CN107455390A - Composition pesticide of environment-protecting pesticide sterilization and preparation method thereof - Google Patents
Composition pesticide of environment-protecting pesticide sterilization and preparation method thereof Download PDFInfo
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- CN107455390A CN107455390A CN201710734655.5A CN201710734655A CN107455390A CN 107455390 A CN107455390 A CN 107455390A CN 201710734655 A CN201710734655 A CN 201710734655A CN 107455390 A CN107455390 A CN 107455390A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Abstract
The invention discloses the composition pesticide of environment-protecting pesticide sterilization, including insecticidal constituent, sterilization component and auxiliary element, the quality parts ratio of the insecticidal constituent and sterilization component is 3~6：1, mass percent of the auxiliary element in composition pesticide is 65%~80%；Wherein, insecticidal constituent is the mixture of OTAC and benzene sulfonate, and sterilization component is copper 8-hydroxyquinolinate.Environment-protecting pesticide bactericidal pesticide composition provided by the invention can be widely used for the preventing and treating of the pest and disease damages such as fruit tree, vegetables, crops, and pesticide-germicide ability is strong, and prevention effect is good, small to air, water source, pollution of agricultural products, raw material components are simple, and cost is low, and noresidue, it is green.Present invention also offers the preparation method of the composition pesticide, the simple production process of said composition, suitable for large-scale production, is easy to promote the use of.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to the composition pesticide of environment-protecting pesticide sterilization and its preparation side
Method.
Background technology
It is increasing with the enhancing of environmental consciousness, the non-polluted farm product market space with the improvement of people ' s living standards.
However, pollution by pesticides has turned into the restraining factors of Agricultural product without pollution.In recent years, it is raw with the adjustment of crop mix
Production condition and disease pest population structure are changed, and pest and disease damage occurring area increases year by year, and the extent of injury is on the rise.For control
The generation of pest and disease damage, part peasant's violation operation pesticide abuse, hidden danger is left for the production of non-polluted farm product；Other medication
Not science, long-term single drug, the harmful organism resistance to the action of a drug is set to increase, drug effect declines, and causes agricultural chemicals to air, water source, agricultural product
Pollution.
Domestic existing sterilization and disinfection class agricultural chemicals is mostly chemical pesticide, and easily causing a large amount of toxin using such agricultural chemicals remains in
In crops, vegetables and melon and fruit, make natural environment heavily contaminated, break ring natural environment and the ecological balance, oneself forms public
Evil, the living environment of the mankind is directly threatened, be unfavorable for developing green agriculture and pollution-free food.
In recent years, someone developed several environment friendly agriculturals, and the insecticidal effect of such agricultural chemicals is preferable, but sterilize, go out poison
Effect is weaker, and more crops are not encouraged, help strong function, and production technology is more complicated, expensive starting materials, and cost is high,
Production scale is very limited, it is difficult to promotes and implements.
As China applies disclosing a kind of nuisanceless broad spectrum disinfestation sterilization soluble powdered precursor agriculture in CN02114170.3
Medicine and its production method, the agricultural chemicals include active matter and various auxiliary agents, and the active matter is that cationic surfactant is organic
The complex compound that complex compound that iodo activation forms, anion surfactant are formed by organosilicon activation.Raw material components be present and answer in it
Miscellaneous, the problem of production cost is high, especially practice have shown that, the agricultural chemicals is owed to the prevention effect of fruit tree, vegetables, diseases and pests of agronomic crop
The defects of preferable；The organic iodine wherein contained has negative effect to crops normal growth.
A kind of composition pesticide of environment-protecting pesticide bactericidal action is studied in consideration of it, needing badly, not only with pesticide-germicide
Double effectses, and drug safety, it is environmentally safe.
The content of the invention
It is an object of the invention to provide composition pesticide of a kind of environment-protecting pesticide sterilization and preparation method thereof, the combination
Thing is small to air, water source, pollution of agricultural products, and raw material components are simple, and simple production process, cost is low, and to the normal of crops
See that worm, the prevention effect of pathogen are good.
To achieve the above object, on the one hand the present invention provides a kind of composition pesticide of environment-protecting pesticide sterilization, including kills
The quality parts ratio of worm composition, sterilization component and auxiliary element, the insecticidal constituent and the sterilization component is 3~6：1, it is described
Mass percent of the auxiliary element in composition pesticide is 65%~80%；
Wherein, insecticidal constituent is the mixture of OTAC, Nylar and benzene sulfonate, and sterilization component is quinoline
Quinoline copper, auxiliary element include cellulose, sucrose, boric acid, anhydrous sodium sulfate, amino acid fertilizer, salt and agalloch eaglewood powder.
Further, in the composition pesticide of environment-protecting pesticide of the present invention sterilization, the auxiliary element include with
The component of lower quality parts ratio：8 parts~16 parts of cellulose, 4 parts~8 parts of sucrose, 16 parts~24 parts of boric acid, 11 parts of anhydrous sodium sulfate
~19 parts, 10 parts~18 parts of amino acid fertilizer, 2 parts~6 parts of 3 parts~7 parts of salt and agalloch eaglewood powder.
Further, in the composition pesticide of environment-protecting pesticide sterilization of the present invention, the insecticidal constituent is by following
The composition composition of parts by weight：10 parts of 4 parts ~ 10 parts of OTAC, 1 part ~ 5 parts of Nylar and benzene sulfonate ~
20 parts.
Further, the composition pesticide of environment-protecting pesticide sterilization of the present invention, by the composition of following parts by weight
Composition：5 parts of OTAC, 2 parts of Nylar, 12 parts of cellulose, 13 parts of benzene sulfonate, 6 parts of sucrose, boric acid 20
4 parts of part, 15 parts of anhydrous sodium sulfate, 14 parts of amino acid fertilizer, 5 parts of salt, 4 parts of agalloch eaglewood powder and copper 8-hydroxyquinolinate.
Further, in the composition pesticide of environment-protecting pesticide sterilization of the present invention, the benzene sulfonate is 12
Sodium alkyl benzene sulfonate or the octyl benzene sulfonic acid sodium salt of biguanides three.
Further, in the composition pesticide of environment-protecting pesticide sterilization of the present invention, the agalloch eaglewood powder is violet
Agalloch eaglewood powder.
Further, in the composition pesticide of environment-protecting pesticide sterilization of the present invention, contain in the amino acid fertilizer
18 kinds of amino acid, whole total amino acid contents are 72 %.
The specific effect of each main component is as follows in the environment-protecting pesticide bactericidal pesticide composition of the present invention：
In the environment-protecting pesticide bactericidal pesticide composition of the present invention, active insecticidal components are OTAC, pyrrole
The insecticidal mechanism of both propyl ether and benzene sulfonate, OTAC and benzene sulfonate is after the two mixing in worm
Exothermic reaction occurs in thalline, so as to reach the effect of kill entomogenous fungi, Nylar is a kind of juvenoid, is a kind of low
Malicious novel pesticide, after above both combine, there is interior suction transfer activity, and less toxic persistence itself is grown, to crop safety,
It is small to eco-environmental impact to fish low toxicity；In addition, OTAC, as alkylating reagent, it is chemically
Can be active, entomogenous fungi vivo protein can not only be made to produce precipitation, moreover it is possible to the carboxyl in entomogenous fungi vivo protein, amino, different pyrrole
The phosphate bond of piperidinyl or DNA works, and then destroys the cell metabolism of entomogenous fungi, and then kill entomogenous fungi.But for tool
There are the humans and animals of red blood cell, because red blood cell transport oxygen has oxidation, it is easy to aoxidize the active matter of low concentration broken
It is bad, inactivate OTAC, therefore, the active insecticidal components are safe for humans and animals.Nylar
In larval phase, the appearance of adult feature can be suppressed, larva state is still kept after making larval molting；In the adult stage, there is controlling
Development, produce sex inducement, promote the effect such as maturation of ovum, infertile phenomenon can be produced；It is sprayed on ovum, embryonic development can be prevented,
[W with 1], the Nylar that the present invention adds can be used for hygienic insecticide, for the larva of mosquitos and flies and maggot etc., thus it is safe to people, animal
And it is harmless to natural enemy, beneficial insect, it is free from environmental pollution.
In the environment-protecting pesticide bactericidal pesticide composition of the present invention, bactericidal active ingredient is copper 8-hydroxyquinolinate, and it has to clamp together state
Machine copper fungicide, for preventing and treating the agricultural chemicals composition of apple tree ring spot etc..With efficient, wide spectrum, safety, low toxicity, low-residual etc.
Feature, all there is excellent prevention effect to fungi, bacterial disease.The product mode of action is unique, is formed and caused in crop surface
Privacy protection film, kill pathogen in film.Inside pathogen, suppress the activity and conduction of the main conduction thing of pathogen, so as to
Kill pathogen.
In the environment-protecting pesticide bactericidal pesticide composition of the present invention, the amino acid fertilizer in auxiliary element contains 18 kinds of amino
Acid, more fully nutrition can be provided for plant, improved soil, promote photosynthesis, maintain nutrient balance, improve the disease-resistant of crop
Anti-adversity ability, inherently improve crop quality, improve yield.Quick after, crop turns green soon, can make crop leaf
Piece is green and thick, increases fruit sugariness, glossiness.
In the environment-protecting pesticide bactericidal pesticide composition of the present invention, the salt in auxiliary element has stronger Pesticidal and sterilizing to make
With being the common drug for preventing and treating a variety of faulty wordings, particularly prevent and treat bacterium, fungi, fish disease caused by a variety of parasites, have significant
Effect.
In the environment-protecting pesticide bactericidal pesticide composition of the present invention, the agalloch eaglewood powder in auxiliary element, main function is regulation
Product odour, lure insect.
The composition pesticide pesticide-germicide double action that the environment-protecting pesticide being prepared according to inventive formulation is sterilized, is killed
Worm and bactericidal action are coordinated mutually, and it is more to kill pest species, and it is more to kill germ application point, be used for multiple times germ will not produce it is anti-
Property, the disease to have been developed immunity to drugs to conventional sterilization agent has efficient prevention, therapeutic effect.
On the other hand, the present invention also provides the preparation method of the composition pesticide of described environment-protecting pesticide sterilization, and it is wrapped
Include following steps：
（1）First by formulation weight number in air-flow pulvis unit premixing tank, first octadecyl is added by predetermined weight percent
Trimethyl ammonium chloride, cellulose, crushing, stirring 5-10 minutes, then add benzene sulfonate, Nylar, sugarcane by predetermined weight percent
Sugar, boric acid, anhydrous sodium sulfate, amino acid powder, salt, agalloch eaglewood powder, copper 8-hydroxyquinolinate, crushing, stirring 5-10 minutes, obtain and slightly mix raw material；
（2）Raw material after above-mentioned steps (1) are slightly mixed through airslide disintegrating mill crush 15 minutes~25 minutes, and fineness reaches
500 mesh；
（3）By the first vacuum feeder and pipeline into double conic rotary vacuum dryer, 0.079-0.099 MPa,
10-15 minutes are dried under the conditions of 35-55 DEG C, then gained compound is delivered in two-dimensional motion mixer, are mixed 10 minutes
~20 minutes, obtain composition pesticide finished product.
Further, the present invention is also provided in the preparation method of the composition pesticide of described environment-protecting pesticide sterilization, also
Including including step（3）By gained finished product by vacuum feeding automatic packaging machine automatic measuring packing, that is, obtain composition pesticide
Product.
The preparation method of the composition pesticide of the environment-protecting pesticide sterilization of the present invention, Preparation equipment cost is low, technical process
Simply, preparation condition is easily achieved, and is easy to large-scale industrialized production.
Compared with prior art, the beneficial effect of the composition pesticide of environment-protecting pesticide of the invention sterilization is：
1st, pesticide-germicide double action：The composition pesticide desinsection of the environment-protecting pesticide sterilization of the present invention and bactericidal action are assisted mutually
Adjust, it is more to kill pest species, kills that germ application point is more, and germ, which is used for multiple times, will not produce resistance, to conventional sterilization agent
Disease through developing immunity to drugs has efficient prevention, therapeutic effect.
2nd, the wide sterilization spectrum lasting period is grown：Environment-protecting pesticide bactericidal pesticide composition of the present invention, has comprehensively to fungi, bacterium
Prophylactic treatment acts on, and the lasting period is up to 15 days.
3rd, it is safe：Environment-protecting pesticide bactericidal pesticide composition of the present invention, fallen leaves, Bao Ye and fruit retention is not stimulated, especially
It is that spire, young fruit period are safe and reliable.
4th, mixture is good：Environment-protecting pesticide bactericidal pesticide composition of the present invention, pH value have excellent mixture in neutrality
Property, can be with most of mixed pesticides.
5th, fruit-vegetable quality can be improved：Environment-protecting pesticide bactericidal pesticide composition of the present invention, fruits and vegetables blade greening blast can be made,
Fruit surface is bright and clean, noresidue stain, strengthens fruit face colouring.
6th, green nuisance free pesticide is belonged to：Environment-protecting pesticide bactericidal pesticide composition of the present invention, pesticide-germicide ability is strong, prevents
It is good to control effect, it is small to human toxicity, it is green, it is production green non-pollution food（Vegetables, melon and fruit etc.）Outstanding bactericide.
Present disclosure is further detailed below in conjunction with embodiment.
Embodiment
Further detailed description is done to the present invention with reference to specific embodiment, but embodiments of the present invention are not limited to
This.
Raw material employed in following examples is that market directly buying obtains.Wherein, the product that amino acid fertilizer is chosen
Containing 17 kinds of amino acid, the total amount of whole amino acid is 72 %, and the species content of specific amino acid is as shown in table 1 below.
Table 1：The content table of amino acid in amino acid fertilizer
First, embodiment is prepared
Prepare embodiment 1：
Environment-protecting pesticide bactericidal pesticide composition, it is made up of the component of following ratio of weight and number：OTAC 3
Part, 1 part of Nylar, 8 parts of cellulose, 20 parts of neopelex, 4 parts of sucrose, 24 parts of boric acid, 19 parts of anhydrous sodium sulfate,
10 parts of amino acid fertilizer, 3 parts of salt, 5 parts of violet agalloch eaglewood powder, 4 parts of copper 8-hydroxyquinolinate.
Preparation method：
（1）Weigh each raw material respectively according to formula ratio, first add the OTAC of formula ratio and cellulose
In airslide disintegrating mill, crushing, stirring 10 minutes；
（2）Again neopelex, Nylar, sucrose, boric acid, anhydrous sodium sulfate, ammonia are added thereto successively by formula
Base acid fertilizer, salt, violet agalloch eaglewood powder and copper 8-hydroxyquinolinate, add follow-up continuous crushing, stirring 5 minutes, obtain mixture；
（3）Gained mixture is delivered in double conic rotary vacuum dryer by vacuum feeder, 0.079 MPa, 35 DEG C
Lower drying 10 minutes；
（4）Then it is delivered to by the second vacuum feeder in two-dimensional motion mixer, mixing obtains pesticide combination in 10 minutes
Thing finished product；
（5）Gained finished product is passed through into vacuum feeding automatic packaging machine automatic measuring packing, you can obtain dispensing product.Often bag packing
Amount is generally 50 g, 100 g or 250 g.
The application method of composition pesticide prepared by the present embodiment：After being diluted with water 400 times, spraying uses.The present invention
Environment-protecting pesticide sterilization composition pesticide pH value in neutrality, there is excellent mixture, can be with most of mixed pesticides.
Prepare embodiment 2：
Environment-protecting pesticide bactericidal pesticide composition, it is made up of the component of following ratio of weight and number：OTAC 6
Part, 5 parts of Nylar, 16 parts of cellulose, 10 parts of three octyl benzene sulfonic acid sodium salt of biguanides, 8 parts of sucrose, 16 parts of boric acid, anhydrous sodium sulfate
11 parts, 18 parts of amino acid fertilizer, 7 parts of salt, 3 parts of violet agalloch eaglewood powder, 4 parts of copper 8-hydroxyquinolinate.
Preparation method：
（1）Weigh each raw material respectively according to formula ratio, first add the OTAC of formula ratio and cellulose
In airslide disintegrating mill, crushing, stirring 20 minutes；
（2）Sequentially add the octyl benzene sulfonic acid sodium salt of biguanides three, Nylar, sucrose, boric acid, the anhydrous slufuric acid of formula ratio thereto again
Sodium, amino acid fertilizer, salt, violet agalloch eaglewood powder and copper 8-hydroxyquinolinate, crushing, stirring 15 minutes, obtain mixture；
（3）Gained mixture is delivered in double conic rotary vacuum dryer by vacuum feeder, 0.099 MPa, 55 DEG C
Lower drying 15 minutes；
（4）Then it is delivered to by the second vacuum feeder in two-dimensional motion mixer, mixing obtains pesticide combination in 20 minutes
Thing finished product；
（5）Gained finished product is passed through into vacuum feeding automatic packaging machine automatic measuring packing, you can obtain dispensing product.
The application method of composition pesticide prepared by the present embodiment：After being diluted with water 1000 times, spraying uses.
Prepare embodiment 3：
Environment-protecting pesticide bactericidal pesticide composition, it is made up of the component of following ratio of weight and number：OTAC 4
Part, 2 parts of Nylar, 10 parts of cellulose, 15 parts of neopelex, 7 parts of sucrose, 22 parts of boric acid, 13 parts of anhydrous sodium sulfate,
12 parts of amino acid fertilizer, 6 parts of salt, 2 parts of violet agalloch eaglewood powder, 7 parts of copper 8-hydroxyquinolinate.
Preparation method：
（1）Weigh each raw material respectively according to formula ratio, first add the OTAC of formula ratio and cellulose
In airslide disintegrating mill, crushing, stirring 15 minutes；
（2）Sequentially add thereto again the neopelex of formula ratio, Nylar, sucrose, boric acid, anhydrous sodium sulfate,
Amino acid fertilizer, salt, violet agalloch eaglewood powder and copper 8-hydroxyquinolinate, crushing, stirring 15 minutes, obtain mixture；
（3）Gained mixture is delivered in double conic rotary vacuum dryer by vacuum feeder, at 0.085MPa, 45 DEG C
Dry 12 minutes；
（4）Then be delivered to by the second vacuum feeder in two-dimensional motion mixer, mix 15 minutes, obtain composition pesticide into
Product；
（5）By gained finished product by vacuum feeding automatic packaging machine automatic measuring packing,.
The application method of composition pesticide prepared by the present embodiment：After being diluted with water 500 times, spraying uses.
Prepare embodiment 4：
Environment-protecting pesticide bactericidal pesticide composition, it is made up of the component of following ratio of weight and number：OTAC
10 parts, 5 parts of Nylar, 8 parts of cellulose, 20 parts of neopelex, 5 parts of sucrose, 17 parts of boric acid, anhydrous sodium sulfate 12
Part, 14 parts of amino acid fertilizer, 3 parts of salt, 6 parts of violet agalloch eaglewood powder, 5 parts of copper 8-hydroxyquinolinate.
Preparation method：
（1）Weigh each raw material respectively according to formula ratio, first add the OTAC of formula ratio and cellulose
In airslide disintegrating mill, crushing, stirring 18 minutes；
（2）Sequentially add thereto again the neopelex of formula ratio, Nylar, sucrose, boric acid, anhydrous sodium sulfate,
Amino acid fertilizer, salt, violet agalloch eaglewood powder and copper 8-hydroxyquinolinate, crushing, stirring 10 minutes, obtain mixture；
（3）Gained mixture is delivered in double conic rotary vacuum dryer by vacuum feeder, at 0.099MPa, 55 DEG C
Dry 12 minutes；
（4）Then be delivered to by the second vacuum feeder in two-dimensional motion mixer, mix 18 minutes, obtain composition pesticide into
Product；
（5）By gained finished product by vacuum feeding automatic packaging machine automatic measuring packing,.
The application method of composition pesticide prepared by the present embodiment：After being diluted with water 700 times, spraying uses.
Prepare embodiment 5：
Environment-protecting pesticide bactericidal pesticide composition, it is made up of the component of following ratio of weight and number：OTAC 5
Part, 2 parts of Nylar, 12 parts of cellulose, 13 parts of neopelex, 6 parts of sucrose, 20 parts of boric acid, 15 parts of anhydrous sodium sulfate,
14 parts of amino acid fertilizer, 5 parts of salt, 4 parts of violet agalloch eaglewood powder, 4 parts of copper 8-hydroxyquinolinate.
Preparation method：
（1）Weigh each raw material respectively according to formula ratio, first add the OTAC of formula ratio and cellulose
In airslide disintegrating mill, crushing, stirring 20 minutes；
（2）Sequentially add thereto again the neopelex of formula ratio, Nylar, sucrose, boric acid, anhydrous sodium sulfate,
Amino acid fertilizer, salt, violet agalloch eaglewood powder and copper 8-hydroxyquinolinate, crushing, stirring 10 minutes, obtain mixture；
（3）Gained mixture is delivered in double conic rotary vacuum dryer by vacuum feeder, at 0.085MPa, 45 DEG C
Dry 12 minutes；
（4）Then be delivered to by the second vacuum feeder in two-dimensional motion mixer, mix 15 minutes, obtain composition pesticide into
Product；
（5）By gained finished product by vacuum feeding automatic packaging machine automatic measuring packing,.
The application method of composition pesticide prepared by the present embodiment：After being diluted with water 600 times, spraying uses.
Effect example
The composition pesticide of environment-protecting pesticide of the present invention sterilization, available for the preventing and treating of the insect pests such as fruit tree, vegetables, rice, using pair
As including coccid, caterpillar, blue or green worm, aphid, acarid, loxostege sticticalis, leafhopper, red spider, rice leaf roller, planthopper, rice plant skipper
Deng；The preventing and treating of the disease as caused by pathogen such as fruit tree, vegetables, rice is can also be used for, such as banded sclerotial blight, rice blast, solanberry anthrax
Disease, powdery mildew, mandarin tree yellow twig etc..The environment-protecting pesticide of the present invention is further illustrated below by specifically used effect test
The purposes and using effect of bactericidal pesticide composition.
（1）Orange scale control is tested
With citrus（Sugar orange）For for studying thing, citrus coccid（Arrowhead scales, icerya purchasi）For controlling object, provided with test group and
Control group；Test group uses the product of the present embodiment 3（500 times of dilution, is used with spray pattern）, control group uses 40% methidathion
EC（500 times of dilution, is used with spray pattern）.
Control time and number：Before dispenser and 3 days after dispenser, respectively investigate once within 7 days, 15 days, investigate 4 times altogether.
Investigation method：Each treatment region takes diagonal to sample, and investigates 5 points, fix 1 plant of fruit tree, in every plant of fruit tree at every
All directions in direction is each fixes 2 young sprouts, investigation records coccid number.Test effect is shown in Table 2 and table 3.
Table 2 prevents and treats the test effect of citrus branch icerya purchasi
Table 3 prevents and treats the test effect of citrus branch arrowhead scales
From table 2 and table 3, the environment-protecting pesticide bactericidal pesticide composition of the present embodiment is prevented with good citrus coccid
Effect is controlled, using 3 days preventive effects of composition pesticide citrus branch arrowhead scales of embodiment 3 up to after 73.68%, 7 day, preventive effect reaches
89.47%, preventive effect is up to 95.32% after medication 15 days；And during same time, experimental group preventive effect is substantially better than control group, says
The composition pesticide of bright the present embodiment effect in terms of citrus branch arrowhead scales is prevented and treated is better than 40% conventional methidathion EC.In addition,
It is also seen that the lasting period length of this composition pesticide, has comprehensive prophylactic treatment to act on, the lasting period is up to 15 to fungi, bacterium
My god.
（2）Prevent and treat paddy rice rice leaf roller, banded sclerotial blight experiment
Carry out the present embodiment product preventing and treating paddy rice rice leaf roller, banded sclerotial blight respectively in Chenzhou City Anren County, Suxian District（Only reviving
Celestial area）Field test.
Using the experimental plot of Anren County as No. 1 experimental plot, the experimental plot is using rice varieties V644 as trial crops, cnaphalocrocis
Snout moth's larva is subjects, provided with test group, control group；Test group uses the product of embodiment 5（600 times of dilution, is made with spray pattern
With）, control group uses 40% Profenofos missible oil（1500 times of dilution, is used with spray pattern）.Result of the test statistics is shown in Table 4.
Using the experimental plot of Suxian District as No. 2 experimental plots, the experimental plot is trial crops with rice varieties C two excellent 396, and rice is indulged
Leaf roll snout moth's larva, banded sclerotial blight are subjects, provided with test group, control group；Test group uses the product of embodiment 5（600 times of dilution, with
Spray pattern uses）, control group uses 40% Profenofos missible oil（1500 times of dilution, is used with spray pattern）, 20% jinggangmycin
Wettable powder（1000 times of dilution, is used with spray pattern）.Result of the test statistics is shown in Table 5, table 6.
Efficacy survey method：Prevent and treat rice leaf roller：Investigate insect density before medicine, 1 day, 3 days, 7 days investigation preventions after medicine
Effect.Using five point sampling（Every root and stem of certain plants of straight line 5）, 25 root and stem of certain plants are investigated per cell, borer population living is counted, calculates Revision insect recluced rate after medicine
And preventive effect.
Prevent and treat banded sclerotial blight：Diseased plant rate, disease index are investigated before medicine, 3 days, 7 days, 14 days investigation prevention effects after medicine.Using
Five point sampling（Every root and stem of certain plants of straight line 5）, 25 root and stem of certain plants are investigated per cell, count total strain number, diseased plant number and sick series, calculate diseased plant after medicine
Rate, disease index and preventive effect.
The result of the test statistical form of table 4（No. 1 experimental plot）
The result of the test statistical form of table 5（No. 2 experimental plots）
The result of the test statistical form of table 6（No. 2 experimental plots）
From table 4, table 5, paddy rice rice leaf roller is prevented and treated using the composition pesticide product of the preparation embodiment 5 of the present invention,
Prevention effect after dispenser 7 days is 93.0%（No. 1 experimental plot）、96.1%（No. 2 experimental plots）, average preventive effect is 94.6%；Use
40% Profenofos EC paddy rice rice leaf roller, the prevention effect after dispenser 7 days are 79.7%（No. 1 experimental plot）、93.5%（2
Number experimental plot）, average preventive effect is 86.6%.From the foregoing, the environment-protecting pesticide bactericidal pesticide composition of the present embodiment is for water
Rice rice leaf roller has good insecticidal effect, and average prevention effect is better than currently used 40% Profenofos missible oil.
As shown in Table 6, rice sheath blight disease is prevented and treated using the present embodiment product, the preventive effect of 14 days is 73.1% after medicine；Use
20% jinggangmycin wettable powder prevents and treats rice sheath blight disease, and the preventive effect of 14 days is 67.2% after medicine.From the foregoing, the present embodiment
Environment-protecting pesticide bactericidal pesticide composition there is good sterilization prevention effect for rice sheath blight disease, averagely prevent and treat rice line
Rot drug effect is better than currently used jinggangmycin wettable powder.
（3）Safety testing
The environment-protecting pesticide bactericidal pesticide composition that the embodiment of the present invention 4 is prepared is according to the conventional toxicology test in this area
And the toxicity test to environmental organism security, its toxicity is tested, specific test result is shown in Table 7.
The present embodiment product toxicology test of table 7 and the toxicity test result to environmental organism security
| Method of administration | Toxicity assessment |
| Rat acute | Male and female rat LD50:Equal ＞ 5000mg/kg；Micro- poison |
| Rat acute is percutaneous | Male and female rat LD50 ＞ 5000mg/kg；Micro- poison |
| Lagophthalmos excitant | It is non-stimulated |
| Rabbit skin excitant | Slight stimulation |
| Cavy sensitization | Slight stimulation |
| Fish acute toxicity | Zebra fish LC50 (48h):47.9mg/L low toxicity |
| The oral acute toxicity of honeybee | LC50(48h):6000mg/L, low-risk |
| Honeybee contacts acute toxicity | The μ g/L of LC50 (48h) ＞ 10；Low toxicity |
| Birds acute toxicity | Quail LD50 (7d) ＞ 300mg/kg quails, low toxicity |
| Silkworm acute toxicity | LC50 (two ages)：4051mg/kg mulberries tell, low-risk |
As shown in Table 7, the environment-protecting pesticide bactericidal pesticide composition of the present embodiment is micro- poison to the toxicity of rat acute, right
The percutaneous toxicity of rat acute is micro- poison, is non-stimulated to lagophthalmos excitant, is slight stimulation to rabbit skin excitant, uses peace
Entirely；Toxicity and risk grade scale according to agricultural chemicals to environmental organism, the present embodiment product is low toxicity to fish and bird, to honeybee
It is low-risk agricultural chemicals with silkworm, it is environmentally safe during use.
（4）Residues of pesticides are tested（Security）
According to this area conventional methods to the environment-protecting pesticide bactericidal pesticide composition of the embodiment of the present invention 2 on citrus it is residual
Experiment is stayed to be tested.Test in 2015-2016 Changshas agriculture university test site and the examination of Zhejiang Hangzhou Zhejiang academy of agricultural sciences
Test base progress.
In the Orange Producing phase, the composition pesticide product that the embodiment of the present invention 2 is prepared dilutes 150 times, to citrus trees
（Including citrus leaf, branch and fruit）Closed with tangerine Orchard Soil spray pesticide 1 time.On Hunan, the full fruit of Zhejiang two places citrus
Resolution half-life period is respectively 3.73 days and 4.08 days in the value measured in 2015, the value that 2016 measure be respectively 3.64 days with
3.85 my god.Hunan, Zhejiang two places tangerine Orchard Soil in resolution half-life period the value measured in 2015 be respectively 3.92 days and
3.08 days, be respectively 3.99 days and 4.49 days in the value that 2016 measure.
As a result show that product is cleared up comparatively fast in the full fruit of citrus and tangerine Orchard Soil, it is 4.08 days that half-life period is cleared up in full fruit
Within, half-life period is cleared up in soil in 4.49 days.Under China's natural environmental condition, OTAC is not
Accumulation can be caused to remain.
Adjust dispenser dosage：The composition pesticide of embodiment 2 is diluted into 1000 times to be sprayed, to citrus trees（Including mandarin orange
Tangerine leaf, branch and fruit）Closed spray pesticide（Citrus leaf and fruit have untill decoction starts drippage）；150 times of dilution, to mandarin orange
Tangerine tree（Including citrus leaf, branch and fruit）Closed spray pesticide（Citrus leaf and fruit have untill decoction starts drippage）.
Experimental study is carried out in the Citrus Orchard for not applying agricultural chemicals.Experiment sets 2 kinds of dispenser dosage, 2 kinds of spraying times（2 times, 3
It is secondary, every minor tick 7 days）With 6 processing of blank control test.Different time harvesting citrus fruit and tangerine Orchard Soil difference after dispenser
The residual quantity of measure wherein OTAC, result of the test are shown in Table 8 and table 9.
Residue test of the 8 2015 years OTACs of table in citrus tangerine meat, tangerine peel and Citrus Orchard soil
As a result
Note：1st, LOD is minimum detectability amount；2nd, citrus tangerine meat, tangerine peel are in terms of fresh weight；3rd, citrus soil is in terms of dry weight.
Residue test of the 9 2016 years OTACs of table in citrus tangerine meat, tangerine peel and Citrus Orchard soil
As a result
Note：1st, LOD is minimum detectability amount；2nd, citrus tangerine meat, tangerine peel are in terms of fresh weight；3rd, citrus soil is in terms of dry weight.
From table 8 and table 9, insect on citrus is prevented and treated, dilute 1000 times using the present embodiment product sprays to citrus number
Dispenser, dispenser 2 times, 20 days away from last time dispenser harvesting tangerine meat and tangerine peel in do not detect（Less than minimum detectability amount）Ten
Eight alkyl trimethyl ammonium chlorides, therefore the composition pesticide of the present invention uses rear noresidue, it is safe to eat.
Environment-protecting pesticide bactericidal pesticide composition of the present invention, pesticide-germicide ability is strong, and prevention effect is good, to human toxicity
It is small, it is green, it is production green non-pollution food（Vegetables, melon and fruit etc.）Outstanding insecticidal bactericide.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge
Make a variety of changes.
So as to effectively kill worm's ovum.
Have no irritating odor, to user safety, on environment without influence.
Have no irritating odor, to user safety, on environment without influence.
Claims (9)
1. the composition pesticide of environment-protecting pesticide sterilization, it is characterised in that including insecticidal constituent, sterilization component and auxiliary element,
The quality parts ratio of the insecticidal constituent and the sterilization component is 3~6：1, matter of the auxiliary element in composition pesticide
It is 65%~80% to measure percentage；Wherein, insecticidal constituent is the mixing of OTAC, Nylar and benzene sulfonate
Thing, sterilization component are copper 8-hydroxyquinolinate, and auxiliary element includes cellulose, sucrose, boric acid, anhydrous sodium sulfate, amino acid fertilizer, salt and sunk
Face powder.
2. the composition pesticide of environment-protecting pesticide sterilization according to claim 1, it is characterised in that the auxiliary element bag
Component containing following quality parts ratio：8 parts~16 parts of cellulose, 4 parts~8 parts of sucrose, 16 parts~24 parts of boric acid, anhydrous sodium sulfate
11 parts~19 parts, 10 parts~18 parts of amino acid fertilizer, 2 parts~6 parts of 3 parts~7 parts of salt and agalloch eaglewood powder.
3. the composition pesticide of environment-protecting pesticide according to claim 1 sterilization, it is characterised in that the insecticidal constituent by
The composition composition of following parts by weight：4 parts ~ 10 parts of OTAC, 1 part ~ 5 parts of Nylar and benzene sulfonate 10
Part ~ 20 parts.
4. the composition pesticide of environment-protecting pesticide sterilization according to claim 1, it is characterised in that by following parts by weight
Composition composition：5 parts of OTAC, 2 parts of Nylar, 12 parts of cellulose, 13 parts of benzene sulfonate, 6 parts of sucrose,
4 parts of 20 parts of boric acid, 15 parts of anhydrous sodium sulfate, 14 parts of amino acid fertilizer, 5 parts of salt, 4 parts of agalloch eaglewood powder and copper 8-hydroxyquinolinate.
5. the composition pesticide of environment-protecting pesticide according to claim 1 sterilization, it is characterised in that the benzene sulfonate is
Neopelex or the octyl benzene sulfonic acid sodium salt of biguanides three.
6. the composition pesticide of environment-protecting pesticide sterilization according to claim 1, it is characterised in that the agalloch eaglewood powder is purple
Rowland agalloch eaglewood powder.
7. the composition pesticide of environment-protecting pesticide sterilization according to claim 1, it is characterised in that in the amino acid fertilizer
Containing 18 kinds of amino acid, whole total amino acid contents are 72 %.
8. the preparation method of the composition pesticide of the environment-protecting pesticide sterilization described in any one of claim 1~7, its feature exist
In comprising the following steps：
（1）First by formulation weight number in air-flow pulvis unit premixing tank, first octadecyl is added by predetermined weight percent
Trimethyl ammonium chloride, cellulose, crushing, stirring 5-10 minutes, then add benzene sulfonate, Nylar, sugarcane by predetermined weight percent
Sugar, boric acid, anhydrous sodium sulfate, amino acid powder, salt, agalloch eaglewood powder, copper 8-hydroxyquinolinate, crushing, stirring 5-10 minutes, obtain and slightly mix raw material；
（2）Raw material after above-mentioned steps (1) are slightly mixed through airslide disintegrating mill crush 15 minutes~25 minutes, and fineness reaches
500 mesh；
（3）By the first vacuum feeder and pipeline into double conic rotary vacuum dryer, 0.079-0.099 MPa,
10-15 minutes are dried under the conditions of 35-55 DEG C, then gained compound is delivered in two-dimensional motion mixer, are mixed 10 minutes
~20 minutes, obtain composition pesticide finished product.
9. the preparation method of the composition pesticide of environment-protecting pesticide sterilization according to claim 8, it is characterised in that also wrap
Include step（3）By gained finished product by vacuum feeding automatic packaging machine automatic measuring packing, that is, obtain composition pesticide product.
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Cited By (2)
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Application publication date: 20171212 |