH value is adjusted by a pH regulator, and the viscosity is adjusted by a viscosity regulator.
In a preferred embodiment, the pH value is 5 to 6.
In a preferred embodiment, the viscosity is 4000 to 6000mPa · S.
In a preferred embodiment, the citric acid is a 5-15% citric acid aqueous solution.
The raw materials of the invention are purchased from the following manufacturers:
hexamidine di (isethionic acid) salt: middle lion
Hydroxypropyl guar hydroxypropyl trimonium chloride: nanjing bannuo
Sodium laureth sulfate: kowadd
Cocoamide methyl MEA: king of Guangzhou flower
Cocamidopropyl hydroxysultaine: microphone forest
Polyquaternium-7: chemical engineering of Yuntai Run
Phytosterol/octyldodecanol lauroyl glutamate: lande chemistry
Avocado oil PEG-11 esters: tianmen Changchang chemical industry
Example 1
This example provides an oil control and dandruff control hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 71.5% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.6% adjuvants, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) The pH value (10%) was adjusted to 5.3 with a 10% by mass aqueous citric acid solution, and the viscosity was adjusted to 5500 mPa.S with cocamide methyl MEA.
Example 2
This example provides an oil control and dandruff control hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 72% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.6% adjuvant, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionate), 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) Adjusting pH to 5.3 with 10% citric acid aqueous solution, and adjusting viscosity to 5500 mPa.S with cocamide methyl MEA.
Comparative example 1
The present comparative example provides an oil-controlling, dandruff-removing hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 71.5% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.6% adjuvant, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternium-7, avocado oil PEG-11 esters, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) Adjusting pH to 5.3 with 10% citric acid aqueous solution, and adjusting viscosity to 5500 mPa.S with cocamide methyl MEA.
Comparative example 2
The present comparative example provides an oil control and dandruff control hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 73% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.6% adjuvant, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) Adjusting pH to 5.3 with 10% citric acid aqueous solution, and adjusting viscosity to 5500 mPa.S with cocamide methyl MEA.
Comparative example 3
The present comparative example provides an oil-controlling, dandruff-removing hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 71.5% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.6% auxiliaries, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises n-butanol.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, n-butanol, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) Adjusting pH to 5.3 with 10% citric acid aqueous solution, and adjusting viscosity to 5500 mPa.S with cocamide methyl MEA.
Comparative example 4
The present comparative example provides an oil-controlling, dandruff-removing hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 71.5% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.3% adjuvant, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) Adjusting pH to 5.3 with 10% citric acid aqueous solution, and adjusting viscosity to 5500 mPa.S with cocamide methyl MEA.
Comparative example 5
The present comparative example provides an oil-controlling, dandruff-removing hair care composition comprising, by weight, 0.2% hydroxypropyl guar hydroxypropyltrimonium chloride, 0.1% disodium EDTA, 17% sodium laureth sulfate, 1.5% cocamidomethyl MEA, 3% cocamidopropyl hydroxysultaine, 71.5% polyquaternium, 0.5% avocado oil PEG-11 esters, 0.5% phytosterol/octyldodecanol lauroyl glutamate, 0.6% auxiliaries, 0.4% sodium benzoate, 0.6% perfume, 0.03% citric acid, 0.05% hexamidine di (isethionic acid) salt, 0.1% dichlorobenzyl alcohol, and the balance water. The auxiliary agent comprises the following components in percentage by weight: 1:1 of phenoxyethanol, benzyl alcohol and benzoic acid.
The preparation method of the oil-control and dandruff-removing hair care composition comprises the following steps:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring for 3min to disperse, adding EDTA disodium, and stirring for 2min
(2) Adding sodium laureth sulfate and cocamidopropyl hydroxysultaine, heating to 80 deg.C, stirring for 20min for dissolving completely, cooling
(3) Cooling to below 38 deg.C, adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt-7, avocado oil PEG-11 esters, phytosterol/octyldodecanol lauroyl glutamate, phenoxyethanol, benzyl alcohol, benzoic acid, sodium benzoate, essence, and dichlorobenzyl alcohol, stirring for 10min
(4) The pH value is adjusted to 6.7 by using a citric acid aqueous solution with the mass fraction of 10%, and the viscosity is adjusted to 5500 mPa.S by using cocoamide methyl MEA.
Performance testing
1. The shampoos of the examples and comparative examples were subjected to the performance test, and the results are shown in table 1.
Table 1 results of performance testing
2. The products prepared in the examples and the comparative examples were left at room temperature, 5 ℃ and 40 ℃ for 30 days, and after observation, whether or not the phenomena of off-flavor and precipitation occurred was observed, and the test results are shown in Table 2.
TABLE 2 Performance test results
The foregoing embodiments are merely illustrative of the principles and utilities of the present invention and are not intended to limit the invention. Any person skilled in the art can modify or change the above-mentioned embodiments without departing from the spirit and scope of the present invention. Accordingly, it is intended that all equivalent modifications or changes which can be made by those skilled in the art without departing from the spirit and technical spirit of the present invention be covered by the claims of the present invention.
Claims (10)
1. An oil-controlling, dandruff-removing hair care composition characterized by: the water-based oil-based emulsion comprises, by weight, 0.3-0.8% of phytosterol ester, 0.01-0.1% of hexamidine di (isethionic acid) salt, 0.01-0.15% of monohydric alcohol, 0.5-0.8% of an auxiliary agent, 0.05-0.2% of a chelating agent, 12-19% of an anionic surfactant, 1-5% of a zwitterionic surfactant, 1.5-2% of a cationic surfactant, 1-2% of a viscosity regulator, 0.01-0.05% of a pH regulator, 0.2-0.7% of a conditioner and the balance of water.
2. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the cationic surfactant comprises hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride and/or polyquaternary ammonium salt.
3. A oil-controlling and dandruff-removing hair care composition according to claim 2, characterized in that: the method is characterized in that: the polyquaternium is one or more of polyquaternium-7, polyquaternium-52, polyquaternium-6 and polyquaternium-10.
4. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the phytosterol ester is phytosterol/octyl dodecanol lauroyl glutamate.
5. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the monohydric alcohol is selected from at least one of ethanol, isopropanol and dichlorobenzyl alcohol.
6. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the solvent is selected from one or more of phenoxyethanol, benzyl alcohol and benzoic acid.
7. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the anionic surfactant is sodium laureth sulfate, and the zwitterionic surfactant is cocamidopropyl hydroxysultaine.
8. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the conditioner is avocado oil PEG-11 esters, and the chelating agent is EDTA disodium.
9. A oil-controlling and dandruff-removing hair care composition according to claim 1, characterized in that: the method is characterized in that: the viscosity regulator is cocoamide methyl MEA, and the pH regulator is citric acid.
10. A method of preparing an oil-controlling and dandruff-removing hair care composition according to claim 2, characterized in that:
(1) adding water and hydroxypropyl guar hydroxypropyl trimethyl ammonium chloride, stirring to disperse, adding chelating agent, and continuing stirring;
(2) adding anionic surfactant and zwitterionic surfactant, heating, stirring to dissolve completely, and cooling;
(3) adding hexamidine di (hydroxyethyl sulfonate) salt, polyquaternary ammonium salt, a conditioning agent, phytosterol ester, an auxiliary agent and monohydric alcohol, and stirring;
(4) the pH value is adjusted by a pH regulator, and the viscosity is adjusted by a viscosity regulator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110869768.2A CN114159330A (en) | 2021-07-30 | 2021-07-30 | Oil-control and dandruff-removing hair care composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110869768.2A CN114159330A (en) | 2021-07-30 | 2021-07-30 | Oil-control and dandruff-removing hair care composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114159330A true CN114159330A (en) | 2022-03-11 |
Family
ID=80476468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110869768.2A Pending CN114159330A (en) | 2021-07-30 | 2021-07-30 | Oil-control and dandruff-removing hair care composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114159330A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115120538A (en) * | 2022-05-24 | 2022-09-30 | 广东博然堂生物科技有限公司 | Silicone oil-free anti-dandruff shampoo and preparation method thereof |
| CN115487127A (en) * | 2022-07-13 | 2022-12-20 | 广东嘉丹婷日用品有限公司 | Anti-hair loss oil-control silicone-oil-free shampoo and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107296771A (en) * | 2017-07-31 | 2017-10-27 | 曾万祥 | A kind of desquamation compositions and extra quality multiple-effect are without silicone oil shampoo |
| CN110236975A (en) * | 2019-07-04 | 2019-09-17 | 杭州诗昀生物科技有限公司 | A kind of scalp care shampoo |
| CN111544332A (en) * | 2020-06-24 | 2020-08-18 | 广州美兮生物科技有限公司 | Anti-dandruff shampoo and preparation method thereof |
| CN111603433A (en) * | 2020-05-29 | 2020-09-01 | 杭州心悦化妆品有限公司 | Mild washing and caring product for infants and preparation method thereof |
-
2021
- 2021-07-30 CN CN202110869768.2A patent/CN114159330A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107296771A (en) * | 2017-07-31 | 2017-10-27 | 曾万祥 | A kind of desquamation compositions and extra quality multiple-effect are without silicone oil shampoo |
| CN110236975A (en) * | 2019-07-04 | 2019-09-17 | 杭州诗昀生物科技有限公司 | A kind of scalp care shampoo |
| CN111603433A (en) * | 2020-05-29 | 2020-09-01 | 杭州心悦化妆品有限公司 | Mild washing and caring product for infants and preparation method thereof |
| CN111544332A (en) * | 2020-06-24 | 2020-08-18 | 广州美兮生物科技有限公司 | Anti-dandruff shampoo and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115120538A (en) * | 2022-05-24 | 2022-09-30 | 广东博然堂生物科技有限公司 | Silicone oil-free anti-dandruff shampoo and preparation method thereof |
| CN115487127A (en) * | 2022-07-13 | 2022-12-20 | 广东嘉丹婷日用品有限公司 | Anti-hair loss oil-control silicone-oil-free shampoo and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114159330A (en) | Oil-control and dandruff-removing hair care composition and preparation method thereof | |
| EP2275104B1 (en) | Pharmaceutical and cosmetic composition including lactoferrin, ciclopirox and etidronic acid | |
| JPH09511740A (en) | Improved, anti-dandruff shampoo | |
| CN103735430A (en) | Three-in-one liquid shampoo and preparation method thereof | |
| EP0914075B1 (en) | Antimicrobial compositions for topical use | |
| CA2240526C (en) | Compositions containing an antifungal and a sulfur compound | |
| CN112402275A (en) | Organic zinc compound oil-control anti-dandruff shampoo and preparation method thereof | |
| CN110772435A (en) | Anti-dandruff shampoo and preparation method thereof | |
| CN104940071A (en) | Mild antidandruff shampoo and preparation method thereof | |
| CN114533586A (en) | Dandruff-removing itching-relieving shampoo composition, and preparation method and application thereof | |
| SK283226B6 (en) | Compositions containing an antifungal and a phospholipid | |
| CN114146012A (en) | Antibacterial and anti-dandruff shampoo and preparation method thereof | |
| CN113908095A (en) | Oil-control moisturizing hair composition containing double proteins | |
| CN112891252A (en) | Mild itching-relieving bath composition and preparation method thereof | |
| WO1998052518A1 (en) | Methods for using compositions containing dichlorophenyl imidazoldioxolan to treat seborrheic dermatitis, dandruff, psoriasis, and acne, and compositions thereof | |
| CN114366702B (en) | Shampoo with effects of removing dandruff, relieving itching and controlling oil and preparation method thereof | |
| CN112043655A (en) | Plant anti-dandruff composition, silicone oil-free shampoo and preparation method thereof | |
| JP5751664B2 (en) | shampoo | |
| DE102012220148A1 (en) | Producing cosmetic or dermatological preparations such as surfactant-containing preparations comprising climbazole, comprises dissolving climbazole in laureth-9 at specific temperature, and then incorporating into preparation | |
| CN114366680A (en) | Shampoo composition for maintaining scalp health, preventing alopecia and strengthening hair and preparation method thereof | |
| CN112006954A (en) | Shampoo and preparation method thereof | |
| KR0147889B1 (en) | Dry foam producing aerosol for cosmetics | |
| CN104721065A (en) | Neticonazole shampoo and formula and production method thereof | |
| CN112545916B (en) | Mild surfactant system and application thereof | |
| CN114917131A (en) | Liquid crystal suspension ginger shampoo and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination |