CN114105715A - Environment-friendly modifier for improving saline-alkali soil and preparation method thereof - Google Patents

Environment-friendly modifier for improving saline-alkali soil and preparation method thereof Download PDF

Info

Publication number
CN114105715A
CN114105715A CN202111594817.2A CN202111594817A CN114105715A CN 114105715 A CN114105715 A CN 114105715A CN 202111594817 A CN202111594817 A CN 202111594817A CN 114105715 A CN114105715 A CN 114105715A
Authority
CN
China
Prior art keywords
soil
parts
saline
environment
friendly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111594817.2A
Other languages
Chinese (zh)
Inventor
李进
段婷婷
陈敏忠
朱银玲
吴方平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Ocean University
Original Assignee
Guangdong Ocean University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Ocean University filed Critical Guangdong Ocean University
Priority to CN202111594817.2A priority Critical patent/CN114105715A/en
Publication of CN114105715A publication Critical patent/CN114105715A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B17/00Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The invention discloses an environment-friendly conditioner for improving saline-alkali soil and a preparation method thereof, belonging to the technical field of soil improvement. The modifier comprises the following raw materials: earthworm cast, fishbone powder, deer marsh soil, red jade soil, grass carbon, urea, potassium sulfate, citric acid and compound microorganisms. The method comprises the steps of fermenting wormcast and fishbone powder under the action of compound microorganisms to obtain a fermentation product; mixing and crushing the deer marsh soil, the red jade soil and the grass carbon to obtain a mixture; and sequentially adding the mixture, urea, potassium sulfate and citric acid into the fermentation product, and uniformly stirring to obtain the environment-friendly modifier for improving the saline-alkali soil. The soil conditioner provided by the invention is applied to the saline-alkali soil, can obviously improve the organic matter content and the water content of the soil, can reduce the volume weight of the soil, adjust the pH value of the soil and reduce the salt content, and has wide application prospects.

Description

Environment-friendly modifier for improving saline-alkali soil and preparation method thereof
Technical Field
The invention relates to the technical field of soil improvement, in particular to an environment-friendly modifier for improving saline-alkali soil and a preparation method thereof.
Background
Soil salination refers to a process in which salt in the bottom layer of soil or underground water rises to the surface along with capillary water and is accumulated in surface soil after water is evaporated. The harm of soil salinization is as follows: when the content of soluble salt in soil is increased, the osmotic pressure of a soil solution is reduced, the water potential is reduced, the root system of a plant is difficult to absorb water, and the plant is physiologically drought and wilted to die due to physiological dehydration in serious conditions; when the concentration of certain ions in the soil is too high, the absorption of other ions by plants is prevented, so that the nutrition of the plants is unbalanced; in saline-alkali soil, the concentration of some ions is higher, so that the supply of some nutrient elements with low concentration is insufficient; when the alkaline salt in the soil is excessive, the soil is subjected to strong alkaline reaction, so that plant nutrient elements such as iron, calcium, zinc, magnesium and the like are easy to form precipitates, and the effectiveness in soil nutrients is reduced.
The soil conditioner is also called soil conditioner, and can improve the physical property of soil and promote the nutrient absorption of crops. The soil conditioner has the functions of preserving soil moisture and increasing temperature, can effectively improve the soil moisture content and increase the temperature of the plough layer. Meanwhile, the method can also improve the soil structure, coordinate the relationship among water, fertilizer, gas, heat and organisms of the soil, prevent water and soil loss, enhance the seepage-proofing capacity of the channel, inhibit secondary salinization of the soil and improve the development and utilization of sandy wasteland. The soil conditioner can change the granular structure of soil, reduce the volume weight of the soil, increase the air permeability of the soil, improve the utilization efficiency of precipitation, increase the organic matters of the soil, adjust the pH value of the soil, improve the ion exchange rate of the soil and enhance the buffering capacity of the soil. Therefore, the research on the soil conditioner which can obviously improve the organic matter content and the water content of the soil, reduce the volume weight of the soil, adjust the pH value of the soil and reduce the salt content has very important significance.
Disclosure of Invention
The invention aims to provide an environment-friendly conditioner for improving saline-alkali soil and a preparation method thereof, so as to reduce the harm brought by the saline-alkali soil.
In order to achieve the purpose, the invention provides the following scheme:
one of the purposes of the invention is to provide an environment-friendly conditioner for improving saline-alkali soil, which comprises the following raw materials in parts by weight: 20-25 parts of wormcast, 12-14 parts of fishbone powder, 16-22 parts of deer biogas, 20-23 parts of red jade soil, 12-16 parts of grass peat, 5-8 parts of urea, 2-4 parts of potassium sulfate, 1-2 parts of citric acid and 3-5 parts of compound microorganism.
Further, the fishbone powder is obtained by drying fishbone, crushing the dried fishbone, adding dilute sulfuric acid to react, and drying the reaction product.
Further, the crushed particle size is required to be 100-mesh sieved, the concentration of the dilute sulfuric acid is 0.5mol/L, and the mass-volume ratio of the fishbone to the dilute sulfuric acid is 3g:10 mL.
Further, the compound microorganism consists of saccharomyces cerevisiae, bacillus licheniformis, streptococcus lactis and azotobacter.
Further, the mass ratio of the saccharomyces cerevisiae, the bacillus licheniformis, the streptococcus lactis and the azotobacter is 3:5:1: 2.
The invention also aims to provide a preparation method of the environment-friendly improver for improving the saline-alkali soil, which comprises the following steps:
(1) mixing wormcast and fishbone powder, adding water and compound microorganisms, and performing fermentation treatment to obtain a fermentation product;
(2) mixing the deer biogas, the red jade soil and the grass peat, drying and crushing to obtain a mixture;
(3) and sequentially adding the mixture, urea, potassium sulfate and citric acid into the fermentation product, and uniformly stirring to obtain the environment-friendly modifier for improving the saline-alkali soil.
Further, in the step (1), the adding amount of the water is 20-40% of the total weight of the wormcast and the fishbone powder.
Further, in the step (1), the fermentation treatment temperature is 25-30 ℃ and the fermentation treatment time is 5-7 days.
Further, in the step (2), the crushed particle size is required to be 100-mesh sieved.
Further, in the step (3), the rotation speed of the stirring is 200-300 rpm, and the time is 3-5 h.
The invention has the following technical effects:
the wormcast used in the invention not only contains major elements such as nitrogen, phosphorus, zinc and the like, but also contains a plurality of trace elements such as iron, manganese, zinc, copper, magnesium and the like and 18 amino acids, and the organic matter content and the humic substance content reach about 30%. The application of the wormcast can enhance the soil fertility, adjust the soil pH value, improve the soil permeability and the water retention property, and is beneficial to the reproduction and increase of microorganisms. The fishbone powder is rich in nutrient components such as calcium, protein and the like, can provide organic substances for soil, can increase the exchange capacity of organic matters and cations in the soil, and further improves the pH value regulating capability of the soil.
The deer marsh soil used by the invention is produced in the volcanic region and is generated by the lower layer volcanic soil, the pH value is acidic, the permeability is very high, and the water storage capacity and the air permeability are strong; the red jade soil is volcanic mud with high permeability, dark red round particles, no harmful bacteria and slightly acidic pH value; peat is a product of the marsh development process and contains a large amount of water and plant residues, humus and a part of minerals which are not completely decomposed. The three components are matched for use, so that the pH value of the soil can be adjusted, the organic matter content of the soil can be increased, and the permeability of the soil can be increased, thereby achieving the effects of improving the soil structure and enhancing the soil. In addition, the use of urea, potassium sulfate and citric acid further provides nutrient substances for the soil and has a certain effect of adjusting the pH value of the soil.
The composite microorganism disclosed by the invention is composed of saccharomyces cerevisiae, bacillus licheniformis, streptococcus lactis and azotobacter according to the mass ratio of 3:5:1:2, and can decompose organic substances in soil, convert the organic substances into amino acid and carbohydrate, further enhance the soil fertility, improve the physicochemical properties of the soil, and enhance the water permeability and water retention capacity of the soil.
The components of wormcast, fishbone powder, deer marsh soil, red jade soil, grass peat, urea, potassium sulfate, citric acid and compound microorganisms are selected and scientifically and reasonably matched, and the raw materials interact with each other.
Detailed Description
Reference will now be made in detail to various exemplary embodiments of the invention, the detailed description should not be construed as limiting the invention but as a more detailed description of certain aspects, features and embodiments of the invention.
It is to be understood that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. Further, for numerical ranges in this disclosure, it is understood that each intervening value, between the upper and lower limit of that range, is also specifically disclosed. Every smaller range between any stated value or intervening value in a stated range and any other stated or intervening value in a stated range is encompassed within the invention. The upper and lower limits of these smaller ranges may independently be included or excluded in the range.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although only preferred methods and materials are described herein, any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention. All documents mentioned in this specification are incorporated by reference herein for the purpose of disclosing and describing the methods and/or materials associated with the documents. In case of conflict with any incorporated document, the present specification will control.
It will be apparent to those skilled in the art that various modifications and variations can be made in the specific embodiments of the present disclosure without departing from the scope or spirit of the disclosure. Other embodiments will be apparent to those skilled in the art from consideration of the specification. The description and examples are intended to be illustrative only.
As used herein, the terms "comprising," "including," "having," "containing," and the like are open-ended terms that mean including, but not limited to.
In the invention, all raw materials are conventional commercial products.
Example 1
(1) Preparing fishbone powder: drying fishbone, crushing, sieving with a 100-mesh sieve, adding 0.5mol/L dilute sulfuric acid for reaction, wherein the mass volume ratio of the fishbone to the dilute sulfuric acid is 3g:10mL, and drying after the reaction is finished to obtain fishbone powder;
(2) mixing 22 parts of wormcast and 13 parts of fishbone powder, adding water accounting for 20% of the weight of the wormcast and the fishbone powder, adding 4 parts of compound microorganism (composed of saccharomyces cerevisiae, bacillus licheniformis, streptococcus lactis and nitrogen-fixing bacteria according to the mass ratio of 3:5:1: 2), and fermenting for 5 days at 25 ℃ to obtain a fermentation product;
(3) mixing 18 parts of deer biogas soil, 21 parts of red jade soil and 14 parts of grass carbon, drying, crushing and sieving with a 100-mesh sieve to obtain a mixture;
(4) and sequentially adding the mixture, 6 parts of urea, 3 parts of potassium sulfate and 2 parts of citric acid into the fermentation product, and uniformly stirring at the rotating speed of 300rpm for 4 hours to obtain the environment-friendly modifier for improving the saline-alkali soil.
Example 2
The difference from the example 1 is that the raw materials are as follows: 24 parts of wormcast, 14 parts of fishbone powder, 20 parts of deer biogas, 22 parts of red jade soil, 16 parts of grass peat, 8 parts of urea, 3 parts of potassium sulfate, 1 part of citric acid and 5 parts of compound microorganism.
Example 3
The difference from the example 1 is that the raw materials are as follows: 21 parts of wormcast, 12 parts of fishbone powder, 16 parts of deer biogas, 20 parts of red jade soil, 13 parts of grass peat, 5 parts of urea, 2 parts of potassium sulfate, 1 part of citric acid and 3 parts of compound microorganism.
Comparative example 1
The difference from example 1 is that wormcast was not added.
Comparative example 2
The difference from example 1 is that no fish bone meal is added.
Comparative example 3
The difference from example 1 is that the complex microorganism does not contain Streptococcus lactis.
Comparative example 4
The difference from example 1 is that no palustre is added.
Comparative example 5
The difference from example 1 is that potassium sulfate was not added.
Effect verification
The conditioner of each example and comparative example was applied to saline-alkali soil at a dosage of 30 kg/mu, the control group was not applied with the conditioner, and the organic matter content (NYT 1121.6-2006), soil bulk density (ring cutter method), water content at 15cm soil depth, soil pH and total salt content (FHDZTR 0070) of the soil were measured after 1 month, and the results are shown in Table 1.
TABLE 1
Figure BDA0003430770670000071
As can be seen from Table 1, when the soil conditioner provided by the invention is applied to saline-alkali soil, the organic matter content and the water content of the soil can be obviously improved, the volume weight of the soil can be reduced, the pH value of the soil can be adjusted, the salt content can be reduced, and the soil conditioner has a wide application prospect.
The above-described embodiments are merely illustrative of the preferred embodiments of the present invention, and do not limit the scope of the present invention, and various modifications and improvements of the technical solutions of the present invention can be made by those skilled in the art without departing from the spirit of the present invention, and the technical solutions of the present invention are within the scope of the present invention defined by the claims.

Claims (10)

1. An environment-friendly improver for improving saline-alkali soil is characterized by comprising the following raw materials in parts by weight: 20-25 parts of wormcast, 12-14 parts of fishbone powder, 16-22 parts of deer biogas, 20-23 parts of red jade soil, 12-16 parts of grass peat, 5-8 parts of urea, 2-4 parts of potassium sulfate, 1-2 parts of citric acid and 3-5 parts of compound microorganism.
2. The environment-friendly improver for improving the soil of saline-alkali soil as claimed in claim 1, wherein the fishbone powder is obtained by drying fishbone, crushing the dried fishbone, adding dilute sulfuric acid to react, and drying the reaction product.
3. The environment-friendly improver for improving the soil of saline-alkali soil according to claim 2, wherein the crushed particle size is required to be 100 mesh, the concentration of the dilute sulfuric acid is 0.5mol/L, and the mass volume ratio of the fishbone to the dilute sulfuric acid is 3g:10 mL.
4. The environment-friendly improver for improving the soil of saline-alkali soil according to claim 1, wherein the compound microorganism consists of saccharomyces cerevisiae, bacillus licheniformis, streptococcus lactis and azotobacter.
5. The environment-friendly improver for improving the soil of saline-alkali soil according to claim 4, wherein the mass ratio of the saccharomyces cerevisiae, the bacillus licheniformis, the streptococcus lactis and the nitrogen-fixing bacteria is 3:5:1: 2.
6. The preparation method of the environment-friendly improver for improving the saline-alkali soil as claimed in any one of claims 1 to 5, characterized by comprising the following steps:
(1) mixing wormcast and fishbone powder, adding water and compound microorganisms, and performing fermentation treatment to obtain a fermentation product;
(2) mixing the deer biogas, the red jade soil and the grass peat, drying and crushing to obtain a mixture;
(3) and sequentially adding the mixture, urea, potassium sulfate and citric acid into the fermentation product, and uniformly stirring to obtain the environment-friendly modifier for improving the saline-alkali soil.
7. The preparation method according to claim 6, wherein in the step (1), the amount of the added water is 20-40% of the total weight of the wormcast and the fishbone powder.
8. The method according to claim 6, wherein the fermentation treatment is carried out at 25 to 30 ℃ for 5 to 7 days in the step (1).
9. The method according to claim 6, wherein in the step (2), the crushed particle size is required to pass through a 100-mesh sieve.
10. The preparation method according to claim 6, wherein in the step (3), the stirring speed is 200-300 rpm and the time is 3-5 h.
CN202111594817.2A 2021-12-24 2021-12-24 Environment-friendly modifier for improving saline-alkali soil and preparation method thereof Pending CN114105715A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111594817.2A CN114105715A (en) 2021-12-24 2021-12-24 Environment-friendly modifier for improving saline-alkali soil and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111594817.2A CN114105715A (en) 2021-12-24 2021-12-24 Environment-friendly modifier for improving saline-alkali soil and preparation method thereof

Publications (1)

Publication Number Publication Date
CN114105715A true CN114105715A (en) 2022-03-01

Family

ID=80362582

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111594817.2A Pending CN114105715A (en) 2021-12-24 2021-12-24 Environment-friendly modifier for improving saline-alkali soil and preparation method thereof

Country Status (1)

Country Link
CN (1) CN114105715A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115216303A (en) * 2022-07-28 2022-10-21 榆林学院 Acidified C-based material for promoting overwintering and green turning of saline-alkali soil plants and preparation method thereof
CN115280926A (en) * 2022-06-13 2022-11-04 上海圣珑环境科技有限公司 Saline-alkali soil improvement and restoration method

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100765909B1 (en) * 2007-07-05 2007-10-10 임규옥 Artificial vegetation base-soil compounds for plant and eco-planting method using it
CN102153420A (en) * 2010-12-15 2011-08-17 沈阳科丰牧业科技有限公司 Compound biofertilizer and preparation method thereof
CN102503661A (en) * 2011-10-13 2012-06-20 山东省农业科学院农业资源与环境研究所 Soil amendment prepared from biogas residue and wormcast as main material and preparation method thereof
CN105993779A (en) * 2016-05-31 2016-10-12 山东胜伟园林科技有限公司 Method for carrying out original coil cultivation on mild saline-alkali soil through wormcast containing organic matter
CN106190137A (en) * 2016-01-11 2016-12-07 中国农业大学 A kind of saline-alkali land soil conditioner and its preparation method and application
CN107285958A (en) * 2017-07-18 2017-10-24 界首市惠康生物技术研发中心 A kind of succulent Nutrition Soil
CN108484286A (en) * 2018-06-01 2018-09-04 新疆泰谷生物肥料有限公司 A kind of salt-soda soil organic-inorganic compound fertilizer special and its preparation method and application
CN109628360A (en) * 2019-02-28 2019-04-16 农业部环境保护科研监测所 A kind of microbial bacterial agent and its soil property amount modifying agent generated that ferments

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100765909B1 (en) * 2007-07-05 2007-10-10 임규옥 Artificial vegetation base-soil compounds for plant and eco-planting method using it
CN102153420A (en) * 2010-12-15 2011-08-17 沈阳科丰牧业科技有限公司 Compound biofertilizer and preparation method thereof
CN102503661A (en) * 2011-10-13 2012-06-20 山东省农业科学院农业资源与环境研究所 Soil amendment prepared from biogas residue and wormcast as main material and preparation method thereof
CN106190137A (en) * 2016-01-11 2016-12-07 中国农业大学 A kind of saline-alkali land soil conditioner and its preparation method and application
CN105993779A (en) * 2016-05-31 2016-10-12 山东胜伟园林科技有限公司 Method for carrying out original coil cultivation on mild saline-alkali soil through wormcast containing organic matter
CN107285958A (en) * 2017-07-18 2017-10-24 界首市惠康生物技术研发中心 A kind of succulent Nutrition Soil
CN108484286A (en) * 2018-06-01 2018-09-04 新疆泰谷生物肥料有限公司 A kind of salt-soda soil organic-inorganic compound fertilizer special and its preparation method and application
CN109628360A (en) * 2019-02-28 2019-04-16 农业部环境保护科研监测所 A kind of microbial bacterial agent and its soil property amount modifying agent generated that ferments

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
周美荣等: "蚯蚓粪的研究及应用", 《山西农业科学》 *
范永强: "《现代中国花生栽培》", 30 November 2014, 山东科学技术出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115280926A (en) * 2022-06-13 2022-11-04 上海圣珑环境科技有限公司 Saline-alkali soil improvement and restoration method
CN115216303A (en) * 2022-07-28 2022-10-21 榆林学院 Acidified C-based material for promoting overwintering and green turning of saline-alkali soil plants and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102816006B (en) Special apple microorganism bacterial manure and method for preparing same
EP3932896B1 (en) Biochar-based fertilizer for improving foreshore saline-alkali soil, and preparation method and use thereof
CN106590671B (en) Soil conditioner and preparation method and application thereof
CN106748425B (en) Conditioner for promoting selenium activation in selenium-containing paddy soil
CN107759392A (en) A kind of improvement soil property matches somebody with somebody fertile auxiliary material and its production method
CN104326848A (en) Water and fertilizer retention organic fertilizer and preparation method thereof
CN104261981A (en) Preparation method of seaweed organic fertilizer and organic fertilizer prepared by using method
CN109095996A (en) Sandy soil conditioner and the preparation method and application thereof
CN107162816A (en) A kind of stalk semi-decomposed alkaline land improving fertilizer
CN106699443B (en) Conditioner for promoting selenium activation in selenium-containing dry land soil
CN114105715A (en) Environment-friendly modifier for improving saline-alkali soil and preparation method thereof
CN101857479B (en) Organic-inorganic compound fertilizer and production method thereof
CN104355787A (en) Organic fertilizer for loosening soil and improving stability and preparing method of organic fertilizer
CN103787776A (en) Biological water flushing fertilizer and preparation method thereof
CN107652147A (en) Improved soil type fertilizer synergistic conditioning agent and its production method
CN106187587A (en) A kind of rapeseed cultivation slow release magnetic compound fertiliser material and preparation method thereof
CN107698363A (en) Expelling parasite type fertilizer synergistic conditioning agent and its production method
CN108623414A (en) A kind of improvement salt-soda soil type biological organic complex fertilizer and preparation method thereof
WO2016107560A1 (en) Ecological functional phosphorus fertilizer and preparation method therefor
CN107673902A (en) It is a kind of to match somebody with somebody fertile auxiliary material and its production method with expelling parasite and slow releasing function
CN111689801A (en) Compound humic acid fertilizer and preparation and application thereof
CN111377780A (en) Natural sodium bentonite soil conditioner and preparation method thereof
CN105693392A (en) Biological organic fertilizer and preparation method and application thereof
CN111232949A (en) Preparation method of chlorella hydrothermal carbon material and application of chlorella hydrothermal carbon material in rice production
CN108329169A (en) A kind of sustained release fertilizer and preparation method thereof improving basic soil

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220301

RJ01 Rejection of invention patent application after publication