CN114053172B - Ice crystal amino acid crystallization composition and preparation method thereof - Google Patents
Ice crystal amino acid crystallization composition and preparation method thereof Download PDFInfo
- Publication number
- CN114053172B CN114053172B CN202111394483.4A CN202111394483A CN114053172B CN 114053172 B CN114053172 B CN 114053172B CN 202111394483 A CN202111394483 A CN 202111394483A CN 114053172 B CN114053172 B CN 114053172B
- Authority
- CN
- China
- Prior art keywords
- amino acid
- phase
- ice crystal
- crystal amino
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0295—Liquid crystals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of daily cosmetics, in particular to an ice crystal amino acid crystallization composition and a preparation method thereof. The ice crystal amino acid crystallization composition contains the components of complex polyol, emulsion stabilizer, taurine, suspension stabilizer, alkaline neutralizer, deionized water and the like. The precipitated taurine crystals can be uniformly distributed in the composition by adding the supersaturated active amino acid component, namely taurine, and matching with the specific complex polyol, the emulsion stabilizer and the suspension stabilizer for use. The ice crystal amino acid crystallization composition can provide high-efficiency skin care effect when being applied to a resident cosmetic product.
Description
Technical Field
The invention relates to the technical field of daily cosmetics, in particular to an ice crystal amino acid crystallization composition and a preparation method thereof.
Background
Amino acids are a generic term for a class of organic compounds containing both amino and carboxyl groups. It is the most basic substance that constitutes a protein of an organism and is involved in life activities, and is the basic unit that constitutes a protein molecule in an organism, and is closely related to life activities of the organism. In recent years, with the progress of research on amino acids, amino acids have been increasingly used in various fields. With the advance of amino acid cosmetics in the market, the amino acid cosmetics industry has also been flourishing. Essential amino acid can be taken in by human body through food or special amino acid products, but amino acid cosmetics are in a new way, and the amino acid cosmetics are directly absorbed by skin or hair by coating and spraying on the surface layer of the skin, so that the beautifying effect is achieved. In the cosmetics industry, amino acid products are skin care products, cleaning products, hair conditioners and the like. The applicant's prior application (CN202110526454.2) discloses an ice crystal amino acid bath lotion and a preparation method thereof, wherein a composite surfactant, a suspension stabilizer and a natural plant extract with specific compositions are used, so that the bath lotion product has the appearance characteristics of a unique ice crystal pattern, is strong in moisturizing capability, and is moist but not greasy, and also has excellent effects of mildly cleaning, moisturizing, skin care and the like. On the basis of this, it is necessary to develop a crystal composition of an ice crystal amino acid which can be used in a leave-on amino acid cosmetic and has an excellent effect in use.
Disclosure of Invention
The invention aims to provide an ice crystal amino acid crystallization composition and a preparation method thereof. The precipitated taurine crystals can be uniformly distributed in the composition by adding the supersaturated active amino acid component, namely taurine, and matching with the specific complex polyol, the emulsion stabilizer and the suspension stabilizer for use. The ice crystal amino acid crystallization composition can provide high-efficiency skin care when being applied to a resident cosmetic product.
In order to achieve the purpose, the invention adopts the technical scheme that:
an ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 1-30% of composite polyol, 0.3-3% of emulsion stabilizer and the balance of deionized water;
phase B: 5-25% of taurine;
and C phase: 3-20% of suspension stabilizer, 6-15% of deionized water and 0.5-3% of alkaline neutralizer.
Preferably, the ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 10-20% of compound polyol, 0.5-2.5% of emulsion stabilizer and the balance of deionized water;
phase B: 10-20% of taurine;
and C phase: 5-15% of suspension stabilizer, 8-12% of deionized water and 1-2% of alkaline neutralizer.
Preferably, the ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 15% of composite polyol, 1.5% of emulsion stabilizer and the balance of deionized water;
phase B: 15% of taurine;
and C phase: 10% of suspension stabilizer, 10% of deionized water and 1.5% of alkaline neutralizer.
Preferably, the complex polyol consists of the following components in percentage by weight based on the total weight of the complex polyol: 10-30% of glycerol, 10-30% of propylene glycol, 5-20% of butanediol, 85-20% of polyethylene glycol, 5-20% of sorbitol and 5-10% of dipropylene glycol.
Preferably, the composite polyol consists of the following components in percentage by weight based on the total weight of the composite polyol: 25% of glycerol, 25% of propylene glycol, 15% of butanediol, 815% of polyethylene glycol, 15% of sorbitol and 5% of dipropylene glycol.
Preferably, the emulsion stabilizer is acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer.
Preferably, the suspension stabilizer is an acrylic acid (ester) copolymer.
Preferably, the acrylic acid (ester) copolymer is acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer.
Preferably, the alkaline neutralizing agent consists of the following components in percentage by weight based on the total weight of the alkaline neutralizing agent: 30-50% of sodium hydroxide, 20-40% of potassium hydroxide and 20-30% of triethanolamine.
Furthermore, the invention also provides a preparation method of the ice crystal amino acid crystallization composition, which comprises the following steps:
(1) adding the phase A component into a stirring kettle, heating to 80-90 ℃, and stirring until the phase A component is completely dissolved;
(2) adding the phase B component, and stirring until the phase B component is completely dissolved;
(3) cooling to 60-65 ℃, adding the C phase component, uniformly stirring until the mixture is transparent, and standing to obtain the ice crystal amino acid crystallization composition.
Taurine (Taurine) is a sulfur-containing amino acid with a simple structure in animals, has a chemical name of 2-aminoethanesulfonic acid, is odorless, has neutral dilute solution, is stable to heat, and is combined with cholic acid in human and animal bile to exist in a combined form. Researches prove that the taurine has the capability of activating skin cells and can continuously provide quick and durable energy supplement and multiple protection for young skin. The taurine also has the effects of improving the immunity of the skin and resisting the invasion of the external environment to the skin.
Compared with the prior art, the invention has the beneficial effects that: the amino acid crystallization suspension technology has the functions of moisturizing in a washing-off product and also has a good effect in a resident product. Taurine has the functions of moisturizing and relieving skin, and is amino acid required by human body. The precipitated taurine crystals can be uniformly distributed in the composition by adding the supersaturated active amino acid component, namely taurine, and matching with the specific complex polyol, the emulsion stabilizer and the suspension stabilizer for use. The addition of the complex polyol and the emulsion stabilizer can reduce the solubility of the taurine in the deionized water, so that crystals can be more easily separated out. The selected acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer has the suspension stabilizing effect, can ensure that precipitated taurine crystals are uniformly distributed, and has a spatial network structure which can form steric hindrance and can promote the directional crystallization of the taurine crystals. The ice crystal amino acid crystallization composition can provide high-efficiency skin care effect when being applied to a resident cosmetic product. In the actual use process, the taurine crystals can be rapidly broken and the high active concentration can be kept by the action of external force such as friction, beating and the like, so that the skin care capability of the resident cosmetic is enhanced.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention. The materials, reagents and the like used are, unless otherwise specified, commercially available reagents and materials.
Example 1
An ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 10% of composite polyol, 0.5% of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and the balance of deionized water;
phase B: 10% of taurine;
and C phase: 5% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 8% of deionized water and 1% of alkaline neutralizing agent.
According to the total weight of the composite polyol, the composite polyol consists of the following components in percentage by weight: 30% of glycerol, 30% of propylene glycol, 15% of butanediol, 815% of polyethylene glycol, 5% of sorbitol and 5% of dipropylene glycol.
The alkaline neutralizing agent consists of the following components in percentage by weight based on the total weight of the alkaline neutralizing agent: 40% of sodium hydroxide, 40% of potassium hydroxide and 20% of triethanolamine.
The preparation method of the ice crystal amino acid crystallization composition comprises the following steps:
(1) adding the phase A component into a stirring kettle, heating to 80 ℃, and stirring until the phase A component is completely dissolved;
(2) adding the phase B component, and stirring until the phase B component is completely dissolved;
(3) cooling to 60 ℃, adding the C phase component, uniformly stirring until the mixture is transparent, and standing to obtain the ice crystal amino acid crystalline composition.
Example 2
An ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 20% of composite polyol, 2.5% of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and the balance of deionized water;
phase B: 20% of taurine;
and C phase: 15% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 12% of deionized water and 2% of alkaline neutralizing agent.
According to the total weight of the composite polyol, the composite polyol consists of the following components in percentage by weight: 20% of glycerin, 20% of propylene glycol, 20% of butanediol, 820% of polyethylene glycol, 10% of sorbitol and 10% of dipropylene glycol.
The alkaline neutralizing agent consists of the following components in percentage by weight based on the total weight of the alkaline neutralizing agent: 35% of sodium hydroxide, 35% of potassium hydroxide and 30% of triethanolamine.
The preparation method of the ice crystal amino acid crystallization composition comprises the following steps:
(1) adding the phase A component into a stirring kettle, heating to 90 ℃, and stirring until the phase A component is completely dissolved;
(2) adding the phase B component, and stirring until the phase B component is completely dissolved;
(3) cooling to 65 ℃, adding the C phase component, uniformly stirring until the mixture is transparent, and standing to obtain the ice crystal amino acid crystalline composition.
Example 3
An ice crystal amino acid crystallization composition comprises the following components in percentage by weight based on the total weight of the composition:
phase A: 15% of composite polyol, 1.5% of acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer and the balance of deionized water;
phase B: 15% of taurine;
and C phase: 10% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 10% of deionized water and 1.5% of alkaline neutralizing agent.
According to the total weight of the composite polyol, the composite polyol consists of the following components in percentage by weight: 25% of glycerol, 25% of propylene glycol, 15% of butanediol, 815% of polyethylene glycol, 10% of sorbitol and 10% of dipropylene glycol.
The alkaline neutralizing agent consists of the following components in percentage by weight based on the total weight of the alkaline neutralizing agent: 40% of sodium hydroxide, 30% of potassium hydroxide and 30% of triethanolamine.
The preparation method of the ice crystal amino acid crystallization composition comprises the following steps:
(1) adding the phase A component into a stirring kettle, heating to 85 ℃, and stirring until the phase A component is completely dissolved;
(2) adding the phase B component, and stirring until the phase B component is completely dissolved;
(3) cooling to 62 ℃, adding the C phase component, uniformly stirring until the mixture is transparent, and standing to obtain the ice crystal amino acid crystallization composition.
Comparative example 1
In comparison with example 3, the composition of the complex polyol used in the ice crystal amino acid crystallization composition was: 50% of glycerin, 30% of butanediol and 20% of dipropylene glycol.
Comparative example 2
Compared with the example 3, the composition of the complex polyol used in the ice crystal amino acid crystallization composition is as follows: 50% of propylene glycol, 830% of polyethylene glycol and 20% of sorbitol.
Comparative example 3
Compared with example 3, the emulsion stabilizer used in the ice crystal amino acid crystallization composition is xanthan gum.
Comparative example 4
Compared with the example 3, the emulsion stabilizer used in the ice crystal amino acid crystallization composition is locust bean gum.
Comparative example 5
In contrast to example 3, the suspension stabilizer used in the ice crystal amino acid crystallization composition was TAB-2 (tallow amide phthalate).
Comparative example 6
In contrast to example 3, the suspension stabilizer used in the ice crystal amino acid crystallization composition was liquid carbomer ST-1 (lightly cross-linked acrylic acid (ester) copolymer emulsion).
Crystallization yield of ice crystal amino acid crystallization compositions
The ice crystal amino acid crystallization compositions of example 3 and comparative examples 1 to 4 were prepared according to the method for preparing the ice crystal amino acid crystallization composition described in example 3, respectively. The taurine crystal yield (%) of each composition was calculated by ultraviolet detection analysis. The results of the experiment are shown in table 1.
TABLE 1 crystallization yield (%)
As can be seen from the experimental results of Table 1, the ice crystal amino acid crystallization composition of example 3 had a high crystallization yield of 96.28%, while the crystallization yields of comparative examples 1 to 4 were relatively low. The results show that the compound polyhydric alcohol and the emulsion stabilizer with specific types and proportions can promote supersaturated taurine crystals to be separated out, so that the taurine crystals exist in higher concentration, and the skin care effect of the composition is enhanced.
Storage stability of ice crystal amino acid crystalline compositions
The ice crystal amino acid crystallization compositions of example 3 and comparative examples 5 to 6 were prepared according to the method for preparing the ice crystal amino acid crystallization composition described in example 3, respectively. The taurine crystal yield (%) of each composition was calculated on days 0, 7, 14 and 28 by ultraviolet detection analysis. The results of the experiment are shown in table 2.
TABLE 2 storage stability of ice crystal amino acid crystallization compositions
As can be seen from the experimental results of Table 2, the ice crystal amino acid crystallization composition of example 3 has good storage stability, and the crystallization yield can be maintained over 91% within 28 days, whereas the storage stability of comparative examples 5 to 6 is poor. The above results show that the specific suspension stabilizer (acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer) has good crystal suspension stabilizing effect, can uniformly distribute precipitated taurine crystals, and can keep the crystals stable for a long time. When the ice crystal amino acid crystallization composition is applied to a resident cosmetic product, a high-efficiency skin care effect can be provided. In the actual use process, the taurine crystals can be rapidly broken and the high active concentration can be kept by the action of external force such as friction, beating and the like, so that the skin care capability of the resident cosmetic is enhanced.
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, several modifications or equivalents may be made to the technical solution without departing from the principle of the present invention, and these modifications or equivalents should also be regarded as the protection scope of the present invention.
Claims (7)
1. An ice crystal amino acid crystallization composition is characterized by comprising the following components in percentage by weight based on the total weight of the composition:
phase A: 10-20% of compound polyol, 0.5-2.5% of emulsion stabilizer and the balance of deionized water;
phase B: 10-20% of taurine;
and C phase: 5-15% of suspension stabilizer, 8-12% of deionized water and 1-2% of alkaline neutralizer;
according to the total weight of the composite polyol, the composite polyol consists of the following components in percentage by weight: 10-30% of glycerol, 10-30% of propylene glycol, 5-20% of butanediol, 85-20% of polyethylene glycol, 5-20% of sorbitol and 5-10% of dipropylene glycol;
the emulsion stabilizer is acrylic acid (ester)/C10-30 alkanol acrylate cross-linked polymer.
2. An ice crystal amino acid crystallization composition according to claim 1, comprising the following components in weight percent based on the total weight of the composition:
Phase A: 15% of composite polyol, 1.5% of emulsion stabilizer and the balance of deionized water;
phase B: 15% of taurine;
and C phase: 10% of suspension stabilizer, 10% of deionized water and 1.5% of alkaline neutralizing agent.
3. An ice crystal amino acid crystallizing composition according to claim 1 or 2, wherein the complex polyol consists of the following components in weight percent based on the total weight of the complex polyol: 25% of glycerol, 25% of propylene glycol, 15% of butanediol, 815% of polyethylene glycol, 15% of sorbitol and 5% of dipropylene glycol.
4. An ice crystal amino acid crystalline composition according to claim 1 or 2, wherein the suspension stabilizer is an acrylic acid (ester) -based copolymer.
5. An ice crystal amino acid crystalline composition according to claim 4, wherein said acrylic acid (ester) -based copolymer is an acrylic acid (ester)/behenyl polyether-25 methacrylate copolymer.
6. An ice crystal amino acid crystallization composition according to claim 1 or 2, wherein the basic neutralizing agent consists of the following components in weight percent based on the total weight of the basic neutralizing agent: 30-50% of sodium hydroxide, 20-40% of potassium hydroxide and 20-30% of triethanolamine.
7. A process for the preparation of an ice crystal amino acid crystallization composition according to any one of claims 1 to 6, comprising the steps of:
(1) adding the phase A component into a stirring kettle, heating to 80-90 ℃, and stirring until the phase A component is completely dissolved;
(2) adding the phase B component, and stirring until the phase B component is completely dissolved;
(3) cooling to 60-65 ℃, adding the C phase component, uniformly stirring until the mixture is transparent, and standing to obtain the ice crystal amino acid crystallization composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111394483.4A CN114053172B (en) | 2021-11-23 | 2021-11-23 | Ice crystal amino acid crystallization composition and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111394483.4A CN114053172B (en) | 2021-11-23 | 2021-11-23 | Ice crystal amino acid crystallization composition and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN114053172A CN114053172A (en) | 2022-02-18 |
CN114053172B true CN114053172B (en) | 2022-06-28 |
Family
ID=80279375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111394483.4A Active CN114053172B (en) | 2021-11-23 | 2021-11-23 | Ice crystal amino acid crystallization composition and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114053172B (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0256656A1 (en) * | 1986-07-11 | 1988-02-24 | The Procter & Gamble Company | A liquid detergent composition |
CN113171331A (en) * | 2021-05-14 | 2021-07-27 | 广州锦同生物科技有限公司 | Ice crystal amino acid shower gel and preparation method thereof |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3383984B1 (en) * | 2015-12-04 | 2020-03-11 | Colgate-Palmolive Company | Cleansing bars with taurine |
CA3024121C (en) * | 2016-08-08 | 2023-10-31 | Colgate-Palmolive Company | Solid cleansing compositions with taurine and methods thereof |
-
2021
- 2021-11-23 CN CN202111394483.4A patent/CN114053172B/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0256656A1 (en) * | 1986-07-11 | 1988-02-24 | The Procter & Gamble Company | A liquid detergent composition |
CN113171331A (en) * | 2021-05-14 | 2021-07-27 | 广州锦同生物科技有限公司 | Ice crystal amino acid shower gel and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN114053172A (en) | 2022-02-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN112402280B (en) | Efficacy-promoting composition and application thereof | |
CN103720595B (en) | Amino acid pattern pearly-lustre facial cleaning cream composition and method of making the same | |
CN105476950B (en) | Moisturizing foam mildy wash and preparation method thereof | |
CN108524406A (en) | A kind of Golden flower facial mask and preparation method thereof | |
CN110772435A (en) | Anti-dandruff shampoo and preparation method thereof | |
CN106212453A (en) | A kind of glufosinate-ammoniumaqua aqua builder containing trimethylamino acid | |
CN110538083B (en) | Mild foam amino acid cleansing cream and preparation method thereof | |
CN114903834A (en) | Cold-storable mild double-tube facial cleanser and preparation method thereof | |
RU2006133386A (en) | SKIN CARE COMPOSITIONS CONTAINING SALICYLIC ACID | |
CN114053172B (en) | Ice crystal amino acid crystallization composition and preparation method thereof | |
CN105380868A (en) | Acne removal foundation make-up and preparation method thereof | |
CN113908097A (en) | Acne-removing composition and application thereof | |
KR101533766B1 (en) | A Soap Composition Containing Algae Fabrics | |
CN110269815A (en) | Shower cream and preparation method thereof containing chufa root oil | |
CN106361595A (en) | Zhiyan introduced solvent essence | |
CN107485598B (en) | It is a kind of to thicken pearl toner and preparation method thereof certainly | |
US20080081052A1 (en) | Topical compositions containing solubilized allantoin and related methods | |
CN112120963A (en) | Application of polylactic acid abrasive particles in cosmetics | |
CN113384488A (en) | Formula and preparation method of water-powder separation dual-phase mask capable of replenishing water and preserving moisture | |
CN106619333A (en) | Cleansing water and preparation method thereof | |
CN112569167A (en) | Washing and caring product based on amino acid anti-allergy component and preparation process thereof | |
CN112353740A (en) | Nail-protecting composition, nail-protecting hand cream and preparation method thereof | |
US9446082B2 (en) | Topical composition for treatment of skin, hair and/or nails and method of using the same | |
CN113559001B (en) | Whitening essence composition and preparation method and application thereof | |
CN111714403B (en) | Novel application of tetrahydropyrimidines and cooling preparation containing tetrahydropyrimidines |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |