CN107057157A - A kind of printing opacity fly net master batch and preparation method thereof - Google Patents
A kind of printing opacity fly net master batch and preparation method thereof Download PDFInfo
- Publication number
- CN107057157A CN107057157A CN201710287883.2A CN201710287883A CN107057157A CN 107057157 A CN107057157 A CN 107057157A CN 201710287883 A CN201710287883 A CN 201710287883A CN 107057157 A CN107057157 A CN 107057157A
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- fly net
- master batch
- antioxidant
- printing opacity
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of printing opacity fly net master batch and preparation method thereof, master batch it is raw materials used including：Polyethylene, glass fibre, makrolon, TPUE, alkyl benzene sulfonic acid ester, coupling agent, antioxidant, ultra-violet absorber, ethylene bis stearic acid amide, soybean oil, toughener.The present invention compounds glass fibre and TPUE with polyethylene, makrolon the base-material as master batch, not only increases the translucency of fly net, can also improve the toughness of fly net.Fly net is made in master batch obtained by the present invention, the light transmittance of fly net reaches 80.3Mpa up to 82%, tensile strength in more than 22.3MPa, flexility.
Description
Technical field
The invention belongs to plastic master batch technical field, and in particular to a kind of printing opacity fly net master batch and preparation method thereof.
Background technology
The relevant data display of the World Health Organization, the whole world has 750,000 people to occur pesticide poisoning every year, wherein nearly 20,000
People dies.China counts according to the Ministry of Agriculture, the Ministry of Public Health in recent years, annual to occur pesticide poisoning number more than 100,000 people.Institute
There are these poisoners 70% above is being poisoned by food because of caused by vegetable residual pesticide.Therefore, reduce and reduce pollution by pesticides
It is current or even research topic very urgent and important in one section of period vegetable cultivation management work from now on.
Fly net is a kind of novel agricultural covering material occurred after agricultural film, sunshade net, using addition anti-aging, is resisted
The high-quality polyethylene of the chemical assistants such as ultraviolet is raw material, is formed through wire drawing weaving, is similar to window screening, with tension, heat resistanceheat resistant, resistance to
Water, it is corrosion-resistant, nonpoisonous and tasteless the features such as.Proved by agricultural practice both at home and abroad in the past few years, promoting the use of insect prevention network technology is
One kind reply pollution by pesticides more effective measures, the pollution-free vegetable produced using insect prevention network technology is extensively by vegetable grower and consumer
Welcome.
Fly net is with artificial constructed barrier, and the net that insect is refused is outer, reaches that the purpose of dish is protected in insect prevention, diseases prevention.In addition, anti-
The reflection of worm net, the light of refraction also have certain repellent action to insect.Cover fly net after, vegetables VC contents, clean vegetables rate compared with
Open country is high, and appearance luster is also good compared with open country, commercially well received, but blade Determination of Chlorophyll content relative reduction, nitrate
Content is compared with open country increase, and this may be relevant with fly net light-proofness.
The content of the invention
The technical problem of solution：It is an object of the invention to provide a kind of printing opacity fly net master batch and preparation method thereof.
Technical scheme：A kind of printing opacity fly net master batch, raw material includes in parts by weight：20-30 parts of polyethylene, glass fibers
4-7 parts of dimension, 1-3 parts of makrolon, 2-4 parts of TPUE, 0.8-1.5 parts of alkyl benzene sulfonic acid ester, coupling agent 3-7
Part, 1-5 parts of antioxidant, 0.8-1.5 parts of ultra-violet absorber, 0.3-1.2 parts of ethylene bis stearic acid amide, soybean oil 0.2-
0.7 part, 0.4-0.7 parts of toughener.
Further, the toughener be polymethyl methacrylate-butadiene-styrene terpolymer or ethene-
Butyl acrylate-glycidyl methacrylate copolymer.
Further, the coupling agent is silane coupler.
Further, the ultra-violet absorber is one kind in cerium oxide, titanium oxide, titanium oxide.
Further, the titanium oxide is Titanium Dioxide Rutile Top grade or anatase-type titanium oxide.
Further, the antioxidant is antioxidant 702, antioxidant 800, antioxidant 1010, antioxidant
501st, one or more of mixtures in antioxidant 168 or antioxidant 1726.
The preparation method of above-mentioned printing opacity fly net master batch, comprises the following steps：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
Further, the screw rod rotary speed control of extruder is in 60-70 rpm in step 3, and extrusion temperature control exists
160-180℃。
Beneficial effect：The present invention makees glass fibre and TPUE with polyethylene, makrolon compounding
For the base-material of master batch, the translucency of fly net is not only increased, the toughness of fly net can also be improved.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Obviously, described embodiment is only embodiment of the invention a part of, rather than whole embodiments.Based on the reality in the present invention
Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made all belongs to
In the scope of protection of the invention.
For a further understanding of the present invention, with reference to embodiment, the present invention will be described in detail, wherein, such as without special
Illustrate, the various reaction reagents being related in embodiment can be commercially available by commercial channel.
Embodiment 1
A kind of printing opacity fly net master batch, raw material includes in parts by weight：20 parts of polyethylene, 4 parts of glass fibre, makrolon 1
Part, 2 parts of TPUE, 0.8 part of alkyl benzene sulfonic acid ester, 3 parts of coupling agent, 1 part of antioxidant, ultra-violet absorber
0.8 part, 0.3 part of ethylene bis stearic acid amide, 0.2 part of soybean oil, 0.4 part of toughener.
Wherein, the toughener is polymethyl methacrylate-butadiene-styrene terpolymer；The coupling agent
For silane coupler；The ultra-violet absorber is cerium oxide；The antioxidant is antioxidant 702.
The preparation method of above-mentioned printing opacity fly net master batch, comprises the following steps：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
Further, the screw rod rotary speed control of extruder is in 60-70 rpm in step 3, and extrusion temperature control exists
160-180℃。
Fly net is made in gained master batch, the light transmittance of fly net reaches in 85%, tensile strength in 21.5MPa, flexility
To 79.8Mpa.
Embodiment 2
A kind of printing opacity fly net master batch, raw material includes in parts by weight：23 parts of polyethylene, 5 parts of glass fibre, makrolon
1.4 parts, 2.7 parts of TPUE, 1.1 parts of alkyl benzene sulfonic acid ester, 5 parts of coupling agent, 3 parts of antioxidant, ultraviolet
1.2 parts of absorbent, 0.7 part of ethylene bis stearic acid amide, 0.5 part of soybean oil, 0.5 part of toughener.
Wherein, the toughener is polymethyl methacrylate-butadiene-styrene terpolymer；The coupling agent
For silane coupler；The ultra-violet absorber is cerium oxide；The antioxidant is antioxidant 702.
The preparation method of above-mentioned printing opacity fly net master batch, comprises the following steps：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
Further, the screw rod rotary speed control of extruder is in 60-70 rpm in step 3, and extrusion temperature control exists
160-180℃。
Fly net is made in gained master batch, the light transmittance of fly net reaches in 87%, tensile strength in 20.9MPa, flexility
To 78.5Mpa.
Embodiment 3
A kind of printing opacity fly net master batch, raw material includes in parts by weight：28 parts of polyethylene, 6 parts of glass fibre, makrolon 2
Part, 3 parts of TPUE, 1.3 parts of alkyl benzene sulfonic acid ester, 5 parts of coupling agent, 4 parts of antioxidant, ultra-violet absorber
1.2 parts, 0.9 part of ethylene bis stearic acid amide, 0.6 part of soybean oil, 0.5 part of toughener.
Wherein, the toughener is polymethyl methacrylate-butadiene-styrene terpolymer；The coupling agent
For silane coupler；The ultra-violet absorber is cerium oxide；The antioxidant is antioxidant 702.
The preparation method of above-mentioned printing opacity fly net master batch, comprises the following steps：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
Further, the screw rod rotary speed control of extruder is in 60-70 rpm in step 3, and extrusion temperature control exists
160-180℃。
Fly net is made in gained master batch, the light transmittance of fly net reaches in 82%, tensile strength in 22.3MPa, flexility
To 80.3Mpa.
Embodiment 4
A kind of printing opacity fly net master batch, raw material includes in parts by weight：30 parts of polyethylene, 7 parts of glass fibre, makrolon 3
Part, 4 parts of TPUE, 1.5 parts of alkyl benzene sulfonic acid ester, 7 parts of coupling agent, 5 parts of antioxidant, ultra-violet absorber
1.5 parts, 1.2 parts of ethylene bis stearic acid amide, 0.7 part of soybean oil, 0.7 part of toughener.
Wherein, the toughener is polymethyl methacrylate-butadiene-styrene terpolymer；The coupling agent
For silane coupler；The ultra-violet absorber is cerium oxide；The antioxidant is antioxidant 702.
The preparation method of above-mentioned printing opacity fly net master batch, comprises the following steps：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
Further, the screw rod rotary speed control of extruder is in 60-70 rpm in step 3, and extrusion temperature control exists
160-180℃。
Fly net is made in gained master batch, the light transmittance of fly net reaches in 86%, tensile strength in 19.8MPa, flexility
To 82.3Mpa.
Claims (8)
1. a kind of printing opacity fly net master batch, it is characterised in that：Raw material includes in parts by weight：20-30 parts of polyethylene, glass fibers
4-7 parts of dimension, 1-3 parts of makrolon, 2-4 parts of TPUE, 0.8-1.5 parts of alkyl benzene sulfonic acid ester, coupling agent 3-7
Part, 1-5 parts of antioxidant, 0.8-1.5 parts of ultra-violet absorber, 0.3-1.2 parts of ethylene bis stearic acid amide, soybean oil 0.2-
0.7 part, 0.4-0.7 parts of toughener.
2. printing opacity fly net master batch according to claim 1, it is characterised in that：The toughener is polymethylacrylic acid
Methyl esters-butadiene-styrene terpolymer or Ethylene-butyl Acrylate-methacrylic Acid Glycerin Ester Copolymer.
3. printing opacity fly net master batch according to claim 1, it is characterised in that：The coupling agent is silane coupler.
4. printing opacity fly net master batch according to claim 1, it is characterised in that：The ultra-violet absorber is oxidation
One kind in cerium, titanium oxide, titanium oxide.
5. printing opacity fly net master batch according to claim 1, it is characterised in that：The titanium oxide is rutile-type oxidation
Titanium or anatase-type titanium oxide.
6. printing opacity fly net master batch according to claim 1, it is characterised in that：The antioxidant is antioxidant
702nd, antioxidant 800, antioxidant 1010, antioxidant 501, antioxidant 168 or one kind in antioxidant 1726 or
Several mixtures.
7. the preparation method of the printing opacity fly net master batch described in any one of claim 1 to 6, it is characterised in that：Including following
Step：
Step 1, polyethylene, glass fibre, makrolon, TPUE, coupling agent are mixed, heating stirring,
Stop stirring when mixed material temperature reaches 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 2, alkyl benzene sulfonic acid ester, antioxidant, ultra-violet absorber, toughener are mixed, heating stirring works as mixed material
Temperature stops stirring when reaching 120-140 DEG C, standing is cooled to 40-50 DEG C；
Step 3, two kinds of mixtures obtained by step 1 and step 2 are mixed, heating stirring, when temperature reaches 90-100 DEG C, plus
Enter ethylene bis stearic acid amide, soybean oil, stop stirring when temperature reaches 135 DEG C, standing is cooled to 40-50 DEG C, imports and squeezes
Go out in machine, then granulated.
8. the preparation method of printing opacity fly net master batch according to claim 7, it is characterised in that：Extruder in step 3
The control of screw rod rotary speed in 60-70 rpm, extrusion temperature is controlled at 160-180 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710287883.2A CN107057157A (en) | 2017-04-27 | 2017-04-27 | A kind of printing opacity fly net master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710287883.2A CN107057157A (en) | 2017-04-27 | 2017-04-27 | A kind of printing opacity fly net master batch and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107057157A true CN107057157A (en) | 2017-08-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710287883.2A Pending CN107057157A (en) | 2017-04-27 | 2017-04-27 | A kind of printing opacity fly net master batch and preparation method thereof |
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| Country | Link |
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| CN (1) | CN107057157A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107593211A (en) * | 2017-10-12 | 2018-01-19 | 蚌埠市天网渔需用品有限公司 | A kind of fly net for carrying anthelminthic effect |
| CN109126283A (en) * | 2018-08-22 | 2019-01-04 | 安徽利思达网业有限公司 | A kind of preparation method of sludge dewatering monofilament filter cloth |
| CN113699613A (en) * | 2021-08-26 | 2021-11-26 | 福建省亚美工贸有限公司 | Insect-proof fabric and manufacturing method thereof |
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| CN102655741A (en) * | 2009-12-25 | 2012-09-05 | 住友化学株式会社 | Insect pest controlling resin composition |
| CN103172943A (en) * | 2011-12-20 | 2013-06-26 | 邱力 | Preparation method of nanometer wave-absorbing plastic sunshade net |
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2017
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| CN103172943A (en) * | 2011-12-20 | 2013-06-26 | 邱力 | Preparation method of nanometer wave-absorbing plastic sunshade net |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107593211A (en) * | 2017-10-12 | 2018-01-19 | 蚌埠市天网渔需用品有限公司 | A kind of fly net for carrying anthelminthic effect |
| CN109126283A (en) * | 2018-08-22 | 2019-01-04 | 安徽利思达网业有限公司 | A kind of preparation method of sludge dewatering monofilament filter cloth |
| CN113699613A (en) * | 2021-08-26 | 2021-11-26 | 福建省亚美工贸有限公司 | Insect-proof fabric and manufacturing method thereof |
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Application publication date: 20170818 |
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