CN113652280A - 一种环保无氯型钛合金切削油及其制备方法 - Google Patents

一种环保无氯型钛合金切削油及其制备方法 Download PDF

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CN113652280A
CN113652280A CN202110912140.6A CN202110912140A CN113652280A CN 113652280 A CN113652280 A CN 113652280A CN 202110912140 A CN202110912140 A CN 202110912140A CN 113652280 A CN113652280 A CN 113652280A
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titanium alloy
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赵波
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Cyma Oil Products Zhenjiang Co ltd
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Abstract

本发明公开了一种环保无氯型钛合金切削油及其制备方法，包括如下以重量计算的制备原料：基础油2：15‑30％，油性剂：15‑30％，耦合剂：4‑7％，极压抗磨剂：12‑20％，分散剂：1‑3％，抗氧剂：0.5‑1.5％，聚和酯：2‑5％，磺酸钙：4％‑8％，余量为基础油1，所述的基础油1为W1‑130、W1‑140、W2‑130、W2‑140中的一种或多种的混合物。本发明提供的环保无氯型环保钛合金切削油，采用磺酸钙和聚和酯配合，替代传统方案中的氯化石蜡，解决氯化石蜡分解产物腐蚀工件、腐蚀机台问题。本发明提供的环保无氯型环保钛合金切削油，加入了低黏度的轻质白油，增加了切削油的散热性，使用过程中，切削油油温可降低10％，解决市面上切削油使用中油温高的问题。

Description

一种环保无氯型钛合金切削油及其制备方法
技术领域
本发明涉及一种环保无氯型钛合金切削油及其制备方法。
背景技术
钛合金材料具有质量轻，强度大，耐高温和耐腐蚀等特点，上至飞机、航天器，下至船舶、深潜器、石油开采、化学工业等行业得到了广泛的应用。随着钛冶炼技术和加工工艺的改进和完善，钛及钛合金产品品种也在进一步扩大，质量控制水平也进一步提升，其应用领域也在扩大。钛是目前医疗器械、人工关节、骨科植入物、心脏起搏器等的理想材质。在眼镜、珠宝、手机、电脑等民用休闲产品，钛合金也是未来的发展方向。
钛合金的是典型的难加工材质，主要有以下特点：
1、强度高，硬度大，要求加工设备的功率大；
2、切屑与前刀面接触面积小，刀尖应力大；
3、弹性模量小，刚性差，切削加工时，回弹大，容易造成剧烈摩擦、粘附、粘结磨损和工件变形。
4、高温下活性高，容易反应生成硬化层，增加钛合金表面硬度，极易造成崩刃现象，加剧刀具磨损。
5、导热系数小，切削温度高，刀具很容易产生粘结磨损。
钛合金加工过程中刀具寿命的关键因素，如何降低切削区域温度，增加散热速度，延长刀具使用寿命，提高加工效率，进一步降低钛合金产品的制造成本，是推动钛合金广泛应用的关键。
同时，社会环保意识越来越强，节能减排、解决环境污染是趋势，欧盟相关法规中已禁止使用短链、中链氯化石蜡，长链氯化石蜡的使用问题也是备受争议。氯化石蜡稳定性差，再加上钛合金切削过程中温度高，极易分解，产生氯气、氯化氢等有毒有害气体，严重危害健康，长期接触刺激呼吸系统、刺激皮肤，严重者可导致肝肾功能损害。分解产生的氯气、氯化氢等还会导致机床、模具生锈，设备故障，设备维修保养成本大幅增加。
因此，环保无氯型钛合金切削油是发展的趋势，也是本发明要解决的关键技术问题。
目前国内现有的钛合金切削油，基本仍然采用氯化石蜡，高活性硫化极压剂、含磷极压剂、动物油、植物油、合成酯等添加剂，虽然可获得极高的润滑性，但此类物质带来的腐蚀性强，分解产物腐蚀工件、腐蚀机台不环保。
现有的无氯切削油为了获得高的油膜强度，采用高黏度基础油，切削油的整体散热性差，使用过程中，切削油油温高，机台、工件烫手，人工操作不方便。
发明内容
本发明的目的是为了解决以上现有技术的不足，提供一种环保无氯型钛合金切削油及其制备方法。
一种环保无氯型钛合金切削油，包括如下以重量计算的制备原料：基础油2：15-30％，油性剂：15-30％，耦合剂：4-7％，极压抗磨剂：12-20％，分散剂：1-3％，抗氧剂：0.5-1.5％，聚和酯：2-5％，磺酸钙：4％-8％，余量为基础油1，所述的基础油1为W1-130、W1-140、W2-130、W2-140中的一种或多种的混合物。
作为进一步改进，所述的基础油2为60N、75N、100N、150N中的一种或多种的混合物。
作为进一步改进，所述的油性剂包括多元醇酯和单酯，多元醇酯和单酯的质量比为：1:1～5:1，多元醇酯为三羟甲基丙烷油酸酯、季戊四醇油酸酯、油酸乙二醇酯中的一种或多种的混合物，单酯为油酸甲酯、油酸异辛酯、棕榈酸异辛酯、硬脂酸正丁酯、硬脂酸异辛酯中的一种或多种的混合物。
作为进一步改进，所述的耦合剂为月桂醇、C12格尔伯特醇、C16格尔伯特醇、C18格尔伯特醇、C20格尔伯特醇中的一种或多种的混合物。
作为进一步改进，所述的极压抗磨剂为硫化脂肪酸甲酯、硫化甘油三酸酯、硫化烯烃、二烷基二硫代氨基甲酸酯、二叔十二烷基三硫化物、二叔十二烷基五硫化物中的一种或多种的混合物。
作为进一步改进，所述的分散剂为聚异丁烯双丁二酰亚胺、硼化聚异丁烯双丁二酰亚胺中的一种或多种的混合物。
作为进一步改进，所述的抗氧剂包括胺类抗氧剂和酚类抗氧剂，胺类抗氧剂为二壬基二苯胺、二辛基二苯胺或丁基辛基二苯胺，酚类抗氧剂为2,6-二叔丁基对甲酚，胺类抗氧剂和酚类抗氧剂质量比值为1:2。
作为进一步改进，所述的聚和酯为Priolube 3986、perfad 8100、Perfad8400、SYNESTER GY 10、SYN ESTER GY 59、SYN ESTER GY 500、Hostagliss1510、PALUB 8466中的一种或多种的混合物。
作为进一步改进，所述的磺酸钙为结晶型磺酸钙和无定型磺酸钙的混合物，结晶型磺酸钙的总碱值大于或等于400mgKOH/g，其核心碳酸钙晶型为方解石形态，粒径大小在20-40nm之间，无定型磺酸钙总碱值大于或等于400mgKOH/g，结晶型磺酸钙和无定型磺酸钙的比值为1:1。
一种环保无氯型钛合金切削油的制备方法，包括以下步骤：
(1)将各组分按比例依次投入调和釜中；
(2)开启搅拌，速度控制在100-200r/min；
(3)开启升温，至温度50-60℃；
(4)保温搅拌30-40min即得成品。
有益效果：
本发明提供的环保无氯型环保钛合金切削油，采用磺酸钙和聚和酯配合，替代传统方案中的氯化石蜡，解决氯化石蜡分解产物腐蚀工件、腐蚀机台问题。
本发明提供的环保无氯型环保钛合金切削油，加入了低黏度的轻质白油，增加了切削油的散热性，使用过程中，切削油油温可降低10％，解决市面上切削油使用中油温高的问题。
具体实施方式
实施例1：
一种环保无氯型钛合金切削油的配方以重量计算包括如下组分：
Figure BDA0003204055060000041
实施例2：
一种环保无氯型钛合金切削油的配方以重量计算包括如下组分：
Figure BDA0003204055060000051
实施例3：
一种环保无氯型钛合金切削油的配方以重量计算包括如下组分：
Figure BDA0003204055060000052
Figure BDA0003204055060000061
环保无氯型钛合金切削油技术指标：
Figure BDA0003204055060000062
上机测试结果：
Figure BDA0003204055060000063
测试结果反馈，实施例3提供的切削油差于市面上传统的含氯切削油，但是优于市面上无氯切削油，实施例2提供的切削油与市面上传统含氯切削油性能相似，实施例1提供的切削油在测试中，各项性能指标均超过了市面上传统的含氯切削油和无氯切削油。

Claims (10)

1.一种环保无氯型钛合金切削油，其特征在于，包括如下以重量计算的制备原料：基础油2：15-30％，油性剂：15-30％，耦合剂：4-7％，极压抗磨剂：12-20％，分散剂：1-3％，抗氧剂：0.5-1.5％，聚和酯：2-5％，磺酸钙：4％-8％，余量为基础油1，所述的基础油1为W1-130、W1-140、W2-130、W2-140中的一种或多种的混合物。
2.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的基础油2为60N、75N、100N、150N中的一种或多种的混合物。
3.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的油性剂包括多元醇酯和单酯，多元醇酯和单酯的质量比为：1:1～5:1，多元醇酯为三羟甲基丙烷油酸酯、季戊四醇油酸酯、油酸乙二醇酯中的一种或多种的混合物，单酯为油酸甲酯、油酸异辛酯、棕榈酸异辛酯、硬脂酸正丁酯、硬脂酸异辛酯中的一种或多种的混合物。
4.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的耦合剂为月桂醇、C12格尔伯特醇、C16格尔伯特醇、C18格尔伯特醇、C20格尔伯特醇中的一种或多种的混合物。
5.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的极压抗磨剂为硫化脂肪酸甲酯、硫化甘油三酸酯、硫化烯烃、二烷基二硫代氨基甲酸酯、二叔十二烷基三硫化物、二叔十二烷基五硫化物中的一种或多种的混合物。
6.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的分散剂为聚异丁烯双丁二酰亚胺、硼化聚异丁烯双丁二酰亚胺中的一种或多种的混合物。
7.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的抗氧剂包括胺类抗氧剂和酚类抗氧剂，胺类抗氧剂为二壬基二苯胺、二辛基二苯胺或丁基辛基二苯胺，酚类抗氧剂为2,6-二叔丁基对甲酚，胺类抗氧剂和酚类抗氧剂质量比值为1:2。
8.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的聚和酯为Priolube 3986、perfad 8100、Perfad 8400、SYN ESTER GY 10、SYN ESTER GY 59、SYNESTER GY 500、Hostagliss 1510、PALUB 8466中的一种或多种的混合物。
9.根据权利要求1所述的一种环保无氯型钛合金切削油，其特征在于，所述的磺酸钙为结晶型磺酸钙和无定型磺酸钙的混合物，结晶型磺酸钙的总碱值大于或等于400mgKOH/g，其核心碳酸钙晶型为方解石形态，粒径大小在20-40nm之间，无定型磺酸钙总碱值大于或等于400mgKOH/g，结晶型磺酸钙和无定型磺酸钙的比值为1:1。
10.一种环保无氯型钛合金切削油的制备方法，其特征在于，包括以下步骤：
(1)将各组分按比例依次投入调和釜中；
(2)开启搅拌，速度控制在100-200r/min；
(3)开启升温，至温度50-60℃；
(4)保温搅拌30-40min即得成品。
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