CN113817550A - Formula of humic acid soap and its preparation process - Google Patents
Formula of humic acid soap and its preparation process Download PDFInfo
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- CN113817550A CN113817550A CN202010562455.8A CN202010562455A CN113817550A CN 113817550 A CN113817550 A CN 113817550A CN 202010562455 A CN202010562455 A CN 202010562455A CN 113817550 A CN113817550 A CN 113817550A
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- humic acid
- soap
- acid soap
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- 239000000344 soap Substances 0.000 title claims abstract description 166
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 151
- 239000004021 humic acid Substances 0.000 title claims abstract description 149
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
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- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/14—Shaping
- C11D13/16—Shaping in moulds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Dermatology (AREA)
- Gerontology & Geriatric Medicine (AREA)
- Cosmetics (AREA)
Abstract
A formula of humic acid soap and its preparation method, which comprises: a humic acid soap, which is prepared by mixing vegetable oil with sodium hydroxide solution to prepare soap lye, mixing with humic acid powder, and placing the mixture into a mould for shaping, wherein the weight ratio of the soap lye to the humic acid powder is 90-95% of the soap lye, 5-10% of the humic acid powder, and the pH value of the humic acid soap is 5.5-7 by neutralizing part of the soap lye with the humic acid powder; therefore, the formula and the preparation process of the humic acid soap are provided, and particularly, the humic acid soap is used for caring skin and neutralizing soap alkali by utilizing the humic acid component contained in the humic acid soap in the cleaning process, so that the skin care soap with humic acid functions is achieved.
Description
Technical Field
The invention provides a formula of humic acid soap and a preparation process thereof, in particular to a skin-care soap with humic acid, which uses humic acid components contained in the humic acid soap to care skin and neutralize soap alkali in a cleaning process to achieve the function of the skin-care soap with humic acid.
Background
The soap is one of the important articles for cleaning in human life, and the soap can greatly improve the environmental sanitation by strong detergency, the soap is simple to prepare and easy to obtain materials, so the soap is an article which is selected by most people to use when in cleaning, particularly in body cleaning, and after people gradually know the components contained in articles used in life, considering that the soap is superior to other detergents in health and price, the soap is still the main choice for cleaning products in daily use, along with the popularization of education, people can more generally recognize the soap, even most people can clearly know substances required by saponification reaction, therefore, people can choose to buy materials to make the soap by themselves, or purchasing handmade soap for convenient use of soap with definite ingredients to avoid body contact with excessive chemical additive substances; in terms of oil product selection, vegetable oil is mainly used as the main oil, the soap made of vegetable oil is mild, the addition amount of sodium hydroxide influences the acid-base property and saponification state of the finished soap product, particularly, the soap product is easy to be excessively added to cause too low acid-base value, so that the soap is easy to damage the skin due to over-alkali, and when the sodium hydroxide is insufficient, the soap is solidified and the cleaning force is reduced due to incomplete saponification reaction.
In view of the above, it is actually a major disadvantage that the soap is easily irritated by the soap due to the alkaline value of the soap being slightly alkaline caused by the excessive addition of sodium hydroxide during the manufacturing process, and the soap is easily uncomfortable to use.
In view of the above, the present inventors have conducted intensive studies and researches on the formulation of humic acid soap and the problems encountered in the manufacturing process thereof based on the related experiences in the field over the years, and have actively sought to solve the problems.
Disclosure of Invention
The main purposes of the invention are as follows: provides a formula for planting humic acid soap and a preparation process thereof, in particular to a skin-care soap which uses humic acid components contained in the humic acid soap to maintain the skin and neutralize soap alkali in the cleaning process so as to achieve the function of humic acid.
In order to achieve the purpose, the invention relates to a formula of humic acid soap and a preparation process thereof, which is characterized in that: comprises the following steps:
the humic acid soap is prepared by mixing vegetable oil with a sodium hydroxide solution to prepare a soap liquid, mixing humic acid powder into the soap liquid, and placing the mixture into a mold for shaping, wherein the weight ratio of the soap liquid to the humic acid powder is 90-95% of the soap liquid, 5-10% of the humic acid powder, and the pH value of the humic acid soap is 5.5-7 by neutralizing the soap liquid with the humic acid powder to be partially alkaline.
The invention has the following effects: the formula and the process of the humic acid soap are provided, the humic acid soap comprises 5-10% of humic acid, the humic acid is weakly acidic to neutralize soap alkali in the humic acid soap, the humic acid soap is weakly acidic, and rich mineral substances are contained in the humic acid, so that the humic acid soap can be used for cleaning, simultaneously, the skin can absorb trace mineral substances, a weakly acidic protective layer is formed on the surface of the skin, the humic acid soap has a skin care function, particularly, the humic acid has an anti-oxidation effect of preventing free radical aging, the humic acid soap is easier to store and is difficult to rancidity, and the skin can be prevented from aging when being cleaned; therefore, the formula and the preparation process of the humic acid soap are provided, and particularly, the humic acid soap is used for caring skin and neutralizing soap alkali by utilizing the humic acid component contained in the humic acid soap in the cleaning process, so that the skin care soap with humic acid functions is achieved.
Drawings
FIG. 1 is a schematic block diagram of a preferred embodiment of the present invention.
FIG. 2 is a schematic diagram of the steps of the cold soap manufacturing process according to the preferred embodiment of the present invention.
FIG. 3 is a schematic diagram of the steps of the hot soap making process according to the preferred embodiment of the present invention.
FIG. 4 is a partial cross-sectional view of the preferred embodiment of the present invention.
Detailed Description
Referring to fig. 4, a formula of humic acid soap and its manufacturing process includes: the humic acid soap 1 is prepared by mixing vegetable oil with a sodium hydroxide solution to prepare a soap lye, mixing with humic acid powder, and placing into a mold for shaping, wherein the weight ratio of the soap lye to the humic acid powder is 90-95% of the soap lye, 5-10% of the humic acid powder, and the pH value of the humic acid soap is 5.5-7 by neutralizing part of the soap lye with the humic acid powder;
with the above structure, the following is further described:
when the soap lye of the humic acid soap 1 is in a paste shape, the humic acid powder is added and mixed, so that the humic acid powder can not be completely dissolved in the soap lye, and the humic acid soap 1 can be added with high-content humic acid powder, thereby not influencing the saponification process of the soap lye easily;
myrrh essential oil is further added into the humic acid soap 1 to increase the antibacterial power of the humic acid soap 1 and avoid rancidity of the humic acid soap 1;
the humic acid powder is fulvic acid powder, fulvic acid is also named as fulvic acid, fulvic acid (mineral source type) is a very complex black organic substance, has biological activity characteristics, is a final aerobic decomposition product of all life substances, has unusual characteristics and capacity, can change and convert molecular combination, almost contains all organic and inorganic substances in the nature, and has the characteristics of fused molecules; the fulvic acid deposition is from decomposition of a large number of vegetation by microorganisms, is a naturally-produced organic substance, is completely from rotten ancient animals and plants, is lack of in modern food crops, is approved by the scientific community, but is not widely applied in the medical community because the complex biological structure of the fulvic acid cannot meet the treatment mechanism of modern western medicine, and a plurality of medical reports show that the fulvic acid has the effects of preventing diseases and prolonging the service life, but the fulvic acid cannot be chemically synthesized, and almost no fulvic acid product can be produced in the market due to the fact that the fulvic acid is required to be refined at high cost, so the fulvic acid is similar to be completely ignored in medicine; the fulvic acid has extremely rare content, low molecular weight and high biological activity, has good solubility and fluidity, can well stick and fuse mineral substances and elements into the molecular structure of the fulvic acid, has more than 70 mineral substances and trace elements, and is a necessary substance for healthy growth of animals and plants; fulvic acid is also an electrolyte: the electrolyte is easily contained in water or other liquid media capable of being electrified, the importance of the electrolyte is revealed to be inexhaustible in a plurality of animal cell tests, the reproducibility of the electrolyte is called as 'beauty demonstration' and 'perfect experiment' by scientists, and when the energy of the electrolyte is removed in the test process, cells are cracked and killed, if the electronic energy is reintroduced after the cells are reconstructed, the research is active again, and similar results are confirmed to occur in the human body;
a plurality of colloids are further arranged in the humic acid soap;
wherein each colloid is prepared from one of pectin, sodium alginate or acacia;
adding any one of potassium sulfide, eucalyptus essential oil or lemongrass essential oil into the soap solution of the humic acid soap;
wherein the soap solution of the humic acid soap is added with alcohol and heated until the soap solution is completely dissolved in the alcohol, and then humic acid powder is mixed in;
the soap solution of the humic acid soap is further added with schisandra chinensis powder;
particularly, the soap solution of the humic acid soap is added with plant fiber, and the plant fiber is selected from any one of bamboo, wood and petals;
the following table shows the ratio of the soap liquid to the humic acid powder and the pH value data of the humic acid soap 1:
unit: pH value
From the above experimental contents, it can be known that humic acid can effectively reduce the pH value of humic acid soap 1, so that the soap is closer to the pH value of skin, and the humic acid can improve the skin condition;
as shown in the above, the recipe of humic acid soap and the description of the operation state of the preferred embodiment of the process of the invention include: humic acid soap 1; wherein: the humic acid soap 1 has the formula already described above, so the following description is omitted:
firstly, the formula of the humic acid soap and the process thereof of the invention, the process of the cold soap comprises the following steps:
s1 material preparation: dissolving sodium hydroxide in water to obtain a sodium hydroxide solution, and cooling the sodium hydroxide solution to below 60 ℃;
s2 mixing step: adding a sodium hydroxide solution into vegetable oil, uniformly mixing to obtain a soap solution, and uniformly mixing the soap solution and humic acid powder to obtain a humic acid soap solution;
s3 solidification step: pouring humic acid soap liquid into a mould and waiting for the humic acid soap liquid to solidify to form humic acid soap 1;
s4 demolding step: demoulding and taking out the humic acid soap 1 in the mould;
s5 soap airing step: standing the humic acid soap 1 in a shady and cool ventilating place for 2-8 weeks;
s6 cutting step: cutting the humic acid soap 1 into proper size according to the requirement and packaging;
furthermore, the formula of the humic acid soap and the process thereof of the invention, the process of the hot soap making comprises the following steps:
s10 material preparation: dissolving sodium hydroxide in water to obtain a sodium hydroxide solution;
s20 mixing step: adding a sodium hydroxide solution into vegetable oil, uniformly mixing to obtain a soap solution, and uniformly mixing the soap solution and humic acid powder to obtain a humic acid soap solution;
s30 heating step: adding humic acid soap liquid into alcohol in a proper proportion, and keeping the temperature at 70-80 ℃ to completely dissolve the humic acid soap liquid into the alcohol;
s40 solidification step: pouring humic acid soap liquid into a mould and waiting for the humic acid soap liquid to solidify to form humic acid soap 1;
s50 demolding step: demoulding and taking out the humic acid soap 1 in the mould;
s60 cutting step: cutting the humic acid soap 1 into proper size according to the requirement and packaging;
further, myrrh essential oil is added to the humic acid soap 1 to increase the antibacterial power of the humic acid soap 1 and prevent the humic acid soap 1 from rancidity, myrrh is not the flower and fruit rhizome of commiphora molmol but resin, and is native to tropical Africa regions such as Somali and Lessobia, and also in Arabian-Seman of the middle east and India. Myrrha is dry oleo-gum resin exuded from Commiphora myrrha of Burseraceae and Commiphora, the Myrrha used as traditional Chinese medicine is resin exuded from dry bark of Commiphora myrrha of Burseraceae or Commiphora, and Commiphora myrrha is low shrub or arbor, thick trunk, and thick branch with irregular and sharp shape; the bark is thin and often flaked, and resin may naturally seep out from cracks in the bark, or the bark may be manually cut and oleoresin may seep out. The resin is one of self-protection mechanisms of plants, and the resin in the myrrh tree bark contains hydroxyl nitrile (aquanitrile) substances, can be decomposed into virulent hydrogen cyanide (aquagencyanide), and can damage tissues of bacteria or fungi. The resin is white sticky when flowing out, becomes solidified reddish brown blocks after being oxidized when meeting air, is harvested from 11 months per year to 2 months next year, is stored in a dry and ventilated place after removing impurities, and the appearance of the myrrh is granular. Myrrh, English letter of Myrrh, is from Arabic and in Greece is meant for fragrancing, since Myrrh is a resin that exudes odors, and can be made into perfumes and essences. The production of the ixobia and the thauma is said to account for most of the supply in the market, while the myrrh trees grown on the limestone, the rind and the wood have stronger fragrance, the resin is more bitter and spicy, and the modern medicine proves that the myrrh contains a plurality of chemical components: the composition comprises myrrh resin, volatile oil, gum, a small amount of bitter substances, and further comprises bisabolol, formic acid, acetic acid and oxidase, and the volatile oil comprises eugenol, m-methyl phenol, limonene, cinnamaldehyde and the like. The gum is similar to Arabic gum, hydrolysis generates arabinose, galactose and xylose, and has different degrees of inhibition effects on various pathogenic fungi such as trichophyton, and possibly related to eugenol, the resin-containing part can reduce the blood cholesterol content of hypercholesterolemia and prevent plaque formation in blood vessels, wherein the different degrees of inhibition effects on various pathogenic fungi such as trichophyton can improve skin diseases caused by fungi such as tinea, tinea pedis and the like;
the humic acid soap 1 is further internally provided with a plurality of colloids 2, wherein each colloid 2 is made of pectin, sodium alginate or Arabic gum, and each colloid 2 is not easy to dissolve in water, so that each colloid 2 can protrude out of the surface of the humic acid soap 1 when the soap is rubbed, and then each colloid 2 can be utilized to massage the skin, so that the absorption rate is increased, and the effects of moisturizing and water retention are added;
the humic acid soap 1 is added with any one of potassium sulfide, eucalyptus essential oil or lemongrass essential oil in the soap liquid, wherein the humic acid soap prepared by adding the potassium sulfide has the characteristics of a sulfur soap, and the sulfur soap has a very strong oil control effect and can effectively control seborrheic dermatitis; the sulfur soap can effectively inhibit bacteria parasitizing on the surface of the skin and has strong bactericidal effect on the skin with acnes and acnes; the sulfur soap has the effects of diminishing inflammation and expelling toxin, can well dispel mites and can be used for treating various skin diseases for a long time;
the humic acid soap 1 has the advantages that the addition of the eucalyptus essential oil or the lemongrass essential oil into the soap liquid can effectively inhibit bacteria, reduce mites and improve skin conditions;
the humic acid soap 1 is characterized in that schisandra chinensis powder is added into the soap liquid, the schisandra chinensis powder has the effects of oxidation resistance and inflammation resistance, is helpful for enhancing cell activity and delaying skin aging, effective components can be still remained after the soap is added, and the product value of the humic acid soap 1 is further improved;
particularly, the soap solution of the humic acid soap 1 is added with plant fiber, the plant fiber is selected from any one of bamboo, wood and petal, and the humic acid soap 1 is mixed with the plant fiber to add the massage effect of the humic acid soap 1;
finally, the humic acid soap has the following effects due to the formula and the preparation process of the humic acid soap: the humic acid soap 1 is made to be weakly acidic by using 5-10% of humic acid, and neutralizing soap alkali in the humic acid soap 1 by using the weak acidity of the humic acid, so that the humic acid soap 1 is made to be weakly acidic, and rich mineral substances are contained in the humic acid, so that the humic acid soap 1 can enable the skin to absorb trace mineral substances while cleaning, and a weak acidic protective layer is formed on the surface of the skin, so that the humic acid soap 1 has a skin care function, particularly the humic acid has an anti-oxidation effect of preventing radical aging, so that the humic acid soap 1 is easier to store and is not easy to rancid, and the skin can be delayed to age when being washed; therefore, a formula of the humic acid soap and a preparation process thereof are provided, in particular to a skin-care soap with humic acid, which is prepared by using humic acid components contained in the humic acid soap 1 to maintain the skin and neutralize the soap lye in the cleaning process.
From the foregoing, it is understood that the present invention is capable of being widely applied to various industries, and has advantages of advancement and novelty. However, the above description is only a preferred embodiment of the present invention, and the scope of the present invention should not be limited by the above description; therefore, all the equivalent changes and modifications made according to the claims of the present invention should be covered by the scope of the present invention.
Claims (10)
1. The formula of humic acid soap and the preparation process thereof are characterized in that: comprises the following steps:
the humic acid soap is prepared by mixing vegetable oil with a sodium hydroxide solution to prepare a soap liquid, mixing humic acid powder into the soap liquid, and placing the mixture into a mold for shaping, wherein the weight ratio of the soap liquid to the humic acid powder is 90-95% of the soap liquid, 5-10% of the humic acid powder, and the pH value of the humic acid soap is 5.5-7 by neutralizing the soap liquid with the humic acid powder to be partially alkaline.
2. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein, the humic acid soap is prepared by adding the humic acid powder when the soap liquid is pasty.
3. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the humic acid soap further comprises myrrh essential oil.
4. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the humic acid powder is fulvic acid powder.
5. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the humic acid soap is internally provided with a plurality of colloids.
6. The humic acid soap formula and its preparation method as claimed in claim 5, wherein: wherein each colloid is prepared from pectin, sodium alginate or acacia.
7. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein, any one of potassium sulfide, eucalyptus essential oil or lemon grass essential oil is added into the soap liquid of the humic acid soap.
8. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the soap solution of the humic acid soap is added with alcohol and heated until the soap solution is completely dissolved in the alcohol, and then humic acid powder is mixed in.
9. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the soap solution of the humic acid soap is added with schisandra chinensis powder.
10. The humic acid soap formula and its preparation method as claimed in claim 1, wherein: wherein the soap solution of the humic acid soap is added with plant fiber, and the plant fiber is selected from any one of bamboo, wood and petal.
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| RU2012136939A (en) * | 2012-08-30 | 2014-03-10 | Александр Иванович Майдан | TOILET SOAP |
| CN107541367A (en) * | 2017-09-08 | 2018-01-05 | 东北师范大学 | A kind of soap base acid-base neutralization auxiliary agent and its preparation method |
| CN107574046A (en) * | 2017-09-08 | 2018-01-12 | 东北师范大学 | A kind of peat handmade soap and its cold method processed |
| CN107805557A (en) * | 2017-11-10 | 2018-03-16 | 北京泰克美高新技术有限公司 | A kind of handmade soap and preparation method thereof |
| CN108085199A (en) * | 2017-12-31 | 2018-05-29 | 跨越生物科技（滁州）有限公司 | It is a kind of can effective skin care perfumed soap |
| CN109576095A (en) * | 2018-12-14 | 2019-04-05 | 杨鹏熙 | A kind of preparation method of sodium humate perfumed soap |
| RU2710362C1 (en) * | 2019-03-26 | 2019-12-26 | Валерий Иванович Федосеев | Toilet soap |
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2020
- 2020-06-18 CN CN202010562455.8A patent/CN113817550A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2012136939A (en) * | 2012-08-30 | 2014-03-10 | Александр Иванович Майдан | TOILET SOAP |
| CN107541367A (en) * | 2017-09-08 | 2018-01-05 | 东北师范大学 | A kind of soap base acid-base neutralization auxiliary agent and its preparation method |
| CN107574046A (en) * | 2017-09-08 | 2018-01-12 | 东北师范大学 | A kind of peat handmade soap and its cold method processed |
| CN107805557A (en) * | 2017-11-10 | 2018-03-16 | 北京泰克美高新技术有限公司 | A kind of handmade soap and preparation method thereof |
| CN108085199A (en) * | 2017-12-31 | 2018-05-29 | 跨越生物科技（滁州）有限公司 | It is a kind of can effective skin care perfumed soap |
| CN109576095A (en) * | 2018-12-14 | 2019-04-05 | 杨鹏熙 | A kind of preparation method of sodium humate perfumed soap |
| RU2710362C1 (en) * | 2019-03-26 | 2019-12-26 | Валерий Иванович Федосеев | Toilet soap |
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