CN113749128A - Medicament for killing invertebrate pests and preparation method thereof - Google Patents

Medicament for killing invertebrate pests and preparation method thereof Download PDF

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Publication number
CN113749128A
CN113749128A CN202111214934.1A CN202111214934A CN113749128A CN 113749128 A CN113749128 A CN 113749128A CN 202111214934 A CN202111214934 A CN 202111214934A CN 113749128 A CN113749128 A CN 113749128A
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medicament
pesticide
urea
adhesive
killing
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Chinese (zh)
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李明华
李翔玉
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/38Solanaceae [Potato family], e.g. nightshade, tomato, tobacco or chilli pepper
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/36Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Organic Chemistry (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Inorganic Chemistry (AREA)
  • Botany (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)

Abstract

The invention discloses a medicament for killing invertebrate pests and a preparation method thereof, wherein the medicament comprises the following components: lime wash, dietary alkali, sea pepper powder, prickly ash powder, urea, the adhesive, with lime wash, dietary alkali, sea pepper powder, prickly ash powder, urea, the adhesive adds in the mixing tank in proper order, with lime wash through agitating unit, dietary alkali, sea pepper powder, prickly ash powder, urea, the adhesive homogeneous mixing, the medicament that will prepare the completion is sealed, store, the medicament through the preparation kills invertebrate pest, solved and used the pesticide to kill after the pest now, a large amount of pesticide composition is left over on crops, leave over the pesticide on crops and be difficult to clear up, lead to the pesticide easily along with food gets into the consumer's internally, and then lead to the problem of harm consumer healthy.

Description

Medicament for killing invertebrate pests and preparation method thereof
Technical Field
The invention relates to a medicament, in particular to a medicament for killing invertebrate pests and a preparation method thereof.
Background
After the existing pesticide is used for killing pests, a large amount of pesticide ingredients are left on crops, the pesticide left on the crops is difficult to clean, the pesticide easily enters the bodies of eaters along with edible food, and further the health of the eaters is harmed, in order to solve the technical problems, it is necessary to search a formula for killing invertebrate pests from the existing minerals, the insects have single taste weakness, in order to achieve the purpose of controlling the pests, the insects need to be checked from the fruits of vegetables, the insects and the items, the micro world insects, such as red pastures, leaf miners, rotifers, ant insects and the like, propagate quite fast, the next generation appears in about 30 hours, the places where the insects come out are vegetables and fruits, other food is not jumped in the lifetime, particularly the most difficult handling of the red flower bottom pests, the common size of the green insects and the invertebrate insects, and the treatment is not difficult by the treatment of two bristlegrass, eggs and chemical transfer, melissitus ruthenicus is damaged in the flowering phase of fruits, and later-stage fruit drop and insect growth are caused, the fruit insects have common food characteristics, all the fruit insects need to be eaten by various species with high vitamins, high protein and high sugar, and for many years, certain areas use minerals for killing the fruit and vegetable, so that the effect is very good.
Disclosure of Invention
The invention aims to solve the technical problems that after the existing pesticide is used for killing pests, a large amount of pesticide ingredients are left on crops, and the pesticide left on the crops is difficult to clean, so that the pesticide easily enters into the bodies of eaters along with edible food, and further the health of the eaters is harmed.
The invention is realized by the following technical scheme:
an agent for exterminating invertebrate pests and a method for preparing the same, comprising the following components: lime water, edible alkali, paprika powder, urea and an adhesive.
The working principle of the invention is as follows: in order to solve the technical problems, the medicament for killing the invertebrate pests is prepared by uniformly mixing lime water, edible alkali, sea pepper powder, urea and a bonding agent, and after the medicament is diluted with clear water, the diluted medicament is sprayed to the crops through a sprayer so as to kill the invertebrate pests on the crops; the pesticide contains lime water, facilitates calcium supplement of crops while killing pests, promotes calcium absorption of crops and promotes growth of crops, has sterilization and disinfection effects, enables fruits and vegetables growing to have good taste after the crops are sterilized, is convenient to eat and sell, has better effect of killing invertebrate pests than existing chemical drugs and biological drugs, facilitates killing invertebrate pests on the crops while avoiding leaving pesticide residues on the crops, has an effective period of 30-60 days, facilitates the effect of permanently killing invertebrate pests on the crops, kills the invertebrate pests by using the pesticide, avoids chemical drugs and harmful substances from leaving on the crops, enables the crops eating the invertebrate pests to kill human beings, Different animals are safe, the harm to the health of eaters is avoided, and the problems of damage to the environment and environmental pollution caused by using the pesticide for killing pests are also avoided.
Further, the weight ratio of the following components is included: 600g of lime water, 200g of edible alkali, 3-10g of pepper powder, 2-10g of pepper powder, 50-90g of urea and 10-20g of adhesive.
Further, the alkali concentration of the prepared medicament is 10-14%.
Further, the adhesive comprises taro.
Further, crushing raw taros, sequentially adding lime water, edible alkali, paprika powder and urea, and uniformly mixing the taros, the lime water, the edible alkali, the paprika powder and the urea by stirring.
Further, lime water, edible alkali, paprika powder, urea and an adhesive are sequentially added into a mixing tank, the lime water, the edible alkali, the paprika powder, the urea and the adhesive are uniformly mixed through a stirring device, and the prepared medicament is sealed and stored.
Compared with the prior art, the invention has the following advantages and beneficial effects:
1. the medicament contains lime water, and is convenient for supplementing calcium to crops while killing pests, so that the absorption of the crops to the calcium is promoted, and the growth of the crops is facilitated;
2. the medicament for killing invertebrate pests and the preparation method thereof have the effects of sterilization and disinfection, and the fruits and vegetables grown by sterilizing crops have better mouthfeel, so that the fruits and vegetables are convenient to eat and sell;
3. the effect of killing invertebrate pests by using the pesticide is better than that of the existing chemical drugs and biological drugs, so that the invertebrate pests on crops can be conveniently killed, the pesticide residue on the crops can be avoided, the pesticide effect lasting period of validity of the pesticide is as long as 30-60 days, and the pesticide can be conveniently and durably killed on the crops.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to examples, and the exemplary embodiments and descriptions thereof are only used for explaining the present invention and are not used as limitations of the present invention.
Example 1
The invention relates to a medicament for killing invertebrate pests and a preparation method thereof, and the specific implementation mode of the embodiment is as follows: 200g of lime water, 100g of edible alkali, 3g of pepper powder, 2g of pepper powder, 50g of urea and 10g of adhesive are prepared into a medicament with the alkali concentration of 10%, and the medicament is sprayed to the paddy by a sprayer.
Example 2
Based on embodiment 1, the specific implementation manner of this embodiment is as follows: 600g of lime water, 200g of edible alkali, 10g of pepper powder, 90g of urea and 20g of adhesive are prepared into a medicament with the alkali concentration of 14%, and the medicament is sprayed to the paddy by a sprayer.
Example 3
Based on the above embodiment, the specific implementation manner of this embodiment is as follows: 400g of lime water, 150g of edible alkali, 6.5g of sea pepper powder, 6g of pepper powder, 70g of urea and 15g of adhesive are prepared into a medicament with the alkali concentration of 12%, and the medicament is sprayed to the paddy through a sprayer.
Comparative example 1
The existing pesticide for killing invertebrate pests is diluted according to a pesticide use instruction, the diluted pesticide is filled into a sprayer, and a water body containing pesticide components is sprayed to rice through the sprayer.
The agents of examples 1 to 3 and the pesticide of comparative example 1 were used to spray rice of the same area for the same time, and the areas sprayed with the agents of examples 1 to 3 and comparative example 1 were examined for their effectiveness in killing invertebrate pests, respectively, and the areas sprayed with the agents of examples 1 to 3 and comparative example 1 were examined for rice leaving harmful substances of the pesticide on the rice. The examination results were as follows:
group of Invertebrate pest killing rate Whether or not it contains a residue of a pesticide or an injurious substance
Example 1 100% Whether or not
Example 2 100% Whether or not
Example 3 100% Whether or not
Comparative example 1 85.2% Is that
Example 4
The invention relates to a medicament for killing invertebrate pests and a preparation method thereof, and the specific implementation mode of the embodiment is as follows: 200g of lime water, 100g of edible alkali, 3g of pepper powder, 2g of pepper powder, 50g of urea and 10g of adhesive are prepared into a medicament with the alkali concentration of 10%, and the medicament is sprayed to lotus plumule by a sprayer.
Example 5
Based on embodiment 4, the specific implementation manner of this embodiment is as follows: 600g of lime water, 200g of edible alkali, 10g of pepper powder, 90g of urea and 20g of adhesive are prepared into a medicament with alkali concentration of 14%, and the medicament is sprayed to lotus plumule by a sprayer.
Example 6
Based on the above embodiment, the specific implementation manner of this embodiment is as follows: 400g of lime water, 150g of edible alkali, 6.5g of paprika powder, 6g of paprika powder, 70g of urea and 15g of adhesive are prepared into a medicament containing 12% alkali, and the medicament is sprayed to the lotus plumule by a sprayer.
Comparative example 2
The existing pesticide for killing invertebrate pests is diluted according to a pesticide use instruction, the diluted pesticide is filled into a sprayer, and a water body containing pesticide components is sprayed to lotus plumule through the sprayer.
The agents of examples 4 to 6 and the pesticide of comparative example 2 were used to spray the lotus leaves of the same area for the same time, the areas sprayed with the agents of examples 4 to 6 and comparative example 2 were examined for their effectiveness in killing invertebrate pests, and the areas sprayed with the agents of examples 4 to 6 and comparative example 2 were examined for the presence of harmful substances of the pesticide left on the lotus leaves. The examination results were as follows:
group of Invertebrate pest killing rate Whether or not it contains a residue of a pesticide or an injurious substance
Example 4 100% Whether or not
Example 5 100% Whether or not
Example 6 100% Whether or not
Comparative example 2 84.7% Is that
Examples 4-6 examination of residue on Liriope Crassifolia (L.) W.H.:
Figure BDA0003310407770000041
example 7
The invention relates to a medicament for killing invertebrate pests and a preparation method thereof, and the specific implementation mode of the embodiment is as follows: 200g of lime water, 100g of edible alkali, 3g of pepper powder, 2g of pepper powder, 50g of urea and 10g of adhesive are prepared into a medicament with the alkali concentration of 10%, and the medicament is sprayed to the oranges through a sprayer.
Example 8
Based on embodiment 7, the specific implementation manner of this embodiment is as follows: 600g of lime water, 200g of edible alkali, 10g of pepper powder, 90g of urea and 20g of adhesive are prepared into a medicament with alkali concentration of 14%, and the medicament is sprayed to the oranges through a sprayer.
Example 9
Based on the above embodiment, the specific implementation manner of this embodiment is as follows: 400g of lime water, 150g of edible alkali, 6.5g of paprika powder, 6g of paprika powder, 70g of urea and 15g of adhesive are prepared into a medicament with the alkali concentration of 12%, and the medicament is sprayed to the oranges through a sprayer.
Comparative example 3
The existing pesticide for killing invertebrate pests is diluted according to a pesticide use instruction, the diluted pesticide is filled into a sprayer, and a water body containing pesticide ingredients is sprayed to oranges through the sprayer.
The agents of examples 7 to 9 and the pesticide of comparative example 3 were used to spray-irrigate oranges of the same area for the same time, and the areas irrigated with the agents of examples 7 to 9 and comparative example 3 were examined for their effectiveness in killing invertebrate pests, respectively, and the oranges of the areas irrigated with the agents of examples 7 to 9 and comparative example 3 were examined for the presence of harmful substances of the pesticide left on the oranges. The examination results were as follows:
group of Invertebrate pest killing rate Whether or not it contains a residue of a pesticide or an injurious substance
Example 7 99.8% Whether or not
Example 8 100% Whether or not
Example 9 99.9% Whether or not
Comparative example 3 83.1% Is that
Examples 7-9 inspection report of residue on oranges appendix:
Figure BDA0003310407770000051
Figure BDA0003310407770000061
the above-mentioned embodiments are intended to illustrate the objects, technical solutions and advantages of the present invention in further detail, and it should be understood that the above-mentioned embodiments are merely exemplary embodiments of the present invention, and are not intended to limit the scope of the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (6)

1. An agent for combating invertebrate pests, comprising the following components: lime water, edible alkali, paprika powder, urea and an adhesive.
2. An agent for exterminating an invertebrate pest according to claim 1 comprising the following components in mass: 600g of lime water, 200g of edible alkali, 3-10g of pepper powder, 2-10g of pepper powder, 50-90g of urea and 10-20g of adhesive.
3. The agent for exterminating an invertebrate pest according to claim 1 wherein the agent is prepared to contain an alkali at a concentration of 10% to 14%.
4. The agent for exterminating invertebrate pests according to claim 1 wherein the adhesive comprises taro.
5. The agent for exterminating invertebrate pests according to claim 4, wherein the lime water, the dietary alkali, the paprika powder and the urea are sequentially added after raw taros are crushed, and the taros are uniformly mixed with the lime water, the dietary alkali, the paprika powder and the urea by stirring.
6. The preparation method of the medicament for killing invertebrate pests according to claim 1, wherein the lime water, the edible alkali, the paprika powder, the urea and the adhesive are sequentially added into a mixing tank, the lime water, the edible alkali, the paprika powder, the urea and the adhesive are uniformly mixed by a stirring device, and the prepared medicament is sealed and stored.
CN202111214934.1A 2021-10-19 2021-10-19 Medicament for killing invertebrate pests and preparation method thereof Pending CN113749128A (en)

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Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031010A (en) * 1988-07-21 1989-02-15 徐建军 A kind of pesticide liquid that kills the mite sterilization
CN101496529A (en) * 2009-03-07 2009-08-05 朱任林 Camellia oleifera environment-friendly pesticide
CN101715793A (en) * 2009-10-30 2010-06-02 茹晖 Ecological pesticide and preparation method thereof
CN101773148A (en) * 2009-01-12 2010-07-14 深圳市湖尔美农业生物科技有限公司 Preparation method of urea using fertilizer to control pests
CN101926372A (en) * 2010-07-12 2010-12-29 重庆东方农药有限公司 Nicotinamide-matrine aqua vegetable insecticide and preparation method thereof
CN102320894A (en) * 2011-06-21 2012-01-18 吕金波 The many mixture of a kind of biological pesticide
CN104855185A (en) * 2015-05-21 2015-08-26 秦盼盼 Strawberry pest control method
CN105053088A (en) * 2015-07-22 2015-11-18 长沙秋点兵信息科技有限公司 Crop pesticide of plant source and preparation method thereof
CN105622260A (en) * 2015-12-27 2016-06-01 哈尔滨泉兴科技有限公司 Chinese chive nutrition composition and preparation method thereof
CN105638769A (en) * 2016-04-13 2016-06-08 储志强 Method for preparing pesticide
CN106818930A (en) * 2017-02-20 2017-06-13 曹国栋 A kind of plant source double play liquid for preventing and treating rice pest and preparation method thereof
CN108353945A (en) * 2018-04-04 2018-08-03 徐州农丰生物化工有限公司 A kind of composite natural pesticide
CN108633927A (en) * 2018-04-08 2018-10-12 徐州农丰生物化工有限公司 A kind of Efficient environment-friendlyinsecticide insecticide
CN110352994A (en) * 2019-07-31 2019-10-22 胡道德 Non-toxic pesticide and preparation method thereof
CN112586516A (en) * 2020-12-02 2021-04-02 蚌埠海上明珠农业科技发展有限公司 Pollution-free strawberry insecticide and preparation method thereof

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031010A (en) * 1988-07-21 1989-02-15 徐建军 A kind of pesticide liquid that kills the mite sterilization
CN101773148A (en) * 2009-01-12 2010-07-14 深圳市湖尔美农业生物科技有限公司 Preparation method of urea using fertilizer to control pests
CN101496529A (en) * 2009-03-07 2009-08-05 朱任林 Camellia oleifera environment-friendly pesticide
CN101715793A (en) * 2009-10-30 2010-06-02 茹晖 Ecological pesticide and preparation method thereof
CN101926372A (en) * 2010-07-12 2010-12-29 重庆东方农药有限公司 Nicotinamide-matrine aqua vegetable insecticide and preparation method thereof
CN102320894A (en) * 2011-06-21 2012-01-18 吕金波 The many mixture of a kind of biological pesticide
CN104855185A (en) * 2015-05-21 2015-08-26 秦盼盼 Strawberry pest control method
CN105053088A (en) * 2015-07-22 2015-11-18 长沙秋点兵信息科技有限公司 Crop pesticide of plant source and preparation method thereof
CN105622260A (en) * 2015-12-27 2016-06-01 哈尔滨泉兴科技有限公司 Chinese chive nutrition composition and preparation method thereof
CN105638769A (en) * 2016-04-13 2016-06-08 储志强 Method for preparing pesticide
CN106818930A (en) * 2017-02-20 2017-06-13 曹国栋 A kind of plant source double play liquid for preventing and treating rice pest and preparation method thereof
CN108353945A (en) * 2018-04-04 2018-08-03 徐州农丰生物化工有限公司 A kind of composite natural pesticide
CN108633927A (en) * 2018-04-08 2018-10-12 徐州农丰生物化工有限公司 A kind of Efficient environment-friendlyinsecticide insecticide
CN110352994A (en) * 2019-07-31 2019-10-22 胡道德 Non-toxic pesticide and preparation method thereof
CN112586516A (en) * 2020-12-02 2021-04-02 蚌埠海上明珠农业科技发展有限公司 Pollution-free strawberry insecticide and preparation method thereof

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Application publication date: 20211207