CN113699613A - Insect-proof fabric and manufacturing method thereof - Google Patents

Insect-proof fabric and manufacturing method thereof Download PDF

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Publication number
CN113699613A
CN113699613A CN202110989503.6A CN202110989503A CN113699613A CN 113699613 A CN113699613 A CN 113699613A CN 202110989503 A CN202110989503 A CN 202110989503A CN 113699613 A CN113699613 A CN 113699613A
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CN
China
Prior art keywords
fabric
pesticide
polyethylene
antioxidant
insect repellent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110989503.6A
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Chinese (zh)
Inventor
陈美英
谢芹芳
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Fujian Yamei Industry & Trade Co ltd
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Fujian Yamei Industry & Trade Co ltd
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Filing date
Publication date
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Priority to CN202110989503.6A priority Critical patent/CN113699613A/en
Publication of CN113699613A publication Critical patent/CN113699613A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/106Radiation shielding agents, e.g. absorbing, reflecting agents
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/10Open-work fabrics
    • D04B21/12Open-work fabrics characterised by thread material
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene

Abstract

An insect-proof fabric is characterized in that: implanting pest repelling components into a fabric, wherein the fabric comprises the following components: polyethylene, insecticide and antioxidant, the weight ratio of each component is: the polyethylene accounts for 80-95% of the total amount, the pesticide accounts for 4-19% of the total amount, and the antioxidant accounts for 0.5-3% of the total amount. The pesticide is thiamethoxam or clothianidin. The invention has the unique point on the formula of the pest repellent, and creatively mixes the pest repellent into the raw materials of the fabric in the manufacturing process, so that the pesticide, the antioxidant, the ultraviolet-resistant additive and the color master batch are implanted into the polyethylene fabric, the pest repellent becomes a component of the fabric and coexists with the fabric to form a whole.

Description

Insect-proof fabric and manufacturing method thereof
Technical Field
The invention belongs to the field of insect-proof article production, and particularly belongs to insect-proof fabrics and a production method thereof.
Background
Nowadays, various countries in the world have the problem of pesticide residues with different degrees, and the pesticide residues can cause harm to agriculture, people and livestock. Due to unreasonable use of pesticides, particularly herbicides, the pesticide damage accidents are frequent, large-area yield reduction and even failure are often caused, and the agricultural production is seriously influenced; the acute poisoning accidents of people and animals can be caused by eating food containing a large amount of highly toxic and extremely toxic pesticide residues, and the chronic poisoning of people and animals can be caused although acute poisoning can not be caused by eating agricultural and sideline products with pesticide residues exceeding the standard after long-term eating, so that diseases such as neurological diseases, cancers, genetic defects and the like can be caused, and even the next generation can be influenced. According to the big pesticide data, the pesticide usage amount in 2017 and 2019 in China is 165.51 ten thousand tons, the pesticide usage amount in 2018 is 150.36 ten thousand tons, and the pesticide usage amount in 2019 is 139.17 ten thousand tons, so that the pesticide yield and usage amount in China are the first in the world. And pesticide poisoning accidents in China are 10 ten thousand times per year, and tens of thousands of people die.
Due to the pursuit of health, many people begin to have a unique look at "pesticide-free" and "organic" agricultural products. It is known that if plants do not use pesticides, insect pests can not be avoided at all to seriously affect the growth and yield of the plants, and the use of low-toxicity and pollution-free biological pesticides is not only high in price but also slow in effect, wastes manpower and material resources, and thus has certain influence on the quality of crops such as fruits and vegetables. The method depends on manual capture, is only suitable for family planting, and is almost impossible in production type planting, in a word, agricultural products without pesticides and organic products are rare and can not meet the daily life requirements of common people.
Disclosure of Invention
The invention aims to overcome the defect that pesticides have to be used for preventing insects in the existing planting industry, and provides an insect-preventing fabric which can reduce the pesticide consumption or can protect plants from insect pests without pesticides and a manufacturing method thereof.
The technical scheme adopted by the invention is an insect-proof fabric, which is characterized in that: implanting pest repelling components into a fabric, wherein the fabric comprises the following components: polyethylene, insecticide and antioxidant, the weight ratio of each component is: the polyethylene accounts for 80-95% of the total amount, the pesticide accounts for 4-19% of the total amount, and the antioxidant accounts for 0.5-3% of the total amount.
The invention creatively implants the pest repelling component on the fiber of the fabric, so that the pest repelling medicine becomes a component of the fabric and coexists with the fabric to form a whole, and the pest repelling medicine is not stored on the surface of the fabric but is wrapped by polyethylene, is slowly released, is resistant to rain washing and can keep the pesticide effect for a long time. The invention is made into plant, fruit and vegetable covering, the covering is not contacted with the plant through the supporting object, physical isolation is formed between pests and the plant, and the pests are driven and killed through the emitted smell, etc., so as to ensure that the plant is not damaged by the pests and achieve the purpose of reducing pesticide or not using the pesticide.
Further: the fabric is also added with an anti-ultraviolet additive, and the anti-ultraviolet additive accounts for 0.05 to 1 percent of the total amount. Because the product is applied outdoors, the addition of the ultraviolet resistant additive components is beneficial to prolonging the service life of the product.
The components of the fabric are also added with color master batches, and the color master batches account for 0.4 to 1 percent of the total weight. In order to meet the color requirement of people on the fabric, the color master batch is added into the components of the fabric, and the color master batch is a finished product and can be purchased and obtained.
The pesticide is thiamethoxam or clothianidin.
A method for preparing the insect-proof fabric is characterized in that: granulating each component with polyethylene, uniformly fusing all the granules together, drawing wire, warp-knitting to form mesh cloth, cutting, sewing, and finally forming the long-acting insect-proof mesh fabric.
Specifically, the method comprises the following steps: the manufacturing steps are as follows: a) preparing pesticide into drug master batch;
b) preparing anti-ultraviolet particles;
c) preparing antioxidant particles;
d) uniformly mixing and stirring all the obtained granules according to a certain proportion, uniformly melting the granules on a wire drawing machine at 130 ℃, drawing wires, and then performing warp knitting and knitting process flows to form the mesh cloth.
The invention creatively prepares a small amount of polyethylene and pesticide into high-content particles, then mixes the particles with the polyethylene during production, and achieves the purpose of uniform mixing by uniformly mixing the particles and remelting.
And d), adding the color master batch and each raw material particle in the step d), mixing and melting, drawing on a wire drawing machine, and then performing subsequent processing.
The step a) of preparing the pesticide into the pesticide master batch refers to adding the pesticide into polyethylene, putting the mixture into a stirrer to be uniformly stirred and fused, and then introducing the mixture into a granulator to granulate at 120-130 ℃ to form the pesticide master batch containing 15-25% of the pesticide.
The step b) of preparing the anti-ultraviolet particles: adding the uvioresistant additive into polyethylene, stirring in a stirrer to fuse, and granulating at 120-130 deg.C in a granulator to obtain granules containing 7-12% of uvioresistant additive.
The step C) of preparing the antioxidant particles refers to adding the antioxidant into polyethylene, putting the mixture into a stirrer, stirring the mixture evenly and fusing the mixture, and then introducing the mixture into a granulator to granulate at the temperature of between 110 and 125 ℃ to form particles containing 8 to 12 percent of the antioxidant.
The invention adds pesticide, antioxidant and color master batch into polyethylene, except that the invention has a unique point on the formula of the pest repellent, the invention also creatively mixes the pest repellent into the raw materials of the fabric in the production, so that the pesticide, the antioxidant, the ultraviolet resistant additive and the color master batch are implanted into the polyethylene fabric, and the pest repellent becomes a component of the fabric and coexists with the fabric to form a whole.
Detailed Description
The present invention is described in detail below to enable those skilled in the art to understand the present invention more clearly.
An insect-proof fabric, wherein a component for repelling pests is implanted into a raw material of the fabric, and the fabric comprises the following components: polyethylene, insecticide and antioxidant, the weight ratio of each component is: the polyethylene accounts for 80-95% of the total amount, the pesticide accounts for 4-19% of the total amount, and the antioxidant accounts for 0.5-3% of the total amount. The pesticide is thiamethoxam or clothianidin.
The invention creatively implants the pest repelling component on the fiber of the fabric, so that the pest repelling medicine becomes a component of the fabric and coexists with the fabric to form a whole, and the pest repelling medicine is not stored on the surface of the fabric but is wrapped by polyethylene, is slowly released, is resistant to rain washing and can keep the pesticide effect for a long time. The invention is made into plant, fruit and vegetable covering, the covering is not contacted with the plant through the supporting object, physical isolation is formed between pests and the plant, and the pests are driven and killed through the emitted smell, etc., so as to ensure that the plant is not damaged by the pests and achieve the purpose of reducing pesticide or not using the pesticide.
The fabric is characterized in that the fabric also comprises an anti-ultraviolet additive and color master batches, wherein the anti-ultraviolet additive accounts for 0.05 to 1 percent of the total weight, and the color master batches account for 0.4 to 1 percent of the total weight. In order to meet the color requirement of people on the fabric, the color master batch is added into the components of the fabric, and the color master batch is a finished product and can be purchased and obtained.
The method for making the insect-proof fabric includes the steps of granulating each component with polyethylene, fully and uniformly fusing all the granules together, drawing wires, knitting to form a net cloth, cutting, sewing and finally forming the long-acting insect-proof net fabric.
Specifically, the method comprises the following steps: the manufacturing steps are as follows: a) preparing pesticide into drug master batch;
b) preparing anti-ultraviolet particles;
c) preparing antioxidant particles;
d) uniformly mixing and stirring all the obtained granules according to a certain proportion, uniformly melting the granules on a wire drawing machine at 130 ℃, drawing wires, and then performing warp knitting and knitting process flows to form the mesh cloth.
The invention creatively prepares a small amount of polyethylene and pesticide into high-content particles, then mixes the particles with the polyethylene during production, and achieves the purpose of uniform mixing by uniformly mixing the particles and remelting.
And d), adding the color master batch and each raw material particle in the step d), mixing and melting, drawing on a wire drawing machine, and then performing subsequent processing.
The step a) of preparing the pesticide into the pesticide master batch refers to adding the pesticide into polyethylene, putting the mixture into a stirrer to be uniformly stirred and fused, and then introducing the mixture into a granulator to granulate at 120-130 ℃ to form the pesticide master batch containing 15-25% of the pesticide.
The step b) of preparing the anti-ultraviolet particles: adding the uvioresistant additive into polyethylene, stirring in a stirrer to fuse, and granulating at 120-130 deg.C in a granulator to obtain granules containing 7-12% of uvioresistant additive.
The step C) of preparing the antioxidant particles refers to adding the antioxidant into polyethylene, putting the mixture into a stirrer, stirring the mixture evenly and fusing the mixture, and then introducing the mixture into a granulator to granulate at the temperature of between 110 and 125 ℃ to form particles containing 8 to 12 percent of the antioxidant.
Example 1:
an insect-proof fabric, namely, the fabric material is evenly mixed with the effective components for repelling pests, and the components of the insect-proof fabric are as follows: polyethylene, insecticide and antioxidant, the weight ratio of each component is: the polyethylene accounts for 80-95% of the total amount, the pesticide accounts for 4-19% of the total amount, and the antioxidant accounts for 0.5-3% of the total amount. The pesticide is thiamethoxam or clothianidin.
Granulating the above components with polyethylene, melting the granules together, drawing on a wire drawing machine, knitting to form mesh, cutting, and sewing to obtain the final product.
The manufacturing method of the insect-proof fabric comprises the following steps:
1. 80kg of 100% polyethylene and 20.4kg of 97% thiamethoxam or clothianidin are put into a stirrer to be uniformly stirred for 30 minutes for fusion, and then the mixture is introduced into a granulator to be granulated at the temperature of 120-130 ℃ to form medicine master batches containing 20% thiamethoxam or clothianidin, and the medicine master batches are delivered out at the speed of 20-28 m/min;
2. 90kg of 100 percent polyethylene and 10.2kg of 98 percent antioxidant are put into a stirrer to be uniformly stirred for 30 minutes for fusion, and then the mixture is introduced into a granulator to be granulated at the temperature of 110 ℃ to 125 ℃ to form particles containing 10 percent antioxidant; the particles are delivered at a speed of 20-28 m/min;
3. taking: 40kg of 100% raw material polyethylene and 45kg of thiamethoxam or clothianidin drug master batch obtained in the step 2; and (3) adding 15kg of antioxidant particles obtained in the step (3) into a stirrer respectively, fully and uniformly stirring for 30 minutes for melting, drawing wires on a wire drawing machine at the temperature of 120-130 ℃, and then forming a mesh fabric through warp knitting and braiding.
The effective component thiamethoxam or clothianidin of the technology has obvious effect on preventing and treating insect pests. Wherein the thiamethoxam is a second generation nicotine low-toxicity insecticide with a brand new structure which is well known to all people, and the chemical formula of the thiamethoxam is C8H10ClN5O3S, among a plurality of insecticides, thiamethoxam has unique advantages, such as low toxicity, high efficiency, safety and the like. Thiamethoxam has stomach toxicity, contact killing and systemic activity on pests, so that the thiamethoxam has a good effect on piercing-sucking pests, such as aphids, plant hoppers, leafhoppers, whiteflies and the like, and can be sprayed. In the actual use process, thiamethoxam can be used for pests such as scarab larva, potato beetle, nematode, ground beetle, leaf miner and the like besides aphid, plant hopper, leafhopper and whitefly. Therefore, the thiamethoxam is widely applied to insect-resistant active ingredients of crops, fruit trees and greening plants.
Clothianidin is an organic compound with a molecular formula of C6H8ClN5O2And S. Clothianidin is an insecticide in neonicotinoids, is a novel efficient, safe and high-selectivity insecticide, has similar action to nicotinic acetylcholine receptors, and has contact poisoning, stomach toxicity and systemic activity. The pesticide is mainly used for preventing and controlling hemiptera, coleopteran, dipteran and certain lepidopteran pests such as aphids, leafhoppers, thrips, plant hoppers and the like on rice, vegetables, fruit trees and other crops, has the advantages of high efficiency, broad spectrum, low dosage, low toxicity, long efficacy duration, no phytotoxicity to the crops, safe use, no cross resistance with conventional pesticides and the like, has excellent systemic and osmotic effects, and is another variety for replacing high-toxicity organophosphorus pesticides.
Example 2
The ultraviolet resistant additive is added on the basis of the embodiment 1, so that the product can resist sunlight irradiation and has longer service life.
Preparing ultraviolet-resistant particles: adding the uvioresistant additive into polyethylene, stirring in a stirrer to fuse, and granulating at 120-130 deg.C in a granulator to obtain granules containing 10% of uvioresistant additive.
Taking: 40kg of 100% raw material polyethylene, 45kg of thiamethoxam or clothianidin drug master batch obtained in example 1, 15kg of antioxidant particles and 0.5 kg of ultraviolet-resistant particles obtained in the previous step are respectively added into a stirrer to be fully and uniformly stirred for 30 minutes for melting, then wire drawing is carried out on a wire drawing machine at 120-130 ℃, and then the mesh cloth is formed through warp knitting and weaving.
Example 3
The color master batch is added on the basis of the embodiment 1 or 2, and the amount of the added color master batch is generally between 0.4 and 1 percent, and in the embodiment, between 0.5 and 0.6 percent, and about 0.6kg mainly according to the color matching requirement.
Example 4
Taking: 40kg of 100% raw material polyethylene, 50kg of thiamethoxam or clothianidin drug master batch obtained in example 1, 10kg of antioxidant particles, 1kg of ultraviolet-resistant particles obtained in example 2 and 1kg of color master batch are respectively added into a stirrer to be fully and uniformly stirred for 30 minutes for melting, and then wire drawing is carried out on a wire drawing machine at 120-130 ℃, and then mesh cloth is formed through warp knitting and weaving.
The invention aims to solve the problem of pesticide residue, and the principle of the invention is to cover crops or other plants by utilizing a long-acting insect-proof net which is woven by planting effective insecticidal components inside, thereby avoiding the plants from directly contacting and absorbing pesticide residue, and the physical pest-killing mode solves the defect of pesticide spraying and pest repelling.
The above embodiments are only for illustrating the technical idea of the present invention, and the protection scope of the present invention is not limited thereby, and any modifications and equivalents made on the basis of the technical idea of the present invention fall within the protection scope of the present invention.

Claims (10)

1. An insect repellent fabric, comprising: implanting pest repelling components into a fabric, wherein the fabric comprises the following components: polyethylene, insecticide and antioxidant, the weight ratio of each component is: the polyethylene accounts for 80-95% of the total amount, the pesticide accounts for 4-19% of the total amount, and the antioxidant accounts for 0.5-3% of the total amount.
2. The insect repellent fabric according to claim 1, wherein: the fabric is also added with an anti-ultraviolet additive, and the anti-ultraviolet additive accounts for 0.05 to 1 percent of the total amount.
3. The insect repellent fabric according to claim 1, wherein: color master batches are also added into the components of the fabric.
4. The insect repellent fabric according to claim 1, wherein: the pesticide is thiamethoxam or clothianidin.
5. A method of making an insect repellent fabric according to any one of claims 1 to 4, wherein: granulating each component with polyethylene, uniformly fusing all the granules together, drawing wire, warp-knitting to form mesh cloth, cutting, sewing, and finally forming the long-acting insect-proof mesh fabric.
6. The method for making an insect repellent fabric as claimed in claim 4, wherein: the manufacturing steps are as follows: a) preparing pesticide into drug master batch;
b) preparing anti-ultraviolet particles;
c) preparing antioxidant particles;
d) uniformly mixing and stirring all the obtained granules according to a certain proportion, uniformly melting the granules on a wire drawing machine at 130 ℃, drawing wires, and then performing warp knitting and knitting process flows to form the mesh cloth.
7. The method for making an insect repellent fabric as claimed in claim 6, wherein: and d), adding the color master batch and each raw material particle in the step d), mixing and melting, drawing on a wire drawing machine, and then performing subsequent processing.
8. The method for making an insect repellent fabric as claimed in claim 6, wherein: the step a) of preparing the pesticide into the pesticide master batch refers to adding the pesticide into polyethylene, putting the mixture into a stirrer to be uniformly stirred and fused, and then introducing the mixture into a granulator to granulate at 120-130 ℃ to form the pesticide master batch containing 15-25% of the pesticide.
9. The method for making an insect repellent fabric as claimed in claim 6, wherein: the step b) of preparing the anti-ultraviolet particles: adding the uvioresistant additive into polyethylene, stirring in a stirrer to fuse, and granulating at 120-130 deg.C in a granulator to obtain granules containing 7-12% of uvioresistant additive.
10. The method for making an insect repellent fabric as claimed in claim 6, wherein: the step C) of preparing the antioxidant particles refers to adding the antioxidant into polyethylene, putting the mixture into a stirrer, stirring the mixture evenly and fusing the mixture, and then introducing the mixture into a granulator to granulate at the temperature of between 110 and 125 ℃ to form particles containing 8 to 12 percent of the antioxidant.
CN202110989503.6A 2021-08-26 2021-08-26 Insect-proof fabric and manufacturing method thereof Pending CN113699613A (en)

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WO2024082086A1 (en) * 2022-10-17 2024-04-25 山东金冠网具有限公司 Weed control net having insecticidal function owing to soot radiation, and method for preparing weed control net
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024082086A1 (en) * 2022-10-17 2024-04-25 山东金冠网具有限公司 Weed control net having insecticidal function owing to soot radiation, and method for preparing weed control net
WO2024082087A1 (en) * 2022-10-17 2024-04-25 山东金冠网具有限公司 Preparation method for insect-proof net containing nano sustained-release agent
CN115852522A (en) * 2022-11-25 2023-03-28 福建德孚新材料科技有限公司 Formula of long-acting insect-repellent net and manufacturing method thereof

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