CN108623414A - A kind of improvement salt-soda soil type biological organic complex fertilizer and preparation method thereof - Google Patents
A kind of improvement salt-soda soil type biological organic complex fertilizer and preparation method thereof Download PDFInfo
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- CN108623414A CN108623414A CN201810651401.1A CN201810651401A CN108623414A CN 108623414 A CN108623414 A CN 108623414A CN 201810651401 A CN201810651401 A CN 201810651401A CN 108623414 A CN108623414 A CN 108623414A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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Abstract
The invention discloses a kind of improvement salt-soda soil type biological organic complex fertilizers and preparation method thereof, belong to technical field of fertilizers.The fertilizer is made of Brewery Wastewater Treatment sludge, weathered coal, agricultural production waste, trace element, zinc ion porphyrin nano complex compound, vermiculite power, fowl and animal excrement biogas slurry, complex micro organism fungicide, humic acid, edible fungi residues, polycaprolactone according to certain weight proportion.The biological organic complex fertilizer of the present invention is suitable for mild or moderate salt-soda soil, there is significant reducing effect to the content of alkali in soil and salt, soil physico-chemical property can be significantly improved, increase soil aggregate structure, alleviate soil hardening problem, soil permeability and retain water and nutrients ability are improved, utilization rate of fertilizer is improved, it is notable to increasing crop yield the effect of increasing income.
Description
Technical field
The present invention relates to a kind of biological organic complex fertilizer, specifically a kind of improvement salt-soda soil type biological organic complex fertilizer
And preparation method thereof.
Background technology
Salt-soda soil refers to soil to be influenced by the factors such as natural or artificial, and salts substances is caused gradually to penetrate into soil
It goes, the saliferous and alkalinity to make soil are more, and cause this kind of soil that can not be used.China salt-soda soil substantially distributed area
Domain is in northwest, northeast, North China and coastal region, and salt-soda soil primarily forms the reason is that more work of the soil of arid area in evaporation
Under, moisture is evaporated into vapor, and is emitted into air, but the salinity in water cannot exclude and stay among soil,
By accumulating for a long time, salinity gradually increases in soil, therefore and forms salt-soda soil.By alkaline land soil institute saliferous itself
Point excessively high, according to plant cell osmosis principle, plant cell is difficult to be absorbed into inorganic nutrient substance and moisture, leads to plant
Because itself lacking inorganic nutrient substance and water due to death, therefore crops are difficult to be grown in salt-soda soil.Currently, global salt-soda soil
Increased with about 100 ~ 1,500,000 hectares every year of speed.It expands, disperse when salt-soda soil shows wet, is muddy, shunk when doing, is hardened,
Hard, the features such as permeability is poor, can cause plant physiology arid, influence crop normal nutrition and even poison and then influence grain
Yield and lead to Cultivated Land Area Decrease.
Chinese saline alkali land area is vast, and type is various, and transformation is administered and rational exploitation and utilization these resources are Chinese agricultures
One of important channel of sustainable development, while to improving the ecological environment, thrust zone economy, society and Ecological Sustainable Development
Have great importance.Agricultural fertilizer technology has very important effect to alkaline land improving, but current market sales of
Fertilizer does not have improving effect mostly to salt-soda soil, and some even can aggravate the salinization of soil.Therefore development & production is for saline and alkaline
The fertilizer of ground improvement is necessary.
Invention content
For problems of the prior art, the present invention provides a kind of improvement salt-soda soil type biological organic complex fertilizer,
The fertilizer can significantly improve alkaline land soil property, increase crop yield.
The present invention also provides a kind of preparation methods of improvement salt-soda soil type biological organic complex fertilizer.
The present invention uses following technical scheme:
A kind of improvement salt-soda soil type biological organic complex fertilizer, it is made of the raw material of following parts by weight:Brewery Wastewater Treatment
400-600 parts of sludge, 200-300 parts of weathered coal, 800-1000 parts of agricultural production waste, 10-30 parts of trace element, zinc from
Son -1-2 parts of porphyrin nano complex compound, 100-200 parts of vermiculite power, 200-300 parts of fowl and animal excrement biogas slurry, complex micro organism fungicide 6-
10 parts, 20-40 parts of humic acid, 100-200 parts of edible fungi residues, 30-50 parts of polycaprolactone;The complex micro organism fungicide is green
Trichoderma is with Bacillus cereus according to 3:1 weight ratio is mixed to prepare.
Preferably, the improvement salt-soda soil type biological organic complex fertilizer, it is made of the raw material of following parts by weight:Beer
500 parts of wine waste water processing station sludge, 250 parts of weathered coal, 900 parts of agricultural production waste, micro- 20 parts, zinc ion-porphin
1.5 parts of quinoline complexing nano object, 150 parts of vermiculite power, 250 parts of fowl and animal excrement biogas slurry, 8 parts of complex micro organism fungicide, 30 parts of humic acid,
150 parts of edible fungi residues, 40 parts of polycaprolactone.
Preferably, the zinc ion-porphyrin nano complex compound is prepared using following methods:By 10ml 1mol/
L acetic acid zinc solutions are added in reaction bulb together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L and mix at room temperature
Conjunction is stirred to react after 24 hours to obtain the final product.
Preferably, the trace element is sodium molybdate, manganese sulfate, borax, ferrous sulfate and zinc sulfate according to 1:5:5:10:
15 weight ratio is formulated.
A kind of preparation method of the improvement salt-soda soil type biological organic complex fertilizer, it includes the following steps:
(1)Agricultural production waste and weathered coal are uniformly mixed according to formula ratio, then into mixture according to solid-liquid ratio
1kg:MgCl is added in 30ml2Solution is stirred continuously, and the 3.0mol/L for accounting for solid material weight ratio 3 ~ 5% is added after stirring 30min
Sodium hydroxide solution continue 10 ~ 15min of stirring, then in baking oven dry after obtain mixed material A, material A is continued to set
It is roasted 3 ~ 6 hours at 450 ~ 650 DEG C under conditions of closed isolation air in Muffle furnace, after being cooled to room temperature, grinding
At the powder material B not less than 100 mesh;
(2)Fowl and animal excrement biogas slurry is taken, flocculant is added thereto, activated carbon is added and is sufficiently stirred, is then removed by filtration precipitation
Biogas slurry that object obtains that treated;
(3)10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
Zinc ion-porphyrin nano complex compound is obtained after entering into reaction bulb to be mixed reaction at room temperature 24 hours, it is spare;
(4)By step(2)Prepared treated biogas slurry and Brewery Wastewater Treatment sludge, vermiculite power, composite microbial bacteria
Agent, edible fungi residues are mixed thoroughly, and stirring is primary daily after 3 days, 3 days for first anaerobic fermentation, continuously stirs 10-15 days, controls
Tunning dries pulverizing is obtained powder C by central temperature of fermenting after fermentation at 55 ~ 65 DEG C;
(5)Powder material B, powder C and trace element, polycaprolactone, humic acid are uniformly mixed, by step(3)Gained zinc ion-porphin
Quinoline complexing nano object is uniformly sprinkled upon in said mixture material, and then mixed material is sent into comminutor and is granulated, and dry, packing is
Obtain product of the present invention.
The step(1)Middle MgCl2Solution concentration is 0.5M.
The step(2)The addition of middle flocculant accounts for the 3 ~ 5% of biogas slurry volume.
The step(2)Middle activated carbon addition accounts for the 5 ~ 10% of biogas slurry weight.
Trichoderma viride used in the present invention is commercial product for Bacillus cereus, viable count be > 20,000,000,000/
Gram.Flocculant used is purchased from Wuhan Lv Yuan water-purifying materials Co., Ltd PAM series of products.
The beneficial effects of the invention are as follows:The biological organic complex fertilizer of the present invention is suitable for mild or moderate salt-soda soil, in soil
The content of alkali and salt has significant reducing effect, can significantly improve soil physico-chemical property, increases soil aggregate structure, alleviates soil
The hardened problem of earth improves soil permeability and retain water and nutrients ability, improves utilization rate of fertilizer, aobvious to increasing crop yield the effect of increasing income
It writes.Fertilizer of the present invention continues for a long time alkaline land soil improved effect, and wherein functional nano complex compound and raw by agricultural
The compounding ingredients synergistic effect with biomass carbon ingredient that production waste and weathered coal are mixed with, makes fertilizer have significant
Slow release effect can also reduce the heavy metal ion content in soil simultaneously, purify crop growth environment, and reclamation result is notable.
In addition, being also rich in a variety of nutrition compositions and a large amount of beneficial activity bacterium in the present invention, also have while supplemented with fertilizer nutrient
Improve soil texture, activating soil improves the ability of soil permeability and retain water and nutrients, promotes the suction of Plant To Nutrient element
It receives, improves disease-resistant, the anti-adversity ability of plant.
Specific implementation mode
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of improvement salt-soda soil type biological organic complex fertilizer, it is made of the raw material of following parts by weight:Brewery Wastewater Treatment
400 parts of sludge, 200 parts of weathered coal, 800 parts of agricultural production waste, micro- 10 parts, zinc ion-porphyrin nano complex compound 1
Part, 100 parts of vermiculite power, 200 parts of fowl and animal excrement biogas slurry, 6 parts of complex micro organism fungicide, 20 parts of humic acid, 100 parts of edible fungi residues,
30 parts of polycaprolactone;The complex micro organism fungicide is trichoderma viride and Bacillus cereus according to 3:1 weight ratio mixing
It is made.
The trace element is sodium molybdate, manganese sulfate, borax, ferrous sulfate and zinc sulfate according to 1:5:5:10:15 weight
Amount ratio is formulated.
The preparation method of above-mentioned improvement salt-soda soil type biological organic complex fertilizer is as follows:
(1)Agricultural production waste and weathered coal are uniformly mixed according to formula ratio, then into mixture according to solid-liquid ratio
1kg:0.5M MgCl are added in 30ml2Solution is stirred continuously, and is added after stirring 30min and is accounted for solid material weight ratio 3 ~ 5%
The sodium hydroxide solution of 3.0mol/L continues 10 ~ 15min of stirring, mixed material A is obtained after then being dried in baking oven, by material
A, which continues to be placed in Muffle furnace, to be roasted 3 ~ 6 hours under conditions of closed isolation air at 450 ~ 650 DEG C, and room temperature is cooled to
Afterwards, it is ground into the powder material B not less than 100 mesh;
(2)Take fowl and animal excrement biogas slurry, be added account for 3 ~ 5% flocculant of biogas slurry volume thereto, add account for biogas slurry weight 5 ~
10% activated carbon is sufficiently stirred, and is then removed by filtration the sediment biogas slurry that obtains that treated;
(3)10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
Zinc ion-porphyrin nano complex compound is obtained after entering into reaction bulb to be mixed reaction at room temperature 24 hours, it is spare;
(4)By step(2)Prepared treated biogas slurry and Brewery Wastewater Treatment sludge, vermiculite power, composite microbial bacteria
Agent, edible fungi residues are mixed thoroughly, and stirring is primary daily after 3 days, 3 days for first anaerobic fermentation, continuously stirs 10-15 days, controls
Tunning dries pulverizing is obtained powder C by central temperature of fermenting after fermentation at 55 ~ 65 DEG C;
(5)Powder material B, powder C and trace element, polycaprolactone, humic acid are uniformly mixed, by step(3)Gained zinc ion-porphin
Quinoline complexing nano object is uniformly sprinkled upon in said mixture material, and then mixed material is sent into comminutor and is granulated, and dry, packing is
Obtain product of the present invention.
A piece of salt-soda soil is chosen as wheat planting experimental plot, ground soil 0cm ~ 20cm soil layer salt in Guangrao County of Shandong Province
Content is average 0.3 ~ 0.5%, pH value 9.32.It is used using the present embodiment fertilizer as base manure, dosage is 500kg per acre, then
Autumn plants wheat, and it is 456 kilograms that harvest time, which harvests per mu yield, than using Common compound fertilizer material(N-P-K contents:15 ~ 15 ~ 15,
100 kilograms of amount of application of mu)376 kilograms of per mu yield volume increase 21.3%, soil 0cm ~ 20cm soil layer salt contents are down to 0.02 ~
0.05%, pH value is reduced to 8.56, and gap increases by 89% between granule.
Embodiment 2
A kind of improvement salt-soda soil type biological organic complex fertilizer, it is made of the raw material of following parts by weight:Brewery Wastewater Treatment
600 parts of sludge, 300 parts of weathered coal, 1000 parts of agricultural production waste, micro- 30 parts, zinc ion-porphyrin nano complex compound
2 parts, 200 parts of vermiculite power, 300 parts of fowl and animal excrement biogas slurry, 10 parts of complex micro organism fungicide, 40 parts of humic acid, edible fungi residues 200
Part, 50 parts of polycaprolactone;The complex micro organism fungicide is trichoderma viride and Bacillus cereus according to 3:1 weight ratio is mixed
It closes and is made.
The trace element is sodium molybdate, manganese sulfate, borax, ferrous sulfate and zinc sulfate according to 1:5:5:10:15 weight
Amount ratio is formulated.
The preparation method of above-mentioned improvement salt-soda soil type biological organic complex fertilizer is as follows:
(1)Agricultural production waste and weathered coal are uniformly mixed according to formula ratio, then into mixture according to solid-liquid ratio
1kg:0.5M MgCl are added in 30ml2Solution is stirred continuously, and is added after stirring 30min and is accounted for solid material weight ratio 3 ~ 5%
The sodium hydroxide solution of 3.0mol/L continues 10 ~ 15min of stirring, mixed material A is obtained after then being dried in baking oven, by material
A, which continues to be placed in Muffle furnace, to be roasted 3 ~ 6 hours under conditions of closed isolation air at 450 ~ 650 DEG C, and room temperature is cooled to
Afterwards, it is ground into the powder material B not less than 100 mesh;
(2)Take fowl and animal excrement biogas slurry, be added account for 3 ~ 5% flocculant of biogas slurry volume thereto, add account for biogas slurry weight 5 ~
10% activated carbon is sufficiently stirred, and is then removed by filtration the sediment biogas slurry that obtains that treated;
(3)10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
Zinc ion-porphyrin nano complex compound is obtained after entering into reaction bulb to be mixed reaction at room temperature 24 hours, it is spare;
(4)By step(2)Prepared treated biogas slurry and Brewery Wastewater Treatment sludge, vermiculite power, composite microbial bacteria
Agent, edible fungi residues are mixed thoroughly, and stirring is primary daily after 3 days, 3 days for first anaerobic fermentation, continuously stirs 10-15 days, controls
Tunning dries pulverizing is obtained powder C by central temperature of fermenting after fermentation at 55 ~ 65 DEG C;
(5)Powder material B, powder C and trace element, polycaprolactone, humic acid are uniformly mixed, by step(3)Gained zinc ion-porphin
Quinoline complexing nano object is uniformly sprinkled upon in said mixture material, and then mixed material is sent into comminutor and is granulated, and dry, packing is
Obtain product of the present invention.
A piece of salt-soda soil is chosen as corn planting experimental plot, ground soil 0cm ~ 20cm soil layer salt in Zouping County of Shandong Province
Content is average 0.2 ~ 0.5%, pH value 9.49.It is used using the present embodiment fertilizer as base manure, dosage is 500kg per acre, then
Maize planting, it is 586 kilograms that harvest time, which harvests per mu yield, than using Common compound fertilizer material(N-P-K contents:15 ~ 15 ~ 15, mu is applied
100 kilograms of dosage)469 kilograms of per mu yield volume increase 24.9%, soil 0cm ~ 20cm soil layer salt contents are down to 0.02 ~ 0.04%, pH
Value is reduced to 8.37, and gap increases by 83% between granule.
Embodiment 3
A kind of improvement salt-soda soil type biological organic complex fertilizer, it is made of the raw material of following parts by weight:Brewery Wastewater Treatment
500 parts of sludge, 250 parts of weathered coal, 900 parts of agricultural production waste, micro- 20 parts, zinc ion-porphyrin nano complex compound
1.5 parts, 150 parts of vermiculite power, 250 parts of fowl and animal excrement biogas slurry, 8 parts of complex micro organism fungicide, 30 parts of humic acid, edible fungi residues 150
Part, 40 parts of polycaprolactone;The complex micro organism fungicide is trichoderma viride and Bacillus cereus according to 3:1 weight ratio is mixed
It closes and is made.
The trace element is sodium molybdate, manganese sulfate, borax, ferrous sulfate and zinc sulfate according to 1:5:5:10:15 weight
Amount ratio is formulated.
The preparation method of above-mentioned improvement salt-soda soil type biological organic complex fertilizer is as follows:
(1)Agricultural production waste and weathered coal are uniformly mixed according to formula ratio, then into mixture according to solid-liquid ratio
1kg:0.5M MgCl are added in 30ml2Solution is stirred continuously, and is added after stirring 30min and is accounted for solid material weight ratio 3 ~ 5%
The sodium hydroxide solution of 3.0mol/L continues 10 ~ 15min of stirring, mixed material A is obtained after then being dried in baking oven, by material
A, which continues to be placed in Muffle furnace, to be roasted 3 ~ 6 hours under conditions of closed isolation air at 450 ~ 650 DEG C, and room temperature is cooled to
Afterwards, it is ground into the powder material B not less than 100 mesh;
(2)Take fowl and animal excrement biogas slurry, be added account for 3 ~ 5% flocculant of biogas slurry volume thereto, add account for biogas slurry weight 5 ~
10% activated carbon is sufficiently stirred, and is then removed by filtration the sediment biogas slurry that obtains that treated;
(3)10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
Zinc ion-porphyrin nano complex compound is obtained after entering into reaction bulb to be mixed reaction at room temperature 24 hours, it is spare;
(4)By step(2)Prepared treated biogas slurry and Brewery Wastewater Treatment sludge, vermiculite power, composite microbial bacteria
Agent, edible fungi residues are mixed thoroughly, and stirring is primary daily after 3 days, 3 days for first anaerobic fermentation, continuously stirs 10-15 days, controls
Tunning dries pulverizing is obtained powder C by central temperature of fermenting after fermentation at 55 ~ 65 DEG C;
(5)Powder material B, powder C and trace element, polycaprolactone, humic acid are uniformly mixed, by step(3)Gained zinc ion-porphin
Quinoline complexing nano object is uniformly sprinkled upon in said mixture material, and then mixed material is sent into comminutor and is granulated, and dry, packing is
Obtain product of the present invention.
A piece of salt-soda soil is chosen as corn planting experimental plot, ground soil 0cm ~ 20cm soil layer salt in Changyi City of Shandong Province
Content is average 0.2 ~ 0.4%, pH value 9.59.It is used using the present embodiment fertilizer as base manure, dosage is 500kg per acre, then
Maize planting, it is 579 kilograms that harvest time, which harvests per mu yield, than using Common compound fertilizer material(N-P-K contents:15 ~ 15 ~ 15, mu is applied
100 kilograms of dosage)455 kilograms of per mu yield volume increase 27.3%, soil 0cm ~ 20cm soil layer salt contents are down to 0.02 ~ 0.04%, pH
Value is reduced to 8.42, and gap increases by 86% between granule.
In addition, improvement salt-soda soil type biological organic complex fertilizer prepared by the present invention contain a large amount of beneficial activity bacterium supplemented with
The ability that soil permeability and retain water and nutrients are also improved while fertilizer nutrient, promotes the absorption of Plant To Nutrient element, improves
Disease-resistant, the anti-adversity ability of plant, and wherein functional nano complex compound and by agricultural production waste and weathered coal mixing system
The standby compounding ingredients synergistic effect with biomass carbon ingredient, makes fertilizer have significant slow release effect while can also reduce soil
Heavy metal ion content in earth, purifies crop growth environment, and reclamation result is notable.
Claims (8)
1. a kind of improvement salt-soda soil type biological organic complex fertilizer, which is characterized in that it is made of the raw material of following parts by weight:Beer
Sludge 400-600 parts of wine waste water processing station, 200-300 parts of weathered coal, 800-1000 parts of agricultural production waste, trace element
10-30 parts, it is zinc ion -1-2 parts of porphyrin nano complex compound, 100-200 parts of vermiculite power, 200-300 parts of fowl and animal excrement biogas slurry, compound
6-10 parts of microbial bacterial agent, 20-40 parts of humic acid, 100-200 parts of edible fungi residues, 30-50 parts of polycaprolactone;The composite microbial
Object microbial inoculum is trichoderma viride and Bacillus cereus according to 3:1 weight ratio is mixed to prepare.
2. improvement salt-soda soil according to claim 1 type biological organic complex fertilizer, which is characterized in that it is by following weight
The raw material of part is made:500 parts of Brewery Wastewater Treatment sludge, 250 parts of weathered coal, 900 parts of agricultural production waste, trace element
20 parts, zinc ion -1.5 parts of porphyrin nano complex compound, 150 parts of vermiculite power, 250 parts of fowl and animal excrement biogas slurry, complex micro organism fungicide 8
Part, 30 parts of humic acid, 150 parts of edible fungi residues, 40 parts of polycaprolactone.
3. improvement salt-soda soil according to claim 1 or 2 type biological organic complex fertilizer, which is characterized in that the zinc ion-
Porphyrin nano complex compound is prepared using following methods:By 10ml 1mol/L acetic acid zinc solutions and 1.5ml
After the acetum of four pyridylporphyrins of 0.05mmol/L is added in reaction bulb mixing reaction at room temperature 24 hours together
To obtain the final product.
4. improvement salt-soda soil according to claim 1 or 2 type biological organic complex fertilizer, which is characterized in that the micro member
Element is sodium molybdate, manganese sulfate, borax, ferrous sulfate and zinc sulfate according to 1:5:5:10:15 weight ratio is formulated.
5. a kind of preparation method of the improvement salt-soda soil type biological organic complex fertilizer described in claim 4, which is characterized in that it is wrapped
Include following steps:
(1)Agricultural production waste and weathered coal are uniformly mixed according to formula ratio, then into mixture according to solid-liquid ratio
1kg:MgCl is added in 30ml2Solution is stirred continuously, and the 3.0mol/L for accounting for solid material weight ratio 3 ~ 5% is added after stirring 30min
Sodium hydroxide solution continue 10 ~ 15min of stirring, then in baking oven dry after obtain mixed material A, material A is continued to set
It is roasted 3 ~ 6 hours at 450 ~ 650 DEG C under conditions of closed isolation air in Muffle furnace, after being cooled to room temperature, grinding
At the powder material B not less than 100 mesh;
(2)Fowl and animal excrement biogas slurry is taken, flocculant is added thereto, activated carbon is added and is sufficiently stirred, is then removed by filtration precipitation
Biogas slurry that object obtains that treated;
(3)10ml 1mol/L acetic acid zinc solutions are added together with the acetum of four pyridylporphyrins of 1.5ml 0.05mmol/L
Zinc ion-porphyrin nano complex compound is obtained after entering into reaction bulb to be mixed reaction at room temperature 24 hours, it is spare;
(4)By step(2)Prepared treated biogas slurry and Brewery Wastewater Treatment sludge, vermiculite power, composite microbial bacteria
Agent, edible fungi residues are mixed thoroughly, and stirring is primary daily after 3 days, 3 days for first anaerobic fermentation, continuously stirs 10-15 days, controls
Tunning dries pulverizing is obtained powder C by central temperature of fermenting after fermentation at 55 ~ 65 DEG C;
(5)Powder material B, powder C and trace element, polycaprolactone, humic acid are uniformly mixed, by step(3)Gained zinc ion-porphin
Quinoline complexing nano object is uniformly sprinkled upon in said mixture material, and then mixed material is sent into comminutor and is granulated, and dry, packing is
Obtain product of the present invention.
6. the preparation method of improvement salt-soda soil type biological organic complex fertilizer according to claim 5, which is characterized in that described
Step(1)Middle MgCl2Solution concentration is 0.5M.
7. the preparation method of improvement salt-soda soil type biological organic complex fertilizer according to claim 5, which is characterized in that described
Step(2)The addition of middle flocculant accounts for the 3 ~ 5% of biogas slurry volume.
8. the preparation method of improvement salt-soda soil type biological organic complex fertilizer according to claim 5, which is characterized in that described
Step(2)Middle activated carbon addition accounts for the 5 ~ 10% of biogas slurry weight.
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Cited By (4)
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CN109761711A (en) * | 2019-03-26 | 2019-05-17 | 广州极慧技术服务有限公司 | A kind of alkaline land soil improvement fertilizer and preparation method thereof |
CN109988017A (en) * | 2019-04-11 | 2019-07-09 | 山东省农业科学院玉米研究所 | A kind of microbial bacterial agent and preparation method thereof suitable for salt affected soil corn planting |
CN111087271A (en) * | 2019-12-30 | 2020-05-01 | 山东省农业科学院农业资源与环境研究所 | Soil conditioner for improving saline-alkali soil and preparation method thereof |
CN117535065A (en) * | 2023-10-27 | 2024-02-09 | 河北唯沃环境工程科技有限公司 | Straw baking and acid washing separation system |
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CN109988017A (en) * | 2019-04-11 | 2019-07-09 | 山东省农业科学院玉米研究所 | A kind of microbial bacterial agent and preparation method thereof suitable for salt affected soil corn planting |
CN109988017B (en) * | 2019-04-11 | 2022-04-08 | 山东省农业科学院玉米研究所 | Microbial agent suitable for saline-alkali soil corn planting and preparation method thereof |
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