CN113728466A - 负极材料、负极极片、电化学装置和电子装置 - Google Patents
负极材料、负极极片、电化学装置和电子装置 Download PDFInfo
- Publication number
- CN113728466A CN113728466A CN202080030134.1A CN202080030134A CN113728466A CN 113728466 A CN113728466 A CN 113728466A CN 202080030134 A CN202080030134 A CN 202080030134A CN 113728466 A CN113728466 A CN 113728466A
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- Prior art keywords
- silicon
- based material
- negative electrode
- conductive agent
- carbon
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Links
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- 239000002210 silicon-based material Substances 0.000 claims abstract description 119
- 239000006258 conductive agent Substances 0.000 claims abstract description 56
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- 239000003575 carbonaceous material Substances 0.000 claims abstract description 31
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 7
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- 239000010703 silicon Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 56
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
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- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- H01M4/02—Electrodes composed of, or comprising, active material
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
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Abstract
本公开提供了负极材料、负极极片、电化学装置和电子装置。负极材料包括硅基材料,其中,硅基材料的颗粒具有至少一个凹部,凹部的宽度为50nm~20μm,深度为50nm~10μm。本公开通过采用具有凹陷结构的硅基材料,这种凹陷结构给硅基材料留出一定的膨胀空间,解决了硅基材料的体积膨胀大的问题。另外,凹陷结构的硅基材料在与碳材料、导电剂等复合制成负极极片时,较小的碳材料颗粒和导电剂嵌入硅基材料的凹部,解决了凹陷结构的硅基负极材料压实密度不高的问题,弥补了凹陷结构体积能量密度低的缺陷。
Description
PCT国内申请,说明书已公开。
Claims (10)
- PCT国内申请,权利要求书已公开。
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PCT/CN2020/082267 WO2021195914A1 (zh) | 2020-03-31 | 2020-03-31 | 负极材料、负极极片、电化学装置和电子装置 |
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CN113728466A true CN113728466A (zh) | 2021-11-30 |
CN113728466B CN113728466B (zh) | 2024-05-14 |
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US (1) | US20230052928A1 (zh) |
EP (1) | EP4131486A4 (zh) |
CN (1) | CN113728466B (zh) |
WO (1) | WO2021195914A1 (zh) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130089783A1 (en) * | 2011-10-05 | 2013-04-11 | Ha-Na Yoo | Negative Active Material and Lithium Battery Containing the Negative Active Material |
CN105047892A (zh) * | 2015-08-03 | 2015-11-11 | 中国科学院宁波材料技术与工程研究所 | 多孔硅材料、其制备方法与应用 |
CN107482206A (zh) * | 2017-09-10 | 2017-12-15 | 绵阳梨坪科技有限公司 | 一种锂离子电池用稳定性佳复合负极材料的制备方法 |
CN108306006A (zh) * | 2018-01-31 | 2018-07-20 | 北京国能电池科技股份有限公司 | 负极材料、负极片及其制备方法、锂离子电池及其制备方法 |
CN108336342A (zh) * | 2018-02-28 | 2018-07-27 | 宁波富理电池材料科技有限公司 | Si/SiOx/C复合负极材料、其制备方法及锂离子电池 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US8148011B2 (en) * | 2006-05-31 | 2012-04-03 | Uchicago Argonne, Llc | Surface stabilized electrodes for lithium batteries |
CN110137485B (zh) * | 2019-06-26 | 2021-02-09 | 珠海冠宇电池股份有限公司 | 一种含有表面修饰膜的硅负极材料的制备方法 |
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2020
- 2020-03-31 WO PCT/CN2020/082267 patent/WO2021195914A1/zh unknown
- 2020-03-31 EP EP20928679.8A patent/EP4131486A4/en active Pending
- 2020-03-31 CN CN202080030134.1A patent/CN113728466B/zh active Active
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2022
- 2022-09-29 US US17/956,373 patent/US20230052928A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130089783A1 (en) * | 2011-10-05 | 2013-04-11 | Ha-Na Yoo | Negative Active Material and Lithium Battery Containing the Negative Active Material |
CN105047892A (zh) * | 2015-08-03 | 2015-11-11 | 中国科学院宁波材料技术与工程研究所 | 多孔硅材料、其制备方法与应用 |
CN107482206A (zh) * | 2017-09-10 | 2017-12-15 | 绵阳梨坪科技有限公司 | 一种锂离子电池用稳定性佳复合负极材料的制备方法 |
CN108306006A (zh) * | 2018-01-31 | 2018-07-20 | 北京国能电池科技股份有限公司 | 负极材料、负极片及其制备方法、锂离子电池及其制备方法 |
CN108336342A (zh) * | 2018-02-28 | 2018-07-27 | 宁波富理电池材料科技有限公司 | Si/SiOx/C复合负极材料、其制备方法及锂离子电池 |
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EP4131486A1 (en) | 2023-02-08 |
EP4131486A4 (en) | 2023-05-10 |
CN113728466B (zh) | 2024-05-14 |
WO2021195914A1 (zh) | 2021-10-07 |
US20230052928A1 (en) | 2023-02-16 |
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